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JPH0472398B2 - - Google Patents
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JPH0472398B2 - - Google Patents

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Publication number
JPH0472398B2
JPH0472398B2 JP58219086A JP21908683A JPH0472398B2 JP H0472398 B2 JPH0472398 B2 JP H0472398B2 JP 58219086 A JP58219086 A JP 58219086A JP 21908683 A JP21908683 A JP 21908683A JP H0472398 B2 JPH0472398 B2 JP H0472398B2
Authority
JP
Japan
Prior art keywords
chip carrier
printed wiring
wiring board
preheating
heating
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
JP58219086A
Other languages
Japanese (ja)
Other versions
JPS60111497A (en
Inventor
Hiromi Ogawa
Kenro Kimata
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Ibiden Co Ltd
Original Assignee
Ibiden Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Ibiden Co Ltd filed Critical Ibiden Co Ltd
Priority to JP21908683A priority Critical patent/JPS60111497A/en
Publication of JPS60111497A publication Critical patent/JPS60111497A/en
Publication of JPH0472398B2 publication Critical patent/JPH0472398B2/ja
Granted legal-status Critical Current

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  • Electric Connection Of Electric Components To Printed Circuits (AREA)

Description

【発明の詳細な説明】 本発明は、チツプキヤリアの塔載接続方法とそ
の装置に係り、特に本発明は有機系樹脂素材基板
のプリント配線板上に有機系樹脂素材の基板から
成るチツプキヤリアを塔載し、上面側より赤外線
ヒータで、他方下側面よりブロツクヒータで加熱
してハンダペーストをリフローすることにより基
板の反りや歪みを防止して簡易迅速に接続するこ
とを特徴とするチツプキヤリアの塔載接続方法と
その装置に関する。
DETAILED DESCRIPTION OF THE INVENTION The present invention relates to a method and device for connecting a chip carrier, and in particular, the present invention relates to a method for mounting a chip carrier on a printed wiring board made of an organic resin material substrate. This chip carrier mounting connection is characterized in that it prevents warping and distortion of the board by heating it with an infrared heater from the top side and a block heater from the bottom side to reflow the solder paste, making the connection simple and quick. Concerning methods and apparatus.

従来は高密度実装などの要求からセラミツクス
製基板のリードレスチツプキヤリアが開発されて
いた。
In the past, leadless chip carriers made of ceramic substrates were developed to meet requirements such as high-density packaging.

しかしながら、上記セラミツクス製のチツプキ
ヤリアは、熱膨張係数の関係で同質のセラミツク
ス製基板のプリント配線板にしか塔載し実装する
ことができず、セラミツクス製基板は一般に比重
が大きく全体の重量が重くなると共に、耐熱衝撃
性が小さいために一定の板厚、例えば2〜5mm位
の板厚のものが用いられており、最近の電子部品
の軽薄短小化に伴う高密度実装に追従してゆくに
は不利である。しかも電子部品を塔載した部分を
保護するためにフリツト接合などによる気密封止
やロウ付け加工を必要とすることから機密封止が
可能である反面、作業が煩雑であり使用する材料
が高価なことからコスト高になる欠点があつた。
一方、異種金属板の貼合せにより熱膨張係数をセ
ラミツクス質基板と同等にした金属製基板が開発
されているが、高価であり、未だに一般に普及さ
れていない。
However, due to the coefficient of thermal expansion, the ceramic chip carrier described above can only be mounted on a printed wiring board made of a homogeneous ceramic substrate, and ceramic substrates generally have a large specific gravity, resulting in a heavy overall weight. At the same time, due to its low thermal shock resistance, a fixed plate thickness, for example, 2 to 5 mm, is used, and in order to keep up with the high-density packaging associated with the recent miniaturization of electronic components. It is disadvantageous. Moreover, in order to protect the parts on which electronic components are mounted, air-tight sealing using frit bonding or brazing is required, so although air-tight sealing is possible, the work is complicated and the materials used are expensive. This resulted in the drawback of high costs.
On the other hand, a metal substrate has been developed that has a coefficient of thermal expansion equal to that of a ceramic substrate by laminating dissimilar metal plates, but it is expensive and has not yet been widely used.

本発明は、このような従来の事情に鑑み、セラ
ミツクス製のチツプキヤリアを有機系樹脂素材の
チツプキヤリアに変更するとによつて、同等の熱
膨張係数の有機系樹脂素材の基板上に同質のチツ
プキヤリアの塔載を短時間内で行うことを可能と
し、該基板とチツプキヤリアの端子間のハンダ接
続に伴う加熱による有機系樹脂素材の基板の反り
や焦げ変質を防止することを目的とするチツプキ
ヤリアの塔載接続方法とその装置を提案するもの
である。
In view of such conventional circumstances, the present invention has been developed by replacing the chip carrier made of ceramic with a chip carrier made of an organic resin material, thereby creating a chip carrier tower of the same quality on a substrate made of an organic resin material with an equivalent coefficient of thermal expansion. A chip carrier mounting connection that enables mounting to be carried out within a short period of time, and is intended to prevent warping and scorching of organic resin material substrates due to heating caused by solder connections between the substrate and the terminals of the chip carrier. This paper proposes a method and its apparatus.

以下、本発明の方法と装置を詳細に説明するに
当り、図面と実施例とに基づいて具体的に説明す
る。
DESCRIPTION OF THE PREFERRED EMBODIMENTS In the following, the method and apparatus of the present invention will be explained in detail based on drawings and embodiments.

第1図は有機系樹脂素材の基板を用いたプリン
ト配線板の裏面側からブロツクヒータなどで直接
熱伝導により加熱してハンダペーストをリフロー
させる状態の側面概要図である。この図面におい
て、1はヒータであり、最も代表的なのがセラミ
ツクスヒータと称される熱伝導による加熱装置で
ある。2は有機系樹脂素材の基板を用いたプリン
ト配線板であり、最も代表的なものはガラス繊維
強化エポキシ樹脂銅張り基板(以下、便宜上「ガ
ラエポ基板」とも略称する)であり、その他、
紙、フエノール樹脂基板、紙、エポキシ樹脂基
板、ポリイミド樹脂基板、変性トリアジン樹脂基
板などがある。なお、tは該基板の反り矢高を示
すものであり、基板の裏面側からの加熱により通
常凹反りが生ずる。すなわち、例えばガラエポ基
板から成るプリント配線板は、その表面や裏面に
形成された導体回路の粗密の差並びにプラスチツ
クと導体回路との熱膨張収縮の差で、加熱による
歪や反りが生じ易い。
FIG. 1 is a schematic side view of a printed wiring board using a substrate made of an organic resin material, in which solder paste is reflowed by heating by direct thermal conduction from the back side with a block heater or the like. In this drawing, reference numeral 1 denotes a heater, the most typical of which is a heating device based on thermal conduction called a ceramic heater. 2 is a printed wiring board using a substrate made of an organic resin material, the most typical one being a glass fiber reinforced epoxy resin copper-clad board (hereinafter also abbreviated as "glass epoxy board" for convenience);
Examples include paper, phenol resin substrates, paper, epoxy resin substrates, polyimide resin substrates, and modified triazine resin substrates. Note that t indicates the height of the warp of the substrate, and concave warpage usually occurs due to heating from the back side of the substrate. That is, a printed wiring board made of a glass epoxy board, for example, tends to be distorted or warped by heating due to differences in the density of the conductor circuits formed on its front and back surfaces, as well as differences in thermal expansion and contraction between the plastic and the conductor circuits.

特に、第1図に示すように、ガラエポ基板の裏
面片側のみの加熱により凹反りやねじれの歪みが
生じ易いことはよく知られているところである。
このことは、本発明のようにガラエポ基板のプリ
ント配線板上に、同じくガラエポ基板のチツプキ
ヤリアを塔載しハンダ接続をする場合についても
そのまま当てはまることである。
In particular, as shown in FIG. 1, it is well known that heating only one side of the back surface of a glass epoxy substrate tends to cause concave warping or twisting distortion.
This also applies to the case where a chip carrier made of a glass epoxy board is mounted on a printed wiring board made of a glass epoxy board and soldered to it as in the present invention.

すなわち、第2図の側面概要図に示すような例
えば、ガラエポ基板製のプリント配線板3の接続
用端子4の上に、同じくガラエポ基板製のチツプ
キヤリア5の接続用端子6が相互に接触するよう
に塔載された場合において、これらを基板の裏面
側のみからハンダ接続のための加熱をすると、第
3図の側面概要図に示すように、前記プリント配
線板3とチツプキヤリア5とのそれぞれが異なつ
た反り矢高でもつて凹反りやねじれの歪みを生ず
る。この場合、プリント配線板3はチツプキヤリ
ア5に比べて基板の板厚やサイズが大きいために
同じ材質のガラエポ基板であつても反り矢高は若
干異なることになり、また両基板上に形成された
導体回路の粗密の差などによつても両基板の反り
矢高はさらに格差を生ずることもあり得る。その
ため、プリント配線板の接続用端子4とチツプキ
ヤリアの接続用端子6との間〓はますます大きく
なり、プリント配線板の接続用端子表面に塗布又
は印刷被覆されたハンダペースト被膜7の塗膜厚
さに対して、加熱により溶融したハンダが両端子
間のギヤツプを埋めるのに費やされて該チツプキ
ヤリアの接続用端子6の側面へのハンダ揚りが不
十分となつたり、顕著な場合は全くハンダ揚りが
できないなどの欠点を生ずることになる。
That is, as shown in the schematic side view of FIG. 2, for example, the connection terminals 6 of the chip carrier 5 made of glass epoxy substrate are brought into contact with the connection terminals 4 of the printed wiring board 3 made of glass epoxy substrate. When the printed wiring board 3 and the chip carrier 5 are heated for soldering only from the back side of the board, as shown in the schematic side view of FIG. Even if the height of the arrow is high, concave warping or twisting distortion will occur. In this case, the printed wiring board 3 has a larger board thickness and size than the chip carrier 5, so even if the glass epoxy board is made of the same material, the warp height will be slightly different, and the conductor formed on both boards Due to differences in circuit density, etc., the warpage heights of the two boards may further differ. Therefore, the distance between the connection terminals 4 of the printed wiring board and the connection terminals 6 of the chip carrier becomes increasingly large, and the thickness of the solder paste coating 7 coated or printed on the surface of the connection terminals of the printed wiring board increases. On the other hand, the solder melted by heating is used to fill the gap between both terminals, and the solder does not reach the side of the connection terminal 6 of the chip carrier insufficiently, or in some cases, it does not spread at all. This results in disadvantages such as not being able to solder.

そこで本発明は、上記の欠点を除去し改善する
ために、第4図の側面概要図に示すように、該基
板の上面側(A側)より赤外線ヒータ8によりふ
く射による加熱で、徐々にガラエポ基板のA表面
側の熱膨張を促進して、A表面側にやや凸反りと
なるようにする工程イと、該基板の下面側(B
側)よりブロツクヒータ9により急熱して、やや
凸反りとなつた基板の裏面が熱膨張して第6図に
示すように表裏面の均衡がとれて基板が平滑とな
るように凸反りを矯正する工程ロとの組合せによ
り、有機系樹脂素材の基材から成るプリント配線
板とこの上に塔載した同質のチツプキヤリアとを
確実にハンダ接続することを特徴とする方法とそ
の方法を実現するための最適の装置を提供するも
のである。
Therefore, in order to eliminate and improve the above-mentioned drawbacks, the present invention gradually heats glass epoxy from the upper surface side (side A) of the substrate by radiation using an infrared heater 8, as shown in the schematic side view of FIG. A process of promoting thermal expansion on the A surface side of the substrate to make it slightly convexly warped on the A surface side;
The back side of the board, which has become slightly warped, is rapidly heated by the block heater 9 (on the side), and the back side of the board, which has become slightly warped, expands thermally, and as shown in Figure 6, the warp is corrected so that the front and back sides are balanced and the board becomes smooth. In order to realize a method characterized in that a printed wiring board made of a base material of an organic resin material and a chip carrier of the same quality mounted thereon are reliably soldered together in combination with a process step of The aim is to provide the most suitable equipment for this purpose.

すなわち、有機系樹脂素材のプリント配線板に
おける接続用端子部分にハンダペーストを印刷方
法等により被覆し、該ハンダペーストを被覆した
部分の上に同等の熱膨張率を有する有機系樹脂素
材の基板から成るチツプキヤリアを位置決めして
塔載した後、該塔載部分の上面側より赤外線ヒー
タでふく射加熱し、一方下面側よりブロツクヒー
タで熱伝導により急熱をして、ハンダペーストを
リフローすると共に、やや凸反りとなつている基
板を平滑状態に是正して、プリント配線板の接続
用端子にチツプキヤリアの接続用端子を迅速確実
に接合する方法である。なお、上記赤外線ヒータ
による加熱は徐々に行うことが好ましいので、ま
ず主として基板全体の昇温をするための予備加熱
を行い、次いで主として基板の接続用端子表面に
被覆されたハンダペーストをリフローする本加熱
を行うことが、本発明の最も好ましい実施態様で
ある。そのためには、第6図に示すように、予備
加熱用の赤外ヒータ10と本加熱用の赤外ヒータ
11とが基板の搬送台12の上面側に夫々設けら
れており、一方ブロツクヒータ9が基板の搬送台
12の下面側に設けられた主として熱伝導による
加熱装置を最低条件兼ね備えたチツプキヤリアの
塔載接続用装置を使用することが有利である。
That is, the connecting terminal portions of a printed wiring board made of an organic resin material are coated with solder paste by a printing method, etc., and the parts coated with the solder paste are coated with a board made of an organic resin material having an equivalent coefficient of thermal expansion. After positioning and mounting the chip carrier, the top surface of the chip carrier is heated by radiation using an infrared heater, while the bottom surface is rapidly heated by heat conduction using a block heater to reflow the solder paste and slightly heat the chip carrier. This is a method for quickly and reliably joining the connection terminals of a chip carrier to the connection terminals of a printed wiring board by correcting a convexly warped board to a smooth state. Note that it is preferable to perform the heating using the infrared heater gradually, so first perform preheating to raise the temperature of the entire board, and then mainly reflow the solder paste coated on the surface of the connection terminals of the board. Providing heating is the most preferred embodiment of the invention. To this end, as shown in FIG. 6, an infrared heater 10 for preheating and an infrared heater 11 for main heating are provided on the upper surface side of the substrate carrier 12, while a block heater 9 It is advantageous to use a device for connecting a chip carrier, which at least has a heating device mainly based on thermal conduction, which is provided on the underside of the substrate carrier 12.

以下、本発明の実施例について説明する。 Examples of the present invention will be described below.

(実施例) 板厚が0.5mmの片面銅張りの市販のガラエポ基
板を常法により加工したプリント配線板の接続用
端子の表面に、共晶ハンダ(錫63%、鉛37%)の
ペーストをシルクスクリーン印刷により塗布し、
このようにしてハンダペーストを塗布した部分の
上に、同じくガラエポ基板から成るチツプキヤリ
アを位置決めして塔載した後、上面側に200V用
500Wの赤外線ヒータを6箇配列した予備加熱帯
を5秒間で通過させ、次いで200V用1000Wの赤
外線ヒータ10箇配列した本加熱帯を10秒間で通過
するように該基板を搬送しつつ、下面側よりブロ
ツクヒータで急熱して、上記ハンダペーストをリ
フローして、プリント配線板の接続用端子とチツ
プキヤリアの接続用端子とが確実にハンダ接続さ
れた複合基板を得た。なお、この場合において、
接続用端子部分は上面側の赤外線ヒータによる本
加熱と下面側のブロツクヒータによる急激加熱で
前記高融点のハンダペーストは15秒間という短時
間内に溶融し、第7図に示すようにプリント配線
板の端子表面上で溶融したハンダは表面張力によ
つて球状の膜が13が形成され、その後溶融ハン
ダの表面張力によつてチツプキヤリアの端子面が
自動的にプリント配線板の端子面と正しい位置に
精度よく位置合せされるいわゆる自己位置合せ効
果(セルフアライメント)によつて正確にかつ確
実に両端子同志が接合され、プリント配線板の定
位置にチツプキヤリアを塔載接続することができ
た。
(Example) A paste of eutectic solder (63% tin, 37% lead) was applied to the surface of the connection terminal of a printed wiring board that was processed using a conventional method using a commercially available glass epoxy board with one side copper-plated and 0.5 mm thick. Applied by silk screen printing,
After positioning and mounting the chip carrier made of glass epoxy board on the part where the solder paste was applied in this way,
While transporting the substrate so that it passes through a preliminary heating zone in which six 500W infrared heaters are arranged for 5 seconds, and then through a main heating zone in which 10 1000W infrared heaters for 200V are arranged in 10 seconds, the bottom side The solder paste was rapidly heated with a block heater and reflowed to obtain a composite board in which the connection terminals of the printed wiring board and the connection terminals of the chip carrier were reliably connected by solder. In this case,
The connection terminal portion is heated by the infrared heater on the top side and rapidly heated by the block heater on the bottom side, and the high melting point solder paste melts within a short time of 15 seconds, forming a printed wiring board as shown in Figure 7. The molten solder on the terminal surface forms a spherical film 13 due to surface tension, and then the surface tension of the molten solder automatically aligns the terminal surface of the chip carrier to the correct position with the terminal surface of the printed wiring board. Due to the so-called self-alignment effect (self-alignment), both terminals were accurately and reliably joined together, making it possible to connect the chip carrier to a fixed position on the printed wiring board.

以上のように、本発明によれば、有機系樹脂素
材から成るプリント配線板上に同質のリードレス
チツプキヤリアを精度よく、しかも加熱実装中の
該基板の反りやねじれによる歪み、さらにまた加
熱による基板の焦げによる変質を生ずることなく
比較的短時間内に塔載接続することができる。
As described above, according to the present invention, a leadless chip carrier of the same quality can be precisely mounted on a printed wiring board made of an organic resin material, and it is possible to prevent distortion caused by warping or twisting of the board during heat mounting, and also by heating. Mounting connections can be made within a relatively short time without causing deterioration due to scorching of the substrate.

【図面の簡単な説明】[Brief explanation of the drawing]

第1図はセラミツクヒータ上で基板を加熱する
状態の側面概要図、第2図は本発明の有機系樹脂
素材のプリント配線板上に同質のチツプキヤリア
を塔載した状態の側面概要図、第3図は凹反りを
生じたプリント配線板上のチツプキヤリアの側面
概要図、第4図及び第5図は本発明の方法による
加熱状態の側面概要図、第6図は本発明の装置の
側面概要図、第7図は本発明の方法によるプリン
ト配線板とチツプキヤリアの接続用端子部分の拡
大側面図である。 上記図面において、1……セラミツクヒータ、
2……ガラエポ基板、3……ガラエポ基板から成
るプリント配線板、4……同プリント配線板上の
接続用端子、5……ガラエポ基板から成るチツプ
キヤリア、6……同チツプキヤリア上の接続用端
子、7……ハンダペースト被膜、8……赤外線ヒ
ータ、9……ブロツクヒータ、10……予備加熱
帯、11……本加熱帯、12……基板搬送台、1
3……球状の溶融ハンダ膜、A側……基板の上面
側、B側……基板の下面側。
Fig. 1 is a schematic side view of a state in which a substrate is heated on a ceramic heater, Fig. 2 is a schematic side view of a state in which a chip carrier of the same quality is mounted on a printed wiring board made of an organic resin material of the present invention, and Fig. 3 The figure is a schematic side view of a chip carrier on a printed wiring board with concave warpage, Figures 4 and 5 are schematic side views of the heated state by the method of the present invention, and Figure 6 is a schematic side view of the device of the present invention. , FIG. 7 is an enlarged side view of a connecting terminal portion between a printed wiring board and a chip carrier according to the method of the present invention. In the above drawings, 1...ceramic heater,
2... a glass epoxy board, 3... a printed wiring board made of a glass epoxy board, 4... a connection terminal on the printed wiring board, 5... a chip carrier made of a glass epoxy board, 6... a connection terminal on the chip carrier, 7...Solder paste coating, 8...Infrared heater, 9...Block heater, 10...Preliminary heating zone, 11...Main heating zone, 12...Substrate carrier, 1
3...Spherical molten solder film, A side...upper surface side of the substrate, B side...lower surface side of the substrate.

Claims (1)

【特許請求の範囲】 1 有機系樹脂素材のプリント配線板に有機系樹
脂素材のリードレスチツプキヤリアをハンダペー
ストを介して塔載した後に、予備加熱と当該予備
加熱に連続する本加熱を行い前記ハンダペースト
をリフローするチツプキヤリアの塔載接続方法で
あつて、 前記予備加熱は、前記リードレスチツプキヤリ
ア側からの赤外線ヒータを用いた輻射伝熱による
漸増的な加熱であり、 前記本加熱は、前記輻射伝熱に加えた前記プリ
ント配線板側からのブロツクヒータを用いた熱伝
導による急加熱であることを特徴とするチツプキ
ヤリアの塔載接続方法。 2 有機系樹脂素材のプリント配線板に有機系樹
脂素材のリードレスチツプキヤリアをハンダペー
ストを介して塔載した後に、予備加熱と当該予備
加熱に連続する本加熱を行い前記ハンダペースト
をリフローするチツプキヤリアの塔載接続用装置
であつて、 前記リードレスチツプキヤリアを塔載した前記
プリント配線板を搬送する基板搬送手段と、 前記予備加熱を実施する、前記基板搬送手段の
前半であつて、当該基板搬送手段の上面側に設け
た赤外線ヒータを用いた輻射伝熱による漸増的な
予備加熱手段と、 前記本加熱を実施する、前記基板搬送手段の後
半であつて、当該基板搬送手段の上面側に設けた
赤外線ヒータを用いる輻射伝熱による加熱手段
と、当該基板搬送手段の下面側に設けたブロツク
ヒータを用いた熱伝導による加熱手段とによる急
熱的な本加熱手段とを備えてなるチツプキヤリア
の塔載接続用装置。
[Scope of Claims] 1. After mounting a leadless chip carrier made of an organic resin material on a printed wiring board made of an organic resin material via solder paste, preheating and main heating subsequent to the preheating are performed. A chip carrier tower-mounted connection method for reflowing solder paste, wherein the preheating is gradual heating by radiant heat transfer using an infrared heater from the leadless chip carrier side, and the main heating is the A method for connecting a chip carrier on a tower, characterized in that rapid heating is performed by heat conduction using a block heater from the printed wiring board side in addition to radiant heat transfer. 2. A chip carrier in which a leadless chip carrier made of an organic resin material is mounted on a printed wiring board made of an organic resin material via a solder paste, and then preheating and main heating subsequent to the preheating are performed to reflow the solder paste. A mounting connection device comprising: a board transport means for transporting the printed wiring board on which the leadless chip carrier is mounted; and a first half of the board transport means for carrying out the preheating, the board transport means for transporting the printed wiring board on which the leadless chip carrier is mounted; a means for gradually increasing preheating by radiant heat transfer using an infrared heater provided on the upper surface side of the substrate conveying means; A chip carrier comprising a heating means using radiation heat transfer using an infrared heater provided therein, and a heating means using heat conduction using a block heater provided on the lower surface of the substrate transport means, and a main heating means using rapid heating. Tower connection device.
JP21908683A 1983-11-21 1983-11-21 Method and device for placing and connecting chip carrier Granted JPS60111497A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP21908683A JPS60111497A (en) 1983-11-21 1983-11-21 Method and device for placing and connecting chip carrier

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP21908683A JPS60111497A (en) 1983-11-21 1983-11-21 Method and device for placing and connecting chip carrier

Publications (2)

Publication Number Publication Date
JPS60111497A JPS60111497A (en) 1985-06-17
JPH0472398B2 true JPH0472398B2 (en) 1992-11-18

Family

ID=16730037

Family Applications (1)

Application Number Title Priority Date Filing Date
JP21908683A Granted JPS60111497A (en) 1983-11-21 1983-11-21 Method and device for placing and connecting chip carrier

Country Status (1)

Country Link
JP (1) JPS60111497A (en)

Family Cites Families (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5426476A (en) * 1977-07-29 1979-02-28 Fujitsu Ltd Reflow solder dipping device
ZA803535B (en) * 1979-06-20 1981-06-24 Hoffmann La Roche Novel quinazoline derivatives and pharmaceutical preparations
JPS5735081U (en) * 1980-08-04 1982-02-24

Also Published As

Publication number Publication date
JPS60111497A (en) 1985-06-17

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