JPH0474322B2 - - Google Patents
Info
- Publication number
- JPH0474322B2 JPH0474322B2 JP63218800A JP21880088A JPH0474322B2 JP H0474322 B2 JPH0474322 B2 JP H0474322B2 JP 63218800 A JP63218800 A JP 63218800A JP 21880088 A JP21880088 A JP 21880088A JP H0474322 B2 JPH0474322 B2 JP H0474322B2
- Authority
- JP
- Japan
- Prior art keywords
- skin
- hair
- methylpolysiloxane
- oil
- solution
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000000243 solution Substances 0.000 claims description 19
- 235000019499 Citrus oil Nutrition 0.000 claims description 12
- 239000010500 citrus oil Substances 0.000 claims description 12
- 239000003795 chemical substances by application Substances 0.000 claims description 10
- XMSXQFUHVRWGNA-UHFFFAOYSA-N Decamethylcyclopentasiloxane Chemical compound C[Si]1(C)O[Si](C)(C)O[Si](C)(C)O[Si](C)(C)O[Si](C)(C)O1 XMSXQFUHVRWGNA-UHFFFAOYSA-N 0.000 claims description 9
- 239000002904 solvent Substances 0.000 claims description 8
- 239000001293 FEMA 3089 Substances 0.000 claims description 6
- 239000002280 amphoteric surfactant Substances 0.000 claims description 6
- 239000007864 aqueous solution Substances 0.000 claims description 5
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 18
- 239000007788 liquid Substances 0.000 description 15
- 239000012153 distilled water Substances 0.000 description 8
- 239000003205 fragrance Substances 0.000 description 8
- -1 hair rinses Substances 0.000 description 8
- 239000006071 cream Substances 0.000 description 7
- 230000000694 effects Effects 0.000 description 7
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 description 6
- XMGQYMWWDOXHJM-UHFFFAOYSA-N limonene Chemical compound CC(=C)C1CCC(C)=CC1 XMGQYMWWDOXHJM-UHFFFAOYSA-N 0.000 description 6
- 239000002453 shampoo Substances 0.000 description 6
- FJKROLUGYXJWQN-UHFFFAOYSA-N 4-hydroxybenzoic acid Chemical compound OC(=O)C1=CC=C(O)C=C1 FJKROLUGYXJWQN-UHFFFAOYSA-N 0.000 description 5
- 235000014113 dietary fatty acids Nutrition 0.000 description 5
- 229930195729 fatty acid Natural products 0.000 description 5
- 239000000194 fatty acid Substances 0.000 description 5
- 239000000049 pigment Substances 0.000 description 5
- 238000006116 polymerization reaction Methods 0.000 description 5
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 4
- NEHNMFOYXAPHSD-UHFFFAOYSA-N citronellal Chemical compound O=CCC(C)CCC=C(C)C NEHNMFOYXAPHSD-UHFFFAOYSA-N 0.000 description 4
- 230000003750 conditioning effect Effects 0.000 description 4
- 239000006210 lotion Substances 0.000 description 4
- 239000004094 surface-active agent Substances 0.000 description 4
- 239000004166 Lanolin Substances 0.000 description 3
- 235000019502 Orange oil Nutrition 0.000 description 3
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 3
- 239000002537 cosmetic Substances 0.000 description 3
- 150000004665 fatty acids Chemical class 0.000 description 3
- 229940039717 lanolin Drugs 0.000 description 3
- 235000019388 lanolin Nutrition 0.000 description 3
- 235000001510 limonene Nutrition 0.000 description 3
- 229940087305 limonene Drugs 0.000 description 3
- 239000010502 orange oil Substances 0.000 description 3
- 230000035515 penetration Effects 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- WTEVQBCEXWBHNA-UHFFFAOYSA-N Citral Natural products CC(C)=CCCC(C)=CC=O WTEVQBCEXWBHNA-UHFFFAOYSA-N 0.000 description 2
- 235000019501 Lemon oil Nutrition 0.000 description 2
- 235000008331 Pinus X rigitaeda Nutrition 0.000 description 2
- 235000011613 Pinus brutia Nutrition 0.000 description 2
- 241000018646 Pinus brutia Species 0.000 description 2
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 2
- 229940043350 citral Drugs 0.000 description 2
- 235000000983 citronellal Nutrition 0.000 description 2
- 229930003633 citronellal Natural products 0.000 description 2
- 239000001279 citrus aurantifolia swingle expressed oil Substances 0.000 description 2
- 239000003086 colorant Substances 0.000 description 2
- 239000000839 emulsion Substances 0.000 description 2
- 235000019441 ethanol Nutrition 0.000 description 2
- WTEVQBCEXWBHNA-JXMROGBWSA-N geranial Chemical compound CC(C)=CCC\C(C)=C\C=O WTEVQBCEXWBHNA-JXMROGBWSA-N 0.000 description 2
- 229960002989 glutamic acid Drugs 0.000 description 2
- 230000005484 gravity Effects 0.000 description 2
- 239000010501 lemon oil Substances 0.000 description 2
- 229940057995 liquid paraffin Drugs 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 230000009965 odorless effect Effects 0.000 description 2
- 239000003921 oil Substances 0.000 description 2
- 235000019198 oils Nutrition 0.000 description 2
- 229920002050 silicone resin Polymers 0.000 description 2
- 150000003505 terpenes Chemical class 0.000 description 2
- 235000007586 terpenes Nutrition 0.000 description 2
- 238000005406 washing Methods 0.000 description 2
- LDMOEFOXLIZJOW-UHFFFAOYSA-N 1-dodecanesulfonic acid Chemical compound CCCCCCCCCCCCS(O)(=O)=O LDMOEFOXLIZJOW-UHFFFAOYSA-N 0.000 description 1
- HIQIXEFWDLTDED-UHFFFAOYSA-N 4-hydroxy-1-piperidin-4-ylpyrrolidin-2-one Chemical compound O=C1CC(O)CN1C1CCNCC1 HIQIXEFWDLTDED-UHFFFAOYSA-N 0.000 description 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- 206010040880 Skin irritation Diseases 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 1
- 125000005211 alkyl trimethyl ammonium group Chemical group 0.000 description 1
- 150000003862 amino acid derivatives Chemical class 0.000 description 1
- 125000003118 aryl group Chemical group 0.000 description 1
- 235000015278 beef Nutrition 0.000 description 1
- 230000003766 combability Effects 0.000 description 1
- 229920005565 cyclic polymer Polymers 0.000 description 1
- PXEDJBXQKAGXNJ-QTNFYWBSSA-L disodium L-glutamate Chemical compound [Na+].[Na+].[O-]C(=O)[C@@H](N)CCC([O-])=O PXEDJBXQKAGXNJ-QTNFYWBSSA-L 0.000 description 1
- 230000002500 effect on skin Effects 0.000 description 1
- 239000003974 emollient agent Substances 0.000 description 1
- 238000004945 emulsification Methods 0.000 description 1
- 239000003995 emulsifying agent Substances 0.000 description 1
- 230000001804 emulsifying effect Effects 0.000 description 1
- 230000002708 enhancing effect Effects 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 230000003700 hair damage Effects 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 230000005923 long-lasting effect Effects 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 235000013923 monosodium glutamate Nutrition 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 229920001296 polysiloxane Polymers 0.000 description 1
- 230000001681 protective effect Effects 0.000 description 1
- 230000036556 skin irritation Effects 0.000 description 1
- 231100000475 skin irritation Toxicity 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 229940073490 sodium glutamate Drugs 0.000 description 1
- GCLGEJMYGQKIIW-UHFFFAOYSA-H sodium hexametaphosphate Chemical compound [Na]OP1(=O)OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])O1 GCLGEJMYGQKIIW-UHFFFAOYSA-H 0.000 description 1
- 235000019982 sodium hexametaphosphate Nutrition 0.000 description 1
- 238000005063 solubilization Methods 0.000 description 1
- 230000007928 solubilization Effects 0.000 description 1
- 150000005846 sugar alcohols Polymers 0.000 description 1
- 239000003760 tallow Substances 0.000 description 1
- 230000009967 tasteless effect Effects 0.000 description 1
- 239000001577 tetrasodium phosphonato phosphate Substances 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/58—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing atoms other than carbon, hydrogen, halogen, oxygen, nitrogen, sulfur or phosphorus
- A61K8/585—Organosilicon compounds
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
- A61K8/89—Polysiloxanes
- A61K8/891—Polysiloxanes saturated, e.g. dimethicone, phenyl trimethicone, C24-C28 methicone or stearyl dimethicone
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/92—Oils, fats or waxes; Derivatives thereof, e.g. hydrogenation products thereof
- A61K8/922—Oils, fats or waxes; Derivatives thereof, e.g. hydrogenation products thereof of vegetable origin
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q19/00—Preparations for care of the skin
Landscapes
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Animal Behavior & Ethology (AREA)
- General Health & Medical Sciences (AREA)
- Public Health (AREA)
- Veterinary Medicine (AREA)
- Birds (AREA)
- Epidemiology (AREA)
- Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Dermatology (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Cosmetics (AREA)
Description
【発明の詳細な説明】
〔発明の目的〕
（産業上の利用分野）
本発明はメチルポリシロキサンを水分散性ない
し水溶性として加えたスキンローシヨン、乳液、
クリーム、ヘアリンス、シヤンプー剤等の皮膚、
毛髪処理剤に関する。[Detailed Description of the Invention] [Object of the Invention] (Industrial Application Field) The present invention provides skin lotions, emulsions,
Creams, hair rinses, shampoos, etc. on the skin,
It relates to a hair treatment agent.
（従来の技術）
従来、重合度の高いゴム状の珪素樹脂例えばメ
チルポリシロキサンを用いた化粧料としては、特
開昭63−183517号公報に記載されているように高
重合度のメチルポリシロキサンをデカメチルシク
ロペンタシロキサンに溶解したヘアオイルや、こ
の溶液に界面活性剤を水溶性多価アルコールを加
えて乳化させ、さらに水に分散させた毛髪セツト
剤などが、毛髪に光沢となめらかさを与え、頭髪
に油じみがなく、適度なセツト力を有する毛髪化
粧料として知られている。(Prior Art) Conventionally, cosmetics using rubber-like silicone resins with a high degree of polymerization, such as methylpolysiloxane, have been produced using methylpolysiloxane with a high degree of polymerization, as described in JP-A-63-183517. hair oil, which is made by dissolving hair in decamethylcyclopentasiloxane, and hair setting agents, which are made by adding a surfactant to this solution and emulsifying it with water-soluble polyhydric alcohol, and then dispersing it in water, give shine and smoothness to the hair. It is known as a hair cosmetic that does not leave oil stains on the hair and has appropriate setting power.
（発明が解決しようとする課題）
上述の特開昭63−183517号公報に記載の毛髪化
粧料は高重合度のメチルポリシロキサンの撥水性
を利用して毛髪に対するセツト力を附与するもの
であり、水に対する溶解性は考慮されていない。
したがつてたとえ乳化して使用したとしてもシヤ
ンプーによつて除去することが容易でなく、その
ため毛髪を団子状に固まらせ、毛髪をこわばらせ
たりするという問題がある。(Problem to be Solved by the Invention) The hair cosmetic described in the above-mentioned Japanese Patent Application Laid-Open No. 63-183517 uses the water repellency of methylpolysiloxane with a high degree of polymerization to impart setting power to hair. Yes, solubility in water is not considered.
Therefore, even if it is emulsified and used, it is not easy to remove with a shampoo, which causes the problem that the hair becomes lumpy and stiff.
本発明の目的は、上述の問題に鑑みメチルポリ
シロキサンを水溶性として皮膚や毛髪に吸収され
易くかつ水で洗滌して容易に除去できる皮膚、毛
髪処理剤を提供するものである。 In view of the above-mentioned problems, an object of the present invention is to provide a skin and hair treatment agent made of water-soluble methylpolysiloxane, which is easily absorbed into the skin and hair and can be easily removed by washing with water.
（課題を解決するための手段）
本発明の皮膚、毛髪処理剤は、メチルポリシロ
キサンを、デカメチルシクロペンタシロキサン、
柑橘油、テレピン油の少くとも何れか一種の溶剤
に溶解した溶液を両性界面活性剤を含む水溶液に
配合したものである。
(Means for Solving the Problems) The skin and hair treatment agent of the present invention uses methylpolysiloxane, decamethylcyclopentasiloxane,
A solution dissolved in at least one of citrus oil and turpentine oil is blended into an aqueous solution containing an amphoteric surfactant.
また、溶剤に対するメチルポリシロキサンの溶
解量は30重量％以下が適当である。 Further, the amount of methylpolysiloxane dissolved in the solvent is suitably 30% by weight or less.
（作用）
本発明の皮膚、毛髪処理剤は、メチルポリシロ
キサンを、デカメチルシクロペンタシロキサンま
たは、テルペン、ピネン、リモネン、シトラー
ル、シトロネラール等を含有した柑橘油または、
テレピン油よりなる溶剤の一種又は二種以上に溶
解した溶液を両性界面活性剤を含む水溶液に配合
し、メチルポリシロキサンを水分散性ないし水溶
性にして皮膚や毛髪にメチルポリシロキサンを有
効に作用させるとともに水による洗滌除去も容易
にしたものである。(Function) The skin and hair treatment agent of the present invention replaces methylpolysiloxane with decamethylcyclopentasiloxane, citrus oil containing terpene, pinene, limonene, citral, citronellal, etc.
A solution of turpentine oil dissolved in one or more solvents is blended with an aqueous solution containing an amphoteric surfactant to make the methylpolysiloxane water-dispersible or water-soluble so that the methylpolysiloxane acts effectively on the skin and hair. It also makes it easy to wash and remove with water.
また、メチルポリシロキサンが溶剤に対して30
重量％以上になるとメチルポリシロキサンの不溶
物が残りこれがクリームやシヤンプーに配合され
ると、皮膚や毛髪に附着し洗滌しても除去し難い
状態となつて皮膚をべたつかせたり毛髪を団子状
に固まらせたりする不都合を生ずる。 In addition, methylpolysiloxane is 30%
If the amount exceeds % by weight, insoluble matter of methylpolysiloxane remains and when this is added to creams or shampoos, it adheres to the skin and hair and becomes difficult to remove even when washed, making the skin sticky and causing the hair to form clumps. This causes the inconvenience of hardening.
（実施例）
本発明の実施例に用いられるメチルポリシロキ
サン、溶剤及び界面活性剤について説明する。(Example) Methylpolysiloxane, solvent, and surfactant used in Examples of the present invention will be explained.
メチルポリシロキサンは高重合度のゴム状珪素
樹脂で次の一般式
を有するシロキサン結合を骨格としたメチルシロ
キサンの重合体であり、無色、無味、無臭の弾性
を有する透明体である。使用規格は次の通りであ
る。 Methylpolysiloxane is a rubbery silicone resin with a high degree of polymerization and has the following general formula: It is a polymer of methylsiloxane with a skeleton of siloxane bonds, and is a colorless, tasteless, and odorless, elastic, transparent body. The standards used are as follows.
針進入度：18〜23mm／min（25℃）
加熱減量：５％以下（15℃、24h）
比重：0.96〜1.00（25℃）
屈折率：1.390〜1.410（nD25）
重合度：ｎ＝5.500〜9.000
［註］針進入度試験は、三田村製自動タイマー式
針進入試験器使用、コーンは、60℃のものを用い
た。 Needle penetration: 18-23mm/min (25℃) Heating loss: 5% or less (15℃, 24h) Specific gravity: 0.96-1.00 (25℃) Refractive index: 1.390-1.410 (nD 25 ) Degree of polymerization: n = 5.500 ~9.000 [Note] For the needle penetration test, an automatic timer type needle penetration tester manufactured by Mitamura was used, and a cone at 60°C was used.
デカメチルシクロペンタシロキサンは、シロキ
サン結合を骨格とした環状の重合体で、主として
デカメチルシクロペンタシロキサンを本体とした
無色、無臭の透明な揮発性の液体であり、デカメ
チルシクロペンタシロキサンの分子式及び特性は
次の通りである。 Decamethylcyclopentasiloxane is a cyclic polymer with a skeleton of siloxane bonds, and is a colorless, odorless, transparent, volatile liquid mainly composed of decamethylcyclopentasiloxane.The molecular formula of decamethylcyclopentasiloxane is The characteristics are as follows.
（以下次頁）
分子式：C10H30O5Si5
構造式：
分子量：370.77
屈折率：1.391〜1.403（nD25）
粘度：3.5〜8.0cs.（第一法25℃）
比重：0.940〜．980（24℃）
柑橘油としてはテルペン、ピネン、リモネン、
シトラール、シトロネラール等を含む精製された
オレンジ油、レモン油、ライム油が用いられる。
さらに、ピネン、リモネンを含むテレピン油も有
効である。(See next page) Molecular formula: C 10 H 30 O 5 Si 5 Structural formula: Molecular weight: 370.77 Refractive index: 1.391-1.403 ( nD25 ) Viscosity: 3.5-8.0cs. (Daiichi method 25℃) Specific gravity: 0.940-. 980 (24℃) Citrus oils include terpenes, pinene, limonene,
Refined orange oil, lemon oil, and lime oil containing citral, citronellal, etc. are used.
Additionally, turpentine oil containing pinene and limonene is also effective.
また、イソプロピールミリステートとかポリオ
キシエチレンの脂肪酸エステルは可溶化剤にも、
乳化剤にも働く力を持ちメチルポリシロキサンと
良好な相溶性を示す。 In addition, isopropyl myristate and polyoxyethylene fatty acid esters can also be used as solubilizers.
It also has the ability to act as an emulsifier and exhibits good compatibility with methylpolysiloxane.
両性界面活性剤としてはアミノ酸誘導体である
アシルグルタメートが有効である。 Acylglutamate, which is an amino acid derivative, is effective as an amphoteric surfactant.
アシルグルタメートは、次の一般式をもつ物質
である。 Acylglutamates are substances with the general formula:
１≦ｎ≦２
COR：天然脂肪酸
アシルグルタメートは、Ｎ−アシル−Ｌ−グル
タミン酸トリエタノールアミンが最も芳しい皮
膚、毛髪に対する効果が得られる。このＮ−アシ
ル−Ｌ−グルタミン酸トリエタノールアミンの製
法としては、グルタミン酸ナトリウムのナトリウ
ムの代わりに、トリエタノールアミンを付け、天
然の脂肪酸でアシル結合をさせて得られる。天然
の脂肪酸の中では、牛脂を用いたものが皮膚に対
する刺激とか毛髪に対する諸条件に好結果が得ら
れる。 1≦n≦2 COR: Natural fatty acid Among the acylglutamates, N-acyl-L-glutamic acid triethanolamine has the most aromatic effect on skin and hair. This N-acyl-L-glutamic acid triethanolamine is produced by adding triethanolamine instead of sodium to sodium glutamate and forming an acyl bond with a natural fatty acid. Among natural fatty acids, those using beef tallow have good results for skin irritation and hair conditions.
上述の材料を次の方法によつて配合する。 The above materials are blended by the following method.
（） メチルポリシロキサンを夫々異なる溶剤
に溶解して次の３種のポリシロキサン溶液（Ａ
液）を得る。以下数値は何れも重量％である。() Methylpolysiloxane was dissolved in different solvents to prepare the following three types of polysiloxane solutions (A
liquid). The following numerical values are all percentages by weight.
Ａ液 (1)
メチルポリシロキサン…… 0.5〜30.0
デカメチルシクロペンタシロキサン99.5〜70.0
計 100
Ａ液 (2)
メチルポリシロキサン…… 0.5〜30.0
柑橘油…… 99.5〜70.0
計 100
Ａ液 (3)
メチルポリシロキサン…… 0.5〜30.0
デカメチルシクロペンタシロキサン49.5〜35.0
柑橘油…… 45.0〜35.0
計 100
（） 両性界面活性剤を水に分散させて次の３
種の界面活性剤水性液を得る。数値は何れも重
量％である。Solution A (1) Methylpolysiloxane...0.5-30.0 Decamethylcyclopentasiloxane 99.5-70.0 Total 100 Solution A (2) Methylpolysiloxane...0.5-30.0 Citrus oil...99.5-70.0 Total 100 Solution A (3) Methylpolysiloxane... 0.5-30.0 Decamethylcyclopentasiloxane 49.5-35.0 Citrus oil... 45.0-35.0 Total 100 () Disperse the amphoteric surfactant in water and add the following 3
Obtain a seed surfactant aqueous solution. All numerical values are weight %.
Ｂ液 (1)
Ｎ−アシル−Ｌ−グルタミン酸トリエタノール
アミン…… 30.0
化学的純水…… 70.0
計 100
Ｂ液 (2)
Ｎ−アシル−Ｌ−グルタミン酸トリエタノール
アミン…… 1.0〜30.0
Ｎ−ラウリルNN−ジメチルアミノステアリル
硫酸塩…… 0.5〜2.0
化学的純水…… 70.0
計 100
Ｂ液 (3)
Ｎ−アシル−Ｌ−グルタミン酸トリエタノール
アミン…… 10.0〜30.0
ラウリルスルフオネート…… 1.0〜3.0
化学的純水…… 67.0〜89.0
計 100
（） 以上のＡ液とＢ液を、適量配合しその中
に皮膚並びに毛髪に有用性物質等を添加し、さ
らに可溶化及び乳化に必要な他の界面活性剤を
任意に添加することにより次の実施例１、〜実
施例８、に示す配合の皮膚、毛髪処理剤を得
た。数値は何れも重量％である。Solution B (1) Triethanolamine N-acyl-L-glutamate...30.0 Chemically pure water...70.0 Total 100 Solution B (2) Triethanolamine N-acyl-L-glutamate...1.0-30.0 N-lauryl NN-dimethylaminostearyl sulfate...0.5-2.0 Chemically pure water...70.0 Total 100 Solution B (3) N-acyl-L-glutamate triethanolamine...10.0-30.0 Lauryl sulfonate...1.0-3.0 Chemically pure water... 67.0~89.0 Total 100 () Mix appropriate amounts of the above A and B solutions, add substances useful for the skin and hair, and add other substances necessary for solubilization and emulsification. Skin and hair treatment agents having the formulations shown in Examples 1 to 8 below were obtained by optionally adding a surfactant. All numerical values are weight %.
実施例 １、透明スキンローシヨン。Example 1, transparent skin lotion.
Ａ液(1)…… 5.0〜10.0 Ｂ液(1)…… 2.0〜5.0 エチルアルコール…… 15.0〜20.0 パラベン…… 0.1 色素…… 適宜 香料…… 適宜 蒸溜水…… 残余 計 100 実施例 ２、整肌用乳液。 A liquid (1)...5.0~10.0 B liquid (1)……2.0～5.0 Ethyl alcohol...15.0~20.0 Paraben...0.1 Dye...as appropriate Fragrance...as appropriate Distilled water... Remainder Total 100 Example 2: Emulsion for skin conditioning.
Ａ液(2)…… 10.0〜15.0 Ｂ液(2)…… 20.0〜30.0 エチルアルコール…… 5.0〜10.0 パラベン…… 0.1 色素、香料…… 若干 蒸溜水…… 残余 計 100 Ａ液(2)の柑橘油としてはオレンジ油を用いた。 A liquid (2)……10.0～15.0 B liquid (2)……20.0～30.0 Ethyl alcohol...5.0~10.0 Paraben...0.1 Pigments, fragrances... some Distilled water... Remainder Total 100 Orange oil was used as the citrus oil for liquid A (2).
実施例 ３、ハンドローシヨン。Example 3, hand lotion.
Ａ液(3)…… 20.0〜25.0 Ｂ液(3)…… 10.0〜15.0 セタノール…… 15.0〜20.0 パラベン…… 0.1 色素、香料…… 若干 蒸溜水…… 残余 計 100 Ａ液(3)の柑橘油としてはレモン油を用いた。 A liquid (3)...20.0~25.0 B liquid (3)……10.0～15.0 Setanol...15.0~20.0 Paraben...0.1 Pigments, fragrances... some Distilled water... Remainder Total 100 Lemon oil was used as the citrus oil for liquid A (3).
実施例 ４、整肌用クリーム。Example 4: Skin conditioning cream.
Ａ液(1)…… 30.0〜40.0 Ｂ液(2)…… 20.0〜30.0 ラノリン脂肪酸イソプロピレン…… 1.5 ポリオキシエチレンラノリン…… 0.5 セタノール…… 10.0〜15.0 ラノリン…… 3.0〜5.0 パラベン…… 0.1 色素、香料…… 若干 蒸溜水…… 残余 計 100 実施例 ５、ボテーマツサージクリーム。 A liquid (1)...30.0~40.0 B liquid (2)……20.0～30.0 Lanolin fatty acid isopropylene... 1.5 Polyoxyethylene lanolin...0.5 Setanol...10.0~15.0 Lanolin...3.0~5.0 Paraben...0.1 Pigments, fragrances... some Distilled water... Remainder Total 100 Example 5, Body Matsurge Cream.
Ａ液(1)…… 35.0〜40.0 Ｂ液(1)…… 20.0〜30.0 プロピレングリコール…… 5.0〜5.5 流動パラフイン…… 4.5〜5.0 セタノール…… 5.0〜6.0 パラベン…… 0.1 色素、香料…… 若干 蒸溜水…… 残余 計 100 実施例 ６、ヘアクリーム。 A liquid (1)...35.0~40.0 B liquid (1)……20.0～30.0 Propylene glycol...5.0~5.5 Liquid paraffin...4.5~5.0 Setanol...5.0~6.0 Paraben...0.1 Pigments, fragrances... some Distilled water... Remainder Total 100 Example 6, hair cream.
Ａ液(2)…… 55.0〜65.0
Ｂ液(1)…… 25.0〜30.0
塩化アルキルトリメチルアンモニウム……
5.0〜5.5
流動パラフイン…… 4.5〜5.0
色素、香料…… 若干
蒸溜水…… 残余
計 100
Ａ液(2)の柑橘油としてはライム油を用いた。 Solution A (2)...55.0~65.0 Solution B (1)...25.0~30.0 Alkyltrimethylammonium chloride...
5.0-5.5 Liquid paraffin... 4.5-5.0 Pigment, fragrance... Some Distilled water... Remainder total 100 Lime oil was used as the citrus oil in Part A (2).
実施例 ７、ヘアリンス。Example 7, hair rinse.
Ａ液(3)…… 30.0〜50.0
Ｂ液(3)…… 40.0〜60.0
ヘキサメタ燐酸ナトリウム…… 1.0〜2.0
ポリオキシエチレンラウリルエーテル硫酸塩…
… 4.5〜5.0
パラベン…… 0.1
色素、香料…… 若干
蒸留水…… 残余
計 100
Ａ液(3)は柑橘油の代りにテレピン油を用いた。 Solution A (3)...30.0~50.0 Solution B (3)...40.0~60.0 Sodium hexametaphosphate...1.0~2.0 Polyoxyethylene lauryl ether sulfate...
... 4.5-5.0 Parabens... 0.1 Colors, fragrances... Some Distilled water... Remaining total 100 For solution A (3), turpentine oil was used instead of citrus oil.
実施例 ８、シヤンプー剤。Example 8, Shampoo agent.
Ａ液(3)…… 10.0〜15.0
Ｂ液(3)…… 65.0〜75.0
ジステアリル硫酸トリエタノールアミン……
5.0〜10.0
パラベン…… 0.1
色素、香料…… 若干
蒸留水…… 残余
計 100
Ａ液(3)の柑橘油としてはオレンジ油を用いた。 Solution A (3)...10.0~15.0 Solution B (3)...65.0~75.0 Triethanolamine distearyl sulfate...
5.0 to 10.0 Parabens... 0.1 Colors, fragrances... Some Distilled water... Remainder Total 100 Orange oil was used as the citrus oil for liquid A (3).
本発明によれば、メチルポリシロキサンをデカ
メチルシクロキサン、柑橘油、テレピン油の一種
又は二種以上の溶剤に溶解し両性界面活性剤を含
む水溶液に配合することにより、メチルポリシロ
キサンが水に対して可溶化、乳化し、スキンロー
シヨンや整肌クリームとして皮膚に使用した場合
は、エモリント効果が高く、皮膚の触感が優れ、
ボデーマツサージクレームとして使用した場合
は、被施術者の皮膚は勿論であるが、施術者の指
先のすべりが良くなりマツサージ効果を一層高め
ることができる。さらに使用後の効果の持続性が
大で４〜５回位の水洗では効果が残存しまた皮膚
のしつとり感は洗滌前と変りがなく、皮膚に用い
た場合は整肌作用と保護作用の効果を有する。
According to the present invention, methylpolysiloxane is dissolved in water by dissolving methylpolysiloxane in one or more solvents of decamethylcycloxane, citrus oil, and turpentine oil and blending it into an aqueous solution containing an amphoteric surfactant. On the other hand, when it is solubilized and emulsified and used on the skin as a skin lotion or skin conditioning cream, it has a high emollient effect and has an excellent texture on the skin.
When used as a body pine surge cream, it not only affects the skin of the recipient but also the fingertips of the practitioner, making it more slippery, thereby further enhancing the pine surge effect. In addition, the effect is long-lasting after use, and the effect remains even after 4 to 5 washes, and the skin feels as moisturized as before washing, and when used on the skin, it has a skin conditioning and protective effect. It has the effect of
またシヤンプーやヘヤリンス等の毛髪処理剤に
用いた場合、使用後の毛髪の手触り、櫛通り、
艶、弾力性が良好となり、この特徴は２、３回の
ジヤンプー後にも効果が残存し、さらに毛髪の損
傷防止の作用もある。 In addition, when used in hair treatment agents such as shampoo and hair rinse, the texture of the hair after use, combability, etc.
It provides good shine and elasticity, and this feature remains effective even after two or three shampoos, and it also has the effect of preventing hair damage.
Claims (1)
ペンタシロキサン、柑橘油、テレピン油の少くと
も何れか一種よりなる溶剤に溶解した溶液に、両
性界面活性剤を含む水溶液を配合してなることを
特徴とする皮膚、毛髪処理剤。 ２ メチルポリシロキサンが溶剤に対して30重量
％以下であることを特徴とする請求項１記載の皮
膚、毛髪処理剤。[Scope of Claims] 1 An aqueous solution containing an amphoteric surfactant is blended with a solution of methylpolysiloxane dissolved in a solvent consisting of at least one of decamethylcyclopentasiloxane, citrus oil, and turpentine oil. A skin and hair treatment agent characterized by: 2. The skin and hair treatment agent according to claim 1, wherein the amount of methylpolysiloxane is 30% by weight or less based on the solvent.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP63218800A JPH0267211A (en) | 1988-09-01 | 1988-09-01 | Skin and hair treating agent |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP63218800A JPH0267211A (en) | 1988-09-01 | 1988-09-01 | Skin and hair treating agent |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPH0267211A JPH0267211A (en) | 1990-03-07 |
| JPH0474322B2 true JPH0474322B2 (en) | 1992-11-26 |
Family
ID=16725559
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP63218800A Granted JPH0267211A (en) | 1988-09-01 | 1988-09-01 | Skin and hair treating agent |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH0267211A (en) |
-
1988
- 1988-09-01 JP JP63218800A patent/JPH0267211A/en active Granted
Also Published As
| Publication number | Publication date |
|---|---|
| JPH0267211A (en) | 1990-03-07 |
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