JPH0474443B2 - - Google Patents
Info
- Publication number
- JPH0474443B2 JPH0474443B2 JP27181188A JP27181188A JPH0474443B2 JP H0474443 B2 JPH0474443 B2 JP H0474443B2 JP 27181188 A JP27181188 A JP 27181188A JP 27181188 A JP27181188 A JP 27181188A JP H0474443 B2 JPH0474443 B2 JP H0474443B2
- Authority
- JP
- Japan
- Prior art keywords
- glove body
- film
- knitted fabric
- glove
- thin film
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000010408 film Substances 0.000 claims description 30
- 239000004744 fabric Substances 0.000 claims description 23
- 239000010409 thin film Substances 0.000 claims description 20
- BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 claims description 17
- 239000000839 emulsion Substances 0.000 claims description 12
- 239000011248 coating agent Substances 0.000 claims description 11
- 238000000576 coating method Methods 0.000 claims description 11
- 239000000701 coagulant Substances 0.000 claims description 10
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims description 9
- JOYRKODLDBILNP-UHFFFAOYSA-N Ethyl urethane Chemical compound CCOC(N)=O JOYRKODLDBILNP-UHFFFAOYSA-N 0.000 claims description 8
- 238000004519 manufacturing process Methods 0.000 claims description 8
- 238000000034 method Methods 0.000 claims description 6
- 239000002253 acid Substances 0.000 claims description 3
- 238000001035 drying Methods 0.000 claims description 3
- 229910052751 metal Inorganic materials 0.000 claims description 3
- 239000002184 metal Substances 0.000 claims description 3
- 150000003839 salts Chemical class 0.000 claims description 3
- 239000000835 fiber Substances 0.000 description 6
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- 230000000149 penetrating effect Effects 0.000 description 3
- 238000005507 spraying Methods 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 2
- ZCCIPPOKBCJFDN-UHFFFAOYSA-N calcium nitrate Chemical compound [Ca+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O ZCCIPPOKBCJFDN-UHFFFAOYSA-N 0.000 description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 1
- 230000001112 coagulating effect Effects 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 230000032798 delamination Effects 0.000 description 1
- 238000007598 dipping method Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000003349 gelling agent Substances 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- -1 phthalate ester Chemical class 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 239000004014 plasticizer Substances 0.000 description 1
- 239000005871 repellent Substances 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 229920003002 synthetic resin Polymers 0.000 description 1
- 239000000057 synthetic resin Substances 0.000 description 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 1
- 229920002554 vinyl polymer Polymers 0.000 description 1
Landscapes
- Gloves (AREA)
Description
（産業上の利用分野）
この発明は塩化ビニル皮膜付の作業用手袋の製
造方法に関する。
（従来技術）
従来、メリヤス布等の編布によつて構成した手
袋体の外表面に、塩化ビニルから成る皮膜を付着
させて成る作業用手袋の製造方法の中に特願昭57
−52300号がある。
上記した製造方法は所定の糸間隔で編まれた手
袋体の外表面に溌油処理を施した後、この手袋体
外表面に塩化ビニルペーストをスプレー若しくは
滴下して無圧塗布し、これをゲル化するものであ
る。而して他の製造方法と比較すると、手袋体外
表面の溌油性により上記ペーストが編布内部に浸
入するのを防止できるので、手袋体外表面の皮膜
を薄く形成することが可能であり、柔軟な使用感
の作業用手袋を提供することができる利点があ
る。
しかし、上記した製造方法は皮膜を薄く形成す
る為に、塩化ビニルペーストを溌油処理した手袋
体の上に塗布するものであるから、手袋体に対す
る皮膜の付着力が弱く、短期間の使用で皮膜自体
が手袋体から剥離してしまうことがあつた。
（発明が解決しようとする課題）
本発明の課題は、塩化ビニルペーストが手袋体
の編布の内部に浸入するのを防止して、皮膜を薄
く形成すると共に、この皮膜の手袋外表面に対す
る付着力を向上させることである。
（課題を解決する為の手段）
上記した課題を解決する為に本発明の柔軟性皮
膜付作業用手袋の製造方法は、編布にて構成した
手袋体に酸若しくは多価金属塩等を溶解して成る
凝固剤を含浸させ、この手袋体の外表面にアクリ
ルエマルジヨン若しくはウレタンエマルジヨンを
塗布して薄膜状に凝固させた後、これを乾燥する
第１工程と、上記手袋体の外表面に塩化ビニルペ
ーストの塗膜を形成した後、キユアさせる第２工
程とからなるものである。
（作用）
以上の手段によれば、第１工程において凝固剤
を含浸させた手袋体の外表面にアクリル、若しく
はウレタンのエマルジヨンを塗布すると、このエ
マルジヨンが手袋体の編布に含浸する凝固剤に触
れて反応し、薄膜状に凝固する。次いでこれを乾
燥すると手袋体の外表面にアクリル若しくはウレ
タンの薄膜が被着され、編布を構成する繊維糸間
の間〓が上記薄膜によつて覆われる。
また、上記したアクリルエマルジヨン若しくは
ウレタンの薄膜には塩化ビニルとの相溶性があ
り、これにより両者間の接着が良好に行なわれ
る。
第２工程にて上記手袋体の外表面に合成樹脂の
ペーストの塗膜を形成すると、この塗膜は上記薄
膜の表面に対して良好に付着し、キユアさせると
前記薄膜と一体化して皮膜となる。
（発明の効果）
本発明は以上の様に、手袋体の外表面にアクリ
ル若しくはウレタンの薄膜を被着させて編布にお
ける繊維糸間の間〓を覆い、これによつて、皮膜
となる塩化ビニルのペーストが上記した編布内に
浸入するのを防止するものであるから、その分、
手袋体外表面の皮膜を薄く形成して柔軟なものに
することができる。
さらに、アクリル若しくはウレタンの薄膜と塩
化ビニルの皮膜とは良好な相溶性を有し、キユア
の際に確実に付着するので、前述した従来のもの
と比較すると手袋体に対する皮膜の付着力を大幅
に向上させることができるものである。
（実施例）
以下、本発明の一実施例を図面に基づいて説明
する。
本発明の柔軟性皮膜付作業用手袋Ａの製造方法
は、編布にて構成した手袋体１に凝固剤ａを含浸
させ、この手袋体１の外表面にアクリル若しくは
ウレタンのエマルジヨンを塗布して薄膜状に凝固
させた後、これを乾燥する第１工程と、上記手袋
体１の外表面に塩化ビニルのペーストの塗膜２′
を形成した後、キユアさせて皮膜２を形成する第
２工程とならなつている。
第１工程で用いる凝固剤ａは多価金属塩若しく
は酸等の溶液で成り、例えば硝酸カルシウム若し
くは塩酸を下記の表で示した比率でメタノール中
に溶解させたものである。
(Industrial Application Field) This invention relates to a method for manufacturing work gloves with a vinyl chloride film. (Prior art) A patent application filed in 1983 is included in a method for manufacturing work gloves, which consists of attaching a film made of vinyl chloride to the outer surface of a glove body made of a knitted fabric such as knitted fabric.
-There is No. 52300. The above manufacturing method involves applying an oil-repellent treatment to the outer surface of a glove body knitted with a predetermined thread spacing, and then spraying or dropping vinyl chloride paste onto the outer surface of the glove body to apply it without pressure, and gel it. It is something to do. Compared to other manufacturing methods, the oil repellency of the outer surface of the glove prevents the paste from penetrating into the knitted fabric, making it possible to form a thin film on the outer surface of the glove, making it flexible. It has the advantage of being able to provide work gloves that are comfortable to use. However, in the above manufacturing method, in order to form a thin film, vinyl chloride paste is applied onto the oil-treated glove body, so the adhesion of the film to the glove body is weak, and it cannot be used for a short period of time. The film itself sometimes peeled off from the glove body. (Problems to be Solved by the Invention) An object of the present invention is to prevent vinyl chloride paste from penetrating into the inside of the knitted fabric of the glove body, form a thin film, and attach the film to the outer surface of the glove. The goal is to improve your wearing power. (Means for Solving the Problems) In order to solve the above-mentioned problems, the method for manufacturing work gloves with a flexible film of the present invention includes dissolving an acid or a polyvalent metal salt in a glove body made of knitted fabric. A first step of impregnating the glove body with a coagulant made of The second step is to form a coating film of vinyl chloride paste on the surface and then cure it. (Function) According to the above means, when an acrylic or urethane emulsion is applied to the outer surface of the glove body impregnated with a coagulant in the first step, this emulsion is applied to the coagulant impregnated into the knitted fabric of the glove body. It reacts on contact and solidifies into a thin film. Next, when this is dried, a thin film of acrylic or urethane is applied to the outer surface of the glove body, and the spaces between the fiber threads constituting the knitted fabric are covered with the thin film. Furthermore, the acrylic emulsion or urethane thin film described above has compatibility with vinyl chloride, which allows good adhesion between the two. When a synthetic resin paste coating is formed on the outer surface of the glove body in the second step, this coating adheres well to the surface of the thin film, and when cured, it integrates with the thin film to form a coating. Become. (Effects of the Invention) As described above, the present invention covers the gaps between the fibers in the knitted fabric by coating the outer surface of the glove body with a thin film of acrylic or urethane, thereby reducing the amount of chloride that forms the film. Since it prevents the vinyl paste from penetrating into the above-mentioned knitted fabric,
A thin film can be formed on the outer surface of the glove to make it flexible. Furthermore, the acrylic or urethane thin film and the vinyl chloride film have good compatibility and adhere reliably during curing, which greatly improves the adhesion of the film to the glove body compared to the conventional ones mentioned above. This is something that can be improved. (Example) Hereinafter, an example of the present invention will be described based on the drawings. The method for manufacturing work gloves A with a flexible film according to the present invention includes impregnating a glove body 1 made of knitted fabric with a coagulant a, and applying an acrylic or urethane emulsion to the outer surface of the glove body 1. After coagulating into a thin film, a first step of drying the solidified film, and a coating film 2' of vinyl chloride paste on the outer surface of the glove body 1 are performed.
After forming the film, the second step is to cure the film to form the film 2. The coagulating agent a used in the first step is a solution of a polyvalent metal salt or an acid, such as calcium nitrate or hydrochloric acid dissolved in methanol in the ratio shown in the table below.
【表】
一方、手袋体１は任意太さの繊維糸１′ａを所
望の密度で編んだ編布１′を用いて構成され、こ
の手袋体１を保持型（図示せず）の外側に装着し
た上で上記凝固剤ａ内に浸漬して編布１′中に凝
固剤ａを適度に含浸させる。
上記手袋体１は、その後、アクリルエマルジヨ
ン（濃度40％、粘度30〜200cps）、若しくはウレ
タンのエマルジヨン（濃度25％、粘度100〜
300cps）中に浸漬させて、手袋体１の外表面に上
記エマルジヨンを塗布させる。
尚、上記エマルジヨンは浸漬以外の方法、例え
ば滴下、又はスプレーによつて塗布してもよいも
のである。
手袋体１の外表面に塗布されたアクリルエマル
ジヨンは、手袋体１の編布１′に含浸される凝固
剤ａに触れて反応し、薄膜ｂ状に凝固する（第２
図）。
次いで、上記手袋体１は90℃の雰囲気中にて60
分間乾燥させる。
乾燥した薄膜ｂは手袋体１の編布１′外表面に
被着され、該編布１′を構成する繊維糸１′ａ間の
間〓を覆い、後述する様に塩化ビニルペーストが
編布１′の間〓に浸入するのを防止せしめる。
第２工程において上記手袋体１の外周面に塗布
する塩化ビニルのペーストには、例えば下記の表
に示した比率の配合を用い、これを前記手袋体１
の外表面に対してスプレーまたは滴下により無圧
塗布するか、若しくは上記ペースト中に手袋体１
を浸漬させて、該手袋体１の外表面に皮膜２とな
る塗膜を形成する。
塩化ビニールペースト配合
（重量比）
塩化ビニルペーストレジン 100
可塑剤（フタル酸エステル）100〜140
安定剤（−Ba−） ４
ゲル化剤（又は） ４
顔 料 １
塩化ビニールペーストを塗布した手袋体１は例
えば170℃の雰囲気中にて４分間セミキユアさせ
た後、さらに200℃の雰囲気中で10分間加熱する
ことによつて上記塗膜をキユアさせ皮膜２を形成
し、冷却した後に脱型する。
以上の様に成形した作業用手袋Ａは、脱型した
後に２〜12時間水中に置いて脱酸し、さらに60℃
の雰囲気中にて３時間程乾燥させる。
前記の如く手袋体１外表面に塗布された塩化ビ
ニールペーストは、前記した様に編布１′を覆う
薄膜ｂによつて編布１′を構成する繊維糸１′ａの
間の間〓内に浸入するのを防止させる。従つて、
塗膜は塩化ビニルペーストが編布１′内部に浸入
しない分、薄く形成され、これによつてキユア後
に形成される皮膜２は薄くて柔軟なものとなる。
また、薄膜ｂと皮膜２とはキユアの際に一体的
に付着されるので、手袋体１に対する皮膜２の付
着性は良好であり、薄膜ｂと皮膜２との間で層間
剥離が生じてしまう様なことがない。[Table] On the other hand, the glove body 1 is constructed using a knitted fabric 1' in which fiber threads 1'a of arbitrary thickness are knitted at a desired density, and the glove body 1 is attached to the outside of a holding mold (not shown). After the knitted fabric 1' is attached, it is immersed in the coagulant a to appropriately impregnate the knitted fabric 1' with the coagulant a. The glove body 1 is then made of acrylic emulsion (concentration 40%, viscosity 30~200 cps) or urethane emulsion (concentration 25%, viscosity 100~200 cps).
300 cps) to coat the outer surface of the glove body 1 with the above emulsion. The above emulsion may be applied by a method other than dipping, such as dropping or spraying. The acrylic emulsion applied to the outer surface of the glove body 1 reacts with the coagulant a impregnated into the knitted fabric 1' of the glove body 1, and coagulates into a thin film b (second
figure). Next, the glove body 1 is heated at 60°C in an atmosphere of 90°C.
Let dry for a minute. The dried thin film b is applied to the outer surface of the knitted fabric 1' of the glove body 1, covering the space between the fiber threads 1'a constituting the knitted fabric 1', and the vinyl chloride paste is applied to the knitted fabric as described below. This prevents the water from entering the water for 1'. In the second step, the vinyl chloride paste to be applied to the outer circumferential surface of the glove body 1 has a proportion shown in the table below, for example, and is applied to the glove body 1.
Apply it to the outer surface of the glove by spraying or dropping without pressure, or add the glove body 1 to the above paste.
to form a coating film 2 on the outer surface of the glove body 1. Vinyl chloride paste composition (weight ratio) Vinyl chloride paste resin 100 Plasticizer (phthalate ester) 100-140 Stabilizer (-Ba-) 4 Gelling agent (or) 4 Pigment 1 Glove body coated with vinyl chloride paste 1 For example, after semi-curing in an atmosphere of 170°C for 4 minutes, the coating film is cured by further heating in an atmosphere of 200°C for 10 minutes to form film 2, and after cooling, it is demolded. After removing the mold, work gloves A molded as described above are placed in water for 2 to 12 hours to deoxidize, and then heated to 60°C.
Dry in an atmosphere for about 3 hours. As described above, the vinyl chloride paste applied to the outer surface of the glove body 1 is spread between the fiber threads 1'a constituting the knitted fabric 1' by the thin film b covering the knitted fabric 1' as described above. prevent it from entering. Therefore,
The coating film is formed thinly so that the vinyl chloride paste does not penetrate into the knitted fabric 1', so that the coating film 2 formed after curing is thin and flexible. In addition, since the thin film b and the film 2 are integrally attached during curing, the adhesion of the film 2 to the glove body 1 is good, and delamination occurs between the thin film b and the film 2. There's nothing like it.
第１図は本発明によつて成形した作業用手袋を
示す一部切欠正面図、第２図は作業用手袋の拡大
断面図、第３図は編布に付着する皮膜を示す拡大
断面図である。
図中 Ａ：柔軟性皮膜付作業用手袋、ａ：凝固
剤、ｂ：薄膜（エマルジヨン）、１：手袋体、
１′：編布、１′ａ：繊維糸、２：皮膜（ペース
ト）。
Fig. 1 is a partially cutaway front view showing a working glove formed according to the present invention, Fig. 2 is an enlarged sectional view of the working glove, and Fig. 3 is an enlarged sectional view showing a film attached to the knitted fabric. be. In the figure A: work gloves with flexible film, a: coagulant, b: thin film (emulsion), 1: glove body,
1': knitted fabric, 1'a: fiber thread, 2: film (paste).
Claims (1)
属塩等を溶解して成る凝固剤を含浸させ、この手
袋体の外表面にアクリルエマルジヨン若しくはウ
レタンエマルジヨンを塗布して薄膜状に凝固させ
た後、これを乾燥する第１工程と、上記手袋体の
外表面に塩化ビニルペーストの塗膜を形成した
後、キユアさせる第２工程とからなる柔軟性皮膜
付作業用手袋の製造方法。1 A glove body made of knitted fabric is impregnated with a coagulant made by dissolving an acid or a polyvalent metal salt, etc., and an acrylic emulsion or urethane emulsion is applied to the outer surface of the glove body and coagulated into a thin film. A method for manufacturing a work glove with a flexible film, comprising a first step of drying the same after drying the glove body, and a second step of forming a coating film of vinyl chloride paste on the outer surface of the glove body and then curing the film.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP63271811A JPH02118102A (en) | 1988-10-26 | 1988-10-26 | Production of working glove with flexible film |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP63271811A JPH02118102A (en) | 1988-10-26 | 1988-10-26 | Production of working glove with flexible film |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPH02118102A JPH02118102A (en) | 1990-05-02 |
| JPH0474443B2 true JPH0474443B2 (en) | 1992-11-26 |
Family
ID=17505181
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP63271811A Granted JPH02118102A (en) | 1988-10-26 | 1988-10-26 | Production of working glove with flexible film |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH02118102A (en) |
Families Citing this family (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP3900530B2 (en) * | 2000-10-30 | 2007-04-04 | 日本ゼオン株式会社 | DIP MOLDED ARTICLE, DIP MOLDING COMPOSITION AND METHOD FOR PRODUCING DIP MOLDED ARTICLE |
| KR20020063462A (en) * | 2001-01-29 | 2002-08-03 | 원인호 | Manufacture of work safety gloves |
| WO2004002252A1 (en) | 2002-06-28 | 2004-01-08 | S.T. Chemical Co.,Ltd. | Moisture retentive gloves and process for producing the same |
| US11305518B2 (en) | 2017-01-13 | 2022-04-19 | Zeon Corporation | Laminate |
-
1988
- 1988-10-26 JP JP63271811A patent/JPH02118102A/en active Granted
Also Published As
| Publication number | Publication date |
|---|---|
| JPH02118102A (en) | 1990-05-02 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| KR100226173B1 (en) | Lubricous gloves and method for making lubricous gloves | |
| US4034751A (en) | Polymeric sheets as synthetic medical dressings or coverings for wounds | |
| US8323764B2 (en) | Methods to produce stretchable products | |
| EP2181826B1 (en) | Production of coated gloves | |
| JP2009243035A (en) | Glove and process for producing the same | |
| JPS5945B2 (en) | How to make protective gloves | |
| KR20060026076A (en) | Glove-footed surface and manufacturing method thereof | |
| US3268355A (en) | Method of producing vinyl coated fabric glove | |
| EP0113526B1 (en) | Method of coating rubber or polymer articles | |
| JPH0474443B2 (en) | ||
| US2526431A (en) | Method of making rubber coated fabric articles | |
| JP3197943B2 (en) | Brushed product made of natural rubber and method for producing the same | |
| JPH0640562Y2 (en) | Work gloves with flexible film | |
| CA2055250A1 (en) | Method of manufacturing working glove | |
| JP3782268B2 (en) | Manufacturing method of work gloves | |
| JP2001081614A (en) | Work gloves | |
| JPH0516167Y2 (en) | ||
| JPS61275407A (en) | Glove and its production | |
| JPH04119833A (en) | Pad molded product and preparation thereof | |
| JPH0561362B2 (en) | ||
| JPH0474442B2 (en) | ||
| JPH07243106A (en) | Gloves coated with silicone rubber and their production | |
| JPH0444003B2 (en) | ||
| JPH0316402B2 (en) | ||
| JPS6094603A (en) | Production of working glove with flexible film |