JPH0478475B2 - - Google Patents
Info
- Publication number
- JPH0478475B2 JPH0478475B2 JP29952088A JP29952088A JPH0478475B2 JP H0478475 B2 JPH0478475 B2 JP H0478475B2 JP 29952088 A JP29952088 A JP 29952088A JP 29952088 A JP29952088 A JP 29952088A JP H0478475 B2 JPH0478475 B2 JP H0478475B2
- Authority
- JP
- Japan
- Prior art keywords
- gold
- silver
- leaf
- sulfide
- layer
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 claims description 38
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 claims description 19
- 229910052737 gold Inorganic materials 0.000 claims description 13
- 239000010931 gold Substances 0.000 claims description 13
- 229910052946 acanthite Inorganic materials 0.000 claims description 8
- 239000004922 lacquer Substances 0.000 claims description 8
- XUARKZBEFFVFRG-UHFFFAOYSA-N silver sulfide Chemical compound [S-2].[Ag+].[Ag+] XUARKZBEFFVFRG-UHFFFAOYSA-N 0.000 claims description 8
- 229940056910 silver sulfide Drugs 0.000 claims description 8
- 229910052709 silver Inorganic materials 0.000 claims description 7
- 239000004332 silver Substances 0.000 claims description 7
- XEIPQVVAVOUIOP-UHFFFAOYSA-N [Au]=S Chemical compound [Au]=S XEIPQVVAVOUIOP-UHFFFAOYSA-N 0.000 claims description 6
- 239000004744 fabric Substances 0.000 claims description 6
- 239000000843 powder Substances 0.000 claims description 6
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims description 4
- 238000000034 method Methods 0.000 claims description 4
- 239000011593 sulfur Substances 0.000 claims description 4
- 229910052717 sulfur Inorganic materials 0.000 claims description 4
- 238000007731 hot pressing Methods 0.000 claims description 3
- 238000004519 manufacturing process Methods 0.000 claims description 2
- 239000010410 layer Substances 0.000 description 9
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 4
- 239000003086 colorant Substances 0.000 description 4
- 230000000694 effects Effects 0.000 description 3
- 244000062175 Fittonia argyroneura Species 0.000 description 2
- 239000005018 casein Substances 0.000 description 2
- BECPQYXYKAMYBN-UHFFFAOYSA-N casein, tech. Chemical compound NCCCCC(C(O)=O)N=C(O)C(CC(O)=O)N=C(O)C(CCC(O)=N)N=C(O)C(CC(C)C)N=C(O)C(CCC(O)=O)N=C(O)C(CC(O)=O)N=C(O)C(CCC(O)=O)N=C(O)C(C(C)O)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=O)N=C(O)C(CCC(O)=O)N=C(O)C(COP(O)(O)=O)N=C(O)C(CCC(O)=N)N=C(O)C(N)CC1=CC=CC=C1 BECPQYXYKAMYBN-UHFFFAOYSA-N 0.000 description 2
- 235000021240 caseins Nutrition 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 239000011888 foil Substances 0.000 description 2
- 229910052742 iron Inorganic materials 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 229920003002 synthetic resin Polymers 0.000 description 2
- 239000000057 synthetic resin Substances 0.000 description 2
- 229920002803 thermoplastic polyurethane Polymers 0.000 description 2
- 241000006351 Leucophyllum frutescens Species 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 230000003197 catalytic effect Effects 0.000 description 1
- 239000011247 coating layer Substances 0.000 description 1
- 238000005034 decoration Methods 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 238000005562 fading Methods 0.000 description 1
- 239000003292 glue Substances 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- 239000002932 luster Substances 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- -1 pottery Chemical compound 0.000 description 1
- 230000033458 reproduction Effects 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
Landscapes
- Laminated Bodies (AREA)
- Decoration Of Textiles (AREA)
Description
【発明の詳細な説明】
〔産業上の利用分野〕
本発明は、優雅で気品のある金銀装飾体とその
製造方法に関するものである。DETAILED DESCRIPTION OF THE INVENTION [Industrial Field of Application] The present invention relates to an elegant and dignified gold and silver ornament and a method for producing the same.
従来、金銀箔は各種の素材と組み合わされ広く
装飾体として使用されている。そして金銀箔等の
装飾体を製造する技術として、台紙の上に鉱物粉
末又は顔料粉末を混合した漆を塗布し、その上に
金箔層を設けることにより、万一金箔が離脱して
も黄色の漆層により離脱が目立たないようにする
とともにより金箔を鮮明なものとするものは公知
である（特許第104309号明細書）。
Traditionally, gold and silver leaf have been combined with various materials and widely used as decorations. The technology for producing decorative objects such as gold and silver foil is to apply lacquer mixed with mineral powder or pigment powder onto the mount, and then provide a layer of gold foil on top of it, so that even if the gold leaf were to come off, the yellow color would remain. A lacquer layer that makes the separation less noticeable and makes the gold leaf clearer is known (Japanese Patent No. 104309).
また銀糸の表面に硫化銀よりなる虹状の種々の
色彩を現出させるものも知られている（特公昭33
−4834号公報）。最近では箔に代り蒸着金属粉を
加工し、樹脂と共に和紙に塗布する方法も採用さ
れている（特開昭49−36945号公報）。 It is also known that various rainbow-like colors made of silver sulfide appear on the surface of silver thread (Special Publication No. 33
-4834). Recently, instead of using foil, a method has been adopted in which vapor-deposited metal powder is processed and applied to Japanese paper together with resin (Japanese Patent Laid-Open No. 49-36945).
〔考案が解決しようとする課題〕
しかしながら、上記の技術はいずれも金箔の鮮
明さを強調するものであつたり、着色銀糸をうる
ものであり、きらびやかな光沢は現出するが装飾
品としての重厚な輝きを得ることはできなかつ
た。特に古代の屏風や絵巻物のような歴史性をか
もしだす金箔すなわち古代金を得ることは困難で
あつた。[Problem that the invention aims to solve] However, all of the above techniques emphasize the sharpness of gold leaf or use colored silver thread, and although they produce a brilliant luster, they lack the solidity of ornaments. I couldn't get any brilliance. In particular, it was difficult to obtain gold leaf, or ancient gold, which gives off the historical character of ancient folding screens and picture scrolls.
本発明は古代金と同等の雰囲気を装飾体上にか
もしだすことにより、重厚な装飾体を提供するも
のである。 The present invention provides a dignified decorative body by creating an atmosphere equivalent to that of ancient gold on the decorative body.
古代金の重厚さは、まず金箔の純度が低く変色
し易いことと、長時間線香から発する成分に曝さ
れていたことによるものであるから、実際に上記
条件に類似した加工処理を行う。すなわち、純度
の低い金箔を用い、この上に銀の硫化物が付着し
たような状態を作ることである。
The thickness of ancient gold is due to the fact that the purity of the gold leaf is low and it easily discolors, and also because it was exposed to components emitted from incense sticks for a long time, so in reality, processing similar to the above conditions is performed. In other words, gold foil of low purity is used to create a state in which silver sulfide adheres to it.
本発明者は各種の実験試行の結果、金箔上に銀
の粉末を部分的に塗布した後、硫黄を含浸させた
布を介して加熱プレスを行う方法が有効であるこ
とに到達した。 As a result of various experimental trials, the inventors of the present invention have found that it is effective to partially apply silver powder onto gold foil and then heat press the silver powder through cloth impregnated with sulfur.
なお、台紙としては和紙に漆を塗つたものを用
い、表面のトツプコート層はカゼイン塗布層その
他液状ウレタン樹脂層を塗布したり、透明合成樹
脂フイルムを積層することにより金銀層の褪色、
剥落を防ぐとともに全体に黒味を消すこともでき
る。 The mount is Japanese paper coated with lacquer, and the top coat layer on the surface is coated with a casein coating layer or other liquid urethane resin layer, or a transparent synthetic resin film is laminated to prevent fading of the gold and silver layer.
It prevents peeling and can also remove the black tinge from the entire surface.
〔実施例〕
以下に本発明の実施例を図面とともに説明す
る。[Example] Examples of the present invention will be described below with reference to the drawings.
(1) 第１図に示すように和紙１に漆２（必要に応
じて適当な着色剤を混入してもよい）を塗布
し、純度97％〜75％の金を0.3μ厚に打箔した金
箔３を漆の上に接着する。(1) As shown in Figure 1, coat Japanese paper 1 with lacquer 2 (appropriate coloring agent may be mixed in if necessary), and apply gold with a purity of 97% to 75% to a thickness of 0.3 μm. Glue the gold leaf 3 on top of the lacquer.
(2) 0.5〜50μの銀粉末４をブラシで金箔３上に薄
く部分的に散布する。(2) 0.5 to 50μ silver powder 4 is thinly and partially sprinkled on the gold leaf 3 using a brush.
(3) ついで硫黄を含浸させた布を加圧面に張設し
たアイロンを130゜〜150℃に加熱して前記銀粉
末を散布した金箔上から加熱プレスすることに
より、金箔は一部硫化金となり、銀粉末は硫化
銀となる。(3) Then, by heating an iron with a sulfur-impregnated cloth stretched over the pressure surface to 130° to 150°C and hot pressing the gold foil on which the silver powder has been sprinkled, part of the gold leaf becomes gold sulfide. , the silver powder becomes silver sulfide.
４ 前記一部硫化金となつた金箔と硫化銀粉末上
にカゼイン水溶液または液状ウレタン樹脂を塗
布してトツプコート層５を形成する。4. A casein aqueous solution or liquid urethane resin is applied on the gold foil and silver sulfide powder, which have partially become gold sulfide, to form the top coat layer 5.
またトツプコート層として透明合成樹脂フイ
ルムを積層してもよい。 A transparent synthetic resin film may also be laminated as a top coat layer.
硫黄を含浸させた布を加圧面に張設したアイロ
ンを温度150℃にして、前記銀粉末を散布した金
箔上から約10秒間加熱する間に、金箔面上の銀粉
末部は銀の硫化現象により硫化銀となり、銀色か
らうす金色⇒茶色⇒青紫色⇒青色と順次変色し、
その大部分は前記硫黄含浸布に付着する。また金
箔面は銀粉の触媒作用により一部硫化金となり、
金色から金茶に変色し、ついで銀が多く含有して
いる金箔の場合は青色に、その他の場合は赤紫色
に変色する。
An iron with a sulfur-impregnated cloth stretched over the pressurized surface is heated to 150°C and heated for about 10 seconds over the gold foil on which the silver powder has been sprinkled. It turns into silver sulfide, which changes color sequentially from silver to pale gold to brown to bluish-purple to blue.
Most of it adheres to the sulfur-impregnated cloth. In addition, some of the gold leaf surface becomes gold sulfide due to the catalytic action of silver powder,
The color changes from gold to golden brown, then to blue in the case of gold leaf containing a large amount of silver, and to reddish-purple in other cases.
これらの現象は、金箔中の含有銀と銀粉末とが
硫化されて硫化金、硫化銀になり、打箔された金
箔中に凹凸と気泡が生じ、加熱プレスされた銀粉
末が金箔中の凹部や気泡中に圧入して一体とな
り、硫黄成分量により種々の色彩を現出するもの
であるが、銀粉末を使用せず単に硫黄含浸布を熱
プレスするだけでは前記のような効果は得られな
い。 These phenomena occur when the silver contained in the gold leaf and the silver powder are sulfurized to become gold sulfide and silver sulfide, which causes unevenness and bubbles to appear in the stamped gold leaf, and when the hot-pressed silver powder forms in the recesses in the gold leaf. It is press-fitted into sulfur and air bubbles to form a single body, producing various colors depending on the amount of sulfur content.However, simply hot pressing a sulfur-impregnated cloth without using silver powder will not produce the above effects. do not have.
本発明は上記のように構成したので、種々の色
彩からなる重厚で美麗な古代金の再現が容易に得
ることができる。また金箔の量を増加させたりし
ないで変色できるので経済的であり、金箔を使用
しているあらゆる装飾品、例えば焼物、箔糸、装
飾紙、絵巻物、ふすま、屏風、仏像等に安価に適
用することができる。またこれらの本物の複製も
容易にかつ再現性よく製作することができる。
Since the present invention is configured as described above, reproductions of profound and beautiful ancient gold made of various colors can be easily obtained. It is also economical because it can change color without increasing the amount of gold leaf, and can be applied at low cost to all kinds of decorative items that use gold leaf, such as pottery, foil thread, decorative paper, picture scrolls, sliding doors, folding screens, and Buddhist statues. be able to. Furthermore, copies of these genuine products can be easily produced with good reproducibility.
第１図は本発明の装飾体の一実施例を示す断面
図、第２図は本発明の装飾体の概略図である。
１：和紙、２：漆、３：金箔、４：硫化金、硫
化銀粉末層、５：トツプコート層。
FIG. 1 is a sectional view showing an embodiment of the decorative body of the present invention, and FIG. 2 is a schematic diagram of the decorative body of the present invention. 1: Washi paper, 2: Lacquer, 3: Gold leaf, 4: Gold sulfide, silver sulfide powder layer, 5: Top coat layer.
Claims (1)
と、硫化銀粉末層と、トツプコート層とから積層
構成されていることを特徴とする金銀装飾体。 ２ 和紙に漆を塗布した後、金箔を接着し、つい
で該金箔上に銀粉末を散布した後、硫黄を含浸さ
せた布を介して加熱プレスし、最後にトツプコー
ト層を塗被する工程からなることを特徴とする金
銀装飾体の製造方法。[Claims] 1. A gold and silver decorative body comprising a laminated structure of Japanese paper, a lacquer layer, gold leaf partially made of gold sulfide, a silver sulfide powder layer, and a top coat layer. 2 The process consists of applying lacquer to Japanese paper, adhering gold leaf, then sprinkling silver powder onto the gold leaf, hot pressing through a cloth impregnated with sulfur, and finally applying a top coat layer. A method for manufacturing a gold and silver decorative body, characterized by:
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP29952088A JPH02145400A (en) | 1988-11-29 | 1988-11-29 | Gold/silver decoration material and manufacture thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP29952088A JPH02145400A (en) | 1988-11-29 | 1988-11-29 | Gold/silver decoration material and manufacture thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPH02145400A JPH02145400A (en) | 1990-06-04 |
| JPH0478475B2 true JPH0478475B2 (en) | 1992-12-11 |
Family
ID=17873657
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP29952088A Granted JPH02145400A (en) | 1988-11-29 | 1988-11-29 | Gold/silver decoration material and manufacture thereof |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH02145400A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102101406A (en) * | 2009-12-17 | 2011-06-22 | 上海富臣化工有限公司 | Application of gold foil and silver foil sticking drawbench retro effect to decoration of picture frames and photo frames |
Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE10064091A1 (en) * | 2000-12-21 | 2002-07-04 | Eva Herrmann | Production of artistic surface effects or properties used on paintings comprises applying one or more different liquid or vaporous chemicals onto one or more different metals |
| JP3874784B2 (en) * | 2004-10-29 | 2007-01-31 | 財団法人京都国際文化交流財団 | Method of replicating old paintings decorated with metal foil |
| JP7028483B2 (en) * | 2018-07-20 | 2022-03-02 | 有限会社橡 | Colored lacquer material and colored lacquer slit thread |
-
1988
- 1988-11-29 JP JP29952088A patent/JPH02145400A/en active Granted
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102101406A (en) * | 2009-12-17 | 2011-06-22 | 上海富臣化工有限公司 | Application of gold foil and silver foil sticking drawbench retro effect to decoration of picture frames and photo frames |
| CN102101406B (en) | 2009-12-17 | 2013-05-15 | 上海富臣化工有限公司 | Application of gold foil and silver foil drawing retro effect in decoration of picture frames and photo frames |
Also Published As
| Publication number | Publication date |
|---|---|
| JPH02145400A (en) | 1990-06-04 |
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