JPH0479468B2 - - Google Patents
Info
- Publication number
- JPH0479468B2 JPH0479468B2 JP2316284A JP2316284A JPH0479468B2 JP H0479468 B2 JPH0479468 B2 JP H0479468B2 JP 2316284 A JP2316284 A JP 2316284A JP 2316284 A JP2316284 A JP 2316284A JP H0479468 B2 JPH0479468 B2 JP H0479468B2
- Authority
- JP
- Japan
- Prior art keywords
- layer
- arc tube
- heat shielding
- black
- lamp
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 20
- 229910001507 metal halide Inorganic materials 0.000 claims description 7
- 150000005309 metal halides Chemical class 0.000 claims description 7
- 229910052708 sodium Inorganic materials 0.000 claims description 6
- 239000011734 sodium Substances 0.000 claims description 6
- QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 claims description 5
- 229910052753 mercury Inorganic materials 0.000 claims description 5
- 239000010453 quartz Substances 0.000 claims description 5
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicon dioxide Inorganic materials O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 5
- -1 sodium halide Chemical class 0.000 claims description 3
- FVAUCKIRQBBSSJ-UHFFFAOYSA-M sodium iodide Chemical compound [Na+].[I-] FVAUCKIRQBBSSJ-UHFFFAOYSA-M 0.000 description 9
- MCMNRKCIXSYSNV-UHFFFAOYSA-N Zirconium dioxide Chemical compound O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 description 6
- 239000000843 powder Substances 0.000 description 6
- 238000009877 rendering Methods 0.000 description 6
- 239000000463 material Substances 0.000 description 5
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 4
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 4
- 229910052799 carbon Inorganic materials 0.000 description 4
- 230000000694 effects Effects 0.000 description 4
- XQPRBTXUXXVTKB-UHFFFAOYSA-M caesium iodide Chemical compound [I-].[Cs+] XQPRBTXUXXVTKB-UHFFFAOYSA-M 0.000 description 3
- 238000000034 method Methods 0.000 description 3
- 235000009518 sodium iodide Nutrition 0.000 description 3
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 description 2
- 239000011248 coating agent Substances 0.000 description 2
- 238000000576 coating method Methods 0.000 description 2
- 230000006866 deterioration Effects 0.000 description 2
- 238000001035 drying Methods 0.000 description 2
- 150000004820 halides Chemical class 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- 239000002245 particle Substances 0.000 description 2
- HUIHCQPFSRNMNM-UHFFFAOYSA-K scandium(3+);triiodide Chemical compound [Sc+3].[I-].[I-].[I-] HUIHCQPFSRNMNM-UHFFFAOYSA-K 0.000 description 2
- 239000000725 suspension Substances 0.000 description 2
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 2
- RMUKCGUDVKEQPL-UHFFFAOYSA-K triiodoindigane Chemical compound I[In](I)I RMUKCGUDVKEQPL-UHFFFAOYSA-K 0.000 description 2
- 229910052582 BN Inorganic materials 0.000 description 1
- PZNSFCLAULLKQX-UHFFFAOYSA-N Boron nitride Chemical compound N#B PZNSFCLAULLKQX-UHFFFAOYSA-N 0.000 description 1
- 239000000020 Nitrocellulose Substances 0.000 description 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 229910052786 argon Inorganic materials 0.000 description 1
- 239000003738 black carbon Substances 0.000 description 1
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 239000006229 carbon black Substances 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 230000004907 flux Effects 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 1
- 229910052737 gold Inorganic materials 0.000 description 1
- 239000010931 gold Substances 0.000 description 1
- XMBWDFGMSWQBCA-UHFFFAOYSA-N hydrogen iodide Chemical compound I XMBWDFGMSWQBCA-UHFFFAOYSA-N 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 229920001220 nitrocellulos Polymers 0.000 description 1
- 238000010422 painting Methods 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 238000002310 reflectometry Methods 0.000 description 1
- 229910052716 thallium Inorganic materials 0.000 description 1
- BKVIYDNLLOSFOA-UHFFFAOYSA-N thallium Chemical compound [Tl] BKVIYDNLLOSFOA-UHFFFAOYSA-N 0.000 description 1
- CMJCEVKJYRZMIA-UHFFFAOYSA-M thallium(i) iodide Chemical compound [Tl]I CMJCEVKJYRZMIA-UHFFFAOYSA-M 0.000 description 1
- 239000010936 titanium Substances 0.000 description 1
- 229910052719 titanium Inorganic materials 0.000 description 1
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01J—ELECTRIC DISCHARGE TUBES OR DISCHARGE LAMPS
- H01J61/00—Gas-discharge or vapour-discharge lamps
- H01J61/02—Details
- H01J61/52—Cooling arrangements; Heating arrangements; Means for circulating gas or vapour within the discharge space
- H01J61/523—Heating or cooling particular parts of the lamp
Landscapes
- Discharge Lamps And Accessories Thereof (AREA)
- Vessels And Coating Films For Discharge Lamps (AREA)
Description
【発明の詳細な説明】
産業上の利用分野
本発明は放電灯とくにナトリウムを含む金属ハ
ログン化物を添加した放電灯に関するものであ
る。DETAILED DESCRIPTION OF THE INVENTION Field of Industrial Application The present invention relates to a discharge lamp, particularly a discharge lamp to which a metal halide containing sodium is added.
従来例の構成とその問題点
発光管内に水銀とともに沃化ナトリウム、沃化
タリウム、沃化インジウム、沃化スカンジウム、
沃化セシウムなどの金属ハロゲン化物のうち一種
またはそれ以上を添加することによつて、通常の
高圧水銀灯に比し発光効率と演色性を改善した放
電灯は公知である。Structure of conventional example and its problems In addition to mercury, sodium iodide, thallium iodide, indium iodide, scandium iodide,
Discharge lamps are known that have improved luminous efficiency and color rendering properties compared to ordinary high-pressure mercury lamps by adding one or more metal halides such as cesium iodide.
このような放電灯において比較的蒸気圧の低い
沃化ナトリウムなどの化合物が発光管内に存在す
る場合は、(イ)発光管管壁温度をランプ動作中に
600℃以上に維持してランプ点灯中の放電を維持
する、(ロ)発光管管端部をある温度以上に高温に維
持して消灯後の電極周辺への金属ハロゲン化物の
凝縮を防止することにより、ランプの再始動性能
を良くする、などの条件を満足させる必要があ
る。このような金属ハロゲン化物添加の放電灯の
問題点の解決手段として従来種々の方法が講じら
れていた。 In such discharge lamps, if a compound such as sodium iodide, which has a relatively low vapor pressure, is present in the arc tube, (a) the arc tube wall temperature should be adjusted during lamp operation.
Maintaining the temperature at 600°C or higher to maintain discharge while the lamp is lit; (b) Maintaining the end of the arc tube at a high temperature above a certain temperature to prevent metal halides from condensing around the electrodes after the lamp is turned off. Therefore, it is necessary to satisfy conditions such as improving the restart performance of the lamp. Various methods have been used in the past to solve the problems of metal halide-added discharge lamps.
たとえば、発光管の電極部周囲壁に耐熱性金属
キヤツプ、ジルコニア白色粉末層、チタニアや窒
化ほう素などの白色粉末層、カーボンブラツク粉
末層などを遮熱膜として設けることが提案されて
いた。とくに近年、その遮熱性を良くする手段と
して第1層に白色のジルコニア膜、第2層に遮熱
性をさらに増すための黒色のカーボン膜を設けた
2層構造が採用されている例もある。 For example, it has been proposed to provide a heat-resistant metal cap, a zirconia white powder layer, a white powder layer of titania or boron nitride, a carbon black powder layer, etc. as a heat shielding film on the wall surrounding the electrode portion of the arc tube. In particular, in recent years, as a means to improve heat shielding properties, a two-layer structure has been adopted in which the first layer is a white zirconia film and the second layer is a black carbon film to further increase heat shielding properties.
しかしながら、上記の2層構造の発光管は、ジ
ルコニア層とカーボン層との接着力が充分に強い
とは云えず、取扱い中に振動などによりカーボン
層が剥離して充分な遮熱および保温効果が得られ
ず、沃化物の蒸気圧を充分高めることができずに
発光効率低下や演色性の低下を生じるなどの問題
があつた。また、再始動特性も不充分となる欠点
があつた。さらに、2層を塗布するため、1層塗
り→乾燥→焼付け→2層塗り→乾燥→焼付けなど
工程も繁雑となり、塗布用の懸濁液の調合も2種
類必要となるなど工数や材料のコスト面でも問題
があつた。また寿命中に熱劣化による膜剥離が生
じる欠点もあつた。 However, in the above-mentioned two-layer arc tube, the adhesion between the zirconia layer and the carbon layer is not strong enough, and the carbon layer peels off due to vibrations during handling, resulting in insufficient heat shielding and heat retention effects. However, the vapor pressure of iodide could not be sufficiently increased, leading to problems such as a decrease in luminous efficiency and a decrease in color rendering properties. Additionally, there was a drawback that the restart characteristics were insufficient. Furthermore, since two layers are applied, the process is complicated, such as applying one layer → drying → baking → painting two layers → drying → baking, and it is necessary to prepare two types of suspension for coating, which costs man-hours and materials. There were also problems on the surface. Another drawback was that the film peeled off due to thermal deterioration during its life.
発明の目的
本発明は発光管内に少なくともナトリウムを封
入した金属ハロゲン化物の蒸気圧を充分に高めて
再始動特性や演色性などを改善することができ、
また遮熱層の構成が簡単で工数や材料コストを低
減することができる放電灯を提供するものであ
る。Purpose of the Invention The present invention is capable of sufficiently increasing the vapor pressure of a metal halide containing at least sodium in an arc tube to improve restart characteristics, color rendering properties, etc.
Further, the present invention provides a discharge lamp in which the structure of the heat shielding layer is simple and the number of man-hours and material costs can be reduced.
発明の構成
本発明は水銀とともに少なくともナトリウムの
ハロゲン化物を含む金層ハロゲン化物を添加した
石英発光管の電極部を囲む管端部の小なくとも片
方の外表面に黒色チタニアよりなる遮熱層を設け
た放電灯を特徴とするものである。Structure of the Invention The present invention provides a heat shielding layer made of black titania on at least one outer surface of the tube end surrounding the electrode portion of a quartz arc tube to which a gold layer halide containing at least a sodium halide is added together with mercury. It is characterized by a discharge lamp provided.
したがつて、上記放電灯では白色チタニアとほ
とんど粒径も同程度で1μ以下の緻密な粉体であ
り、かつ熱遮へい性で優れた黒色のチタニア層を
採用しているので従来の2層遮熱膜と同様の保温
効果と熱遮へい性能を発揮することができる。さ
らには、遮熱膜が1層ですみ、付着力も強いので
従来みられた第1層と第2層間の膜剥離と云う問
題点も解消できるので、ランプ寿命中を通じて、
発光効率面、演色性の面、再始動特性の面での従
来欠点を解消することができる。また塗布焼付け
工程も材料調合も単純化でき、さらにはカーボン
を使用しなくてすむので、製作環循も黒色汚れが
生じないなどの利点も得られる。 Therefore, the above-mentioned discharge lamp uses a black titania layer, which is a dense powder with almost the same particle size as white titania and less than 1μ, and has excellent heat shielding properties, so it is not possible to use the conventional two-layer shield. It can exhibit the same heat retention effect and heat shielding performance as a thermal film. Furthermore, since only one layer of heat shielding film is required and the adhesion is strong, the conventional problem of film peeling between the first and second layers can be solved, so that
Conventional drawbacks in terms of luminous efficiency, color rendering properties, and restart characteristics can be overcome. Furthermore, the coating and baking process and material preparation can be simplified, and furthermore, since there is no need to use carbon, there are also advantages in the manufacturing cycle, such as no black stains.
実施例の説明 以下、本発明の実施例を説明する。Description of examples Examples of the present invention will be described below.
内径20mm、電極間距離40mmの石英発光管内に水
銀54mg、沃化ナトリウム21mg、沃化スカンジウム
4.5mg、沃化セシウム0.5mgを封入するとともにア
ルゴンを封入して定格400Wの放電灯を製作した。
前記石英発光管の片放電極周囲管壁外周囲には、
商品名チタン・ブラツクと称する粒径0.2μの黒色
チタニア粉末を錯酸ブチルとニトロセルロースと
少量の低融点ガラス粉末を混合した懸濁液を塗布
乾燥焼付けて約20μの遮熱層を設けた。 54 mg of mercury, 21 mg of sodium iodide, and scandium iodide in a quartz arc tube with an inner diameter of 20 mm and a distance between electrodes of 40 mm.
A discharge lamp with a rating of 400W was manufactured by filling 4.5mg of cesium iodide and 0.5mg of cesium iodide with argon.
Around the single-discharge electrode of the quartz arc tube, around the outside of the tube wall,
A suspension of black titania powder with a particle size of 0.2 microns (trade name: Titanium Black) mixed with butyl complex acid, nitrocellulose, and a small amount of low melting point glass powder was applied, dried and baked to form a heat shielding layer of about 20 microns.
上記放電灯を遮熱層を設けた部分が下側になる
ような方向に垂直点灯して特性を確認した結果、
発光光束は初期100時間点灯時の値で40000ルーメ
ンとなり、従来品で2層遮熱膜のカーボン膜剥離
のランプに比し6%上昇し、演色性もよくかつ再
始動電圧も従来の185Vが160Vに低下した。さら
に、ランプ点灯時間が2500時間を経過しても、黒
色チタニア遮熱層の剥離や遮熱性の低下は見られ
ず、ランプ特性への著しい悪影響は生じなかつ
た。 As a result of checking the characteristics of the above discharge lamp by lighting it vertically in a direction with the heat shield layer facing downwards, we found that:
The luminous flux is 40,000 lumens when lit for the initial 100 hours, which is a 6% increase compared to the conventional lamp with a double-layered heat shielding film and a peeled carbon film.The color rendering properties are also good, and the restart voltage is lower than the conventional 185V. It dropped to 160V. Furthermore, even after 2,500 hours of lamp lighting time had elapsed, no peeling of the black titania heat shielding layer or deterioration of heat shielding properties was observed, and no significant adverse effects on lamp characteristics occurred.
また、発光管内への封入ハロゲン化物を変えて
タリウム、ナトリウム、インジウムの沃化物を添
加した放電灯においても、同様に従来の遮熱層を
有するランプの欠点を解消でき特性の安定化をな
し得た。 Furthermore, even in discharge lamps in which thallium, sodium, and indium iodides are added instead of the halides sealed in the arc tube, the drawbacks of conventional lamps with heat shielding layers can be overcome and the characteristics stabilized. Ta.
なお、実施例においては発光管端の片方のみに
黒色チタニア層を設けたが、必要であれば両管端
部に設けてもよい。ただし、垂直点灯の場合発光
管の上、下の温度均一化をはかるために下側の管
端のみに黒色酸化チタン、上側の管端に遮熱性、
熱反射性が黒色酸化チタンよりも劣る材料を設け
てもよい。 In the example, the black titania layer was provided on only one end of the arc tube, but it may be provided on both ends of the arc tube if necessary. However, in the case of vertical lighting, in order to equalize the temperature at the top and bottom of the arc tube, black titanium oxide is applied only to the lower tube end, and heat shielding is applied to the upper tube end.
A material whose heat reflectivity is inferior to black titanium oxide may be provided.
発明の効果
以上説明したように、本発明は発光管内にナト
リウムを含む金属ハロゲン化物を添加した放電灯
において点灯中における管壁温度を充分高く維持
して金属ハロゲン化物の蒸気圧を上昇し、再始動
特性や演色性を改善することができる。また、遮
熱層が黒色チタニア単独ですむので、工数や材料
コストを低減することができる。Effects of the Invention As explained above, the present invention maintains the tube wall temperature sufficiently high during lighting in a discharge lamp in which a metal halide containing sodium is added to the arc tube, increases the vapor pressure of the metal halide, and regenerates the discharge lamp. Starting characteristics and color rendering properties can be improved. Furthermore, since the heat shielding layer can be made of black titania alone, the number of man-hours and material costs can be reduced.
Claims (1)
ン化物を含む金属ハロゲン化物を添加した石英発
光管の電極部を囲む管端部の少なくとも片方の外
表面に黒色チタニアよりなる遮熱層を設けたこと
を特徴とする放電灯。1. A heat shielding layer made of black titania is provided on the outer surface of at least one end of a quartz arc tube that surrounds an electrode part of a quartz arc tube to which a metal halide containing at least a sodium halide is added together with mercury. electric light.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2316284A JPS60167254A (en) | 1984-02-09 | 1984-02-09 | Electric discharge lamp |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2316284A JPS60167254A (en) | 1984-02-09 | 1984-02-09 | Electric discharge lamp |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS60167254A JPS60167254A (en) | 1985-08-30 |
| JPH0479468B2 true JPH0479468B2 (en) | 1992-12-16 |
Family
ID=12102911
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2316284A Granted JPS60167254A (en) | 1984-02-09 | 1984-02-09 | Electric discharge lamp |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS60167254A (en) |
-
1984
- 1984-02-09 JP JP2316284A patent/JPS60167254A/en active Granted
Also Published As
| Publication number | Publication date |
|---|---|
| JPS60167254A (en) | 1985-08-30 |
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