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JPH048484B2 - - Google Patents
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JPH048484B2 - - Google Patents

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Publication number
JPH048484B2
JPH048484B2 JP20145181A JP20145181A JPH048484B2 JP H048484 B2 JPH048484 B2 JP H048484B2 JP 20145181 A JP20145181 A JP 20145181A JP 20145181 A JP20145181 A JP 20145181A JP H048484 B2 JPH048484 B2 JP H048484B2
Authority
JP
Japan
Prior art keywords
cast iron
base material
energy source
phase
annular
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
JP20145181A
Other languages
Japanese (ja)
Other versions
JPS58104118A (en
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed filed Critical
Priority to JP56201451A priority Critical patent/JPS58104118A/en
Publication of JPS58104118A publication Critical patent/JPS58104118A/en
Publication of JPH048484B2 publication Critical patent/JPH048484B2/ja
Granted legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D5/00Heat treatments of cast-iron

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Mechanical Engineering (AREA)
  • Materials Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Heat Treatment Of Articles (AREA)

Description

【発明の詳細な説明】 この発明はレーザビームのような高密度エネル
ギー源を使用して耐摩耗性表面を生成する生成方
法に関する。
DETAILED DESCRIPTION OF THE INVENTION This invention relates to a method of producing a wear-resistant surface using a high density energy source such as a laser beam.

一般にフエライト基地の球状黒鉛鋳鉄またはコ
ンパクトバーミユキユラ鋳鉄(以下単にCV鋳鉄
という)は鋼に匹敵する延性を有しているが、そ
の反面硬度が低いため耐摩耗性に劣る欠点があつ
た。そこで従来では高周波焼入れなどの熱処理に
よつてフエライト基地、あるいは一部パーライト
を含む球状黒鉛鋳鉄またはCV鋳鉄の球状黒鉛の
周囲をマルテンサイト組織もしくはベイナイト組
織、ソルバイト組織で囲んでやる(以下このよう
な組織を環状第2相という)ことによつて耐塑性
流動性の改善と耐摩耗性の向上を図つていた。
In general, ferrite-based spheroidal graphite cast iron or compact vermiform cast iron (hereinafter simply referred to as CV cast iron) has a ductility comparable to that of steel, but on the other hand, it has the disadvantage of poor wear resistance due to its low hardness. Conventionally, heat treatment such as induction hardening is used to surround the ferrite base or the spheroidal graphite in spheroidal graphite cast iron or CV cast iron containing some pearlite with a martensitic structure, bainite structure, or sorbite structure (hereinafter, such a structure is used). The structure is called an annular second phase) to improve plastic flow resistance and wear resistance.

しかし従来の熱処理方法では加熱温度のバラツ
キが大きいなどから安定した環状第2相を得るの
が困難であつたり、環状第2相の生成によりフエ
ライト基地球状黒鉛鋳鉄の特徴である延性、耐摩
耗性が阻害されるなど、上記母材の有する性質が
低下するなどの欠点があつた。
However, with conventional heat treatment methods, it is difficult to obtain a stable annular second phase due to large variations in heating temperature. There were drawbacks such as the properties of the base material deteriorated, such as inhibition of the properties of the base material.

この発明はかかる欠点を改善する目的でなされ
たもので、レーザビームや電子ビームなどの高密
度エネルギー源をフエライト基地のまたは一部パ
ーライトを含む球状黒鉛鋳鉄やCV鋳鉄に照射す
ることにより、安定した環状第2相が容易に得ら
れるようにした高密度エネルギー源による耐摩耗
性表面の生成方法を提供して、延性や耐衝撃性を
損なうことなく耐摩耗表面が得られるようにした
ものである。
This invention was made with the aim of improving such drawbacks, and by irradiating ferrite-based or partially pearlite-based spheroidal graphite cast iron or CV cast iron with a high-density energy source such as a laser beam or an electron beam, stable The present invention provides a method for producing a wear-resistant surface using a high-density energy source in which an annular second phase is easily obtained, thereby providing a wear-resistant surface without compromising ductility or impact resistance. .

以下この発明の一実施例を図面を参照して詳述
すると、耐摩耗性表面を生成すべき母材1をフエ
ライト基地またはパーライトを一部含んだフエラ
イト基地の球状黒鉛鋳鉄及びCV鋳鉄より形成し、
この母材1の表面にCO2ガスレーザビームよりな
る高密度エネルギー源2を照射したところ、エネ
ルギー密度が2J/s・cm2〜200J/s・cm2の範囲で
環状第2相を有する組織が母材1の表面に生成さ
れた。またエネルギー密度を1J/s・cm2〜150J/
s・cm2の範囲で2回以上同様な高密度エネルギー
源2を照射したところ、環状第2相を母材1の表
面に生成することもできた。
Hereinafter, one embodiment of the present invention will be described in detail with reference to the drawings. The base material 1 on which the wear-resistant surface is to be formed is made of ferrite-based or ferrite-based spheroidal graphite cast iron and CV cast iron containing a portion of pearlite. ,
When the surface of this base material 1 was irradiated with a high-density energy source 2 consisting of a CO 2 gas laser beam, a structure having an annular second phase was formed at an energy density in the range of 2 J/s·cm 2 to 200 J/s·cm 2 . generated on the surface of base material 1. Also, the energy density is 1J/s・cm 2 ~150J/
When the same high-density energy source 2 was irradiated twice or more in the range of s·cm 2 , it was also possible to generate an annular second phase on the surface of the base material 1 .

なお、高密度エネルギー源のエネルギー密度が
2J/s・cm2未満の場合には、表面温度上昇不足と
なり、炭素のフエライト地への拡散が不足してα
化せず、環状第2相が生成しなくなり、一方、
200J/s・cm2以上は表面溶融によるチル化領域で
あるため、エネルギー密度2〜200J/s・cm2の範
囲が最適の環状第2相生成領域である。
Note that the energy density of the high-density energy source is
If it is less than 2J/s・cm2, the surface temperature will not rise enough, and the diffusion of carbon into the ferrite layer will be insufficient, resulting in α
, and the cyclic second phase is no longer generated; on the other hand,
Since a region of 200 J/s·cm 2 or more is a chilling region due to surface melting, an energy density range of 2 to 200 J/s·cm 2 is an optimal annular second phase generation region.

さらにレーザビームに変え電子ビームを高密度
エネルギー源2に使用して上記と同様なエネルギ
ー密度範囲で照射しても同様な環状第2相が生成
されることが確認できた。
Furthermore, it was confirmed that a similar annular second phase was generated even if an electron beam was used as the high-density energy source 2 instead of a laser beam and irradiated in the same energy density range as above.

次に高密度エネルギー源2の照射前及び照射後
の組織を顕微鏡写真(×200)で撮影して比較し
たところ第2図a,b及び第3図a,bに示す通
りであつた。すなわち第2図aは高密度エネルギ
ー源照射前の球状黒鉛鋳鉄のミクロ組織、そして
第2図bが照射後のミクロ組織で、球状黒鉛の周
囲が環状第2相で囲まれている状態がよくわか
る。また第3図aは高密度エネルギー源照射前の
CV鋳鉄のミクロ組織、そして第3図bが照射後
のミクロ組織で、CV鋳鉄の場合も環状第2相の
生成状態がよくわかる。なおこれら写真の何れも
上側が母材1の表面である。
Next, microscopic photographs (×200) of the tissues before and after irradiation with the high-density energy source 2 were taken and compared, and the results were as shown in FIGS. 2a, b and 3 a, b. In other words, Figure 2a shows the microstructure of spheroidal graphite cast iron before irradiation with a high-density energy source, and Figure 2b shows the microstructure after irradiation.The spheroidal graphite is often surrounded by an annular second phase. Recognize. In addition, Figure 3a shows the state before irradiation with the high-density energy source.
The microstructure of CV cast iron, and Figure 3b shows the microstructure after irradiation, clearly showing the formation of the annular second phase in the case of CV cast iron as well. Note that in all of these photographs, the upper side is the surface of the base material 1.

次に上記熱処理により環状第2相が生成された
耐摩耗性表面の耐摩耗性を確認するため、第5図
に示す耐摩擦摩耗試験機で摩耗試験を行つた。
Next, in order to confirm the wear resistance of the wear-resistant surface on which the annular second phase was generated by the heat treatment, a wear test was conducted using a friction and wear tester shown in FIG.

また比較のため、SCSiMn2材に高周波焼入れ
したものを従来品として同様な摩耗試験を行つた
結果も併せて記載する。試験に当つては高密度エ
ネルギー源2で熱処理した母材1と、高周波焼入
れをした従来品(第5図に示す)を試験機の取付
けソケツト5に取付けて、周速0.5m/secで回転
する試料デイスク6へ350Kg/cm2の面圧で圧接し、
摩耗を測定した。
For comparison, we also report the results of a similar wear test conducted on a conventional SCSiMn 2 material subjected to induction hardening. For the test, the base material 1 heat-treated with the high-density energy source 2 and the conventional product (shown in Figure 5) subjected to induction hardening were attached to the mounting socket 5 of the testing machine and rotated at a circumferential speed of 0.5 m/sec. Press the sample disk 6 with a surface pressure of 350 kg/cm 2 to
Wear was measured.

なお7は面圧監視用の圧力計で、取付けソケツ
ト5に連結されたガイド軸8に荷動測定用ロード
セル9及びカツプリング10を介して接続されて
いる。
Reference numeral 7 denotes a pressure gauge for monitoring surface pressure, which is connected to a guide shaft 8 connected to the mounting socket 5 via a load cell 9 for measuring load movement and a coupling 10.

また相手材(試料デイスク6)にはLBc−3を
用いた。
In addition, LBc-3 was used as the mating material (sample disk 6).

上記方法で12時間摩耗試験を行つた結果を第4
図に示す。この図から明らかなように、高周波焼
入れをした従来品に比べて耐摩耗性が格段に向上
したことがわかる。
The results of a 12-hour wear test using the above method are shown in the 4th test.
As shown in the figure. As is clear from this figure, it can be seen that the wear resistance has been significantly improved compared to conventional products that have been induction hardened.

また第4図中oは母材1を熱処理しない場合の
耐摩耗性を示したもので、熱処理による効果が一
層明らかである。
Further, o in FIG. 4 shows the wear resistance when the base material 1 is not heat treated, and the effect of the heat treatment is even clearer.

この発明は以上詳述したように、フエライト基
地または一部パーライトを含むフエライト基地の
球状黒鉛鋳鉄またはCV鋳鉄に高密度エネルギー
源を照射して、球状黒鉛の周囲に環状第2相を生
成するようにしたことから、上記環状第2相によ
り母材表面の耐摩耗性が著じるしく向上すると共
に、上記環状第2相は母材の表面付近のみに生成
されるため、母材の延材や耐衝撃性が阻害される
ことも少ない。また高密度エネルギー源を母材の
表面のみに照射することから、母材に熱歪が発生
することも少なく、これによつて歪取りなどの作
業が不要になると共に研削も容易に行なえること
から、研削作業などの工数も大幅に低減できる。
しかも高周波熱処理のように冷却水に投入する必
要がないため、酸化などによる面粗れもほとんど
なく、これによつて処理後の手直しも必要としな
い。
As described in detail above, this invention irradiates spheroidal graphite cast iron or CV cast iron with a ferrite base or a ferrite base containing some pearlite with a high-density energy source to generate an annular second phase around the spheroidal graphite. Therefore, the wear resistance of the base material surface is significantly improved by the annular second phase, and since the annular second phase is generated only near the surface of the base material, the rolled material of the base material is and impact resistance are less likely to be impaired. In addition, since the high-density energy source is irradiated only on the surface of the base material, thermal distortion is less likely to occur in the base material, which eliminates the need for work such as strain relief and makes grinding easier. Therefore, the man-hours required for grinding work etc. can be significantly reduced.
Moreover, unlike high-frequency heat treatment, there is no need to pour cooling water, so there is almost no surface roughening due to oxidation, etc., and therefore no rework is required after treatment.

【図面の簡単な説明】[Brief explanation of drawings]

第1図はこの発明方法の一実施例を示す説明
図、第2図a,b及び第3図a,bは球状黒鉛鋳
鉄及びCV鋳鉄の処理前及び処理後の顕微鏡写真、
第4図は耐摩耗試験結果を示す線図、第5図は摩
擦摩耗試験機の説明図である。 1は母材、2は高密度エネルギー源。
FIG. 1 is an explanatory diagram showing an embodiment of the method of the present invention, FIGS. 2 a, b and 3 a, b are micrographs of spheroidal graphite cast iron and CV cast iron before and after treatment,
FIG. 4 is a diagram showing the results of the abrasion test, and FIG. 5 is an explanatory diagram of the friction and wear tester. 1 is the base material and 2 is the high-density energy source.

Claims (1)

【特許請求の範囲】[Claims] 1 球状黒鉛鋳鉄及びコンパクトバーミユキラ鋳
鉄(CV鋳鉄)のフエライト基地や、一部パーラ
イトを含むフエライト基地よりなる母材1の表面
に、レーザや電子ビームよりなるエネルギー密度
2〜200J/s・cm2の高密度エネルギー源2を照射
して、上記母材1の表面にマルテンサイト組織の
環状第2相を生成することを特徴とする高密度エ
ネルギー源による耐摩耗性表面の生成方法。
1. An energy density of 2 to 200 J/s cm by a laser or an electron beam is applied to the surface of the base material 1, which is made of a ferrite base of spheroidal graphite cast iron and compact vermilion cast iron (CV cast iron), or a ferrite base containing some pearlite. 2. A method for producing a wear-resistant surface using a high-density energy source, the method comprising: irradiating the base material 1 with a high-density energy source 2 to generate an annular second phase of martensitic structure on the surface of the base material 1.
JP56201451A 1981-12-16 1981-12-16 Formation of abrasion resistant surface by high density energy source Granted JPS58104118A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP56201451A JPS58104118A (en) 1981-12-16 1981-12-16 Formation of abrasion resistant surface by high density energy source

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP56201451A JPS58104118A (en) 1981-12-16 1981-12-16 Formation of abrasion resistant surface by high density energy source

Publications (2)

Publication Number Publication Date
JPS58104118A JPS58104118A (en) 1983-06-21
JPH048484B2 true JPH048484B2 (en) 1992-02-17

Family

ID=16441299

Family Applications (1)

Application Number Title Priority Date Filing Date
JP56201451A Granted JPS58104118A (en) 1981-12-16 1981-12-16 Formation of abrasion resistant surface by high density energy source

Country Status (1)

Country Link
JP (1) JPS58104118A (en)

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS58175620A (en) * 1982-04-08 1983-10-14 株式会社東芝 Method of molding powdered body
JP5088912B2 (en) * 2001-01-16 2012-12-05 高周波熱錬株式会社 Method of strengthening fatigue strength of spheroidal graphite cast iron by induction surface hardening and spheroidal graphite cast iron with excellent fatigue strength
ITRE20050025A1 (en) * 2005-03-10 2006-09-11 Ognibene Spa METHOD AND EQUIPMENT FOR THE HARDENING OF THE INTERNAL SURFACE OF HOLES, IN MECHANICAL PIECES OF CAST IRON WITH A FERRITIC MATRIX
RU2711389C1 (en) * 2019-05-06 2020-01-17 федеральное государственное бюджетное образовательное учреждение высшего образования "Волгоградский государственный аграрный университет" (ФГБОУ ВО Волгоградский ГАУ) Method of increasing wear resistance of working elements from high-strength cast iron with co2-laser

Family Cites Families (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6262495B1 (en) * 1998-03-30 2001-07-17 The Regents Of The University Of California Circuit and method for eliminating surface currents on metals
US6628242B1 (en) * 2000-08-23 2003-09-30 Innovative Technology Licensing, Llc High impedence structures for multifrequency antennas and waveguides
US6411261B1 (en) * 2001-02-26 2002-06-25 E-Tenna Corporation Artificial magnetic conductor system and method for manufacturing
JP2008191139A (en) * 2007-01-09 2008-08-21 Mitsubishi Electric Corp Physical quantity measuring device
JP4821722B2 (en) * 2007-07-09 2011-11-24 ソニー株式会社 Antenna device

Also Published As

Publication number Publication date
JPS58104118A (en) 1983-06-21

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