JPH05342B2 - - Google Patents
Info
- Publication number
- JPH05342B2 JPH05342B2 JP59133423A JP13342384A JPH05342B2 JP H05342 B2 JPH05342 B2 JP H05342B2 JP 59133423 A JP59133423 A JP 59133423A JP 13342384 A JP13342384 A JP 13342384A JP H05342 B2 JPH05342 B2 JP H05342B2
- Authority
- JP
- Japan
- Prior art keywords
- alumina
- double prime
- beta
- cations
- beta double
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims description 105
- 150000001768 cations Chemical class 0.000 claims description 88
- 239000000463 material Substances 0.000 claims description 60
- 239000013078 crystal Substances 0.000 claims description 46
- 238000000034 method Methods 0.000 claims description 31
- 150000003839 salts Chemical group 0.000 claims description 22
- 239000000203 mixture Substances 0.000 claims description 16
- 238000002844 melting Methods 0.000 claims description 3
- 230000008018 melting Effects 0.000 claims description 3
- 238000013508 migration Methods 0.000 claims description 3
- 230000005012 migration Effects 0.000 claims description 3
- 150000002258 gallium Chemical class 0.000 claims 1
- 230000003287 optical effect Effects 0.000 description 36
- 239000011734 sodium Substances 0.000 description 23
- 229910000873 Beta-alumina solid electrolyte Inorganic materials 0.000 description 17
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 17
- 229910052708 sodium Inorganic materials 0.000 description 17
- 238000009830 intercalation Methods 0.000 description 16
- 230000002687 intercalation Effects 0.000 description 14
- 150000002500 ions Chemical class 0.000 description 12
- 229910052747 lanthanoid Inorganic materials 0.000 description 12
- 150000002602 lanthanoids Chemical class 0.000 description 11
- 230000008569 process Effects 0.000 description 10
- 239000007787 solid Substances 0.000 description 9
- 239000007858 starting material Substances 0.000 description 8
- 150000004645 aluminates Chemical class 0.000 description 7
- JLJWIVHYUCBSRC-UHFFFAOYSA-N benzene;9-[fluoren-9-ylidene(phenyl)methyl]fluorene Chemical compound C1=CC=CC=C1.C1=CC=CC=C1C([C]1C2=CC=CC=C2C2=CC=CC=C21)=C1C2=CC=CC=C2C2=CC=CC=C21 JLJWIVHYUCBSRC-UHFFFAOYSA-N 0.000 description 7
- 238000006243 chemical reaction Methods 0.000 description 7
- 238000003780 insertion Methods 0.000 description 7
- 230000037431 insertion Effects 0.000 description 7
- 238000005342 ion exchange Methods 0.000 description 7
- 238000004020 luminiscence type Methods 0.000 description 7
- 229910052768 actinide Inorganic materials 0.000 description 6
- 150000001255 actinides Chemical class 0.000 description 6
- 239000007789 gas Substances 0.000 description 6
- 230000015572 biosynthetic process Effects 0.000 description 4
- 238000005086 pumping Methods 0.000 description 4
- 125000002091 cationic group Chemical group 0.000 description 3
- 238000010586 diagram Methods 0.000 description 3
- LNTHITQWFMADLM-UHFFFAOYSA-N gallic acid Chemical compound OC(=O)C1=CC(O)=C(O)C(O)=C1 LNTHITQWFMADLM-UHFFFAOYSA-N 0.000 description 3
- -1 lanthanide aluminate Chemical class 0.000 description 3
- 238000002360 preparation method Methods 0.000 description 3
- 229910052709 silver Inorganic materials 0.000 description 3
- 239000004332 silver Substances 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- 238000003786 synthesis reaction Methods 0.000 description 3
- 229910052693 Europium Inorganic materials 0.000 description 2
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 description 2
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 2
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 2
- 230000004913 activation Effects 0.000 description 2
- 229910052783 alkali metal Inorganic materials 0.000 description 2
- ANBBXQWFNXMHLD-UHFFFAOYSA-N aluminum;sodium;oxygen(2-) Chemical compound [O-2].[O-2].[Na+].[Al+3] ANBBXQWFNXMHLD-UHFFFAOYSA-N 0.000 description 2
- 229910001422 barium ion Inorganic materials 0.000 description 2
- 239000011575 calcium Substances 0.000 description 2
- 230000008859 change Effects 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- OGPBJKLSAFTDLK-UHFFFAOYSA-N europium atom Chemical compound [Eu] OGPBJKLSAFTDLK-UHFFFAOYSA-N 0.000 description 2
- 238000002189 fluorescence spectrum Methods 0.000 description 2
- 229910052742 iron Inorganic materials 0.000 description 2
- 229910052744 lithium Inorganic materials 0.000 description 2
- 229910052700 potassium Inorganic materials 0.000 description 2
- 239000011591 potassium Substances 0.000 description 2
- 230000002285 radioactive effect Effects 0.000 description 2
- 238000012552 review Methods 0.000 description 2
- 229910052701 rubidium Inorganic materials 0.000 description 2
- IGLNJRXAVVLDKE-UHFFFAOYSA-N rubidium atom Chemical compound [Rb] IGLNJRXAVVLDKE-UHFFFAOYSA-N 0.000 description 2
- 229910001388 sodium aluminate Inorganic materials 0.000 description 2
- 229910001415 sodium ion Inorganic materials 0.000 description 2
- QDNXSIYWHYGMCD-UHFFFAOYSA-N 2-(methylamino)-1-(3-methylphenyl)propan-1-one Chemical compound CNC(C)C(=O)C1=CC=CC(C)=C1 QDNXSIYWHYGMCD-UHFFFAOYSA-N 0.000 description 1
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
- 229910052684 Cerium Inorganic materials 0.000 description 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- 229920000742 Cotton Polymers 0.000 description 1
- 241000254158 Lampyridae Species 0.000 description 1
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 1
- 229910020068 MgAl Inorganic materials 0.000 description 1
- 229910052779 Neodymium Inorganic materials 0.000 description 1
- FKNQFGJONOIPTF-UHFFFAOYSA-N Sodium cation Chemical compound [Na+] FKNQFGJONOIPTF-UHFFFAOYSA-N 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- 229910052776 Thorium Inorganic materials 0.000 description 1
- 150000001242 acetic acid derivatives Chemical class 0.000 description 1
- 239000011149 active material Substances 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 150000001340 alkali metals Chemical class 0.000 description 1
- 229910045601 alloy Inorganic materials 0.000 description 1
- 239000000956 alloy Substances 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- 230000003466 anti-cipated effect Effects 0.000 description 1
- 125000004429 atom Chemical group 0.000 description 1
- 229910052788 barium Inorganic materials 0.000 description 1
- DSAJWYNOEDNPEQ-UHFFFAOYSA-N barium atom Chemical compound [Ba] DSAJWYNOEDNPEQ-UHFFFAOYSA-N 0.000 description 1
- 239000002585 base Substances 0.000 description 1
- 229910052791 calcium Inorganic materials 0.000 description 1
- 238000005341 cation exchange Methods 0.000 description 1
- 239000000919 ceramic Substances 0.000 description 1
- ZMIGMASIKSOYAM-UHFFFAOYSA-N cerium Chemical compound [Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce] ZMIGMASIKSOYAM-UHFFFAOYSA-N 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 230000005518 electrochemistry Effects 0.000 description 1
- 230000005281 excited state Effects 0.000 description 1
- 229910052733 gallium Inorganic materials 0.000 description 1
- 238000007496 glass forming Methods 0.000 description 1
- 150000004820 halides Chemical class 0.000 description 1
- 238000007654 immersion Methods 0.000 description 1
- 230000001939 inductive effect Effects 0.000 description 1
- 238000006713 insertion reaction Methods 0.000 description 1
- 238000011835 investigation Methods 0.000 description 1
- 230000001678 irradiating effect Effects 0.000 description 1
- 238000002372 labelling Methods 0.000 description 1
- 229910052746 lanthanum Inorganic materials 0.000 description 1
- FZLIPJUXYLNCLC-UHFFFAOYSA-N lanthanum atom Chemical compound [La] FZLIPJUXYLNCLC-UHFFFAOYSA-N 0.000 description 1
- 229910052749 magnesium Inorganic materials 0.000 description 1
- 239000011777 magnesium Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000011159 matrix material Substances 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 239000000155 melt Substances 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 125000005609 naphthenate group Chemical group 0.000 description 1
- QEFYFXOXNSNQGX-UHFFFAOYSA-N neodymium atom Chemical compound [Nd] QEFYFXOXNSNQGX-UHFFFAOYSA-N 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 125000004430 oxygen atom Chemical group O* 0.000 description 1
- ISWSIDIOOBJBQZ-UHFFFAOYSA-M phenolate Chemical compound [O-]C1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-M 0.000 description 1
- 229940031826 phenolate Drugs 0.000 description 1
- 238000001953 recrystallisation Methods 0.000 description 1
- 229910052706 scandium Inorganic materials 0.000 description 1
- SIXSYDAISGFNSX-UHFFFAOYSA-N scandium atom Chemical compound [Sc] SIXSYDAISGFNSX-UHFFFAOYSA-N 0.000 description 1
- 239000007784 solid electrolyte Substances 0.000 description 1
- 241000894007 species Species 0.000 description 1
- 238000001228 spectrum Methods 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 229910052712 strontium Inorganic materials 0.000 description 1
- CIOAGBVUUVVLOB-UHFFFAOYSA-N strontium atom Chemical compound [Sr] CIOAGBVUUVVLOB-UHFFFAOYSA-N 0.000 description 1
- 238000000859 sublimation Methods 0.000 description 1
- 230000008022 sublimation Effects 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
- 150000003467 sulfuric acid derivatives Chemical class 0.000 description 1
- 238000012546 transfer Methods 0.000 description 1
- 230000007704 transition Effects 0.000 description 1
- 238000009281 ultraviolet germicidal irradiation Methods 0.000 description 1
- 229910000859 α-Fe Inorganic materials 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C30—CRYSTAL GROWTH
- C30B—SINGLE-CRYSTAL GROWTH; UNIDIRECTIONAL SOLIDIFICATION OF EUTECTIC MATERIAL OR UNIDIRECTIONAL DEMIXING OF EUTECTOID MATERIAL; REFINING BY ZONE-MELTING OF MATERIAL; PRODUCTION OF A HOMOGENEOUS POLYCRYSTALLINE MATERIAL WITH DEFINED STRUCTURE; SINGLE CRYSTALS OR HOMOGENEOUS POLYCRYSTALLINE MATERIAL WITH DEFINED STRUCTURE; AFTER-TREATMENT OF SINGLE CRYSTALS OR A HOMOGENEOUS POLYCRYSTALLINE MATERIAL WITH DEFINED STRUCTURE; APPARATUS THEREFOR
- C30B31/00—Diffusion or doping processes for single crystals or homogeneous polycrystalline material with defined structure; Apparatus therefor
- C30B31/04—Diffusion or doping processes for single crystals or homogeneous polycrystalline material with defined structure; Apparatus therefor by contacting with diffusion materials in the liquid state
-
- C—CHEMISTRY; METALLURGY
- C30—CRYSTAL GROWTH
- C30B—SINGLE-CRYSTAL GROWTH; UNIDIRECTIONAL SOLIDIFICATION OF EUTECTIC MATERIAL OR UNIDIRECTIONAL DEMIXING OF EUTECTOID MATERIAL; REFINING BY ZONE-MELTING OF MATERIAL; PRODUCTION OF A HOMOGENEOUS POLYCRYSTALLINE MATERIAL WITH DEFINED STRUCTURE; SINGLE CRYSTALS OR HOMOGENEOUS POLYCRYSTALLINE MATERIAL WITH DEFINED STRUCTURE; AFTER-TREATMENT OF SINGLE CRYSTALS OR A HOMOGENEOUS POLYCRYSTALLINE MATERIAL WITH DEFINED STRUCTURE; APPARATUS THEREFOR
- C30B29/00—Single crystals or homogeneous polycrystalline material with defined structure characterised by the material or by their shape
- C30B29/10—Inorganic compounds or compositions
- C30B29/16—Oxides
- C30B29/22—Complex oxides
-
- C—CHEMISTRY; METALLURGY
- C30—CRYSTAL GROWTH
- C30B—SINGLE-CRYSTAL GROWTH; UNIDIRECTIONAL SOLIDIFICATION OF EUTECTIC MATERIAL OR UNIDIRECTIONAL DEMIXING OF EUTECTOID MATERIAL; REFINING BY ZONE-MELTING OF MATERIAL; PRODUCTION OF A HOMOGENEOUS POLYCRYSTALLINE MATERIAL WITH DEFINED STRUCTURE; SINGLE CRYSTALS OR HOMOGENEOUS POLYCRYSTALLINE MATERIAL WITH DEFINED STRUCTURE; AFTER-TREATMENT OF SINGLE CRYSTALS OR A HOMOGENEOUS POLYCRYSTALLINE MATERIAL WITH DEFINED STRUCTURE; APPARATUS THEREFOR
- C30B31/00—Diffusion or doping processes for single crystals or homogeneous polycrystalline material with defined structure; Apparatus therefor
- C30B31/02—Diffusion or doping processes for single crystals or homogeneous polycrystalline material with defined structure; Apparatus therefor by contacting with diffusion materials in the solid state
-
- C—CHEMISTRY; METALLURGY
- C30—CRYSTAL GROWTH
- C30B—SINGLE-CRYSTAL GROWTH; UNIDIRECTIONAL SOLIDIFICATION OF EUTECTIC MATERIAL OR UNIDIRECTIONAL DEMIXING OF EUTECTOID MATERIAL; REFINING BY ZONE-MELTING OF MATERIAL; PRODUCTION OF A HOMOGENEOUS POLYCRYSTALLINE MATERIAL WITH DEFINED STRUCTURE; SINGLE CRYSTALS OR HOMOGENEOUS POLYCRYSTALLINE MATERIAL WITH DEFINED STRUCTURE; AFTER-TREATMENT OF SINGLE CRYSTALS OR A HOMOGENEOUS POLYCRYSTALLINE MATERIAL WITH DEFINED STRUCTURE; APPARATUS THEREFOR
- C30B31/00—Diffusion or doping processes for single crystals or homogeneous polycrystalline material with defined structure; Apparatus therefor
- C30B31/06—Diffusion or doping processes for single crystals or homogeneous polycrystalline material with defined structure; Apparatus therefor by contacting with diffusion material in the gaseous state
- C30B31/08—Diffusion or doping processes for single crystals or homogeneous polycrystalline material with defined structure; Apparatus therefor by contacting with diffusion material in the gaseous state the diffusion materials being a compound of the elements to be diffused
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Crystallography & Structural Chemistry (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Compounds Of Alkaline-Earth Elements, Aluminum Or Rare-Earth Metals (AREA)
- Crystals, And After-Treatments Of Crystals (AREA)
- Luminescent Compositions (AREA)
- Compounds Of Iron (AREA)
Description
æ¬çºæã¯ããŒã¿ããã«ãã©ã€ã ã¢ã«ããïŒbeta
double prime aluminaïŒç¥ç§°ã¯BDPAãšããïŒ
ããã³ããçš®ã®è¿çžç©è³ªã®æ§é å ãžã®å€äŸ¡éœã€ãª
ã³ã®æ¿å ¥ïŒintercalationïŒã«é¢ãããæ¬çºæã¯ãŸ
ããããŒã¿ããã«ãã©ã€ã ã¢ã«ãããžã®å€äŸ¡éœã€
ãªã³æ¿å ¥æ¹æ³ããã³ããã«ãã€ãŠè£œé ãããå€æ§
ããã«ãã©ã€ã ã¢ã«ããã䜿çšããç©åã«ãé¢ã
ããããã«ãŸããæ¬çºæã¯ãããå€æ§ãããç©è³ª
ã®ããçš®ã®ãã®ã®èå ç¹æ§ãŸãã¯ããå ç¹æ§ãã
ãã®ç©è³ªã®ã¬ãŒã¶çºå èœåãéçºããè£ çœ®ãšå ±ã«
å©çšããè£ çœ®ãæäŸããããšããæå³ããŠããã ïŒäŸ¡éœã€ãªã³ããã³ããçš®ã®ïŒäŸ¡éœã€ãªã³ãã
ãŒã¿ã¢ã«ããããã³ããŒã¿ããã«ãã©ã€ã ã¢ã«ã
ãã®äž¡è ã«æ¿å ¥ããããšã¯å ¬ç¥ã§ãããããã«ã€
ããŠã¯ããã¢ãªã³ãã³ïŒFarringtonïŒçã®
ãFast Ionic Transport in SolidsãïŒScienceïŒ
Vol.204ïŒppã»1371â1379ïŒ1979ïŒãåç §ãããã
ãããªãŠã ïŒã«ãªãŠã ïŒéïŒé ïŒãªããŠã ã®ããš
ãéœã€ãªã³ããã³ããçš®ã®ä»ã®å çŽ ã®éœã€ãªã³ã
äžèšïŒã€ã®ç©è³ªãžå°å ¥ããã³å°åºãããããšã¯ã
ã§ã«å ¬ç¥ã«å±ãããç°ãªãã¢ã«ããæ Œåå ã§ã®éœ
ã€ãªã³ã®å°é»çã¯åããã»ã¹ã®æŽ»æ§åãšãã«ã®ãŒ
ã«äŸåããäžæ¹ãã®æŽ»æ§åãšãã«ã®ãŒã¯ã€ãªã³ã®
倧ãããšããã®ã€ãªã³ã®åçš®ç©è³ªã®äŒå°é¢å ã§ã®
é žçŽ ååãšã®çµåæ§åãšã«é¢ä¿ããŠãããããªã
ã¡ãããŒã¿ã¢ã«ããã®å Žåã§ã¯ã掻æ§åãšãã«ã®
ãŒã¯ãããªãŠã ããã«ããžãŠã ãžãšã€ãªã³ã®ãµã€
ãºãå¢å€§ããã®ã«åŸã€ãŠå¢å ãããããŒã¿ã¢ã«ã
ãã®å Žåã«ã¯æ¿å ¥ããã€ãªã³ã®ãµã€ãºã倧ãããª
ãã«ãããã€ãŠæ¿å ¥ã®å°é£ã¯å¢å€§ããããšãäºæ
ããããåæ§ãªé¢ä¿ããã°ãããã©ã³ãã€ã
ïŒmagnetoplumbiteïŒãªãã³ã«ããŒã¿ããã«ãã©
ã€ã ã¢ã«ããã«ã€ããŠãååšãããšåŸæ¥ä¿¡ããã
ãŠããããã¢ãªã³ãã³ïŒFarringtonïŒãšãã³
ïŒDunnïŒã®ãDivalent Beta AluminasïŒHigh
Conductivity SolidElectrolytes for Divalent
CationsãïŒSolid State IonicsïŒVolã»ïŒïŒNo.
ïŒïŒppã»267â281ïŒ1982ïŒåç §ãïŒäŸ¡éœã€ãªã³ã
容æã«ããŒã¿ããã«ãã©ã€ã ã¢ã«ããå ã«æ¿å ¥ãŸ
ãã¯æ¡æ£ãããŠæ¿å ¥ããããŸãŸãã®ïŒäŸ¡ã€ãªã³ã
ãã®äžã«æ®ãããšãã§ããããšãèŠåºãããŠã
ããããããªãããïŒäŸ¡éœã€ãªã³ã¯ããŒã¿ã¢ã«ã
ãå ã§ã¯ããããŠç·©æ ¢ã«æ¡æ£ããããšã芳å¯ãã
ãŠãããïŒäŸ¡éœã€ãªã³ãããŒã¿ããã«ãã©ã€ã ã¢
ã«ããå ã«æ¡æ£ãããŠæ¿å ¥ãããæ§é ã圢æãã
ãããšã¯åã€ãŠããããåŸæ¥ïŒïŒïŒãŸãã¯ãã以
äžã®éœé»è·ãæã€éœã€ãªã³ãããªãã¡ïŒäŸ¡ïŒïŒäŸ¡
ãŸãã¯ãã以äžã®éœã€ãªã³ïŒä»¥äžãããããç·ç§°
ããŠå€äŸ¡éœã€ãªã³ãšããïŒã¯ããŒã¿ããã«ãã©ã€
ã ã¢ã«ããæ§é ãå«ãããããã®ã¢ã«ããæ Œåã«
ã浞éãåŸãªãã§ããããšæ³å®ãããŠããããã®
æšè«ã¯åŸæ¥ã®å®éšããŒã¿ã«ãã€ãŠãæ¯æãããŠã
ããããªãã¡ãããšãã°ãããŒã¿ããã«ãã©ã€ã
ã¢ã«ããå ã§ã®ãããªãŠã ã€ãªã³ã®å°é»çã¯25â
ã§çŽ10-2ohm-1cm-1ã§ããã®ã«å¯ŸããïŒïŒäŸ¡ïŒã
ãªãŠã ã€ãªã³ã®å°é»çã¯25âã§çŽ10-7ohm-1cm-1
ã§ããããããã®å°é»çã¯ããŒã¿ã¢ã«ããããã³
ãã°ãããã©ã³ãã€ãå ã§ã®å°é»çãããå®è³ªç
ã«é«ãããã§ããããŒã¿ããã«ãã©ã€ã ã¢ã«ãã
ãå«ãããããªãã¢ã«ããå ã§ãïŒäŸ¡éœã€ãªã³
ïŒïŒäŸ¡éœã€ãªã³ã¯èšããŸã§ããªãïŒã®å°é»çã¯æ¶
æ» çã«åŸ®å°ã§ããããŸãã¯å®åšããªãã§ããããš
äžè¬ã«äºæ³ãããŠããã 以äžã®ç¹ãèæ ®ããŠãããŸã§å€äŸ¡éœã€ãªã³ãæ¿
å ¥ããã¢ã«ããã®è£œé ã¯è©Šã¿ãããŠããªãã€ãã
ããããé«æž©åæãŸãã¯åçµæ¶ã«ãã€ãŠãäŸã
ã°ãã©ã³ã¿ããã¢ã«ãããŒãã¿ã€ãã®ææã®è£œé
ãè©Šã¿ãããŠãããããã«ã€ããŠã¯äžèšã®æç®ã
åç §ããããã ã«ãŒã³ïŒKahnïŒçã®ãPreparationïŒ
StructureïŒOptical and Magnetic Properties
of Lanthanide Alnminate Single Crystals
ïŒLnMAl11O19ïŒãïŒJournal of Applied PhysicsïŒ
Volã»52ïŒNo.11ïŒppã»6864â6869ïŒ1981ïŒïŒ Verstegenã®ã Survey of ïœ Group of
PhosphorsïŒBased on Hexagonal Aluminate
and Gallate Host LatticesãïŒJournal of the
Electrochemical SocietyïŒVolã»121ïŒNo.12ïŒ
ppã»1623â1627ïŒ1974ïŒïŒ DexpertâGhysçã®ãOptical and Slructural
Investigation of the Lanthanum βâAlumina
Phase Doped With EuropiumãïŒJournal of
Solid State ChemistryïŒVolã»19ïŒppã»193â
204ïŒ1976ïŒïŒ Stevelsçã®ãEu2+Luminescence
inHexagonal Aluminates Containing Large
Divalent or Trivalent CationsãïŒJournal of
the Electrochemical SocietyïŒVolã»123ïŒNo.
ïŒïŒppã»691â697ïŒ197ïŒãããã«ãKennedyçã®
ãProperties of βâAlumina Doped With
CeriumãïŒJournal of Solid States ChemislryïŒ
Volã»42ïŒppã»170â175ïŒ1982ïŒïŒ Verstegençã®ãThe Relation Between
Crystal Structure and Luminescence in βâ
Alumina and Magnetoplumbite PhasesãïŒ
Journal of LuminescenceïŒVolã»ïŒïŒppã»406
â414ïŒ1974ïŒã ããŒã¿ã¢ã«ãããŸãã¯ãã°ãããã©ã³ãã€ãã¿
ã€ãææäžã®éœã€ãªã³çœ®æãæ±ã€ããã®ä»ã®æç®
ãšããŠäžèšã®ãã®ãããã Mcwhançã®ãâRay Diffuse Scattering
from AlkaliïŒSilver and Europium βâ
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Claims (1)
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ããŠããç¹èš±è«æ±ã®ç¯å²ç¬¬ïŒé èšèŒã®æ¹æ³ã
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US509237 | 1983-06-29 | ||
| US06/509,237 US4664849A (en) | 1983-06-29 | 1983-06-29 | Optical materials from intercalation of polyvalent cations in beta double prime alumina |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS6051614A JPS6051614A (ja) | 1985-03-23 |
| JPH05342B2 true JPH05342B2 (ja) | 1993-01-05 |
Family
ID=24025801
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP59133423A Granted JPS6051614A (ja) | 1983-06-29 | 1984-06-29 | ãâã¿ãããã«ãã©ã€ã ãã¢ã«ããã«å€äŸ¡éœã€ãªã³ãæ¿å ¥ããå åŠææ |
Country Status (5)
| Country | Link |
|---|---|
| US (1) | US4664849A (ja) |
| EP (1) | EP0132321B1 (ja) |
| JP (1) | JPS6051614A (ja) |
| CA (1) | CA1240480A (ja) |
| DE (1) | DE3465753D1 (ja) |
Families Citing this family (14)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0196062B1 (en) * | 1985-03-27 | 1993-07-28 | Hitachi, Ltd. | Generator of coherent radiation using an intercalation compound |
| FR2600055B1 (fr) * | 1986-06-16 | 1988-08-26 | Commissariat Energie Atomique | Aluminates mixtes de lanthanide-magnesium, lasers utilisant des monocristaux de ces aluminates |
| US5458868A (en) * | 1989-11-09 | 1995-10-17 | Lilliwyte Societe Anonyme | Method of making analogues of β-alumina |
| GB8925289D0 (en) * | 1989-11-09 | 1989-12-28 | Lilliwyte Sa | Method of making analogues of beta"-alumina |
| DE4102136C1 (ja) * | 1991-01-25 | 1992-05-14 | Werner Prof. Dr.Rer.Nat. 3007 Gehrden De Urland | |
| US5415127A (en) * | 1993-07-07 | 1995-05-16 | Ontario Centre For Materials Research | Method of forming a single crystal film of sodium-beta "-alumina |
| RU2156329C2 (ru) * | 1996-04-18 | 2000-09-20 | ÐлекÑеев ÐгПÑÑ ÐаÑОлÑÐµÐ²ÐžÑ | СпПÑПб пПлÑÑÐµÐœÐžÑ ÐžÐœÑеÑкалОÑПваММÑÑ ÑПеЎОМеМОй О ÑПеЎОМеМОÑ, пПлÑÑеММÑе ÑÑОЌ ÑпПÑПбПЌ |
| DE19861087C2 (de) * | 1998-08-19 | 2000-11-23 | Dornier Gmbh | Verfahren zur Herstellung eines Werkstoffs aus Me-Ã"-Al¶2¶O¶3¶ und dessen Verwendung |
| DE19837505C1 (de) * | 1998-08-19 | 1999-12-30 | Dornier Gmbh | Nitrosyl-Ionen leitender Werkstoff aus NO+-beta"-Al¶2¶O¶3¶ und Verfahren zu seiner Herstellung |
| DE19847034C2 (de) * | 1998-10-13 | 2000-12-07 | Dornier Gmbh | Verfahren zur Herstellung einer lithiumstabilisierten Me-Ã"Al¶2¶O¶3¶-Keramik und deren Verwendung |
| DE10249443B4 (de) * | 2002-10-24 | 2004-09-30 | Daimlerchrysler Ag | Verfahren zur Herstellung von Keramiken mit ausgerichteten IonenleitfÀhigkeitsebenen, Keramik und Verwendung des Verfahrens zur Herstellung von Keramiken mit ausgerichteten IonenleitfÀhigkeitsebenen |
| US8741119B1 (en) | 2011-03-03 | 2014-06-03 | U.S. Department Of Energy | Actinide ion sensor for pyroprocess monitoring |
| US9163297B2 (en) | 2012-08-07 | 2015-10-20 | Justin Langley | Method for the integration of carbochlorination into a staged reforming operation as an alternative to direct residue oxidation for the recovery of valuable metals |
| US10601062B2 (en) | 2015-10-01 | 2020-03-24 | Dynantis Corp. | Sodium metal batteries with intercalating cathode |
Family Cites Families (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4376709A (en) * | 1980-11-10 | 1983-03-15 | Exxon Research And Engineering Co. | Intercalated layered mixed oxides |
-
1983
- 1983-06-29 US US06/509,237 patent/US4664849A/en not_active Expired - Fee Related
-
1984
- 1984-06-28 CA CA000457689A patent/CA1240480A/en not_active Expired
- 1984-06-28 EP EP84304400A patent/EP0132321B1/en not_active Expired
- 1984-06-28 DE DE8484304400T patent/DE3465753D1/de not_active Expired
- 1984-06-29 JP JP59133423A patent/JPS6051614A/ja active Granted
Also Published As
| Publication number | Publication date |
|---|---|
| DE3465753D1 (en) | 1987-10-08 |
| EP0132321A1 (en) | 1985-01-30 |
| EP0132321B1 (en) | 1987-09-02 |
| JPS6051614A (ja) | 1985-03-23 |
| US4664849A (en) | 1987-05-12 |
| CA1240480A (en) | 1988-08-16 |
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