JPH0559150B2 - - Google Patents
Info
- Publication number
- JPH0559150B2 JPH0559150B2 JP13980183A JP13980183A JPH0559150B2 JP H0559150 B2 JPH0559150 B2 JP H0559150B2 JP 13980183 A JP13980183 A JP 13980183A JP 13980183 A JP13980183 A JP 13980183A JP H0559150 B2 JPH0559150 B2 JP H0559150B2
- Authority
- JP
- Japan
- Prior art keywords
- parts
- water
- powder
- composition
- pigment
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000000049 pigment Substances 0.000 claims description 28
- 239000000203 mixture Substances 0.000 claims description 27
- 239000000839 emulsion Substances 0.000 claims description 20
- 239000003973 paint Substances 0.000 claims description 20
- 229920005989 resin Polymers 0.000 claims description 14
- 239000011347 resin Substances 0.000 claims description 14
- 229920003169 water-soluble polymer Polymers 0.000 claims description 5
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 25
- 239000000843 powder Substances 0.000 description 19
- 239000011248 coating agent Substances 0.000 description 13
- 238000000576 coating method Methods 0.000 description 13
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 description 9
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 6
- 229910052751 metal Inorganic materials 0.000 description 6
- 239000002184 metal Substances 0.000 description 6
- 229920001353 Dextrin Polymers 0.000 description 5
- 239000004375 Dextrin Substances 0.000 description 5
- 235000019425 dextrin Nutrition 0.000 description 5
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 5
- 229920002554 vinyl polymer Polymers 0.000 description 5
- 239000002202 Polyethylene glycol Substances 0.000 description 4
- 229920006026 co-polymeric resin Polymers 0.000 description 4
- 238000002845 discoloration Methods 0.000 description 4
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 4
- 229920001223 polyethylene glycol Polymers 0.000 description 4
- 238000007711 solidification Methods 0.000 description 4
- 230000008023 solidification Effects 0.000 description 4
- 229920002134 Carboxymethyl cellulose Polymers 0.000 description 3
- 102000004190 Enzymes Human genes 0.000 description 3
- 108090000790 Enzymes Proteins 0.000 description 3
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 3
- 239000004606 Fillers/Extenders Substances 0.000 description 3
- 229920003114 HPC-L Polymers 0.000 description 3
- 229920002153 Hydroxypropyl cellulose Polymers 0.000 description 3
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 description 3
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 3
- 229910000019 calcium carbonate Inorganic materials 0.000 description 3
- 239000001768 carboxy methyl cellulose Substances 0.000 description 3
- 235000010948 carboxy methyl cellulose Nutrition 0.000 description 3
- 239000008112 carboxymethyl-cellulose Substances 0.000 description 3
- 238000001035 drying Methods 0.000 description 3
- 239000001863 hydroxypropyl cellulose Substances 0.000 description 3
- 235000010977 hydroxypropyl cellulose Nutrition 0.000 description 3
- 229920000036 polyvinylpyrrolidone Polymers 0.000 description 3
- 239000001267 polyvinylpyrrolidone Substances 0.000 description 3
- 235000013855 polyvinylpyrrolidone Nutrition 0.000 description 3
- 229910001369 Brass Inorganic materials 0.000 description 2
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 2
- -1 acrylic ester Chemical class 0.000 description 2
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 239000010951 brass Substances 0.000 description 2
- 229920001577 copolymer Polymers 0.000 description 2
- 238000007865 diluting Methods 0.000 description 2
- 239000001023 inorganic pigment Substances 0.000 description 2
- 229920000609 methyl cellulose Polymers 0.000 description 2
- 239000001923 methylcellulose Substances 0.000 description 2
- 235000010981 methylcellulose Nutrition 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- GSGDTSDELPUTKU-UHFFFAOYSA-N nonoxybenzene Chemical compound CCCCCCCCCOC1=CC=CC=C1 GSGDTSDELPUTKU-UHFFFAOYSA-N 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 239000004094 surface-active agent Substances 0.000 description 2
- JNYAEWCLZODPBN-JGWLITMVSA-N (2r,3r,4s)-2-[(1r)-1,2-dihydroxyethyl]oxolane-3,4-diol Chemical compound OC[C@@H](O)[C@H]1OC[C@H](O)[C@H]1O JNYAEWCLZODPBN-JGWLITMVSA-N 0.000 description 1
- QTSNFLIDNYOATQ-UHFFFAOYSA-N 2-[(4-chloro-2-nitrophenyl)diazenyl]-n-(2-chlorophenyl)-3-oxobutanamide Chemical compound C=1C=CC=C(Cl)C=1NC(=O)C(C(=O)C)N=NC1=CC=C(Cl)C=C1[N+]([O-])=O QTSNFLIDNYOATQ-UHFFFAOYSA-N 0.000 description 1
- NBOCQTNZUPTTEI-UHFFFAOYSA-N 4-[4-(hydrazinesulfonyl)phenoxy]benzenesulfonohydrazide Chemical compound C1=CC(S(=O)(=O)NN)=CC=C1OC1=CC=C(S(=O)(=O)NN)C=C1 NBOCQTNZUPTTEI-UHFFFAOYSA-N 0.000 description 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 1
- 239000005977 Ethylene Substances 0.000 description 1
- 229920000084 Gum arabic Polymers 0.000 description 1
- 229920000663 Hydroxyethyl cellulose Polymers 0.000 description 1
- 239000004354 Hydroxyethyl cellulose Substances 0.000 description 1
- 229920000881 Modified starch Polymers 0.000 description 1
- 239000004372 Polyvinyl alcohol Substances 0.000 description 1
- 241000978776 Senegalia senegal Species 0.000 description 1
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 1
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 1
- 239000004288 Sodium dehydroacetate Substances 0.000 description 1
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 1
- 239000000205 acacia gum Substances 0.000 description 1
- 235000010489 acacia gum Nutrition 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 125000005396 acrylic acid ester group Chemical group 0.000 description 1
- 239000012190 activator Substances 0.000 description 1
- 150000005215 alkyl ethers Chemical class 0.000 description 1
- 239000003945 anionic surfactant Substances 0.000 description 1
- QRUDEWIWKLJBPS-UHFFFAOYSA-N benzotriazole Chemical compound C1=CC=C2N[N][N]C2=C1 QRUDEWIWKLJBPS-UHFFFAOYSA-N 0.000 description 1
- 239000012964 benzotriazole Substances 0.000 description 1
- 239000012461 cellulose resin Substances 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 1
- 229910052737 gold Inorganic materials 0.000 description 1
- 239000010931 gold Substances 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 235000019447 hydroxyethyl cellulose Nutrition 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 235000010187 litholrubine BK Nutrition 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 235000019426 modified starch Nutrition 0.000 description 1
- PSZYNBSKGUBXEH-UHFFFAOYSA-N naphthalene-1-sulfonic acid Chemical compound C1=CC=C2C(S(=O)(=O)O)=CC=CC2=C1 PSZYNBSKGUBXEH-UHFFFAOYSA-N 0.000 description 1
- 229920005615 natural polymer Polymers 0.000 description 1
- 239000012860 organic pigment Substances 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 230000035515 penetration Effects 0.000 description 1
- 229920002451 polyvinyl alcohol Polymers 0.000 description 1
- 235000019422 polyvinyl alcohol Nutrition 0.000 description 1
- 239000003755 preservative agent Substances 0.000 description 1
- 230000003449 preventive effect Effects 0.000 description 1
- RMAQACBXLXPBSY-UHFFFAOYSA-N silicic acid Chemical compound O[Si](O)(O)O RMAQACBXLXPBSY-UHFFFAOYSA-N 0.000 description 1
- 235000012239 silicon dioxide Nutrition 0.000 description 1
- 229910052709 silver Inorganic materials 0.000 description 1
- 239000004332 silver Substances 0.000 description 1
- 229940079839 sodium dehydroacetate Drugs 0.000 description 1
- 235000019259 sodium dehydroacetate Nutrition 0.000 description 1
- DSOWAKKSGYUMTF-GZOLSCHFSA-M sodium;(1e)-1-(6-methyl-2,4-dioxopyran-3-ylidene)ethanolate Chemical compound [Na+].C\C([O-])=C1/C(=O)OC(C)=CC1=O DSOWAKKSGYUMTF-GZOLSCHFSA-M 0.000 description 1
- HIEHAIZHJZLEPQ-UHFFFAOYSA-M sodium;naphthalene-1-sulfonate Chemical compound [Na+].C1=CC=C2C(S(=O)(=O)[O-])=CC=CC2=C1 HIEHAIZHJZLEPQ-UHFFFAOYSA-M 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 150000005846 sugar alcohols Polymers 0.000 description 1
- 229920003002 synthetic resin Polymers 0.000 description 1
- 239000000057 synthetic resin Substances 0.000 description 1
- 229910001887 tin oxide Inorganic materials 0.000 description 1
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 1
- REDSKZBUUUQMSK-UHFFFAOYSA-N tributyltin Chemical compound CCCC[Sn](CCCC)CCCC.CCCC[Sn](CCCC)CCCC REDSKZBUUUQMSK-UHFFFAOYSA-N 0.000 description 1
Landscapes
- Paints Or Removers (AREA)
Description
【発明の詳細な説明】
本発明は粉末状絵具組成物に関し、詳しくは水
でうすめ塗布した塗膜が乾燥した後は耐水性とな
る粉末状絵具組成物を得ることを目的とする。DETAILED DESCRIPTION OF THE INVENTION The present invention relates to a powdered paint composition, and more specifically, it is an object of the present invention to obtain a powdered paint composition that becomes water resistant after a coating film diluted with water is dried.
従来の係る組成物は顔料、水溶性高分子等より
なり使用時水で溶き所望粘度のペースト状絵具に
調整し使用するものである。しかしその塗膜は耐
水性を有しない為に水に触れると再溶解し塗面が
汚れる欠点があり屋外へ出すポスター等には使用
できなかつた。一方、アクリル酸エステル樹脂エ
マルジヨンを用いて塗膜が乾燥後耐水性となるペ
ースト状絵具があるが顔料の選択性があり、ビリ
ジヤンやオーレオリン等無機顔料やアルミ粉、真
鋳粉等金属粉顔料は使用できない欠点がある。 Such conventional compositions are composed of pigments, water-soluble polymers, etc., and are dissolved in water and adjusted to a paste-like paint of a desired viscosity before use. However, since the coating film is not water resistant, it re-dissolves when exposed to water and stains the coating surface, making it unsuitable for use in posters and the like to be displayed outdoors. On the other hand, there are paste-like paints that use acrylic acid ester resin emulsion to make the paint film waterproof after drying, but there is pigment selectivity, and inorganic pigments such as viridian and aureolin, and metal powder pigments such as aluminum powder and brass powder are used. There are drawbacks that make it unusable.
即ち、この絵具は保存中に於て常に顔料が水分
と接触しているため化学変化をおこし、変色や固
化しやすい。特に金属顔料を使用した場合は錆を
生じる欠点を有するからである。 That is, since the pigments of this paint are constantly in contact with moisture during storage, they undergo chemical changes and are prone to discoloration and solidification. This is because, in particular, when metal pigments are used, they have the disadvantage of causing rust.
本発明はこれら欠点を解消するものである。本
発明で用いる顔料は、従来より絵具に用いられて
いる弁柄、酸化チタン等無機顔料、ハンザエロー
10G、カーミン6B等有機顔料、アルミ粉、真鋳
粉等の金属粉顔料、その他パール顔料等の各種顔
料を使用できる。これら顔料は単独或は混合して
組成物100部に対して３〜80重量部が、好ましく
は５〜75重量部（以下重量部を単に部と称する）
が使用できる。 The present invention eliminates these drawbacks. The pigments used in the present invention include inorganic pigments such as Bengara and titanium oxide, which have been conventionally used in paints, and Hansa Yellow.
Various pigments such as organic pigments such as 10G and Carmine 6B, metal powder pigments such as aluminum powder and brass powder, and other pearl pigments can be used. These pigments may be used alone or as a mixture in an amount of 3 to 80 parts by weight, preferably 5 to 75 parts by weight (hereinafter, parts by weight are simply referred to as parts) based on 100 parts of the composition.
can be used.
顔料は過少になると絵具の発色が不良となり、
過剰になると画用紙等塗面に対する顔料の定着性
が不良となる。 If there is too little pigment, the color development of the paint will be poor,
If it is in excess, the fixability of the pigment to the painted surface such as drawing paper will be poor.
また本発明で用いる顔料として組成物を水でう
すめた時の粘稠性の調整や塗布した時の被覆力の
調整の為に、従来より絵具に用いられている炭酸
カルシウムや無水ケイ酸或はアルミナシリケート
等の体質顔料を使用できる。 In addition, in order to adjust the viscosity when the composition is diluted with water and the covering power when applied, calcium carbonate, silicic acid anhydride, or Extender pigments such as alumina silicate can be used.
体質顔料は組成物100部に対して０〜90部が、
好ましくは０〜60部が使用できるが過剰になると
絵具の発色が不良となる。 The extender pigment is present in an amount of 0 to 90 parts per 100 parts of the composition.
Preferably, 0 to 60 parts can be used, but if it is in excess, the color development of the paint will be poor.
本発明で用いる粉末状樹脂エマルジヨンは、塗
面への顔料の定着性を付与すると共に塗膜に耐水
性を付与する為に用いるものである。 The powdered resin emulsion used in the present invention is used to impart fixability of the pigment to the coating surface and to impart water resistance to the coating film.
粉末状樹脂エマルジヨンとは、単に粉末エマル
ジヨン、エマルジヨンパウダー或は再乳化粉末等
と俗称されているもので、例えば酢酸ビニル等の
樹脂エマルジヨンを熱風や減圧中へ噴霧分散して
急速乾燥し、通常５〜100μ程度の粒子径を有す
る粉末状としたものである。そして、この粉末は
水に対して容易に再分散することができ、再分散
液が乾燥した時の塗膜は耐水性を有し水に対して
再分散しない特徴を有する。 Powdered resin emulsion is simply called powder emulsion, emulsion powder, re-emulsified powder, etc. For example, a resin emulsion such as vinyl acetate is sprayed and dispersed in hot air or under reduced pressure and then quickly dried. It is in the form of a powder having a particle size of about 5 to 100 microns. This powder can be easily redispersed in water, and when the redispersion liquid dries, the coating film is water resistant and has the characteristic of not being redispersed in water.
これら粉末状樹脂エマルジヨンとしては酢酸ビ
ニル樹脂エマルジヨン、酢酸ビニル・ビニルバー
サテート共重合樹脂エマルジヨン、酢酸ビニル・
アクリル酸エステル共重合樹脂エマルジヨン、エ
チレン・酢酸ビニル共重合樹脂エマルジヨン等が
例示できる。 These powdered resin emulsions include vinyl acetate resin emulsion, vinyl acetate/vinyl versatate copolymer resin emulsion, and vinyl acetate/vinyl versatate copolymer resin emulsion.
Examples include acrylic ester copolymer resin emulsion and ethylene/vinyl acetate copolymer resin emulsion.
更に具体的には市販されているものとしてヘキ
スト合成(株)製の商品名モビニールパウダー
DM200（酢酸ビニル・ビニルバーサテート共重合
粉末状樹脂エマルジヨン）、モビニールパウダー
Ｍ−１（酢酸ビニル粉末状樹脂エマルジヨン）等
が例示できる。 More specifically, a commercially available product is Movinyl Powder manufactured by Hoechst Synthetic Co., Ltd.
Examples include DM200 (vinyl acetate/vinyl versatate copolymer powder resin emulsion) and Movinyl Powder M-1 (vinyl acetate powder resin emulsion).
これらエマルジヨンは組成物100部に対して10
〜70部が、好ましくは20〜60部が使用できる。エ
マルジヨンは過剰になると絵具の発色は不良とな
り過少になると塗膜の耐水性と顔料の定着性が不
良となる。 These emulsions contain 10 parts per 100 parts of the composition.
~70 parts can be used, preferably 20 to 60 parts. If the amount of emulsion is too much, the color development of the paint will be poor, and if it is too little, the water resistance of the paint film and the fixability of the pigment will be poor.
本発明で用いる水溶性樹脂は塗面への顔料の定
着性を付与すると共に組成物を水でうすめた時の
粘稠性を付与する為に用いるものであるが、従来
より水彩絵具に用いられているメチルセルロー
ス、カルボキシメチルセルロース、ヒドロキシエ
チルセルロース、ヒドロキシプロピルセルロース
等のセルロース系樹脂、ポリビニルアルコール、
ポリビニルピロリドン等ビニル系合成樹脂、デキ
ストリン、酵素デキストリン等加工澱粉、アラビ
アゴム等天然高分子など各種の水溶性高分子を使
用できる。これらのうちメチルセルロース、カル
ボキシメチルセルロース、ヒドロキシプロピルセ
ルロース、ポリビニルピロリドン、デキストリ
ン、酵素デキストリン等が好ましく使用できる。
これら水溶性高分子は組成物100部に対して0.5〜
25部が、好ましくは１〜20部が使用できる。水溶
性高分子は過少になると水でうすめた時の絵具の
粘性がなくなり、過剰になると塗膜の耐水性が不
良となる。 The water-soluble resin used in the present invention is used to provide pigment fixability to the painted surface and to provide viscosity when the composition is diluted with water. Cellulose resins such as methylcellulose, carboxymethylcellulose, hydroxyethylcellulose, and hydroxypropylcellulose, polyvinyl alcohol,
Various water-soluble polymers can be used, such as vinyl-based synthetic resins such as polyvinylpyrrolidone, modified starches such as dextrin and enzyme dextrin, and natural polymers such as gum arabic. Among these, methylcellulose, carboxymethylcellulose, hydroxypropylcellulose, polyvinylpyrrolidone, dextrin, enzyme dextrin, etc. can be preferably used.
These water-soluble polymers are 0.5 to 100 parts of the composition.
25 parts can be used, preferably 1 to 20 parts. If the amount of water-soluble polymer is too low, the paint will lose its viscosity when diluted with water, and if it is in excess, the water resistance of the paint film will be poor.
その他本発明に於ては必要により組成物を水で
うすめるとき顔料の水ぬれと分散性を良くする為
に従来より絵具に用いられているポリエチレング
リコールアルキルエーテル、ソルビタンエステル
エーテル等ノニオン系、或はナフタレンスルホン
酸ソーダホルマリン縮合物、アルキルベンゼンス
ルホン酸等アニオン系の界面活性剤を使用できる
がこのうちHLBが８〜18のものが望ましい。界
面活性剤は組成物100部に対して０〜2.0部が、好
ましくは0.2〜1.5部が使用できる。活性剤は過剰
になると塗膜の耐水性が不良となり塗面への浸透
が速くなる。 In addition, in the present invention, when diluting the composition with water if necessary, in order to improve the water wettability and dispersibility of the pigment, nonionic materials such as polyethylene glycol alkyl ether, sorbitan ester ether, etc., which have been conventionally used in paints, or Anionic surfactants such as naphthalene sulfonic acid soda formalin condensate and alkylbenzenesulfonic acid can be used, but among these, those having an HLB of 8 to 18 are preferable. The surfactant can be used in an amount of 0 to 2.0 parts, preferably 0.2 to 1.5 parts, based on 100 parts of the composition. If the activator is used in excess, the water resistance of the coating film will be poor and its penetration into the coating surface will be rapid.
また、必要によりデハイドロ酢酸ソーダ、ビス
−トリ−ｎ−ブチル−スズオキサイド等防腐剤、
金属顔料を用いる場合にはベンゾトリアゾール等
の防錆剤を混合添加する。さらにエチレングリコ
ール等多価アルコール類を本発明の組成物に噴霧
することにより添加することができる。 In addition, if necessary, preservatives such as sodium dehydroacetate and bis-tri-n-butyl-tin oxide,
When using a metal pigment, a rust preventive agent such as benzotriazole is mixed and added. Furthermore, polyhydric alcohols such as ethylene glycol can be added by spraying onto the composition of the present invention.
本発明の組成物を製造するには種々の方法があ
るが例えばまず、顔料および必要に応じて体質顔
料を所定量秤量し、ミキサー、ニーダー等の混合
機で均一に混合する。 There are various methods for producing the composition of the present invention, but for example, first, a predetermined amount of the pigment and, if necessary, an extender pigment are weighed and mixed uniformly using a mixing machine such as a mixer or a kneader.
次いで、アルコールに加熱溶解或は分散した界
面活性剤の溶液を添加して充分に混合しその後粉
末状樹脂エマルジヨンと水溶性樹脂を所定量加え
て再度混合する。得られた混合物を粉砕機等で50
〜150メツシユ程度に粉砕して粉絵具とする。或
は造粒機にて造粒し顆粒絵具とした本発明の粉末
状絵具組成物を得る。 Next, a solution of a surfactant dissolved or dispersed by heating in alcohol is added and thoroughly mixed, and then a predetermined amount of a powdered resin emulsion and a water-soluble resin are added and mixed again. The resulting mixture is crushed in a crusher etc. for 50 min.
Grind it to about 150 mesh pieces and use it as powder paint. Alternatively, the powdered paint composition of the present invention is granulated using a granulator to obtain a granular paint.
本発明で得た組成物はビン等の密閉容器に入れ
保存しておけば保存中に於て水と接触することが
ないので化学変化により変色、固化或は錆を生じ
る恐れはなく各種顔料を使用することができると
共に本発明の組成物を水でうすめて塗布した塗膜
は乾燥後強力な耐水性を発揮するので屋外に掲示
されるポスター用絵具としても使用できる。又そ
の塗膜も保存中と同様変色、固化或は錆を生ずる
ことがない。 If the composition obtained according to the present invention is stored in an airtight container such as a bottle, it will not come into contact with water during storage, so there is no risk of discoloration, solidification, or rust due to chemical changes, and it can be used with various pigments. The composition of the present invention can also be used as paint for posters displayed outdoors, since a coating film obtained by diluting the composition of the present invention with water exhibits strong water resistance after drying. Also, the coating film will not change color, solidify or rust as during storage.
特に本発明は従来不可能であつた金色、銀色な
どの金属粉顔料を含有する絵具に耐水性を付与で
きた点に意義がある。 In particular, the present invention is significant in that it is possible to impart water resistance to paints containing metal powder pigments such as gold and silver, which was previously impossible.
以下、実施例に従い本発明を詳説する。 Hereinafter, the present invention will be explained in detail according to Examples.
実施例 １
弁柄〔三重顔料(株)製〕 32.0部
炭酸カルシウム 20.0部
アルミナシリケート 10部
モビニールパウダーDM200 30部
〔商品名ヘキスト合成(株)製 酢酸ビニル・ビニル
バーサテート共重合粉末状樹脂エマルジヨン〕
パインデツクス＃１〔松谷化学(株)製酵素デキスト
リン〕 7.8部
ラベリン〔商品名第一工業製薬(株)製ナフタレンス
ルホン酸ソーダ〕 0.2部
上記を混合機に投入して充分混合した後、得ら
れた混合物を粉砕機で粉砕し、次いでその粉砕物
を造粒機に投入して100メツシユ造粒し茶色を呈
する本発明の組成物を得た。得られた組成物を密
閉容器に収納して室温40度、湿度80％恒温恒湿槽
中に１週間放置後、確認したところ変色や固化な
どの現象はなく良好な保存性を示した。得られた
組成物を筆に含ませた水でうすめ、画用紙に塗布
した。次いで塗布した塗膜を室内に放置して自然
乾燥した後、水に浸漬したが、塗膜は再分散する
ことなく良好な耐水性を示した。Example 1 Bengara [manufactured by Mie Pigment Co., Ltd.] 32.0 parts Calcium carbonate 20.0 parts Alumina silicate 10 parts Movinyl powder DM200 30 parts [Product name: Hoechst Gosei Co., Ltd. Vinyl acetate/vinyl versatate copolymer powder resin emulsion] ] Pinedex #1 [enzyme dextrin manufactured by Matsutani Chemical Co., Ltd.] 7.8 parts Labelin [trade name sodium naphthalene sulfonate manufactured by Daiichi Kogyo Seiyaku Co., Ltd.] 0.2 parts After putting the above into a mixer and mixing thoroughly, the obtained The resulting mixture was pulverized using a pulverizer, and then the pulverized product was put into a granulator and granulated into 100 meshes to obtain a brown colored composition of the present invention. The obtained composition was stored in a sealed container and left in a constant temperature and humidity chamber at a room temperature of 40 degrees Celsius and a humidity of 80% for one week. When the composition was checked, there was no phenomenon such as discoloration or solidification, indicating good storage stability. The resulting composition was diluted with water in a brush and applied to drawing paper. Next, the applied coating film was left indoors to air dry, and then immersed in water, but the coating showed good water resistance without being redispersed.
実施例 ２
ハンザエロー10G〔Ｃ・Ｉピグメントエロー３ヘ
キスト合成(株)製〕 8.0部
炭酸カルシウム 26.0部
モビニールパウダーＭ−１〔商品名、ヘキスト合
成(株)製酢酸ビニル粉末状樹脂エマルジヨン〕
50.0部
ルビスコールＫ−90〔商品名、BASF社製ポリビ
ニルピロリドン〕 10.0部
HPC−Ｌ〔商品名、日本曹造(株)製ヒドロキシプロ
ピルセルロース〕 5.0部
ノニポール160〔商品名、三洋化成(株)製、ポリエチ
レングリコール、ノニルフエニルエーテル、
HLB15.2〕 1.0部
実施例 ３
ビリジヤン〔Ｃ・Ｉピグメントグリーン18東洋顔
料(株)製〕 70.0部
無水ケイ酸 1.0部
モビニールパウダーＭ−１ 22.0部
HPC−Ｌ 5.0部
ノニポール400〔商品名、三洋化成(株)製、ポリエチ
レングリコールノニルフエニルエーテル、
HLB17.8〕 1.0部
実施例 ４
オーレオリン〔Ｃ・Ｉピグメントエロー40〕
62.0部
アルミナシリケート 5.0部
モビニールパウダーDM200 30.0部
セロゲン6A〔商品名、第一工業製薬(株)製、カルボ
キシメチルセルロース〕 2.5部
実施例 ５
ギンプンAA−12〔Ｃ・Ｉピグメントメタル、福
田金属(株)製〕 40.0部
モビニールパウダーDM200 50.0部
HPC−Ｌ 4.5部
ノイゲンEA141〔商品名、第一工業製薬(株)製、ポ
リエチレングリコールアルキルアリルエーテル、
HLB14.0〕 1.5部
実施例２〜５の組成物も実施例１に準じて製造
した。得られた組成物は第１の実施例同様にいず
れも変色や固化することなく良好な保存性を示し
た。又その塗膜も乾燥後は良好な耐水性を示し
た。Example 2 Hansa Yellow 10G [C.I Pigment Yellow 3 manufactured by Hoechst Synthesis Co., Ltd.] 8.0 parts Calcium carbonate 26.0 parts Movinyl Powder M-1 [trade name, vinyl acetate powder resin emulsion manufactured by Hoechst Synthesis Co., Ltd.]
50.0 parts Rubiscoll K-90 [Product name, Polyvinylpyrrolidone manufactured by BASF] 10.0 parts HPC-L [Product name, Hydroxypropylcellulose manufactured by Nippon Sozo Co., Ltd.] 5.0 parts Nonipol 160 [Product name, Sanyo Kasei Co., Ltd.] made of polyethylene glycol, nonyl phenyl ether,
HLB15.2] 1.0 parts Example 3 Viridian [C.I. Pigment Green 18 manufactured by Toyo Pigment Co., Ltd.] 70.0 parts Silicic anhydride 1.0 parts Movinyl Powder M-1 22.0 parts HPC-L 5.0 parts Nonipole 400 [Product name, Manufactured by Sanyo Chemical Co., Ltd., polyethylene glycol nonyl phenyl ether,
HLB17.8〕 1.0 part Example 4 Aureolin [C.I Pigment Yellow 40]
62.0 parts Alumina silicate 5.0 parts Movinyl powder DM200 30.0 parts Celogen 6A [Product name, manufactured by Daiichi Kogyo Seiyaku Co., Ltd., carboxymethyl cellulose] 2.5 parts Example 5 Gimpun AA-12 [C・I Pigment Metal, Fukuda Metal Co., Ltd.] )] 40.0 parts Movinyl Powder DM200 50.0 parts HPC-L 4.5 parts Neugen EA141 [Product name, manufactured by Daiichi Kogyo Seiyaku Co., Ltd., polyethylene glycol alkyl allyl ether,
HLB14.0] 1.5 parts The compositions of Examples 2 to 5 were also produced according to Example 1. Like the first example, the obtained compositions exhibited good storage stability without discoloration or solidification. The coating film also showed good water resistance after drying.
Claims (1)
高分子を含有することを特徴とする粉末状絵具組
成物。1. A powdery paint composition characterized by containing a pigment, a powdery resin emulsion, and a water-soluble polymer.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP13980183A JPS6032861A (en) | 1983-07-30 | 1983-07-30 | Powdery pigment composition |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP13980183A JPS6032861A (en) | 1983-07-30 | 1983-07-30 | Powdery pigment composition |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS6032861A JPS6032861A (en) | 1985-02-20 |
| JPH0559150B2 true JPH0559150B2 (en) | 1993-08-30 |
Family
ID=15253746
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP13980183A Granted JPS6032861A (en) | 1983-07-30 | 1983-07-30 | Powdery pigment composition |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS6032861A (en) |
Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103571288A (en) * | 2013-10-25 | 2014-02-12 | 安徽工贸职业技术学院 | Color powder coating |
| CN103571286A (en) * | 2013-10-25 | 2014-02-12 | 安徽工贸职业技术学院 | Preparation method of color powder coating |
| JP2015089930A (en) * | 2013-11-07 | 2015-05-11 | 株式会社サクラクレパス | Finger pigment |
-
1983
- 1983-07-30 JP JP13980183A patent/JPS6032861A/en active Granted
Also Published As
| Publication number | Publication date |
|---|---|
| JPS6032861A (en) | 1985-02-20 |
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