JPH0574197B2 - - Google Patents
Info
- Publication number
- JPH0574197B2 JPH0574197B2 JP62037362A JP3736287A JPH0574197B2 JP H0574197 B2 JPH0574197 B2 JP H0574197B2 JP 62037362 A JP62037362 A JP 62037362A JP 3736287 A JP3736287 A JP 3736287A JP H0574197 B2 JPH0574197 B2 JP H0574197B2
- Authority
- JP
- Japan
- Prior art keywords
- charging
- battery
- voltage
- internal resistance
- reverse
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/42—Methods or arrangements for servicing or maintenance of secondary cells or secondary half-cells
- H01M10/44—Methods for charging or discharging
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/10—Energy storage using batteries
Landscapes
- Engineering & Computer Science (AREA)
- Manufacturing & Machinery (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Secondary Cells (AREA)
Description
産業上の利用分野
本発明は密閉形鉛蓄電池の充電方法の改良に関
するものである。
従来の技術
従来密閉形鉛蓄電池用充電器の問題点として、
過放電後放置された電池(以下「過放電放置電
池」という)に対する充電性がある。これは、過
放電放置電池の内部抵抗が高いため、充電電流が
流れにくい事によるものである。特に陰極吸収式
の密閉形鉛蓄電池では、充電末期電圧を検出後微
小電流による充電(以下「トリクル充電」とい
う)に入る方式が多く用いられている。
この方式の充電器で過放電放置電池を充電した
場合、過放電放置電池の内部抵抗が高いため充電
開始直後に充電電圧が上昇してトリクル充電に入
り、ほとんど充電されないという欠点があつた。
この欠点を解消する方法の一つとして特願昭61−
16196号にある様に過放電放置電池に対して交流
電圧を印加するか又は逆充電し、その後に正規の
充電を施すことにより、回復させようとする方法
がある。
発明が解決しようとする問題点
上記の充電方法を実際の充電器に適用する場
合、正規の充電に切り替えるために、充電及び放
電方向に流れる電流が等量もしくはそれに近くな
つたことを判断する条件によつては回復しないと
いう問題点が存在する。
逆充電を切り替える条件として、最も簡単な方
法は交流電圧印加又は逆充電をする時間を一定と
する方法がある。しかし、この方式では、内部抵
抗が非常に高い過放電放置電池では回復性が悪
く、内部抵抗が比較的低い場合には、必要以上の
交流電圧印加又は逆充電により、充電時間の増
加、充電時の発熱増大、回復後の寿命特性の悪化
などの弊害などがある。この例を次に示す。
使用した電池は4V、4Vhの密閉形鉛電池であ
る。逆充電時間を60分とした場合の充電特性を第
4図及び第5図に示す。第4図は内部抵抗が約
300Ωの過放電電池の充電特性、第5図は内部抵
抗が約1600Ωの場合の充電特性である。
内部抵抗が約300Ωの場合は逆充電後に正常の
充電に入つているが、内部抵抗が約1600Ωと高い
場合には通常の充電に戻つた後早期にトリクル充
電に入り、充電されなかつた。第1表に内部抵抗
が約300Ωの過放電電池を用い、逆充電時間を変
えた場合の電池表面温度の最高値を示す。明らか
に、逆充電時間が長い程発熱も多くなつている。
INDUSTRIAL APPLICATION FIELD The present invention relates to an improvement in a charging method for a sealed lead-acid battery. Conventional technology Problems with conventional sealed lead-acid battery chargers include:
It has the ability to charge batteries that have been left unattended after being over-discharged (hereinafter referred to as "over-discharged batteries"). This is because the internal resistance of the overdischarged battery is high, making it difficult for charging current to flow. In particular, for cathode absorption type sealed lead-acid batteries, a method is often used in which charging is performed using a minute current (hereinafter referred to as "trickle charging") after detecting the voltage at the end of charging. When an over-discharged battery is charged with this type of charger, the internal resistance of the over-discharged battery is high, so the charging voltage rises immediately after charging starts and the battery enters trickle charging, resulting in almost no charge.
As one of the ways to overcome this drawback, the patent application
As described in No. 16196, there is a method of applying an AC voltage to an over-discharged battery or reverse charging it, and then performing regular charging to restore the battery. Problems to be Solved by the Invention When the above charging method is applied to an actual charger, the conditions for determining that the current flowing in the charging and discharging directions are equal or close to it in order to switch to regular charging There is a problem that in some cases, recovery may not be possible. As a condition for switching reverse charging, the simplest method is to apply an alternating current voltage or keep the reverse charging time constant. However, with this method, recovery performance is poor for over-discharged batteries with extremely high internal resistance, and when the internal resistance is relatively low, the charging time increases and charging There are adverse effects such as increased heat generation and deterioration of life characteristics after recovery. An example of this is shown below. The battery used was a 4V, 4Vh sealed lead-acid battery. Charging characteristics when the reverse charging time is 60 minutes are shown in FIGS. 4 and 5. Figure 4 shows that the internal resistance is approximately
Charging characteristics of a 300Ω over-discharged battery. Figure 5 shows the charging characteristics when the internal resistance is about 1600Ω. If the internal resistance is about 300Ω, normal charging will begin after reverse charging, but if the internal resistance is high, about 1600Ω, the battery will enter trickle charging early after returning to normal charging and will not be charged. Table 1 shows the maximum battery surface temperature when an overdischarged battery with an internal resistance of approximately 300Ω is used and the reverse charging time is varied. Obviously, the longer the reverse charging time is, the more heat is generated.
【表】
第6図に逆充電時間が60分で回復した過放電放
置電池の回復後のサイクル寿命特性を示す。内部
抵抗が約10Ωの過放電放置電池Aでは、必要以上
の逆充電がなされたことにより、内部抵抗が約
300Ωを過放電放置電池Bに比べて容量低下が早
く、約150サイクルで寿命となつている。
これらのことより、逆充電を行なつて回復させ
る場合、過放電放置電池の内部抵抗に応じて逆充
電を行なう方式が好ましいと考えられる。
問題点を解決するための手段
本発明は上記の如き点に鑑み、過放電放置電池
の場合には、その内部抵抗に応じて逆充電を行な
うもので、充電電圧に含まれる交流電圧成分は内
部抵抗が高くなる程多くなると考えられることに
着目し、過放電放置電池の充電時には、充電々圧
に含まれる交流電圧成分が一定値以下になるまで
一定時間の逆充電を繰り返えした後通常の充電に
復帰させることを特徴とするものである。
作 用
過放電放置電池の内部抵抗に応じて逆充電を行
なう事が可能となる。
これは、過放電放置電池の内部抵抗が高い場合
には充電電圧に含まれる交流電圧成分(常に正の
値)が大きくなる事を応用するもので、一度の逆
充電で回復しない場合には充電電圧に含まれる交
流電圧成分が一定値以下になるまで繰り返して逆
充電を行なう事により、内部抵抗に応じて逆充電
を行なうものである。
実施例
第1図は本発明に使用する充電器の構成図であ
る。通常の充電時には、充電末期電圧を検出後ト
リクル充電に入るもので、電圧検出部1により充
電末期電圧を検出すると制御部2が動作し、電流
制御部3を制御して抵抗4によるトリクル充電に
入る。
過放電放置電池の充電の場合、密閉形鉛蓄電池
5に発生した交流電圧成分はコンデンサ6を通り
抵抗7に印加される。この交流電圧は交流電圧検
出部8の入力となり、一定値以上の場合にはタイ
マ9を動作させる。該タイマ9は、一定時間リレ
ーのコイル10に電流を流しリレーの接点11を
切り換えると共に制御部2を動作させ逆充電電流
を流す。この様な動作で、充電電圧に含まれる交
流成分が一定値以下になるまで逆充電を繰り返
し、通常の充電に入る事が可能である。
4V、4Ahの密閉形鉛電池を用いた場合の充電
特性を第2図と第3図に示す。充電末期検出電圧
は4.9V、タイマの設定軸関は15(min)交流成分
検出電圧は1.0Vp-pである。第2図は内部抵抗が
約1600Ωの場合の充電特性で6回逆充電を繰り返
した後通常充電に入つている。第3図は内部抵抗
が約50Ωの場合の充電特性で、1度の逆充電後に
通常の充電に入つている。
このように、内部抵抗の高いものから低いもの
まで内部抵抗に応じて逆充電を繰り返し充電可能
であつた。
なお12はダイオード、13は変圧整流部であ
る。
発明の効果
上述のように本発明によれば、内部抵抗が応じ
て逆充電を行なうことができるので、通常の電池
や過放電放置電池にこだわりなく充電すること容
易となる等工業的価値甚だ大なるものである。[Table] Figure 6 shows the cycle life characteristics of an over-discharged battery that recovered after 60 minutes of reverse charging. Over-discharged battery A, which has an internal resistance of about 10Ω, has been reverse-charged more than necessary, so the internal resistance has decreased to about 10Ω.
Compared to battery B, which was left over-discharged at 300Ω, the capacity decreased faster, and its life span was approximately 150 cycles. From these facts, when performing reverse charging to recover, it is considered preferable to perform reverse charging according to the internal resistance of the overdischarged battery. Means for Solving the Problems In view of the above-mentioned problems, the present invention reversely charges an over-discharged battery according to its internal resistance, so that the AC voltage component included in the charging voltage is Focusing on the fact that the higher the resistance, the higher the resistance, when charging a battery that has been left over-discharged, reverse charging is repeated for a certain period of time until the AC voltage component included in the charging voltage drops below a certain value. The feature is that the battery can be returned to charging. Function: It is possible to perform reverse charging according to the internal resistance of an over-discharged battery. This applies the fact that when the internal resistance of an over-discharged battery is high, the AC voltage component included in the charging voltage (always a positive value) becomes large. Reverse charging is performed in accordance with the internal resistance by repeatedly performing reverse charging until the AC voltage component included in the voltage falls below a certain value. Embodiment FIG. 1 is a block diagram of a charger used in the present invention. During normal charging, trickle charging starts after detecting the voltage at the end of charging. When the voltage detecting section 1 detects the voltage at the end of charging, the control section 2 operates and controls the current control section 3 to perform trickle charging using the resistor 4. enter. In the case of charging an over-discharged battery, the AC voltage component generated in the sealed lead-acid battery 5 is applied to the resistor 7 through the capacitor 6 . This alternating current voltage becomes an input to an alternating current voltage detecting section 8, and if it exceeds a certain value, a timer 9 is operated. The timer 9 causes a current to flow through the coil 10 of the relay for a certain period of time to switch the contacts 11 of the relay, and also operates the control section 2 to flow a reverse charging current. With such an operation, reverse charging is repeated until the AC component included in the charging voltage falls below a certain value, and normal charging can begin. Charging characteristics when using a 4V, 4Ah sealed lead acid battery are shown in Figures 2 and 3. The detection voltage at the end of charging is 4.9V, the timer setting axis is 15 (min), and the AC component detection voltage is 1.0V pp . Figure 2 shows the charging characteristics when the internal resistance is approximately 1600Ω, and normal charging is started after 6 times of reverse charging. Figure 3 shows the charging characteristics when the internal resistance is approximately 50Ω, and normal charging begins after one reverse charge. In this way, reverse charging could be repeated depending on the internal resistance from high to low internal resistance. Note that 12 is a diode, and 13 is a transformer rectifier. Effects of the Invention As described above, according to the present invention, reverse charging can be performed depending on the internal resistance, so it has great industrial value, such as making it easy to charge a normal battery or a battery that has been left over-discharged. It is what it is.
第1図は本発明に使用する充電器の一実施例を
示す構成図、第2図および第3図は第1図におけ
る充電器を用いた場合の充電特性を示す特性曲線
図、第4図および第5図は逆充電時間を一定とし
た場合の充電特性を示す特性曲線図、第6図は逆
充電回復後のサイクル寿命特性を示す特性曲線図
である。
1は電圧検出部、3は電流制御部、5は密閉形
鉛蓄電池、8は交流電圧検出部。
FIG. 1 is a configuration diagram showing one embodiment of the charger used in the present invention, FIGS. 2 and 3 are characteristic curve diagrams showing charging characteristics when the charger in FIG. 1 is used, and FIG. 4 5 is a characteristic curve diagram showing charging characteristics when reverse charging time is constant, and FIG. 6 is a characteristic curve diagram showing cycle life characteristics after reverse charging recovery. 1 is a voltage detection section, 3 is a current control section, 5 is a sealed lead acid battery, and 8 is an AC voltage detection section.
Claims (1)
交流電圧成分が一定値を超える場合には、通常と
は逆方向の電流を一定時間流す動作を、前記交流
電圧成分が前記一定値以下になるまで繰り返した
後、通常の充電に復帰させることを特徴とする密
閉形鉛蓄電池の充電方法。1. At the start of normal charging, if the AC voltage component included in the charging voltage exceeds a certain value, an operation is performed to flow a current in the opposite direction to the normal one for a certain period of time until the AC voltage component becomes below the certain value. A method for charging a sealed lead-acid battery, which is characterized by returning to normal charging after repeating up to 30 seconds.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP62037362A JPS63205064A (en) | 1987-02-20 | 1987-02-20 | Charging method for sealed lead-acid battery |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP62037362A JPS63205064A (en) | 1987-02-20 | 1987-02-20 | Charging method for sealed lead-acid battery |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS63205064A JPS63205064A (en) | 1988-08-24 |
| JPH0574197B2 true JPH0574197B2 (en) | 1993-10-15 |
Family
ID=12495428
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP62037362A Granted JPS63205064A (en) | 1987-02-20 | 1987-02-20 | Charging method for sealed lead-acid battery |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS63205064A (en) |
Family Cites Families (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS55111079A (en) * | 1979-02-20 | 1980-08-27 | Matsushita Electric Ind Co Ltd | Capacity recovery method in lead acid battery |
-
1987
- 1987-02-20 JP JP62037362A patent/JPS63205064A/en active Granted
Also Published As
| Publication number | Publication date |
|---|---|
| JPS63205064A (en) | 1988-08-24 |
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