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JPH0583226B2 - - Google Patents
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JPH0583226B2 - - Google Patents

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Publication number
JPH0583226B2
JPH0583226B2 JP62303596A JP30359687A JPH0583226B2 JP H0583226 B2 JPH0583226 B2 JP H0583226B2 JP 62303596 A JP62303596 A JP 62303596A JP 30359687 A JP30359687 A JP 30359687A JP H0583226 B2 JPH0583226 B2 JP H0583226B2
Authority
JP
Japan
Prior art keywords
aqueous phase
oils
fats
cyclodextrin
oil
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
JP62303596A
Other languages
Japanese (ja)
Other versions
JPH01144930A (en
Inventor
Takehiko Oofuji
Koichi Ogata
Itsutomo Yamamoto
Takayo Yasuda
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Kanegafuchi Chemical Industry Co Ltd
Original Assignee
Kanegafuchi Chemical Industry Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Kanegafuchi Chemical Industry Co Ltd filed Critical Kanegafuchi Chemical Industry Co Ltd
Priority to JP62303596A priority Critical patent/JPH01144930A/en
Publication of JPH01144930A publication Critical patent/JPH01144930A/en
Publication of JPH0583226B2 publication Critical patent/JPH0583226B2/ja
Granted legal-status Critical Current

Links

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01FMIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
    • B01F25/00Flow mixers; Mixers for falling materials, e.g. solid particles
    • B01F25/20Jet mixers, i.e. mixers using high-speed fluid streams
    • B01F25/23Mixing by intersecting jets
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01FMIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
    • B01F2101/00Mixing characterised by the nature of the mixed materials or by the application field
    • B01F2101/06Mixing of food ingredients
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01FMIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
    • B01F23/00Mixing according to the phases to be mixed, e.g. dispersing or emulsifying
    • B01F23/40Mixing liquids with liquids; Emulsifying
    • B01F23/41Emulsifying

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Edible Oils And Fats (AREA)
  • Seasonings (AREA)

Description

【発明の詳細な説明】[Detailed description of the invention]

「産業上の利用分野」 本発明は、サイクロデキストリン、油脂及び水
を主成分とする水中油型乳化油脂食品を連続的に
製造する方法に関するものである。 「従来技術と問題点」 水中油型の乳化油脂を製造するには、一般に乳
化剤(界面活性剤)が用いられ、その製造装置が
種々開発されている。 例えば、市販の製造方法の一例をあげると、熱
交換で50〜60℃に予熱した後、殺菌前にゴーリン
式などホモジナイザーで140〜210Kg/cm2に加圧し
つつ均質化を行つた後、加熱殺菌して充填して製
品とする。 又、同じく水中油型の乳化油脂であるマヨネー
ズは、原料の卵黄中に含まれるリポタンパク等の
乳化機能を利用して製造され、その製造工程は卵
黄、調味量、香辛料、ビネガーをプレミツクス装
置内で先に均一に混合し、次いでサラダ油を添加
して撹拌し、これをコロイドミルで送つて仕上げ
撹拌され、充填後製品とされる。上記のプレミツ
クス装置として、ホモミキサー、アジホモミキサ
ー(特殊機化工業(株))等が開発されている。これ
らはいずれもバツチ式である。 一方、連続式としてホモミツクラインフロー
(特殊機化工業(株))等が開発検討されている。尚、
上記の市販マヨネーズは原料中に含まれている天
然の物質(例えば乳タンパクやレシチン等)の乳
化機能を活かして作られている。 その他に、イミテーシヨンクリーム等は食品添
加物の乳化剤等を添加して同様の工程・装置で製
造される。 本発明者らは、サイクロデキストリン、油脂及
び水相を主成分とする水中油型乳化油脂を連続的
に製造する方法を、前述の装置等を用いて種々検
討した。 先ず、市乳等の製造に用いられている連続式の
ホモジナイザーを用いて製造することを検討した
が、処理圧、処理液温度等をいかに工夫しても部
分的に乳化してない部分がある等の不十分な点が
多く、良好な乳化を得るに到らなかつた。又、ホ
モミツクラインフローを用いても検討したが、処
理液の流動が不均一に起こり(所謂シヨートパ
ス)乳化が不十分であつた。 「問題点を解決するための手段」 本発明者らは、かかる実情に鑑み、上記問題点
を解決すべく鋭意研究した結果、サイクロデキス
トリン、油脂、水を主成分とする水中油型乳化油
脂を連続的に乳化する方法を見出し、本発明を完
成した。 即ち、本発明は油脂類、水相及びサイクロデキ
ストリンを主成分とする混合液を、10〜800Kg/
cm2の圧力で相対する2方向より混合室内に噴出導
入して該混合液を衝突させるとともに、該混合液
を該混合室内に設けた凹窩部に導いてその壁面に
衝突させて乱噴流を生ぜしめた後、該混合液を低
圧領域に噴出させることにより、乱噴流相互を利
用して連続的に乳化することを特徴とする水中油
型乳化油脂食品の製造方法を内容とするものであ
る。 本発明に使用される油脂類は、乳製品、バタ
ー、調整油脂、植物油、動物油等の天然又は加工
油脂、上記の天然又は加工油脂に分別・水素添
加・エステル交換等の単独又は組み合わして加工
処理を施した油脂加工品から1種又は2種以上が
選択される。 本発明に使用される水相は特に制限されない
が、酢、果汁、牛乳、乳製品、卵の黄身、卵の白
身等が水以外に使用される。 又、上白糖やグラニユー糖等のシヨ糖類;麦芽
糖、ブドウ糖等の澱粉糖類;粉末水あめやハイマ
ルトース等の水あめ類;異性化液糖類、蜂蜜類、
マンニトール、ソルビトール等の糖アルコール等
に代表される糖類や、食塩、有機酸類、塩類、ガ
ム類、微結晶セルロース等の乳化安定剤;各種乳
化剤;香料等が上記水相や油脂類に添加して用い
られる。 本発明に使用されるサイクロデキストリンとし
ては、澱粉に、バチルス(Bacillus)属、又はミ
クロコツカス(Micrococcus)属等の細菌が生産
したアミラーゼを作用させて生成したものを使用
する。サイクロデキストリンはα、β、γサイク
ロデキストリン、分岐サイクロデキストリン、修
飾サイクロデキストリン等を単独又は組み合わせ
て用いる。又、各サイクロデキストリンは必ずし
も高純度のものである必要はなく、デキストリ
ン、分岐デキストリン、糖類が残存しているもの
でもかまわない。尚、本発明においてはサイクロ
デキストリン使用量はサイクロデキストリン純品
(100%サイクロデキストリン)換算値で示すもの
で、デキストリン等の不純物残存品を使用する場
合は濃度を換算して使用する必要がある。 本発明の水中油型乳化油脂の製造方法におい
て、送液圧力は10〜800Kg/cm2であるが、更に好
ましくは水中油型乳化油脂中の油脂類、水相、サ
イクロデキストリンの比率及び水相の種類・濃度
によつて選択した方がより良い乳化が得られる。 即ち、油脂類と水相とサイクロデキストリンの
比率が1.28〜3.10:1.0:0.03〜0.15の範囲におい
ては、送液圧力は10〜450Kg/cm2である事が好ま
しい。送液圧力が450Kg/cm2を越えると、やや乳
化が悪くなる傾向にある。また、油脂類と水相と
サイクロデキストリンの比率が0.60〜1.20:1.0:
0.02〜0.13の範囲においては、送液圧力は10〜
800Kg/cm2である事が好ましい。尚、送液圧力50
Kg/cm2未満では得られる水中油型乳化油脂は粘度
が低いことが多く、クリーミング現象等の離水の
原因になり易い事から、送液圧力50Kg/cm2〜800
Kg/cm2である事がさらに好ましい。尚、800Kg/
cm2よりも大きい送液圧力でも乳化は良好である
が、粒径が大きくなる傾向にある。尚、本発明に
使用される水相は前述したように、酢、果汁、牛
乳、乳製品、卵等から選択され、更に糖類、食
塩、有機酢酸、塩類、ガム類、乳化安定剤、香料
等を添加することができるが、水相に酢及び/又
は果汁を使用し、その水相中の比率が25重量%以
上である場合には、送液圧力を前述の範囲とやや
違えた方が好ましい。 即ち、水相に酢及び/又は果汁を含み、その水
相中の比率が25重量%以上である場合には、油脂
と水相とサイクロデキストリンの比率が1.58〜
3.10:1.0:0.03〜0.15(重量比)の範囲において
は、送液圧力は10〜150Kg/cm2である事が好まし
い。送液圧力が150Kg/cm2を越えると、乳化がや
や悪くなる傾向にある。 同じく、水相に酢及び/又は果汁を含み、その
水相中の比率が25重量%以上である場合におい
て、油脂と水相とサイクロデキストリンの比率が
1.20〜1.50:1.0:0.03〜0.15(重量比)の範囲にお
いては、送液圧力は10〜400Kg/cm2である事が好
ましい。送液圧力が400Kg/cm2を越えると、乳化
がやや悪くなる傾向にある。 同じく、水相に酢及び/又は果汁を含み、その
水相中の比率が25重量%以上である場合におい
て、油脂と水相とサイクロデキストリンの比率が
0.60〜1.15:1.0:0.03〜0.13(重量比)の範囲にあ
る場合は、送液圧力は10〜800Kg/cm2である事が
好ましい。尚、送液圧力50Kg/cm2未満では得られ
る水中油型乳化油脂は粘度が低い事が多く、クリ
ーミング現象等の離水の原因になり易い事から、
送液圧力は50〜800Kg/cm2である事が更に好まし
い。尚、800Kg/cm2より大きい送液圧力でも乳化
は良好であるが、粒径が大きくなる傾向にある。 本発明においては、サイクロデキストリンは水
相1に対し0.02〜0.15(重量比)使用するが、0.02
未満比率では乳化が不安定となり好ましくない。
尚、0.15を越える比率でも乳化は良好であるが、
価格的に高くつき、0.15以下の比率で十分であ
る。又、本発明における油脂類の比率は水相1に
対し3.18未満である事が好ましい。油脂類の比率
が3.18以上になると乳化が不安定となる傾向があ
る。尚、本発明における油脂類の比率の下限は特
に制限されない。尚、上記の送液圧力は後述第3
表に示した処理流量を有する規模のテスト機にお
ける乳化条件であり、装置スケール等により影響
を受けるものと考えられる。 本発明においては、油脂類、水相及びサイクロ
デキストリンを主成分とする混合液を、上記した
10〜800Kg/cm2の圧力で相対する2方向より混合
室内に噴出導入して該混合液を衝突させるととも
に、該混合液を該混合室内に設けた凹窩部に導い
てその壁面に衝突させて乱噴流を生ぜしめた後、
該混合液を低圧領域に噴出させることにより、乱
噴流相互作用を利用して連続的に乳化する。 本発明方法を実施するための具体的装置として
は、例えば米国特許第4533254号に記載された装
置を用いることができる。この装置の概要は第1
図に図示する如く、光学的に平滑な表面を有する
2つのチヤンネル1と2と両チヤンネルの間の平
滑面に介装され両チヤンネルと液もれがないよう
接触しているスペーサー3とからなり、且つ1方
のチヤンネル2には高圧液を供給する導入孔3に
接続され、他方のチヤンネル1は径を大きくした
排出孔4に接続され、又、前記スペーサー3は両
チヤンネル1及び2と相通ずる孔5を有してお
り、両チヤンネルとスペーサー孔との間に形成さ
れる相対するノズル6a,6bにより細長いオリ
フイスを形成している混合室7内に凹窩部8が設
けられている。油脂類、水相、サイクロデキスト
リンを主成分とする混合液は、定常流送液可能な
ポンプにより10〜800機/cm2の圧力で導入孔9に
導入され、チヤンネル2の2つの液入口2a,2
bより対向するようにノズル6a,6bを経て混
合室7に噴出導入され、衝突せしめられる。衝突
せしめられた乱噴射は凹窩部8内に衝突方向と略
垂直方向に導かれ、凹窩部の壁面に衝突して乱噴
射となり、チヤンネル1を経て、低圧領域である
排出孔4内に噴射され、乱噴流相互作用を生じさ
せ乍ら乳化される。混合液の混合室内への噴出導
入は均一な供給量で行う。 「作用・効果」 本発明により、油脂類、水相、サイクロデキス
トリンを主成分とする水中油型乳化油脂を連続的
に乳化することが可能となる。しかも、その乳化
状態は実施例のコールターカウンター測定結果に
示すように、平均粒径約5〜12ミクロンであり粒
径分布もシヤープであり、非常に良好である。前
述したように連続乳化機の一つであるホモジナイ
ザー(マントン−ゴーリン社)を用いて本発明の
サイクロデキストリン、油脂類、水相を主成分と
する水中油型乳化油脂を製造しようとしても、処
理圧、処理温度等をいかに工夫しても部分的に乳
化していない部分が残る等の不十分な点が多く、
良好な乳化を得るに到らない。又、ホモミツクラ
インフロー(特殊機化工業)を使用しても同じく
良好な乳化が得られない。このことは、サイクロ
デキストリンがその構造から推察できるように親
油基を有しておらず、一般の乳化剤が親水性基部
と親油基部をあわせ有しており界面活性剤である
のに反し、界面活性効果を有していない事に起因
していると考えられる。又、油脂とサイクロデキ
ストリンを包接化合物も同じく界面活性効果を有
していない。界面活性剤は、気/水、油/水、
固/液界面に顕著な吸着を起こす。即ち、水中油
型乳化油脂製造時に乳化剤は油/水界面に顕著な
吸着を示し、油/水界面を保護するのに反し、サ
イクロデキストリン及びその油脂と包接化合物は
油/水界面への配向が乳化剤とは異なる機構によ
るものと考えざるを得ない。 又、油脂類と水相とサイクロデキストリンを主
成分とする水中油型乳化油脂は、乳化前には各々
油脂類、又は水相の粘度を有し液状であるのに反
し、乳化途中でその油脂類の割合に応じて急激に
粘性が上昇する。 以上の事が、他のホモジナイザーや、ホモミツ
クラインフローといつた連続乳化機ではサイクロ
デキストリン、油脂類、水相を主成分とする水中
油型乳化油脂においては良好な乳化が得られない
原因となり、又、本発明においても油脂類と水相
の比率や、水相の種類に応じて送液圧力を選定し
なければならない原因の1つになつているものと
考えられる。 「実施例」 以下、本発明を実施例及び比較例にて説明する
が、本発明はこれらのみに限定されるものではな
い。 実施例 1 植物油73部(重量部、以下同じ)、水24部、β
−サイクロデキストリン2部を予備混合し、マイ
クロフルダイザー(M−110TC型)
(Microfluidics Corporation製)で送液圧力10
Kg/cm2、50Kg/cm2、100Kg/cm2、200Kg/cm2、400
Kg/cm2、500Kg/cm2でそれぞれ乳化した。この水
中油型乳化油脂の粒径をコールターカウンター
(TA−11型、日科機製)を用い、50ミクロン又
は280ミクロンのアパチヤー径のチユーブで測定
した。測定値はコンピユーター処理し、体積分布
による平均値を表中に示した。又、ビスコテスタ
ー(VT−04型、小林理化器械製)を用い粘度を
測定した。又、乳化状態を外観、1%水分散液の
顕微鏡観察より判断し、表中に示した。 実施例 2 植物油65部、水33部、β−サイクロデキストリ
ン2部を予備混合し送液圧力10Kg/cm2、50Kg/
cm2、100Kg/cm2、200Kg/cm2、400Kg/cm2、550Kg/
cm2で乳化した。他は実施例1と同様に行つた。 実施例 3 植物油60部、水38部、β−サイクロデキストリ
ン2部を予備混合し、送液圧力10Kg/cm2、50Kg/
cm2、100Kg/cm2、200Kg/cm2、400Kg/cm2、550Kg/
cm2で乳化した。他は実施例1と同様に行つた。 実施例 4 植物油55部、水43部、β−サイクロデキストリ
ン2部を予備混合し、送液圧力10Kg/cm2、50Kg/
cm2、100Kg/cm2、200Kg/cm2、400Kg/cm2、550Kg/
cm2で乳化した。他は実施例1と同様に行つた。 実施例 5 植物油50部、水48部、β−サイクロデキストリ
ン2部を予備混合し、送液圧力10Kg/cm2、30Kg/
cm2、50Kg/cm2、100Kg/cm2、200Kg/cm2、300Kg/
cm2、400Kg/cm2、600Kg/cm2で乳化した。他は実施
例1と同様に行つた。 実施例 6 植物油40部、水58部、β−サイクロデキストリ
ン2部を予備混合し、送液圧力10Kg/cm2、50Kg/
cm2、100Kg/cm2、200Kg/cm2、400Kg/cm2、600Kg/
cm2で乳化し、他は実施例1と同様に行つた。 実施例 7 植物油74.5部、水23.4部、β−サイクロデキス
トリン2.1部を予備混合し、送液圧力10Kg/cm2
50Kg/cm2、100Kg/cm2、200Kg/cm2で乳化し、他は
実施例1と同様にした。同じく、植物油73.8部、
水21.7部、β−サイクロデキストリン4.5部を予
備混合し、送液圧力50Kg/cm2、100Kg/cm2、200
Kg/cm2で乳化し、他は実施例1と同様にした。 実施例 8 植物油57.9部、水36部、β−サイクロデキスト
リン5.5部を予備混合し、送液圧力50Kg/cm2、100
Kg/cm2で乳化し、他は実施例1と同様に行つた。 実施例 9 植物油48部、水46部、β−サイクロデキストリ
ン6部を予備混合し、送液圧力100Kg/cm2、400
Kg/cm2で乳化し、他は実施例1と同様に行つた。 実施例 10 植物油38部、水55部、β−サイクロデキストリ
ン7部を予備混合し、送液圧力50Kg/cm2、400
Kg/cm2で乳化し、他は実施例1と同様に行つた。 実施例1〜10により得られた水中油型乳化油脂
の乳化特性を平均粒径、粘度、乳化状態を代表特
性値として第1表に示した。第1表から明らかな
ように、油脂類と水相とサイクロデキストリンの
比率が1.28〜3.10:1.0:0.03〜0.15(重量比)の範
囲においては送液圧力が10〜400Kg/cm2の範囲に
おいて良好なる乳化が得られている。また、処理
乳化液の流れに脈流等の不連続は無く連続乳化性
も良好であつた。一方、上記油脂類、水相、サイ
クロデキストリン比率範囲において、相液圧力が
500Kg/cm2以上では大粒径が若干含まれていた。 次に、油脂類と水相とサイクロデキストリンの
比率が0.60〜1.20:1.0:0.02〜0.13(重量比)の範
囲においては送液圧力が10〜600Kg/cm2の範囲に
おいて良好なる乳化が得られている。ただし、送
液圧力50Kg/cm2未満では得られた水中油型乳化油
脂は、送液圧力50Kg/cm2以上で乳化した水中油型
乳化油脂に比較して粘度が低く、離水(クリーミ
ング現象)し易くなつている。 一方、油脂類と水相の比率が3.18:1.0以上で
は、送液圧力を変化させても大粒径が若干混在し
ていた。
"Industrial Application Field" The present invention relates to a method for continuously producing an oil-in-water type emulsified fat-and-oil food containing cyclodextrin, fats and oils, and water as main components. "Prior Art and Problems" In order to produce oil-in-water type emulsified fats and oils, emulsifiers (surfactants) are generally used, and various production apparatuses have been developed. For example, to give an example of a commercially available manufacturing method, after preheating to 50 to 60℃ by heat exchange, homogenization is performed using a homogenizer such as the Gorlin type before sterilization while pressurizing to 140 to 210 kg/cm 2 , and then heating The product is sterilized and filled. Also, mayonnaise, which is also an oil-in-water type emulsified fat, is manufactured using the emulsifying function of lipoproteins contained in the raw material egg yolk, and the manufacturing process involves combining egg yolk, seasoning, spices, and vinegar in a premix machine. First, the mixture is mixed uniformly, then salad oil is added and stirred, and this is sent to a colloid mill for finishing stirring, and after being filled, the product is made. Homo mixer, Ajihomo mixer (Tokushu Kika Kogyo Co., Ltd.), etc. have been developed as the above-mentioned premix equipment. All of these are batch type. On the other hand, continuous type systems such as Homomitsu Line Flow (Tokushu Kika Kogyo Co., Ltd.) are being developed and considered. still,
The commercially available mayonnaise mentioned above is made by taking advantage of the emulsifying function of natural substances (such as milk protein and lecithin) contained in the raw materials. In addition, imitation creams and the like are manufactured using similar processes and equipment by adding food additives such as emulsifiers. The present inventors have studied various methods for continuously producing an oil-in-water emulsified fat containing cyclodextrin, fat and oil, and an aqueous phase as main components using the above-mentioned apparatus and the like. First, we considered producing the product using a continuous homogenizer, which is used to produce city milk, etc., but no matter how much we tried to adjust the processing pressure, processing liquid temperature, etc., there were some parts that were not emulsified. There were many insufficiencies such as, etc., and it was not possible to obtain good emulsification. Further, a study was also conducted using a homogeneous line flow, but the flow of the processing solution was non-uniform (so-called short pass), resulting in insufficient emulsification. "Means for Solving the Problems" In view of the above circumstances, the inventors of the present invention have conducted intensive research to solve the above problems, and have developed an oil-in-water emulsified fat containing cyclodextrin, fats and oils, and water as main components. They discovered a method for continuous emulsification and completed the present invention. That is, in the present invention, a mixed liquid mainly composed of oils and fats, an aqueous phase, and cyclodextrin is mixed at a rate of 10 to 800 kg/
The mixed liquid is introduced into the mixing chamber from two opposite directions at a pressure of cm 2 to collide with each other, and the mixed liquid is guided into a concave part provided in the mixing chamber and collided with the wall surface of the concave part to create a turbulent jet flow. The method of producing an oil-in-water emulsified fat food is characterized by continuously emulsifying the mixed liquid by jetting it into a low-pressure area by making use of mutual turbulent jets. . The oils and fats used in the present invention include dairy products, butter, modified oils, vegetable oils, animal oils, and other natural or processed oils; the above-mentioned natural or processed oils and fats are processed by fractionation, hydrogenation, transesterification, etc., either alone or in combination. One or more types are selected from the processed oil and fat products. The aqueous phase used in the present invention is not particularly limited, but vinegar, fruit juice, milk, dairy products, egg yolk, egg white, etc. may be used in addition to water. In addition, sucrose such as caster sugar and granulated sugar; starch sugars such as maltose and glucose; starch syrups such as powdered starch syrup and high maltose; isomerized liquid sugar, honey,
Sugars represented by sugar alcohols such as mannitol and sorbitol; emulsion stabilizers such as salt, organic acids, salts, gums, and microcrystalline cellulose; various emulsifiers; fragrances, etc. are added to the aqueous phase and oils and fats. used. The cyclodextrin used in the present invention is produced by reacting starch with amylase produced by bacteria such as Bacillus or Micrococcus. As the cyclodextrin, α, β, γ cyclodextrin, branched cyclodextrin, modified cyclodextrin, etc. are used alone or in combination. Furthermore, each cyclodextrin does not necessarily have to be of high purity; it may be one in which dextrin, branched dextrin, or saccharide remains. In the present invention, the amount of cyclodextrin used is expressed in terms of pure cyclodextrin (100% cyclodextrin), and when using a product with residual impurities such as dextrin, it is necessary to convert the concentration. In the method for producing an oil-in-water emulsified fat of the present invention, the liquid feeding pressure is 10 to 800 Kg/cm 2 , and more preferably the ratio of oils and fats, aqueous phase, and cyclodextrin in the oil-in-water emulsified fat, and the aqueous phase. Better emulsification can be obtained by selecting the type and concentration of the emulsifier. That is, when the ratio of fats and oils to the aqueous phase and cyclodextrin is in the range of 1.28 to 3.10:1.0:0.03 to 0.15, the liquid feeding pressure is preferably 10 to 450 Kg/ cm2 . When the liquid feeding pressure exceeds 450 Kg/cm 2 , emulsification tends to deteriorate somewhat. In addition, the ratio of oils and fats, aqueous phase, and cyclodextrin is 0.60 to 1.20:1.0:
In the range of 0.02 to 0.13, the liquid delivery pressure is 10 to
It is preferable that it is 800Kg/cm 2 . In addition, the liquid feeding pressure is 50
If it is less than Kg/ cm2 , the obtained oil-in-water emulsified oil often has a low viscosity, which tends to cause syneresis such as creaming phenomenon, so the liquid delivery pressure is 50Kg/ cm2 to 800.
More preferably, it is Kg/cm 2 . In addition, 800Kg/
Emulsification is good even at a liquid delivery pressure higher than cm 2 , but the particle size tends to increase. As mentioned above, the aqueous phase used in the present invention is selected from vinegar, fruit juice, milk, dairy products, eggs, etc., and further contains sugars, common salt, organic acetic acid, salts, gums, emulsion stabilizers, fragrances, etc. However, if vinegar and/or fruit juice is used in the aqueous phase, and the ratio in the aqueous phase is 25% by weight or more, it is better to set the liquid feeding pressure slightly different from the above range. preferable. That is, when the aqueous phase contains vinegar and/or fruit juice and the ratio in the aqueous phase is 25% by weight or more, the ratio of oil and fat to the aqueous phase and cyclodextrin is 1.58 to 1.58.
In the range of 3.10:1.0:0.03 to 0.15 (weight ratio), the liquid feeding pressure is preferably 10 to 150 Kg/cm 2 . When the liquid feeding pressure exceeds 150 Kg/cm 2 , emulsification tends to deteriorate somewhat. Similarly, when the aqueous phase contains vinegar and/or fruit juice and the ratio in the aqueous phase is 25% by weight or more, the ratio of oil and fat to the aqueous phase and cyclodextrin is
In the range of 1.20 to 1.50:1.0:0.03 to 0.15 (weight ratio), the liquid feeding pressure is preferably 10 to 400 Kg/ cm2 . When the liquid feeding pressure exceeds 400 Kg/cm 2 , emulsification tends to deteriorate somewhat. Similarly, when the aqueous phase contains vinegar and/or fruit juice and the ratio in the aqueous phase is 25% by weight or more, the ratio of oil and fat to the aqueous phase and cyclodextrin is
When the weight ratio is in the range of 0.60 to 1.15:1.0:0.03 to 0.13 (weight ratio), the liquid feeding pressure is preferably 10 to 800 Kg/ cm2 . Furthermore, if the liquid delivery pressure is less than 50 kg/cm 2 , the obtained oil-in-water emulsified oil often has a low viscosity, which can easily cause syneresis such as creaming phenomenon.
It is more preferable that the liquid feeding pressure is 50 to 800 Kg/cm 2 . Although emulsification is good even when the liquid feeding pressure is higher than 800 Kg/cm 2 , the particle size tends to increase. In the present invention, cyclodextrin is used at a weight ratio of 0.02 to 0.15 per aqueous phase 1;
If the ratio is less than this, emulsification becomes unstable, which is not preferable.
Although emulsification is good even at ratios exceeding 0.15,
It is expensive and a ratio of 0.15 or less is sufficient. Further, the ratio of oils and fats in the present invention is preferably less than 3.18 to 1 part of the aqueous phase. When the ratio of fats and oils is 3.18 or more, emulsification tends to become unstable. Note that the lower limit of the ratio of oils and fats in the present invention is not particularly limited. In addition, the above-mentioned liquid feeding pressure is explained in the third section below.
These are the emulsification conditions for a test machine with the processing flow rate shown in the table, and are thought to be affected by the scale of the equipment, etc. In the present invention, a liquid mixture mainly composed of oils and fats, an aqueous phase, and cyclodextrin is used as described above.
The mixed liquid is jetted into the mixing chamber from two opposing directions at a pressure of 10 to 800 kg/cm 2 to collide with each other, and the mixed liquid is guided into a concave part provided in the mixing chamber and collided with the wall surface thereof. After creating a turbulent jet,
By jetting the mixed liquid into a low pressure region, it is continuously emulsified using turbulent jet interaction. As a specific device for carrying out the method of the present invention, for example, the device described in US Pat. No. 4,533,254 can be used. An overview of this device is provided in the first section.
As shown in the figure, it consists of two channels 1 and 2 having optically smooth surfaces and a spacer 3 interposed between the smooth surfaces between both channels and in contact with both channels to prevent liquid leakage. , and one channel 2 is connected to an inlet hole 3 for supplying high-pressure liquid, the other channel 1 is connected to a discharge hole 4 with a larger diameter, and the spacer 3 is connected to both channels 1 and 2. A recess 8 is provided in a mixing chamber 7 having a communicating hole 5 and forming an elongated orifice by opposing nozzles 6a, 6b formed between both channels and the spacer hole. A mixed liquid mainly composed of oils and fats, an aqueous phase, and cyclodextrin is introduced into the inlet hole 9 at a pressure of 10 to 800 g/cm 2 by a pump capable of constant flow, and is introduced into the two liquid inlets 2a of the channel 2. ,2
b is ejected and introduced into the mixing chamber 7 through nozzles 6a and 6b so as to be opposed to each other, and are caused to collide with each other. The collided turbulent jet is guided into the recess 8 in a direction substantially perpendicular to the collision direction, collides with the wall surface of the recess, becomes a turbulent jet, passes through the channel 1, and enters the discharge hole 4, which is a low pressure region. The liquid is injected and emulsified while causing turbulent jet interaction. The mixed liquid is jetted into the mixing chamber at a uniform supply rate. "Action/Effect" According to the present invention, it becomes possible to continuously emulsify an oil-in-water type emulsified fat containing oils and fats, an aqueous phase, and cyclodextrin as main components. Moreover, the emulsified state is very good, with an average particle size of about 5 to 12 microns and a sharp particle size distribution, as shown in the Coulter counter measurement results in Examples. As mentioned above, even if an attempt is made to produce the oil-in-water type emulsified fat containing cyclodextrin, fats and oils, and an aqueous phase as main components using a homogenizer (Manton-Gaulin), which is one of the continuous emulsifying machines, the processing will be unsuccessful. No matter how much the pressure, processing temperature, etc.
Good emulsification cannot be obtained. Similarly, good emulsification cannot be obtained even if Homo Mik Line Flow (Tokushu Kika Kogyo) is used. This means that, as can be inferred from its structure, cyclodextrin does not have a lipophilic group, whereas general emulsifiers have both a hydrophilic group and a lipophilic group and are surfactants. This is thought to be due to the fact that it does not have a surfactant effect. In addition, inclusion compounds containing fats and oils and cyclodextrin also do not have a surfactant effect. Surfactants include air/water, oil/water,
Causes significant adsorption at the solid/liquid interface. That is, during the production of oil-in-water emulsified fats and oils, emulsifiers exhibit significant adsorption to the oil/water interface and protect the oil/water interface, whereas cyclodextrins and their fats and clathrates are oriented toward the oil/water interface. We cannot help but think that this is due to a mechanism different from that of emulsifiers. In addition, oil-in-water emulsified oils, which are mainly composed of oils and fats, an aqueous phase, and cyclodextrin, are liquid with the viscosity of the oils and fats or the aqueous phase before emulsification, but during emulsification, the oils and fats The viscosity increases rapidly depending on the proportion of The above is the reason why good emulsification cannot be obtained with other homogenizers or continuous emulsifiers such as Homomitsu Line Flow with oil-in-water emulsified fats and oils whose main components are cyclodextrin, fats and oils, and an aqueous phase. Also, in the present invention, this is considered to be one of the reasons why the liquid feeding pressure must be selected depending on the ratio of oils and fats to the aqueous phase and the type of the aqueous phase. "Examples" The present invention will be described below with reference to Examples and Comparative Examples, but the present invention is not limited to these. Example 1 73 parts of vegetable oil (parts by weight, same below), 24 parts of water, β
- Premix 2 parts of cyclodextrin and use a microfluidizer (M-110TC type)
(manufactured by Microfluidics Corporation) with a liquid delivery pressure of 10
Kg/cm 2 , 50Kg/cm 2 , 100Kg/cm 2 , 200Kg/cm 2 , 400
Emulsification was carried out at Kg/cm 2 and 500Kg/cm 2 , respectively. The particle size of this oil-in-water emulsified fat was measured using a Coulter Counter (Model TA-11, manufactured by Nikkaki Corporation) using a tube with an aperture diameter of 50 microns or 280 microns. The measured values were processed by computer, and the average values based on volume distribution are shown in the table. In addition, the viscosity was measured using a Visco tester (model VT-04, manufactured by Kobayashi Rikakikai Co., Ltd.). In addition, the emulsified state was determined from the appearance and microscopic observation of the 1% aqueous dispersion, and is shown in the table. Example 2 65 parts of vegetable oil, 33 parts of water, and 2 parts of β-cyclodextrin were pre-mixed and the liquid feeding pressure was 10 Kg/cm 2 and 50 Kg/cm 2 .
cm 2 , 100Kg/cm 2 , 200Kg/cm 2 , 400Kg/cm 2 , 550Kg/
emulsified in cm 2 . The rest was carried out in the same manner as in Example 1. Example 3 60 parts of vegetable oil, 38 parts of water, and 2 parts of β-cyclodextrin were premixed, and the liquid feeding pressure was 10 Kg/cm 2 and 50 Kg/cm 2 .
cm 2 , 100Kg/cm 2 , 200Kg/cm 2 , 400Kg/cm 2 , 550Kg/
emulsified in cm 2 . The rest was carried out in the same manner as in Example 1. Example 4 55 parts of vegetable oil, 43 parts of water, and 2 parts of β-cyclodextrin were premixed, and the liquid feeding pressure was 10 Kg/cm 2 and 50 Kg/cm 2 .
cm 2 , 100Kg/cm 2 , 200Kg/cm 2 , 400Kg/cm 2 , 550Kg/
emulsified in cm 2 . The rest was carried out in the same manner as in Example 1. Example 5 50 parts of vegetable oil, 48 parts of water, and 2 parts of β-cyclodextrin were premixed, and the liquid feeding pressure was 10 Kg/cm 2 and 30 Kg/cm 2 .
cm 2 , 50Kg/cm 2 , 100Kg/cm 2 , 200Kg/cm 2 , 300Kg/
cm 2 , 400Kg/cm 2 and 600Kg/cm 2 . The rest was carried out in the same manner as in Example 1. Example 6 40 parts of vegetable oil, 58 parts of water, and 2 parts of β-cyclodextrin were premixed, and the liquid delivery pressure was 10 Kg/cm 2 and 50 Kg/cm 2 .
cm 2 , 100Kg/cm 2 , 200Kg/cm 2 , 400Kg/cm 2 , 600Kg/
The emulsification was carried out in the same manner as in Example 1 except that the emulsification was carried out in the same manner as in Example 1. Example 7 74.5 parts of vegetable oil, 23.4 parts of water, and 2.1 parts of β-cyclodextrin were premixed, and the liquid feeding pressure was 10 Kg/cm 2 .
Emulsification was carried out at 50Kg/cm 2 , 100Kg/cm 2 , and 200Kg/cm 2 , and the rest was the same as in Example 1. Similarly, 73.8 parts of vegetable oil,
21.7 parts of water and 4.5 parts of β-cyclodextrin are premixed, and the liquid delivery pressure is 50Kg/cm 2 , 100Kg/cm 2 , 200
Emulsification was carried out at Kg/cm 2 , and the other procedures were the same as in Example 1. Example 8 57.9 parts of vegetable oil, 36 parts of water, and 5.5 parts of β-cyclodextrin were premixed, and the liquid feeding pressure was 50 Kg/cm 2 , 100
Emulsification was carried out at kg/cm 2 , and the other procedures were the same as in Example 1. Example 9 48 parts of vegetable oil, 46 parts of water, and 6 parts of β-cyclodextrin were premixed, and the liquid delivery pressure was 100 Kg/cm 2 , 400
Emulsification was carried out at kg/cm 2 , and the other procedures were the same as in Example 1. Example 10 38 parts of vegetable oil, 55 parts of water, and 7 parts of β-cyclodextrin were premixed, and the liquid feeding pressure was 50 Kg/cm 2 , 400
Emulsification was carried out at kg/cm 2 , and the other procedures were the same as in Example 1. The emulsification properties of the oil-in-water type emulsified fats and oils obtained in Examples 1 to 10 are shown in Table 1, with average particle diameter, viscosity, and emulsification state as representative property values. As is clear from Table 1, when the ratio of oils and fats, aqueous phase, and cyclodextrin is in the range of 1.28 to 3.10:1.0:0.03 to 0.15 (weight ratio), the liquid feeding pressure is in the range of 10 to 400 Kg/ cm2. Good emulsification was obtained. Further, there was no discontinuity such as pulsation in the flow of the treated emulsion, and the continuous emulsification was good. On the other hand, the phase liquid pressure is
At 500Kg/cm 2 or more, some large particles were included. Next, when the ratio of oils and fats, aqueous phase, and cyclodextrin is in the range of 0.60 to 1.20:1.0:0.02 to 0.13 (weight ratio), good emulsification can be obtained when the liquid feeding pressure is in the range of 10 to 600 kg/ cm2 . ing. However, the oil-in-water type emulsified oil obtained at a liquid feeding pressure of less than 50 kg/ cm2 has a lower viscosity than the oil-in-water type emulsified oil and fat obtained at a liquid feeding pressure of 50 kg/cm2 or more , and syneresis (creaming phenomenon) occurs. It's getting easier. On the other hand, when the ratio of oils and fats to the aqueous phase was 3.18:1.0 or higher, some large particles were present even when the liquid feeding pressure was changed.

【表】【table】

【表】 実施例 11 植物油62部、穀物酢22部、水14部、β−サイク
ロデキストリン2部を予備混合し、送液圧力10
Kg/cm2、20Kg/cm2、30Kg/cm2、50Kg/cm2、100
Kg/cm2、150Kg/cm2、200Kg/cm2で乳化し、他は実
施例1と同様に行つた。 実施例 12 植物油55部、穀物酢22部、水21部、β−サイク
ロデキストリン2部を予備混合し、送液圧力10
Kg/cm2、20Kg/cm2、30Kg/cm2、50Kg/cm2、100
Kg/cm2、150Kg/cm2、200Kg/cm2、300Kg/cm2、400
Kg/cm2、500Kg/cm2で乳化し、他は実施例1と同
様に行つた。 実施例 13 植物油50部、穀物酢22部、水26部、β−サイク
ロデキストリン2部を予備混合し、送液圧力10
Kg/cm2、20Kg/cm2、30Kg/cm2、50Kg/cm2、100
Kg/cm2、150Kg/cm2、200Kg/cm2、300Kg/cm2、400
Kg/cm2、500Kg/cm2で乳化し、他は実施例1と同
様に行つた。 実施例 14 植物油55部、穀物酢22部、水21部、β−サイク
ロデキストリン2部、上白糖60部を予備混合し、
送液圧力10Kg/cm2、30Kg/cm2、50Kg/cm2、100
Kg/cm2、150Kg/cm2、200Kg/cm2、300Kg/cm2、400
Kg/cm2、500Kg/cm2、600Kg/cm2、750Kg/cm2で乳
化し、他は実施例1と同様に行つた。 実施例11〜14により得られた水中油型乳化油脂
の乳化特性を平均粒径、粘度、乳化状態を代表特
性値として第2表に示した。 第2表から明らかなように、水相に酢及び/又
は果汁を含み、その水相中の比率が25重量%以上
である場合には、油脂類と水相とサイクロデキス
トリンの比率が1.58〜3.10:1.0:0.03〜0.15(重量
比)の範囲においては、送液圧力10〜150Kg/cm2
の範囲において良好なる乳化が得られている。一
方、上記油脂類、水相、サイクロデキストリンの
比率範囲において、送液圧力が200Kg/cm2以上で
は大粒径が若干含有されていた。同じく水相に酢
及び/又は果汁を含み、その水相中の比率が25重
量%以上であり、油脂類と水相とサイクロデキス
トリンの比率が1.20〜1.50:1.0:0.03〜0.15(重量
比)の範囲においては、送液圧力10〜400Kg/cm2
の範囲において良好なる乳化が得られている。一
方、上記油脂類、水相、サイクロデキストリンの
比率範囲において、送液圧力が500Kg/cm2以上で
は大粒径のものが若干混在していた。同じく水相
に酢及び/又は果汁を含み、その水相中の比率が
25重量%以上であり、油脂類と水相とサイクロデ
キストリンの比率が0.60〜1.15:1.0:0.03〜0.13
(重量比)の範囲においては、送液圧力10〜500
Kg/cm2の範囲において良好なる乳化が得られてい
る。但し、送液圧力50Kg/cm2未満では得られた水
中油型乳化油脂は送液圧力50Kg/cm2以上で乳化し
た水中油型乳化油脂に比較して粘度が低く、離水
(クリーミング現象)しやすくなつている。
[Table] Example 11 62 parts of vegetable oil, 22 parts of grain vinegar, 14 parts of water, and 2 parts of β-cyclodextrin were premixed, and the liquid delivery pressure was 10
Kg/cm 2 , 20Kg/cm 2 , 30Kg/cm 2 , 50Kg/cm 2 , 100
Emulsification was carried out at Kg/cm 2 , 150 Kg/cm 2 and 200 Kg/cm 2 , and the rest was carried out in the same manner as in Example 1. Example 12 55 parts of vegetable oil, 22 parts of grain vinegar, 21 parts of water, and 2 parts of β-cyclodextrin were premixed, and the liquid delivery pressure was 10
Kg/cm 2 , 20Kg/cm 2 , 30Kg/cm 2 , 50Kg/cm 2 , 100
Kg/cm 2 , 150Kg/cm 2 , 200Kg/cm 2 , 300Kg/cm 2 , 400
Kg/cm 2 and 500 Kg/cm 2 , and the rest was carried out in the same manner as in Example 1. Example 13 50 parts of vegetable oil, 22 parts of grain vinegar, 26 parts of water, and 2 parts of β-cyclodextrin were premixed, and the liquid delivery pressure was 10
Kg/cm 2 , 20Kg/cm 2 , 30Kg/cm 2 , 50Kg/cm 2 , 100
Kg/cm 2 , 150Kg/cm 2 , 200Kg/cm 2 , 300Kg/cm 2 , 400
Kg/cm 2 and 500 Kg/cm 2 , and the rest was carried out in the same manner as in Example 1. Example 14 55 parts of vegetable oil, 22 parts of grain vinegar, 21 parts of water, 2 parts of β-cyclodextrin, and 60 parts of white sugar were premixed,
Liquid feeding pressure 10Kg/cm 2 , 30Kg/cm 2 , 50Kg/cm 2 , 100
Kg/cm 2 , 150Kg/cm 2 , 200Kg/cm 2 , 300Kg/cm 2 , 400
Emulsification was carried out at Kg/cm 2 , 500Kg/cm 2 , 600Kg/cm 2 , and 750Kg/cm 2 , and the rest was carried out in the same manner as in Example 1. The emulsification properties of the oil-in-water type emulsified fats and oils obtained in Examples 11 to 14 are shown in Table 2, with average particle diameter, viscosity, and emulsification state as representative property values. As is clear from Table 2, when the aqueous phase contains vinegar and/or fruit juice and the ratio in the aqueous phase is 25% by weight or more, the ratio of oils and fats to the aqueous phase and cyclodextrin is 1.58 to 1.58. In the range of 3.10:1.0:0.03~0.15 (weight ratio), the liquid delivery pressure is 10~150Kg/ cm2
Good emulsification was obtained within this range. On the other hand, in the above ratio range of fats and oils, aqueous phase, and cyclodextrin, when the liquid feeding pressure was 200 Kg/cm 2 or higher, some large particles were contained. Similarly, the aqueous phase contains vinegar and/or fruit juice, the ratio in the aqueous phase is 25% by weight or more, and the ratio of oils and fats to the aqueous phase and cyclodextrin is 1.20 to 1.50: 1.0: 0.03 to 0.15 (weight ratio) In the range of 10 to 400Kg/cm 2
Good emulsification was obtained within this range. On the other hand, in the above ratio range of fats and oils, aqueous phase, and cyclodextrin, when the liquid feeding pressure was 500 Kg/cm 2 or more, some large particles were mixed. Similarly, the aqueous phase contains vinegar and/or fruit juice, and the ratio in the aqueous phase is
25% by weight or more, and the ratio of oils and fats to aqueous phase and cyclodextrin is 0.60 to 1.15:1.0:0.03 to 0.13
In the range of (weight ratio), the liquid delivery pressure is 10 to 500.
Good emulsification was obtained within the range of Kg/cm 2 . However, the oil-in-water emulsified fat obtained at a delivery pressure of less than 50 kg/ cm2 has a lower viscosity than the oil-in-water emulsified fat obtained at a delivery pressure of 50 kg/cm2 or more , and syneresis (creaming phenomenon) occurs. It's getting easier.

【表】【table】

【表】 次に、実施例で用いたマイクロフルイダイザー
の機械特性を見るために、実施例11、実施例12に
おける処理流量を第3表に示す。
[Table] Next, in order to see the mechanical properties of the microfluidizer used in the examples, the processing flow rates in Examples 11 and 12 are shown in Table 3.

【表】 又、実施例1〜14により得られた水中油型乳化
油脂のコールターカウンター(TA−型、日科
機製)の粒径分布の全体像を見るために、実施例
11において送液圧力100Kg/cm2及び400Kg/cm2で得
た水中油型乳化油脂の粒径分布測定例を第4表に
示す。
[Table] In addition, in order to see the overall image of the particle size distribution of the Coulter Counter (TA-type, manufactured by Nikkaki) of the oil-in-water emulsified fats obtained in Examples 1 to 14,
Table 4 shows an example of measuring the particle size distribution of the oil-in-water emulsified fat obtained in Example No. 11 at liquid delivery pressures of 100 Kg/cm 2 and 400 Kg/cm 2 .

【表】 比較例 1 植物油65部、水33部、β−サイクロデキストリ
ン2部を予備混合し、次いでホモジナイザー(マ
ントンゴーリン社製)を用い、処理圧10Kg/cm2
30Kg/cm2、50Kg/cm2、100Kg/cm2で乳化した。 その結果、処理済は乳化されていない部分が多
く、処理条件をどのように変化させても良好な乳
化状態を得るに到らなかつた。 比較例 2 植物油50部、水48部、β−サイクロデキストリ
ン2部を予備混合し、次いでホモジナイザー(マ
ントンゴーリン社製)を用い、処理圧10Kg/cm2
30Kg/cm2、50Kg/cm2、100Kg/cm2で乳化した。 その結果、比較例1と同様に処理済は乳化され
てない部分が多く、処理条件をどのように変化さ
せても良好な乳化状態を得るに到らなかつた。 以上のように、本発明により、従来効果的手段
が無かつた油脂類、水相、サイクロデキストリン
を主成分とする水中油型乳化油脂の連続乳化が可
能となり、上記水中油型乳化油脂の特徴を活かし
た乳化油脂食品、例えばマヨネーズ、ドレツシン
グ類、ソース類、パン・洋菓子練り込み・フイリ
ング素材等の製造が容易になる。
[Table] Comparative Example 1 65 parts of vegetable oil, 33 parts of water, and 2 parts of β-cyclodextrin were premixed, and then using a homogenizer (manufactured by Manton-Gorlin), a treatment pressure of 10 kg/cm 2 was applied.
Emulsification was carried out at 30Kg/cm 2 , 50Kg/cm 2 and 100Kg/cm 2 . As a result, there were many parts of the treated product that were not emulsified, and no matter how the processing conditions were changed, a good emulsified state could not be obtained. Comparative Example 2 50 parts of vegetable oil, 48 parts of water, and 2 parts of β-cyclodextrin were premixed, and then using a homogenizer (manufactured by Manton-Gorlin), the treatment pressure was 10 Kg/cm 2 .
Emulsification was carried out at 30Kg/cm 2 , 50Kg/cm 2 and 100Kg/cm 2 . As a result, as in Comparative Example 1, there were many unemulsified portions of the treated sample, and a good emulsified state could not be obtained no matter how the treatment conditions were changed. As described above, the present invention enables continuous emulsification of oil-in-water type emulsified fats mainly composed of oils and fats, an aqueous phase, and cyclodextrin, for which no effective means existed conventionally, and features of the oil-in-water type emulsified fats mentioned above. This makes it easier to produce emulsified oil and fat foods that take advantage of this, such as mayonnaise, dressings, sauces, bread/Western confectionery kneading/filling materials, etc.

【図面の簡単な説明】[Brief explanation of the drawing]

第1図は本発明に用いられる装置の概要図であ
る。 1……チヤンネル、2……チヤツネル、2a,
2b…チヤンネルの液入口、3……スペーサー、
4……排出孔、5……孔、6a,6b……ノズ
ル、7……混合室、8……凹窩部、9……導入
孔。
FIG. 1 is a schematic diagram of the apparatus used in the present invention. 1... Channel, 2... Channel, 2a,
2b...Channel liquid inlet, 3...Spacer,
4... Discharge hole, 5... Hole, 6a, 6b... Nozzle, 7... Mixing chamber, 8... Concave portion, 9... Introduction hole.

Claims (1)

【特許請求の範囲】 1 油脂類、水相及びサイクロデキストリンを主
成分とする混合液を、10〜800Kg/cm2の圧力で相
対する2方向より混合室内に噴出導入して該混合
液を衝突させるとともに、該混合液を該混合室内
に設けた凹窩部に導いてその壁面に衝突させて乱
噴流を生じせしめた後、該混合液を低圧領域に噴
出させることにより、乱噴流相互作用を利用して
連続的に乳化することを特徴とする水中油型乳化
油脂食品の製造方法。 2 混合液を2方向からの衝突方向に対して略垂
直方向に設けられた凹窩部に導いてその壁面に衝
突させた後、該凹窩部と反対方向の低圧領域に噴
出させる特許請求の範囲第1項記載の製造方法。 3 混合液を均一な供給量で混合室内に噴出導入
する特許請求の範囲第1項又は第2項記載の製造
方法。 4 水相が酢、果汁、牛乳、乳製品、卵から選択
される特許請求の範囲第1項記載の製造方法。 5 油脂類が乳製品、バター、調整油脂、植物
油、動物油、これらの油脂類に分別・水素添加・
エステル交換処理を単独又は組み合わせて処理を
施した油脂加工品から少なくとも1種が選択され
る特許請求の範囲第1項又は第4項記載の製造方
法。 6 油脂類、サイクロデキストリン、水相以外の
成分が、上白糖やグラニユー糖等のシヨ糖類;麦
芽糖、ブドウ糖等の澱粉糖類;粉末水あめ、ハイ
マルトース等の水あめ類;異性化液糖類、蜂蜜
類、マンニトール、ソルビトール等の糖アルコー
ル糖等に代表される糖類;食塩、有機酸類、塩
類、ガム類、微結晶セルロース等の乳化安定剤;
各種乳化剤;香料から選択される少なくとも1種
である特許請求の範囲第1項、第4項又は第5項
記載の製造方法。 7 油脂類と水相とサイクロデキストリンの比率
が1.28〜3.10:1.0:0.03〜0.15(重量比)の範囲に
ある油脂類、水相及びサイクロデキストリンを主
成分とする水中油型乳化油脂を送液圧力10〜450
Kg/cm2で乳化する特許請求の範囲第1項、第4
項、第5項又は第6項記載の製造方法。 8 油脂類と水相とサイクロデキストリンの比率
が0.60〜1.20:1.0:0.02〜0.13(重量比)の範囲に
ある油脂類、水相及びサイクロデキストリンを主
成分とする水中油型乳化油脂を送液圧力10〜800
Kg/cm2で乳化する特許請求の範囲第1項、第4
項、第5項又は第6項記載の製造方法。 9 油脂類と水相とサイクロデキストリンの比率
が1.58〜3.10:1.0:0.03〜0.15(重量比)の範囲に
あり、且つ水相中に酢及び/又は果汁を含みその
水相中の比率が25重量%以上である、油脂類、水
相及びサイクロデキストリンを主成分とする水中
油型乳化油脂を送液圧力10〜150Kg/cm2で乳化す
る特許請求の範囲第1項、第4項、第5項又は第
6項記載の製造方法。 10 油脂類と水相とサイクロデキストリンの比
率が1.20〜1.50:1.0:0.03〜0.15(重量比)の範囲
にあり、且つ水相中に酢及び/又は果汁を含みそ
の水相中の比率が25重量%以上である、油脂類、
水相及びサイクロデキストリンを主成分とする水
中油型乳化油脂を送液圧力10〜400Kg/cm2で乳化
する特許請求の範囲第1項、第4項、第5項又は
第6項記載の製造方法。 11 油脂類と水相とサイクロデキストリンの比
率が0.60〜1.15:1.0:0.03〜0.13(重量比)の範囲
にあり、且つ水相中に酢及び/又は果汁を含みそ
の水相中の比率が25重量%以上である、油脂類、
水相及びサイクロデキストリンを主成分とする水
中油型乳化油脂を送液圧力50〜800Kg/cm2で乳化
する特許請求の範囲第1項、第4項、第5項又は
第6項記載の製造方法。
[Scope of Claims] 1. A mixed liquid containing oils and fats, an aqueous phase, and cyclodextrin as main components is jetted into a mixing chamber from two opposing directions at a pressure of 10 to 800 Kg/cm 2 and the mixed liquid collides. At the same time, the mixed liquid is guided into a concave part provided in the mixing chamber and collided with the wall surface to generate a turbulent jet flow, and then the mixed liquid is jetted into a low pressure region to prevent turbulent jet interaction. 1. A method for producing an oil-in-water type emulsified fat food, characterized by continuous emulsification. 2. A patent claim in which the mixed liquid is introduced into a recess provided in a direction substantially perpendicular to the direction of collision from two directions, collided with the wall surface of the recess, and then ejected into a low-pressure region in the opposite direction to the recess. The manufacturing method according to scope 1. 3. The manufacturing method according to claim 1 or 2, wherein the mixed liquid is jetted into the mixing chamber at a uniform supply amount. 4. The manufacturing method according to claim 1, wherein the aqueous phase is selected from vinegar, fruit juice, milk, dairy products, and eggs. 5 Oils and fats are separated into dairy products, butter, modified oils, vegetable oils, animal oils, and these oils and fats are separated, hydrogenated, and
5. The manufacturing method according to claim 1 or 4, wherein at least one type of processed oil or fat product is selected from processed oils and fats that have been subjected to transesterification treatment alone or in combination. 6 Components other than fats and oils, cyclodextrin, and the aqueous phase include sucrose such as caster sugar and granulated sugar; starch sugars such as maltose and glucose; starch syrup such as powdered starch syrup and high maltose; high-fructose corn syrup, honey, Saccharides represented by sugar alcohols such as mannitol and sorbitol; Emulsion stabilizers such as common salt, organic acids, salts, gums, and microcrystalline cellulose;
The manufacturing method according to claim 1, 4, or 5, wherein the emulsifier is at least one selected from perfumes. 7. Pour an oil-in-water emulsion containing oils and fats, an aqueous phase, and cyclodextrin as main components in a ratio of 1.28 to 3.10:1.0:0.03 to 0.15 (weight ratio). pressure 10~450
Claims 1 and 4 emulsifying at Kg/cm 2
5. The manufacturing method according to item 5 or 6. 8. Pour an oil-in-water emulsion containing oils and fats, an aqueous phase, and cyclodextrin as main components, with a ratio of oils and fats, aqueous phase, and cyclodextrin in the range of 0.60 to 1.20:1.0:0.02 to 0.13 (weight ratio). pressure 10~800
Claims 1 and 4 emulsifying at Kg/cm 2
5. The manufacturing method according to item 5 or 6. 9 The ratio of oils and fats, aqueous phase, and cyclodextrin is in the range of 1.58 to 3.10:1.0:0.03 to 0.15 (weight ratio), and the aqueous phase contains vinegar and/or fruit juice, and the ratio in the aqueous phase is 25 Claims 1, 4, and 4, which emulsify an oil-in-water type emulsified oil whose main components are oils and fats, an aqueous phase, and cyclodextrin in an amount of % by weight or more at a liquid delivery pressure of 10 to 150 Kg/ cm2 . The manufacturing method according to item 5 or 6. 10 The ratio of oils and fats, aqueous phase and cyclodextrin is in the range of 1.20 to 1.50:1.0:0.03 to 0.15 (weight ratio), and the aqueous phase contains vinegar and/or fruit juice, and the ratio in the aqueous phase is 25 % by weight or more, oils and fats,
The production according to claim 1, 4, 5, or 6, which emulsifies an oil-in-water emulsified fat containing an aqueous phase and cyclodextrin at a liquid delivery pressure of 10 to 400 Kg/ cm2 . Method. 11 The ratio of oils and fats, aqueous phase, and cyclodextrin is in the range of 0.60 to 1.15:1.0:0.03 to 0.13 (weight ratio), and the aqueous phase contains vinegar and/or fruit juice, and the ratio in the aqueous phase is 25 % by weight or more, oils and fats,
The production according to claim 1, 4, 5, or 6, which emulsifies an oil-in-water emulsified fat containing an aqueous phase and cyclodextrin at a liquid delivery pressure of 50 to 800 Kg/ cm2 . Method.
JP62303596A 1987-11-30 1987-11-30 Preparation of oil-in-water type emulsified fat and oil food Granted JPH01144930A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP62303596A JPH01144930A (en) 1987-11-30 1987-11-30 Preparation of oil-in-water type emulsified fat and oil food

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP62303596A JPH01144930A (en) 1987-11-30 1987-11-30 Preparation of oil-in-water type emulsified fat and oil food

Publications (2)

Publication Number Publication Date
JPH01144930A JPH01144930A (en) 1989-06-07
JPH0583226B2 true JPH0583226B2 (en) 1993-11-25

Family

ID=17922903

Family Applications (1)

Application Number Title Priority Date Filing Date
JP62303596A Granted JPH01144930A (en) 1987-11-30 1987-11-30 Preparation of oil-in-water type emulsified fat and oil food

Country Status (1)

Country Link
JP (1) JPH01144930A (en)

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JP2625645B2 (en) * 1994-09-08 1997-07-02 利春 藤見 Stirrer
US6443610B1 (en) * 1998-12-23 2002-09-03 B.E.E. International Processing product components
JP2004210957A (en) * 2002-12-27 2004-07-29 Ogawa & Co Ltd Emulsion composition and emulsion to finely turbid beverage containing the emulsion composition
JP5161178B2 (en) * 2009-09-11 2013-03-13 株式会社 鋳物屋 Pressure cooker for soup extraction, pressure cooker apparatus using the same, and soup extraction method using them
KR101513831B1 (en) * 2014-01-23 2015-04-20 순창군 Vinegar beverages containing Opunita humifusa included in cyclodextrin and method of preparing the same

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JPS57132851A (en) * 1981-02-13 1982-08-17 Takeda Chem Ind Ltd Emulsifying agent and food containing oil and fat
US4533254A (en) * 1981-04-17 1985-08-06 Biotechnology Development Corporation Apparatus for forming emulsions
JPS5847151A (en) * 1981-09-11 1983-03-18 Osaka Gas Co Ltd Internal combustion engine

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Publication number Priority date Publication date Assignee Title
US20150279753A1 (en) * 2014-04-01 2015-10-01 Fuji Electric Co., Ltd. Power semiconductor module
US9812431B2 (en) * 2014-04-01 2017-11-07 Fuji Electric Co., Ltd. Power semiconductor module

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