JPH06102761B2 - Antistatic coating floor - Google Patents
Antistatic coating floorInfo
- Publication number
- JPH06102761B2 JPH06102761B2 JP1050547A JP5054789A JPH06102761B2 JP H06102761 B2 JPH06102761 B2 JP H06102761B2 JP 1050547 A JP1050547 A JP 1050547A JP 5054789 A JP5054789 A JP 5054789A JP H06102761 B2 JPH06102761 B2 JP H06102761B2
- Authority
- JP
- Japan
- Prior art keywords
- floor
- coating
- parts
- resin
- antistatic coating
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 239000011248 coating agent Substances 0.000 title claims description 23
- 238000000576 coating method Methods 0.000 title claims description 21
- 229920005989 resin Polymers 0.000 claims description 11
- 239000011347 resin Substances 0.000 claims description 11
- 239000011231 conductive filler Substances 0.000 claims description 9
- 230000005484 gravity Effects 0.000 claims description 8
- 239000000463 material Substances 0.000 claims description 6
- 229910044991 metal oxide Inorganic materials 0.000 claims description 5
- 150000004706 metal oxides Chemical class 0.000 claims description 5
- 239000011342 resin composition Substances 0.000 claims description 2
- 229910052751 metal Inorganic materials 0.000 description 7
- 239000002184 metal Substances 0.000 description 7
- 239000003822 epoxy resin Substances 0.000 description 5
- 229920000647 polyepoxide Polymers 0.000 description 5
- 239000002245 particle Substances 0.000 description 4
- 239000000126 substance Substances 0.000 description 4
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 3
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 3
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
- 239000010425 asbestos Substances 0.000 description 3
- 239000000203 mixture Substances 0.000 description 3
- 229910052895 riebeckite Inorganic materials 0.000 description 3
- 239000010454 slate Substances 0.000 description 3
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 3
- 229920000049 Carbon (fiber) Polymers 0.000 description 2
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 2
- MCMNRKCIXSYSNV-UHFFFAOYSA-N Zirconium dioxide Chemical compound O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 description 2
- 239000011230 binding agent Substances 0.000 description 2
- 239000004917 carbon fiber Substances 0.000 description 2
- 230000000052 comparative effect Effects 0.000 description 2
- OEPOKWHJYJXUGD-UHFFFAOYSA-N 2-(3-phenylmethoxyphenyl)-1,3-thiazole-4-carbaldehyde Chemical compound O=CC1=CSC(C=2C=C(OCC=3C=CC=CC=3)C=CC=2)=N1 OEPOKWHJYJXUGD-UHFFFAOYSA-N 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 1
- 229910000323 aluminium silicate Inorganic materials 0.000 description 1
- 239000002518 antifoaming agent Substances 0.000 description 1
- 229910000410 antimony oxide Inorganic materials 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 239000005388 borosilicate glass Substances 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 239000011247 coating layer Substances 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 238000004040 coloring Methods 0.000 description 1
- 239000004020 conductor Substances 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- 230000006866 deterioration Effects 0.000 description 1
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 description 1
- 238000002845 discoloration Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000011888 foil Substances 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 229910000464 lead oxide Inorganic materials 0.000 description 1
- 229910052759 nickel Inorganic materials 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- VTRUBDSFZJNXHI-UHFFFAOYSA-N oxoantimony Chemical compound [Sb]=O VTRUBDSFZJNXHI-UHFFFAOYSA-N 0.000 description 1
- YEXPOXQUZXUXJW-UHFFFAOYSA-N oxolead Chemical compound [Pb]=O YEXPOXQUZXUXJW-UHFFFAOYSA-N 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 238000007747 plating Methods 0.000 description 1
- 229920006122 polyamide resin Polymers 0.000 description 1
- 239000013049 sediment Substances 0.000 description 1
- 238000004062 sedimentation Methods 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 229920002803 thermoplastic polyurethane Polymers 0.000 description 1
- XOLBLPGZBRYERU-UHFFFAOYSA-N tin dioxide Chemical compound O=[Sn]=O XOLBLPGZBRYERU-UHFFFAOYSA-N 0.000 description 1
- 229910001887 tin oxide Inorganic materials 0.000 description 1
- 229920006337 unsaturated polyester resin Polymers 0.000 description 1
- 229920001567 vinyl ester resin Polymers 0.000 description 1
- 239000011787 zinc oxide Substances 0.000 description 1
Landscapes
- Floor Finish (AREA)
- Pigments, Carbon Blacks, Or Wood Stains (AREA)
- Paints Or Removers (AREA)
Description
【発明の詳細な説明】 ＜技術分野＞ 本発明は帯電防止塗床に関するものである。Description: TECHNICAL FIELD The present invention relates to an antistatic coating floor.
＜従来技術＞ 従来、１〜3mm厚に流し展べ仕上された帯電防止塗床は
金属片、カーボンファイバー等を樹脂中に分散させた塗
床材を床下地に塗工して仕上げるものであるが、金属片
は樹脂に比べ比重が大きく、塗工後、樹脂の硬化するま
でに沈降する欠点があり、カーボンファイバーにあって
は導電性に不均一さが生ずる、帯電圧の半減期が長くな
る、コテムラによる仕上り不良になりやすい等の問題が
あった。<Prior art> Conventionally, an antistatic coating floor that has been flow-finished to a thickness of 1 to 3 mm is finished by coating a floor coating with metal pieces, carbon fibers, etc. dispersed in resin. However, metal pieces have a larger specific gravity than resins and have the drawback of settling by the time the resin is cured after coating. Carbon fibers have non-uniform conductivity, and the half-life of charged voltage is long. However, there is a problem that the finish is likely to be poor due to the unevenness.
＜発明の目的＞ 本発明の目的は叙上の如き問題に鑑み検討された結果な
されたもので導電フイラーの沈降がなく、均一で高性能
の帯電防止塗床を提供することにある。<Purpose of the Invention> An object of the present invention is to provide a uniform and high-performance antistatic coating floor, which has been made as a result of studies in view of the above problems and in which the conductive filler does not sediment.
＜発明の構成＞ 本発明の要旨は前記の通りであり、以下詳細に説明す
る。本発明に係る導電フイラーは微小中空体、具体的に
は粒径10〜500μのガラスバルーン、シリカバルーン、
シラスバルーン、カーボンバルーン、フェノールバルー
ン、塩化ビニリデンバルーン、アルミナバルーン、ジル
コニアバルーン、アルミノシリケート系バルーン等の表
面に導電性物質がコーティングされ比重1.0±0.2gr/cm3
に調製されたものが使用される。通常、上記の如き微小
中空体は比重が0.1〜0.8gr/cm3であり比重1.0±0.2gr/c
m3に調節するためコーティング層の厚みが適宜選定され
る。<Structure of Invention> The gist of the present invention is as described above, and will be described in detail below. The conductive filler according to the present invention is a minute hollow body, specifically, a glass balloon having a particle size of 10 to 500μ, a silica balloon,
The surface of shirasu balloon, carbon balloon, phenol balloon, vinylidene chloride balloon, alumina balloon, zirconia balloon, aluminosilicate balloon, etc. is coated with a conductive material and has a specific gravity of 1.0 ± 0.2 gr / cm 3
The one prepared in 1. is used. Usually, the above-mentioned micro hollow body has a specific gravity of 0.1 to 0.8 gr / cm 3 and a specific gravity of 1.0 ± 0.2 gr / c.
The thickness of the coating layer is appropriately selected to adjust to m 3 .
導電性物質には銅、アルミニウム、ニッケル等の金属あ
るいは酸化チタン、酸化錫、酸化アンチモン、酸化亜
鉛、酸化鉛等の金属酸化物が採用され、金属にあっては
メッキ又は溶射により金属コーティングされる。金属酸
化物にあっては樹脂組成中に分散され、樹脂コーティン
グされる。A metal such as copper, aluminum or nickel or a metal oxide such as titanium oxide, tin oxide, antimony oxide, zinc oxide or lead oxide is adopted as the conductive substance, and the metal is coated with metal by plating or spraying. . The metal oxide is dispersed in the resin composition and coated with the resin.
導電フイラーは塗床材のバインダー成分として使用され
るエポキシ樹脂、ウレタン樹脂、不飽和ポリエステル樹
脂、ビニルエステル樹脂等の硬化性樹脂100重量部（以
下単に部という）に対して20〜150部、更に詳しくは金
属コーティングされたものにあっては20〜100部、樹脂
コーティングされたものにあっては30〜150部が混入さ
れる。前者にあっては20部以下、後者にあっては30部以
下では導電特性が不十分になる。また前者において100
部以上、後者において150部以上では導電性が過剰にな
り人体への影響があるため帯電防止床材としては好まし
くない。The conductive filler is 20 to 150 parts per 100 parts by weight (hereinafter simply referred to as "parts") of curable resin such as epoxy resin, urethane resin, unsaturated polyester resin, vinyl ester resin used as a binder component of floor coating material, Specifically, 20 to 100 parts are mixed in the case of metal coating, and 30 to 150 parts are mixed in the case of resin coating. In the former case, the electrical conductivity will be insufficient at 20 parts or less and in the latter case at 30 parts or less. In the former case, 100
If the content is 150 parts or more, and the latter is 150 parts or more, the conductivity becomes excessive and the human body is affected.
導電フイラー以外にカラー着色するための着色剤、消泡
剤ならびに流れ調整剤が添加されて塗床材が調製され
る。In addition to the conductive filler, a colorant for coloring, a defoaming agent, and a flow control agent are added to prepare a floor coating material.
このように調製された塗床材はコンクリート床、木質床
等の床下地に塗工されるに際し、直接又はプライマー塗
布したのち塗工される。また一度に所定厚が得られない
時は、複数回塗工されてもよい。The coating floor material thus prepared is applied directly or after applying a primer when it is applied to a floor base such as a concrete floor or a wooden floor. If the predetermined thickness cannot be obtained at one time, it may be applied multiple times.
実施例１ 平均粒径65μのホウケイ酸ソーダガラス系微小中空球体
に下記の導電性樹脂コーティング剤でコーティングし比
重1.03gr/cm3の導電フイラーを調製し、実施例１と同一
のエポキシ樹脂160部に60部混合して塗床材とし、石綿
スレート板に厚み1mmに塗工し、７日間放置した。塗膜
の様子及び帯電防止性能は表の通りであった。Example 1 A conductive filler having a specific gravity of 1.03 gr / cm 3 was prepared by coating sodium borosilicate glass-based micro hollow spheres having an average particle diameter of 65 μ with the following conductive resin coating agent, and 160 parts of the same epoxy resin as in Example 1 was prepared. The mixture was mixed with 60 parts to prepare a floor coating material, coated on an asbestos slate board to a thickness of 1 mm, and left for 7 days. The appearance of the coating film and the antistatic performance are as shown in the table.
導電性樹脂コーティング剤配合 エピコート1001×75（油化シエルエポキシ（株）製エポ
キシ樹脂） 100部 導電性酸化チタン500W（石原産業（株）製） 475 トーマイド213A（富士化成工業（株）ポリアミド樹脂）
100 トルエン 160 ブタノール 65 比較例１ 実施例と同一のエポキシ樹脂160部に平均粒径５μ比重
8.9gr/cm3のニッケル粉末（福田金属箔粉工業（株）
製）を160部混合したものを石綿スレート板に1mm厚に塗
工し７日間放置した。塗膜の様子及び帯電防止性能は表
の通りであった。Containing conductive resin coating agent Epicoat 1001 × 75 (Epoxy resin manufactured by Yuka Shell Epoxy Co., Ltd.) 100 parts Conductive titanium oxide 500W (manufactured by Ishihara Sangyo Co., Ltd.) 475 TOMIDE 213A (Fuji Kasei Co., Ltd. polyamide resin)
100 Toluene 160 Butanol 65 Comparative Example 1 160 parts of the same epoxy resin as in Example was used, and the average particle size was 5μ
8.9 gr / cm 3 nickel powder (Fukuda Metal Foil & Powder Co., Ltd.)
A mixture of 160 parts of the above) was coated on an asbestos slate plate to a thickness of 1 mm and left for 7 days. The appearance of the coating film and the antistatic performance are as shown in the table.
比較例２ 実施例と同一のエポキシ樹脂160部に平均粒径30μ、比
重4.6gr/cm3の白色導電性酸化チタン500Wを60部混合し
たものを石綿スレート板に1mm厚に塗工し、７日間放置
した。Comparative Example 2 A mixture of 160 parts of the same epoxy resin as in Example and 60 parts of 500 W of white conductive titanium oxide having an average particle size of 30 μ and a specific gravity of 4.6 gr / cm 3 was applied to an asbestos slate board to a thickness of 1 mm, and 7 Left for days.
塗膜の様子及び帯電防止性能は表の通りであった。The appearance of the coating film and the antistatic performance are as shown in the table.
＜発明の効果＞ 本発明になる帯電防止塗床はバインダー成分として使用
される樹脂成分と同等の比重を持つ導電フイラーを混合
分散させた塗床材が塗工されたものであるため導電フイ
ラーが均一に分散されているため均質な帯電防止特性を
発揮する。しかも導電フイラーの沈降がなく、繊維状物
質が混入されていないから施工性が良好である。 <Effects of the Invention> Since the antistatic coating floor according to the present invention is coated with the coating floor material in which the conductive filler having the same specific gravity as the resin component used as the binder component is mixed and dispersed, the conductive filler is Since it is uniformly dispersed, it exhibits uniform antistatic properties. Moreover, there is no sedimentation of the conductive filler and no fibrous substance is mixed, so that the workability is good.
導電性物質として金属酸化物を使用しているので、従来
の金属を使用したものに比べて、空気中の酸素による酸
化による変質や変色などの化学変化が少なく、経時安定
性が優れている。Since a metal oxide is used as a conductive substance, it has less chemical change such as deterioration or discoloration due to oxidation by oxygen in the air and excellent stability over time as compared with a conventional metal oxide.
Claims (1)
れた樹脂組成物がコーティングされた比重1.0±0.2の導
電フィラーを硬化性樹脂に混合分散された塗床材が下地
に塗工されていることを特徴とする帯電防止塗床。1. A floor coating material in which a resin composition containing a metal oxide is coated on the surface of a micro hollow body, and a conductive filler having a specific gravity of 1.0 ± 0.2 is mixed and dispersed in a curable resin. An antistatic coating floor that is characterized by being.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP1050547A JPH06102761B2 (en) | 1989-03-02 | 1989-03-02 | Antistatic coating floor |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP1050547A JPH06102761B2 (en) | 1989-03-02 | 1989-03-02 | Antistatic coating floor |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPH02228370A JPH02228370A (en) | 1990-09-11 |
| JPH06102761B2 true JPH06102761B2 (en) | 1994-12-14 |
Family
ID=12862036
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP1050547A Expired - Fee Related JPH06102761B2 (en) | 1989-03-02 | 1989-03-02 | Antistatic coating floor |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH06102761B2 (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2025020433A (en) * | 2020-08-21 | 2025-02-12 | 住友ゴム工業株式会社 | How to form a painted floor |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP4864200B2 (en) * | 2000-12-11 | 2012-02-01 | 株式会社ミマキエンジニアリング | Ink for inkjet recording apparatus and printing method by inkjet recording apparatus using the ink |
Family Cites Families (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS6096548A (en) * | 1983-10-31 | 1985-05-30 | Nippon Chem Ind Co Ltd:The | Electrically conductive material |
| JPS61152775A (en) * | 1984-12-27 | 1986-07-11 | Toshiba Corp | Electrically-conductive coating compound |
-
1989
- 1989-03-02 JP JP1050547A patent/JPH06102761B2/en not_active Expired - Fee Related
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2025020433A (en) * | 2020-08-21 | 2025-02-12 | 住友ゴム工業株式会社 | How to form a painted floor |
Also Published As
| Publication number | Publication date |
|---|---|
| JPH02228370A (en) | 1990-09-11 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| US4431764A (en) | Antistatic transparent coating composition | |
| EP0250905B1 (en) | Resistive paste, electric heating resistance and preparation process using this paste | |
| JPH0421721B2 (en) | ||
| JP2017147163A (en) | Conductive paste and conductive film formed using the same | |
| JPS6025067B2 (en) | Conductive white coating | |
| JPH06102761B2 (en) | Antistatic coating floor | |
| JPS63145490A (en) | Conductive floor finish material | |
| JPH02255787A (en) | Antistatic sealing material | |
| CN108928073A (en) | Composite board and preparation method thereof, shell and electronic equipment | |
| JPH10146913A (en) | Inorganic decorative board having antibacterial properties and method for producing the same | |
| JPH10324846A5 (en) | ||
| JP2567432B2 (en) | Conductive resin composition | |
| JP2002008443A (en) | Thermal hardening type low resistance conductive paste | |
| JPS60181177A (en) | Electrically-conductive coating compound composition, electrically-conductive plastic sheet or plate using it | |
| JPS62149756A (en) | Electrically conductive resin composition | |
| JPH08143793A (en) | Method for producing conductive coating material and antistatic layer | |
| JPH08167320A (en) | Conductive composition | |
| JPH02129265A (en) | Conductive resin composition | |
| JPH0242548B2 (en) | ||
| JP2595001B2 (en) | Neutron absorption shielding paint | |
| JPS61157541A (en) | conductive filler | |
| JPH08138437A (en) | Conductive material and conductive paste using it | |
| JPH0247168A (en) | Powder coating composition | |
| JPS63176566A (en) | Conductive resin mortar floor | |
| JP2001049594A (en) | Conductive nonwoven sheet |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| LAPS | Cancellation because of no payment of annual fees | ||
| S531 | Written request for registration of change of domicile |
Free format text: JAPANESE INTERMEDIATE CODE: R313532 |
|
| R360 | Written notification for declining of transfer of rights |
Free format text: JAPANESE INTERMEDIATE CODE: R360 |
|
| R370 | Written measure of declining of transfer procedure |
Free format text: JAPANESE INTERMEDIATE CODE: R370 |