JPH061355B2 - Packaging materials for photographic photosensitive materials that are safe in terms of photographic characteristics - Google Patents
Packaging materials for photographic photosensitive materials that are safe in terms of photographic characteristicsInfo
- Publication number
- JPH061355B2 JPH061355B2 JP61189425A JP18942586A JPH061355B2 JP H061355 B2 JPH061355 B2 JP H061355B2 JP 61189425 A JP61189425 A JP 61189425A JP 18942586 A JP18942586 A JP 18942586A JP H061355 B2 JPH061355 B2 JP H061355B2
- Authority
- JP
- Japan
- Prior art keywords
- pigment
- red
- present
- sample
- photographic
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000000463 material Substances 0.000 title claims description 39
- 239000005022 packaging material Substances 0.000 title claims description 28
- 239000000049 pigment Substances 0.000 claims description 142
- ZLFVRXUOSPRRKQ-UHFFFAOYSA-N chembl2138372 Chemical compound [O-][N+](=O)C1=CC(C)=CC=C1N=NC1=C(O)C=CC2=CC=CC=C12 ZLFVRXUOSPRRKQ-UHFFFAOYSA-N 0.000 claims description 9
- PXZQEOJJUGGUIB-UHFFFAOYSA-N isoindolin-1-one Chemical compound C1=CC=C2C(=O)NCC2=C1 PXZQEOJJUGGUIB-UHFFFAOYSA-N 0.000 claims description 7
- MOUPNEIJQCETIW-UHFFFAOYSA-N lead chromate Chemical compound [Pb+2].[O-][Cr]([O-])(=O)=O MOUPNEIJQCETIW-UHFFFAOYSA-N 0.000 claims description 7
- 239000001052 yellow pigment Substances 0.000 claims description 7
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 claims description 6
- NRCMAYZCPIVABH-UHFFFAOYSA-N Quinacridone Chemical compound N1C2=CC=CC=C2C(=O)C2=C1C=C1C(=O)C3=CC=CC=C3NC1=C2 NRCMAYZCPIVABH-UHFFFAOYSA-N 0.000 claims description 4
- 239000000523 sample Substances 0.000 description 48
- 230000002411 adverse Effects 0.000 description 31
- 239000000976 ink Substances 0.000 description 21
- 230000000052 comparative effect Effects 0.000 description 20
- 239000000123 paper Substances 0.000 description 20
- 239000011347 resin Substances 0.000 description 20
- 229920005989 resin Polymers 0.000 description 20
- 229910021645 metal ion Inorganic materials 0.000 description 18
- 239000000839 emulsion Substances 0.000 description 15
- 239000003973 paint Substances 0.000 description 14
- 239000006229 carbon black Substances 0.000 description 12
- 239000000853 adhesive Substances 0.000 description 10
- 230000001070 adhesive effect Effects 0.000 description 10
- 230000000694 effects Effects 0.000 description 10
- 239000011248 coating agent Substances 0.000 description 8
- 238000000576 coating method Methods 0.000 description 8
- 229910052751 metal Inorganic materials 0.000 description 8
- 239000002184 metal Substances 0.000 description 8
- 230000004888 barrier function Effects 0.000 description 7
- 239000011230 binding agent Substances 0.000 description 7
- 229920013716 polyethylene resin Polymers 0.000 description 7
- 239000000126 substance Substances 0.000 description 7
- 239000013068 control sample Substances 0.000 description 6
- -1 acryl Chemical group 0.000 description 5
- 125000000751 azo group Chemical group [*]N=N[*] 0.000 description 5
- 238000000034 method Methods 0.000 description 5
- 239000000203 mixture Substances 0.000 description 5
- 229940099800 pigment red 48 Drugs 0.000 description 5
- 229920000728 polyester Polymers 0.000 description 5
- 150000003839 salts Chemical class 0.000 description 5
- BIIBYWQGRFWQKM-JVVROLKMSA-N (2S)-N-[4-(cyclopropylamino)-3,4-dioxo-1-[(3S)-2-oxopyrrolidin-3-yl]butan-2-yl]-2-[[(E)-3-(2,4-dichlorophenyl)prop-2-enoyl]amino]-4,4-dimethylpentanamide Chemical compound CC(C)(C)C[C@@H](C(NC(C[C@H](CCN1)C1=O)C(C(NC1CC1)=O)=O)=O)NC(/C=C/C(C=CC(Cl)=C1)=C1Cl)=O BIIBYWQGRFWQKM-JVVROLKMSA-N 0.000 description 4
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 4
- 229920000180 alkyd Polymers 0.000 description 4
- 238000004040 coloring Methods 0.000 description 4
- 229920001577 copolymer Polymers 0.000 description 4
- 239000000835 fiber Substances 0.000 description 4
- VOVZXURTCKPRDQ-CQSZACIVSA-N n-[4-[chloro(difluoro)methoxy]phenyl]-6-[(3r)-3-hydroxypyrrolidin-1-yl]-5-(1h-pyrazol-5-yl)pyridine-3-carboxamide Chemical compound C1[C@H](O)CCN1C1=NC=C(C(=O)NC=2C=CC(OC(F)(F)Cl)=CC=2)C=C1C1=CC=NN1 VOVZXURTCKPRDQ-CQSZACIVSA-N 0.000 description 4
- 238000004806 packaging method and process Methods 0.000 description 4
- HFGHRUCCKVYFKL-UHFFFAOYSA-N 4-ethoxy-2-piperazin-1-yl-7-pyridin-4-yl-5h-pyrimido[5,4-b]indole Chemical compound C1=C2NC=3C(OCC)=NC(N4CCNCC4)=NC=3C2=CC=C1C1=CC=NC=C1 HFGHRUCCKVYFKL-UHFFFAOYSA-N 0.000 description 3
- 239000004698 Polyethylene Substances 0.000 description 3
- AUNAPVYQLLNFOI-UHFFFAOYSA-L [Pb++].[Pb++].[Pb++].[O-]S([O-])(=O)=O.[O-][Cr]([O-])(=O)=O.[O-][Mo]([O-])(=O)=O Chemical compound [Pb++].[Pb++].[Pb++].[O-]S([O-])(=O)=O.[O-][Cr]([O-])(=O)=O.[O-][Mo]([O-])(=O)=O AUNAPVYQLLNFOI-UHFFFAOYSA-L 0.000 description 3
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 3
- 239000000654 additive Substances 0.000 description 3
- HEQCHSSPWMWXBH-UHFFFAOYSA-L barium(2+) 1-[(2-carboxyphenyl)diazenyl]naphthalen-2-olate Chemical compound [Ba++].Oc1ccc2ccccc2c1N=Nc1ccccc1C([O-])=O.Oc1ccc2ccccc2c1N=Nc1ccccc1C([O-])=O HEQCHSSPWMWXBH-UHFFFAOYSA-L 0.000 description 3
- 229910052804 chromium Inorganic materials 0.000 description 3
- 239000011651 chromium Substances 0.000 description 3
- 239000000470 constituent Substances 0.000 description 3
- 230000006866 deterioration Effects 0.000 description 3
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 3
- 150000002739 metals Chemical class 0.000 description 3
- XULSCZPZVQIMFM-IPZQJPLYSA-N odevixibat Chemical compound C12=CC(SC)=C(OCC(=O)N[C@@H](C(=O)N[C@@H](CC)C(O)=O)C=3C=CC(O)=CC=3)C=C2S(=O)(=O)NC(CCCC)(CCCC)CN1C1=CC=CC=C1 XULSCZPZVQIMFM-IPZQJPLYSA-N 0.000 description 3
- 229920000573 polyethylene Polymers 0.000 description 3
- 229920000915 polyvinyl chloride Polymers 0.000 description 3
- 229920003987 resole Polymers 0.000 description 3
- 229920003051 synthetic elastomer Polymers 0.000 description 3
- 239000005061 synthetic rubber Substances 0.000 description 3
- 229920005992 thermoplastic resin Polymers 0.000 description 3
- 235000010215 titanium dioxide Nutrition 0.000 description 3
- 229920002554 vinyl polymer Polymers 0.000 description 3
- QIVUCLWGARAQIO-OLIXTKCUSA-N (3s)-n-[(3s,5s,6r)-6-methyl-2-oxo-1-(2,2,2-trifluoroethyl)-5-(2,3,6-trifluorophenyl)piperidin-3-yl]-2-oxospiro[1h-pyrrolo[2,3-b]pyridine-3,6'-5,7-dihydrocyclopenta[b]pyridine]-3'-carboxamide Chemical compound C1([C@H]2[C@H](N(C(=O)[C@@H](NC(=O)C=3C=C4C[C@]5(CC4=NC=3)C3=CC=CN=C3NC5=O)C2)CC(F)(F)F)C)=C(F)C=CC(F)=C1F QIVUCLWGARAQIO-OLIXTKCUSA-N 0.000 description 2
- WZSFTHVIIGGDOI-UHFFFAOYSA-N 4,5,6,7-tetrachloro-3-[2-methyl-3-[(4,5,6,7-tetrachloro-3-oxoisoindol-1-yl)amino]anilino]isoindol-1-one Chemical compound ClC1=C(Cl)C(Cl)=C(Cl)C2=C1C(NC1=CC=CC(NC=3C4=C(C(=C(Cl)C(Cl)=C4Cl)Cl)C(=O)N=3)=C1C)=NC2=O WZSFTHVIIGGDOI-UHFFFAOYSA-N 0.000 description 2
- 239000004593 Epoxy Substances 0.000 description 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 description 2
- FMRLDPWIRHBCCC-UHFFFAOYSA-L Zinc carbonate Chemical compound [Zn+2].[O-]C([O-])=O FMRLDPWIRHBCCC-UHFFFAOYSA-L 0.000 description 2
- 239000004840 adhesive resin Substances 0.000 description 2
- 229920006223 adhesive resin Polymers 0.000 description 2
- WNROFYMDJYEPJX-UHFFFAOYSA-K aluminium hydroxide Chemical compound [OH-].[OH-].[OH-].[Al+3] WNROFYMDJYEPJX-UHFFFAOYSA-K 0.000 description 2
- 229910052793 cadmium Inorganic materials 0.000 description 2
- BDOSMKKIYDKNTQ-UHFFFAOYSA-N cadmium atom Chemical compound [Cd] BDOSMKKIYDKNTQ-UHFFFAOYSA-N 0.000 description 2
- CJOBVZJTOIVNNF-UHFFFAOYSA-N cadmium sulfide Chemical compound [Cd]=S CJOBVZJTOIVNNF-UHFFFAOYSA-N 0.000 description 2
- 239000002657 fibrous material Substances 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- 235000010187 litholrubine BK Nutrition 0.000 description 2
- 239000000395 magnesium oxide Substances 0.000 description 2
- CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 description 2
- AXZKOIWUVFPNLO-UHFFFAOYSA-N magnesium;oxygen(2-) Chemical compound [O-2].[Mg+2] AXZKOIWUVFPNLO-UHFFFAOYSA-N 0.000 description 2
- 238000000465 moulding Methods 0.000 description 2
- 238000006116 polymerization reaction Methods 0.000 description 2
- 229920002635 polyurethane Polymers 0.000 description 2
- 239000004814 polyurethane Substances 0.000 description 2
- 229920002689 polyvinyl acetate Polymers 0.000 description 2
- 239000011118 polyvinyl acetate Substances 0.000 description 2
- 239000004800 polyvinyl chloride Substances 0.000 description 2
- 239000001054 red pigment Substances 0.000 description 2
- 238000003860 storage Methods 0.000 description 2
- KMIOJWCYOHBUJS-HAKPAVFJSA-N vorolanib Chemical compound C1N(C(=O)N(C)C)CC[C@@H]1NC(=O)C1=C(C)NC(\C=C/2C3=CC(F)=CC=C3NC\2=O)=C1C KMIOJWCYOHBUJS-HAKPAVFJSA-N 0.000 description 2
- 239000011667 zinc carbonate Substances 0.000 description 2
- 229910000010 zinc carbonate Inorganic materials 0.000 description 2
- 235000004416 zinc carbonate Nutrition 0.000 description 2
- NYNZQNWKBKUAII-KBXCAEBGSA-N (3s)-n-[5-[(2r)-2-(2,5-difluorophenyl)pyrrolidin-1-yl]pyrazolo[1,5-a]pyrimidin-3-yl]-3-hydroxypyrrolidine-1-carboxamide Chemical compound C1[C@@H](O)CCN1C(=O)NC1=C2N=C(N3[C@H](CCC3)C=3C(=CC=C(F)C=3)F)C=CN2N=C1 NYNZQNWKBKUAII-KBXCAEBGSA-N 0.000 description 1
- DWKNOLCXIFYNFV-HSZRJFAPSA-N 2-[[(2r)-1-[1-[(4-chloro-3-methylphenyl)methyl]piperidin-4-yl]-5-oxopyrrolidine-2-carbonyl]amino]-n,n,6-trimethylpyridine-4-carboxamide Chemical compound CN(C)C(=O)C1=CC(C)=NC(NC(=O)[C@@H]2N(C(=O)CC2)C2CCN(CC=3C=C(C)C(Cl)=CC=3)CC2)=C1 DWKNOLCXIFYNFV-HSZRJFAPSA-N 0.000 description 1
- UXHQLGLGLZKHTC-CUNXSJBXSA-N 4-[(3s,3ar)-3-cyclopentyl-7-(4-hydroxypiperidine-1-carbonyl)-3,3a,4,5-tetrahydropyrazolo[3,4-f]quinolin-2-yl]-2-chlorobenzonitrile Chemical compound C1CC(O)CCN1C(=O)C1=CC=C(C=2[C@@H]([C@H](C3CCCC3)N(N=2)C=2C=C(Cl)C(C#N)=CC=2)CC2)C2=N1 UXHQLGLGLZKHTC-CUNXSJBXSA-N 0.000 description 1
- IYHIFXGFKVJNBB-UHFFFAOYSA-N 5-chloro-2-[(2-hydroxynaphthalen-1-yl)diazenyl]-4-methylbenzenesulfonic acid Chemical compound C1=C(Cl)C(C)=CC(N=NC=2C3=CC=CC=C3C=CC=2O)=C1S(O)(=O)=O IYHIFXGFKVJNBB-UHFFFAOYSA-N 0.000 description 1
- RSWGJHLUYNHPMX-UHFFFAOYSA-N Abietic-Saeure Natural products C12CCC(C(C)C)=CC2=CCC2C1(C)CCCC2(C)C(O)=O RSWGJHLUYNHPMX-UHFFFAOYSA-N 0.000 description 1
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 description 1
- 239000004925 Acrylic resin Substances 0.000 description 1
- 229920000178 Acrylic resin Polymers 0.000 description 1
- ZLFVRXUOSPRRKQ-VHEBQXMUSA-N CI Pigment Red 3 Chemical compound [O-][N+](=O)C1=CC(C)=CC=C1\N=N\C1=C(O)C=CC2=CC=CC=C12 ZLFVRXUOSPRRKQ-VHEBQXMUSA-N 0.000 description 1
- 239000004831 Hot glue Substances 0.000 description 1
- 239000004677 Nylon Substances 0.000 description 1
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 1
- 239000004793 Polystyrene Substances 0.000 description 1
- 229920000297 Rayon Polymers 0.000 description 1
- KHPCPRHQVVSZAH-HUOMCSJISA-N Rosin Natural products O(C/C=C/c1ccccc1)[C@H]1[C@H](O)[C@@H](O)[C@@H](O)[C@@H](CO)O1 KHPCPRHQVVSZAH-HUOMCSJISA-N 0.000 description 1
- MCRWZBYTLVCCJJ-DKALBXGISA-N [(1s,3r)-3-[[(3s,4s)-3-methoxyoxan-4-yl]amino]-1-propan-2-ylcyclopentyl]-[(1s,4s)-5-[6-(trifluoromethyl)pyrimidin-4-yl]-2,5-diazabicyclo[2.2.1]heptan-2-yl]methanone Chemical compound C([C@]1(N(C[C@]2([H])C1)C(=O)[C@@]1(C[C@@H](CC1)N[C@@H]1[C@@H](COCC1)OC)C(C)C)[H])N2C1=CC(C(F)(F)F)=NC=N1 MCRWZBYTLVCCJJ-DKALBXGISA-N 0.000 description 1
- 125000000217 alkyl group Chemical group 0.000 description 1
- LFZDEAVRTJKYAF-UHFFFAOYSA-L barium(2+) 2-[(2-hydroxynaphthalen-1-yl)diazenyl]naphthalene-1-sulfonate Chemical compound [Ba+2].C1=CC=CC2=C(S([O-])(=O)=O)C(N=NC3=C4C=CC=CC4=CC=C3O)=CC=C21.C1=CC=CC2=C(S([O-])(=O)=O)C(N=NC3=C4C=CC=CC4=CC=C3O)=CC=C21 LFZDEAVRTJKYAF-UHFFFAOYSA-L 0.000 description 1
- 239000001055 blue pigment Substances 0.000 description 1
- DQXBYHZEEUGOBF-UHFFFAOYSA-N but-3-enoic acid;ethene Chemical compound C=C.OC(=O)CC=C DQXBYHZEEUGOBF-UHFFFAOYSA-N 0.000 description 1
- 125000002843 carboxylic acid group Chemical group 0.000 description 1
- 235000012730 carminic acid Nutrition 0.000 description 1
- JYNBEDVXQNFTOX-UHFFFAOYSA-N chembl2008134 Chemical compound OS(=O)(=O)C1=CC(C)=CC=C1N=NC1=C(O)C(C(O)=O)=CC2=CC=CC=C12 JYNBEDVXQNFTOX-UHFFFAOYSA-N 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 229920006026 co-polymeric resin Polymers 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 125000000664 diazo group Chemical group [N-]=[N+]=[*] 0.000 description 1
- UUDYLQGRFBLCTF-UHFFFAOYSA-L disodium 2-oxido-5-[(6-sulfonaphthalen-2-yl)diazenyl]benzoate Chemical compound [Na+].[Na+].Oc1ccc(cc1C([O-])=O)N=Nc1ccc2cc(ccc2c1)S([O-])(=O)=O UUDYLQGRFBLCTF-UHFFFAOYSA-L 0.000 description 1
- VPWFPZBFBFHIIL-UHFFFAOYSA-L disodium 4-[(4-methyl-2-sulfophenyl)diazenyl]-3-oxidonaphthalene-2-carboxylate Chemical compound [Na+].[Na+].[O-]S(=O)(=O)C1=CC(C)=CC=C1N=NC1=C(O)C(C([O-])=O)=CC2=CC=CC=C12 VPWFPZBFBFHIIL-UHFFFAOYSA-L 0.000 description 1
- OOYIOIOOWUGAHD-UHFFFAOYSA-L disodium;2',4',5',7'-tetrabromo-4,5,6,7-tetrachloro-3-oxospiro[2-benzofuran-1,9'-xanthene]-3',6'-diolate Chemical compound [Na+].[Na+].O1C(=O)C(C(=C(Cl)C(Cl)=C2Cl)Cl)=C2C21C1=CC(Br)=C([O-])C(Br)=C1OC1=C(Br)C([O-])=C(Br)C=C21 OOYIOIOOWUGAHD-UHFFFAOYSA-L 0.000 description 1
- 239000002270 dispersing agent Substances 0.000 description 1
- STVZJERGLQHEKB-UHFFFAOYSA-N ethylene glycol dimethacrylate Chemical compound CC(=C)C(=O)OCCOC(=O)C(C)=C STVZJERGLQHEKB-UHFFFAOYSA-N 0.000 description 1
- 239000005038 ethylene vinyl acetate Substances 0.000 description 1
- 239000012943 hotmelt Substances 0.000 description 1
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 238000004898 kneading Methods 0.000 description 1
- 238000010030 laminating Methods 0.000 description 1
- 239000004335 litholrubine BK Substances 0.000 description 1
- 229910052748 manganese Inorganic materials 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000000155 melt Substances 0.000 description 1
- AYOOGWWGECJQPI-NSHDSACASA-N n-[(1s)-1-(5-fluoropyrimidin-2-yl)ethyl]-3-(3-propan-2-yloxy-1h-pyrazol-5-yl)imidazo[4,5-b]pyridin-5-amine Chemical compound N1C(OC(C)C)=CC(N2C3=NC(N[C@@H](C)C=4N=CC(F)=CN=4)=CC=C3N=C2)=N1 AYOOGWWGECJQPI-NSHDSACASA-N 0.000 description 1
- 231100000989 no adverse effect Toxicity 0.000 description 1
- 229920001778 nylon Polymers 0.000 description 1
- 239000001053 orange pigment Substances 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 230000001590 oxidative effect Effects 0.000 description 1
- 239000010893 paper waste Substances 0.000 description 1
- 150000002989 phenols Chemical class 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920001200 poly(ethylene-vinyl acetate) Polymers 0.000 description 1
- 229920001225 polyester resin Polymers 0.000 description 1
- 239000004645 polyester resin Substances 0.000 description 1
- 229920000098 polyolefin Polymers 0.000 description 1
- 229920005672 polyolefin resin Polymers 0.000 description 1
- 229920002223 polystyrene Polymers 0.000 description 1
- 229920005990 polystyrene resin Polymers 0.000 description 1
- 239000012851 printed packaging material Substances 0.000 description 1
- 230000001012 protector Effects 0.000 description 1
- 239000002964 rayon Substances 0.000 description 1
- 238000007789 sealing Methods 0.000 description 1
- VVNRQZDDMYBBJY-UHFFFAOYSA-M sodium 1-[(1-sulfonaphthalen-2-yl)diazenyl]naphthalen-2-olate Chemical compound [Na+].C1=CC=CC2=C(S([O-])(=O)=O)C(N=NC3=C4C=CC=CC4=CC=C3O)=CC=C21 VVNRQZDDMYBBJY-UHFFFAOYSA-M 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 125000001424 substituent group Chemical group 0.000 description 1
- 125000000542 sulfonic acid group Chemical group 0.000 description 1
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 1
- KHPCPRHQVVSZAH-UHFFFAOYSA-N trans-cinnamyl beta-D-glucopyranoside Natural products OC1C(O)C(O)C(CO)OC1OCC=CC1=CC=CC=C1 KHPCPRHQVVSZAH-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03C—PHOTOSENSITIVE MATERIALS FOR PHOTOGRAPHIC PURPOSES; PHOTOGRAPHIC PROCESSES, e.g. CINE, X-RAY, COLOUR, STEREO-PHOTOGRAPHIC PROCESSES; AUXILIARY PROCESSES IN PHOTOGRAPHY
- G03C3/00—Packages of films for inserting into cameras, e.g. roll-films, film-packs; Wrapping materials for light-sensitive plates, films or papers, e.g. materials characterised by the use of special dyes, printing inks, adhesives
Landscapes
- Engineering & Computer Science (AREA)
- Microelectronics & Electronic Packaging (AREA)
- Physics & Mathematics (AREA)
- General Physics & Mathematics (AREA)
- Inks, Pencil-Leads, Or Crayons (AREA)
- Pigments, Carbon Blacks, Or Wood Stains (AREA)
Description
【発明の詳細な説明】 ［産業上の利用分野］ 本発明は写真感光材料用包装材料に関し、詳しくは写真
特性に悪影響を与えない顔料を有する写真感光材料用包
装材料に関する。TECHNICAL FIELD The present invention relates to a packaging material for a photographic light-sensitive material, and more particularly to a packaging material for a photographic light-sensitive material having a pigment that does not adversely affect photographic characteristics.
［発明の背景］ フィルム、印画紙等の写真感光材料の包装や保管を行う
ために、写真感光材料が収納される写真フィルムマガジ
ンやカートリッジ、さらにはこれらを包装する包装紙を
含めた包装に用いられている包装材料では、金属、樹
脂、紙、これらの積層体等に塗装、印刷されたものが用
いられている。[Background of the Invention] For packaging and storing photographic light-sensitive materials such as films and photographic papers, it is used for packaging including photographic film magazines and cartridges in which photographic light-sensitive materials are stored, and packaging paper for packaging these. As the packaging material used, those coated and printed on metal, resin, paper, a laminate of these, and the like are used.
従来、この包装材料に施されている塗装や印刷に用いら
れている塗料、印刷インキ等の塗工剤にあっては、金属
用としては金属用塗料、金属用印刷インキ等を用いて、
酸化重合型の樹脂による皮膜が加熱焼付を経て、包装材
料に設けられていた。また他の紙等の包装材料にも同様
の処置の行なわれたものが使用されていた。Conventionally, in coating materials used for coating and printing applied to this packaging material, coating agents such as printing inks, metal coatings for metals, printing inks for metals, etc. are used.
A film made of an oxidation polymerization type resin was provided on the packaging material through heating and baking. Also, other packaging materials, such as paper, which have been subjected to the same treatment have been used.
しかしながら、加熱により硬化させる酸化重合型の樹脂
を主体とした塗工剤にあっては、その構成素材に、写真
性能上悪影響を及ぼすものが多く、これらの構成素材を
用いている塗工剤によって塗装、印刷した包装材料によ
ると写真感光材料が保管中、その使用前に故障を生じて
しまうという欠点があった。However, in the coating agent mainly composed of an oxidative polymerization type resin that is cured by heating, many of its constituent materials adversely affect the photographic performance. The coated and printed packaging material has a drawback that the photographic light-sensitive material may be damaged during storage and before use.
また、これら塗料、インキには、着色のための顔料が含
まれており、この顔料が写真性能を劣化させることもし
ばしば起こり、例えば、同じ樹脂をバインダーに用いた
インキであっても含まれる顔料により写真性能の劣化度
合が異なるという現象としてあらわれる。また、これら
顔料はインキ、塗料だけに限らず、感光材料の包装材料
となる樹脂成型品、紙、繊維等に着色または遮光性付与
等の目的で混入されている場合が多く、これも前記と同
様に写真性能を劣化させる因子となることがあった。In addition, these paints and inks include pigments for coloring, and this pigment often deteriorates photographic performance. For example, pigments included in inks using the same resin as a binder. It appears as a phenomenon that the degree of deterioration of photographic performance is different. Further, these pigments are not limited to inks and paints, but are often mixed in resin moldings, papers, fibers, etc., which are packaging materials for photosensitive materials, for the purpose of coloring or imparting light-shielding properties. Similarly, it may be a factor that deteriorates photographic performance.
このような状況において、塗料、インキのバインダーを
改良して写真性能の劣化を防止する技術が特開昭60-260
61号、同60-26062号、同60-26063号、特願昭60-265897
号、同60-265898号等に開示されているが、これらの技
術では、塗料、インキ中のバインダーによる写真性能の
劣化は防止できるものの、例えばある種の顔料等のよう
な写真性能に悪影響を与える因子がバインダー以外に存
在する場合は、写真感光材料用包装材料全体として写真
性能に悪影響を与えることになり、その利用範囲は限ら
れていた。Under such circumstances, a technique for improving the binder of paints and inks to prevent deterioration of photographic performance is disclosed in JP-A-60-260.
No. 61, No. 60-26062, No. 60-26063, Japanese Patent Application No. 60-265897
No. 60-265898, etc., these techniques can prevent deterioration of photographic performance due to binders in paints and inks, but do not adversely affect photographic performance such as certain pigments. If the factor to be provided is present other than the binder, it adversely affects the photographic performance of the packaging material for the photographic light-sensitive material as a whole, and its range of use is limited.
従って、塗料、インキについては、その構成成分である
バインダー成分と共に顔料成分についても写真性能に与
える影響を調査する必要があり、また塗料、インキに限
らず、顔料を含有する着色された樹脂製品等の写真感光
材料用包装材料にも同様の対策が必要であった。Therefore, for paints and inks, it is necessary to investigate the influence of the pigment component as well as the binder component that is a constituent component on the photographic performance. Not only paints and inks, but also colored resin products containing pigments, etc. The same measures were required for the packaging material for the photographic light-sensitive material.
従来用いられていた写真特性上好ましくない顔料として
は、例えばある種の酸化チタン等の白色顔料、ある種の
カーボンブラック等の黒色顔料、ある種の酸化鉄（ベン
ガラ）等の赤色顔料等が代表的なものとして知られてい
るが、一般的に着色剤として用いられる顔料については
写真性能に与える影響が充分解明されているとは言い難
く、またその機構についても明確ではない。Typical pigments that have hitherto been used in view of photographic characteristics are, for example, white pigments such as titanium oxide, black pigments such as carbon black, and red pigments such as iron oxide (red iron oxide). However, it is difficult to say that the effect on the photographic performance of pigments generally used as colorants has been sufficiently clarified, and its mechanism is not clear.
現在着色が施されていないものはほとんどないといって
よいほど、写真感光材料用包装材料には着色が施されて
おり、その目的も、製品の仕様等を表示する文字、遮光
性付与のための着色、美観を高めるための着色等多岐に
わたり、着色に用いられる顔料も少なくとも２種以上を
組み合わせて用いる場合も多く、例えばパトローネの商
標印刷、ラベルや遮光紙の印刷、バリヤ包材の印刷、デ
ィスクフィルム用プロテクター、外箱等ではほとんどす
べて２種以上の顔料が用いられている。このような状況
下では、用いられる樹脂、添加剤等の他に用いられる複
数の顔料の個々について１つ１つ写真性能に与える影響
を調査する必要があり、多大の時間と費用を要してい
た。The packaging materials for photographic light-sensitive materials are colored to the extent that it is almost uncolored at present, and the purpose is also to display characters such as product specifications and to provide light-shielding properties. There are many types of pigments used for coloring, such as trademark printing of labels, printing of labels and light-shielding paper, printing of barrier packaging materials, Almost all two kinds or more of pigments are used in protectors for disc films, outer boxes and the like. Under such a situation, it is necessary to investigate the influence on the photographic performance of each of a plurality of pigments used in addition to the resins, additives, etc., which requires a great deal of time and cost. It was
［発明の目的］ 本発明の第１の目的は写真性能に悪影響を与えない顔料
を有する写真感光材料用包装材料を提供するものであ
り、本発明の第２の目的は、写真性能に悪影響を与える
顔料が含まれていても、その悪影響をなくす写真性能上
全く不安のない写真感光材料用包装材料を提供するもの
であり、本発明の第３の目的は、顔料以外の写真性能に
悪影響を与える物質、例えばバインダー、その他の添加
剤等が含まれていても、それらの悪影響をもなくす写真
感光材料用包装材料を提供するものである。[Object of the Invention] A first object of the present invention is to provide a packaging material for a photographic light-sensitive material having a pigment that does not adversely affect the photographic performance, and a second object of the present invention is to adversely affect the photographic performance. A third object of the present invention is to provide a packaging material for a photographic light-sensitive material, which is free from any adverse effects on photographic performance even if it contains a pigment to be given. The present invention provides a packaging material for a photographic light-sensitive material, which eliminates adverse effects of a substance to be given such as a binder and other additives.
［発明の構成］ 本発明の上記目的は、下記に示される顔料群から選ばれ
る少なくとも１種の顔料を含有している写真感光材料用
包装材料により達成される。[Constitution of Invention] The above object of the present invention is achieved by a packaging material for a photographic light-sensitive material, which contains at least one pigment selected from the pigment group shown below.
クロムエロー顔料、クロムバーミリオン顔料、 溶性アゾ系顔料、キナクリドン系顔料、イソインドリノ
ン系顔料、レーキレッド４Ｒ顔料 ［発明の具体的構成］ 本発明に用いられるクロムエロー（Chrome Yellow）顔
料としては、ＣＩ No.77600、ＣＩ No.77603、ＣＩ
Pigment Yellow３４に分類される顔料が挙げられ、具体
的にはクロムエロー１０Ｇ、クロムエロー５Ｇ、クロム
エローＧ、クロムエローＲ、クロムエロー５Ｒ等の名称
のものが知られており、主成分はPbCrO4であり、PbO等
も混合されるものである。Chrome Yellow Pigment, Chrome Vermillion Pigment, Soluble Azo Pigment, Quinacridone Pigment, Isoindolinone Pigment, Lake Red 4R Pigment [Specific Configuration of the Invention] As a Chrome Yellow pigment used in the present invention, CI No. .77600, CI No.77603, CI
Pigments classified into Pigment Yellow 34 are mentioned, and specifically, those having names such as chrome yellow 10G, chrome yellow 5G, chrome yellow G, chrome yellow R, and chrome yellow 5R are known, and the main component is PbCrO 4 and PbO etc. Is also mixed.
クロムバーミリオン（Chrome Vermilion）顔料として
は、ＣＩ No.77605、ＣＩ Pigment Red 104、ＣＩ
No.77601、ＣＩ Pigment Red 103、ＣＩ Pigment
Orange ２１に分類される顔料が挙げられ、具体的に
はモリブデートオレンジ、モリブデートレッド等の名称
のものが知られており、主成分はPbCrO4、PbMoO4、PbSO
4である。Examples of Chrome Vermilion pigments include CI No. 77605, CI Pigment Red 104, CI
No.77601, CI Pigment Red 103, CI Pigment
Pigments categorized as Orange 21 are listed, and specifically, those having names such as molybdate orange and molybdate red are known, and the main components are PbCrO 4 , PbMoO 4 , and PbSO.
Is 4 .
本発明における溶性アゾ系顔料としては、アゾ基を有し
て水溶性の顔料はすべて包含するが、化学構造式中に１
つのアゾ基を有し、さらにスルホン酸基および／または
カルボン酸基を有してその金属塩であるものが代表的で
あり、具体的には、ウォッチングレッド（Watching Re
d）、リソールレッド（Lithol Red）、ボルドー１０Ｂ
（Bor deaux １０Ｂ）、ブリリアンカーミン６Ｂ（Br
illiant Carmine ６Ｂ）、レーキレッドＣ（Lake Re
d Ｃ）、レーキレッドＤ（Lake Red Ｄ）等が挙げら
れる。The soluble azo pigment in the present invention includes all water-soluble pigments having an azo group.
A typical example thereof is a metal salt thereof having two azo groups and further having a sulfonic acid group and / or a carboxylic acid group.
d), Lithol Red, Bordeaux 10B
(Bor deaux 10B), Brilliant Angamine 6B (Br
illiant Carmine 6B), Rake Red C (Lake Re
d C), Lake Red D and the like.
以下、溶性アゾ系顔料の具体例を説明する。Hereinafter, specific examples of the soluble azo pigment will be described.
ウォッチングレッドとしては、ＣＩ No.15865、ＣＩ
Pigment Red ４８（Na）、ＣＩ No.15865：１、ＣＩ
Pigment Red ４８：１（Ba）、ＣＩ No.15865：
２、ＣＩ Pigment Red ４８：２（Ca）、ＣＩ No.1
5865：３、ＣＩ Pigment Red ４８：３（Sr）、ＣＩ
No.15865：４、ＣＩ Pigment Red ４８：４（Mn）
等に分類される顔料が挙げられ、下記一般式で示される
ものが代表的である。As a watching red, CI No.15865, CI
Pigment Red 48 (Na), CI No.15865: 1, CI
Pigment Red 48: 1 (Ba), CI No. 15865:
2, CI Pigment Red 48: 2 (Ca), CI No.1
5865: 3, CI Pigment Red 48: 3 (Sr), CI
No.15865: 4, CI Pigment Red 48: 4 (Mn)
And the like, and those represented by the following general formula are typical.
（式中、Ｍは１価または２価の金属イオン、具体的には
Na+、Ba++、Ca++、Sr++またはMn++を表わし、ｎはＭが
１価の金属イオンのときは２、２価の金属イオンのとき
は１を表わす。） 通常、ＭがCaであり、Ba、Mnではそれぞれウォッチング
レッドBa、ウォッチングレッドMnと言われ、またパーマ
ネントレッド（Permanent Red）Ｆ５Ｒ、パーマネント
レッド２BBa、パーマネントレッド２BMnと呼ばれること
もある。 (In the formula, M is a monovalent or divalent metal ion, specifically
It represents Na + , Ba ++ , Ca ++ , Sr ++ or Mn ++ , and n represents 2 when M is a monovalent metal ion and 1 when M is a divalent metal ion. In general, M is Ca, and Ba and Mn are referred to as Watching Red Ba and Watching Red Mn, respectively, and may also be called Permanent Red F5R, Permanent Red 2BBa, and Permanent Red 2BMn.
リソールレッドとしては、ＣＩ No.15630、ＣＩ Pigm
ent Red４９（Na）、ＣＩ No.15630：１、ＣＩ Pigm
ent Red ４９：１（Ba）、ＣＩ No.15630：２、ＣＩ
Pigment Red ４９：２（Ca）、ＣＩ No.15630：
３、ＣＩ Pigment Red ４９：３（Sr）、さらに、Mn
等を含有した顔料が挙げられ、下記の一般式で示される
ものが代表的である。As Resole Red, CI No. 15630, CI Pigm
ent Red49 (Na), CI No.15630: 1, CI Pigm
ent Red 49: 1 (Ba), CI No.15630: 2, CI
Pigment Red 49: 2 (Ca), CI No.15630:
3, CI Pigment Red 49: 3 (Sr), and Mn
Pigments containing the following are listed, and those represented by the following general formula are typical.
一般式 （式中、Ｍは１価または２価の金属イオン、具体的には
Ba++、Na+、Ca++、Sr++、Mn等を表わし、ｎはＭが１価
の金属イオンのときは１、２価の金属イオンのときは２
を表わす。） ＭがBa++であるものが一般的である。General formula (In the formula, M is a monovalent or divalent metal ion, specifically
Ba ++ , Na + , Ca ++ , Sr ++ , Mn, etc., where n is 1 when M is a monovalent metal ion and 2 when M is a divalent metal ion.
Represents It is common that M is Ba ++ .
ボルドー１０Ｂとしては、ＣＩ No.15880、ＣＩ Pigm
ent Red ６３（Na）、ＣＩ No.15880：１、ＣＩ Pi
gment Red ６３：１（Ca）、ＣＩ No.15880：２、Ｃ
Ｉ Pigment Red ６３：２（Mn）、さらにBa等を含有
した顔料が挙げられ、下記の一般式で示されるものが代
表的である。For Bordeaux 10B, CI No. 15880, CI Pigm
ent Red 63 (Na), CI No.15880: 1, CI Pi
gment Red 63: 1 (Ca), CI No. 15880: 2, C
Pigments containing I Pigment Red 63: 2 (Mn) and Ba and the like are mentioned, and those represented by the following general formula are typical.
一般式 （式中、Ｍは１価または２価の金属イオン、具体的には
Na+、Ca++、Mn++等を表わし、ｎはＭが１価の金属イオ
ンのときは２、２価の金属イオンのときは１を表わ
す。） ブリリアンカーミン６Ｂとしては、ＣＩ No.15850、Ｃ
Ｉ Pigment Red ５７（Na）、ＣＩ No.15850：１、
ＣＩ Pigment Red ５７：１（Ca）、ＣＩ No.1585
0：２、ＣＩ Pigment Red ５７：２（Ba）等に分類
される顔料が挙げられ、下記の一般式で示されるものが
代表的である。General formula (In the formula, M is a monovalent or divalent metal ion, specifically
It represents Na + , Ca ++ , Mn ++, etc., and n represents 2 when M is a monovalent metal ion and 1 when M is a divalent metal ion. ) For Brilyankamine 6B, CI No. 15850, C
I Pigment Red 57 (Na), CI No. 15850: 1,
CI Pigment Red 57: 1 (Ca), CI No.1585
Pigments classified into 0: 2, CI Pigment Red 57: 2 (Ba) and the like are mentioned, and those represented by the following general formula are typical.
一般式 （式中、Ｍは１価または２価の金属イオン、具体的には
Na+、Ca++、Ba++等を表わし、ｎはＭが１価の金属イオ
ンのときは２、２価の金属イオンのときは１を表わ
す。） また、リソールルビンＢＫ（Lithol Rubine ＢＫ）、
パーマネントレッドＦ６Ｒ（Pigment Red Ｆ６Ｒ）と
も呼ばれることもある。General formula (In the formula, M is a monovalent or divalent metal ion, specifically
Represents Na + , Ca ++ , Ba ++, etc., and n represents 2 when M is a monovalent metal ion and 1 when M is a divalent metal ion. ) In addition, Lithol Rubine BK,
It may also be called Permanent Red F6R (Pigment Red F6R).
レーキレッドＣとしては、ＣＩ No.15585、ＣＩ Pigm
ent Red ５３（Na）、ＣＩ No.15585：１、ＣＩ Pi
gment Red ５３：１（Ba）、ＣＩ No.15585：２、Ｃ
Ｉ Pigment Red ５３：２（Ca）、さらにAl等を含有
した顔料が挙げられ、下記の一般式で示されるものが代
表的である。Rake Red C is CI No.15585, CI Pigm
ent Red 53 (Na), CI No.15585: 1, CI Pi
gment Red 53: 1 (Ba), CI No.15585: 2, C
Pigments containing I Pigment Red 53: 2 (Ca) and Al and the like are mentioned, and those represented by the following general formula are typical.
一般式 （式中、Ｍは金属イオン、具体的にはNa+、Ba++、Ca++
等を表わし、ｎはＭが１価の金属イオンのときは１、２
価の金属イオンのときは２を表わす。） レーキレッドＤとしては、ＣＩ No.15500、ＣＩ Pigm
ent Red ５０（Na）、ＣＩ No.15500：１、ＣＩ Pi
gment Red ５０：１（Ba）、ＣＩ No.15500：２、Ｃ
Ｉ Pigment Red ５０：２（Ca）等に分類される顔料
が挙げられ、下記の一般式で表されるものが代表的であ
る。General formula (In the formula, M is a metal ion, specifically Na + , Ba ++ , Ca ++
And n is 1, 2 when M is a monovalent metal ion.
In the case of a valent metal ion, it represents 2. ) As Lake Red D, CI No. 15500, CI Pigm
ent Red 50 (Na), CI No.15500: 1, CI Pi
gment Red 50: 1 (Ba), CI No. 15500: 2, C
Pigments classified into I Pigment Red 50: 2 (Ca) and the like are mentioned, and those represented by the following general formula are typical.
一般式 （式中、Ｍは金属イオン、具体的にはNa+、Ba++、Ca++
等を表わし、ｎはＭが１価の金属イオンのときは１、２
価の金属イオンのときは２を表わす。） キナクリドン系顔料としては、ＣＩ Pigment Red 12
2、ＣＩ Pigment Red 192、ＣＩ No.46500、ＣＩ
Pigment Violet １９、ＣＩ Pigment Violet ３
０、ＣＩ Pigment Yellow 155等に分類される顔料が
挙げられ、下記一般式で表わされるものが代表的であ
る。General formula (In the formula, M is a metal ion, specifically Na + , Ba ++ , Ca ++
And n is 1, 2 when M is a monovalent metal ion.
In the case of a valent metal ion, it represents 2. ) As a quinacridone pigment, CI Pigment Red 12
2, CI Pigment Red 192, CI No. 46500, CI
Pigment Violet 19, CI Pigment Violet 3
No. 0, CI Pigment Yellow 155 and the like, and those represented by the following general formula are typical.
一般式 （式中、R1およびR2はそれぞれ水素原子、アルキル基等
の置換基を表わす。） イソインドリノン系顔料としては、ＣＩ Pigment Yel
low109、ＣＩ Pigment Yellow 110、ＣＩ Pigment
Orange ４２等に分類される顔料が挙げられ、「8382
の化学商品」（化学工業日報社）等に記載されている如
く、以下の式で示されるイソインドリノンエローレディ
シュ、イソインドリノンエローグリーニッシュが代表的
なものとして挙げられる。General formula (In the formula, R 1 and R 2 each represent a substituent such as a hydrogen atom or an alkyl group.) Examples of the isoindolinone pigment include CI Pigment Yel.
low109, CI Pigment Yellow 110, CI Pigment
Pigments classified into Orange 42 and the like are listed, and “8382
As described in "Chemical Products of Chemical Industry" (Chemical Industry Daily Co., Ltd.) and the like, isoindolinone eroredish and isoindolinone erogreenish represented by the following formulas are typical examples.
（イソインドリノンエローレディシュ） （イソインドリノンエローグリーニッシュ） レーキレッド４Ｒ顔料としては、ＣＩ No.12120、ＣＩ
Pigment Red ３に分類されるものが挙げられ、以下
の式で示されるものが代表的である。(Isoindolinone ello reddish) (Isoindolinone Yellow Greenish) As lake red 4R pigment, CI No. 12120, CI
Pigment Red 3 is included, and those represented by the following formulas are typical.
また、レーキレッド４Ｒは、トルイジンレッド（Toluid
ine Red）、パーマネントレッド４Ｒ（Permanent Red
４Ｒ）、ハンザスカーレッド（Hansa Scarlet）、ハ
ンザレッド（Hansa Red）、リソールファーストスカー
レット（Lithol Fast Scarlet）とも呼ばれる。 In addition, Rake Red 4R is Toluidine Red (Toluid
ine Red), Permanent Red 4R (Permanent Red)
4R), Hansa Scarlet, Hansa Red, and Lithol Fast Scarlet.
上記本発明の顔料を有する本発明の包装材料としては、
本発明の顔料を含有する塗料、インキの塗設物、本発明
の顔料を含有する接着剤の接着物、さらには本発明の顔
料が材料中に混入されたもの等が挙げられ、紙、繊維、
プラスチック、金属類およびこれらの組み合わせ物等の
材料に上記塗設、接着、混入等がされたものである。The packaging material of the present invention having the pigment of the present invention,
Paints containing the pigment of the present invention, ink coatings, adhesives of adhesives containing the pigment of the present invention, and further those in which the pigment of the present invention is mixed in the material, paper, fiber ,
Materials such as plastics, metals, and combinations thereof are coated, adhered, and mixed with the materials described above.
本発明の顔料を含有する塗料、インキとしては、本発明
の顔料が各種の樹脂、分散剤、溶剤等と共に均一に分散
されたものである。上記塗料、インキに用いられる各種
の樹脂としては、通常のインキ、塗料に用いられる樹
脂、例えばアルキド、変性アルキド、ポリビニル、アク
リル、エポキシ、ポリウレタン、ポリエステル、フェノ
ール、変性フェノール等の各樹脂の単体、ブレンド、コ
ポリマー等が挙げられる。The coating material and ink containing the pigment of the present invention are obtained by uniformly dispersing the pigment of the present invention together with various resins, dispersants, solvents and the like. As the above-mentioned paint, various resins used in the ink, ordinary ink, resins used in the paint, for example, alkyd, modified alkyd, polyvinyl, acryl, epoxy, polyurethane, polyester, phenol, modified phenol and the like simple substance of each resin, Blends, copolymers and the like can be mentioned.
本発明の顔料を含有する接着剤としては、本発明の顔料
が各種接着剤樹脂中に均一に分散されたものである。こ
こで用いられる接着剤樹脂としては、通常の接着剤に用
いられる樹脂、例えばポリエチレン、ポリエステル、ポ
リ酢酸ビニル、ポリビニル、アクリル、ポリウレタン、
エポキシ、ポリ塩化ビニル、合成ゴム等の各樹脂の単
体、ブレンド、コポリマー等が挙げられ、さらにこれら
のホットメルト型、エマルジョン型、粘着剤型等任意の
接着剤に適用できる。The adhesive containing the pigment of the present invention is one in which the pigment of the present invention is uniformly dispersed in various adhesive resins. The adhesive resin used here is a resin used for ordinary adhesives, for example, polyethylene, polyester, polyvinyl acetate, polyvinyl, acrylic, polyurethane,
Examples include individual resins, blends, copolymers, and the like of each resin such as epoxy, polyvinyl chloride, and synthetic rubber, and the present invention can be applied to any adhesive such as hot melt type, emulsion type, and adhesive type.
本発明の顔料を材料中に混入したものとしては、本発明
の顔料が練り込まれたカートリッジ、スプール、コア等
の樹脂成型品、本発明の顔料を製紙過程で混入した遮光
紙、挟紙、封紙、接着紙、ラベル、カートン、バリヤ袋
等の紙製材料、本発明の顔料を繊維の製造過程で混入し
た遮光部材等の繊維製材料、さらには本発明の顔料を熱
可塑性樹脂に練り込んだものをコーティングまたはラミ
ネート材としたバリヤ袋、遮光紙等の包装材料等が挙げ
られる。Examples of the pigment of the present invention mixed in the material include a resin-molded product such as a cartridge, a spool, or a core in which the pigment of the present invention is kneaded, a light-shielding paper in which the pigment of the present invention is mixed in a papermaking process, a sandwich paper, Paper materials such as sealing paper, adhesive paper, labels, cartons, barrier bags, etc., fiber materials such as light-shielding members mixed with the pigment of the present invention during the fiber manufacturing process, and further kneading the pigment of the present invention into a thermoplastic resin. Examples of the packaging material include barrier bags, light-shielding paper, and the like, in which the inclusions are coated or laminated.
上記において樹脂成型品に用いられる樹脂としては、ポ
リエチレン等のポリオレフィン系、ポリスチレン系、ポ
リエステル系、ポリ塩化ビニル、合成ゴム等の単体、ブ
レンド、コポリマー等各種の樹脂が挙げられ、紙材料と
しては、Ｎ−パルプ、Ｌ−パルプ、古紙、再生紙等が挙
げられ、繊維材料としては、ナイロン、ポリエステル、
アクリル、レーヨン、アセテート等が挙げられ、さらに
コーティングまたはラミネート剤に用いられる熱可塑性
樹脂としては、ポリエチレン等のポリオレフィン、エチ
レン−酢酸ビニル等のポリビニル系、エチレン−メタク
リレート等のアクリル系、ポリエステル、合成ゴム等の
単体、ブレンド、コポリマー等各種の熱可塑性樹脂が挙
げられる。Examples of the resin used in the resin molded product in the above include polyolefin-based resins such as polyethylene, polystyrene-based, polyester-based, polyvinyl chloride, various types of resins such as synthetic rubbers, blends, and copolymers. N-pulp, L-pulp, waste paper, recycled paper and the like can be mentioned, and as the fiber material, nylon, polyester,
Acrylic, rayon, acetate and the like can be mentioned. Further, as the thermoplastic resin used for the coating or laminating agent, polyolefin such as polyethylene, polyvinyl such as ethylene-vinyl acetate, acrylic such as ethylene-methacrylate, polyester, synthetic rubber Examples thereof include various thermoplastic resins such as simple substance, blend, and copolymer.
本発明の写真感光材料用包装材料に用いられる上記本発
明の顔料の使用量は、本発明の顔料の種類、包装される
写真感光材料の種類、本発明の顔料が用いられる形態、
包装材料の構成素材中に含まれる写真特性に悪影響を与
える物質または因子によっても大きく異なるが、例えば
塗料、インキ中に本発明の顔料を添加する場合、本発明
の顔料を含んだ全顔料が塗料、インキ中の全組成物中３
〜５０重量％の範囲が好ましく、より好ましくは５〜３
０重量％であり、塗料、インキ中の全顔料に対する本発
明の顔料の割合は５〜100重量％が好ましく、より好ま
しくは２０〜100重量％であり、さらに好ましくは４０
〜100重量％である。また、例えば接着剤に本発明の顔
料を添加する場合、接着剤中0.1〜２０重量％の範囲が
好ましく、より好ましくは１〜１０重量％である。さら
に樹脂、紙、繊維等に本発明の顔料を添加する場合、そ
れらの部材に対して３０重量％以下、0.01重量％以上の
範囲で用いるのが好ましく、より好ましくは0.1〜２０
重量％の範囲である。The use amount of the pigment of the present invention used in the packaging material for a photographic light-sensitive material of the present invention is the type of the pigment of the present invention, the type of the photographic light-sensitive material to be packaged, the form in which the pigment of the present invention is used,
Although it greatly varies depending on substances or factors which adversely affect the photographic characteristics contained in the constituent materials of the packaging material, for example, when the pigment of the present invention is added to a paint or ink, all pigments including the pigment of the present invention are paints. , 3 in all compositions in ink
The range is preferably 50 to 50% by weight, more preferably 5 to 3
It is 0% by weight, and the ratio of the pigment of the present invention to the total pigment in the paint or ink is preferably 5 to 100% by weight, more preferably 20 to 100% by weight, and further preferably 40%.
~ 100% by weight. In addition, for example, when the pigment of the present invention is added to the adhesive, the amount in the adhesive is preferably 0.1 to 20% by weight, more preferably 1 to 10% by weight. Further, when the pigment of the present invention is added to resin, paper, fiber, etc., it is preferably used in the range of 30% by weight or less and 0.01% by weight or more, more preferably 0.1 to 20% with respect to those members.
It is in the range of% by weight.
本発明の包装材料においては、上記の如く本発明の顔料
を種々の形態で含有させることにより、本発明の顔料が
写真性能に悪影響を与えないことはもちろんのこと、写
真性能に悪影響を与える顔料が同時に含有された包装材
料においても、本発明の顔料により写真性能への悪影響
をなくすことができ、さらに写真性能に悪影響を与える
ものが顔料以外、例えばバインダー、その他の添加物等
である場合においても、本発明の顔料の添加によって写
真性能への悪影響をなくすことが可能であるという驚く
べき効果を見い出したものである。従って本発明におい
ては、本発明の顔料を着色、遮光だけの目的でなく、例
えば写真性能に悪影響を与える恐れのある部材に混入す
る等の応用も可能である。In the packaging material of the present invention, by incorporating the pigment of the present invention in various forms as described above, the pigment of the present invention does not adversely affect the photographic performance, and the pigment adversely affects the photographic performance. Even in the packaging material containing at the same time, the pigment of the present invention can eliminate adverse effects on the photographic performance, and when the adverse effect on the photographic performance is other than the pigment, for example, a binder, other additives, etc. Also, the surprising effect that the adverse effect on the photographic performance can be eliminated by adding the pigment of the present invention has been found. Therefore, in the present invention, not only the purpose of coloring and shading the pigment of the present invention but also application such as mixing in a member that may adversely affect photographic performance is possible.
本発明の包装材料においては、本発明の顔料を含有させ
ることにより写真性能上不安のない包装材料を提供でき
るが、さらに特開昭60-26061号、同60-26062号、同60-2
6063号、特願昭60-265897号、同60-265898号等に記載の
技術を併用することにより、さらに写真性能上の悪影響
の除去に対する信頼性が増し、また特願昭60-282627
号、同60-282628号、同60-282629号に記載の技術を併用
することにより、カブリ等の写真性能を積極的に改良で
きる等の効果があり、それぞれ本発明のさらに好ましい
態様である。In the packaging material of the present invention, by incorporating the pigment of the present invention, it is possible to provide a packaging material with no concern for photographic performance, and further, JP-A-60-26061, 60-26062 and 60-2.
By using the techniques described in 6063, Japanese Patent Application No. 60-265897, and Japanese Patent Application No. 60-265898, etc., the reliability of removing adverse effects on photographic performance is further increased, and Japanese Patent Application No. 60-282627 is also used.
No. 60-282628 and No. 60-282629 have the effect of positively improving the photographic performance such as fog by using the techniques described in No. 60-282628 and 60-282629, and each is a further preferred embodiment of the present invention.
本発明の顔料を含有する包装材料が適用される写真感光
材料はあらゆる写真感光材料であり、例えば、Ｘ−レイ
写真感光材料、印刷用リス型写真感光材料、黒白型写真
感光材料、カラー写真感光材料等が挙げられ、この他の
写真感光材料にも適用される。The photographic light-sensitive material to which the packaging material containing the pigment of the present invention is applied is any photographic light-sensitive material, for example, an X-ray photographic light-sensitive material, a lith type photographic light-sensitive material for printing, a black-and-white type photographic light-sensitive material, a color photographic light-sensitive material. Examples of the material include materials, and the invention is also applicable to other photographic light-sensitive materials.
［発明の具体的実施例］ 以下、本発明を実施例によりさらに具体的に説明する
が、本発明の実施の態様はこれらに限定されるものでは
ない。EXAMPLES Specific Examples of the Invention Hereinafter, the present invention will be described in more detail with reference to Examples, but the embodiments of the present invention are not limited thereto.
実施例−１ 対乳剤性に悪影響を与えるべんがらおよびチタンホワイ
ト、さらに本発明のクロムエロー顔料をそれぞれ重量比
で２０：５０：３０の割合で用いてポリビニル系の樹脂
に対して全顔料を２５重量％含有させたインキをパトロ
ーネ用金属部材上に塗設したものを用いてパトローネを
作製した。装填したフィルムはサクラＳＲ−400フィル
ムである。係る試料をNo.１とする。Example 1 Red iron oxide and titanium white, which adversely affect the emulsion properties, and the chromium yellow pigment of the present invention were used in a weight ratio of 20:50:30, respectively, and the total pigment was 25% by weight with respect to the polyvinyl resin. A patrone was produced by using the contained ink coated on a metallic member for patrone. The loaded film is Sakura SR-400 film. This sample is No. 1.
比較例−１ 実施例−１の比較として、上記試料No.１において、ク
ロムエロー顔料に代えてカドミウムイエロー顔料を同じ
割合で用いた以外は同様にして比較試料No.１を作製し
た。Comparative Example-1 As a comparison with Example-1, Comparative Sample No. 1 was prepared in the same manner as in Sample No. 1 described above except that the cadmium yellow pigment was used in the same ratio in place of the chrome yellow pigment.
実施例−２ 対乳剤性に悪影響を与える変性アルキド樹脂に対し、本
発明のクロムバーミリオン顔料を該樹脂に対して２０重
量％含有させたインキをパトローネ用金属部材上に塗設
したものを用いてパトローネを作製した。装填したフィ
ルムは試料No.１と同じであり、係る試料をNo.２とす
る。Example 2 An ink containing 20% by weight of the chromium vermillion pigment of the present invention with respect to a modified alkyd resin having an adverse effect on emulsion resistance was coated on a metallic member for a cartridge. A patrone was made. The loaded film is the same as Sample No. 1, and the sample is No. 2.
実施例−３ 実施例−２の試料No.２において、クロムバーミリオン
顔料に代えてレーキレッドＣ１０重量とべんがら１０重
量を用いた以外は同様にして試料No.３を得た。Example-3 A sample No. 3 was obtained in the same manner as in the sample No. 2 of the example-2, except that 10% by weight of Lake Red C and 10% by weight of red iron oxide were used instead of the chrome vermillion pigment.
比較例−３ 実施例−２および３の比較として、上記試料No.２にお
いて、クロムバーミリオン顔料に代えてジアゾオレンジ
顔料を同じ割合で用いた以外は同様にして比較試料No.
２を作製した。Comparative Example-3 As a comparison between Examples-2 and 3, Comparative Sample No. 2 was prepared in the same manner as in Sample No. 2 except that the diazo orange pigment was used in the same ratio in place of the chromium vermillion pigment.
2 was produced.
実施例−４ 対乳剤性に悪影響を与えるカーボンブラック顔料と本発
明の顔料であるキナクリドンレッドおよびクロムエロー
顔料を６０：１０：３０の重量比で用いて、ポリエステ
ル系の樹脂に対して全顔料を１０重量％含有させた塗料
をパトローネ用金属部材上に塗設したものを用いてパト
ローネを作製した。装填したフィルムは試料No.１と同
じであり、係る試料をNo.４とする。Example 4 A carbon black pigment, which adversely affects the emulsion property, and a pigment of the present invention, quinacridone red and chrome yellow pigment, were used in a weight ratio of 60:10:30, and a total of 10 pigments were added to a polyester resin. A paint was prepared by coating a metal member for a patrone with the coating material containing the weight% of the paint. The loaded film is the same as Sample No. 1, and the sample is No. 4.
比較例−３ 実施例−４の比較として、上記試料No.４において、本
発明の顔料を用いずカーボンブラック顔料を100重量％
とした以外は同様にして比較試料No.３を作製した。Comparative Example-3 As a comparison with Example-4, in the above sample No. 4, 100% by weight of carbon black pigment was used without using the pigment of the present invention.
Comparative sample No. 3 was prepared in the same manner except that
実施例−５ 対乳剤性に悪影響を与えるチタンホワイト、さらに本発
明のウォッチングレッドCa顔料を重量比で７０：３０の
割合とした顔料を対乳剤性に悪影響を与える変性アルキ
ド樹脂に対して２０重量％含有させたインキキをパトロ
ーネ用金属部材上に塗設したものを用いてパトローネを
作製した。装填したフィルムは試料No.１と同じであ
り、係る試料をNo.５とする。Example-5 Titanium white, which adversely affects the emulsion property, and a weight ratio of the Watching Red Ca pigment of the present invention of 70:30, relative to the modified alkyd resin, which adversely affects the emulsion property, is 20% by weight. % Of the ink ink was applied on a metal member for a cartridge, and a cartridge was produced. The loaded film is the same as Sample No. 1, and the sample is No. 5.
比較例−４ 実施例−５の比較として、上記試料No.５において、本
発明のウォッチングレッドCa顔料に代えてカドミウムレ
ッドを同じ割合で用いた以外は同様にして比較試料No.
４を作製した。Comparative Example-4 As a comparison with Example-5, Comparative Sample No. 5 was prepared in the same manner as in the above Sample No. 5, except that cadmium red was used in the same ratio in place of the watching red Ca pigment of the present invention.
4 was produced.
実施例−６ 対乳剤性に悪影響を与えるアイアンブルー顔料、チタン
ホワイト、さらに本発明のイソインドリノンエローグロ
ーニッシュ顔料をそれぞれ重量比で２０：５０：３０の
割合で用いてアクリル系樹脂に３０重量％含有させたイ
ンキを遮光紙上に塗設したものを内装してカートリッジ
試料を作製した。装填したフィルムはサクラＳＲ−400
フィルムである。係る試料をNo.６とする。Example 6 An iron blue pigment, titanium white, and the isoindolinone yellow polish pigment of the present invention, which adversely affect the emulsion properties, were used in a weight ratio of 20:50:30, respectively, and 30 weight% was added to an acrylic resin. %, The ink was coated on a light-shielding paper to prepare a cartridge sample. The loaded film is Sakura SR-400.
It is a film. The sample concerned is No. 6.
比較例−５ 実施例−６の比較として、上記試料No.６において、イ
ソインドリノンエローグリーニッシュに代えてカドミウ
ムエローを同じ割合で用いた以外は同様にして比較試料
No.５を作製した。Comparative Example-5 As a comparison with Example-6, a comparative sample was prepared in the same manner as in Sample No. 6 except that cadmium yellow was used in the same ratio in place of the isoindolinone ellosh greenish.
No. 5 was produced.
実施例−７ 対乳剤性に悪影響を与えるカーボンブラック顔料と本発
明の顔料であるボルドー１０Ｂ顔料を重量比で９０：１
０の割合で、ポリスチレン樹脂に対し全顔料を３重量％
含有させて樹脂を成型加工してカートリッジ試料を作製
した。装填したフィルムは試料No.６と同じであり、係
る試料をNo.７とする。Example 7 A weight ratio of carbon black pigment, which adversely affects the emulsion property, to Bordeaux 10B pigment, which is the pigment of the present invention, is 90: 1.
3% by weight of all pigments based on polystyrene resin at a ratio of 0
A cartridge sample was prepared by incorporating and molding the resin. The loaded film is the same as Sample No. 6, and the sample is No. 7.
実施例−８ 実施例−７の試料No.７において、ボルドー１０Ｂ顔料
に代えてレーキレッドＤを用いた以外は同様にして試料
No.８を得た。Example-8 Sample No. 7 of Example-7 was repeated except that Lake Red D was used instead of Bordeaux 10B pigment.
I got No. 8.
比較例６ 実施例−７および８の比較として、上記試料No.７にお
いて、本発明の顔料を用いずカーボンブラック顔料を10
0重量％とした以外は同様にして比較試料No.６を作製し
た。Comparative Example 6 As a comparison of Examples 7 and 8, in the above Sample No. 7, a carbon black pigment was used without using the pigment of the present invention.
Comparative sample No. 6 was prepared in the same manner except that it was 0% by weight.
実施例−９ 対乳剤性に悪影響を与えるカーボンブラック顔料と本発
明の顔料であるリソールレッドCa塩を９５：５の重量比
でポリエチレン樹脂に対し全顔料を２重量％含有させて
ブラックポリエチレン樹脂とし該樹脂を遮光紙上に塗設
して遮光紙を得、該遮光紙を内装してカートリッジ試料
を作製した。装填したフィルムは試料No.６と同じであ
り、係る試料をNo.９とする。Example-9 A black polyethylene resin was prepared by adding 2% by weight of all pigments to a polyethylene resin in a weight ratio of 95: 5 of a carbon black pigment which adversely affects the emulsion property and a pigment of the present invention, resole red Ca salt. The resin was applied on a light-shielding paper to obtain a light-shielding paper, and the light-shielding paper was incorporated to prepare a cartridge sample. The loaded film is the same as Sample No. 6, and the sample is No. 9.
比較例−７ 実施例−９の比較として、上記試料No.９において、本
発明のリソールレッドCa塩顔料を用いずカーボンブラッ
クを100重量％とした以外は同様にして比較試料No.７を
作製した。Comparative Example-7 As a comparison with Example-9, Comparative Sample No. 7 was prepared in the same manner as in Sample No. 9 except that the lysole red Ca salt pigment of the present invention was not used and carbon black was 100% by weight. did.
実施例−１０ 対乳剤性に悪影響を与えるカーボンブラック顔料と本発
明のレーキレッド４Ｒ顔料を５０：５０の重量比でポリ
エチレン樹脂に対し全顔料を５重量％含有させてブラッ
クポリエチレン樹脂とし、該樹脂をバリヤ袋に塗設して
バリヤ袋を得、カートリッジを内装して試料を得た。装
填したフィルムは試料No.６と同じであり、係る試料をN
o.１０とする。Example-10 A black polyethylene resin was prepared by adding 5% by weight of all pigments to a polyethylene resin in a weight ratio of 50:50 of a carbon black pigment which adversely affects the emulsion property and the lake red 4R pigment of the present invention. Was coated on a barrier bag to obtain a barrier bag, and a cartridge was internally provided to obtain a sample. The loaded film is the same as sample No. 6, and
o.
比較例−８ 実施例−１０の比較として、上記試料No.１０におい
て、本発明のレーキレッド４Ｒ顔料を用いずカーボンブ
ラックを100重量％とした以外は同様にして比較試料No.
８を作製した。Comparative Example-8 As a comparison with Example-10, Comparative Sample No. 10 was prepared in the same manner as in Sample No. 10 except that the lake red 4R pigment of the present invention was not used and carbon black was 100% by weight.
8 was produced.
実施例−１１ 対乳剤性に悪影響を与えるロジン系粘着付与剤を有する
ポリエチレン−ポリ酢酸ビニルコポリマー樹脂のホット
メルト接着剤に本発明のブリリアントカーミン６BBa塩
顔料を５重量％で含有させたものをホットメルト接着剤
として設けた封紙を用いて120フィルムを内装しバリヤ
内装した。装填したフィルムはサクラＳＲ−400フィル
ムであり、係る試料をNo.１１とする。Example 11 A hot melt adhesive of a polyethylene-polyvinyl acetate copolymer resin having a rosin-based tackifier which adversely affects the emulsion property, containing 5% by weight of the brilliant carmine 6BBa salt pigment of the present invention, was hot. A 120-film interior was used as a barrier interior by using a wrapping paper provided as a melt adhesive. The loaded film is Sakura SR-400 film, and the sample is No. 11.
比較例−９ 実施例−１１の比較として、上記試料No.１１におい
て、本発明のブリリアントカーミン６BBa顔料に代えて
カドミウムレッド顔料を同じ割合で用いた以外は同様に
して比較試料No.９を得た。Comparative Example-9 As a comparison with Example-11, Comparative Sample No. 9 was obtained in the same manner as in Sample No. 11 except that the Brilliant Carmine 6BBa pigment of the present invention was replaced with the cadmium red pigment in the same proportion. It was
実施例−１２ 実施例−９の試料No.９において、対乳剤性に悪影響を
与えるカーボンブラック顔料と本発明の顔料であるリソ
ールレッドCa塩と酸化マグネシウム（重量比で８５：
５：１０）をポリエチレン樹脂に対し総量で２重量％含
有させた以外は同様にして試料No.１２を作製した。Example-12 In the sample No. 9 of Example-9, the carbon black pigment which adversely affects the emulsion property, the pigment of the present invention such as resole red Ca salt and magnesium oxide (weight ratio: 85:
Sample No. 12 was prepared in the same manner except that 5:10) was added to the polyethylene resin in a total amount of 2% by weight.
実施例−１３ 実施例−７の試料No.７において、対乳剤性に悪影響を
与えるカーボンブラック顔料と本発明の顔料であるボル
ドー１０Ｂ顔料と水酸化アルミニウム（重量比で７５：
１０：２５）をポリエチレン樹脂に対し総量で３重量％
含有させた以外は同様にして試料No.１３を作製した。Example-13 In the sample No. 7 of Example-7, the carbon black pigment which adversely affects the emulsion property, the Bordeaux 10B pigment which is the pigment of the present invention and the aluminum hydroxide (weight ratio: 75:
10:25) based on polyethylene resin in a total amount of 3% by weight
Sample No. 13 was prepared in the same manner except that it was contained.
実施例−１４ 実施例−１０の試料No.１０において、対乳剤性に悪影
響を与えるカーボンブラック顔料と本発明の顔料である
レーキレッド４Ｒ顔料と炭酸亜鉛（重量比で４０：４
０：２０）をポリエチレン樹脂に対し総量で５重量％含
有させた以外は同様にして試料No.１４を作製した。Example-14 In the sample No. 10 of Example-10, the carbon black pigment which adversely affects the emulsion property, the lake red 4R pigment which is the pigment of the present invention and the zinc carbonate (40: 4 in weight ratio).
0:20) was added to the polyethylene resin in a total amount of 5% by weight to prepare Sample No. 14.
比較例−１０ 対乳剤性に悪影響を与えない材料でパトローネを作製し
た。装填したフィルムはサクラＳＲ−400フィルムであ
り、係る試料をコントロール試料とする。Comparative Example-10 A patrone was made of a material that did not adversely affect the emulsion properties. The loaded film is Sakura SR-400 film, and such a sample is used as a control sample.
以上の実施例−１〜１４および比較例−１〜１０で得た
それぞれの試料をバリヤ袋に入れ、６０℃３日間保管処
理した。またコントロール試料についてはさらに４０℃
３日間保管処理した。The samples obtained in Examples-1 to 14 and Comparative Examples-1 to 10 described above were put in a barrier bag and stored at 60 ° C for 3 days. For control samples, 40 ℃
It was stored for 3 days.
上記の保管処理済試料中のサクラＳＲ−400フィルムを
全て未露光のまま通常の現像処理をし、各フィルムの濃
度を測定した。結果を表−１に示す。All the Sakura SR-400 films in the above-mentioned samples which had been subjected to the storage treatment were subjected to a normal developing treatment while leaving all unexposed, and the densities of the respective films were measured. The results are shown in Table-1.
ここでコントロール試料については、６０℃３日間で保
管した試料をコントロール試料Ａとし、４０℃３日間保
管した試料をコントロール試料Ｂとする。Here, regarding the control sample, a sample stored at 60 ° C. for 3 days is referred to as a control sample A, and a sample stored at 40 ° C. for 3 days is referred to as a control sample B.
得られたフィルム濃度は以下の如くで評価した。The obtained film density was evaluated as follows.
◎……コントロール試料Ｂと同じ濃度レベル 〇……コントロール試料Ａと同じ濃度レベル △……［〇＋（0.01〜0.1）］の濃度レベル ×……［〇＋（0.1以上）］の濃度レベル 表−１より明らかなように、本発明の顔料を含有した包
装材料を用いた写真感光材料用試料は、いずれも写真性
能に悪影響を与える因子が含まれているものでの経時で
の写真性能への悪影響が全く見られず、写真性能上不安
のないものであることがわかる。本発明の写真感光材料
用包装材料にさらに酸化マグネシウム、水酸化アルミニ
ウム、炭酸亜鉛等の化合物を用いると、さらにカブリ濃
度が抑えられて好ましい態様であることがわかる。◎ …… The same concentration level as control sample B 〇 …… The same concentration level as control sample A △ …… [○ + (0.01 to 0.1)] concentration level × …… [[+ (0.1 or more)] concentration level As is clear from Table 1, all the samples for photographic light-sensitive materials using the packaging material containing the pigment of the present invention contain factors that adversely affect the photographic performance, and the photographic performance with time. It can be seen that there is no adverse effect on photographic performance and there is no concern about photographic performance. It can be seen that the use of a compound such as magnesium oxide, aluminum hydroxide or zinc carbonate in the packaging material for a photographic light-sensitive material of the present invention is a preferable mode because the fog density is further suppressed.
───────────────────────────────────────────────────── フロントページの続き (56)参考文献 特開 昭60−26062（ＪＰ，Ａ) 特公 平１−19702（ＪＰ，Ｂ２) 特公 平３−40743（ＪＰ，Ｂ２) 特公 平４−13697（ＪＰ，Ｂ２) ─────────────────────────────────────────────────── ─── Continuation of the front page (56) References JP-A-60-26062 (JP, A) JP-B 1-19702 (JP, B2) JP-B 3-40743 (JP, B2) JP-B 4- 13697 (JP, B2)
Claims (1)
とも１種の顔料を包含していることを特徴とする写真感
光材料用包装材料。 クロムエロー顔料、クロムバーミリオン顔料、 溶性アゾ系顔料、キナクリドン系顔料、イソインドリノ
ン系顔料、レーキレッド４Ｒ顔料1. A packaging material for a photographic light-sensitive material, comprising at least one pigment selected from the group of pigments shown below. Chrome yellow pigment, chrome vermillion pigment, soluble azo pigment, quinacridone pigment, isoindolinone pigment, lake red 4R pigment
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP61189425A JPH061355B2 (en) | 1986-08-12 | 1986-08-12 | Packaging materials for photographic photosensitive materials that are safe in terms of photographic characteristics |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP61189425A JPH061355B2 (en) | 1986-08-12 | 1986-08-12 | Packaging materials for photographic photosensitive materials that are safe in terms of photographic characteristics |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS6344653A JPS6344653A (en) | 1988-02-25 |
| JPH061355B2 true JPH061355B2 (en) | 1994-01-05 |
Family
ID=16241033
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP61189425A Expired - Lifetime JPH061355B2 (en) | 1986-08-12 | 1986-08-12 | Packaging materials for photographic photosensitive materials that are safe in terms of photographic characteristics |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH061355B2 (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR101054661B1 (en) * | 2002-09-09 | 2011-08-08 | 소니 주식회사 | Resin composition |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH0833617B2 (en) * | 1989-12-07 | 1996-03-29 | 富士写真フイルム株式会社 | Photosensitive material cartridge |
Family Cites Families (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5843730A (en) * | 1981-09-11 | 1983-03-14 | 小嶋 康明 | Fishing rod hanger |
| JPS5968238A (en) * | 1982-10-13 | 1984-04-18 | 富士写真フイルム株式会社 | Packing material for photosensitive substance |
| JPS60196335A (en) * | 1984-03-21 | 1985-10-04 | 富士写真フイルム株式会社 | Laminated film |
| JPS6173947A (en) * | 1984-09-20 | 1986-04-16 | Fuji Photo Film Co Ltd | Plastic container body for film cartridge |
-
1986
- 1986-08-12 JP JP61189425A patent/JPH061355B2/en not_active Expired - Lifetime
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR101054661B1 (en) * | 2002-09-09 | 2011-08-08 | 소니 주식회사 | Resin composition |
Also Published As
| Publication number | Publication date |
|---|---|
| JPS6344653A (en) | 1988-02-25 |
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