JPH0621057B2 - Cosmetic composition - Google Patents
Cosmetic compositionInfo
- Publication number
- JPH0621057B2 JPH0621057B2 JP60207493A JP20749385A JPH0621057B2 JP H0621057 B2 JPH0621057 B2 JP H0621057B2 JP 60207493 A JP60207493 A JP 60207493A JP 20749385 A JP20749385 A JP 20749385A JP H0621057 B2 JPH0621057 B2 JP H0621057B2
- Authority
- JP
- Japan
- Prior art keywords
- fine particle
- iron oxide
- titanium oxide
- cosmetic composition
- component
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
Classifications
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q17/00—Barrier preparations; Preparations brought into direct contact with the skin for affording protection against external influences, e.g. sunlight, X-rays or other harmful rays, corrosive materials, bacteria or insect stings
- A61Q17/04—Topical preparations for affording protection against sunlight or other radiation; Topical sun tanning preparations
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
- A61K8/29—Titanium; Compounds thereof
Landscapes
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Animal Behavior & Ethology (AREA)
- General Health & Medical Sciences (AREA)
- Public Health (AREA)
- Veterinary Medicine (AREA)
- Chemical & Material Sciences (AREA)
- Inorganic Chemistry (AREA)
- Birds (AREA)
- Epidemiology (AREA)
- Dermatology (AREA)
- Cosmetics (AREA)
Description
【発明の詳細な説明】 発明の分野 本発明は、日焼け止めとして用いられる化粧料組成物に
関する。Description: FIELD OF THE INVENTION The present invention relates to a cosmetic composition used as a sunscreen.
従来の技術 酸化チタン粉末は、従来より、化粧品用顔料として広く
使用されている。特に、最大粒径０．１μ以下で、平均
粒径０．００５〜０．０７５μｍの微粒子酸化チタン粉
末は、可視光領域では比較的光を透過し、一方紫外線領
域では選択的に光を遮断する効果があるところから、日
焼け止めの化粧料に広く使用されている。しかしなが
ら、かかる微粒子酸化チタンは凝集しやすく、その生成
した二次粒子はわずかながらも可視光線を遮断するた
め、充分に紫外線を遮断すべく大量に化粧料に配合する
と、仕上がりの塗布色が白くなったり、またブルーミン
グをおこしてやや青白くなってしまうなど化粧料として
重大な問題点がある。このため、メークアップ化粧料の
場合には、該微粒子酸化チタンに、通常の酸化チタンお
よび酸化鉄を併用することにより調色を行っている。2. Description of the Related Art Titanium oxide powder has hitherto been widely used as a pigment for cosmetics. In particular, fine titanium oxide powder having a maximum particle size of 0.1 μm or less and an average particle size of 0.005 to 0.075 μm relatively transmits light in the visible light region, while selectively blocking light in the ultraviolet region. Because of its effectiveness, it is widely used in sunscreen cosmetics. However, such fine particles of titanium oxide tend to agglomerate, and the generated secondary particles block visible light though they are a little. Therefore, when a large amount is blended with cosmetics to sufficiently block ultraviolet rays, the finish coating color becomes white. There are also serious problems as cosmetics, such as blooming and a slight bluish tinge. Therefore, in the case of makeup cosmetics, toning is performed by using ordinary titanium oxide and iron oxide in combination with the fine particle titanium oxide.
発明が解決しようとする問題点 しかしながら、かかる微粒子酸化チタンと、通常の酸化
チタンおよび酸化鉄の併用による化粧料組成物では、肌
に対する穏蔽力、カバー力がかなり大きくなり、使用者
が極く薄い化粧を好む人である場合や、男性である場
合、かかる化粧料は好まれない。一方、これを回避する
ため、顔料濃度を低下させると、これに伴い、紫外線遮
断の効果も減少する。また、紫外線遮断効果を補うため
に紫外線吸収剤を使用することも可能であるが、紫外線
吸収剤による皮膚障害の懸念が生ずる。DISCLOSURE OF THE INVENTION Problems to be Solved by the Invention However, in such a cosmetic composition comprising fine particle titanium oxide and ordinary titanium oxide and iron oxide in combination, the pacing power to the skin and the covering power are considerably increased, and the user is extremely limited. Such cosmetics are not preferred if the person prefers light makeup or if he is a man. On the other hand, if the pigment concentration is reduced in order to avoid this, the effect of blocking ultraviolet rays also decreases accordingly. In addition, it is possible to use an ultraviolet absorber to supplement the ultraviolet blocking effect, but there is a concern of skin damage due to the ultraviolet absorber.
問題点を解決するための手段 そこで本発明者らは、紫外線遮断効果に優れた微粒子酸
化チタンを主体とする日焼け止め化粧料において、前記
着色(白色化および青白色化)の生じない化粧料組成物を
得るべく種々検討を行った結果、微粒子酸化チタンに微
粒子酸化鉄を併用することにより前記問題点が解決しう
ることを見出し本発明を完成するに至った。Means for Solving the Problems Therefore, the present inventors, in a sunscreen cosmetic mainly composed of fine particle titanium oxide excellent in ultraviolet blocking effect, the cosmetic composition without the coloring (whitening and bluish white) As a result of various studies to obtain a product, it was found that the above problems can be solved by using fine particle titanium oxide in combination with fine particle titanium oxide, and the present invention has been completed.
すなわち、本発明は、微粒子酸化チタンおよび微粒子酸
化鉄を配合したことを特徴とする化粧料組成物を提供す
るものである。That is, the present invention provides a cosmetic composition containing fine particle titanium oxide and fine particle iron oxide.
本発明の化粧料組成物は、微粒子酸化チタンに対し通常
の粒径の酸化鉄ではなく、微粒子の酸化鉄を併用したと
ころに特徴を有し、これによって、穏蔽力を増大するこ
となく、肌色に近い色に調色が可能となり、塗布時にお
いて微粒子酸化チタンのみの場合よりも微粒子酸化チタ
ンの分散性が向上し、その結果、見掛けの着色力が低下
し、肌への塗布時の透明性が増大する。The cosmetic composition of the present invention is characterized in that fine particle titanium oxide is used in combination with fine particle iron oxide, not iron oxide having a normal particle size, whereby the softening power is not increased. It is possible to adjust to a color close to the skin color, and the dispersibility of fine particle titanium oxide is improved at the time of application compared to the case of using only fine particle titanium oxide, and as a result, the apparent coloring power is reduced and the transparency when applied to the skin is improved. Sex increases.
ここでいう通常の粒径の酸化鉄とは、ベンガラ(短径
０．０６〜１．０μｍ、長径０．１〜４．０μｍの針状
結晶、または０．２〜５．０μｍの粒状結晶)、黄酸化
鉄(短径０．０６〜１．０μｍ、長径０．１〜４．０μ
ｍの針状結晶)、黒酸化鉄(０．１〜１．０μｍの粒状結
晶)を意味する。Iron oxide having a normal particle size as used herein means red iron oxide (acicular crystals with a minor axis of 0.06 to 1.0 μm and major axis of 0.1 to 4.0 μm, or granular crystals of 0.2 to 5.0 μm). , Yellow iron oxide (minor axis 0.06-1.0μm, major axis 0.1-4.0μ
m needle-like crystals) and black iron oxide (0.1-1.0 μm granular crystals).
本発明にて用いられる微粒子酸化チタンとしては、平均
粒径０．００５〜０．０７５μｍの市販のものがいずれ
も用いうる。As the fine particle titanium oxide used in the present invention, any commercially available titanium oxide having an average particle size of 0.005 to 0.075 μm can be used.
また、本発明にて用いられる微粒子酸化鉄としては、短
径０．０１〜０．０５μｍ、長径０．０５〜０．２０μ
ｍの市販の微粒子酸化鉄を用いることができる。かかる
微粒子酸化鉄の具体例としては、透明性ベンガラ(短径
０．０１〜０．０５μｍの針状結晶)、透明性黄酸化鉄
(短径０．０１〜０．０５μｍの針状結晶)、透明性黒酸
化鉄(０．０２〜０．１０μｍ)を挙げることができる。The fine iron oxide particles used in the present invention have a short diameter of 0.01 to 0.05 μm and a long diameter of 0.05 to 0.20 μ.
m commercially available iron oxide fine particles can be used. Specific examples of such fine particle iron oxide include transparent red iron oxide (acicular crystals with a minor axis of 0.01 to 0.05 μm), transparent yellow iron oxide.
(Acicular crystals having a minor axis of 0.01 to 0.05 μm) and transparent black iron oxide (0.02 to 0.10 μm).
つぎに、微粒子酸化チタンおよび微粒子酸化鉄を併用し
た試験日焼止めスティックの塗布色および透明感の評価
結果につき、微粒子酸化鉄を併用しない従来のスティッ
クの場合と比較して第１表に示す。なお、以下において
％とあるは、すべて重量％を意味する。Next, Table 1 shows the evaluation results of the coating color and the transparency of the test sunscreen sticks in which the fine particle titanium oxide and the fine particle iron oxide were used in combination, in comparison with the case of the conventional stick in which the fine particle iron oxide was not used in combination. In the following, "%" means "% by weight".
試験化粧料はつぎの組成および製造方法により得た。The test cosmetic was obtained by the following composition and manufacturing method.
試験日焼止めスティックの組成：成分Ａ 配合量(％) シリコンオイル １５．０ ミリスチン酸イソプロピル １５．０ キャンデリラワックス ４．０ マルチワックス １．５ ステアリン酸 ０．５成分Ｂ 配合量(％) セリカイト ８．０ 微粒子酸化チタン 第１表に記載 微粒子酸化鉄 〃 通常の酸化鉄 〃 タルク 残部 上記成分Ａを８０℃まで加温溶解後、乾式混合した成分
Ｂを成分Ａに投入し、充分に分散した後容器に流し込み
冷却する。Composition of test sunscreen: Component A content (%) Silicon oil 15.0 Isopropyl myristate 15.0 Candelilla wax 4.0 Multi-wax 1.5 Stearic acid 0.5 Component B content (%) Serikite 8.0 Fine Titanium Oxide as shown in Table 1 Fine Iron Oxide 〃 Normal Iron Oxide 〃 Talc Remainder After the above component A was dissolved by heating to 80 ° C, dry mixed component B was added to component A and dispersed well. It is poured into a rear container and cooled.
得られた試験化粧料組成物の透明感に対する評価結果
は、試験スティックを肌に塗布して、１０名のパネラー
により透明感があるか否かを評価したとき、透明感があ
るとするパネラーの数で表した。The evaluation results for the transparency of the obtained test cosmetic composition are as follows: When a test stick is applied to the skin and evaluated by 10 panelists, whether or not there is transparency Expressed in numbers.
第１表より明らかなごとく、微粒子酸化鉄を配合した本
発明のスティックは、従来の微粒子酸化鉄を配合せず微
粒子酸化チタン、あるいはこれと通常の酸化鉄を配合し
たスティックよりはるかに好ましい塗布色および透明感
が得られる。 As is clear from Table 1, the stick of the present invention containing fine particle iron oxide has a coating color much more preferable than the conventional stick containing fine particle titanium oxide without the fine particle iron oxide, or the normal iron oxide. And a transparent feeling is obtained.
微粒子酸化チタンの配合量は、組成物全体に対して３〜
３０％であるのが好ましい。微粒子酸化チタンの配合量
が３％未満の場合は紫外線遮断効果が充分ではなく、一
方、３０％を越えると、ぬり壁様の仕上がりとなり好ま
しくない。The amount of the particulate titanium oxide added is 3 to the total composition.
It is preferably 30%. If the amount of the finely divided titanium oxide is less than 3%, the effect of blocking ultraviolet rays is not sufficient, whereas if it exceeds 30%, a wet wall-like finish is obtained, which is not preferable.
また、微粒子酸化鉄の配合量は、組成物全体に対して
０．２〜１０％であるのが好ましい。配合量が０．２％
未満であると、塗布色が好ましくなく透明感が低い。一
方、１０％を越えると、透明性および色調を整える上で
不都合である。Further, the amount of the fine particle iron oxide compounded is preferably 0.2 to 10% with respect to the entire composition. 0.2%
When it is less than 1, the coating color is not preferable and the transparency is low. On the other hand, if it exceeds 10%, it is inconvenient in adjusting transparency and color tone.
本発明の化粧料組成物としては、例えば日焼け止めクリ
ーム、日焼け止めスティック、口紅のほか頬紅、ケーキ
状または乳液状のファンデーション、白粉、乳液などが
挙げられる。これら化粧料組成物を製造するには、前記
の微粒子酸化チタンおよび微粒子酸化鉄を配合し、それ
ぞれ常法により処理を行って得られる。Examples of the cosmetic composition of the present invention include sunscreen creams, sunscreen sticks, lipsticks, blushers, cake-like or emulsion foundations, white powders, and emulsions. In order to produce these cosmetic compositions, the above-mentioned fine particle titanium oxide and fine particle iron oxide are blended and treated by a conventional method.
実施例 以下に本発明を実施例にもとづき、さらに詳しく説明す
る。EXAMPLES The present invention will be described in more detail based on examples given below.
実施例１ つぎの組成により、日焼止めクリームを製造した。成分Ａ 配合量(％) 流動パラフィン ４．２ モノステアリン酸グリセリン ２．０ ステアリン酸 ３．０ ラノリン ２．０ 固型パラフィン ０．５成分Ｂ 配合量(％) 精製水 ５７．６ トリエタノールアミン １．０ カルボキシメチルセルロースナトリウム ０．２ ベントナイト ０．５ モノステアリン酸ポリオキシ １．５ エチレンソルビタン プロピレングリコール ７．５成分Ｃ 配合量(％) 微粒子酸化チタン(平均粒径０．０１μｍ) １０．０ 微粒子酸化鉄 黄 ２．０ (平均粒径 短径0.02μｍ、長径0.06μｍ) 〃 赤 ０．７ 〃 黒 ０．３ タルク ７．０ 上記成分Ａおよび成分Ｂを別々の容器で８０℃まで加温
溶解後、成分Ｂを成分Ａに投入し、撹拌し、これに更に
成分Ｃを投入して充分に分散した後冷却する。Example 1 A sunscreen cream was prepared according to the following composition. Component A content (%) Liquid paraffin 4.2 Glycerin monostearate 2.0 Stearic acid 3.0 Lanolin 2.0 Solid paraffin 0.5 Component B content (%) Purified water 57.6 Triethanolamine 1 0.0 Sodium carboxymethyl cellulose 0.2 Bentonite 0.5 Polyoxymonostearate 1.5 Ethylenesorbitan Propylene glycol 7.5 Component C Blending amount (%) Fine particle titanium oxide (average particle diameter 0.01 μm) 10.0 Fine particle iron oxide Yellow 2.0 (average particle size: minor axis 0.02 μm, major axis 0.06 μm) 〃 red 0.7 〃 black 0.3 talc 7.0 After the above components A and B are dissolved by heating to 80 ° C in separate containers, The component B is added to the component A and stirred, and the component C is further added to the component A to sufficiently disperse the mixture, followed by cooling.
得られた日焼け止めクリームは、肌に塗布したとき、透
明感のある肌色を呈し、全身に使っても、また、男性が
使っても違和感のない仕上がりが得られる。When the sunscreen cream thus obtained is applied to the skin, it gives a transparent flesh-colored skin, and a finish that does not feel uncomfortable when used on the whole body or when used by men.
実施例２ つぎの組成により、日焼け止めリップクリームを製造し
た。成分Ａ 配合量(％) ヒマシ油 ４０．７ ヘキサデシルアルコール ２１．３ ラノリン ３．５ ミツロウ ３．０ オゾケライト ４．０ カルナウバロウ ５．５ 成分Ｂ 配合量(％) 微粒子酸化チタン ２０．０ 微粒子酸化鉄 黄 ０．４５ 〃 赤 １．５０ 〃 黒 ０．０５ 成分Ａを８０℃にて加熱溶解し、これに乾式混合した成
分Ｂを添加して充分に撹拌し、容器に流し込み成型す
る。Example 2 A sunscreen lip balm was produced with the following composition. Ingredient A content (%) Castor oil 40.7 Hexadecyl alcohol 21.3 Lanolin 3.5 Beeswax 3.0 Ozokerite 4.0 Carnauba wax 5.5 Component B content (%) Fine particle titanium oxide 20.0 Fine particle iron oxide Yellow 0.45〃 Red 1.50〃 Black 0.05 Ingredient A is heated and dissolved at 80 ° C, dry blended Ingredient B is added, stirred sufficiently, and poured into a container for molding.
得られた日焼止めリップクリームは、唇に塗布した場
合、従来品のようにまっ白にならず、ごくうすい赤色で
男性がつけても不自然さを感じさせない。When applied to the lips, the obtained sunscreen lip balm does not become white like the conventional product, and is a very light red color that does not feel unnatural when applied by a man.
発明の効果 本発明の化粧料組成物によれば、微粒子酸化チタンと微
粒子酸化鉄との併用により透明性が高くかつ、充分な紫
外線遮断効果をもつ化粧料が得られる。また、さらに微
粒子酸化鉄自体が通常の粒径のものに比べ紫外線の選択
的な遮断性を有し、化粧料組成物の紫外線遮断性を増加
させる。EFFECTS OF THE INVENTION According to the cosmetic composition of the present invention, a cosmetic having high transparency and a sufficient UV blocking effect can be obtained by using fine particle titanium oxide and fine particle iron oxide in combination. Further, the fine particle iron oxide itself has a selective blocking property of ultraviolet rays as compared with a particle having a normal particle size, thereby increasing the ultraviolet blocking property of the cosmetic composition.
───────────────────────────────────────────────────── フロントページの続き (56)参考文献 特開 昭57−120514（ＪＰ，Ａ) 特開 昭59−62517（ＪＰ，Ａ) 特公 昭47−42502（ＪＰ，Ｂ１) 「周知−慣用技術集（化粧料及び類似 品）」（昭和59−８−21） 特許庁 第35 頁 ─────────────────────────────────────────────────── --Continued from the front page (56) References JP-A-57-120514 (JP, A) JP-A-59-62517 (JP, A) JP-B-47-42502 (JP, B1) "well-known technology" (Cosmetics and similar products) ”(Showa 59-8-21) JPO page 35
Claims (1)
３〜３０重量％および微粒子酸化鉄０．２〜１０重量％
を配合したことを特徴とする化粧料組成物。1. Fine particle titanium oxide 3 to 30% by weight and fine particle iron oxide 0.2 to 10% by weight based on the total weight of the composition.
A cosmetic composition comprising:
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP60207493A JPH0621057B2 (en) | 1985-09-18 | 1985-09-18 | Cosmetic composition |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP60207493A JPH0621057B2 (en) | 1985-09-18 | 1985-09-18 | Cosmetic composition |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS6267014A JPS6267014A (en) | 1987-03-26 |
| JPH0621057B2 true JPH0621057B2 (en) | 1994-03-23 |
Family
ID=16540634
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP60207493A Expired - Fee Related JPH0621057B2 (en) | 1985-09-18 | 1985-09-18 | Cosmetic composition |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH0621057B2 (en) |
Families Citing this family (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH0674204B2 (en) * | 1987-04-28 | 1994-09-21 | 鐘紡株式会社 | Sunscreen cosmetics |
| JPH0676307B2 (en) * | 1987-09-07 | 1994-09-28 | 鐘紡株式会社 | Sunscreen cosmetics |
| JP2656773B2 (en) * | 1987-09-16 | 1997-09-24 | ポーラ化成工業株式会社 | Cosmetics |
| JP2915454B2 (en) * | 1989-11-30 | 1999-07-05 | 株式会社資生堂 | Photochromic skin color pigment and method for producing the same |
| JP3053667B2 (en) * | 1991-06-10 | 2000-06-19 | 株式会社資生堂 | Photochromic ultraviolet shielding powder, method for producing the same, and external preparation for skin |
| ES2224104T3 (en) * | 1993-12-13 | 2005-03-01 | Ishihara Sangyo Kaisha, Ltd. | ULTRAFIN PARTICLES OF TITANIUM DIOXIDE TYPE RUTILO CONTAINING IRON AND PROCEDURE FOR PREPARATION. |
| US5837050A (en) * | 1995-08-11 | 1998-11-17 | Ishihara Sangyo Kaisha, Ltd. | Ultrafine iron-containing rutile titanium oxide and process for producing the same |
| US20100061947A1 (en) * | 2006-11-17 | 2010-03-11 | David Schlossman | Uv protective cosmetic product incorporating titanium dioxide and transparent iron oxide |
| ES2359184T3 (en) * | 2008-07-01 | 2011-05-19 | THE PROCTER & GAMBLE COMPANY | PROCEDURE TO REDUCE THE SKIN OR SKIN ASPECT. |
| EP2140855A1 (en) * | 2008-07-01 | 2010-01-06 | The Procter and Gamble Company | Cosmetic Composition |
| EP2140854A1 (en) * | 2008-07-01 | 2010-01-06 | The Procter & Gamble | Cosmetic Composition |
Family Cites Families (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5119974B2 (en) * | 1972-09-11 | 1976-06-22 | ||
| JPS57120514A (en) * | 1981-01-20 | 1982-07-27 | Pola Chem Ind Inc | Cosmetic having ultraviolet light shielding effect |
| JPS57200230A (en) * | 1981-06-05 | 1982-12-08 | Mitsubishi Metal Corp | Ultra-fine powder of black ferrosoferric oxide and its preparation |
| JPS5849307A (en) * | 1981-09-16 | 1983-03-23 | Pola Chem Ind Inc | Cosmetic |
| JPS5962517A (en) * | 1982-10-04 | 1984-04-10 | Shiseido Co Ltd | Anti-suntan cosmetic |
-
1985
- 1985-09-18 JP JP60207493A patent/JPH0621057B2/en not_active Expired - Fee Related
Non-Patent Citations (1)
| Title |
|---|
| 「周知−慣用技術集（化粧料及び類似品）」（昭和５９−８−２１）特許庁第３５頁 |
Also Published As
| Publication number | Publication date |
|---|---|
| JPS6267014A (en) | 1987-03-26 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
| LAPS | Cancellation because of no payment of annual fees |