JPH0623699B2 - Liquid metal purity monitor - Google Patents
Liquid metal purity monitorInfo
- Publication number
- JPH0623699B2 JPH0623699B2 JP62129097A JP12909787A JPH0623699B2 JP H0623699 B2 JPH0623699 B2 JP H0623699B2 JP 62129097 A JP62129097 A JP 62129097A JP 12909787 A JP12909787 A JP 12909787A JP H0623699 B2 JPH0623699 B2 JP H0623699B2
- Authority
- JP
- Japan
- Prior art keywords
- liquid metal
- temperature
- impurities
- sodium
- orifices
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 229910001338 liquidmetal Inorganic materials 0.000 title claims description 15
- 238000011010 flushing procedure Methods 0.000 claims description 11
- 238000001816 cooling Methods 0.000 claims description 7
- 238000012544 monitoring process Methods 0.000 claims description 6
- 239000012535 impurity Substances 0.000 description 23
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 21
- 239000011734 sodium Substances 0.000 description 21
- 229910052708 sodium Inorganic materials 0.000 description 21
- 238000005259 measurement Methods 0.000 description 15
- 239000007788 liquid Substances 0.000 description 11
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 7
- 239000001257 hydrogen Substances 0.000 description 7
- 229910052739 hydrogen Inorganic materials 0.000 description 7
- 239000001301 oxygen Substances 0.000 description 7
- 229910052760 oxygen Inorganic materials 0.000 description 7
- 239000000112 cooling gas Substances 0.000 description 6
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 5
- 230000008021 deposition Effects 0.000 description 5
- 230000000694 effects Effects 0.000 description 5
- 238000004090 dissolution Methods 0.000 description 4
- 238000012806 monitoring device Methods 0.000 description 4
- 238000001556 precipitation Methods 0.000 description 4
- 230000002411 adverse Effects 0.000 description 2
- 239000002826 coolant Substances 0.000 description 2
- 150000002431 hydrogen Chemical class 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 238000007796 conventional method Methods 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 239000002244 precipitate Substances 0.000 description 1
Landscapes
- Investigating Or Analyzing Materials Using Thermal Means (AREA)
Description
【発明の詳細な説明】 [産業上の利用分野] 本発明は、液体ナトリウム等の純度をオンラインで監視
できるプラギング計方式の純度監視装置に関し、更に詳
しくは、液体金属の流路中に設けられる複数のオリフィ
ス部と液体金属流入部との間をそれぞれ延長管で連結
し、各延長管にそれぞれ独立に作動可能なフラッシング
用の電気ヒータを取り付けた液体金属の純度監視装置に
関するものである。TECHNICAL FIELD The present invention relates to a plugging meter type purity monitoring device capable of monitoring the purity of liquid sodium or the like online, and more specifically, it is provided in a liquid metal channel. The present invention relates to a liquid metal purity monitoring apparatus in which a plurality of orifices and a liquid metal inflow portion are connected by extension pipes, and each extension pipe is equipped with an electric heater for flushing that can operate independently.
[従来の技術] 液体ナトリウムの純度をオンラインで監視する装置とし
てプラギング計が実用化されている。これは液体ナトリ
ウム中の不純物がその飽和温度以下の温度条件で析出す
るという性質を利用したもので、ナトリウムを冷却する
ことにより不純物をオリフィス部で析出させ、この時の
流量変化から飽和温度を測定し、予め用意されている不
純物溶解度とナトリウム温度との関係から間接的にナト
リウム中不純物の濃度を測定するものである。[Prior Art] A plugging meter has been put into practical use as an apparatus for monitoring the purity of liquid sodium online. This utilizes the property that impurities in liquid sodium precipitate under temperature conditions below the saturation temperature.By cooling sodium, impurities are precipitated at the orifice, and the saturation temperature is measured from the change in the flow rate at this time. However, the concentration of impurities in sodium is indirectly measured from the relationship between the solubility of impurities and the temperature of sodium prepared in advance.
第3図に従来のプラギング計の一例を示す。液体ナトリ
ウムの流路中に複数のオリフィス部12を設け(第4図
参照)、その外側に冷却部14を設けた構造を有する。FIG. 3 shows an example of a conventional plugging meter. It has a structure in which a plurality of orifice portions 12 are provided in the flow path of liquid sodium (see FIG. 4) and a cooling portion 14 is provided outside thereof.
ナトリウム流入部10へ入ってきた液体ナトリウムを、
冷却ガス入口配管16から冷却ガス出口配管18へと流
れる冷却ガスにより冷却し、これによって不純物がオリ
フィス部12に析出してナトリウムの流量変化が生じる
ように設計されている。オリフィス部12は、通常、数
個ないし数十個形成されている。The liquid sodium that has entered the sodium inflow section 10 is
It is designed to be cooled by the cooling gas flowing from the cooling gas inlet pipe 16 to the cooling gas outlet pipe 18, whereby impurities are deposited on the orifice portion 12 and the flow rate of sodium changes. Normally, several to several tens of orifice portions 12 are formed.
プラギング計による測定の概略を第5図に示す。測定開
始時Aでオリフィス部の温度を下げ始める。やがて飽和
温度以下になるとオリフィス部への不純物析出が始まる
(流量降下開始時B)。流量が予め設定した規定値(一
般には90〜80%程度)に下がると温度を上昇させる
制御信号が出る(温度降下から上昇への反転時C)。し
かし温度が飽和温度に回復するまでは流量減少が続く。
やがて飽和温度に達すると流量は増加に転ずる(流量上
昇開始時D)。流量が規定値以下のため温度は更に上昇
する。The outline of the measurement by the plugging meter is shown in FIG. At the start of measurement A, the temperature of the orifice begins to drop. Eventually, when the temperature becomes lower than the saturation temperature, the precipitation of impurities on the orifice portion starts (at the time of starting the flow rate decrease B). When the flow rate falls to a preset specified value (generally about 90 to 80%), a control signal for raising the temperature is issued (at the time of reversal C from temperature drop to rise). However, the flow rate continues to decrease until the temperature recovers to the saturation temperature.
When the saturation temperature is reached, the flow rate starts to increase (at the start of flow rate increase D). The temperature rises further because the flow rate is below the specified value.
ここでBとDの時の温度を読みプラギング温度とする。
しかし実際には流量降下開始(析出開始)時Bと流量上
昇開始(溶解開始)時Dの飽和温度には差があり、両者
の平均値をプラギング温度ということが多い。Here, the temperatures at B and D are read and set as plugging temperatures.
However, in reality, there is a difference between the saturation temperature at the start B of the flow rate decrease (start of precipitation) and the saturation temperature at the start of the flow rate increase (dissolution start), and the average value of both is often called the plugging temperature.
[発明が解決しようとする問題点] 不純物の飽和温度と析出速度および一旦析出したものが
再び溶解する速度は不純物の種類によって異なる。高速
炉冷却材としてのナトリウム純度管理上重要な酸素およ
び水素不純物に関しては、析出・溶解速度が明らかにさ
れており、酸素が約20分、水素が約20秒程度であ
る。[Problems to be Solved by the Invention] The saturation temperature and deposition rate of impurities and the rate at which once deposited materials are dissolved again depend on the type of impurities. Regarding the oxygen and hydrogen impurities, which are important in controlling the purity of sodium as a fast reactor coolant, the precipitation and dissolution rates have been clarified, and oxygen is about 20 minutes and hydrogen is about 20 seconds.
ところが原子炉の運転を開始し冷却材ナトリウムの温度
が高くなると、酸素や水素以外の不純物(種類が同定さ
れていないところから第3の不純物といわれている)が
ナトリウム中に溶出してくる。この第3の不純物は飽和
温度が高く(酸素や水素の飽和温度が150℃程度の時
に約200℃位と考えられている)且つ析出・溶解速度
も遅い(約25時間位)。However, when the operation of the nuclear reactor is started and the temperature of the coolant sodium rises, impurities other than oxygen and hydrogen (which are said to be the third impurities because the type has not been identified) elute into the sodium. The third impurity has a high saturation temperature (it is considered to be about 200 ° C. when the saturation temperature of oxygen or hydrogen is about 150 ° C.) and the deposition / dissolution rate is slow (about 25 hours).
このため第3の不純物はプラギング計のオリフィス部に
ゆっくりと析出し、酸素や水素を対象にした制御系では
制御できず指示が不安定になり、測定精度が低下する欠
点があった。For this reason, the third impurity slowly deposits in the orifice of the plugging meter, cannot be controlled by the control system for oxygen and hydrogen, and the indication becomes unstable, resulting in a decrease in measurement accuracy.
そこでオリフィス部に析出した第3の不純物を取り除く
ため、適宜手動フラッシング操作を行う必要があり、操
作が煩雑であるばかりでなく、フラッシングのために測
定が中断される等の欠点があった。Therefore, in order to remove the third impurities deposited on the orifice portion, it is necessary to perform a manual flushing operation as appropriate, which not only complicates the operation but also has a drawback that the measurement is interrupted due to the flushing.
本発明の目的は、上記のような従来技術の欠点を解消
し、析出した第3の不純物を取り除くための手動フラッ
シング操作が不要で省力化を図ることができると共に、
プラギング温度の測定を中断する必要がなく、液体金属
の温度が上昇しても指示が不安定にならず測定精度を向
上させることができるような純度監視装置を提供するこ
とにある。An object of the present invention is to solve the above-mentioned drawbacks of the conventional technology, to eliminate the need for a manual flushing operation for removing the deposited third impurities, and to save labor.
It is an object of the present invention to provide a purity monitoring device that does not need to interrupt the measurement of the plugging temperature and that does not make the indication unstable even if the temperature of the liquid metal rises and can improve the measurement accuracy.
[問題点を解決するための手段] 上記のような目的を達成することのできる本発明は、液
体金属の流路中に設けられる複数のオリフィス部と、流
通する液体金属のための冷却部とを備えた装置におい
て、前記各オリフィス部と液体金属流入部との間をそれ
ぞれ延長管で連結し、該延長管にそれぞれ独立に作動制
御可能なフラッシング用の電気ヒータを取り付けた構成
の液体金属用の純度監視装置である。[Means for Solving the Problems] The present invention that can achieve the above-described object is to provide a plurality of orifice portions provided in a liquid metal flow path, and a cooling portion for flowing liquid metal. In a device comprising: a liquid metal having a configuration in which each of the orifices and the liquid metal inflow portion are connected by an extension pipe, and an electric heater for flushing that can independently control the operation is attached to the extension pipe. Is a purity monitoring device.
各電気ヒータは、その通電時間や通電間隔をタイマー等
により自動的にコントロールできるようにするのが望ま
しい。It is desirable that each electric heater can automatically control the energization time and the energization interval by a timer or the like.
[作用] 延長管に取り付けられている各電気ヒータへの通電時間
および間隔をそれぞれ独立に制御することにより、多数
のオリフィス部を一個ずつ順次フラッシングすれば他の
オリフィス部により測定しながら不純物を取り除くこと
ができる。これにより純度管理上は特に問題としなくて
よいが、析出するまでに長時間を要し且つプラギング温
度の高い不純物がオリフィス部へ析出し、純度管理上、
監視が必要なプラギング温度が低く析出速度の速い酸素
や水素の測定に与える悪影響を除去して安定した測定が
可能となる。[Operation] By independently controlling the energization time and interval of each electric heater attached to the extension pipe, if a large number of orifices are sequentially flushed one by one, impurities are removed while measuring with other orifices. be able to. Therefore, it does not have to be a problem in terms of purity control, but it takes a long time to deposit and impurities with a high plugging temperature are deposited in the orifice portion.
Stable measurement is possible by eliminating the adverse effect on the measurement of oxygen and hydrogen, which require low monitoring of plugging temperature and high deposition rate.
[実施例] 第1図は本発明によるナトリウム純度監視装置の一実施
例を示す説明図である。液体ナトリウムの流路中に設け
られる多数のオリフィス部12と液体ナトリウム流入部
10との間がそれぞれ延長管20で連結され、各延長管
20の外側に電気ヒータ22が巻き付けられている(第
2図参照)。これらの各電気ヒータ22はタイマー等を
介して電源と接続され、それぞれ独立に作動制御可能に
なっている。液体ナトリウム流入部10の外側には冷却
部14が設けられ、冷却ガス入口配管16と冷却ガス出
口配管18が接続されている。[Embodiment] FIG. 1 is an explanatory view showing an embodiment of the sodium purity monitoring apparatus according to the present invention. A large number of orifices 12 provided in the liquid sodium flow path and the liquid sodium inflow portion 10 are connected by extension pipes 20, and an electric heater 22 is wound around each extension pipe 20 (second). See figure). Each of these electric heaters 22 is connected to a power source via a timer or the like, and can be independently operated and controlled. A cooling unit 14 is provided outside the liquid sodium inflow unit 10, and a cooling gas inlet pipe 16 and a cooling gas outlet pipe 18 are connected to each other.
本装置の使用方法は次の通りである。基本的な測定手順
は従前の場合と同様である。測定開始時に冷却ガスによ
って液体ナトリウムを冷却する。やがて飽和温度以下に
なるとオリフィス部への不純物析出が始まる。流量が予
め設定した規定値に下がると冷却を停止し温度を上昇さ
せる。しかし温度が飽和温度に回復するまでは流量減少
が続く。やがて飽和温度に達すると流量は増加に転ず
る。The method of using this device is as follows. The basic measurement procedure is the same as before. Liquid sodium is cooled by a cooling gas at the start of measurement. When the temperature reaches the saturation temperature or lower, impurity deposition on the orifice begins. When the flow rate falls to a preset specified value, cooling is stopped and the temperature is raised. However, the flow rate continues to decrease until the temperature recovers to the saturation temperature. When the saturation temperature is reached, the flow rate starts to increase.
ここで析出開始時と溶解開始時の飽和温度の平均値をプ
ラギング温度とし、ナトリウム中不純物の濃度を求め
る。Here, the average value of the saturation temperatures at the start of precipitation and at the start of dissolution is taken as the plugging temperature, and the concentration of impurities in sodium is determined.
本発明では、延長管20の電気ヒータ22への通電時間
および通電間隔をタイマー等によりコントロールする。
これにより多数のオリフィス部12を一個ずつ順次フラ
ッシングし、他のオリフィス部で測定している間、その
オリフィス部に付着している第3の不純物を取り除くこ
とができる。In the present invention, the energization time and the energization interval of the electric heater 22 of the extension tube 20 are controlled by a timer or the like.
As a result, a large number of orifices 12 can be sequentially flushed one by one, and the third impurities adhering to the orifices can be removed while the other orifices are being measured.
このようにして析出・溶解するまでに長時間を要し且つ
プラギング温度の高い第3の不純物による悪影響を除去
し、プラギング温度が低く析出速度の速い酸素や水素に
ついての安定した測定が可能になる。従って不純物を取
り除くための手動フラッシング操作が不要となるし、測
定をその都度中断する必要もなくなる。In this way, it takes a long time to precipitate / dissolve and removes the adverse effect of the third impurity having a high plugging temperature, and enables stable measurement of oxygen and hydrogen having a low plugging temperature and a high deposition rate. . Therefore, a manual flushing operation for removing impurities is unnecessary, and it is not necessary to interrupt the measurement each time.
[発明の効果] 本発明は上記のように各オリフィス部と液体金属流入部
との間をそれぞれ延長管で連結し、それに独立に制御可
能なフラッシング用の電気ヒータを取り付けた構成だか
ら、オリフィス部を自動的に順次フラッシングできるた
め煩雑な手動フラッシング操作が不要となり省力化でき
る効果がある。EFFECTS OF THE INVENTION Since the present invention has a configuration in which each orifice portion and the liquid metal inflow portion are connected by an extension pipe as described above, and an independently controllable electric heater for flushing is attached to the extension pipe, the orifice portion is provided. Since it is possible to automatically perform sequential flushing, there is an effect that laborious manual flushing operation is unnecessary and labor can be saved.
また本発明では、析出するまでに長時間を要し且つプラ
ギング温度の高い第3の不純物の影響が除去され安定し
た測定が可能となるし、更にはフラッシングのために測
定が中断されることもない等の優れた効果を有する。Further, in the present invention, it takes a long time to precipitate and the influence of the third impurity having a high plugging temperature is removed, and stable measurement is possible, and further, the measurement may be interrupted due to flushing. It has an excellent effect such as no.
第1図は本発明に係る液体ナトリウムの純度監視装置の
一実施例を示す説明図、第2図はその延長管とそれに取
り付けた電気ヒータとを示す斜視図、第3図は従来技術
の一例を示す説明図、第4図はそのオリフィス部の配列
状態を示す平面図、第5図はプラギング計による測定の
概要を示す説明図である。 10……液体ナトリウム流入部、12……オリフィス
部、14……冷却部、20……延長管、22……電気ヒ
ータ。FIG. 1 is an explanatory view showing an embodiment of a liquid sodium purity monitoring device according to the present invention, FIG. 2 is a perspective view showing an extension pipe thereof and an electric heater attached thereto, and FIG. 3 is an example of a conventional technique. FIG. 4 is a plan view showing the arrangement of the orifices, and FIG. 5 is an explanatory view showing the outline of measurement by a plugging meter. 10 ... Liquid sodium inflow part, 12 ... Orifice part, 14 ... Cooling part, 20 ... Extension tube, 22 ... Electric heater.
Claims (1)
フィス部と、流通する液体金属のための冷却部とを備え
た装置において、前記各オリフィス部と液体金属流入部
との間をそれぞれ延長管で連結し、該延長管にそれぞれ
独立に作動制御可能なフラッシング用の電気ヒータを取
り付けたことを特徴とする液体金属の純度監視装置。1. An apparatus comprising a plurality of orifices provided in a liquid metal flow path and a cooling unit for circulating liquid metal, wherein each of the orifices and the liquid metal inflow unit is provided between the orifice unit and the liquid metal inflow unit. A liquid metal purity monitoring apparatus, characterized in that the heaters are connected by extension pipes, and each of the extension pipes is provided with an electric heater for flushing that can be independently controlled in operation.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP62129097A JPH0623699B2 (en) | 1987-05-26 | 1987-05-26 | Liquid metal purity monitor |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP62129097A JPH0623699B2 (en) | 1987-05-26 | 1987-05-26 | Liquid metal purity monitor |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS63292044A JPS63292044A (en) | 1988-11-29 |
| JPH0623699B2 true JPH0623699B2 (en) | 1994-03-30 |
Family
ID=15001000
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP62129097A Expired - Lifetime JPH0623699B2 (en) | 1987-05-26 | 1987-05-26 | Liquid metal purity monitor |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH0623699B2 (en) |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH0754285B2 (en) * | 1989-02-04 | 1995-06-07 | 動力炉・核燃料開発事業団 | Sampling method and apparatus for precipitated impurities in liquid sodium |
Family Cites Families (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS4327114Y1 (en) * | 1965-01-20 | 1968-11-09 | ||
| JPS533276A (en) * | 1976-06-29 | 1978-01-12 | Mitsubishi Electric Corp | Pulse detecting apparatus |
-
1987
- 1987-05-26 JP JP62129097A patent/JPH0623699B2/en not_active Expired - Lifetime
Also Published As
| Publication number | Publication date |
|---|---|
| JPS63292044A (en) | 1988-11-29 |
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