Deprecated: The each() function is deprecated. This message will be suppressed on further calls in /home/zhenxiangba/zhenxiangba.com/public_html/phproxy-improved-master/index.php on line 456
JPH0649134B2 - Exhaust gas treatment device - Google Patents
[go: Go Back, main page]

JPH0649134B2 - Exhaust gas treatment device - Google Patents

Exhaust gas treatment device

Info

Publication number
JPH0649134B2
JPH0649134B2 JP59230313A JP23031384A JPH0649134B2 JP H0649134 B2 JPH0649134 B2 JP H0649134B2 JP 59230313 A JP59230313 A JP 59230313A JP 23031384 A JP23031384 A JP 23031384A JP H0649134 B2 JPH0649134 B2 JP H0649134B2
Authority
JP
Japan
Prior art keywords
filter medium
exhaust gas
layer
present
gas treatment
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
JP59230313A
Other languages
Japanese (ja)
Other versions
JPS61111128A (en
Inventor
光弘 洞口
裕二 貝原
成元 富澤
往男 飯田
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Mitsubishi Heavy Industries Ltd
Original Assignee
Mitsubishi Heavy Industries Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Mitsubishi Heavy Industries Ltd filed Critical Mitsubishi Heavy Industries Ltd
Priority to JP59230313A priority Critical patent/JPH0649134B2/en
Priority to EP86730067A priority patent/EP0242488B1/en
Priority claimed from EP86730067A external-priority patent/EP0242488B1/en
Priority to US06/854,936 priority patent/US4728503A/en
Publication of JPS61111128A publication Critical patent/JPS61111128A/en
Publication of JPH0649134B2 publication Critical patent/JPH0649134B2/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02ATECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
    • Y02A50/00TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE in human health protection, e.g. against extreme weather
    • Y02A50/20Air quality improvement or preservation, e.g. vehicle emission control or emission reduction by using catalytic converters

Landscapes

  • Treating Waste Gases (AREA)
  • Exhaust Gas Treatment By Means Of Catalyst (AREA)

Description

【発明の詳細な説明】 〔産業上の利用分野〕 本発明は、排ガス処理装置に関し、特に都市ごみ焼却プ
ラント等から大量に排出される焼却飛灰,塩化水素,窒
素酸化物,硫黄酸化物を含むガスを効果的に処理する装
置に関する。
TECHNICAL FIELD The present invention relates to an exhaust gas treatment apparatus, and particularly to incinerator fly ash, hydrogen chloride, nitrogen oxides, and sulfur oxides that are discharged in large quantities from municipal solid waste incineration plants and the like. The present invention relates to a device for effectively treating a gas containing the same.

〔従来の技術〕[Conventional technology]

本発明者らは、先に塩化水素除去を高める為に織布ろ布
に消石灰及び塩化カルシウムの固形物層を形成させる技
術を開発した。
The present inventors have previously developed a technique for forming a solid layer of slaked lime and calcium chloride on a woven filter cloth in order to enhance the removal of hydrogen chloride.

ここで使用しているろ布は、グラスウール材であり、耐
熱性に劣るため、通気ガスの温度を250℃以下に維持
する必要がある。
Since the filter cloth used here is a glass wool material and has poor heat resistance, it is necessary to maintain the temperature of the ventilation gas at 250 ° C. or lower.

耐熱性のあるろ過材料としては、炭素繊維の織布ろ材や
ステンレス鋼製の織りろ材等がある。
Examples of heat-resistant filtering materials include woven carbon fiber filter media and woven stainless steel filter media.

〔発明が解決しようとする問題点〕[Problems to be solved by the invention]

上記炭素繊維の織布ろ材は摩擦に弱く、ステンレス鋼製
の織りろ材は価格が非常に高い等の難点がある。
The above-mentioned carbon fiber woven filter medium is vulnerable to friction, and the stainless steel woven filter medium is very expensive.

また、本発明では、塩化水素除去機能の他に、窒素酸化
物除去(すなわち脱硝)機能をも併合させようとするも
のであるが、脱硝機能を維持する為の脱硝触媒を上記ス
テンレス鋼製織りろ材に保持させることは困難である。
すなわち、該ろ材表面に脱硝触媒をコーテイングするに
は、コーテイング材(脱硝触媒)とろ材表面が十分に濡
れることが必要であるが、ステンレス鋼製のろ材は濡れ
性が悪く、均一なコーテイング層を形成することが困難
である。
Further, in the present invention, in addition to the function of removing hydrogen chloride, it is also intended to combine the function of removing nitrogen oxides (that is, denitration). However, the denitration catalyst for maintaining the denitration function is made of the above-mentioned stainless steel weave. It is difficult to hold it on the filter medium.
That is, in order to coat a denitration catalyst on the surface of the filter medium, it is necessary that the coating material (denitration catalyst) and the surface of the filter medium are sufficiently wet. Difficult to form.

本発明は、以上の問題点を解決し、ろ材の耐熱性を低コ
ストで向上させ、かつ塩化水素除去機能と窒素酸化物除
去機能を併せ持つ排ガス処理装置を提供しようとするも
のである。
The present invention is intended to solve the above problems, to improve the heat resistance of a filter medium at low cost, and to provide an exhaust gas treatment device having both a hydrogen chloride removing function and a nitrogen oxide removing function.

〔問題点を解決するための手段〕[Means for solving problems]

本発明者らは、上記問題点を解決するために鋭意研究の
結果、ろ材として多孔質セラミツクを用いれば、耐熱性
が向上するのみならず、触媒との濡れ性にも優れ、更に
は集塵効果、逆洗空気によるろ材表面の清浄化効果をも
奏することができ、好適な排ガス処理装置を提供し得る
との知見を得て本発明を提案するに至つた。
The inventors of the present invention have conducted extensive studies to solve the above problems, and when a porous ceramic is used as a filter medium, not only the heat resistance is improved, but also the wettability with a catalyst is excellent, and further dust collection is performed. The present invention has been proposed on the basis of the finding that the effect and the effect of cleaning the surface of the filter medium by the backwash air can be obtained and a suitable exhaust gas treatment device can be provided.

すなわち本発明は、ろ材として多孔質セラミツク材によ
る内筒・外筒の二重筒構造としたものを用い、少くとも
内筒ろ材表面に窒素酸化物除去用触媒層を設け、外筒ろ
材表面に特殊反応助剤プリコート層を介して消石灰又は
炭酸カルシウム及び塩化カルシウムを含む固形物層を形
成したことを特徴とする排ガス処理装置に関するもので
ある。
That is, the present invention uses a double-cylinder structure of an inner cylinder and an outer cylinder made of a porous ceramic material as the filter medium, and at least a catalyst layer for removing nitrogen oxides is provided on the surface of the inner cylinder filter medium, and the outer cylinder filter medium surface is provided. The present invention relates to an exhaust gas treating apparatus, wherein a solid matter layer containing slaked lime or calcium carbonate and calcium chloride is formed via a special reaction aid precoat layer.

第1図は本発明装置の一実施態様例を示す概要図、第2
図は第1図の一部拡大概要図である。
FIG. 1 is a schematic diagram showing an embodiment of the device of the present invention, FIG.
The figure is a partially enlarged schematic view of FIG.

第1,2図に示すように、本発明に係るろ材は、多孔質
セラミツク(例えば、ムライト,高純度アルミナ等)製
の外筒1と内筒2からなる2重円筒構造で、少なくとも
内筒ろ材表面(ここでは、内筒2のガス流入側と流出側
の2面及び外筒1のガス流出側の面)に脱硝触媒(例え
ば、五酸化バナジウムと酸化チタンの混合物)層5が、
例えばろ材表面の焼結作業を経て形成される。上記外筒
1のガス流入側には、ろ材の目詰を防ぐために特殊反応
助剤プリコート層5が設けられ、その上に消石灰又は炭
酸カルシウム(以下消石灰という)と塩化カルシウムを
含む固形物層4が形成される。なお、図中の矢印はガス
の流れ方向を示す。
As shown in FIGS. 1 and 2, a filter medium according to the present invention has a double cylindrical structure composed of an outer cylinder 1 and an inner cylinder 2 made of a porous ceramic (for example, mullite, high-purity alumina, etc.), and at least the inner cylinder A denitration catalyst (for example, a mixture of vanadium pentoxide and titanium oxide) layer 5 is formed on the surface of the filter medium (here, the two surfaces of the inner cylinder 2 on the gas inflow side and the outflow side and the surface of the outer cylinder 1 on the gas outflow side).
For example, it is formed through a sintering operation on the surface of the filter medium. A special reaction aid precoat layer 5 is provided on the gas inflow side of the outer cylinder 1 to prevent clogging of the filter medium, and a solid layer 4 containing slaked lime or calcium carbonate (hereinafter referred to as slaked lime) and calcium chloride is provided thereon. Is formed. In addition, the arrow in a figure shows the flow direction of gas.

本発明における特殊反応助剤としては、かさ密度が小
さい、通気性がよい、吸気してもベトつかない、
1〜100μ粒径、好ましくは10〜50μ粒径のもの
が適当で、例えば、ゼオライト,アルミナ,ケイソウ
土,パーライト,活性白土,カオリン,長石,石英等の
粉末の中から選ばれ、1種もしくは2種以上の混合粉末
として使用する。この粉体の中でも好適なものとしては
ゼオライト,ケイソウ土,パーライトがあげられる。
As the special reaction aid in the present invention, the bulk density is small, the air permeability is good, it is not sticky even when inhaled,
Particles having a particle size of 1 to 100 μ, preferably 10 to 50 μ are suitable. For example, one selected from powders of zeolite, alumina, diatomaceous earth, perlite, activated clay, kaolin, feldspar, quartz, etc., or Used as a mixed powder of two or more kinds. Among these powders, zeolite, diatomaceous earth, and perlite are preferable.

第1,2図に示すような本発明装置は、例えば次のよう
な態様で構成される。
The device of the present invention as shown in FIGS. 1 and 2 is configured in the following manner, for example.

先ず、排ガスダクト内に、脱硝触媒層5を形成したろ材
1,2を設置する(第3図中の10)。
First, the filter media 1 and 2 on which the denitration catalyst layer 5 is formed are installed in the exhaust gas duct (10 in FIG. 3).

次に、前記した特殊反応助剤を(第3図中の11から)
導入し、プリコート層3を形成する。一方、消石灰を吹
込んだ排ガスを導入する。消石灰は排ガス中の塩化水素
と反応し、塩化カルシウムとなる。この塩化カルシウム
と未反応の消石灰とが外筒ろ材1表面に達し、固形物層
4を形成する。
Next, the above-mentioned special reaction aid (from 11 in FIG. 3)
Then, the precoat layer 3 is formed. On the other hand, the exhaust gas blown with slaked lime is introduced. Slaked lime reacts with hydrogen chloride in the exhaust gas to form calcium chloride. This calcium chloride and unreacted slaked lime reach the surface of the outer cylinder filter medium 1 to form a solid layer 4.

上記した塩化カルシウムは潮解性を有し、排ガス中の水
分の凝縮等により粘着性の固体となるおそれがある。こ
のような状態になると、ろ材の孔を防いだり、粉体層の
圧密性を助長して装置の正常維持が困難になる。
The above-mentioned calcium chloride has a deliquescent property and may become a sticky solid due to condensation of water in exhaust gas. In such a state, it becomes difficult to prevent the pores of the filter medium and promote the compaction of the powder layer, and it is difficult to maintain the apparatus normally.

斯る状況を防ぐために、本発明では、予め、ろ材表面に
上述の特殊反応助剤によるプリコート層3を形成するの
である。
In order to prevent such a situation, in the present invention, the precoat layer 3 made of the above-mentioned special reaction aid is formed on the surface of the filter medium in advance.

その後、上述の消石灰が吹込まれた排ガスが通気され、
該ガス中の上記した固形物が、プリコート層3の上に固
形物層(粉体層)4を形成して行く。同時に、第3図に
示すように、上述のろ材10に通じる排ガスダクト内に
供給装置11から特殊反応助剤を常時噴射し、粉体層4
の圧密化を抑制する。
After that, the exhaust gas blown with the above-mentioned slaked lime is aerated,
The above solid matter in the gas forms a solid matter layer (powder layer) 4 on the precoat layer 3. At the same time, as shown in FIG. 3, the special reaction aid is constantly injected from the supply device 11 into the exhaust gas duct leading to the above-mentioned filter medium 10, and the powder layer 4
Suppresses consolidation.

これらの層は、時間と共に成長し、その結果、装置の圧
力損失を上昇させる。そこで、ある一定時間間隔をおい
て粉体層を払い落とし、新たに層の形成を上述の態様で
行う。
These layers grow over time, resulting in increased pressure drop in the device. Therefore, the powder layer is brushed off at a certain time interval, and a new layer is formed in the above-described mode.

〔作用〕[Action]

以上の本発明装置において、排ガスが粉体層4を通過す
る際に、該排ガス中の未反応塩化水素が該粉体層4中の
消石灰と再度反応し、塩化水素が高効率で除去される。
In the above-mentioned device of the present invention, when the exhaust gas passes through the powder layer 4, the unreacted hydrogen chloride in the exhaust gas reacts again with the slaked lime in the powder layer 4, and the hydrogen chloride is removed with high efficiency. .

また、この時、排ガス中のダクトも除去され、集塵効果
を得ることもできる。
At this time, the duct in the exhaust gas is also removed, and the dust collecting effect can be obtained.

更に、特殊反応助剤としてアルカリ性のものを使用すれ
ば、排ガス中の硫黄酸化物を除去することができる。
Furthermore, when an alkaline special reaction aid is used, sulfur oxides in the exhaust gas can be removed.

また、本発明装置においては、脱硝触媒層5が形成され
ており、予めアンモニアガスが注入された排ガスが該層
5に接触(通過)して窒素酸化物が除去される。
Further, in the apparatus of the present invention, the denitration catalyst layer 5 is formed, and the exhaust gas into which ammonia gas has been injected in advance contacts (passes through) the layer 5 to remove nitrogen oxides.

〔発明の効果〕〔The invention's effect〕

本発明の装置によれば、次のような効果を奏することが
できる。
According to the device of the present invention, the following effects can be obtained.

(1)塩化水素と窒素酸化物の双方を高効率で除去するこ
とができ、また集じん効率を高め、かつ硫黄酸化物をも
効果的に除去することができる。
(1) Both hydrogen chloride and nitrogen oxides can be removed with high efficiency, dust collection efficiency can be improved, and sulfur oxides can also be effectively removed.

(2)排ガス温度が、従来の250℃以下に制限されず、
250℃以上の高温度でも処理できる。
(2) Exhaust gas temperature is not limited to the conventional 250 ° C or lower,
It can be processed even at a high temperature of 250 ° C. or higher.

(3)ろ剤の汚れに対して、取りはずし、水洗いすること
により、繰返し使用ができる。
(3) It can be used repeatedly by removing the dirt of the filter agent and washing it with water.

【図面の簡単な説明】[Brief description of drawings]

第1図は本発明装置に係るろ材の一実施態様例を示す
図、第2図は第1図の一部拡大図、第3図は本発明装置
の構成態様例を示す図である。
FIG. 1 is a diagram showing an example of an embodiment of a filter medium according to the device of the present invention, FIG. 2 is a partially enlarged view of FIG. 1, and FIG. 3 is a diagram showing an example of the configuration of the device of the present invention.

Claims (1)

【特許請求の範囲】[Claims] 【請求項1】ろ材として多孔質セラミツク材による内筒
・外筒の二重筒構造としたものを用い、少くとも内筒ろ
材表面に窒素酸化物除去用触媒層を設け、外筒ろ材表面
に特殊反応助剤プリコート層を介して消石灰又は炭酸カ
ルシウム及び塩化カルシウムを含む固形物層を形成した
ことを特徴とする排ガス処理装置。
1. A filter medium having a double cylinder structure of an inner cylinder and an outer cylinder made of a porous ceramic material is used, and a catalyst layer for removing nitrogen oxides is provided on the surface of the inner cylinder filter medium at least, and the outer cylinder filter medium surface is provided. An exhaust gas treatment apparatus, wherein a solid layer containing slaked lime or calcium carbonate and calcium chloride is formed through a special reaction aid precoat layer.
JP59230313A 1984-11-02 1984-11-02 Exhaust gas treatment device Expired - Lifetime JPH0649134B2 (en)

Priority Applications (3)

Application Number Priority Date Filing Date Title
JP59230313A JPH0649134B2 (en) 1984-11-02 1984-11-02 Exhaust gas treatment device
EP86730067A EP0242488B1 (en) 1984-11-02 1986-04-22 Filter medium for treating an exhaust gas
US06/854,936 US4728503A (en) 1984-11-02 1986-04-23 Filter medium for treating an exhaust gas

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
JP59230313A JPH0649134B2 (en) 1984-11-02 1984-11-02 Exhaust gas treatment device
EP86730067A EP0242488B1 (en) 1984-11-02 1986-04-22 Filter medium for treating an exhaust gas

Publications (2)

Publication Number Publication Date
JPS61111128A JPS61111128A (en) 1986-05-29
JPH0649134B2 true JPH0649134B2 (en) 1994-06-29

Family

ID=26106495

Family Applications (1)

Application Number Title Priority Date Filing Date
JP59230313A Expired - Lifetime JPH0649134B2 (en) 1984-11-02 1984-11-02 Exhaust gas treatment device

Country Status (1)

Country Link
JP (1) JPH0649134B2 (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP4807935B2 (en) * 2001-12-29 2011-11-02 ポール・コーポレーション Filter element

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH0655251B2 (en) * 1985-05-20 1994-07-27 旭硝子株式会社 Dust removal purifier
JPS6439819U (en) * 1987-09-01 1989-03-09

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP4807935B2 (en) * 2001-12-29 2011-11-02 ポール・コーポレーション Filter element

Also Published As

Publication number Publication date
JPS61111128A (en) 1986-05-29

Similar Documents

Publication Publication Date Title
US4728503A (en) Filter medium for treating an exhaust gas
US5567394A (en) SOx , NOx , and particulate removal system
AU2003240988B2 (en) Filter elements
JPH05154345A (en) Method for removing soot particle and organic compounds from waste gas
EP0242488B1 (en) Filter medium for treating an exhaust gas
JPH0649135B2 (en) Exhaust gas treatment device
JPH0649134B2 (en) Exhaust gas treatment device
JP4252166B2 (en) Dust removal and harmful gas decomposition equipment
JP4029029B2 (en) Bug filter
JP4649587B2 (en) Exhaust gas purification filter and collection method of particulate matter
JPH04219124A (en) Treatment of waste gas
KR102172490B1 (en) Multi-layered Filter Cartridge for Air Cleaning
JPS63171615A (en) Catalytic filter for treating exhaust gas
JP2000107562A (en) Treating apparatus for exhaust combustion gas
CA1264314A (en) Filter medium for treating an exhaust gas
JP2001246209A (en) Gas permeable body, manufacturing method thereof, and dust removing device
JPH0436729B2 (en)
JPH0655251B2 (en) Dust removal purifier
WO1994021351A1 (en) Active filters for integrated cleanup of gas streams
JPH11267432A (en) Treating device of waste gas
JP3844898B2 (en) Incinerator exhaust gas dust collector and dust collection method
CA1340720C (en) Method for treating a combustion exhaust gas using a catalyst filter
JP4246412B2 (en) Exhaust gas treatment catalyst and exhaust gas purification method using the same
CN114618297B (en) Manufacturing method, device and system of flue gas treatment device
JPS6090028A (en) Removing method of hydrogen chloride