JPH0649880B2 - Foaming liquid detergent composition - Google Patents
Foaming liquid detergent compositionInfo
- Publication number
- JPH0649880B2 JPH0649880B2 JP61129852A JP12985286A JPH0649880B2 JP H0649880 B2 JPH0649880 B2 JP H0649880B2 JP 61129852 A JP61129852 A JP 61129852A JP 12985286 A JP12985286 A JP 12985286A JP H0649880 B2 JPH0649880 B2 JP H0649880B2
- Authority
- JP
- Japan
- Prior art keywords
- weight
- hypochlorite
- liquid detergent
- composition
- detergent composition
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
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- Detergent Compositions (AREA)
Description
【発明の詳細な説明】 (1) 発明の目的 〔産業上の利用分野〕 本発明は、住居内の壁、タイル、プラスチック、目地、
陶器等の表面に付着する汚垢物質やカビ汚れを除去また
は洗浄する起泡性液体洗浄剤組成物に関する。DETAILED DESCRIPTION OF THE INVENTION (1) Purpose of the invention [Industrial field of application] The present invention relates to a wall, tile, plastic, joint,
The present invention relates to a foamable liquid detergent composition that removes or cleans dirt substances and mold stains that adhere to the surface of pottery and the like.
近年の住宅環境の変化は、住居内の気密性を高め、湿気
によるカビ汚れという問題を発生し、汚垢物質ばかりで
なくカビ汚れも同時に洗浄する液体洗浄剤が要望されて
いる。そこで、特開昭59−93799に開示されているよう
に、カビ汚れ除去成分である次亜塩素酸塩と、該塩の安
定剤としてのアルカリ剤と、汚垢物質洗浄成分の界面活
性剤とを混合した液体洗浄剤が提案されている。Due to recent changes in the housing environment, the airtightness in the house is increased, and the problem of mold stain due to moisture occurs. Therefore, there is a demand for a liquid cleaning agent that cleans not only dirt substances but also mold stains at the same time. Therefore, as disclosed in JP-A-59-93799, a hypochlorite which is a mold stain removing component, an alkali agent as a stabilizer of the salt, and a surfactant which is a stain substance cleaning component are used. A liquid detergent mixed with is proposed.
しかし、上記液体洗浄剤は、起泡性に乏しく、一般には
スプレーで噴霧して使用されるが、次亜塩素酸塩は刺激
物であるため、飛散による刺激臭や、例えば人体の呼吸
器系に入ると吐気やさらには発熱をひきおこすという危
険があった。同時にまた、低起泡性のため垂れ落ちの少
ないボリュームのある泡を形成し難く、汚れを長時間に
わたって泡で包囲することができないので、洗浄成分の
洗浄力を十分に発揮されないという問題もあった。However, the above liquid cleaning agent has poor foaming property and is generally used by spraying. However, since hypochlorite is an irritant, it causes an irritating odor caused by scattering, for example, the respiratory system of the human body. When entering, there was a danger of causing nausea and further fever. At the same time, because of its low foaming property, it is difficult to form a voluminous foam with little dripping, and since dirt cannot be surrounded by the foam for a long time, there is also a problem that the cleaning power of the cleaning component cannot be fully exerted. It was
そこで、本発明者らは、上記問題点を解決することを目
的として鋭意検討の結果、次亜塩素酸塩およびアルカリ
剤を含む液体洗浄成分に、それらの成分に対して安定な
特定の溶剤を添加すると、上記目的を達成することがで
きる起泡性液体洗浄剤組成物が得られることを見出し、
本発明に到達した。Therefore, the present inventors have conducted intensive studies for the purpose of solving the above-mentioned problems, and as a liquid cleaning component containing hypochlorite and an alkaline agent, a specific solvent stable to those components is used. When added, it is found that a foamable liquid detergent composition capable of achieving the above object is obtained,
The present invention has been reached.
(2) 発明の構成 〔問題点を解決するための手段〕 上記目的を達成するための本発明の要旨とするところ
は、少なくとも下記成分を含有することを特徴とする起
泡性液体洗浄剤組成物に存する。(2) Configuration of the invention [Means for solving the problems] The gist of the present invention for achieving the above object is to include a foamable liquid detergent composition containing at least the following components: It exists in things.
a)次亜塩素酸塩 0.1〜８重量％。a) 0.1-8% by weight of hypochlorite.
b)アルカリ剤 0.1〜10重量％。b) 0.1-10% by weight of alkaline agent.
c)次亜塩素酸塩およびアルカリ剤に対して実質的に安定
である界面活性剤 0.1〜８重量％。c) 0.1-8% by weight of a surfactant which is substantially stable to hypochlorite and alkaline agents.
d)一般式ＣＨ3−Ｏ−（ＥＯ）ｎ（ＰＯ）m−ＣＨ3で表
わされる溶剤0.1〜10重量％（ただし、式中、ＥＯは−
ＣＨ2−ＣＨ2−Ｏ−を、ＰＯは を示し、ｎは１〜455、ｍは０〜５、ｎ＋ｍ≧１であ
る）。d) 0.1 to 10% by weight of a solvent represented by the general formula CH 3 —O— (EO) n (PO) m—CH 3 (wherein, EO is
CH 2 and -CH 2 -O-, PO is , N is 1 to 455, m is 0 to 5, and n + m ≧ 1).
本発明組成物の第一成分である次亜塩素酸塩は、強力な
酸化作用により有機物を効果的に分解洗浄し、優れた殺
菌力を示し、カビ汚れの除去に有効である。次亜塩素酸
塩としては、時に次亜塩素酸ソーダまたは／および次亜
塩素酸カリウムが適当であり、配合量としては、0.1〜
８重量％、好ましくは0.1〜５重量％である。0.1重量％
未満では効果が低くて実用性に乏しく、８重量％を超え
ても、その割には効果が向上せず不経済である。ちなみ
に、保存が比較的長期間にわたると、経時的に分解して
効果の低下を来す傾向があるので、その点からしても不
経済である。The hypochlorite, which is the first component of the composition of the present invention, effectively decomposes and cleans organic substances by a strong oxidizing action, exhibits excellent bactericidal power, and is effective in removing mold stains. As the hypochlorite, sodium hypochlorite or / and potassium hypochlorite is sometimes suitable, and the compounding amount is 0.1 to
It is 8% by weight, preferably 0.1-5% by weight. 0.1% by weight
If it is less than 8%, the effect is low and it is poor in practicality. Even if it exceeds 8% by weight, the effect is not improved, and it is uneconomical. By the way, if it is stored for a relatively long period of time, it tends to be decomposed with time and its effect tends to be deteriorated, which is also uneconomical.
本発明組成物の第二成分であるアルカリ剤は、次亜塩素
酸塩の分解を抑制するとともに、その効果を促進するの
に有効である。アルカリ剤としては、水酸化ナトリウ
ム、水酸化カリウム等の水酸化アルカリ金属炭酸ソー
ダ、ケイ酸ソーダ等が挙げられるが、比較的長期間の安
定性を考慮すると、特に水酸化ナトリウム、水酸化カリ
ウムが適当であり、配合量としては、0.1〜10重量％、
好ましくは0.1〜５重量％である。0.1重量％未満では効
果が低く、10重量％を超えると、却って次亜塩素酸塩の
分解を経時的に促進する傾向がある。The alkaline agent which is the second component of the composition of the present invention is effective in suppressing the decomposition of hypochlorite and promoting the effect thereof. Examples of the alkaline agent include sodium hydroxide alkali metal carbonate such as sodium hydroxide and potassium hydroxide, sodium silicate, and the like. Considering stability for a relatively long period, sodium hydroxide and potassium hydroxide are particularly preferable. Suitable, as a blending amount, 0.1-10 wt%,
It is preferably 0.1 to 5% by weight. If it is less than 0.1% by weight, the effect is low, and if it exceeds 10% by weight, the decomposition of hypochlorite tends to be accelerated over time.
本発明組成物の第三成分である界面活性剤は、次亜塩素
酸塩の効果、特に浸透力を向上させる作用を有するが、
次亜塩素酸塩の安定性を保つためには、ポリオキシエチ
レンアルキルフェニルエーテル硫酸塩、アルキルジフェ
ニルエーテルジスルフォン酸塩、アルキル硫酸塩、アル
カン(ジ)硫酸塩、アルキルジメチルアミンオキサイド、
脂肪酸セッケン等が特に好ましいが、その他、従来、液
体洗浄剤組成物に使用されているものの使用を禁示また
は除外するものではない。これらは、単独または複数種
混合して使用することができ、配合量としては、0.1〜
８重量％、好ましくは0.1〜３重量％である。0.1重量％
未満では効果が低く、８重量％を超えると、次亜塩素酸
塩の安定性を害し、その浸透力を低下させる。The surfactant, which is the third component of the composition of the present invention, has the effect of hypochlorite, particularly the effect of improving the penetrating power,
In order to maintain the stability of hypochlorite, polyoxyethylene alkylphenyl ether sulfate, alkyl diphenyl ether disulphonate, alkyl sulfate, alkane (di) sulfate, alkyldimethylamine oxide,
Fatty acid soaps and the like are particularly preferable, but the use of those conventionally used in liquid detergent compositions is not prohibited or excluded. These can be used alone or as a mixture of two or more kinds, and as a blending amount, 0.1 to
It is 8% by weight, preferably 0.1-3% by weight. 0.1% by weight
If the amount is less than 8%, the effect is low, and if it exceeds 8% by weight, the stability of the hypochlorite is impaired and the penetrating power thereof is reduced.
本発明組成物の第四成分であり、かつ、本発明組成物に
おいて最も特徴的成分である上記一般式で表わされる溶
剤は、起泡性を与え、浸透性を向上させるのに極めて効
果があるとともに、油脂系の汚れの除去にも有効に作用
する。この溶剤は、アルキレングリコールジメチルエー
テレであり、オキシエチレン、オキシプロピレンの結合
順序は問わない。末端の結合基は特にメチル基が好まし
く、エチル基以上の長さになると、次亜塩素酸ソーダと
の安定性が著しく低下する。エチレンオキサイド、プロ
ピレンオキサイドの付加モル数については、エチレンオ
キサイドは１〜455モル、プロピレンオキサイドは０〜
５モルであることが必要である。エチレンオキサイドの
付加モル数が455モルを超えるものは技術的に製造が困
難であり、プロピレンオキサイドの付加モル数が５を超
えると、不溶性となり好ましくない。そして、エチレン
オキサイド付加モル数＞プロピレンオキサイド付加モル
数で、かつ前者＋後者≧１であることが好ましい。特に
好ましい溶剤としては、エチレングリコールジメチルエ
ーテル、ジエチレングリコールジメチルエーテル、トリ
エチレングリコールジメチルエーテル、ノナエチレング
リコールジメチルエーテル等が挙げられ、ポリエチレン
グリコールジメチルエーテルでエチレンオキサイド付加
モル数が１〜455モルのものは有効である。配合量は0.1
〜10重量％、好ましくは0.1〜５重量％であり、0.1重量
％未満では効果がなく、10重量％を超えると、次亜塩素
酸塩の安定性が極端に悪化する。The solvent represented by the above-mentioned general formula, which is the fourth component of the composition of the present invention and is the most characteristic component of the composition of the present invention, has a foaming property and is extremely effective in improving the permeability. At the same time, it effectively acts to remove oil-based stains. This solvent is alkylene glycol dimethyl ether, and the order of bonding oxyethylene and oxypropylene does not matter. The terminal bonding group is particularly preferably a methyl group, and when the length is equal to or longer than the ethyl group, the stability with sodium hypochlorite is significantly reduced. Regarding the number of moles of ethylene oxide and propylene oxide added, ethylene oxide is 1 to 455 moles and propylene oxide is 0 to 0 moles.
It should be 5 moles. Those having an addition mole number of ethylene oxide exceeding 455 moles are technically difficult to produce, and those having an addition mole number of propylene oxide exceeding 5 are insoluble and are not preferred. It is preferable that the number of moles of ethylene oxide added> the number of moles of propylene oxide added, and the former + the latter ≧ 1. Particularly preferred solvents include ethylene glycol dimethyl ether, diethylene glycol dimethyl ether, triethylene glycol dimethyl ether, nonaethylene glycol dimethyl ether and the like, and polyethylene glycol dimethyl ether having an ethylene oxide addition mole number of 1 to 455 moles is effective. Compounding amount is 0.1
The amount is up to 10% by weight, preferably 0.1 to 5% by weight. Below 0.1% by weight, there is no effect, and above 10% by weight, the stability of hypochlorite is extremely deteriorated.
なお、本発明組成物において、上記四つの基本成分のほ
か、それらの成分、特に次亜塩素酸塩およびアルカリ剤
に対して安定性を有する公知の香料、着色剤等を適宜量
配合することがあることはいうまでもない。In addition, in the composition of the present invention, in addition to the above four basic components, those components, in particular, known fragrances having stability to hypochlorite and alkaline agents, colorants and the like may be added in appropriate amounts. Needless to say.
〔実施例〕 配合成分 配合量(wt%) ａ）次亜塩素酸ソーダ 3.0 ｂ）苛性ソーダ 1.0 ｃ）アルキルジフェニルエーテル ジスルホン酸ソーダ 1.0 ｄ）溶剤（第１表に示す） 3.0 ｅ）精製水 バランス 上記配合の液体洗浄剤を調整し、吉野工業(株)製のトリ
ガー式スプレー容器を使用して、浴室のカビ汚れをして
いる部位に塗布した。その結果を第１表に示す。[Examples] Blending ingredients Blending amount (wt%) a) Sodium hypochlorite 3.0 b) Sodium hydroxide 1.0 c) Sodium alkyldiphenyl ether disulfonate 1.0 d) Solvent (shown in Table 1) 3.0 e) Purified water balance Above blending The liquid cleaning agent was prepared and applied to a portion of the bathroom where the mold is stained by using a trigger type spray container manufactured by Yoshino Industry Co., Ltd. The results are shown in Table 1.
上記評価は、つぎの方法によった。 The above evaluation was based on the following method.
洗浄力 実施サンプルおよび比較サンプル（以下単にサンプルと
いう）を噴出塗布して３分間放置した後、汚れの状態を
目視判定した。Detergency After spraying and applying the execution sample and the comparative sample (hereinafter simply referred to as sample) for 3 minutes, the state of stain was visually determined.
○…きれいに汚れが落ちる。○: Dirt will be removed cleanly.
△…残存汚れがある。Δ: There is residual stain.
×…全く汚れが落ちない。X: Dirt does not come off at all.
泡立性（起泡力） スプレー容器を３回操作してその都度サンプルを噴出塗
布したときの発泡量を目視判定した。Foamability (foaming power) The spray container was operated three times, and the amount of foaming when the sample was jetted and applied each time was visually judged.
○…泡立ちにボリューム感がある。○: There is a volume feeling in foaming.
△…泡立ちがやや水ぽい ×…泡立ちがほとんどない。Δ: Foaming is slightly watery ×: Foaming is almost absent.
泡質 スプレー容器を３回操作してその都度サンプルを噴出塗
布したときの泡立ちの状態を目視判定した。Foam quality The state of foaming when the sample was jetted and applied each time the spray container was operated three times was visually judged.
○…泡がきめ細かくてクリーミーである。○: The bubbles are fine and creamy.
△…やや大きい泡が混じっている。Δ: A slightly large bubble is mixed.
×…泡が大きく水ぽい。×: The bubbles are large and watery.
泡の流れ落ち スプレー容器のノズルを垂直で滑らかな壁面に向けてサ
ンプルを噴出塗布し、泡の汚れ落ちを目視判定した。Bubble run-off The sample was jet-applied with the nozzle of the spray container facing the vertical and smooth wall surface, and the stain removal of foam was visually judged.
○…泡が徐々に全体に拡がるように落ちる。○: Bubbles gradually fall so as to spread all over.
×…泡がはやく流れるように落ちる。× ... Bubbles quickly and fall off.
安定性 サンプル調整後40℃の恒温槽に保存し、調整直後と、30
日経過後の内溶液全体に対する有効塩素濃度を測定して
比較した。Stability After adjusting the sample, store it in a constant temperature bath at 40 ° C and
After a day, the available chlorine concentration in the whole inner solution was measured and compared.
におい サンプル調整後、溶剤特有のにおいが人体にどのように
感じるかを10人に問うた。After preparing the odor sample, we asked 10 people how the smell peculiar to the solvent is felt by the human body.
○…10人が全く気にならないと答えた。○… 10 people said they didn't care at all.
△…４〜５人がやや気になると答えた。Δ: 4 to 5 people answered that they were a little worried.
×…９人が非常にいやなにおいと答えた。×: 9 people replied that they had a very unpleasant odor.
浸透力 キャンバス沈降法により測定して比較した。なお、水だ
けの場合について測定したが、１分以上経過しても浸透
しなかった。Osmotic force A comparison was made by measuring by the canvas sedimentation method. The measurement was carried out only with water, but it did not penetrate even after 1 minute or more.
さらに、溶剤濃度に対する次亜塩素酸ソーダの安定度試
験を行った。この試験はサンプルを７日間40℃の恒温保
存し、有効塩素濃度測定により次亜塩素酸ソーダの残存
率を算出した。その結果を第２表に示す。Furthermore, the stability test of sodium hypochlorite with respect to the solvent concentration was conducted. In this test, the sample was kept at 40 ° C. for 7 days, and the residual rate of sodium hypochlorite was calculated by measuring the effective chlorine concentration. The results are shown in Table 2.
(3) 発明の効果 本発明組成物によれば、従来公知の液体洗浄剤組成物に
特定の溶剤を添加してあって、実施例から明らかのよう
に、起泡性が与えられるので、起泡用スプレーで噴出す
ると、特にボリュームがあり均質な泡立ちで塗布され
る。したがって、次亜塩素酸塩含有液体が飛散すること
にともなう人体への危険を未然に防止することができる
うえ、その泡立ちで汚れを比較的長時間にわたり包囲す
るとともに、前記溶剤の添加による浸透性の向上によっ
て洗浄力を十分に発揮させることができる。また、優れ
た泡立ち状態であるから、これを視認することができる
こと相俟ってカビ汚れ等を除去すべき所望部位に的確に
塗布することができ、そのため経済的に使用することが
できるという利点もあり、液体洗浄剤として実用に供し
て極めて有益である。 (3) Effect of the Invention According to the composition of the present invention, a specific solvent is added to a conventionally known liquid detergent composition, and as it is apparent from the examples, foamability is imparted. When sprayed with a foam spray, it is applied with a particularly voluminous and homogeneous foam. Therefore, it is possible to prevent the danger to the human body due to the scattering of the hypochlorite-containing liquid, and at the same time the dirt is surrounded by the foaming for a relatively long time, and the permeability by the addition of the solvent is increased. It is possible to sufficiently exert the cleaning power by improving. In addition, since it is in an excellent foaming state, it can be visually recognized, and in combination with this, it can be accurately applied to a desired site where mold stains and the like should be removed, and therefore, it can be economically used. Therefore, it is extremely useful for practical use as a liquid detergent.
Claims (5)
とする起泡性液体洗浄剤組成物。 a)次亜塩素酸塩 0.1〜８重量％。 b)アルカリ剤 0.1〜10重量％。 c)次亜塩素酸塩およびアルカリ剤に対して実質的に安定
である界面活性剤 0.1〜８重量％。 d)一般式ＣＨ3−Ｏ−（ＥＯ）ｎ（ＰＯ）m−ＣＨ3で表
わされる溶剤0.1〜10重量％（ただし、式中、ＥＯは−
ＣＨ2−ＣＨ2−Ｏ−を、ＰＯは を示し、ｎは１〜455、ｍは０〜５、ｎ＋ｍ≧１であ
る）。1. A foamable liquid detergent composition comprising at least the following components. a) 0.1-8% by weight of hypochlorite. b) 0.1-10% by weight of alkaline agent. c) 0.1-8% by weight of a surfactant which is substantially stable to hypochlorite and alkaline agents. d) 0.1 to 10% by weight of a solvent represented by the general formula CH 3 —O— (EO) n (PO) m—CH 3 (wherein, EO is
CH 2 and -CH 2 -O-, PO is , N is 1 to 455, m is 0 to 5, and n + m ≧ 1).
および次亜塩素酸カリウムである特許請求の範囲第１項
記載の組成物。2. The hypochlorite is sodium hypochlorite or /
And the composition of claim 1 which is potassium hypochlorite.
よび水酸化カリウムで 0.1〜５重量％である特許請求の
範囲第２項記載の組成物。3. The composition according to claim 2, wherein the alkaline agent is 0.1 to 5% by weight of sodium hydroxide and / or potassium hydroxide.
ＣＨ3で表わされる溶剤において、ｎ＝１〜15、ｍ＝０
で特許請求の範囲第２項記載の組成物。4. The general formula CH 3 --O-(EO) n (PO) m--.
In the solvent represented by CH 3 , n = 1 to 15 and m = 0
A composition as claimed in claim 2.
ＣＨ3で表わされる溶剤が１〜５重量％である特許請求
の範囲第４項記載の組成物。5. The general formula CH 3 --O-(EO) n (PO) m--.
The composition according to claim 4, wherein the solvent represented by CH 3 is 1 to 5% by weight.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP61129852A JPH0649880B2 (en) | 1986-06-04 | 1986-06-04 | Foaming liquid detergent composition |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP61129852A JPH0649880B2 (en) | 1986-06-04 | 1986-06-04 | Foaming liquid detergent composition |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS62286000A JPS62286000A (en) | 1987-12-11 |
| JPH0649880B2 true JPH0649880B2 (en) | 1994-06-29 |
Family
ID=15019847
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP61129852A Expired - Lifetime JPH0649880B2 (en) | 1986-06-04 | 1986-06-04 | Foaming liquid detergent composition |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH0649880B2 (en) |
Families Citing this family (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH02180998A (en) * | 1989-01-05 | 1990-07-13 | Katsutoshi Mizutani | Cleaning liquid for hard surface |
| CA2096452A1 (en) * | 1992-06-19 | 1993-12-20 | William E. Elias | Inorganic oxidant compositions for removing contaminants |
| ZA935882B (en) * | 1992-10-19 | 1994-03-11 | Clorox Co | Composition and method for developing extensional viscosity in cleaning compositions. |
| CA2107938C (en) * | 1993-01-11 | 2005-01-11 | Clement K. Choy | Thickened hypochlorite solutions with reduced bleach odor and methods of manufacture and use |
| GB9307804D0 (en) * | 1993-04-15 | 1993-06-02 | Unilever Plc | Hygienic spray cleaner |
| DE19803054A1 (en) * | 1998-01-28 | 1999-07-29 | Henkel Kgaa | Hypochlorite bleaching and disinfecting compositions, especially for hard surfaces, containing cleaning enhancer |
| EP1497404A4 (en) * | 2002-04-01 | 2005-04-20 | Fiber Engineering Inc | ELIMINATION OF COLORING TENACE OF MOLD |
Family Cites Families (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5993799A (en) * | 1982-11-20 | 1984-05-30 | サンポ−ル・クロロツクス株式会社 | Liquid detergent |
| JPS60141800A (en) * | 1983-12-28 | 1985-07-26 | ライオン株式会社 | Liquid detergent composition |
-
1986
- 1986-06-04 JP JP61129852A patent/JPH0649880B2/en not_active Expired - Lifetime
Also Published As
| Publication number | Publication date |
|---|---|
| JPS62286000A (en) | 1987-12-11 |
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