JPH0662372B2 - Stable solid pesticide composition - Google Patents
Stable solid pesticide compositionInfo
- Publication number
- JPH0662372B2 JPH0662372B2 JP6689186A JP6689186A JPH0662372B2 JP H0662372 B2 JPH0662372 B2 JP H0662372B2 JP 6689186 A JP6689186 A JP 6689186A JP 6689186 A JP6689186 A JP 6689186A JP H0662372 B2 JPH0662372 B2 JP H0662372B2
- Authority
- JP
- Japan
- Prior art keywords
- group
- stable solid
- general formula
- compound
- composition according
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000000203 mixture Substances 0.000 title claims description 13
- 239000007787 solid Substances 0.000 title claims description 13
- 239000000575 pesticide Substances 0.000 title description 3
- 235000014113 dietary fatty acids Nutrition 0.000 claims description 9
- 239000000194 fatty acid Substances 0.000 claims description 9
- 229930195729 fatty acid Natural products 0.000 claims description 9
- 230000000749 insecticidal effect Effects 0.000 claims description 8
- 150000003839 salts Chemical class 0.000 claims description 8
- 238000002360 preparation method Methods 0.000 claims description 7
- 150000004665 fatty acids Chemical class 0.000 claims description 6
- -1 sulfenyl carbamate derivative Chemical compound 0.000 claims description 6
- 239000002917 insecticide Substances 0.000 claims description 5
- 238000002156 mixing Methods 0.000 claims description 3
- 125000003161 (C1-C6) alkylene group Chemical group 0.000 claims description 2
- 125000004209 (C1-C8) alkyl group Chemical group 0.000 claims description 2
- 125000000217 alkyl group Chemical group 0.000 claims description 2
- 125000004744 butyloxycarbonyl group Chemical group 0.000 claims 1
- 125000001449 isopropyl group Chemical group [H]C([H])([H])C([H])(*)C([H])([H])[H] 0.000 claims 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims 1
- 125000004108 n-butyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 claims 1
- 239000000843 powder Substances 0.000 description 11
- 239000008187 granular material Substances 0.000 description 8
- 229940125904 compound 1 Drugs 0.000 description 5
- 238000000354 decomposition reaction Methods 0.000 description 5
- 239000004563 wettable powder Substances 0.000 description 5
- VMHLLURERBWHNL-UHFFFAOYSA-M Sodium acetate Chemical compound [Na+].CC([O-])=O VMHLLURERBWHNL-UHFFFAOYSA-M 0.000 description 4
- 150000001875 compounds Chemical class 0.000 description 4
- 239000001632 sodium acetate Substances 0.000 description 4
- 235000017281 sodium acetate Nutrition 0.000 description 4
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical class CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 3
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 3
- 238000004458 analytical method Methods 0.000 description 3
- 239000004927 clay Substances 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 238000009472 formulation Methods 0.000 description 3
- 239000011521 glass Substances 0.000 description 3
- 238000004128 high performance liquid chromatography Methods 0.000 description 3
- 229910052500 inorganic mineral Inorganic materials 0.000 description 3
- 239000011707 mineral Substances 0.000 description 3
- FERIUCNNQQJTOY-UHFFFAOYSA-N Butyric acid Chemical class CCCC(O)=O FERIUCNNQQJTOY-UHFFFAOYSA-N 0.000 description 2
- 239000004480 active ingredient Substances 0.000 description 2
- 239000000440 bentonite Substances 0.000 description 2
- 229910000278 bentonite Inorganic materials 0.000 description 2
- SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical compound O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 description 2
- 125000002915 carbonyl group Chemical group [*:2]C([*:1])=O 0.000 description 2
- 229940125782 compound 2 Drugs 0.000 description 2
- 229940126214 compound 3 Drugs 0.000 description 2
- XBDQKXXYIPTUBI-UHFFFAOYSA-N dimethylselenoniopropionate Chemical class CCC(O)=O XBDQKXXYIPTUBI-UHFFFAOYSA-N 0.000 description 2
- BDAGIHXWWSANSR-UHFFFAOYSA-N methanoic acid Natural products OC=O BDAGIHXWWSANSR-UHFFFAOYSA-N 0.000 description 2
- 239000003381 stabilizer Substances 0.000 description 2
- 239000000454 talc Substances 0.000 description 2
- 229910052623 talc Inorganic materials 0.000 description 2
- NQPDZGIKBAWPEJ-UHFFFAOYSA-N valeric acid Chemical class CCCCC(O)=O NQPDZGIKBAWPEJ-UHFFFAOYSA-N 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- GLGNXYJARSMNGJ-VKTIVEEGSA-N (1s,2s,3r,4r)-3-[[5-chloro-2-[(1-ethyl-6-methoxy-2-oxo-4,5-dihydro-3h-1-benzazepin-7-yl)amino]pyrimidin-4-yl]amino]bicyclo[2.2.1]hept-5-ene-2-carboxamide Chemical compound CCN1C(=O)CCCC2=C(OC)C(NC=3N=C(C(=CN=3)Cl)N[C@H]3[C@H]([C@@]4([H])C[C@@]3(C=C4)[H])C(N)=O)=CC=C21 GLGNXYJARSMNGJ-VKTIVEEGSA-N 0.000 description 1
- OSWFIVFLDKOXQC-UHFFFAOYSA-N 4-(3-methoxyphenyl)aniline Chemical class COC1=CC=CC(C=2C=CC(N)=CC=2)=C1 OSWFIVFLDKOXQC-UHFFFAOYSA-N 0.000 description 1
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
- IMROMDMJAWUWLK-UHFFFAOYSA-N Ethenol Chemical compound OC=C IMROMDMJAWUWLK-UHFFFAOYSA-N 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- 239000005909 Kieselgur Substances 0.000 description 1
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 1
- 241001465754 Metazoa Species 0.000 description 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
- UCKMPCXJQFINFW-UHFFFAOYSA-N Sulphide Chemical compound [S-2] UCKMPCXJQFINFW-UHFFFAOYSA-N 0.000 description 1
- 241000607479 Yersinia pestis Species 0.000 description 1
- 235000011054 acetic acid Nutrition 0.000 description 1
- 239000003905 agrochemical Substances 0.000 description 1
- 229910052783 alkali metal Inorganic materials 0.000 description 1
- 150000001340 alkali metals Chemical class 0.000 description 1
- 229910052784 alkaline earth metal Inorganic materials 0.000 description 1
- 150000001342 alkaline earth metals Chemical class 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- 229910052788 barium Inorganic materials 0.000 description 1
- DSAJWYNOEDNPEQ-UHFFFAOYSA-N barium atom Chemical compound [Ba] DSAJWYNOEDNPEQ-UHFFFAOYSA-N 0.000 description 1
- FYZBOYWSHKHDMT-UHFFFAOYSA-N benfuracarb Chemical compound CCOC(=O)CCN(C(C)C)SN(C)C(=O)OC1=CC=CC2=C1OC(C)(C)C2 FYZBOYWSHKHDMT-UHFFFAOYSA-N 0.000 description 1
- 239000011230 binding agent Substances 0.000 description 1
- 229910052791 calcium Inorganic materials 0.000 description 1
- 239000011575 calcium Substances 0.000 description 1
- JLQUFIHWVLZVTJ-UHFFFAOYSA-N carbosulfan Chemical compound CCCCN(CCCC)SN(C)C(=O)OC1=CC=CC2=C1OC(C)(C)C2 JLQUFIHWVLZVTJ-UHFFFAOYSA-N 0.000 description 1
- 239000000969 carrier Substances 0.000 description 1
- 150000001768 cations Chemical group 0.000 description 1
- 229910052570 clay Inorganic materials 0.000 description 1
- 229940125758 compound 15 Drugs 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 235000019253 formic acid Nutrition 0.000 description 1
- 231100000053 low toxicity Toxicity 0.000 description 1
- 229910052749 magnesium Inorganic materials 0.000 description 1
- 239000011777 magnesium Substances 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 230000000361 pesticidal effect Effects 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
- 235000019260 propionic acid Nutrition 0.000 description 1
- IUVKMZGDUIUOCP-BTNSXGMBSA-N quinbolone Chemical class O([C@H]1CC[C@H]2[C@H]3[C@@H]([C@]4(C=CC(=O)C=C4CC3)C)CC[C@@]21C)C1=CCCC1 IUVKMZGDUIUOCP-BTNSXGMBSA-N 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 238000001228 spectrum Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- 229940005605 valeric acid Drugs 0.000 description 1
Landscapes
- Agricultural Chemicals And Associated Chemicals (AREA)
Description
【発明の詳細な説明】 産業上の利用分野 本発明は、安定な固体殺虫剤組成物に関する。FIELD OF THE INVENTION This invention relates to stable solid pesticide compositions.
従来の技術 一般式 〔式中Ｒ１及びＲ２は同一又は異なってＣ１〜Ｃ８アル
キル基、−（Ｃ１〜Ｃ６アルキレン）ＣＯＯＲ３基又は
−ＣＯＯＲ４基を示す。ここでＲ３及びＲ４はＣ１〜Ｃ
８のアルキル基を示す。〕 で表わされるスルフエニルカーバメイト誘導体は、各種
害虫に対して卓越した効果を有し幅広い殺虫スペクトラ
ムを有する一方、温血動物に対する毒性が低いことが知
られている。このため、上記一般式（Ｉ）で表わされる
スルフエニルカーバメイト誘導体は、有用な殺虫剤成分
として市販又は開発されつつある。しかしながら上記ス
ルフエニルカーバメイト誘導体は、場合によっては不安
定であり、特に通常使用される鉱物質担体の種類によつ
ては粉末状又は粒状に製剤化した場合に著しく分解する
ことがある。Conventional technology General formula Shows a (C 1 -C 6 alkylene) COOR 3 group or -COOR 4 radical - [wherein R 1 and R 2 are the same or different C 1 -C 8 alkyl group. Here, R 3 and R 4 are C 1 to C
8 represents an alkyl group. It is known that the sulfenylcarbamate derivative represented by the following formula has an excellent effect against various pests and has a broad insecticidal spectrum, while having low toxicity to warm-blooded animals. Therefore, the sulfenylcarbamate derivative represented by the above general formula (I) is being marketed or developed as a useful insecticide component. However, the above-mentioned sulfenylcarbamate derivative is unstable in some cases, and depending on the type of the commonly used mineral carrier, it may be significantly decomposed when formulated into powder or granules.
安価で且つ効果的な殺虫剤を提供するためには、いかな
る鉱物質担体を配合しても上記スルフエニルカーバメイ
ト誘導体の分解を抑制し得る技術の開発が要望されてお
り、従来より種々の検討がなされているが、未だ充分な
成果が挙げられていない。In order to provide an inexpensive and effective insecticide, it has been desired to develop a technique capable of suppressing the decomposition of the sulfenylcarbamate derivative even if any mineral substance carrier is added, and various studies have been conventionally conducted. Has been done, but not enough results have been achieved yet.
問題点を解決するための手段 本発明者は、斯かる現状に鑑み安定な固体殺虫剤組成物
を開発すべく鋭意研究を重ねた結果、上記一般式（Ｉ）
で表わされるスルフエニルカーバメイト誘導体の固体殺
虫製剤に低級脂肪酸の塩を配合することにより本発明の
所期の目的を達成し得ることを見い出し、ここに本発明
を完成するに至つた。Means for Solving Problems The present inventor has conducted diligent research in order to develop a stable solid insecticide composition in view of the present situation, and as a result, the above general formula (I)
It was found that the intended purpose of the present invention can be achieved by incorporating a salt of a lower fatty acid into a solid insecticidal preparation of a sulfenylcarbamate derivative represented by the following, and the present invention has been completed here.
即ち、本発明は、上記一般式（Ｉ）で表わされるスルフ
エニルカーバメイト誘導体の固体殺虫製剤に低級脂肪酸
の塩を配合することを特徴とする安定な固体殺虫剤組成
物に係る。That is, the present invention relates to a stable solid pesticide composition characterized by incorporating a salt of a lower fatty acid into a solid pesticidal preparation of the sulfenylcarbamate derivative represented by the general formula (I).
本発明において、固体殺虫製剤とは、殺虫有効成分を含
有する粒剤、微粒剤、水和剤、粉剤等の経済形態を意味
するものであり、これに使用される担体としては通常農
薬製剤に使用される鉱物質担体、例えばベントナイト、
珪藻土、ホワイトカーボン、クレー、タルク等の１種又
は２種以上を配合したものであるか、或はそれらの粉末
状のものをバインダー、界面活性剤、水等を用いて造粒
したものでもよい。In the present invention, the solid insecticide formulation means an economic form such as granules, fine granules, wettable powders, powders and the like containing an insecticidal active ingredient, and a carrier used for this is usually an agricultural chemical formulation. Mineral carriers used, such as bentonite,
One or two or more kinds of diatomaceous earth, white carbon, clay, talc, etc. may be blended, or a powder thereof may be granulated using a binder, a surfactant, water or the like. .
本発明の固体殺虫製剤中に配合される一般式（Ｉ）のス
ルフエニルカーバメイト誘導体としては、上記一般式に
包含されている限り従来公知のものをいずれも使用で
き、具体的には以下の化合物を例示できる。As the sulfenylcarbamate derivative of the general formula (I) to be incorporated in the solid insecticidal preparation of the present invention, any conventionally known one can be used as long as it is included in the above general formula, and specifically, A compound can be illustrated.
２，３−ジヒドロ−２，２−ジメチル−７−ベンゾフ
ラニル Ｎ−〔Ｎ−（２−エトキシカルボニルエチル）
−Ｎ−イソプロピルアミノスルフエニル〕−Ｎ−メチル
カーバメイト（以下「化合物１」という） ２，３−ジヒドロ−２，２−ジメチル−７−ベンゾフ
ラニル Ｎ−（Ｎ，Ｎ−ジブチルアミノスルフエニル）
−Ｎ−メチルカーバメイト（以下「化合物２」という） 〔（２，３−ジヒドロ−２，２−ジメチルベンゾフラ
ニル−７−オキシ）−（Ｎ−メチルアミノ）カルボニ
ル〕−〔ｎ−ブトキシ−（Ｎ′−メチルアミノ）カルボ
ニル〕サルフアイド（以下「化合物３」という） 本発明の固体殺虫製剤中に配合される上記一般式（Ｉ）
のスルフエニルカーバメイト誘導体の量としては、特に
制限されず広範囲内から適宜選択することができるが、
通常該製剤中に０．５〜６０重量％程度、好ましくは２
〜５０重量％程度とするのがよい。2,3-dihydro-2,2-dimethyl-7-benzofuranyl N- [N- (2-ethoxycarbonylethyl)
-N-isopropylaminosulfenyl] -N-methylcarbamate (hereinafter referred to as "compound 1") 2,3-dihydro-2,2-dimethyl-7-benzofuranyl N- (N, N-dibutylaminosulfenyl)
-N-methylcarbamate (hereinafter referred to as "compound 2") [(2,3-dihydro-2,2-dimethylbenzofuranyl-7-oxy)-(N-methylamino) carbonyl]-[n-butoxy- ( N′-methylamino) carbonyl] sulfide (hereinafter referred to as “compound 3”) The above general formula (I) compounded in the solid insecticidal preparation of the present invention.
The amount of the sulfenylcarbamate derivative of is not particularly limited and can be appropriately selected from a wide range,
Usually about 0.5 to 60% by weight, preferably 2
It is preferable to be about 50% by weight.
本発明で使用される低級脂肪酸の塩としては、例えば蟻
酸、酢酸、プロピオン酸、酪酸、吉草酸等の塩を挙げる
ことができ、また斯かる塩のカチオン部分としては、例
えばナトリウム、カリウム等のアルカリ金属、マグネシ
ウム、カルシウム、バリウム等のアルカリ土類金属等を
挙げることができる。これら低級脂肪酸の塩は、工業的
に入手が容易な化合物である。斯かる低級脂肪酸塩の配
合量としては、特に限定されるものではないが、通常本
発明の固体殺虫製剤中に０．０１〜２０重量％程度、好
ましくは０．１〜１０重量％程度配合するのがよい。Examples of the salts of lower fatty acids used in the present invention include salts of formic acid, acetic acid, propionic acid, butyric acid, valeric acid, etc., and the cation moiety of such salts include, for example, sodium, potassium, etc. Examples thereof include alkali metals, alkaline earth metals such as magnesium, calcium and barium. These salts of lower fatty acids are industrially easily available compounds. The amount of the lower fatty acid salt to be blended is not particularly limited, but is usually about 0.01 to 20% by weight, preferably about 0.1 to 10% by weight in the solid insecticidal preparation of the present invention. Is good.
本発明では、他の安定剤、例えば上記一般式（Ｉ）のス
ルフエニルカーバメイト誘導体の安定剤として知られて
いるエポキシ化物、アミン類等を低級脂肪酸塩と共に添
加することにより、本発明の所期の効果をより一層発現
させることもできる。In the present invention, other stabilizers, for example, epoxidized compounds, amines and the like, which are known as stabilizers of the sulfenylcarbamate derivative of the above-mentioned general formula (I), are added together with the lower fatty acid salt to obtain the present invention. The effect of the period can be further expressed.
発明の効果 上記一般式（Ｉ）のスルフエニルカーバメイト誘導体の
固体殺虫製剤に低級脂肪酸の塩を配合することにより、
該製剤の安定性を著しく向上させることができる。Effects of the Invention By incorporating a salt of a lower fatty acid into a solid insecticidal preparation of the sulfenylcarbamate derivative of the above general formula (I),
The stability of the formulation can be significantly improved.
実施例 以下に実施例を掲げて本発明をより一層明らかにする。Examples The present invention will be further clarified with reference to the following examples.
実施例１（粉剤） 化合物１、化合物２又は化合物３ ２ｇ、酢酸ナトリウ
ム１ｇ、クレー粉末〔クニミエ工業(株)製〕９４ｇ及び
カープレツクス８０〔塩野義製薬(株)製〕３ｇを混合し
た後、ハンマーミルで混合粉砕し、２％粉剤を得た。Example 1 (powder) Compound 1, compound 2 or compound 3 2 g, sodium acetate 1 g, clay powder [Kunimie Industry Co., Ltd.] 94 g and Carprex 80 [Shionogi Pharmaceutical Co., Ltd.] 3 g were mixed, and then hammered. It was mixed and pulverized with a mill to obtain 2% powder.
この粉剤をガラスビンに入れて蜜栓し、４０℃で１ケ月
間保存した後、高速液体クロマトグラフイー分析により
粉剤中の有効成分化合物の含量分析を行ない、初期含量
に対する分解率を求めた。The powder was placed in a glass bottle, stoppered, and stored at 40 ° C. for 1 month, and then the content of the active ingredient compound in the powder was analyzed by high performance liquid chromatography analysis to determine the decomposition rate with respect to the initial content.
比較のために酢酸ナトリウムを配合しない以外は上記と
同様にして粉剤を得、分解率を求めた。For comparison, a powder was obtained in the same manner as above except that sodium acetate was not added, and the decomposition rate was determined.
これらの結果を下記第１表に示す。The results are shown in Table 1 below.
実施例２（粒剤） 低級脂肪酸塩、クレー粉末〔クニミエ工業(株)製〕、タ
ルクＧＴＡ〔クニミエ工業(株)製〕及びベントナイト
〔豊順鉱業(株)製〕を下記第２表に示す割合で配合した
混合物にクラレポバール２０５〔クラレ(株)製〕３ｇ及
び水１５ｇを加えて混練し、０．７ｍｍφのスクリーン
を装着したＥＸＫペレツター〔不二パウエル社製〕で造
粒した。得られた粒剤を流乾燥機にて乾燥し、粒状担体
を得た。 Example 2 (Granule) Lower fatty acid salt, clay powder [Kunimi Industry Co., Ltd.], talc GTA [Kunimi Industry Co., Ltd.] and bentonite [Toyoshun Mining Co., Ltd.] are shown in Table 2 below. 3 g of Kuraray Poval 205 (manufactured by Kuraray Co., Ltd.) and 15 g of water were added to the blended mixture and kneaded, and granulated with an EXK pelletizer (manufactured by Fuji Powell) equipped with a 0.7 mmφ screen. The obtained granules were dried with a flow dryer to obtain a granular carrier.
この粒状担体９５ｇに化合物１ ５ｇをスプレー混合し
て５％粒剤を得た。95 g of this granular carrier was spray-mixed with 15 g of Compound 15 to obtain 5% granules.
この粒剤をガラスビンに入れて蜜栓し、４０℃で１ケ月
間保存した後、高速液体クロマトグラフイー分析により
粒剤中の化合物１の含量分析を行ない、初期含量に対す
る分解率を求めた。結果を第２表に示す。This granule was placed in a glass bottle, tightly stoppered, and stored at 40 ° C. for 1 month, and then the content of Compound 1 in the granule was analyzed by high performance liquid chromatography analysis to determine the decomposition rate with respect to the initial content. The results are shown in Table 2.
実施例３（水和剤） 化合物１ ２０ｇ、カープレツクス８０〔塩野義製薬
(株)製〕２８ｇ、クニライト２０１〔クニミエ工業(株)
製〕４８ｇ、酢酸ナトリウム２ｇ、アグリゾールＷ１６
０〔花王石鹸(株)製〕１ｇ及びネオペレツクスＮＯ．６
Ｆ〔花王石鹸(株)製〕１ｇを混合した後、ジエツトミル
〔セイシン企業(株)製〕で微粉砕して２０％水和剤を得
た。 Example 3 (Wettable powder) Compound 1 20 g, Carplex 80 [Shionogi & Co., Ltd.
28 g, Kunilite 201 [Kunimi Industry Co., Ltd.]
Made] 48 g, sodium acetate 2 g, agrisol W16
0 [manufactured by Kao Soap Co., Ltd.] and Neoperex NO. 6
After mixing 1 g of F (manufactured by Kao Soap Co., Ltd.), it was finely pulverized with a jet mill (manufactured by Seishin Enterprise Co., Ltd.) to obtain 20% wettable powder.
この水和剤をガラスビンに入れて蜜栓し、４０℃で１ケ
間保存した後、高速液体クロマトグラフイー分析により
水和剤中の化合物１の含量分析を行ない、初期含量に対
する分解率を求めた。This wettable powder was placed in a glass bottle, stoppered, and stored at 40 ° C. for one time, and then the content of Compound 1 in the wettable powder was analyzed by high performance liquid chromatography analysis to determine the decomposition rate with respect to the initial content. It was
比較のために酢酸ナトリウムを配合せず、クニライト２
０１の配合量を増やす以外は、上記と同様にして水和剤
を得、分割率を求めた。Kunilite 2 without sodium acetate for comparison
A wettable powder was obtained in the same manner as above except that the blending amount of 01 was increased, and the split ratio was determined.
これらの結果を下記第３表に示す。The results are shown in Table 3 below.
Claims (4)
キル基、−（Ｃ１〜Ｃ６アルキレン）ＣＯＯＲ３基又は
−ＣＯＯＲ４基を示す。ここでＲ３及びＲ４はＣ１〜Ｃ
８のアルキル基を示す。〕 で表わされるスルフェニルカーバメイト誘導体の固体殺
虫製剤に低級脂肪酸の塩を配合することを特徴とする安
定な固体殺虫剤組成物。1. A general formula Shows a (C 1 -C 6 alkylene) COOR 3 group or -COOR 4 radical - [wherein R 1 and R 2 are the same or different C 1 -C 8 alkyl group. Here, R 3 and R 4 are C 1 to C
8 represents an alkyl group. ] The stable solid insecticide composition characterized by mix | blending the salt of a lower fatty acid with the solid insecticidal preparation of the sulfenyl carbamate derivative represented by these.
ルボニルエチル基である特許請求の範囲第１項記載の組
成物。2. The composition according to claim 1, wherein R 1 is an isopropyl group and R 2 is an ethoxycarbonylethyl group.
許請求の範囲第１項記載の組成物。3. The composition according to claim 1, wherein R 1 and R 2 are both n-butyl groups.
ル基である特許請求の範囲第１項記載の組成物。4. The composition according to claim 1, wherein R 1 is a methyl group and R 2 is a butoxycarbonyl group.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP6689186A JPH0662372B2 (en) | 1986-03-24 | 1986-03-24 | Stable solid pesticide composition |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP6689186A JPH0662372B2 (en) | 1986-03-24 | 1986-03-24 | Stable solid pesticide composition |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS62221606A JPS62221606A (en) | 1987-09-29 |
| JPH0662372B2 true JPH0662372B2 (en) | 1994-08-17 |
Family
ID=13328986
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP6689186A Expired - Lifetime JPH0662372B2 (en) | 1986-03-24 | 1986-03-24 | Stable solid pesticide composition |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH0662372B2 (en) |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2022064646A (en) * | 2020-10-14 | 2022-04-26 | バイエルクロップサイエンス株式会社 | Composition for preservation of wood |
-
1986
- 1986-03-24 JP JP6689186A patent/JPH0662372B2/en not_active Expired - Lifetime
Also Published As
| Publication number | Publication date |
|---|---|
| JPS62221606A (en) | 1987-09-29 |
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