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JPH0668366B2 - High efficiency coal burner - Google Patents
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JPH0668366B2 - High efficiency coal burner - Google Patents

High efficiency coal burner

Info

Publication number
JPH0668366B2
JPH0668366B2 JP62181033A JP18103387A JPH0668366B2 JP H0668366 B2 JPH0668366 B2 JP H0668366B2 JP 62181033 A JP62181033 A JP 62181033A JP 18103387 A JP18103387 A JP 18103387A JP H0668366 B2 JPH0668366 B2 JP H0668366B2
Authority
JP
Japan
Prior art keywords
coal
burner
pulverized coal
mixing chamber
gasification
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
JP62181033A
Other languages
Japanese (ja)
Other versions
JPS6428407A (en
Inventor
真二 田中
仁一 戸室
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Hitachi Ltd
Original Assignee
Hitachi Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Hitachi Ltd filed Critical Hitachi Ltd
Priority to JP62181033A priority Critical patent/JPH0668366B2/en
Publication of JPS6428407A publication Critical patent/JPS6428407A/en
Publication of JPH0668366B2 publication Critical patent/JPH0668366B2/en
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

Description

【発明の詳細な説明】 〔産業上の利用分野〕 本発明は、噴流層粉末固体燃料ガス化装置に係り、特に
粉末固体燃料として石炭を使用し、これと未燃カーボン
を50%以上含有したチヤーを同時に閉塞なく連続的に
供給でき、効率的にガス化できるバーナに関する。
Description: TECHNICAL FIELD The present invention relates to a spouted bed powder solid fuel gasifier, in particular, coal is used as a powder solid fuel and contains 50% or more of unburned carbon. The present invention relates to a burner that can continuously supply a chain at the same time without blockage and can efficiently gasify.

〔従来の技術〕[Conventional technology]

石炭は化石燃料資源の中で埋蔵量が最大であり石油代替
エネルギーとして注目されている。
Coal has the largest reserves among fossil fuel resources and is attracting attention as an alternative energy source for oil.

石炭は、固体で取り扱いが不便な上、灰分,硫黄,窒素
等を含有しており有効利用するためには液化,ガス化等
によりクリーンなエネルギー源に変換し、利用すること
が望まれる。現在、石炭のクリーン燃料化の有力な方法
として石炭ガス化が注目されている。その中でも、石炭
からのクリーンガスを発電に用いる石炭ガス化複合発電
方式が注目されている。石炭ガス化発電複合発電方式を
支える重要技術の1つは石炭ガス化技術であり発電用ガ
ス化炉としては、高いガス化効率,電力需要に対応でき
る運転性及び信頼性、幅広い炭種に対する適用性等が要
求される。これらを満足させるには、微粉炭を気流中で
反応させる噴硫層ガス化炉が有望である。
Coal is solid and inconvenient to handle, and contains ash, sulfur, nitrogen and the like, and in order to be effectively used, it is desired to convert it into a clean energy source by liquefaction, gasification and the like before use. At present, coal gasification is drawing attention as an effective method for converting coal into a clean fuel. Among them, a coal gasification combined cycle power generation system that uses clean gas from coal for power generation is drawing attention. Coal gasification power generation One of the important technologies that supports the combined power generation system is coal gasification technology. As a gasification furnace for power generation, high gasification efficiency, operability and reliability that can meet power demand, application to a wide range of coal types Sex is required. In order to satisfy these requirements, a fusulized bed gasification furnace in which pulverized coal is reacted in an air stream is promising.

噴硫層ガス化炉は、米国でKoppers−Totzek方式,CE
方式,Texaco方式等が大容量化,高性能化を目指して開
発中である。我国では、昭和25〜35年の間に数社が
開発に着手し、アンモニア合成用ガスの製造を目的とし
て独自のガス化炉を開発した。
The blown-bed gasifier is the Koppers-Totzek system, CE in the United States.
Methods, Texaco method, etc. are under development aiming at large capacity and high performance. In Japan, several companies started development in 1945-35, and developed their own gasifier for the purpose of producing ammonia synthesis gas.

これらに用いられているガス化炉の効率を向上させる手
段として、大半が固体燃料をできるだけ炉内に滞留さ
せ、ガス化反応を促進させることを主眼としている。し
かし、どのようなガス化炉でも、ガス化炉から反応しな
いで飛散していく未燃カーボンを含有したチヤーが存在
する。そこで、この飛散チヤー量を抑制する手段とし
て、炉構造,バーナの設置位置,バーナの吹き出し速度
等につき検討しているが、飛散抑制には限界がある。
As a means for improving the efficiency of the gasification furnaces used for these, most of them mainly aim to retain the solid fuel in the furnace as much as possible to promote the gasification reaction. However, in any gasification furnace, there is a chain containing unburned carbon that scatters from the gasification furnace without reacting. Therefore, as a means for suppressing the amount of scattering char, the furnace structure, the installation position of the burner, the blowing speed of the burner, etc. are examined, but there is a limit to the suppression of scattering.

よつて、どのような反応装置でも、飛散チヤーのガス化
炉への循環系を有している。その供給方式には、1)常
時石炭と一緒に供給する場合、2)間欠的にある一定時
間ごとに供給する方式がある。
Therefore, any reactor has a circulating system to the gasification furnace of the scattered chaff. The supply method includes 1) a case where it is always supplied with coal, and 2) a case where it is supplied intermittently at a certain fixed time.

効率を常時ある一定以上のレベルに維持するには、1)
の常時供給する方式になる。
To maintain efficiency above a certain level at all times, 1)
It will be a method of always supplying.

そのため、チヤーを閉塞もなく連続的に供給し効率よく
ガス化できるバーナの構造及び手段が重要になる。
Therefore, a structure and means of a burner that can efficiently supply gas without causing blockage by continuously supplying it are important.

チヤーを供給する手段としては、1)石炭とチヤーを別
々のバーナから供給する方式。2)同一のバーナからガ
ス化炉内に供給する方式がある。1)の方式では、炉内
に設置している石炭供給用バーナとは別個の位置にチヤ
ー供給用のバーナを設置するため炉内の粒子の流れ状態
に悪影響を及ぼしチヤー飛散量を増大させる可能性があ
る。2)の方式では、定められた位置から石炭と一緒に
チヤーを供給するため、炉内の粒子の流れに対してはそ
れ程影響を及ぼさない。また、新たなガス化剤ラインも
いらず、制御が簡単である。
As a means for supplying the char, 1) a method of supplying coal and the char from separate burners. 2) There is a method of supplying gas from the same burner into the gasification furnace. In the method of 1), since the burner for supplying the coal is installed at a position different from the burner for supplying the coal installed in the furnace, it is possible to adversely affect the flow state of the particles in the furnace and increase the amount of the scattered shatter. There is a nature. In the method of 2), since the chain is supplied together with the coal from the determined position, the flow of particles in the furnace is not so affected. Moreover, a new gasifying agent line is not required and the control is easy.

よつて、1)と2)の方式を比較すると2)の方式が有
利と言える。そこで2)の方式で本発明を考えることに
した。
Therefore, comparing the methods 1) and 2), it can be said that the method 2) is advantageous. Therefore, we decided to consider the present invention by the method of 2).

従来、微粉炭とチヤーを同時に供給させるバーナ構造は
基本的には2方式に代表される。1)同心円状の円筒内
を2重管にしその中心流路と外筒管内にチヤー及び微粉
炭を供給する方式(特開昭59−134405)。2)バーナ内
に粉末供給管をそれぞれ並列に挿入する方式(特開昭56
−124812)等がある。
Conventionally, a burner structure for simultaneously supplying pulverized coal and chewer is basically represented by two methods. 1) A method in which a concentric circular cylinder is made into a double tube and a channel and a pulverized coal are supplied into the central flow passage and the outer tube (JP-A-59-134405). 2) A method in which the powder supply pipes are inserted in parallel in the burner (JP-A-56)
-124812) etc.

〔発明が解決しようとする問題〕[Problems to be solved by the invention]

固形燃料のガス化は、一般に粉末固体燃料を輸送するの
に必要なガス量をできるだけ低減させる必要がある。こ
の理由は、粉末燃料搬送用として一般に不活性ガス(窒
素及び一酸化炭素等)を用いており、その量が多いと炉
内温度の上昇を抑制するため、反応面及びスラグ流下に
悪影響を及ぼす。このため搬送用ガス量を低減させる必
要があり、必然的に混層流の粉末燃料の密度が高くな
る。よつて、前記(1)を用いると石炭供給管曲部が摩
耗することが考えられる。また、石炭供給系にチヤー供
給管を設置すると抵抗が増大し、バーナ内及び石炭供給
ラインで閉塞することが考えられる。また、1)の方式
の先端部が外部混合型であり、石炭とチヤーの混合状態
及びこれら粉末燃料とガス化剤との接触が条件変化時に
悪化する等の欠点が考えられる。
Gasification of solid fuels generally requires reducing the amount of gas required to transport powdered solid fuels as much as possible. The reason for this is that an inert gas (nitrogen, carbon monoxide, etc.) is generally used for powder fuel transportation, and if the amount is large, it suppresses the rise in the temperature inside the furnace, which adversely affects the reaction surface and the slag flow. . Therefore, it is necessary to reduce the amount of carrier gas, which inevitably increases the density of the powder fuel in the mixed laminar flow. Therefore, when the above (1) is used, it is considered that the bent portion of the coal supply pipe is worn. In addition, if a chain supply pipe is installed in the coal supply system, resistance increases, and it is conceivable that blockage will occur in the burner and in the coal supply line. In addition, the tip of the method 1) is an external mixing type, and there is a possibility that the mixed state of coal and cheer and the contact between the powdered fuel and the gasifying agent deteriorate when the conditions change.

2)の方式では、バーナ先端出口部でのガス化剤との接
触が悪く未燃カーボンを多量に含有したチヤーが増大す
る可能性がある。
In the method 2), the contact with the gasifying agent at the outlet of the burner tip is poor and there is a possibility that the amount of the char containing a large amount of unburned carbon will increase.

本発明の目的は、粉末固体燃料とチヤーを単体のバーナ
から閉塞もなく連続的に供給できると同時に粉末燃料と
ガス化剤との接触を良好にでき効率向上をはかることの
できるバーナの構造を提供するにある。
An object of the present invention is to provide a burner structure capable of continuously supplying powdered solid fuel and a chain from a single burner without blockage, and at the same time improving the contact between the powdered fuel and the gasifying agent to improve efficiency. To provide.

〔問題点を解決するための手段〕[Means for solving problems]

上記目的は、バーナ内に設置した粉末供給管内を二重管
にし、中心流路に微粉炭、その外筒管内にチヤーを別々
に流通させるとともに、粉末供給管先端内部で石炭とチ
ヤーを混合させる粒子混合室及びガス化剤(酸素,空
気)との接触を良好にするためバーナ出口先端部にガス
化混合室を設けることにより、粉末供給管内での閉塞も
なく、連続的に供給でき、かつ効率向上がはかれるよう
にしたものである。
The above-mentioned purpose is to make the inside of the powder supply pipe installed in the burner into a double pipe, to separately circulate the pulverized coal in the central flow passage and the inside of its outer cylinder pipe, and to mix the coal and the chaper inside the tip of the powder supply pipe. By providing a gasification mixing chamber at the burner outlet tip in order to make good contact with the particle mixing chamber and the gasifying agent (oxygen, air), there is no blockage in the powder supply pipe, and continuous supply is possible, and It is designed to improve efficiency.

〔作用〕[Action]

すなわち、バーナ内に供給される石炭とチヤーをバーナ
手前から二重管にしてそれぞれ別々の入口から供給し、
中心流路に微粉炭その外筒管内にチヤーを流通させるこ
とにより中心流路では抵抗となるものがないことから微
粉炭の閉塞がなくなる。また、チヤーは微粉炭に比べて
かつ密度が小さいため、搬送用に用いるガス量が少なく
てすむことから摩耗等がなくなる。また、バーナ内粉末
供給管先端内部で石炭とチヤーを混合(粉末混合室)さ
せた後、ガス化剤(酸素又は空気)と接触させる部屋
(ガス化混合室)を設置した、いわゆる二段混合室を設
けることにより接触を良好にし性能を向上させようとし
たものである。
That is, the coal and the chaff to be fed into the burner are made into double pipes from the front of the burner and fed from different inlets,
Since the pulverized coal is circulated in the outer tube of the pulverized coal in the central flow passage, there is no resistance in the central flow passage, so that the pulverized coal is not clogged. In addition, since the density of char is smaller than that of pulverized coal and the amount of gas used for transportation is small, wear does not occur. In addition, so-called two-stage mixing, in which a room (gasification mixing chamber) for contacting with a gasifying agent (oxygen or air) is installed after mixing coal and char inside the tip of the powder supply pipe in the burner (powder mixing chamber) By providing the chamber, the contact is improved and the performance is improved.

〔実施例〕〔Example〕

実施例は、粉末固体燃料を高圧のガス化炉内に供給する
場合に本発明を適用したものである。
In the embodiment, the present invention is applied to the case where the powdered solid fuel is supplied into the high pressure gasification furnace.

本発明を第1図及び第2図に従つて説明する。The present invention will be described with reference to FIGS. 1 and 2.

全体は、外筒管(又は冷却管)9、ガス化剤供給系2、
粉末供給管5、微粉炭供給管13より成る。バーナ全体
は四重管構造となつており、バーナ内は冷却水流通ライ
ン10を通る冷却水3によつて冷却される。
As a whole, an outer cylinder pipe (or a cooling pipe) 9, a gasifying agent supply system 2,
It comprises a powder supply pipe 5 and a pulverized coal supply pipe 13. The entire burner has a quadruple pipe structure, and the inside of the burner is cooled by the cooling water 3 passing through the cooling water distribution line 10.

微粉炭供給管中心流路4は、粉末供給管5内に埋設され
ている。粉末供給管5と微粉炭供給管13との環状管内
12にガス化炉から飛散して回収された末燃カーボンを
多量に含有したチヤー1が圧送されて出口孔19より流
出する。微粉炭供給管13と粉末供給管5は一体もので
あり、粉末供給管先端内部は微粉炭17とチヤー1を混
合せしめる粒子混合室15を設け、お互いの混合を良く
した後、外筒管9の先端内でガス化剤出口孔8から噴出
するガス化剤(酸素又は空気)と石炭+チヤーが良好に
接触するような部屋すなわちガス化混合室16を設ける
ことにより、粒子とガス化剤との接触を良好に促進させ
た後、噴出口11より噴出させるものである。
The pulverized coal supply pipe central flow path 4 is embedded in the powder supply pipe 5. In the annular pipe 12 between the powder supply pipe 5 and the pulverized coal supply pipe 13, the chain 1 containing a large amount of end-burning carbon scattered and recovered from the gasification furnace is pressure-fed and flows out from the outlet hole 19. The pulverized coal supply pipe 13 and the powder supply pipe 5 are integrated, and a particle mixing chamber 15 for mixing the pulverized coal 17 and the chain 1 is provided inside the tip of the powder supply pipe to improve mutual mixing, and then the outer pipe 9 By providing a room in which the gasifying agent (oxygen or air) ejected from the gasifying agent outlet hole 8 and the coal + char are in good contact with each other inside the tip of the gas, that is, the gasification mixing chamber 16, the particles and the gasifying agent are provided. Is favorably promoted and then ejected from the ejection port 11.

高効率バーナは四重管構造とし、外筒管内に冷却水を流
通した。このバーナの材質は、ステンレス(SUS30
4)を用いて製作した。
The high-efficiency burner had a quadruple tube structure, and the cooling water was circulated in the outer tube. The material of this burner is stainless steel (SUS30
4) was used.

各部の寸法は、バーナの外筒管の外径φ48,長さ60
0mm,ガス化剤保護管7の外径φ32である。粉末供給
管5は内径φ12、微粉炭供給管13の外径φ6、内径
φ4のものを用いた。また、粉末供給管5先端内部の粒
子混合室15の大きさは内径φ12、微粉炭供給管13
の先端から粉末供給管先端までの長さ12mm、ガス化混
合室16の大きさは、内径φ20、粉末供給管5先端か
ら外筒管先端までの長さ24mm、ガス化剤噴出孔の孔径
をφ0.5mmとした。
The dimensions of each part are the outer diameter of the outer cylinder of the burner φ48, length 60
0 mm, the outer diameter of the gasifying agent protection tube 7 is φ32. The powder supply pipe 5 used had an inner diameter of 12 and an outer diameter of the pulverized coal supply pipe 13 of 6 and an inner diameter of 4. The size of the particle mixing chamber 15 inside the tip of the powder supply pipe 5 is an inner diameter φ12, and the pulverized coal supply pipe 13 is
12 mm from the tip of the powder supply tube to the tip of the powder supply tube, the size of the gasification mixing chamber 16 is 20 mm inside diameter, 24 mm from the tip of the powder supply tube 5 to the tip of the outer tube, and the diameter of the gasifying agent ejection hole φ0.5 mm

微粉炭の搬送条件は、搬送ガス量8kg/hである。チヤ
ー搬送条件は、搬送ガス量2kg/hである。チヤー供給
量は2〜3kg/h、微粉炭供給量は35kg/hとした。
The pulverized coal transportation condition is a carrier gas amount of 8 kg / h. The carrier transport condition is a carrier gas amount of 2 kg / h. The supply rate of the char was 2-3 kg / h, and the supply rate of the pulverized coal was 35 kg / h.

本発明バーナは、ガス化炉反応部(内径300mm、高さ
750mm)に1本設置した。
One burner of the present invention was installed in the reaction part of the gasification furnace (inner diameter 300 mm, height 750 mm).

ガス化剤には酸素を用い、酸素供給量と微粉炭供給量の
比(以下O/coalと称す)が0.6〜0.8となるように2
4〜32kg/h供給した。試験圧力は4kg/cm2Gで行
つた。用いた石炭は太平洋炭である。
Oxygen is used as the gasifying agent, and the ratio of the oxygen supply amount to the pulverized coal supply amount (hereinafter referred to as O 2 / coal) is adjusted to 0.6 to 0.8.
4 to 32 kg / h was supplied. The test pressure was 4 kg / cm 2 G. The coal used is Pacific coal.

試験方法は、微粉炭及びチヤーの供給量を一定にして、
/coalが0.6から0.8になるように、酸素量を24か
ら32kg/hに変化させて試験を行つた。
The test method is to supply a constant amount of pulverized coal and a
The test was conducted by changing the oxygen amount from 24 to 32 kg / h so that the O 2 / coal was from 0.6 to 0.8.

その結果、バーナ内での圧力変動による微粉炭供給管出
口等での閉塞もなく、良好に供給でき特に問題は発生し
なかつた。
As a result, there was no blockage at the pulverized coal supply pipe outlet or the like due to pressure fluctuations in the burner, and good supply was possible with no particular problems.

実験結果を第3図に示す。横軸に酸素供給量/微粉炭+
チヤー(O/coal+チヤー)、縦軸に効率を示す。こ
の図のように従来型ドーナに比べて、本発明バーナは、
冷ガス効率、カーボンガス化率とも2〜3%程高くなり
効果があることがわかつた。
The experimental results are shown in FIG. Oxygen supply on the horizontal axis / pulverized coal +
The chart (O 2 / coal + chair) shows the efficiency on the vertical axis. As shown in this figure, the burner of the present invention is
It was found that both the cold gas efficiency and the carbon gasification rate are increased by about 2 to 3%, which is effective.

〔発明の効果〕〔The invention's effect〕

本発明によれば、微粉炭とチヤーの混合粒子を閉塞もな
く、連続的に供給することが可能で、バーナ内に2段混
合室を設置することにより従来型のバーナに比べて効率
を向上させる効果を有する。
According to the present invention, it is possible to continuously supply the mixed particles of the pulverized coal and the char without clogging, and by installing the two-stage mixing chamber in the burner, the efficiency is improved as compared with the conventional burner. Has the effect of

【図面の簡単な説明】[Brief description of drawings]

第1図、本発明の高効率粉末混合バーナの横断面図、第
2図、本発明のバーナの正面図及び第3図は燃焼効率と
(酸素供給量/石炭+チヤー)比との関係を示す線図で
ある。 1……チヤー、2……ガス化剤(酸素又は空気)、3…
…冷却水、4……微粉炭中心流路、5……粉末供給管、
6……ガス化剤供給ライン、7……ガス化剤保護管、8
……ガス化剤噴出孔、9……外筒管(又は冷却管)、1
0……冷却水供給ライン、11……噴出口、12……チ
ヤー流通ライン、13……微粉炭供給管、14……微粉
炭流通ライン、15……粒子混合室、16……ガス化混
合室、17……微粉炭、18……微粉炭噴出孔、19…
…チヤー噴出孔。
FIG. 1, a cross-sectional view of a high-efficiency powder mixing burner of the present invention, FIG. 2, a front view of the burner of the present invention and FIG. 3 show the relationship between combustion efficiency and (oxygen supply amount / coal + chair) ratio. It is a diagram showing. 1 ... chair, 2 ... gasification agent (oxygen or air), 3 ...
… Cooling water, 4 …… Pulverized coal central flow path, 5 …… Powder supply pipe,
6 ... Gas agent supply line, 7 ... Gas agent protective tube, 8
...... Gasifying agent ejection holes, 9 ...... Outer cylinder pipe (or cooling pipe), 1
0 ... Cooling water supply line, 11 ... Spout, 12 ... Chir distribution line, 13 ... Pulverized coal supply pipe, 14 ... Pulverized coal distribution line, 15 ... Particle mixing chamber, 16 ... Gasification mixing Chamber, 17 ... Pulverized coal, 18 ... Pulverized coal ejection hole, 19 ...
... Cha spout hole.

Claims (1)

【特許請求の範囲】[Claims] 【請求項1】同軸上に円管を数個重ね合わせて微粉炭と
その搬送ガスとの流路,チャーとその搬送ガスとの流路
及びガス化剤の流路を個別に設けた石炭バーナにおい
て、前記円管を四個重ね合わせて四重管構造とし、該四
重管の最も内側の中心流路に微粉炭とその搬送ガスを供
給し、その外側の流路にチャーとその搬送ガスを供給
し、更にその外側の流路にガス化剤を供給し、最外周の
流路に冷却水を供給し、前記微粉炭とその搬送ガスとの
流路と前記チャーとその搬送ガスとの流路とが合流する
粒子混合室及び該粒子混合室の前方にて該粒子混合室で
混合された微粉炭とチャーにガス化剤を合流させるガス
化混合室を設けたことを特徴とする高効率石炭バーナ。
1. A coal burner in which several circular pipes are coaxially overlapped and a flow path for pulverized coal and its carrier gas, a flow path for char and its carrier gas, and a flow path for a gasifying agent are individually provided. In the above, four circular tubes are stacked to form a quadruple tube structure, pulverized coal and its carrier gas are supplied to the innermost central channel of the quadruple tube, and char and its carrier gas are supplied to its outer channel. Of the pulverized coal and its carrier gas, and the char and its carrier gas. A particle mixing chamber in which the flow path merges, and a gasification mixing chamber that joins the pulverized coal mixed in the particle mixing chamber with the gasifying agent in front of the particle mixing chamber are provided. Efficiency coal burner.
JP62181033A 1987-07-22 1987-07-22 High efficiency coal burner Expired - Fee Related JPH0668366B2 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP62181033A JPH0668366B2 (en) 1987-07-22 1987-07-22 High efficiency coal burner

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP62181033A JPH0668366B2 (en) 1987-07-22 1987-07-22 High efficiency coal burner

Publications (2)

Publication Number Publication Date
JPS6428407A JPS6428407A (en) 1989-01-31
JPH0668366B2 true JPH0668366B2 (en) 1994-08-31

Family

ID=16093593

Family Applications (1)

Application Number Title Priority Date Filing Date
JP62181033A Expired - Fee Related JPH0668366B2 (en) 1987-07-22 1987-07-22 High efficiency coal burner

Country Status (1)

Country Link
JP (1) JPH0668366B2 (en)

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6986311B2 (en) * 2003-01-22 2006-01-17 Joel Vatsky Burner system and method for mixing a plurality of solid fuels

Family Cites Families (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS6215600A (en) * 1985-07-15 1987-01-23 中興化成工業株式会社 Sound insulating material

Also Published As

Publication number Publication date
JPS6428407A (en) 1989-01-31

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