JPH0679549B2 - Clear liquid whiteness improving agent for frozen fish meat surimi or fish paste product and method of using the same - Google Patents
Clear liquid whiteness improving agent for frozen fish meat surimi or fish paste product and method of using the sameInfo
- Publication number
- JPH0679549B2 JPH0679549B2 JP60128280A JP12828085A JPH0679549B2 JP H0679549 B2 JPH0679549 B2 JP H0679549B2 JP 60128280 A JP60128280 A JP 60128280A JP 12828085 A JP12828085 A JP 12828085A JP H0679549 B2 JPH0679549 B2 JP H0679549B2
- Authority
- JP
- Japan
- Prior art keywords
- whiteness
- parts
- surimi
- frozen
- liquid
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
Landscapes
- Fish Paste Products (AREA)
Description
【発明の詳細な説明】 本発明は冷凍魚肉摺身及び水産練り製品用の白度向上剤
及びその使用方法に関する。The present invention relates to a whiteness improving agent for frozen fish meat surimi and fish paste products and a method of using the same.
近年,魚場の遠隔地化等の問題に依り魚価の上昇を来た
し,その結果歩留向上のために限度ぎりぎりまでの採
肉,水晒の制限,鮮度の低下した魚肉の使用等製品の白
度と矛盾した条件を強いられ,その対策として摺身又は
水産練り製品の味覚,物性を低下することなく白度を向
上する添加剤が要望されている。In recent years, fish prices have risen due to problems such as the remoteness of fish farms. As a result, to improve the yield, meat mining to the limit, water exposure, use of fish meat with low freshness, etc. There is a demand for an additive that improves the whiteness without deteriorating the taste and physical properties of surimi or fish paste products as a countermeasure against the conditions contradictory to the degree.
現在,冷凍摺身は魚肉に冷凍変性防止剤としてソルビト
ール,庶糖等の糖質及びポリリン酸塩を加え,擂かい後
凍結する事が一般に行なわれている。白度を向上させる
ために,これに油脂,界面活性剤等を添加する試みが種
々行なわれて来た。例えば特公昭48−18468号では摺身
に対しグリセリン脂肪酸エステルを添加する冷凍魚肉摺
身の製造方法が提案されており、特公昭54−28464号で
はグリセリンの脂肪酸エステルを主成分とする界面活性
剤にエチルアルコール,プロピレングリコール,D−ソル
ビトール…糖類のうちの一種又は二種以上を溶解した水
溶液を配合した水産練製品用品質改良剤が提案されてい
る。この他,元来冷凍魚肉摺身の製造には不可欠の添加
剤である糖質とポリリン酸塩にこの他の添加物を均一に
混合した摺身添加物の製造方法も提案されている(特公
昭59−39114号)。At present, frozen surimi is generally added to fish meat by adding carbitol such as sorbitol and sucrose as a freezing denaturing agent, and polyphosphate, and then freezing after grinding. Various attempts have been made to add fats and oils, surfactants, etc. to improve whiteness. For example, Japanese Patent Publication No. 48-18468 proposes a method for producing frozen fish meat surimi by adding glycerin fatty acid ester to the surimi, and Japanese Patent Publication No. 54-28464 discloses a surfactant containing a fatty acid ester of glycerin as a main component. There has been proposed a quality improving agent for fishery paste products, which comprises an aqueous solution in which one or more of ethyl alcohol, propylene glycol, D-sorbitol ... Sugar is dissolved. In addition, a method for producing a surimi additive, which is a mixture of sugar and polyphosphate, which are essentially indispensable additives for the production of frozen fish meat, and other additives, has been proposed (special feature). Kosho 59-39114).
しかしながら,従来の添加剤には様々な欠点がある。例
えば,グリセリン脂肪酸モノエステル(モノグリセリ
ド)を主成分とした水溶液製剤は一度脱水した肉質に余
分な水を加える事になるため,−10℃〜−40℃にもなる
低温下での使用の際には含有成分中の水分が固結や凍結
をおこす上に,粉末製剤で造るのと同様にカマボコ等の
製品を造った場合,粉末製剤の場合よりも著しくゼリー
強度の低い製品になってしまう。更に,モノグリセリド
を主成分とした粉末製剤には重大な欠点があり,それは
モノグリセリドは安価で分子蒸留等に依り精製も容易で
食品分野でも古くより利用されているが,結晶に多形が
あり溶融物より結晶化直後のα形は起泡力が最も強い
が,常温で保存中に安定なβ形に変化しこの物は起泡力
もα形の半分以下で効果が安定しないと云う事である。
又,前記特公昭59−39114号公報に紹介されているよう
な糖アルコールに液状油脂を微粒子状に分散させた粉末
製剤の場合にはソルビトールが糖アルコールとして用い
られる例が多いが,ソルビトール粉末の固結や空気にさ
らされる表面積が大きくなるため製剤の保存中に油脂が
自動酸化され変敗臭を発生するという致命的な欠点があ
る。However, conventional additives have various drawbacks. For example, an aqueous solution formulation containing glycerin fatty acid monoester (monoglyceride) as the main ingredient requires extra water to be added to the once dehydrated meat, so when used at a low temperature of -10 ℃ to -40 ℃. In addition to the solidification and freezing of water in the ingredients, when a product such as Kamaboko is made in the same way as a powder formulation, the product has a significantly lower jelly strength than a powder formulation. In addition, powdered preparations containing monoglyceride as a main component have serious drawbacks. Monoglyceride is inexpensive and easy to purify by molecular distillation and has been used in the food field for a long time. The α form immediately after crystallization has the strongest foaming power than the product, but it changes to a stable β form during storage at room temperature, and it is said that the foaming power is less than half of the α form and the effect is not stable. .
Further, in the case of powder formulations in which liquid oil and fat are finely dispersed in sugar alcohol as described in JP-B-59-39114, sorbitol is often used as the sugar alcohol, but sorbitol powder There is a fatal drawback in that fats and oils are autoxidized during storage of the preparation to generate a rancid odor due to a large surface area exposed to solidification and air.
本発明者らはこれら従来の発明を追試すると共に,従来
言われている添加剤を数種類組み合わせて魚肉に添加し
て摺身を製造してその色並びに品質に及ぼす効果を研究
した。その結果,夫々が常温液体である植物油とソルビ
タン脂肪酸エステル及びポリグリセリン脂肪酸エステル
の組合わせが保存期間中に粉末製造のように糖アルコー
ルの固結を起こしたり油脂成分が自動酸化したりするこ
とがなく,冷凍魚肉摺身の白度向上に関して,他の配合
に比べ著しい効果を有し,水を含有成分として有してい
ないので,−10℃〜−40℃にもなる低温下での使用の際
にも固結や凍結をおこすことなく,魚肉と擂かい時に分
散も非常に容易であり,又これを添加して製造したカマ
ボコの白度向上が見られゼリー強度が低下していないこ
とを発見しこの発明を完成するに至った。The present inventors repeated these conventional inventions and, at the same time, added several kinds of conventionally known additives to fish meat to produce surimi and studied its effect on color and quality. As a result, the combination of vegetable oil, which is liquid at room temperature, and sorbitan fatty acid ester and polyglycerin fatty acid ester, respectively, may cause the solidification of sugar alcohol and the autoxidation of fats and oils during the storage period as in powder production. However, it has a significant effect on improving the whiteness of frozen fish meat compared to other formulations, and since it does not contain water as a component, it can be used at temperatures as low as -10 ℃ to -40 ℃. It does not solidify or freeze, and it is very easy to disperse when it is mixed with fish meat. Moreover, the whiteness of the kamaboko produced by adding it is improved and the jelly strength is not reduced. I discovered it and came to complete this invention.
更に本発明について詳述すると,その白度向上剤として
は各々常温で液体のソルビタン脂肪酸エステル1−5部
と,ポリグリセリン脂肪酸エステル1−5部と,植物油
1−10部を均一に混合した澄明な油性液状である。植物
油としてはコーン油,大豆油,なたね油,等が好まし
く,ソルビタン脂肪酸エステルとしてはソルビタントリ
オレエート,ソルビタンモノオレエートが好ましく,ポ
リグリセリン脂肪酸エステルとしてはテトラグリセリン
ペンタオレエート,ヘキサグリセリンペンタオレエート
が好ましい。発明者らは上記白度向上剤を摺身製造工程
中の魚肉の擂かい時に常法によりソルビトール及びポリ
リン酸ソーダと共に魚肉に対し0.1−1%添加すると著
しく摺身の白度が向上することを発見した。The present invention will be further described in detail. As its whiteness improving agent, a clear mixture obtained by uniformly mixing 1-5 parts of sorbitan fatty acid ester, 1-5 parts of polyglycerin fatty acid ester, and 1-10 parts of vegetable oil, each of which is liquid at room temperature. It is an oily liquid. The vegetable oil is preferably corn oil, soybean oil, rapeseed oil, etc., the sorbitan fatty acid ester is preferably sorbitan trioleate or sorbitan monooleate, and the polyglycerin fatty acid ester is preferably tetraglycerin pentaoleate or hexaglycerin pentaoleate. . The inventors found that the whiteness of the surimi is remarkably improved by adding 0.1-1% to the fish meat together with sorbitol and sodium polyphosphate by a conventional method when the fish meat is added with the above-mentioned whiteness improver during the polishing of the surimi. discovered.
次に実施例により本発明の態様を説明する。Next, embodiments of the present invention will be described with reference to examples.
実施例1 新鮮なスケソウダラを使用して常法により脱水肉(水分
83%)を得る。この脱水肉をサイレントカッター上に移
し、脱水肉100部に対してソルビトール(東和化成工業
(株)製,WP)4部,砂糖4部,重合リン酸塩(大洋化
学工業(株)製,マスコリンF−26)0.3部,並に本発
明の液状白度向上剤(コーン油4部,ソルビタンモノオ
レエート1部及びテトラグリセリンペンタオレエート1
部を混合したもの)0.4部を加え5分間擂かいする。次
に,−40度に急速冷凍したのち−20度の冷蔵庫に保存し
て冷凍摺身を製造した。又,この冷凍摺身を用いてカマ
ボコを製造した。ただし,この場合は増量剤としての澱
粉を加えずに,即ち,冷凍摺身を5度の定温室で解凍し
た後,食塩を摺身に対して3%添加し20分間擂かいし,
ポリエチレン製チューブに充填した85度の熱油で60分間
加熱したのち,流水中で冷却してカマボコ製品とした
(以下の実施例でも同じ)。Example 1 Dehydrated meat (water content) was prepared by a conventional method using fresh pollock.
83%). Transfer the dehydrated meat to a silent cutter, and for 100 parts of dehydrated meat, 4 parts sorbitol (WP, Towa Kasei Co., Ltd., WP), 4 parts sugar, polymerized phosphate (manufactured by Taiyo Kagaku Co., Ltd., muskolin) F-26) 0.3 part, as well as the liquid whiteness improver of the present invention (corn oil 4 parts, sorbitan monooleate 1 part and tetraglycerin pentaoleate 1)
(Mixed parts) 0.4 parts and stir for 5 minutes. Next, it was frozen rapidly at -40 degrees and stored in a refrigerator at -20 degrees to produce frozen surimi. Moreover, Kamaboko was manufactured using this frozen surimi. However, in this case, without adding starch as a bulking agent, that is, after thawing the frozen surimi in a constant temperature room of 5 degrees, add 3% of salt to the surimi and grind for 20 minutes,
After heating for 60 minutes with hot oil of 85 degrees filled in a polyethylene tube, it was cooled in running water to obtain a champagne product (the same applies to the following examples).
実施例2 実施例1の白度向上剤の組成をコーン油4部,ソルビタ
ントリオレエート1部及びヘキサグリセリンペンタオレ
エート1部とする以外は実施例1と同様に操作してスケ
ソウダラの冷凍摺身を製造し,又これよりカマボコを製
造した。Example 2 The same procedure as in Example 1 was repeated except that the composition of the whiteness improver of Example 1 was 4 parts of corn oil, 1 part of sorbitan trioleate and 1 part of hexaglycerin pentaoleate, and frozen slides of Alaska pollack. Was manufactured, and Kamaboko was manufactured from this.
実施例3 実施例1の白度向上剤の組成をなたね油1部,ソルビタ
ントリオレエート1部及びヘキサグリセリンペンタオレ
エート1部とする以外は実施例1と同様に操作してスケ
ソウダラの冷凍摺身を製造し,又これよりカマボコを製
造した。Example 3 The frozen surimi of Alaska pollack was operated in the same manner as in Example 1 except that the composition of the whiteness improving agent of Example 1 was 1 part rapeseed oil, 1 part sorbitan trioleate and 1 part hexaglycerin pentaoleate. It was manufactured, and Kamaboko was manufactured from this.
実施例4 実施例1の白度向上剤の組成を大豆油10部,ソルビタン
トリオレエート1部及びテトラグリセリンペンタオレエ
ート3部とする以外は実施例1と同様に操作してスケソ
ウダラの冷凍摺身を製造し,又これよりカマボコを製造
した。Example 4 Frozen surimi of Alaska pollack operated in the same manner as in Example 1 except that the composition of the whiteness improver of Example 1 was 10 parts of soybean oil, 1 part of sorbitan trioleate and 3 parts of tetraglycerin pentaoleate. Was manufactured, and Kamaboko was manufactured from this.
実施例5 実施例1の白度向上剤の組成をコーン油10部,ソルビタ
ンモノオレエート3部及びヘキサグリセリンペンタオレ
エート1部とする以外は実施例1と同様に操作してスケ
ソウダラの冷凍摺身を製造し,又これよりカマボコを製
造した。Example 5 A frozen slide of Alaska pollack was operated in the same manner as in Example 1 except that the composition of the whiteness improver of Example 1 was 10 parts of corn oil, 3 parts of sorbitan monooleate and 1 part of hexaglycerin pentaoleate. Manufactured the body, and also manufactured Kamaboko.
なお,対照の摺身として液状白度向上剤を加えない以外
は実施例1と同様に操作してスケソウダラの冷凍摺身を
製造した。The frozen surimi of Alaska pollack was manufactured in the same manner as in Example 1 except that the liquid whiteness improver was not added as the control surimi.
以上の実施例により製造した摺身及びカマボコの物性を
実験した結果を示す。第1表は摺身の白度の測定結果で
(サンプル数3個の平均。以下同じ),試験方法は冷凍
摺身を−20度で1−6ケ月冷凍貯蔵したのちその一部を
解凍してハンター白度を日本電色工業(株)製,ND−V6B
で測定した。The results of experiments on the physical properties of the surimi and the scorpion fish produced according to the above examples are shown. Table 1 shows the result of measuring the whiteness of the surimi (the average of three samples, the same applies below). The test method was to freeze-store the frozen surimi at -20 degrees for 1-6 months and then thaw a part of it. ND-V6B manufactured by Nippon Denshoku Industries Co., Ltd.
It was measured at.
第2表はカマボコの白度の測定結果,第3表はそのゼリ
ー強度の測定結果で,カマボコのゼリー強度の測定はカ
マボコを一夜5度に放冷したのち室温に戻しレオメータ
ー(不動工業(株)製)で行った。 Table 2 shows the whiteness measurement results of Kamaboko, and Table 3 shows the jelly strength of Kamaboko. The measurement of the Jelly strength of Kamaboko was carried out by allowing the Kamaboko to cool to 5 ° C overnight and then returning it to room temperature. Co., Ltd.).
第1表及び第2表に示すごとく,本発明の白度向上剤を
添加した摺身及びこれから製造したカマボコは対照の摺
身及びこれから製造したカマボコよりも白度向上が見ら
れた。又、第3表に示すごとくゼリー強度については差
がなかった。As shown in Tables 1 and 2, the surimi to which the whiteness improving agent of the present invention was added and the Kamaboko produced from the surimi showed a higher whiteness than the control Surimi and the Kamaboko produced from the surimi. Further, as shown in Table 3, there was no difference in jelly strength.
さらに通常の摺身100部に対して実施例1−5で添加し
た本発明の白度向上剤0.4%を食塩3%と同時に加え,
上記の方法でカマボコを製造して白度及びゼリー強度を
測定したところ,第4表に示す通り対照の摺身によるカ
マボコよりも白度向上が見られたが,ゼリー強度には差
が見られなかった。 Furthermore, 0.4% of the whiteness improving agent of the present invention added in Example 1-5 was added to 100 parts of the usual surimi simultaneously with 3% of salt,
When the whiteness and jelly strength were manufactured by the above method and the whiteness and jelly strength were measured, as shown in Table 4, the whiteness was improved more than the control fish paste, but there was a difference in the jelly strength. There wasn't.
各表に示すごとく,本発明の液状の白度向上剤を加える
ことにより冷凍摺身及びカマボコの白度が向上し,ゼリ
ー強度の低下は見られなかった。 As shown in each table, the addition of the liquid whiteness improver of the present invention improved the whiteness of the frozen surimi and kamaboko, and did not reduce the jelly strength.
───────────────────────────────────────────────────── フロントページの続き (72)発明者 山本 康博 埼玉県川口市大字新井宿1112―19 菱青寮 内 (56)参考文献 特開 昭51−86165(JP,A) 特開 昭54−49365(JP,A) 特公 昭54−28464(JP,B2) 特公 昭59−39114(JP,B2) ─────────────────────────────────────────────────── ─── Continuation of the front page (72) Inventor Yasuhiro Yamamoto 1112-19 Araijuku, Kawaguchi City, Saitama Prefecture Ryosei Dormitory (56) References JP-A-51-86165 (JP, A) JP-A-54-49365 (JP, A) JP-B 54-28464 (JP, B2) JP-B 59-39114 (JP, B2)
Claims (2)
−5部と、常温で液体のポリグリセリン脂肪酸エステル
1−5部と、常温で液体の植物油1−10部とから成る冷
凍魚肉摺身及び同水産練り製品用の澄明な液状白度向上
剤。1. A sorbitan fatty acid ester 1 which is liquid at room temperature
A clear liquid whiteness improver for frozen fish meat and its seafood paste product, which comprises -5 parts, 1-5 parts of a polyglycerin fatty acid ester which is liquid at room temperature, and 1-10 parts of a vegetable oil which is liquid at room temperature.
−5部と、常温で液体のポリグリセリン脂肪酸エステル
1−5部と、常温で液体の植物油1−10部とから成る冷
凍魚肉摺身及び同水産練り製品用の澄明な液状白度向上
剤を、魚肉に対して0.1−1%、糖質及びポリリン酸塩
類と共に加えることを特徴とする冷凍魚肉摺身及び同水
産練り製品用の澄明な液状白度向上剤の使用方法。2. A sorbitan fatty acid ester 1 which is liquid at room temperature.
-5 parts, 1-5 parts of polyglycerin fatty acid ester that is liquid at room temperature, and 1-10 parts of vegetable oil that is liquid at room temperature, a clear liquid whiteness improver for frozen fish meat and fish paste products. A method for using a clear liquid whiteness improver for frozen fish meat and fish paste products, which comprises adding 0.1-1% to fish meat together with sugars and polyphosphates.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP60128280A JPH0679549B2 (en) | 1985-06-14 | 1985-06-14 | Clear liquid whiteness improving agent for frozen fish meat surimi or fish paste product and method of using the same |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP60128280A JPH0679549B2 (en) | 1985-06-14 | 1985-06-14 | Clear liquid whiteness improving agent for frozen fish meat surimi or fish paste product and method of using the same |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS61285964A JPS61285964A (en) | 1986-12-16 |
| JPH0679549B2 true JPH0679549B2 (en) | 1994-10-12 |
Family
ID=14980918
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP60128280A Expired - Lifetime JPH0679549B2 (en) | 1985-06-14 | 1985-06-14 | Clear liquid whiteness improving agent for frozen fish meat surimi or fish paste product and method of using the same |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH0679549B2 (en) |
Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2521059B2 (en) * | 1986-08-28 | 1996-07-31 | 太陽化学株式会社 | Method for inhibiting microbial growth in fish paste products |
| JPH01262777A (en) * | 1988-04-12 | 1989-10-19 | Asama Kasei Kk | Quality-improving agent for frozen ground meat and meat paste product |
| DE102004051932A1 (en) * | 2004-10-25 | 2006-04-27 | Chemische Fabrik Budenheim Kg | Use of alkaline earth phosphates |
Family Cites Families (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5428464B2 (en) * | 1975-01-20 | 1979-09-17 | ||
| JPS5428464A (en) * | 1977-08-04 | 1979-03-03 | Shin Meiwa Ind Co Ltd | Cleaner of bottom of water of pool, etc. |
| JPS5947592B2 (en) * | 1977-09-26 | 1984-11-20 | 武田薬品工業株式会社 | Quality improving agent and quality improvement method for frozen fish minced meat and fish paste products |
| JPS5939114A (en) * | 1982-08-27 | 1984-03-03 | Matsushita Electric Ind Co Ltd | Automatic gain control signal detection device |
-
1985
- 1985-06-14 JP JP60128280A patent/JPH0679549B2/en not_active Expired - Lifetime
Also Published As
| Publication number | Publication date |
|---|---|
| JPS61285964A (en) | 1986-12-16 |
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