JPH0679677B2 - Planetary ball mill with temperature adjustment function - Google Patents
Planetary ball mill with temperature adjustment functionInfo
- Publication number
- JPH0679677B2 JPH0679677B2 JP14463490A JP14463490A JPH0679677B2 JP H0679677 B2 JPH0679677 B2 JP H0679677B2 JP 14463490 A JP14463490 A JP 14463490A JP 14463490 A JP14463490 A JP 14463490A JP H0679677 B2 JPH0679677 B2 JP H0679677B2
- Authority
- JP
- Japan
- Prior art keywords
- mill
- planetary ball
- ball mill
- liquid
- case
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000007788 liquid Substances 0.000 claims description 24
- 238000001816 cooling Methods 0.000 claims description 10
- 238000000227 grinding Methods 0.000 claims description 10
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 10
- 239000003921 oil Substances 0.000 claims description 6
- 230000002093 peripheral effect Effects 0.000 claims description 5
- 239000000314 lubricant Substances 0.000 claims description 4
- 238000010438 heat treatment Methods 0.000 claims description 3
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 claims description 2
- 230000003449 preventive effect Effects 0.000 claims description 2
- 239000000843 powder Substances 0.000 description 5
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 3
- 238000004891 communication Methods 0.000 description 3
- 238000005096 rolling process Methods 0.000 description 3
- 230000002411 adverse Effects 0.000 description 2
- 230000020169 heat generation Effects 0.000 description 2
- 229910052500 inorganic mineral Inorganic materials 0.000 description 2
- 230000001050 lubricating effect Effects 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 239000011707 mineral Substances 0.000 description 2
- 239000002245 particle Substances 0.000 description 2
- 229910000831 Steel Inorganic materials 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 230000006866 deterioration Effects 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000012847 fine chemical Substances 0.000 description 1
- 230000005484 gravity Effects 0.000 description 1
- 239000010687 lubricating oil Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 238000005551 mechanical alloying Methods 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- NJPPVKZQTLUDBO-UHFFFAOYSA-N novaluron Chemical compound C1=C(Cl)C(OC(F)(F)C(OC(F)(F)F)F)=CC=C1NC(=O)NC(=O)C1=C(F)C=CC=C1F NJPPVKZQTLUDBO-UHFFFAOYSA-N 0.000 description 1
- 230000002265 prevention Effects 0.000 description 1
- 238000010298 pulverizing process Methods 0.000 description 1
- 238000003908 quality control method Methods 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 239000003507 refrigerant Substances 0.000 description 1
- 239000004576 sand Substances 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 230000002195 synergetic effect Effects 0.000 description 1
Landscapes
- Crushing And Grinding (AREA)
Description
【発明の詳細な説明】 [産業上の利用分野] 本願発明は遊星ボールミル、特にバッチ式で1回ごとに
装入した砕料を微粉砕するミルに最適であるが、連続式
に対しても適用が可能である。DETAILED DESCRIPTION OF THE INVENTION [Industrial field of application] The present invention is most suitable for a planetary ball mill, particularly a mill for finely pulverizing a crushed material charged in each batch type, but also for a continuous type. Applicable.
[従来の技術] 遊星ボールミルの一般構造は主軸の回転を受けて公転す
る複数のミルポットを主軸の周囲に均等(2ヶならば対
称的に、3ヶ以上ならば主軸から等距離放射状に)に配
設し、該ミルポット自体も自己の回転軸を中心に自転す
るものである。[Prior Art] The general structure of a planetary ball mill is to equip a plurality of mill pots that revolve around the rotation of the spindle evenly around the spindle (if there are two or more, symmetrically and equidistantly from the spindle if there are three or more). The mill pot itself is also arranged to rotate on its own axis of rotation.
具体的には主軸と共に回転するケーシングにミルケース
を固着し、主軸に周設した太陽歯車とミルケース外周に
周設した遊星歯車とを噛合させて、ミルケースを公転し
つつ自転させ、バッチ式においてはミルケースの内へ嵌
合係止したミルポットをケースと共に連動し、粉砕が終
了すればミルポットだけをミルケースから取り外してポ
ット内の微粉を回収するのが典型である。Specifically, the mill case is fixed to the casing that rotates together with the main shaft, and the sun gear around the main shaft meshes with the planetary gears around the outer periphery of the mill case, causing the mill case to rotate while revolving. It is typical to interlock the mill pot fitted and locked in the inside of the container with the case, and when the crushing is completed, remove only the mill pot from the mill case and collect the fine powder in the pot.
通常の転動式ボールミルは粉砕媒体のボールと砕料とが
1本の転動する円筒内でカスケード運動を起し、その重
力落下による圧潰と摩滅によって粉砕させるものである
のに対し、遊星ボールミルは前記の公転,自転運動によ
る遠心力と、コリオリスカとが相乗的に働いて粉砕力は
抜群に強化され優れた効率を誇っている。In the normal rolling ball mill, the balls of the grinding medium and the ground material cause a cascade motion in one rolling cylinder, and the particles are crushed and crushed by the gravity drop, and the planetary ball mill is used. Has a synergistic effect of the centrifugal force due to the above-mentioned orbital and rotational movements and Coriolisca, and the crushing force has been remarkably strengthened and boasts excellent efficiency.
特に高速回転による摩擦力は強力で例えば数ミリサイズ
の珪砂を装入して僅か数分間稼動しただけで平均粒径が
数ミクロンの微粉を得ることができる。In particular, the frictional force due to high-speed rotation is strong, and fine powder having an average particle size of several microns can be obtained by charging silica sand of, for example, several millimeters and operating for only a few minutes.
[発明が解決しようとする課題] 遊星ボールミルは前記のように短時間で強力な破砕効率
を特徴としているが、高速で公転しつつ自転を加えると
言う激しい遊星運動のためミルケースを支える軸受は苛
酷な負荷を集中され発熱と摩耗の悪条件に直面する。勿
論、従来のすべての遊星ボールミルについてもミルケー
スの軸受に対しては潤滑油(主として鉱物性)を循環給
油させることによって悪条件に対応しているが、この場
合別途循環装置が必要になり、その結果装置も大きくな
り費用もかかる。[Problems to be Solved by the Invention] As described above, the planetary ball mill is characterized by a strong crushing efficiency in a short time. However, the bearing that supports the mill case is harsh due to the intense planetary motion of revolving at high speed and adding rotation. Are concentrated under heavy load and face adverse conditions of heat generation and wear. Of course, all conventional planetary ball mills also cope with adverse conditions by circulating lubricating oil (mainly mineral) to the bearings of the mill case, but in this case a separate circulation device is required, As a result, the device is large and expensive.
さらに遊星ボールミルの最大の問題点はミルポット内に
おける強力な摩砕作用のために、粉砕媒体である鋼球な
どが遠心力を受けて激しい摺動運動と衝突を続けるた
め、多量の粉砕摩擦熱を発生し、被粉砕物も昇温して変
質したり化学反応が生じたりして品質上の欠陥を生じる
原因となる虞れがある。この装置がその特徴を評価され
て精緻な化学品,薬品類の微粉砕を対象とするため、こ
の課題は重要である。Furthermore, the biggest problem of the planetary ball mill is that the strong grinding action in the mill pot causes the steel balls, which are the grinding media, to receive centrifugal force and continue to collide with violent sliding motion, so a large amount of grinding friction heat is generated. There is a risk that the crushed product may be heated and the quality of the crushed product may be altered or a chemical reaction may occur to cause quality defects. This problem is important because this device is evaluated for its characteristics and is targeted for fine grinding of fine chemicals and chemicals.
しかも単に発熱の防止だけではなく、粉砕条件を常温以
上の一定温度に保持する機能がもし付与できれば、例え
ばミルポット内に特殊なガスを封入し粉体の表面改質や
メカニカルアロイイングを可能とするなどこの型式の装
置の適応範囲をさらに拡張することもできる。Moreover, if not only the prevention of heat generation but also the function of maintaining the grinding condition at a constant temperature above normal temperature can be added, for example, a special gas is enclosed in the mill pot to enable surface modification of powder and mechanical alloying. It is also possible to further extend the range of applicability of this type of device.
本願発明は以上の課題を解決するために、粉砕条件にお
いて温度調整機能を新たに具備した遊星ボールミルの提
供を目的とする。In order to solve the above problems, an object of the present invention is to provide a planetary ball mill that additionally has a temperature adjusting function under grinding conditions.
[課題を解決するための手段] 本願発明に係る温度調整機能を具えた遊星ボールミル
は、主軸と平行に複数個のミルケースを等間隔に周設
し、該ミルケース内へ嵌入係止するミルポット内へ粉砕
媒体と被粉砕物を収容して主軸を中心とする公転に該ミ
ルケースの自転を加える構成において、前記のミルケー
ス内周面とミルポットの外周面との間に環状の中空部を
形成し、ミルケースの軸受部および該環状中空部へそれ
ぞれ同質の液体を同時に強制循環することによって前記
の課題を解決した。[Means for Solving the Problems] A planetary ball mill having a temperature adjusting function according to the present invention has a plurality of mill cases arranged at equal intervals in parallel with a main shaft, and is inserted into a mill pot that is fitted and locked in the mill case. In a configuration in which a crushing medium and an object to be crushed are accommodated and the rotation of the mill case is added to the revolution around the spindle, an annular hollow portion is formed between the inner peripheral surface of the mill case and the outer peripheral surface of the mill pot, The above problems were solved by forcibly circulating liquids of the same quality into the bearing part and the annular hollow part at the same time.
さらにより具体的には前記の液体が水又は水に減摩剤,
防錆剤等を添加したものであること、または液体が油類
であること、およびさらにこの液体を加熱又は冷却する
手段を流路に具えたことが最も望ましい実施態様である
ことを明らかにした。Even more specifically, said liquid is water or a water-lubricating agent,
It has been clarified that it is the most desirable embodiment that a rust preventive agent or the like is added, or that the liquid is an oil, and that the passage is provided with a means for heating or cooling the liquid. .
[作用] 前記の構成があるから、ミルケースとミルポットの間の
環状中空部へ常に温度をコントロールされた液体が流入
して粉砕条件を一定温度に保持するように作用する。一
般的には冷媒としての働きを務めて発生熱を奪いポット
を冷却する目的が大半であるが、時として特殊な条件を
形成するために特定の温度下に常時保持する機能を発揮
する要請にも応え得る。[Operation] Due to the above-mentioned configuration, the liquid whose temperature is controlled always flows into the annular hollow portion between the mill case and the mill pot, and acts so as to maintain the grinding conditions at a constant temperature. Generally, most of the purpose is to act as a refrigerant to take away the heat generated and cool the pot, but sometimes there is a request to exert the function of constantly maintaining at a specific temperature to form special conditions. Can also respond.
この液体は同時にミルケースを支える軸受部に対しても
強制的に進入して行くから軸受の加熱焼付きを防止して
円滑な高速回転を保証する。At the same time, this liquid also forcibly enters the bearing portion that supports the mill case, so that heating and seizing of the bearing is prevented and smooth high-speed rotation is guaranteed.
冷却自体については水又は水を主体に添加剤で補強した
水軸受が能力大であり、一般の鉱物性潤滑剤に比較して
ほぼ10倍以上という優れた値をもつのに、価格的にはき
わめて安価なであるという利点がある。Regarding cooling itself, water or a water bearing mainly composed of water and reinforced with additives has a large capacity, and while it has an excellent value of about 10 times or more compared with general mineral lubricants, it is priced. It has the advantage of being extremely cheap.
油類の場合は冷却効果については水に及ばないが、流路
の発錆銹を防いで部材の腐食などの劣化を予防する利点
もある。その他、主軸回りの自転用軸受と公転用軸受を
同一の油類で強制潤滑することも可能である。どの液体
を選ぶかについては粉砕条件や装置の設計によって最適
のものを選ぶ必要がある。In the case of oils, the cooling effect is inferior to that of water, but it also has an advantage of preventing rusting of the flow path and preventing deterioration such as corrosion of members. In addition, it is possible to forcibly lubricate the rotation bearing and the revolution bearing around the main shaft with the same oil. Regarding the liquid to be selected, it is necessary to select the most suitable liquid depending on the grinding conditions and the design of the device.
[実施例] 第1図から第3図は本願発明の第一実施例を示し温度調
整の媒体としては、水又は水主体の調整液を使用するの
に適当な構成である。[Embodiment] FIGS. 1 to 3 show a first embodiment of the present invention, which has a structure suitable for using water or a water-based adjusting liquid as a temperature adjusting medium.
架台1の上に軸受台2を立設して装置全体を支え、モー
タ20の駆動力は駆動車5から従動車4を経由して主軸3
へ伝えられる。主軸3の中心に液体の通過孔31を設け、
主軸の途中から円盤状の回転体7と連通する連孔71を経
て液室73へ通じている。The bearing stand 2 is erected on the pedestal 1 to support the entire apparatus, and the driving force of the motor 20 is from the drive vehicle 5 via the driven vehicle 4 to the spindle 3
Is transmitted to. A liquid passage hole 31 is provided at the center of the main shaft 3,
From the middle of the main shaft to a liquid chamber 73 through a communication hole 71 that communicates with the disk-shaped rotating body 7.
回転体7には主軸中心線と平行に等間隔の孔を設けて筒
状の液中軸受14を嵌め込み、複数の円筒状ミルケース8
がこの液中軸受14によって支持されている。The rotating body 7 is provided with holes at equal intervals in parallel with the center line of the main shaft, and the cylindrical submerged bearings 14 are fitted therein.
Are supported by the submerged bearing 14.
ミルケース8は底孔81,側面孔82を穿孔し、この内側に
環状中空部(冷却室)80を隔ててミルポット10を着脱自
在に嵌入し連結ピン9を介して両者を係止するので、両
者は一体的に回転を共にする。The mill case 8 is formed with a bottom hole 81 and a side hole 82, and the mill pot 10 is detachably fitted inside the mill case 8 with an annular hollow portion (cooling chamber) 80 interposed therebetween to lock the two via a connecting pin 9. Rotate together.
なお冷却室80には熱伝導の能力を高めるためにフィン83
を周壁に螺旋状に巻回して下から上へ至っているのは好
ましい実施例の一つである。この冷却室80の頂端からス
リーブ状の液中軸受15,回転体7を共通して貫通し回転
体外の流路を形成するカバー16へ抜ける連孔72を穿孔す
る。The cooling chamber 80 has fins 83 in order to enhance the heat conduction ability.
It is one of the preferred embodiments to spirally wind around the peripheral wall from the bottom to the top. A communication hole 72 is bored from the top end of the cooling chamber 80 to pass through the sleeve-shaped submerged bearing 15 and the rotating body 7 in common and to the cover 16 that forms a flow path outside the rotating body.
装置の運転としては、まずミルケース8の上部の蓋11を
外して被粉砕原料の入ったミルポット8をミルケース内
へ嵌入しピン9によって係止する。主軸3の回転によっ
て回転体7が公転すると共に、主軸に固定した太陽歯車
13と噛合する遊星歯車12の回転によってミルケース8が
回転体内で自転をはじめる。In operation of the apparatus, first, the lid 11 on the upper part of the mill case 8 is removed, the mill pot 8 containing the raw material to be crushed is inserted into the mill case, and locked by the pin 9. The rotating body 7 revolves by the rotation of the main shaft 3 and the sun gear fixed to the main shaft.
The rotation of the planetary gear 12 meshing with the gear 13 causes the mill case 8 to start rotating in the rotating body.
第3図に示すように、液槽30に蓄えられた液体は加熱器
33,又は冷却器32の作用を受けて温度を所定の範囲内に
調整し、ポンプ34によって回転接手6を経て主軸内の通
過孔31内を圧送され連孔71,液室73に至って流路は別
れ、底孔81から冷却室80へ進入した媒体は螺旋状に回動
しながら効率的な熱交換を果し連孔72からケーシング16
の傾斜面を流下して排出口17から液槽30へ戻入する。別
れたもう一方の液体はミルケース側面孔82を通過して液
中軸受15とミルケース8外周との微小な間隙を通過して
潤滑作用を果す。この他液室73から直接液中軸受14とミ
ルケース8との微小間隙を押し上げられて前記ミルケー
ス8外周の流路と合流する系路も形成され、結局、両軸
受の摺動面には常に豊富な液体が介在して十分な潤滑作
用を施すことができる。なお第2図は本実施例の平面図
である。As shown in FIG. 3, the liquid stored in the liquid tank 30 is a heater.
The temperature is adjusted within a predetermined range by the action of the cooling device 33 or the cooler 32, and is pumped by the pump 34 through the rotary joint 6 through the passage hole 31 in the main shaft to reach the communication hole 71 and the liquid chamber 73. The medium that has entered the cooling chamber 80 through the bottom hole 81 rotates efficiently in a spiral manner and efficiently exchanges heat, and the casing 16 through the communicating hole 72.
And then flow back into the liquid tank 30 through the discharge port 17. The other separated liquid passes through the mill case side surface hole 82, passes through a minute gap between the submerged bearing 15 and the outer periphery of the mill case 8, and performs a lubricating action. The other liquid chamber 73 directly pushes up the minute gap between the submerged bearing 14 and the mill case 8 to form a system passage that joins with the flow passage on the outer periphery of the mill case 8. In the end, the sliding surfaces of both bearings are always rich. A sufficient liquid can intervene to provide a sufficient lubricating action. FIG. 2 is a plan view of this embodiment.
次に第4図に示すのは本願発明の第二実施例であって、
液体としてはむしろ油類を採用するのに好適な構成であ
る。概要な前例と殆ど等しいが、前例の液中軸受14に代
ってころがり軸受18を採用し自転用軸受にも同一の油類
を強制潤滑すると共に液の流路も若干違えて水と異なる
油類の流動性を考慮した系路に変更している。Next, FIG. 4 shows a second embodiment of the present invention,
Rather, it is a configuration suitable for adopting oils as the liquid. Almost the same as the previous example, but instead of the submerged bearing 14 of the previous example, a rolling bearing 18 is adopted, the same oil is forcibly lubricated for the rotation bearing, and the flow path of the liquid is slightly different and different from water. It has been changed to a system that takes into account the liquidity of various types.
[発明の効果] 本願発明は以上に述べた構成,作用よりなるから、過激
な粉砕作用に伴なう発生熱を吸収して微粉の品質を担保
すると共に、軸受部分の潤滑剤を強制的に循環させるこ
とにより、軸受の摩擦抵抗をへらし、軸受の寿命を長く
し、かつ消費動力を少なくすることができる。また特殊
な粉砕使用によって求められる特定の温度下における条
件設定にも対応し、広範な用途と精緻な品質管理を可能
とする。このような機能が従来の遊星ボールミルの特性
を大きく増幅するもので、新しい微粉製造法の可能性を
展開したと言うことができる。[Advantages of the Invention] Since the present invention has the configuration and operation described above, it absorbs the heat generated by the extreme crushing operation to ensure the quality of the fine powder and forcibly applies the lubricant to the bearing portion. By circulating, the frictional resistance of the bearing can be reduced, the life of the bearing can be extended, and the power consumption can be reduced. In addition, it corresponds to the condition setting under the specific temperature required by the special crushing use, and enables a wide range of applications and precise quality control. It can be said that such a function greatly expands the characteristics of the conventional planetary ball mill and has developed the possibility of a new fine powder manufacturing method.
第1図は本願発明の第一実施例を示す垂直断面図、第2
図は同じく平面図、第3図は全体の正面図、第4図は別
の実施例を示す垂直断面図。 3……主軸、8……ミルケース 10……ミルポット、80……環状中空部(冷却室) 14,15,18……軸受FIG. 1 is a vertical sectional view showing a first embodiment of the present invention, and FIG.
The same drawing is a plan view, FIG. 3 is an overall front view, and FIG. 4 is a vertical sectional view showing another embodiment. 3 ... Spindle, 8 ... Mill case, 10 ... Mill pot, 80 ... Annular hollow part (cooling chamber) 14,15, 18 ... Bearing
Claims (4)
に周設し、該ミルケース内へ嵌入係止するミルポット内
へ粉砕媒体と被粉砕物を収容して主軸を中心とする公転
に該ミルケースの自転を加えて遠心力のもとで強力な粉
砕力を発揮する遊星ボールミルにおいて、前記のミルケ
ース内周面とミルポットの外周面との間に環状の中空部
を形成し、ミルケースの軸受部および該環状中空部へそ
れぞれ同質の液体を同時に強制循環することを特徴とす
る温度調整機能を具えた遊星ボールミル。1. A plurality of mill cases are provided at equal intervals in parallel with a spindle, and a grinding pot and an object to be ground are housed in a mill pot which is fitted and locked in the mill case, and revolves around the spindle. In a planetary ball mill that exerts a strong crushing force under centrifugal force by adding the rotation of the mill case, an annular hollow part is formed between the inner peripheral surface of the mill case and the outer peripheral surface of the mill pot, and the bearing part of the mill case is formed. And a planetary ball mill having a temperature adjusting function, characterized in that the liquid of the same quality is forcedly circulated simultaneously to the annular hollow portion.
剤,防錆剤等を添加したことを特徴とする温度調整機能
を具えた遊星ボールミル。2. A planetary ball mill having a temperature adjusting function, wherein the liquid is water or water to which a lubricant, a rust preventive and the like are added.
特徴とする温度調整機能を具えた遊星ボールミル。3. A planetary ball mill having a temperature adjusting function, wherein the liquid is oils according to claim 1.
熱又は冷却する手段を流路に具えたことを特徴とする温
度調整機能を具えた遊星ボールミル。4. A planetary ball mill having a temperature adjusting function, characterized in that the passage is provided with means for heating or cooling a liquid according to any one of claims 1 to 3.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP14463490A JPH0679677B2 (en) | 1990-06-01 | 1990-06-01 | Planetary ball mill with temperature adjustment function |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP14463490A JPH0679677B2 (en) | 1990-06-01 | 1990-06-01 | Planetary ball mill with temperature adjustment function |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPH0440245A JPH0440245A (en) | 1992-02-10 |
| JPH0679677B2 true JPH0679677B2 (en) | 1994-10-12 |
Family
ID=15366618
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP14463490A Expired - Lifetime JPH0679677B2 (en) | 1990-06-01 | 1990-06-01 | Planetary ball mill with temperature adjustment function |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH0679677B2 (en) |
Families Citing this family (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2586778B2 (en) * | 1992-06-30 | 1997-03-05 | 株式会社栗本鐵工所 | Batch type planetary ball mill with temperature control |
| JP2904392B2 (en) * | 1993-12-17 | 1999-06-14 | 株式会社栗本鐵工所 | Vertical continuous planetary ball mill |
| KR20010112144A (en) * | 2001-10-17 | 2001-12-20 | 김춘규 | The pulverizer activator |
| JP4773072B2 (en) * | 2004-08-03 | 2011-09-14 | 安井器械株式会社 | Cell disruption device |
| JP4871159B2 (en) * | 2007-02-15 | 2012-02-08 | 株式会社栗本鐵工所 | Planetary ball mill |
| KR101708280B1 (en) * | 2015-09-30 | 2017-02-20 | 케이엠텍 주식회사 | Apparatus for agitation and grinding |
| CN108339645A (en) * | 2017-04-08 | 2018-07-31 | 李晓媛 | A kind of Chinese medicine rolling grinding device |
| TWI838175B (en) * | 2023-03-21 | 2024-04-01 | 台灣立凱電能科技股份有限公司 | Manufacturing method of carbon-coated lithium iron phosphate material |
-
1990
- 1990-06-01 JP JP14463490A patent/JPH0679677B2/en not_active Expired - Lifetime
Also Published As
| Publication number | Publication date |
|---|---|
| JPH0440245A (en) | 1992-02-10 |
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