JPH0687736B2 - Aged hard cheese and method for producing the same - Google Patents
Aged hard cheese and method for producing the sameInfo
- Publication number
- JPH0687736B2 JPH0687736B2 JP2318067A JP31806790A JPH0687736B2 JP H0687736 B2 JPH0687736 B2 JP H0687736B2 JP 2318067 A JP2318067 A JP 2318067A JP 31806790 A JP31806790 A JP 31806790A JP H0687736 B2 JPH0687736 B2 JP H0687736B2
- Authority
- JP
- Japan
- Prior art keywords
- cheese
- stringiness
- hard cheese
- aged
- temperature
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 238000004519 manufacturing process Methods 0.000 title claims description 42
- 235000011617 hard cheese Nutrition 0.000 title claims description 30
- 235000013351 cheese Nutrition 0.000 claims description 136
- 238000010411 cooking Methods 0.000 claims description 57
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 53
- 229910052757 nitrogen Inorganic materials 0.000 claims description 26
- JVTAAEKCZFNVCJ-UHFFFAOYSA-N lactic acid Chemical compound CC(O)C(O)=O JVTAAEKCZFNVCJ-UHFFFAOYSA-N 0.000 claims description 22
- 239000007858 starting material Substances 0.000 claims description 16
- 102000004169 proteins and genes Human genes 0.000 claims description 14
- 108090000623 proteins and genes Proteins 0.000 claims description 14
- 239000004310 lactic acid Substances 0.000 claims description 11
- 235000014655 lactic acid Nutrition 0.000 claims description 11
- 241000894006 Bacteria Species 0.000 claims description 9
- 235000013336 milk Nutrition 0.000 claims description 5
- 239000008267 milk Substances 0.000 claims description 5
- 210000004080 milk Anatomy 0.000 claims description 5
- 239000002994 raw material Substances 0.000 claims description 5
- 238000000034 method Methods 0.000 description 21
- 238000002844 melting Methods 0.000 description 19
- 230000008569 process Effects 0.000 description 18
- 238000010438 heat treatment Methods 0.000 description 16
- 239000005862 Whey Substances 0.000 description 15
- 102000007544 Whey Proteins Human genes 0.000 description 15
- 108010046377 Whey Proteins Proteins 0.000 description 15
- 240000002129 Malva sylvestris Species 0.000 description 13
- 235000006770 Malva sylvestris Nutrition 0.000 description 13
- 239000011575 calcium Substances 0.000 description 11
- 230000000694 effects Effects 0.000 description 11
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 10
- 229910052791 calcium Inorganic materials 0.000 description 10
- 230000007423 decrease Effects 0.000 description 10
- 239000000796 flavoring agent Substances 0.000 description 10
- 235000019634 flavors Nutrition 0.000 description 10
- 230000008018 melting Effects 0.000 description 10
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 10
- 230000032683 aging Effects 0.000 description 9
- 230000005070 ripening Effects 0.000 description 9
- 238000005520 cutting process Methods 0.000 description 8
- 235000019640 taste Nutrition 0.000 description 8
- 230000008859 change Effects 0.000 description 7
- 238000000855 fermentation Methods 0.000 description 7
- 230000004151 fermentation Effects 0.000 description 7
- 235000020185 raw untreated milk Nutrition 0.000 description 7
- 229940108461 rennet Drugs 0.000 description 6
- 108010058314 rennet Proteins 0.000 description 6
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 5
- 238000011049 filling Methods 0.000 description 4
- 239000000047 product Substances 0.000 description 4
- 230000017854 proteolysis Effects 0.000 description 4
- 239000000523 sample Substances 0.000 description 4
- 239000000126 substance Substances 0.000 description 4
- 238000012360 testing method Methods 0.000 description 4
- 238000010792 warming Methods 0.000 description 4
- 238000007696 Kjeldahl method Methods 0.000 description 3
- 238000004458 analytical method Methods 0.000 description 3
- 230000006866 deterioration Effects 0.000 description 3
- 239000000706 filtrate Substances 0.000 description 3
- 239000002245 particle Substances 0.000 description 3
- 230000000704 physical effect Effects 0.000 description 3
- 239000011780 sodium chloride Substances 0.000 description 3
- 244000068988 Glycine max Species 0.000 description 2
- 235000010469 Glycine max Nutrition 0.000 description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- 239000007864 aqueous solution Substances 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- 238000007796 conventional method Methods 0.000 description 2
- 238000000354 decomposition reaction Methods 0.000 description 2
- 230000018044 dehydration Effects 0.000 description 2
- 238000006297 dehydration reaction Methods 0.000 description 2
- XBDQKXXYIPTUBI-UHFFFAOYSA-N dimethylselenoniopropionate Natural products CCC(O)=O XBDQKXXYIPTUBI-UHFFFAOYSA-N 0.000 description 2
- 238000007599 discharging Methods 0.000 description 2
- 239000012153 distilled water Substances 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 238000000465 moulding Methods 0.000 description 2
- 238000003825 pressing Methods 0.000 description 2
- 238000012545 processing Methods 0.000 description 2
- 238000011160 research Methods 0.000 description 2
- 230000000717 retained effect Effects 0.000 description 2
- 238000009938 salting Methods 0.000 description 2
- 239000012488 sample solution Substances 0.000 description 2
- 235000020183 skimmed milk Nutrition 0.000 description 2
- 238000003756 stirring Methods 0.000 description 2
- 108090000790 Enzymes Proteins 0.000 description 1
- 102000004190 Enzymes Human genes 0.000 description 1
- 235000006089 Phaseolus angularis Nutrition 0.000 description 1
- 240000007098 Vigna angularis Species 0.000 description 1
- 235000010711 Vigna angularis Nutrition 0.000 description 1
- 230000001580 bacterial effect Effects 0.000 description 1
- 230000000721 bacterilogical effect Effects 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 238000013124 brewing process Methods 0.000 description 1
- 244000309466 calf Species 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 238000004132 cross linking Methods 0.000 description 1
- 230000009849 deactivation Effects 0.000 description 1
- 230000002950 deficient Effects 0.000 description 1
- 238000006731 degradation reaction Methods 0.000 description 1
- 230000003111 delayed effect Effects 0.000 description 1
- 238000000280 densification Methods 0.000 description 1
- 238000003795 desorption Methods 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 235000021113 dry cheese Nutrition 0.000 description 1
- 235000006694 eating habits Nutrition 0.000 description 1
- 230000002255 enzymatic effect Effects 0.000 description 1
- 229940088598 enzyme Drugs 0.000 description 1
- 230000001747 exhibiting effect Effects 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 230000005764 inhibitory process Effects 0.000 description 1
- 230000035800 maturation Effects 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 230000007246 mechanism Effects 0.000 description 1
- 230000001404 mediated effect Effects 0.000 description 1
- 239000000155 melt Substances 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 235000019629 palatability Nutrition 0.000 description 1
- 235000021116 parmesan Nutrition 0.000 description 1
- 235000013550 pizza Nutrition 0.000 description 1
- 239000002244 precipitate Substances 0.000 description 1
- 108090000765 processed proteins & peptides Proteins 0.000 description 1
- 230000002250 progressing effect Effects 0.000 description 1
- 235000019260 propionic acid Nutrition 0.000 description 1
- IUVKMZGDUIUOCP-BTNSXGMBSA-N quinbolone Chemical compound O([C@H]1CC[C@H]2[C@H]3[C@@H]([C@]4(C=CC(=O)C=C4CC3)C)CC[C@@]21C)C1=CCCC1 IUVKMZGDUIUOCP-BTNSXGMBSA-N 0.000 description 1
- 239000011435 rock Substances 0.000 description 1
- 239000001509 sodium citrate Substances 0.000 description 1
- NLJMYIDDQXHKNR-UHFFFAOYSA-K sodium citrate Chemical compound O.O.[Na+].[Na+].[Na+].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O NLJMYIDDQXHKNR-UHFFFAOYSA-K 0.000 description 1
- 241000894007 species Species 0.000 description 1
- 230000001954 sterilising effect Effects 0.000 description 1
- 230000036962 time dependent Effects 0.000 description 1
- YNJBWRMUSHSURL-UHFFFAOYSA-N trichloroacetic acid Chemical compound OC(=O)C(Cl)(Cl)Cl YNJBWRMUSHSURL-UHFFFAOYSA-N 0.000 description 1
Landscapes
- Dairy Products (AREA)
Description
【発明の詳細な説明】 [産業上の利用分野] 本発明は優れた糸ひき性を有し、しかもその糸ひき性
が、劣化することなく長期間保持できる熟成硬質チーズ
及びその製造方法に関する。Description: TECHNICAL FIELD The present invention relates to an aged hard cheese having excellent stringing properties and capable of holding the stringing properties for a long time without deterioration, and a method for producing the same.
[従来の技術] 近年食生活の洋風化が一段と進み、それに伴って日本人
の嗜好も変化しつつあり、ナチュラルチーズの需要も年
々増加する傾向にある。その中で特にゴーダタイプのチ
ーズは、独特なマイルドな風味を有している点で最も日
本人の嗜好に合っているものと考えられる。このタイプ
に類似したチーズとしては、エダムチーズ、サムソーチ
ーズ、チェダーチーズ等が挙げられる。[Prior Art] In recent years, westernization of eating habits has further advanced, and Japanese tastes are changing accordingly, and demand for natural cheese tends to increase year by year. Among them, the gouda type cheese is considered to be most suitable for the Japanese because it has a unique mild flavor. Cheese similar to this type includes Edam cheese, Samsoe cheese, Cheddar cheese and the like.
上記に挙げたチーズは熟成硬質チーズに分類されるナチ
ュラルチーズであり、その代表的製造方法として以下の
ものが知られている。The above-mentioned cheeses are natural cheeses classified as aged hard cheeses, and the following typical production methods are known.
原料乳処理工程:原料乳を殺菌後冷却する。 Raw milk processing step: The raw milk is sterilized and then cooled.
乳酸発酵工程:チーズの種類に応じ所望の乳酸菌ス
ターターを添加し乳酸発酵を行う。Lactic acid fermentation step: Lactic acid fermentation is performed by adding a desired lactic acid bacterium starter according to the type of cheese.
レンネッテング工程:塩化カルシウム、レンネット
を添加し乳を凝固させカードを製造する。Renneting step: Calcium and rennet are added to coagulate milk to produce curd.
カッテング工程:チーズの種類に応じ所望の大きさ
にカードを裁断しカード粒とする。Cutting process: The curd is cut into a desired size according to the type of cheese to make curd.
クッキング工程:加熱するとともにカード粒から排
出されるホエーを抜く。通常3回に分けて行う。Cooking process: Heat and remove the whey discharged from the curd grains. Usually, it is divided into 3 times.
マッティング工程:ホエーを排出したカード粒をバ
ット上に堆積しさらにホエー排出を行う。Matting process: The curd particles from which the whey has been discharged are deposited on the vat, and the whey is further discharged.
型詰工程:ホエーを排出し収縮したカードを粉砕
し、所望の型に詰め必要な圧力をかけて圧搾しチーズを
成型する。Mold filling step: Whey is discharged, and the curd that has shrunk is crushed, packed in a desired mold and pressed under the required pressure to mold cheese.
熟成工程:以上の工程で得られたグリーンチーズ
(生チーズ)を所定条件で熟成させ、チーズ特有の風
味、食感を付与する。Aging step: The green cheese (raw cheese) obtained in the above steps is aged under predetermined conditions to impart a cheese-specific flavor and texture.
上記一連の工程は、いくつかの変法も知られているが、
永年のチーズ製造の過程でチーズの種類によりほぼ決ま
っている。特有の香り、食感、味を付与するには特定の
製造条件が必要だからである。特に、クッキング温度条
件は、発酵による反応がチーズの組織上及び化学構造上
大きな影響を与えることから重要であり、比較的厳格に
管理される(管理指標としてはpH、酸度等が知られ
る。)。尚、ゴーダチーズでは型詰工程後に加塩工程を
設け、チーズを食塩水に浸漬している。Although several modified methods are known for the above series of steps,
In the process of manufacturing cheese for many years, it is almost decided by the type of cheese. This is because specific manufacturing conditions are required to impart a unique scent, texture and taste. In particular, the cooking temperature condition is important because the reaction due to fermentation has a great influence on the structure and chemical structure of cheese, and is controlled relatively rigorously (pH, acidity, etc. are known as management indices). . In addition, in Gouda cheese, a salting step is provided after the mold filling step, and the cheese is immersed in saline.
[発明が解決しようとする課題] しかしこれらのタイプのチーズでは、熟成の進行によ
り、糸ひき性が徐々に劣化していく傾向が認められ、特
に熟成期間が4〜5ケ月を過ぎると糸ひき性の低下が顕
著に表われるという問題点がある。[Problems to be Solved by the Invention] However, in these types of cheese, it is recognized that the threading property gradually deteriorates with the progress of ripening, and especially when the aging period exceeds 4 to 5 months. There is a problem that the deterioration of sex is markedly shown.
一方、比較的長期間糸ひき性を維持できるチーズとして
は、エメンタールチーズ、グリュエールチーズ等が挙げ
られる。しかし、これらのチーズは、特有の香りを持
ち、癖が強いため、一般の日本人の嗜好を十分満足させ
るまでには至っていない。On the other hand, examples of cheeses that can maintain stringiness for a relatively long time include Emmental cheese and Gruyere cheese. However, since these cheeses have a peculiar scent and have a strong habit, they have not yet fully satisfied the tastes of ordinary Japanese people.
ここで糸ひき性とは、一般に、ピザ用などに用いられる
チーズのようにチーズを加熱、溶融させ、引き伸ばした
時の糸ひきの度合のことをいう。Here, the thread drawability generally means the degree of thread drawability when cheese is heated and melted and stretched like cheese used for pizza.
ところで、ナチュラルチーズにおける糸ひき性の発現メ
カニズムについては、現在はほとんど研究が進んでいな
いのが現状であり、使用原材料、製造条件等が影響して
いることは予想されるが不明なところが多く、ゴーダタ
イプのナチュラルチーズの糸ひき性改良についての研究
報告も何ら知られていない。ゴーダタイプのナチュラル
チーズは前述したように日本人の嗜好に合うこと、又加
熱調理に供卓される調理構造を勘案すれば、ゴーダタイ
プを中心とするナチュラルチーズにおける糸ひき性を改
良しその特性を長期間保持させることができればその商
品的価値が大いに高まるものと期待される。By the way, regarding the expression mechanism of the stringiness in natural cheese, at present, little research is progressing, and it is expected that the raw materials used, manufacturing conditions, etc. are expected, but there are many unclear points, There is no known research report on the improvement of stringiness of gouda type natural cheese. As mentioned above, gouda-type natural cheese is suitable for Japanese tastes, and considering the cooking structure used for cooking, it improves the stringiness of natural cheese centering on gouda-type cheese and its characteristics. If the product can be retained for a long period of time, its commercial value is expected to increase greatly.
本発明は、上述従来技術の実情に鑑み、ゴーダチーズに
代表される熟成硬質チーズの糸ひき性を長期間、良好な
状態で維持させることが可能な糸ひき性の優れたチーズ
およびそれを製造する方法を提供するものである。The present invention, in view of the circumstances of the above-mentioned prior art, the stringiness of aged hard cheese typified by Gouda cheese for a long period of time, it is possible to maintain a good state of stringability cheese and it is produced. It provides a way to do it.
[課題を解決するための手段] 本発明者らは、前述、熟成硬質チーズの製造条件と得ら
れるチーズの糸ひき性との関係について鋭意研究した結
果、特にクッキング工程における温度条件がチーズ組織
の糸ひき性に関与する蛋白網状構造にのみ効果的な変化
をもたらしうることを見い出し、本発明を完成するに至
ったものである。[Means for Solving the Problems] The inventors of the present invention have diligently studied the relationship between the production conditions of the aged hard cheese and the stringiness of the obtained cheese, and particularly, the temperature condition in the cooking step is the cheese structure. The present inventors have completed the present invention by discovering that effective changes can be brought only to the protein network structure that is involved in stringiness.
即ち、前述製造の工程の中で特にクッキング工程におけ
るカードの温度を特定の範囲内で調節することにより、
チーズの熟成が進行しても糸ひき性を長期間良好な状態
で保持させることが可能となるのである。That is, by adjusting the temperature of the card in the cooking step in the above-mentioned manufacturing process within a specific range,
Even if the ripening of the cheese progresses, it is possible to maintain the stringiness in a good state for a long period of time.
従って、本発明は第1に、糸ひき性を改良するための製
造方法であって、熟成硬質チーズの製造において、クッ
キング工程における到達温度が43〜55℃の範囲になるよ
うに加温することを特徴とする、糸ひき性の改良された
熟成硬質チーズの製造方法である。Therefore, the present invention is, firstly, a production method for improving the threading property, wherein in the production of an aged hard cheese, the temperature reached in the cooking step is heated to a range of 43 to 55 ° C. And a method for producing an aged hard cheese having improved stringiness.
糸ひき性が改良されたチーズは特有な性質を有してお
り、本発明は第2に、可溶性窒素熟度指標(可溶性窒素
熟度指標すなわちSTN/TNとは可溶性窒素/全窒素×100
で表わす)が少なくとも15〜25%の範囲において、糸ひ
き性が40cm以上である熟成硬質チーズであり、又、非蛋
白態窒素熟度指数(非蛋白態窒素熟度指数すなわちNPN/
TNとは非蛋白態窒素/全窒素×100で表わす)が少なく
とも10〜20%の範囲において、糸ひき性が40cm以上であ
る最近熟成硬質チーズである。本発明のチーズは糸ひき
性が有効に改良されている以外はほとんど同種の従来の
チーズと同じ香り、食感、味、その他の物性を有してい
る点で特徴的である。Cheese with improved stringiness has unique properties, and secondly, the present invention provides a soluble nitrogen maturity index (soluble nitrogen maturity index or STN / TN: soluble nitrogen / total nitrogen x 100).
Is at least 15 to 25%, and is a mature hard cheese having a stringiness of 40 cm or more, and a non-protein nitrogen maturity index (non-protein nitrogen maturity index or NPN /
TN is a recently aged hard cheese having a stringiness of 40 cm or more in the range of at least 10 to 20% of (non-protein nitrogen / total nitrogen x 100). The cheese of the present invention is characteristic in that it has almost the same aroma, texture, taste and other physical properties as conventional cheeses of the same kind except that the stringiness is effectively improved.
ここで、糸ひき性の評価は以下方法に準じて行うもので
ある。Here, the threading property is evaluated according to the following method.
(糸ひき性試験) 試料チーズを20gシャーレに採取しこれを約90℃で1分
間加熱溶融させる。次にこのチーズを糸ひき性測定機に
よって10cm/sの速度で引っぱり上げチーズの糸ひきの長
さ(cm)を測定する。(Stringiness test) Sample cheese is sampled in a 20 g petri dish and heated and melted at about 90 ° C for 1 minute. Next, this cheese is pulled up at a speed of 10 cm / s by a stringiness measuring machine and the length (cm) of the stringiness of the cheese is measured.
以下、本発明を詳述する。Hereinafter, the present invention will be described in detail.
まず、本発明において対象となるチーズは熟成硬質チー
ズ(以下特記しない限り「チーズ」という。)である。
即ち、水分40%以下程度であるゴーダ、エダム、チェダ
ー、マリボー、サムソー等の硬質チーズであり、ロック
ホールやブルーなどカビ熟成チーズは含まない。カビ熟
成チーズでは蛋白質分解が相当に進行し、蛋白質による
構造性がほぼ完全に破壊されており、通常は、糸ひき性
が問題とされないためである。熟成硬質チーズにおける
種類のちがいは、本質的な製造条件上の差異というより
も、原料面や製造工程中におけるチーズの形態等の差異
による。例えば、ゴーダとエダムでは原料乳脂肪量、カ
ッティング工程におけるカード粒の大きさ、型詰工程に
おける型の形状、圧力、塩漬け処理等が相違し、又、ゴ
ーダやエダムではスターターとして乳酸菌を用いるがグ
リュエールやエメンタールではプロピオン酸菌も用いる
点で相違する。この他、レンネットの添加量等にも差異
はあるが、基本的な製造条件は共通している。但し、本
発明においては一般需要者層の嗜好性を考慮すればコー
ダタイプに適用することが産業上有意義である。First, the target cheese in the present invention is an aged hard cheese (hereinafter referred to as "cheese" unless otherwise specified).
That is, it is a hard cheese such as Gouda, Edam, Cheddar, Maribo, Samsaw having a water content of 40% or less, and does not include mold-aged cheese such as rock hole and blue. This is because, in the mold-aged cheese, proteolysis is considerably progressed, and the structural property due to the protein is almost completely destroyed, and the stringiness is usually not a problem. The difference in the types of aged hard cheeses is due to the difference in the raw material surface and the form of cheese during the manufacturing process, rather than the essential difference in the manufacturing conditions. For example, Gouda and Edam differ in the amount of raw milk fat, the size of curd grains in the cutting process, the shape of the mold in the molding process, the pressure, and the salting treatment.In Gouda and Edam, lactic acid bacteria are used as a starter, but Gruere. And Emmental differ in that they also use propionic acid bacteria. In addition, although there are differences in the amount of rennet added, the basic manufacturing conditions are the same. However, in the present invention, it is industrially significant to apply it to a coder type in consideration of the preference of general consumers.
従って本発明の製造方法は基本的に、原料乳処理工
程、乳酸発酵工程、レンネッテング工程、カッテ
ング工程、クッキング工程、マッティング工程、
型詰工程、熟成工程を包含してなるものである。これ
らの工程は各工程における細部の条件に差異があるもの
の熟成硬質チーズにおいてほぼ共通する。本発明の特徴
は、上記工程のうち、クッキング工程の加温温度条件を
通常の範囲より高く設定することにあり、その他の工程
においては常法に基づいて実施しうるものである。Therefore, the production method of the present invention is basically a raw material milk treatment step, a lactic acid fermentation step, a renneting step, a cutting step, a cooking step, a matting step,
It includes a mold filling step and an aging step. These steps are almost common in ripened hard cheese, although there are differences in the detailed conditions in each step. The feature of the present invention lies in that the heating temperature condition of the cooking step is set higher than the normal range among the above-mentioned steps, and the other steps can be carried out based on a conventional method.
次に、本発明の理解を容易とするため通常行われるクッ
キング工程の条件についてゴーダ及びエダムを例に説明
する。Next, in order to facilitate understanding of the present invention, conditions of a cooking process that is usually performed will be described by taking Gouda and Edam as an example.
第1段階〜第3段階と3回に分けて加温しているのは、
ホエー排出の効率上、各段階終了後にホエーを約1/3づ
つ抜くためである。 The first stage to the third stage is divided into 3 heating steps.
This is because about 1/3 of the whey is removed after each step for the efficiency of whey discharge.
いずれにせよレンネットで凝固しカッテングされたカー
ド粒は、乳酸発酵の阻害を防ぐため所定の温度以上に加
温されることはなく、上記以外のチーズでもチェダーチ
ーズ(40℃)、サムソーチーズ(37℃)とされている。
乳酸菌スターターが温度の影響を受け活性が低下すれ
ば、チーズのpHは酸生成が進まないために製造直後で高
くなり、これはクッキング工程における加温温度(以下
「クッキング温度」という。)が高い程顕著となる。pH
が高いチーズではイオン性カルシウム量が少なく熱溶融
性が低減しているので、チーズ加熱時の物性に影響がで
る。更にクッキング温度が高くなればチーズは硬くなる
傾向がある。このような観点から硬質チーズの製造にお
いては、クッキング温度が40℃以上にされることはなか
ったのである。因に、パルメザン等の超硬質チーズでは
クッキング温度を55℃前後まで、又特殊な乾燥チーズで
は70〜80℃にまで上昇させている。これらチーズは含有
率が低く、硬度が著しく増大しており、製造方法自体硬
質チーズのものとは本質的に異なっているため一概に比
較できないが、一般にクッキング温度が上昇するとカー
ド粒のシネリシスが促進されカードからの脱水が進み、
チーズの硬度を増加させる効果を奏することが一般に知
られている。In any case, curd particles that have been solidified and cut with rennet are not heated above a predetermined temperature to prevent inhibition of lactic acid fermentation, and even cheeses other than the above cheddar cheese (40 ° C), Samsaw cheese ( 37 ℃).
If the lactic acid bacterium starter is affected by temperature and the activity decreases, the pH of the cheese becomes high immediately after production because the acid production does not proceed, and this is because the heating temperature in the cooking step (hereinafter referred to as "cooking temperature") is high. It becomes remarkable. pH
In high cheese, the amount of ionic calcium is small and the heat melting property is reduced, so the physical properties during heating of cheese are affected. Furthermore, higher cooking temperatures tend to make cheese harder. From such a viewpoint, the cooking temperature was never set to 40 ° C. or higher in the production of hard cheese. By the way, the cooking temperature is increased up to around 55 ℃ for ultra-hard cheeses such as parmesan, and up to 70-80 ℃ for special dry cheeses. The content of these cheeses is low, the hardness is significantly increased, and the manufacturing method itself is fundamentally different from that of hard cheeses, so it is not possible to make a general comparison, but generally when the cooking temperature rises, the syneresis of curd grains is accelerated. And the dehydration from the card progresses,
It is generally known to have the effect of increasing the hardness of cheese.
一方、糸ひき性は専らチーズの経時的変化という観点か
ら研究され、熟成が進むとペプチド鎖の網状構造が切断
され糸ひき性が劣化することはよく知られている事項で
ある。従って、糸ひき性がチーズ組織の何らかの構造性
に関係することが予想されるにしても、具体的にどのよ
うな要因が関与してるのか明らかではなかった。On the other hand, stringiness is studied exclusively from the viewpoint of time-dependent change of cheese, and it is a well known matter that the network structure of peptide chains is broken and the stringiness is deteriorated as ripening progresses. Therefore, even if it is expected that the stringiness is related to some structural property of the cheese tissue, it was not clear what factor is specifically involved.
本発明者らは、クッキング温度、即ち、カード粒からの
ホエー排出の工程における温度が単にチーズの硬度に影
響を及ぼすだけではなく、糸ひき性に大きく関与してい
ることを見い出したのである。クッキング温度を上昇さ
れることにより生じるチーズ組織上の作用効果の概略を
次に挙げる。The present inventors have found that the cooking temperature, that is, the temperature in the process of discharging whey from curd grains, not only affects the hardness of cheese, but also has a great influence on the stringiness. The following is a summary of the effects on the cheese texture produced by raising the cooking temperature.
1.組織を構成するCaを介したパラカゼイネート架橋構造
が特異な密な構造形態(patially network-structured
Ca-paracaseinate in cheese)をとる。この構造は
実質的に糸ひき性に関与する構造であり、チーズの硬さ
を決定する構造と同一のものではない。即ち、硬さに関
連した構造が緻密となるよりは、糸ひき性に関連した構
造が緻密となるのである。一般に硬いチーズは水分量が
少ないが、本発明のチーズでは通常のチーズと一般分析
上で差異はほとんど認められない。1. Patially network-structured peculiar dense structure of paracaseinate cross-linking structure
Take Ca-paracaseinate in cheese). This structure is substantially related to the stringiness and is not the same as the structure that determines the hardness of cheese. That is, the structure related to stringiness is denser than the structure related to hardness is denser. Generally, hard cheese has a small amount of water, but the cheese of the present invention shows almost no difference from ordinary cheese in general analysis.
2.上記構造形態を有するチーズでは、熟成中に蛋白質分
解を受けても、通常のチーズ組織のようにほぼ平均的に
分解が進行することなく、比較的高分子の画分が相当量
残存し、この結果、同じ熟度でも糸ひき性が充分保持さ
れる。2.In the cheese having the above structural morphology, even if it undergoes proteolysis during ripening, the decomposition does not progress almost on average like ordinary cheese tissue, and a considerable amount of a relatively high molecular fraction remains. As a result, sufficient stringiness is maintained even with the same maturity.
上記特異なCa−パラカゼイネート架橋構造は通常実施さ
れているクッキング温度38℃以下では形成されないもの
であり、又43℃以上でなければ有効な効果として顕在化
しないことが判明した。即ち、43℃以上のクッキング温
度により、糸ひき性保持能力が発揮される程度に、分子
のからみ合いが進行する。一方、スターターの失活、圧
搾時のカードの結着不良、熟成の著しい遅延等を考慮
し、クッキング温度の適正範囲は55℃以下がよい。同類
のチーズを製造しかつ糸ひき性を大幅に改善するという
観点からすれば、43〜55℃の温度帯は臨界条件的意義が
ある。但し、従来行われていたクッキング温度40℃を越
える温度帯であれば若干でも糸ひき性改良効果は得られ
るので、場合により、40〜55℃の範囲で調節することも
可能である。It has been found that the above-mentioned unique Ca-paracaseinate crosslinked structure is not formed at a cooking temperature of 38 ° C or lower, which is usually practiced, and does not manifest as an effective effect unless it is 43 ° C or higher. That is, at a cooking temperature of 43 ° C. or higher, the entanglement of molecules proceeds to such an extent that the ability to retain the stringiness is exhibited. On the other hand, considering the deactivation of the starter, defective binding of the curd at the time of pressing, and significant delay in aging, the appropriate cooking temperature range is 55 ° C or lower. From the viewpoint of producing similar cheeses and greatly improving the stringiness, the temperature range of 43 to 55 ° C has critical significance. However, since the effect of improving the threading property can be obtained even in the temperature range which exceeds the conventional cooking temperature of 40 ° C, it is possible to adjust the temperature in the range of 40 to 55 ° C depending on the case.
このようにクッキング温度がその他嗜好性に係る物性に
は有意な影響を与えることなく、糸ひき性に関係するチ
ーズの構造形態を質的に変えてほぼ決定してしまうとい
う知見は従来まったく知られていなかったものである。
本発明によれば、糸ひき性をクッキング温度により制御
することが可能となる。従来の38℃で加温した場合は、
上述の強固な構造形態は形成されていないため、熟成の
進行によって構造は徐々に破壊される。それに応じて糸
ひき性は、顕著に劣化することになる。As described above, it has been known that the cooking temperature does not significantly affect the physical properties related to other palatability and qualitatively changes the structural form of cheese that is related to the stringiness and determines it. I didn't.
According to the present invention, it becomes possible to control the stringiness by the cooking temperature. When heated at the conventional temperature of 38 ℃,
Since the above-mentioned strong structural morphology is not formed, the structure is gradually destroyed by the progress of aging. Accordingly, the threading property is significantly deteriorated.
実際にゴーダチーズの製造でクッキング温度を変化させ
た場合、糸ひき性のシェルフライフは38℃の場合、4ケ
月だったものが、例えば55℃では12ケ月まで延長させる
ことが可能となる。When the cooking temperature is actually changed in the production of gouda cheese, the string life of shelf life is 38 months at 38 ° C., but it can be extended to 12 months at 55 ° C., for example.
ここで、チーズ製造工程中に、加温温度を上昇させるこ
とにより前述パラカゼイネートの緻密な架橋構造を形成
させるには、クッキング工程中に行わなければならない
点に留意すべきである。即ち、レンネットにより形成さ
れたカードであってカッティングされたカード粒に対し
て所定の加温を施すことが必要で、前記構造はカード粒
内のホエー排出の過程で構築される。又、加温条件のう
ち糸ひき性に係る緻密構造の生成にはクッキング温度の
調節が有効である。Here, it should be noted that in order to form the dense crosslinked structure of the paracaseinate by increasing the heating temperature during the cheese manufacturing process, it must be performed during the cooking process. That is, it is necessary to apply a predetermined heating to the cut card grains formed of rennet, and the structure is constructed in the process of discharging whey in the card grains. In addition, adjusting the cooking temperature is effective for producing a dense structure related to the stringiness of the heating conditions.
本発明に係るクッキング工程は次のように実施すること
ができる。The cooking process according to the present invention can be carried out as follows.
常法の技術に基づきチーズの種類に応じてカッティング
工程まで実施し、得られている所定の大きさのカード粒
をまず、比較的定温(〜30℃)を保持して数分間〜数十
分間静かに撹拌して、ホエーの一部(約1/3量)を抜
き、加温を始める。加熱は撹拌しながら熱水を少量づつ
注加する方法、ジャケットに蒸気を通ずる方法等いずれ
でもよい。クッキングはカード粒の破砕を起こさないた
めにおだやかに行うが目標到達温度等に応じて通常1℃
/3分間前後程度の一定加温速度で行うとよい。クッキン
グには通常90分間程度を要する。クッキング中にホエー
抜きを2回実施しても、又最後に1度に抜いてもよい。
又、ホエー抜き量も通常と同様でよい。Carry out up to the cutting process according to the type of cheese based on the conventional technique, and then the curd grains of the specified size are first kept at a relatively constant temperature (~ 30 ° C) for several minutes to several tens of minutes. Gently stir for a while, remove a portion of whey (about 1/3 amount), and start heating. Heating may be performed by adding hot water little by little while stirring, or by passing steam through a jacket. Cooking is done gently to prevent crushing of curd grains, but usually 1 ° C depending on the target temperature
/ It is recommended to perform the heating at a constant heating rate of about 3 minutes. Cooking usually takes about 90 minutes. The whey may be removed twice during cooking, or at the end once.
The whey removal amount may be the same as usual.
本発明によるクッキング工程で得られる最終的カードは
従来技術に基づいて得られるカードと外観上ほぼ同じで
ある。即ち、クッキング温度が高いと、カード粒表面か
らの脱水が促進されるが、同時に酸生成速度が遅れるた
め、結果的に水分値に大きな違いは生じない。カード粒
の大きさもほぼ同じとなる。The final card obtained from the cooking process according to the invention is virtually identical in appearance to the card obtained according to the prior art. That is, when the cooking temperature is high, dehydration from the surface of the curd particles is promoted, but at the same time, the acid generation rate is delayed, and as a result, a large difference in water value does not occur. The size of the curd grain is almost the same.
一方、クッキング温度条件の違いは、チーズのpHや熱溶
融性にも影響を与える。高温で活性の低下するスタータ
ーを使用した場合、チーズのpHは、製造直後でクッキン
グ温度による差が現れ、温度が高い程製造直後のチーズ
のpHは、高くなる。そして徐々に下がっていき、約1週
間経過すると、温度による差は、殆どなくなり、その後
ほぼ一定のpHになって安定していく。クッキング温度が
高いとpHが高くなるのは、スターターの活性が低下する
ためでこれにより、Ca−パラカゼイネートからのCaの脱
離が不充分となる。熱溶融性は、pHの変化に関連してお
り、pHが安定する約一週間が経過するまでは、熱溶融性
は悪いがpHが安定してくると、急激に向上する。即ち、
チーズの熱溶融性は、チーズ中のイオン性カルシウム量
と相関があり、製造後1週間位経過し、チーズのpHが低
下し安定してくるに伴なってカルシウムがCa−パラカゼ
イネートからはずれ、イオン性のカルシウム量が増加
し、ある程度イオン性のカルシウム量が増加した時点
で、チーズの熱溶融性は良くなる。製造後1ケ月以上す
ると、チーズの熱溶融性は高く安定してくるのは、その
ためである。On the other hand, the difference in cooking temperature conditions also affects the pH and heat meltability of cheese. When a starter whose activity decreases at high temperature is used, the pH of the cheese will differ depending on the cooking temperature immediately after the production, and the higher the temperature, the higher the pH of the cheese immediately after the production. Then, the temperature gradually decreases, and after about one week, the difference due to the temperature almost disappears, and thereafter, the pH becomes almost constant and becomes stable. Higher cooking temperatures lead to higher pH, which is due to a decrease in the activity of the starter, which leads to insufficient Ca desorption from Ca-paracaseinate. The heat-melting property is related to a change in pH. The heat-melting property is poor until about one week after the pH becomes stable, but it rapidly improves when the pH becomes stable. That is,
The heat-melting property of cheese has a correlation with the amount of ionic calcium in the cheese, and the calcium deviates from Ca-paracaseinate as the pH of the cheese decreases and stabilizes about one week after the production. When the amount of ionic calcium increases, and when the amount of ionic calcium increases to some extent, the heat melting property of cheese becomes good. This is why the cheese has a high heat-melting property and becomes stable after one month or more after the production.
ところで、熱溶融性は糸ひき性を示すための前提条件と
なるものであり、熱溶融性がある程度以上、向上しない
と良好な糸ひき性は得られない。そのため製造直後のチ
ーズでは、熱溶融性が低いので糸ひき性も十分発揮され
ない。従って、クッキング温度を高くすれば、製造後の
チーズの熱溶融性が若干低減する可能性がある。しか
し、これは本質的問題とはならない。時間経過において
自然と改善されるからであり、チーズのシャルフライフ
を考慮すれば必要な時間経過は製品価値において問題と
ならないためである。従来は、クッキング温度調節をチ
ーズの硬さ、熱溶融性、スターターの活性等の観点のみ
から規定し、糸ひき性という観点がまったく考慮されて
いなかったため、クッキング温度の上昇はマイナス効果
しかもたらさないものと考えられていたのである。By the way, the heat meltability is a prerequisite for exhibiting the thread drawability, and good thread drawability cannot be obtained unless the heat meltability is improved to some extent or more. Therefore, the cheese immediately after production has a low heat-melting property and thus cannot sufficiently exhibit stringiness. Therefore, if the cooking temperature is increased, the heat melting property of the cheese after production may be slightly reduced. However, this is not an essential issue. This is because it will be improved naturally over time, and considering the charf life of cheese, the necessary time will not be a problem in product value. In the past, cooking temperature control was specified only from the viewpoint of hardness of cheese, heat melting property, activity of starter, etc., and the viewpoint of stringiness was not taken into consideration at all, so an increase in cooking temperature has only a negative effect. It was thought to be a thing.
しかしながら、上記製造直後の熱溶融性の低さは比較的
55℃程度の高温でも十分な活性を示す高温菌スターター
を選択して用いることにより改善することができる。高
温菌スターターの使用により、クッキング温度を高温に
しても製造直後のpHは低くなり早い時期に安定するの
で、そのため、熱溶融性も向上し、良好な糸ひき性を示
すことになる。このような乳酸菌スターターに用いられ
る菌種としては、高温耐性のあるStr.thermophililus
等、高温でも発育しうるStr.durance等、特に高温クッ
キング用としてLact.casei,Lact.bulgarius,Lact.helve
ticum等を挙げることができる。但し、高温菌スタータ
ーを用いなくとも、Str.cremoris,Str.lactis,Str.diac
etilactis等の通常用いられる中温菌スターターでも充
分な糸ひき性保持能力を有するチーズが製造可能であ
る。However, the low thermal meltability immediately after the above production is relatively low.
It can be improved by selecting and using a thermophilic bacterium starter that exhibits sufficient activity even at a high temperature of about 55 ° C. By using a thermophilic bacterium starter, even if the cooking temperature is high, the pH immediately after production is low and stable at an early stage. Therefore, the heat-melting property is also improved, and good stringing property is exhibited. As a bacterial species used for such a lactic acid bacterium starter, Str. Thermophililus which has high temperature resistance
Lact.casei, Lact.bulgarius, Lact.helve, especially for high temperature cooking, such as Str.durance that can grow even at high temperatures
ticum etc. can be mentioned. However, even without using a thermophilic starter, Str.cremoris, Str.lactis, Str.diac
A cheese having a sufficient ability to retain stringiness can be produced even by a commonly used mesophilic starter such as etilactis.
クッキング工程におけるCa−パラカゼイネート架橋構造
の変化は、又、原料乳の脂肪率にも影響されうる。即
ち、脂肪率が少なくなると同一加温条件下でも構造形態
の緻密化が更に進む。好ましい原料乳の脂肪率は3.0%
以下である。Changes in the Ca-paracaseinate crosslinked structure during the cooking process can also be affected by the fat percentage of the raw milk. That is, when the fat percentage decreases, the densification of the structural morphology proceeds further even under the same heating conditions. The preferred fat percentage of raw milk is 3.0%
It is the following.
次に、前述製造方法により得られたチーズについて説明
する。Next, the cheese obtained by the above-mentioned manufacturing method will be described.
これらチーズの特徴は、可溶性窒素熟度指標が少なくと
も15〜25%の範囲において、糸ひき性が40cm以上であ
り、又非蛋白態窒素熟度指標が少なくとも10〜20%の範
囲において、糸ひき性が40cm以上であることである。The characteristics of these cheeses are that the soluble nitrogen maturity index is at least 15 to 25%, the threading property is 40 cm or more, and the non-protein nitrogen maturity index is at least 10 to 20%. The sex is 40 cm or more.
ここで、STN/TNが少なくとも15〜25%の範囲において糸
ひき性が40cm以上とは、当該範囲内では糸ひき性が増加
又は減少傾向にあるかにかかわらず糸ひき性が40cm以上
を保持するということであるが、クッキング温度を高く
したチーズではSTN/TNが25%のとき糸ひき性は同15%の
ときの糸ひき性より大きい。従来チーズではSTN/TNが15
%では糸ひき性が40cm以上であっても、STN/TNの増加に
伴い糸ひき性は急激に低下し、従って、STN/TNが20〜25
%の範囲では糸ひき性40cmを保持しえなくなる。一方本
発明のチーズではSTN/TNが20〜25%の範囲でも糸ひき性
は良好に保持され60cm以上を保持しうる。従って本発明
の好ましい態様においては、STN/TNが20〜25%の範囲で
糸ひき性が60cm以上である。Here, when the STN / TN is at least 15 to 25%, the threading property is 40 cm or more, and within the range, the threading property is 40 cm or more regardless of whether the threading property tends to increase or decrease. However, in cheese with a higher cooking temperature, the thread-forming property at STN / TN of 25% is higher than that at 15%. STN / TN of conventional cheese is 15
%, Even if the threading property is 40 cm or more, the threading property decreases sharply as STN / TN increases.
In the range of%, the thread pulling property of 40 cm cannot be maintained. On the other hand, in the cheese of the present invention, even if STN / TN is in the range of 20 to 25%, the threading property is kept good and it can hold 60 cm or more. Therefore, in a preferred embodiment of the present invention, the threading property is 60 cm or more in the STN / TN range of 20 to 25%.
STN/TNが15〜25%としたのは、この範囲における熟成度
は熟成工程、流通過程及びシャルフライフを勘定し、需
要者の嗜好性の観点から重要でこの範囲における糸ひき
性保持能力に意義があるためである。又、糸ひき性の基
準を40cm以上としたのは一般的な需要者層の嗜好が要求
する程度であると判断されるためである。STN / TN was set at 15 to 25% because the maturity in this range accounts for the maturation process, the distribution process and the shuffle life, and is important from the viewpoint of the taste of the consumer, and it is important to determine the ability to maintain the stringiness in this range. This is because it has significance. Further, the reason for setting the thread-pulling property to 40 cm or more is that it is judged to be a level required by the taste of a general consumer group.
又NPN/TNが少なくとも10〜20%の範囲において糸ひき性
が40cm以上であるとは、前述STN/TNと同義である。同様
に、好ましい態様においては、NPN/TNが12〜17%の範囲
で糸ひき性が60cm以上である。The fact that the thread-pulling property is 40 cm or more in the range of NPN / TN of at least 10 to 20% is synonymous with the above-mentioned STN / TN. Similarly, in a preferred embodiment, the threading property is 60 cm or more in the NPN / TN range of 12 to 17%.
NPN/TNが10〜20%としたのはSTN/TNが15〜25%としたの
と同義である。NPN / TN of 10 to 20% is synonymous with STN / TN of 15 to 25%.
従来チーズは熟成により、酵素化学的、細菌学的及び有
機化学的反応等を組織上、風味上の変化を発現するが、
熟成過程のチーズの構造性をになう蛋白質の分解が進行
し可溶性窒素及び非蛋白態窒素量の増加と伴に低分子化
し、この結果糸ひき性に関与する構造形態が破壊され、
糸ひき性が劣化する。本発明のチーズは、糸ひき性に関
与する構造、即ちCa−パラカゼイネート架橋構造が緻密
となっているため、熟成中における蛋白質分解のパター
ンが均一に進行せず、比較的高分子の画分が相当量残存
する結果、糸ひき性の劣化に対し優れた耐性を示し、糸
ひき性保持能力が大幅に改善される。これは従来チーズ
は特異の構造形態をもたないために蛋白質分解が比較的
均一に進行し構造性の崩壊が速いことと対照をなす。Conventional cheese develops changes in texture and flavor such as enzymatic chemical, bacteriological and organic chemical reactions upon aging,
Degradation of protein that becomes the structural property of cheese during ripening progresses to a low molecular weight with the increase of the amount of soluble nitrogen and non-protein nitrogen, and as a result, the structural morphology involved in stringiness is destroyed,
Threading property deteriorates. The cheese of the present invention has a structure involved in stringiness, that is, the Ca-paracaseinate crosslinked structure is dense, so that the pattern of proteolysis during ripening does not proceed uniformly, and a relatively high molecular weight As a result that a considerable amount remains, it exhibits excellent resistance to deterioration of the threading property and the ability to retain the threading property is greatly improved. This contrasts with the conventional cheese, which does not have a peculiar structural morphology, so that the proteolysis proceeds relatively uniformly and the structural disintegration is rapid.
更に、本発明のチーズにおいて特徴的なことは、風味、
食感等、糸ひき性以外の特性は従来チーズと実質的な差
異がないことで、これは風味醸成の熟成過程の物質変化
においては差異がないことを意味する。即ち、可溶性窒
素量等の変化に顕著な差異はなく、従来チーズと同様に
種々の酵素等の作用を受ける。チーズの硬さに関与する
組織構造が有意に異なる場合は、水分の分散状態等も異
なっており、風味醸成過程における物質変化に違いが生
じ風味、食感等が同じチーズは製造できないことと対照
をなす。Furthermore, the characteristic of the cheese of the present invention is the flavor,
Properties other than stringiness, such as texture, are not substantially different from those of conventional cheeses, which means that there is no difference in substance change during the ripening process of flavor brewing. That is, there is no noticeable difference in the change of the amount of soluble nitrogen and the like, and it is affected by various enzymes and the like like conventional cheese. When the tissue structure involved in the hardness of cheese is significantly different, the dispersion state of water is also different, resulting in a difference in substance change in the flavor brewing process, in contrast to the fact that cheeses with the same flavor and texture cannot be produced. Make up.
ここで、チーズの組成構造を、硬さに関与するもの、糸
ひき性に関与するもの、及び熱溶融性に関与するものの
3つに分けて考えると、硬さに関与するものはチーズの
組織自体の緻密性(含水率と相関有)、熱溶融性に関与
するものはチーズ中のイオン性カルシウム量(pHと相関
有)と関連している一方、糸ひき性はカルシウムを介し
たパラカゼイネート架橋構造の緻密性に直接関連してい
る点で大きく異なっている。(溶けの悪いチーズは糸ひ
き以前の問題といえる。) 熱溶融性は糸ひき性を発現させるための必要条件ではあ
るが、同義でなく、熱溶融性に差異がないチーズ同士で
も糸ひき性に差異が生じる場合があり、特に、糸ひき性
発現に必要な熱溶融性をかくとくした後は、熱溶融性の
値のいかんを問わず糸ひき性は変化する。又硬いチーズ
でも蛋白分解が比較的均一に生じれば糸ひき性の劣化は
速い。Here, when the compositional structure of cheese is divided into three parts, one related to hardness, one related to stringiness, and one related to heat melting property, the one related to hardness is the texture of cheese. The factors involved in the compactness (correlation with water content) of itself and the heat-melting property are related to the amount of ionic calcium in cheese (correlation with pH), whereas the stringiness is paracasei mediated by calcium. The difference is that it is directly related to the compactness of the nate crosslinked structure. (Cheese that melts poorly can be said to be a problem before stringing.) Heat meltability is a necessary condition for developing stringiness, but it is not synonymous and even cheeses that have no difference in heat meltability can be stringed. May occur, and in particular, after the heat-melting property required for expression of the thread-drawing property is removed, the thread-drawing property changes regardless of the value of the heat-melting property. In addition, even with hard cheese, if the protein decomposition occurs relatively uniformly, the threading property deteriorates quickly.
前述したように、クッキング温度を高くすると製造直後
の熱溶融性は良好ではない。これはイオン性カルシウム
量が不充分なためで、経時的にpHが低がり、イオン性カ
ルシウムが増加してくればまったく問題がないので、そ
のこと自体は本質的な問題でなない。糸ひき性は熱溶融
性と関連があり、製造直後の糸ひき性は不充分となりう
るが、その程度の糸ひき性の低下は従来チーズでもみら
れる程度である。従来チーズでも製造直後の熱溶融性は
悪い。但し、従来チーズでは経時変化にともない熱溶融
性が改善された後は糸ひき性の劣化が始まる。本発明チ
ーズでは熱溶融性が改善された後も糸ひき性の劣化を生
じることなく、優れた糸ひき性を保持する。As described above, when the cooking temperature is increased, the heat meltability immediately after production is not good. This is not an essential problem because there is no problem if the amount of ionic calcium is insufficient and the pH decreases over time and the amount of ionic calcium increases. The thread drawability is related to the heat melting property, and the thread drawability immediately after the production may be insufficient, but such a decrease in the thread drawability is only observed in conventional cheese. Even conventional cheese has poor heat meltability immediately after production. However, in conventional cheese, the threading property begins to deteriorate after the heat melting property is improved with the lapse of time. In the cheese of the present invention, even after the heat melting property is improved, the threading property is not deteriorated and the excellent threading property is retained.
本発明のチーズは従来チーズと水分等の一般分析値に差
異はない。Ca−パラカゼイネート架橋構造による構造性
にのみ差異がある。この特異構造の存在は同一可溶性窒
素量(%)等における糸ひき性の値を測定することによ
り知りうる。本発明のチーズでは可溶性窒素及び非蛋白
態窒素の両者の値が従来チーズと同一でも、糸ひき性が
有効に大きい。The cheese of the present invention does not differ from conventional cheese in general analysis values such as water content. There is only a difference in the structural properties due to the Ca-paracaseinate crosslinked structure. The existence of this specific structure can be known by measuring the threading property value at the same soluble nitrogen content (%). In the cheese of the present invention, even if the values of both soluble nitrogen and non-protein nitrogen are the same as those of conventional cheese, the threading property is effectively large.
[実施例] 以下、実施例により本発明を説明する。[Examples] Hereinafter, the present invention will be described with reference to Examples.
実施例1 ゴーダチーズを以下の要領で製造した。Example 1 Gouda cheese was produced in the following manner.
脂肪率を調節した乳(Fat=2.8%及び2.0%)150kgを殺
菌冷却(原料乳処理工程)した後、30℃になったらBD−
CH01(ハンセン社)スターター(Str.Cremoris,Str.Lac
tis等)を1%添加し、60分間前後熱(乳酸発酵工
程)、子牛レンネット(HR)を0.003%添加し30分間程
静置させ(レンネッティング工程)、カッティング(カ
ード粒の大きさはアズキから大豆粒程度の大きさ)(カ
ッティング工程)を行ない以下のクッキング工程を実施
した。After sterilizing and cooling 150kg of milk (Fat = 2.8% and 2.0%) with adjusted fat percentage (raw milk processing step), when it reaches 30 ° C, BD-
CH01 (Hansen) Starter (Str.Cremoris, Str.Lac
(Tis etc.) 1%, heat for about 60 minutes (lactic acid fermentation process), add veal rennet (HR) 0.003% and let stand for about 30 minutes (rennetting process), cutting (size of curd grain) Was processed from adzuki bean to soybean grains (cutting step) and the following cooking step was performed.
・1/3量のホエーを除去後、加温開始 ・到達温度:38℃,43℃,55℃の3種類 ・加温速度:1℃/3分間 ・加温時間:90分間 ・加温終了後、残りホエーを除去 つづいて、圧搾(0.35Kg/cm2)し(型詰工程)チーズ成
型物を得た。これを23%NaCl水溶液に2時間浸漬させリ
ンドレスタイプにして熟成させた。熟成条件は、温度10
℃,湿度75〜85%であった。・ Start heating after removing 1/3 amount of whey ・ Achieved temperature: 3 types of 38 ℃, 43 ℃, 55 ℃ ・ Warming speed: 1 ℃ / 3 minutes ・ Warming time: 90 minutes ・ End of heating After that, the remaining whey was removed, followed by pressing (0.35 Kg / cm 2 ) (molding step) to obtain a cheese molded product. This was immersed in a 23% NaCl aqueous solution for 2 hours to make it a Lindless type and aged. Aging conditions are temperature 10
The temperature and humidity were 75 to 85%.
結果を表1〜3及び第1図に示す。各数値は以下の要領
で得られたものである。The results are shown in Tables 1 to 3 and FIG. Each value is obtained as follows.
(糸ひき性試験) 試料チーズを20gシャーレに採取しこれを約90℃で1分
間加熱溶融させる。次にこのチーズを糸ひき性測定機に
よって10cm/sの速度で引っぱり上げチーズの糸ひきの長
さ(cm)を測定した(5回の平均を長さとした)。(Stringiness test) Sample cheese is sampled in a 20 g petri dish and heated and melted at about 90 ° C for 1 minute. Next, this cheese was pulled up at a speed of 10 cm / s by a stringiness measuring machine and the length (cm) of the stringiness of the cheese was measured (an average of 5 times was taken as the length).
(熱溶融性試験) 試料(一辺15mmの立方体に切ったチーズをオーブントー
スタ(230℃)で2分30秒間加熱溶融させ、熱溶融後の
チーズの大きさ(mm)を測定した。(Heat Meltability Test) Sample (cheese cut into cubes of 15 mm on a side was heated and melted for 2 minutes and 30 seconds with an oven toaster (230 ° C.), and the size (mm) of the cheese after heat melting was measured.
(チーズ熟度の測定) (1)試料溶液:チーズ10gを採取し、それに0.5Nクエ
ン酸ナトリウム40ml、蒸溜水40mlを加え、ホモブレンダ
ーで5分間磨砕後、メスフラスコに移し水を加え200ml
定容とする。(Measurement of cheese maturity) (1) Sample solution: 10 g of cheese is sampled, 40 ml of 0.5N sodium citrate and 40 ml of distilled water are added thereto, and the mixture is ground in a homoblender for 5 minutes, then transferred to a volumetric flask and water is added to 200 ml.
The volume is fixed.
(2)全窒素(TN):試料10mlを採取しケルダール法で
測定した。(2) Total nitrogen (TN): 10 ml of a sample was sampled and measured by the Kjeldahl method.
(3)可溶性窒素(STN):試料液100mlに1.41N塩酸を1
0ml加え、混合後蒸溜水で125mlに定容した。生成した蛋
白沈澱物を濾過し、濾液10mlを採取しケルダール法で測
定した。(3) Soluble nitrogen (STN): 1 ml of 1.41N hydrochloric acid in 100 ml of sample solution
After adding 0 ml and mixing, the volume was adjusted to 125 ml with distilled water. The produced protein precipitate was filtered, and 10 ml of the filtrate was collected and measured by the Kjeldahl method.
(4)非蛋白態窒素(NPN):(3)の濾液20mlに24%
トリクロル酢酸20mlを加え、30分放置後濾過して得られ
た濾液を採取しケルダール法で測定した。(4) Non-protein nitrogen (NPN): 24% in 20 ml of the filtrate of (3)
20 ml of trichloroacetic acid was added, and the mixture was allowed to stand for 30 minutes and filtered, and the resulting filtrate was collected and measured by the Kjeldahl method.
表1が示すように、クッキング温度を43℃,55℃に高め
たもの、更に脂肪分を2.0%まで下げたものは糸ひき性
保持能力が良好でありしかも糸ひき性のシェルフライフ
も長くなることがわかる。この様にクッキング温度条件
及び脂肪率を変化させることで熟成期間に応じた糸ひき
性の変化に大きな差異が生じ、基本的にクッキング温度
を上げることにより、チーズの糸ひき性を長期間持続さ
せることが可能であった。As shown in Table 1, those with the cooking temperature raised to 43 ° C and 55 ° C and those with the fat content reduced to 2.0% have good thread-pulling ability and have a long thread-pulling shelf life. I understand. By changing the cooking temperature conditions and the fat percentage in this way, a large difference occurs in the change in the thread-forming property according to the aging period, and basically by increasing the cooking temperature, the thread-forming property of the cheese is maintained for a long period of time. It was possible.
一方、熟度に対して糸ひき性は第1図及び表1に示すよ
うに変化するが、クッキング温度を高くすることで熟成
が進行しても良好な糸ひき性を保持できた。具体的に
は、熟度指数STN/TNで規定すると43〜55℃の範囲で加温
したチーズは、STN/TNが15%以上でも糸ひき性試験で40
cm以上の良好な値を示し、またもう一つの熟度指数NPN/
TNで規定した場合も43〜55℃の範囲で加熱したチーズは
NPN/TNが10%以上でも糸ひき性試験で40cm以上の良好な
値を示していた。 On the other hand, although the threading property changes depending on the maturity as shown in FIG. 1 and Table 1, by increasing the cooking temperature, good threading property could be maintained even when aging progressed. Specifically, when cheese is heated in the range of 43 to 55 ℃ when defined by the maturity index STN / TN, even if STN / TN is 15% or more, it is 40
It shows a good value of cm or more and another maturity index NPN /
Even if specified by TN, cheese heated in the range of 43 to 55 ° C
Even when NPN / TN was 10% or more, a good value of 40 cm or more was shown in the stringiness test.
又、pH,熱溶融性の結果を表2,表3に示す。製造直後は
クッキング温度が43℃,55℃と高くなるとpHは高くなっ
ているが、それらは約1〜2週間後では、クッキング温
度38℃のものとほぼ同様の値に近づき、その後わずかづ
つ上昇し、pH5.4位で一定で安定した。熱溶融性は製造
直後は不十分であったが、約1週間後から向上し、2週
間以上経過すると安定した良好な水準を維持した。又、
クッキング温度の差による一般分析上の有意差に認めら
れず(表4)、風味、食感上の差異はなくいずれも美味
なゴーダチーズと認められた。The results of pH and heat melting property are shown in Tables 2 and 3. Immediately after the production, the pH increased as the cooking temperature increased to 43 ℃ and 55 ℃, but after about 1 to 2 weeks, the pH approached the value similar to that at 38 ℃, and then gradually increased. However, it was constant and stable at about pH 5.4. The heat meltability was insufficient immediately after production, but improved from about 1 week later, and remained stable and good level after 2 weeks or more. or,
No significant difference was found in the general analysis due to the difference in cooking temperature (Table 4), and there was no difference in flavor and texture, and all were recognized as delicious gouda cheese.
実施例2 脱脂チーズを以下の要領で製造した。 Example 2 Defatted cheese was produced in the following manner.
原料乳として脱脂乳を用い脱脂乳(Fat=0.1%)150Kg
を殺菌冷却し30℃まで温度が下がったら(原料乳処理工
程)BD−CH01(ハンセン社)スターター(Str.Cremori
s,Str.Lactis等)を1%添加し、60分間前熱後(乳酸発
酵工程)、子牛レンネット(HR)を0.003%添加し30分
間程静置させ(レンネッティング工程)、カードを形成
させた後、カッティング(カード粒の大きさはアズキか
ら大豆粒程度の大きさ)(カッティング工程)を行な
い、以下のクッキング工程を実施した。Skim milk (Fat = 0.1%) 150Kg using skim milk as raw material milk
When sterilized and cooled to a temperature of 30 ° C (raw milk treatment process), BD-CH01 (Hansen) starter (Str.Cremori
s, Str.Lactis etc.) is added 1%, and after preheating for 60 minutes (lactic acid fermentation process), 0.003% of calf rennet (HR) is added and allowed to stand for about 30 minutes (rennetting process). After the formation, cutting (the size of curd grains is from Azuki to soybean grains) (cutting process) was performed, and the following cooking process was carried out.
・1/3量のホエーを除去後、加温開始 ・到達温度:38℃,43℃,55℃の3種類 ・加温速度:1℃/3分間 ・加温時間:90分間 ・加温終了後、残りホエーを除去 その後2時間圧搾し型詰工程を行ないチーズ成型物を得
た。これを23%NaCl水溶液に2時間浸漬させ、リンドレ
スタイプにして熟成させた。この結果、糸ひき性に関し
て表5の様な結果が得られた。クッキング温度が43℃,5
5℃と高い程、糸ひき性のシェルフライフは延び組織の
硬さも適当なチーズが作れ、このものは、チーズの風
味、食感等はまったく変わらない美味なチーズであっ
た。・ Start heating after removing 1/3 amount of whey ・ Achieved temperature: 3 types of 38 ℃, 43 ℃, 55 ℃ ・ Warming speed: 1 ℃ / 3 minutes ・ Warming time: 90 minutes ・ End of heating After that, the remaining whey was removed, followed by squeezing for 2 hours to perform a mold filling step to obtain a cheese molded product. This was immersed in a 23% NaCl aqueous solution for 2 hours to make it a Lindless type and aged. As a result, the results as shown in Table 5 were obtained regarding the stringiness. Cooking temperature is 43 ℃, 5
The higher the temperature was 5 ° C., the longer the stringy shelf life was, and the cheese with an appropriate tissue hardness could be made. This was a delicious cheese with no change in cheese flavor or texture.
[発明の効果] 以上説明したように本発明によればクッキング温度の調
節により糸ひき性の制御が可能となり、需要者層の嗜好
性に合わせ適度な糸ひき性を有する熟成硬質チーズを適
宜製造することが可能となる。 [Effects of the Invention] As described above, according to the present invention, it is possible to control the threading property by adjusting the cooking temperature, and appropriately produce an aged hard cheese having an appropriate threading property in accordance with the taste of the consumer group. It becomes possible to do.
更に得られたチーズは、糸ひき性保持能力に優れている
他は、従来チーズと同様の風味、食感を有しており、本
発明の技術はチーズ産業上、非常に有用なものである。Furthermore, the obtained cheese has a flavor and texture similar to those of conventional cheese, in addition to being excellent in stringiness retaining ability, and the technique of the present invention is very useful in the cheese industry. .
第1図は本発明の実施例1において得られたチーズの熟
成と糸ひき性との関係を示すグラフであり、(a)は熟
度としてSTN/TNをとったもの、(b)は熟度としてNPN/
TNをとったものを示す。FIG. 1 is a graph showing the relationship between ripening and stringiness of the cheese obtained in Example 1 of the present invention, where (a) is STN / TN as maturity, and (b) is ripening. NPN / as a degree
Shown is the TN.
Claims (9)
工程の到達温度を40℃を超え55℃以下の温度範囲内とす
ることにより得られる、可溶性窒素熟度指標(可溶性窒
素/全窒素×100)が少なくとも15〜25%の範囲におい
て、糸ひき性が40cm以上である熟成硬質チーズ。1. A soluble nitrogen maturity index (soluble nitrogen / total nitrogen × 100) obtained by controlling the temperature reached in the cooking step in the production of aged hard cheese to be in the temperature range of higher than 40 ° C. and lower than 55 ° C. Aged hard cheese having a stringiness of 40 cm or more in at least 15 to 25%.
工程の到達温度を40℃を超え55℃以下の温度範囲内とす
ることにより得られる、非蛋白態窒素熟度指標(非蛋白
態窒素/全窒素×100)が少なくとも10〜20%の範囲に
おいて、糸ひき性が40cm以上である熟成硬質チーズ。2. A non-protein nitrogen maturity index (non-protein nitrogen / total nitrogen) obtained by controlling the temperature reached in the cooking step in the production of aged hard cheese to be in the temperature range of more than 40 ° C. and less than 55 ° C. Aged hard cheese having a stringiness of 40 cm or more in the range of (x100) of at least 10 to 20%.
の範囲において糸ひき性が60cm以上である請求項1に記
載の熟成硬質チーズ。3. A soluble nitrogen maturity index of at least 20-25%
The aged hard cheese according to claim 1, which has a stringiness of 60 cm or more in the range.
%の範囲において、糸ひき性が60cm以上である請求項2
に記載の熟成硬質チーズ。4. A non-protein nitrogen maturity index of at least 12 to 17
% In the range of 60% or more and the threading property is 60 cm or more.
Aged hard cheese according to.
いずれかに記載の熟成硬質チーズ。5. The aged hard cheese according to any one of claims 1 to 4, which is classified as Gouda cheese.
グ工程における到達温度が43〜55℃の範囲になるように
加温することを特徴とする、糸ひき性の改良された熟成
硬質チーズの製造方法。6. A method for producing an aged hard cheese with improved stringiness, which is characterized in that in the production of an aged hard cheese, the temperature reached in the cooking step is heated to a range of 43 to 55 ° C. .
に記載の熟成硬質チーズの製造方法。7. A raw material milk having a fat percentage of 3% or less is used.
The method for producing an aged hard cheese according to 1.
の熟成硬質チーズの製造方法。8. The method for producing an aged hard cheese according to claim 6, which is classified as Gouda cheese.
ーである請求項6に記載の熟成硬質チーズの製造方法。9. The method for producing an aged hard cheese according to claim 6, wherein the lactic acid bacterium starter used is a thermophilic bacterium starter.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2318067A JPH0687736B2 (en) | 1990-11-26 | 1990-11-26 | Aged hard cheese and method for producing the same |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2318067A JPH0687736B2 (en) | 1990-11-26 | 1990-11-26 | Aged hard cheese and method for producing the same |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPH04190740A JPH04190740A (en) | 1992-07-09 |
| JPH0687736B2 true JPH0687736B2 (en) | 1994-11-09 |
Family
ID=18095115
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2318067A Expired - Fee Related JPH0687736B2 (en) | 1990-11-26 | 1990-11-26 | Aged hard cheese and method for producing the same |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH0687736B2 (en) |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP2052625B1 (en) * | 2007-10-23 | 2017-12-13 | FrieslandCampina Nederland B.V. | Semi-hard cheese with Mozzarella-like textural properties, and its preparation |
Family Cites Families (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5495769A (en) * | 1977-12-30 | 1979-07-28 | Hausu Shiyokuhin Kougiyou Kk | Finely cut cheese for pizza pie and production of said pie |
| JPS62285755A (en) * | 1986-06-04 | 1987-12-11 | Snow Brand Milk Prod Co Ltd | Production of stringy cheese |
| JP2557262B2 (en) * | 1988-09-28 | 1996-11-27 | 雪印乳業株式会社 | Process for producing cheese-like food with high water content and excellent spinnability |
-
1990
- 1990-11-26 JP JP2318067A patent/JPH0687736B2/en not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| JPH04190740A (en) | 1992-07-09 |
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