JPH0687975B2 - Catalyst for the production of heavy aliphatic hydrocarbons - Google Patents
Catalyst for the production of heavy aliphatic hydrocarbonsInfo
- Publication number
- JPH0687975B2 JPH0687975B2 JP3053271A JP5327191A JPH0687975B2 JP H0687975 B2 JPH0687975 B2 JP H0687975B2 JP 3053271 A JP3053271 A JP 3053271A JP 5327191 A JP5327191 A JP 5327191A JP H0687975 B2 JPH0687975 B2 JP H0687975B2
- Authority
- JP
- Japan
- Prior art keywords
- catalyst
- ruthenium
- heavy aliphatic
- aliphatic hydrocarbons
- hydrocarbons
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000003054 catalyst Substances 0.000 title claims description 39
- 150000001338 aliphatic hydrocarbons Chemical class 0.000 title claims description 19
- 238000004519 manufacturing process Methods 0.000 title description 7
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 17
- 229910052739 hydrogen Inorganic materials 0.000 claims description 17
- 239000001257 hydrogen Substances 0.000 claims description 17
- KJTLSVCANCCWHF-UHFFFAOYSA-N Ruthenium Chemical compound [Ru] KJTLSVCANCCWHF-UHFFFAOYSA-N 0.000 claims description 14
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 13
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 claims description 13
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 claims description 10
- 229910002091 carbon monoxide Inorganic materials 0.000 claims description 10
- LEONUFNNVUYDNQ-UHFFFAOYSA-N vanadium atom Chemical compound [V] LEONUFNNVUYDNQ-UHFFFAOYSA-N 0.000 claims description 9
- 229910052720 vanadium Inorganic materials 0.000 claims description 8
- 229910052707 ruthenium Inorganic materials 0.000 claims description 7
- 229910001925 ruthenium oxide Inorganic materials 0.000 claims description 7
- 229910001935 vanadium oxide Inorganic materials 0.000 claims description 3
- 229930195733 hydrocarbon Natural products 0.000 description 21
- 150000002430 hydrocarbons Chemical class 0.000 description 16
- 239000004215 Carbon black (E152) Substances 0.000 description 11
- 238000006243 chemical reaction Methods 0.000 description 8
- 239000007789 gas Substances 0.000 description 7
- 238000000034 method Methods 0.000 description 6
- -1 chloride can be used Chemical class 0.000 description 5
- 238000009826 distribution Methods 0.000 description 5
- 229910052799 carbon Inorganic materials 0.000 description 4
- YBCAZPLXEGKKFM-UHFFFAOYSA-K ruthenium(iii) chloride Chemical compound [Cl-].[Cl-].[Cl-].[Ru+3] YBCAZPLXEGKKFM-UHFFFAOYSA-K 0.000 description 4
- 239000000126 substance Substances 0.000 description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 4
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 description 3
- 239000000243 solution Substances 0.000 description 3
- 229910002012 Aerosil® Inorganic materials 0.000 description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- 229910010413 TiO 2 Inorganic materials 0.000 description 2
- 239000007864 aqueous solution Substances 0.000 description 2
- UNTBPXHCXVWYOI-UHFFFAOYSA-O azanium;oxido(dioxo)vanadium Chemical compound [NH4+].[O-][V](=O)=O UNTBPXHCXVWYOI-UHFFFAOYSA-O 0.000 description 2
- 230000000052 comparative effect Effects 0.000 description 2
- 238000002474 experimental method Methods 0.000 description 2
- 238000005470 impregnation Methods 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 238000001556 precipitation Methods 0.000 description 2
- 238000003756 stirring Methods 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 1
- 125000004432 carbon atom Chemical group C* 0.000 description 1
- 238000000975 co-precipitation Methods 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 150000003303 ruthenium Chemical class 0.000 description 1
- 150000003304 ruthenium compounds Chemical class 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 229910052719 titanium Inorganic materials 0.000 description 1
- 239000010936 titanium Substances 0.000 description 1
- XJDNKRIXUMDJCW-UHFFFAOYSA-J titanium tetrachloride Chemical compound Cl[Ti](Cl)(Cl)Cl XJDNKRIXUMDJCW-UHFFFAOYSA-J 0.000 description 1
- 150000003681 vanadium Chemical class 0.000 description 1
- 150000003682 vanadium compounds Chemical class 0.000 description 1
Classifications
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts
Landscapes
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
- Catalysts (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Description
【０００１】[0001]
【産業上の利用分野】本発明は、水素と一酸化炭素から
炭素数１２以上の重質脂肪族炭化水素を製造するために
用いられる触媒に関する。BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a catalyst used for producing a heavy aliphatic hydrocarbon having 12 or more carbon atoms from hydrogen and carbon monoxide.
【０００２】[0002]
【従来の技術】水素と一酸化炭素との混合ガス（合成ガ
ス）から重質脂肪族炭化水素を製造する方法は知られて
いる。この反応における触媒としては、従来、ルテニウ
ムを酸化アルミニウムに担持させた触媒が提案されてい
る。また、重質脂肪族炭化水素を製造するには、２００
気圧以上の高圧下で反応を行うことが必要であることも
報告されている。しかしながら、１００気圧以下では触
媒あたりの重質脂肪族炭化水素生成速度および全生成物
中の重質脂肪族炭化水素選択率が十分ではなかった。2. Description of the Related Art A method for producing heavy aliphatic hydrocarbons from a mixed gas (synthesis gas) of hydrogen and carbon monoxide is known. As a catalyst for this reaction, a catalyst in which ruthenium is supported on aluminum oxide has been conventionally proposed. Also, in order to produce heavy aliphatic hydrocarbons, 200
It has also been reported that it is necessary to carry out the reaction under high pressure above atmospheric pressure. However, at 100 atm or less, the production rate of heavy aliphatic hydrocarbons per catalyst and the selectivity of heavy aliphatic hydrocarbons in all products were not sufficient.
【０００３】[0003]
【発明が解決しようとする課題】水素と一酸化炭素から
１００気圧以下の圧力で触媒あたりの重質脂肪族炭化水
素生成速度および全生成物中の重質脂肪族炭化水素選択
率が高い触媒を提供することである。A catalyst having a high production rate of heavy aliphatic hydrocarbons per catalyst and a high selectivity of heavy aliphatic hydrocarbons in all products from hydrogen and carbon monoxide at a pressure of 100 atm or less. Is to provide.
【０００４】[0004]
【課題を解決するための手段】本発明によれば、ルテニ
ウムおよびバナジウムおよび酸化チタンを含有する水素
と一酸化炭素からの重質脂肪族炭化水素製造用触媒が提
供される。本発明の触媒は、最初にルテニウムと酸化チ
タンとからなる物質を調製し、続いてこれにバナジウム
を添加することによって得られる。According to the present invention, there is provided a catalyst for producing a heavy aliphatic hydrocarbon from hydrogen and carbon monoxide containing ruthenium, vanadium and titanium oxide. The catalyst of the present invention is obtained by first preparing a substance consisting of ruthenium and titanium oxide, and then adding vanadium to it.
【０００５】本触媒に用いられるルテニウム化合物とし
ては、塩化物等の可溶性ルテニウム塩の各種溶液が使用
できるが、とくに塩化物を用いるのがよい。本触媒に用
いられる酸化チタンの製造法及び処理法は如何なるもの
でもよい。要は、触媒中で酸化チタンの形態をとること
にあり、原料としては、酸化チタンの他に塩化チタン、
チタンアルコキシド等を用いることができる。また、本
触媒に用いられるバナジウム化合物としては、可溶性バ
ナジウム塩の各種溶液が使用できる。As the ruthenium compound used in the present catalyst, various solutions of a soluble ruthenium salt such as chloride can be used, but chloride is particularly preferable. Any method may be used for producing and treating the titanium oxide used in the present catalyst. The point is that it takes the form of titanium oxide in the catalyst, and as a raw material, in addition to titanium oxide, titanium chloride,
Titanium alkoxide or the like can be used. As the vanadium compound used in the present catalyst, various solutions of soluble vanadium salt can be used.
【０００６】ルテニウムと酸化チタンからなる物質の調
製は、公知の含浸法、共沈法、沈澱法等によって行われ
る。調製後の物質は、水素気流中にて２５０〜４５０℃
で処理される。このようにして得られたルテニウムと酸
化チタンからなる物質へのバナジウムの添加は、公知の
含浸法、沈澱法等によって行われる。得られたルテニウ
ム及びバナジウム及び酸化チタンからなる物質は、この
まま又は１５０〜４５０℃で水素処理して重質脂肪族炭
化水素製造用触媒として用いることができる。全触媒中
のルテニウム含有量は、ルテニウム原子として０．１〜
１０wt％であり、バナジウム含有量は、原子比でルテニ
ウムに対して０．１〜２．０である。本発明の触媒は、
流動床、固定床のいずれにも使用することができる。触
媒の粒子径、形状は、反応器の形式に応じて任意に選択
し得る。The substance consisting of ruthenium and titanium oxide is prepared by a known impregnation method, coprecipitation method, precipitation method or the like. The prepared material is 250 to 450 ° C in a hydrogen stream.
Is processed in. The addition of vanadium to the thus-obtained substance consisting of ruthenium and titanium oxide is carried out by a known impregnation method, precipitation method or the like. The obtained substance consisting of ruthenium, vanadium and titanium oxide can be used as it is or after hydrogen treatment at 150 to 450 ° C. to be used as a catalyst for producing heavy aliphatic hydrocarbons. The ruthenium content in all catalysts is 0.1 to 10 as the ruthenium atom.
The vanadium content is 0.1 to 2.0 with respect to ruthenium in atomic ratio. The catalyst of the present invention is
It can be used in both fluidized beds and fixed beds. The particle size and shape of the catalyst can be arbitrarily selected according to the type of reactor.
【０００７】本発明の触媒を用いて重質脂肪族炭化水素
を製造するには、水素と一酸化炭素の混合ガスを温度１
００〜３００℃、好ましくは１５０〜２５０℃、圧力１
〜１００気圧、好ましくは１０〜５０気圧の条件で、本
発明触媒と接触させればよい。To produce heavy aliphatic hydrocarbons using the catalyst of the present invention, a mixed gas of hydrogen and carbon monoxide is used at a temperature of 1
00-300 ° C, preferably 150-250 ° C, pressure 1
It may be contacted with the catalyst of the present invention under the conditions of -100 atm, preferably 10-50 atm.
【０００８】[0008]
【実施例】以下、本発明を実施例によりさらに詳細に説
明する。EXAMPLES The present invention will now be described in more detail with reference to examples.
【０００９】実施例１ 塩化ルテニウム０．３６ｇを水約１７０ｍｌに溶解させ
た。酸化チタン（日本アエロジル製Ｐ−２５）１４．８
５ｇに上記の塩化ルテニウム水溶液を加えてよくかきま
ぜながら含浸させた。これを、常温下で減圧乾燥させた
後、水素気流中、４００℃で５時間処理した。水素処理
して得られた物に、メタバナジン酸アンモニウム０．０
８７ｇを水約４０ｍｌに溶解させたものを添加した。こ
れを、常温下で減圧乾燥させて触媒を得た。得られた触
媒の組成は、Ｒｕ１wt％、Ｖ／Ｒｕ比０．５、ＴｉＯ2
残余であった。Example 1 0.36 g of ruthenium chloride was dissolved in about 170 ml of water. Titanium oxide (Nippon Aerosil P-25) 14.8
The above ruthenium chloride aqueous solution was added to 5 g to thoroughly impregnate it with stirring. This was dried under reduced pressure at room temperature and then treated at 400 ° C. for 5 hours in a hydrogen stream. Ammonium metavanadate 0.0
A solution of 87 g dissolved in about 40 ml of water was added. This was dried under reduced pressure at room temperature to obtain a catalyst. The composition of the obtained catalyst was Ru 1 wt%, V / Ru ratio of 0.5, TiO 2
It was the rest.
【００１０】このようにして得られた触媒０．２ｇを反
応管（ＳＵＳ３０４製）に充填し、これを水素気流中、
４００℃で３時間処理した。次に、これに水素と一酸化
炭素の混合ガス（Ｈ2 ／ＣＯ＝１．０）を流量１００Ｎ
ｍｌ／ｍｉｎ、圧力３０気圧、温度２７５℃の条件で接
触させた。その結果、ＣＯの全炭化水素への変換速度＝
全炭化水素生成速度（１０-4ｍｏｌ／ｍｉｎ・ｇ（触
媒））は９．１であった。炭化水素の生成物分布は、Ｃ
1〜Ｃ4炭化水素３１．６wt％、Ｃ5〜Ｃ11 炭化水素４
３．４wt％、Ｃ12以上の重質脂肪族炭化水素２５．０wt
％であった。0.2 g of the catalyst thus obtained was filled in a reaction tube (made of SUS304), which was placed in a hydrogen stream,
It processed at 400 degreeC for 3 hours. Next, a mixed gas of hydrogen and carbon monoxide (H 2 /CO=1.0) was added to this with a flow rate of 100N.
Contact was performed under the conditions of ml / min, pressure of 30 atm, and temperature of 275 ° C. As a result, the conversion rate of CO to total hydrocarbons =
The total hydrocarbon generation rate (10 −4 mol / min · g (catalyst)) was 9.1. The product distribution of hydrocarbons is C
1 to C 4 hydrocarbons 31.6 wt%, C 5 to C 11 hydrocarbons 4
3.4 wt%, C 12 or higher heavy aliphatic hydrocarbon 25.0 wt
%Met.
【００１１】比較例１ バナジウムを添加せずに、実施例１と同様にしてルテニ
ウムと酸化チタンを含有する触媒を調製した。Comparative Example 1 A catalyst containing ruthenium and titanium oxide was prepared in the same manner as in Example 1 without adding vanadium.
【００１２】次いで、触媒０．２ｇを用いて実施例１と
同様に反応実験を行った。その結果、全炭化水素生成速
度（１０-4ｍｏｌ／ｍｉｎ・ｇ（触媒））は６．８であ
った。炭化水素の生成物分布は、Ｃ1〜Ｃ4炭化水素３
８．６wt％、Ｃ5〜Ｃ11 炭化水素４５．５wt％、Ｃ12以
上の重質脂肪族炭化水素１５．９wt％であった。Then, a reaction experiment was conducted in the same manner as in Example 1 using 0.2 g of the catalyst. As a result, the total hydrocarbon generation rate (10 −4 mol / min · g (catalyst)) was 6.8. The hydrocarbon product distribution is C 1 -C 4 hydrocarbon 3
The amounts were 8.6 wt%, C 5 to C 11 hydrocarbons 45.5 wt%, and C 12 or more heavy aliphatic hydrocarbons 15.9 wt%.
【００１３】比較例２ 酸化チタンに代えて酸化アルミニウム（ＪＲＣ−ＡＬＯ
４）を用いて実施例１と同様に調製したルテニウム及び
バナジウム及び酸化アルミニウムを含有する触媒を調製
した。Comparative Example 2 Instead of titanium oxide, aluminum oxide (JRC-ALO
4) was used to prepare a catalyst containing ruthenium and vanadium and aluminum oxide prepared in the same manner as in Example 1.
【００１４】次いで、触媒０．２ｇを用いて実施例１と
同様に反応実験を行った。その結果、全炭化水素生成速
度（１０-4ｍｏｌ／ｍｉｎ・ｇ（触媒））は３．０であ
った。炭化水素の生成物分布は、Ｃ1〜Ｃ4炭化水素３
０．６wt％、Ｃ5〜Ｃ11 炭化水素４２．３wt％、Ｃ12以
上の重質脂肪族炭化水素２７．１wt％であった。Then, a reaction experiment was conducted in the same manner as in Example 1 using 0.2 g of the catalyst. As a result, the total hydrocarbon generation rate (10 −4 mol / min · g (catalyst)) was 3.0. The hydrocarbon product distribution is C 1 -C 4 hydrocarbon 3
The content was 0.6 wt%, C 5 to C 11 hydrocarbons 42.3 wt%, and C 12 or more heavy aliphatic hydrocarbons 27.1 wt%.
【００１５】実施例２ 塩化ルテニウム１．８１ｇを水約１７０ｍｌに溶解させ
た。酸化チタン（日本アエロジル製Ｐ−２５）１４．２
５ｇに上記の塩化ルテニウム水溶液を加えてよくかきま
ぜながら含浸させた。これを、常温下で減圧乾燥させた
後、水素気流中、４００℃で５時間処理した。水素処理
して得られた物に、メタバナジン酸アンモニウム０．６
９ｇを水約３５０ｍｌに溶解させたものを添加した。こ
れを、常温下で減圧乾燥させて触媒を得た。得られた触
媒の組成は、Ｒｕ５wt％、Ｖ／Ｒｕ比０．８、ＴｉＯ2
残余であった。Example 2 1.81 g of ruthenium chloride was dissolved in about 170 ml of water. Titanium oxide (P-25 made by Nippon Aerosil) 14.2
The above ruthenium chloride aqueous solution was added to 5 g to thoroughly impregnate it with stirring. This was dried under reduced pressure at room temperature and then treated at 400 ° C. for 5 hours in a hydrogen stream. Ammonium metavanadate 0.6
What dissolved 9g in about 350 ml of water was added. This was dried under reduced pressure at room temperature to obtain a catalyst. The composition of the obtained catalyst was Ru 5 wt%, V / Ru ratio of 0.8, TiO 2
It was the rest.
【００１６】このようにして得られた触媒０．２ｇを反
応管（ＳＵＳ３０４製）に充填し、これを水素気流中、
４００℃で３時間処理した。次に、これに水素と一酸化
炭素の混合ガス（Ｈ2 ／ＣＯ＝１．０）を流量１００Ｎ
ｍｌ／ｍｉｎ、圧力５０気圧、温度２２０℃の条件で接
触させた。その結果、全炭化水素生成速度（１０-4ｍｏ
ｌ／ｍｉｎ・ｇ（触媒））は４．０であった。炭化水素
の生成物分布は、Ｃ1〜Ｃ4炭化水素５．１wt％、Ｃ5〜
Ｃ11 炭化水素１３．５wt％、Ｃ12以上の重質脂肪族炭
化水素８１．４wt％であった。0.2 g of the catalyst thus obtained was filled in a reaction tube (made of SUS304), and this was placed in a hydrogen stream.
It processed at 400 degreeC for 3 hours. Next, a mixed gas of hydrogen and carbon monoxide (H 2 /CO=1.0) was added to this with a flow rate of 100N.
The contact was performed under the conditions of ml / min, pressure of 50 atm, and temperature of 220 ° C. As a result, the total hydrocarbon production rate (10 -4 mo
The l / min · g (catalyst) was 4.0. The product distribution of hydrocarbons is C 1 to C 4 hydrocarbons 5.1 wt%, C 5 to
The C 11 hydrocarbon was 13.5 wt% and the C 12 or more heavy aliphatic hydrocarbon was 81.4 wt%.
【００１７】実施例３ 実施例２で用いた触媒と同じ触媒１．０ｇを反応管（Ｓ
ＵＳ３０４製）に充填し、これを水素気流中、４００℃
で３時間処理した。次に、これに水素と一酸化炭素の混
合ガス（Ｈ2 ／ＣＯ＝２．１）を流量１００Ｎｍｌ／ｍ
ｉｎ、圧力５０気圧、温度１８０℃の条件で接触させ
た。その結果、全炭化水素生成速度（１０-4ｍｏｌ／ｍ
ｉｎ・ｇ（触媒））は３．２であった。炭化水素の生成
物分布は、Ｃ1〜Ｃ4炭化水素４．３wt％、Ｃ5〜Ｃ11 炭
化水素１０．２wt％、Ｃ12以上の重質脂肪族系炭化水素
８５．５wt％であった。Example 3 1.0 g of the same catalyst as used in Example 2 was added to a reaction tube (S
(Made of US304), and filled with this in a hydrogen stream at 400 ° C.
Treated for 3 hours. Next, a mixed gas of hydrogen and carbon monoxide (H 2 /CO=2.1) was added thereto at a flow rate of 100 Nml / m 2.
The contact was performed under the conditions of in, pressure of 50 atm, and temperature of 180 ° C. As a result, the total hydrocarbon production rate (10 -4 mol / m 2
The in.g (catalyst) was 3.2. The distribution of hydrocarbon products was C 1 to C 4 hydrocarbons 4.3 wt%, C 5 to C 11 hydrocarbons 10.2 wt%, and C 12 or more heavy aliphatic hydrocarbons 85.5 wt%. .
【００１８】[0018]
【発明の効果】以上説明したように、本発明の触媒を使
用すれば、一酸化炭素と水素との混合ガスから重質脂肪
族炭化水素を高い生成速度及び高い選択率で製造するこ
とができる。As described above, when the catalyst of the present invention is used, a heavy aliphatic hydrocarbon can be produced from a mixed gas of carbon monoxide and hydrogen with a high production rate and a high selectivity. .
───────────────────────────────────────────────────── フロントページの続き (51)Int.Cl.5 識別記号 庁内整理番号 ＦＩ 技術表示箇所 // Ｃ０７Ｂ 61/00 ３００ ─────────────────────────────────────────────────── ─── Continuation of front page (51) Int.Cl. 5 Identification code Internal reference number FI technical display location // C07B 61/00 300
Claims (2)
ンを含有することを特徴とする水素と一酸化炭素からの
重質脂肪族炭化水素製造用触媒。1. A catalyst for producing a heavy aliphatic hydrocarbon from hydrogen and carbon monoxide, which comprises ruthenium, vanadium and titanium oxide.
し、バナジウムをルテニウムに対して０．１〜２．０
（原子比）含有していることを特徴とする請求項１の重
質脂肪族炭化水素製造用触媒。2. A ruthenium content of 0.1 to 10 wt% and vanadium content of 0.1 to 2.0 with respect to ruthenium.
The catalyst for producing heavy aliphatic hydrocarbons according to claim 1, wherein the catalyst contains (atomic ratio).
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP3053271A JPH0687975B2 (en) | 1991-02-26 | 1991-02-26 | Catalyst for the production of heavy aliphatic hydrocarbons |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP3053271A JPH0687975B2 (en) | 1991-02-26 | 1991-02-26 | Catalyst for the production of heavy aliphatic hydrocarbons |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPH04271837A JPH04271837A (en) | 1992-09-28 |
| JPH0687975B2 true JPH0687975B2 (en) | 1994-11-09 |
Family
ID=12938082
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP3053271A Expired - Lifetime JPH0687975B2 (en) | 1991-02-26 | 1991-02-26 | Catalyst for the production of heavy aliphatic hydrocarbons |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH0687975B2 (en) |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP5483045B2 (en) * | 2008-06-20 | 2014-05-07 | 独立行政法人産業技術総合研究所 | Process for producing hydrocarbons from carbon monoxide and hydrogen |
-
1991
- 1991-02-26 JP JP3053271A patent/JPH0687975B2/en not_active Expired - Lifetime
Also Published As
| Publication number | Publication date |
|---|---|
| JPH04271837A (en) | 1992-09-28 |
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