JPH0694412B2 - Insect repellent film - Google Patents
Insect repellent filmInfo
- Publication number
- JPH0694412B2 JPH0694412B2 JP23117692A JP23117692A JPH0694412B2 JP H0694412 B2 JPH0694412 B2 JP H0694412B2 JP 23117692 A JP23117692 A JP 23117692A JP 23117692 A JP23117692 A JP 23117692A JP H0694412 B2 JPH0694412 B2 JP H0694412B2
- Authority
- JP
- Japan
- Prior art keywords
- insect repellent
- test
- repellent film
- mites
- film
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 239000000077 insect repellent Substances 0.000 title claims description 11
- 239000000126 substance Substances 0.000 claims description 23
- 241000238876 Acari Species 0.000 description 13
- 238000000034 method Methods 0.000 description 9
- 230000000694 effects Effects 0.000 description 6
- 239000002245 particle Substances 0.000 description 6
- 239000011734 sodium Substances 0.000 description 6
- 239000000843 powder Substances 0.000 description 5
- 229910004298 SiO 2 Inorganic materials 0.000 description 4
- 238000004090 dissolution Methods 0.000 description 4
- 238000010998 test method Methods 0.000 description 4
- 241000699666 Mus <mouse, genus> Species 0.000 description 3
- 241000699670 Mus sp. Species 0.000 description 3
- 150000001639 boron compounds Chemical class 0.000 description 3
- 239000004033 plastic Substances 0.000 description 3
- 229920003023 plastic Polymers 0.000 description 3
- 229910052708 sodium Inorganic materials 0.000 description 3
- 231100000419 toxicity Toxicity 0.000 description 3
- 230000001988 toxicity Effects 0.000 description 3
- 241001465754 Metazoa Species 0.000 description 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 2
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical class [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 2
- KGBXLFKZBHKPEV-UHFFFAOYSA-N boric acid Chemical compound OB(O)O KGBXLFKZBHKPEV-UHFFFAOYSA-N 0.000 description 2
- 235000010338 boric acid Nutrition 0.000 description 2
- 229960002645 boric acid Drugs 0.000 description 2
- 230000000857 drug effect Effects 0.000 description 2
- 230000036541 health Effects 0.000 description 2
- 230000000749 insecticidal effect Effects 0.000 description 2
- 229920001684 low density polyethylene Polymers 0.000 description 2
- 239000004702 low-density polyethylene Substances 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 239000002994 raw material Substances 0.000 description 2
- 231100000820 toxicity test Toxicity 0.000 description 2
- 229910018072 Al 2 O 3 Inorganic materials 0.000 description 1
- KXDHJXZQYSOELW-UHFFFAOYSA-M Carbamate Chemical compound NC([O-])=O KXDHJXZQYSOELW-UHFFFAOYSA-M 0.000 description 1
- 241000238713 Dermatophagoides farinae Species 0.000 description 1
- 241000238631 Hexapoda Species 0.000 description 1
- 241000124008 Mammalia Species 0.000 description 1
- 230000005856 abnormality Effects 0.000 description 1
- 230000000895 acaricidal effect Effects 0.000 description 1
- 229920005822 acrylic binder Polymers 0.000 description 1
- 231100000215 acute (single dose) toxicity testing Toxicity 0.000 description 1
- 238000011047 acute toxicity test Methods 0.000 description 1
- 229910052784 alkaline earth metal Inorganic materials 0.000 description 1
- 150000001342 alkaline earth metals Chemical class 0.000 description 1
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 1
- 229910021538 borax Inorganic materials 0.000 description 1
- 239000004327 boric acid Substances 0.000 description 1
- 229910052796 boron Inorganic materials 0.000 description 1
- 238000009395 breeding Methods 0.000 description 1
- 230000001488 breeding effect Effects 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- FHIVAFMUCKRCQO-UHFFFAOYSA-N diazinon Chemical compound CCOP(=S)(OCC)OC1=CC(C)=NC(C(C)C)=N1 FHIVAFMUCKRCQO-UHFFFAOYSA-N 0.000 description 1
- 239000012153 distilled water Substances 0.000 description 1
- 239000003814 drug Substances 0.000 description 1
- 229940079593 drug Drugs 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 238000010828 elution Methods 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 238000000227 grinding Methods 0.000 description 1
- 238000004898 kneading Methods 0.000 description 1
- 230000007721 medicinal effect Effects 0.000 description 1
- 231100000956 nontoxicity Toxicity 0.000 description 1
- 230000005180 public health Effects 0.000 description 1
- 238000010298 pulverizing process Methods 0.000 description 1
- 239000002728 pyrethroid Substances 0.000 description 1
- 238000012797 qualification Methods 0.000 description 1
- 235000010339 sodium tetraborate Nutrition 0.000 description 1
- 239000000725 suspension Substances 0.000 description 1
- LEZAYTDLNNEFJT-UHFFFAOYSA-N tetracosasodium octaborate tetrahydrate Chemical compound O.O.O.O.[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[O-]B([O-])[O-].[O-]B([O-])[O-].[O-]B([O-])[O-].[O-]B([O-])[O-].[O-]B([O-])[O-].[O-]B([O-])[O-].[O-]B([O-])[O-].[O-]B([O-])[O-] LEZAYTDLNNEFJT-UHFFFAOYSA-N 0.000 description 1
- 231100000331 toxic Toxicity 0.000 description 1
- 230000002588 toxic effect Effects 0.000 description 1
- 231100000048 toxicity data Toxicity 0.000 description 1
- BSVBQGMMJUBVOD-UHFFFAOYSA-N trisodium borate Chemical compound [Na+].[Na+].[Na+].[O-]B([O-])[O-] BSVBQGMMJUBVOD-UHFFFAOYSA-N 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Landscapes
- Agricultural Chemicals And Associated Chemicals (AREA)
- Chemical Or Physical Treatment Of Fibers (AREA)
- Carpets (AREA)
Description
【０００１】[0001]
【産業上の利用分野】本発明はB2O3を含有する硝子質物
質を利用した、ダニ等に対する防虫効果に優れた防虫フ
ィルムに関するものである。BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to an insect repellent film using a vitreous substance containing B 2 O 3 and having an excellent insect repellent effect against mites and the like.
【０００２】[0002]
【従来の技術】従来、ダニの駆除のためには、有機リン
酸、ピレスロイド系物質、カーバメイト系物質、ダイア
ジノン系物質等の有機物質や、オルト硼酸、硼酸ソー
ダ、８硼酸ナトリウム４水和物等の無機系の硼素化合物
が使用されている。またこれらの物質をシート中に含有
させることも、例えば特開昭63-130509 号公報等によっ
て知られている。ところが、上記したような防ダニ効果
のある有機物質は毒性が強いため、大量に使用すると人
体に対する影響が懸念される。一方、無機系の硼素化合
物は毒性の問題はないが、水溶性であるために短期間で
薬効が失われるという問題があった。2. Description of the Related Art Conventionally, for the control of mites, organic substances such as organic phosphoric acid, pyrethroid type substances, carbamate type substances, diazinon type substances, orthoboric acid, sodium borate, sodium octaborate tetrahydrate, etc. Inorganic boron compounds are used. It is also known to incorporate these substances into a sheet, for example, as disclosed in JP-A-63-130509. However, since the above-mentioned organic substance having a tick-proofing effect is highly toxic, there is a concern that it may affect the human body when used in a large amount. On the other hand, the inorganic boron compound has no problem of toxicity, but has a problem that the drug effect is lost in a short period of time because it is water-soluble.
【０００３】[0003]
【発明が解決しようとする課題】本発明は上記した従来
の問題点を解決して、毒性がほとんどなく、しかも長期
間にわたり薬効を維持することができる防虫フィルムを
提供するために完成されたものである。The present invention has been completed to solve the above-mentioned conventional problems and to provide an insect-repellent film having little toxicity and capable of maintaining a medicinal effect for a long period of time. Is.
【０００４】[0004]
【課題を解決するための手段】上記の課題を解決するた
めになされた本発明は、B2O3を20℃、１時間の条件で１
mg/g〜300 mg/g の速度で溶出する硝子質物質を含有さ
せたことを特徴とする防虫フィルムを要旨とするもので
ある。The present invention, which has been made to solve the above-mentioned problems, provides a method in which B 2 O 3 is added at a temperature of 20 ° C. for 1 hour.
The gist is an insect-repellent film characterized by containing a vitreous substance which is eluted at a rate of mg / g to 300 mg / g.
【０００５】上記のように、本発明ではB2O3を溶出する
ことができる硝子質物質が使用される。このような機能
を持つ硝子としては、B2O3−SiO2−Na2O系、B2O3−Na2O
−RO系、B2O3−Na2O−Al2O3 系のものがある。ここでRO
はCaO 、MgO のようなアルカリ土類金属の酸化物を意味
する。これらの硝子質物質はダニが繁殖し易い高温多湿
の条件下でダニの駆除に有効なB2O3を溶出するが、ダニ
の繁殖に適しない低温乾燥の条件下ではB2O3をあまり溶
出させないため、ダニの駆除にきわめて適したものであ
る。As described above, the present invention uses a vitreous substance capable of eluting B 2 O 3 . As a glass having such a function, B 2 O 3 --SiO 2 --Na 2 O system, B 2 O 3 --Na 2 O system
-RO based, there is a B 2 O 3 -Na 2 O- Al 2 O 3 system. Where RO
Means an oxide of an alkaline earth metal such as CaO or MgO. These vitreous substances elute B 2 O 3 which is effective in controlling mites under high temperature and high humidity conditions where mites easily proliferate, but B 2 O 3 is not so much produced under low temperature drying conditions that are not suitable for mites breeding. Since it does not elute, it is extremely suitable for controlling ticks.
【０００６】B2O3の溶出速度は、20℃の蒸留水中に粒径
を例えば420 〜600 μm とした硝子質物質を１時間浸漬
し、硝子質物質１ｇ当りのB2O3重量として算出される。
ただし本発明においては粒径はこれに限定されるもので
はない。本発明においてB2O3の溶出速度を１mg/g〜300
mg/gとしたのは、溶出速度がこれより低いと防虫効果が
なく、逆にこれより高くても防虫効果に変化がなくて無
駄となり、しかも短期間に溶出が完了してしまうからで
ある。[0006] dissolution rate of B 2 O 3 is a vitreous material and a particle size in distilled water at 20 ° C. for example 420 to 600 [mu] m was immersed for 1 hour, calculated as B 2 O 3 by weight per vitreous material 1g To be done.
However, in the present invention, the particle size is not limited to this. In the present invention, the dissolution rate of B 2 O 3 is 1 mg / g to 300
The reason why the mg / g is set is that if the dissolution rate is lower than this, there is no insect repellent effect, and conversely, if it is higher than this, there is no change in the insect repellent effect, which is wasted, and the dissolution is completed in a short period of time. .
【０００７】上記の硝子質物質をフィルム中に含有させ
るには種々の方法が考えられるが、硝子質物質を微粉末
として例えばアクリル系バインダーと混合し、ロールコ
ート等の方法でフィルム表面に付着させる方法と、硝子
質物質の微粉末をフィルムの原料中に最初から練り込ん
でおき、フィルムを製造する方法が普通である。このよ
うにして得られた本発明の防虫フィルムは、例えば畳等
の下に敷いてダニ等を防ぐ効果がある。Various methods are conceivable for incorporating the above-mentioned vitreous substance into the film, but the vitreous substance is mixed as a fine powder with, for example, an acrylic binder and is attached to the film surface by a method such as roll coating. The method and the method of producing a film by kneading fine powder of a vitreous substance into the raw material of the film from the beginning are common. The insect-repellent film of the present invention thus obtained is laid under a tatami mat or the like, for example, and has an effect of preventing ticks and the like.
【０００８】[0008]
【実施例】以下に本発明を実施例により更に詳細に説明
する。まず本発明で使用する硝子質物質の毒性試験を行
った。その内容は次の通りである。 〔毒性試験〕 試験に使用した物質 (1) B2O3 80モル％、SiO2 10 モル％、Na2O 10 モル
％の硝子質物質を粒径20μm 以下に粉砕した微粉末。 (2) B2O3 45モル％、SiO2 40 モル％、Na2O 15 モル
％の硝子質物質を粒径20μm 以下に粉砕した微粉末。 試験方法 マウス使用の急性毒性試験であり、5000mg/kg を上限と
して、３段階の用量を雌雄マウスに経口単回投与し、マ
ウスの異常を観察する方法で行った。 試験実施場所 財団法人 日本食品分析センター大阪支所 試験結果 (1) ＬＤ50マウス 3250mg/kg (2) ＬＤ50マウス 5000mg/kg 以上 考察 この結果は、H3BO3(硼酸) のＬＤ50マウスが3450mg/kg
（文献値：米国国立労働安全衛生研究所編、化学物質毒
性データー総覧）と比較してほとんど差のない値であ
り、本発明で使用する硝子質物質の哺乳類に対する毒性
は極めて弱いことが確認された。EXAMPLES The present invention will be described in more detail below with reference to examples. First, the toxicity test of the vitreous substance used in the present invention was conducted. The contents are as follows. [Toxicity test] Substances used in the test (1) Fine powder obtained by grinding a glassy substance of 80 mol% B 2 O 3 , 10 mol% SiO 2 and 10 mol% Na 2 O to a particle size of 20 μm or less. (2) Fine powder obtained by pulverizing a glassy substance of B 2 O 3 45 mol%, SiO 2 40 mol% and Na 2 O 15 mol% to a particle size of 20 μm or less. Test method This is an acute toxicity test using mice. It was carried out by a method of observing abnormalities in mice by single oral administration to male and female mice in three steps with an upper limit of 5000 mg / kg. Test location Japanese Food Analysis Center Osaka Branch Test results (1) LD 50 mouse 3250mg / kg (2) LD 50 mouse 5000mg / kg or more Discussion This result shows that LD 50 mouse of H 3 BO 3 (boric acid) is 3450mg /kg
(Reference value: Comprehensive data on toxicity data of chemical substances, edited by National Institute of Occupational Safety and Health, Comprehensive list), it was confirmed that the toxicity of the vitreous substance used in the present invention to mammals is extremely weak. It was
【０００９】〔殺ダニ試験１〕 試験に使用した試料 B2O3 80モル％、SiO2 10 モル％、Na2O 10 モル％の
硝子質物質を各種粒度に粉砕した微粉末（但し粒径を50
0 μとしたときの20℃、１時間の条件下におけるB2O3の
溶出速度は300mg/g ）を表１に示すとおり原料中に練り
込み、フィルムを製造した。なお、試料番号４のフィル
ムは内側のＬＤＰＥ（低密度ポリエチレン）のみに微粉
末を含有させてある。[Acaricidal Test 1] Sample used for the test B 2 O 3 80 mol%, SiO 2 10 mol%, Na 2 O 10 mol% vitreous substance was pulverized into various particle sizes (however, particle size To 50
The B 2 O 3 elution rate under conditions of 20 ° C. and 1 hour at 0 μ was kneaded into the raw material as shown in Table 1 to produce a film. In the film of sample No. 4, fine powder is contained only in the inner LDPE (low density polyethylene).
【００１０】[0010]
【表１】 [Table 1]
【００１１】 試験方法 厚生省指定の医薬部外品認定基準の方法を準用した大阪
府立公衆衛生研究所の試験方法（培地接触方法）で実施
した。即ち、プラスチックシャーレ（面積28cm2 ）の底
面に上記試料を密着するように敷き込み、その表面にコ
ナヒョウダニを含む培地0.025gを一様に拡げた。培地中
の生存ダニ数は予め試験開始直前に0.1gを飽和食塩水浮
遊法により計数しておく。このようにしたプラスチック
シャーレを各処理区毎に飽和食塩水を入れて湿度を75％
に保った食品保存用のプラスチック容器に収納し、温度
25±１℃の恒温器中で飼育した。同様に試料を敷き込ま
ないものを対照区として飼育し、14日後にシャーレ内の
生存ダニ数を全数調査し、対照区の生存ダニ数との比較
により殺虫率を次式により算出した。 殺虫率（％）＝〔（対照区のダニ数−処理区のダニ数）
／対照区のダニ数〕 なお、試験は３連１区にて行った。 試験結果 各試料の殺虫率は、前記の表１に記したとおりである。Test Method The test method was carried out by the test method (medium contact method) of Osaka Prefectural Institute of Public Health, which mutatis mutandis applies the method of Quasi-drug Qualification Standard designated by the Ministry of Health and Welfare. That is, the above sample was laid on the bottom of a plastic petri dish (area: 28 cm 2 ) so as to be in close contact, and 0.025 g of a medium containing Dermatophagoides farinae was uniformly spread on the surface. The number of surviving mites in the medium is previously counted by 0.1 g by the saturated saline suspension method immediately before the start of the test. Put a saturated saline solution into each treated area of the plastic petri dish to keep the humidity at 75%.
Store in a plastic container for food storage kept at
The animals were kept in an incubator at 25 ± 1 ° C. Similarly, the animals without the sample spread were bred as a control group, and after 14 days, the total number of living mites in the petri dish was investigated, and the insecticidal rate was calculated by the following formula by comparison with the number of living mites in the control group. Insect killing rate (%) = [(number of mites in control plot-number of mites in treatment plot))
/ Number of mites in control group] The test was carried out in three groups and one group. Test Results The insecticidal rate of each sample is as described in Table 1 above.
【００１２】[0012]
【発明の効果】以上に説明したように、本発明の防虫フ
ィルムはB2O3を20℃、１時間の条件で１mg/g〜300 mg/g
の速度で溶出する硝子質物質をフィルム中に含有させ
ることにより、優れた防虫効果を発揮させることができ
たものである。しかも従来の有機物質を使用したものに
比較して毒性がほとんどなく、また従来の無機系の硼素
化合物を使用したものに比較してしかも長期間にわたり
薬効を維持することができる利点がある。As described above, the insect repellent film of the present invention contains B 2 O 3 at 1 mg / g to 300 mg / g at 20 ° C. for 1 hour.
It was possible to exhibit an excellent insect repellent effect by incorporating a vitreous substance which is eluted at a rate of 1. into the film. Moreover, it has almost no toxicity as compared with the one using the conventional organic substance, and has an advantage that the drug effect can be maintained for a long period of time as compared with the one using the conventional inorganic boron compound.
Claims (1)
0 mg/g の速度で溶出する硝子質物質を含有させたこと
を特徴とする防虫フィルム。1. B 2 O 3 is 1 mg / g to 30 at 20 ° C. for 1 hour.
An insect-repellent film containing a vitreous substance which is eluted at a rate of 0 mg / g.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2-40030 | 1990-02-21 | ||
| JP4003090 | 1990-02-21 |
Related Parent Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2187574A Division JPH0645522B2 (en) | 1990-02-21 | 1990-07-16 | Composition having insect repellent effect |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPH05246811A JPH05246811A (en) | 1993-09-24 |
| JPH0694412B2 true JPH0694412B2 (en) | 1994-11-24 |
Family
ID=12569511
Family Applications (4)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP23117792A Expired - Fee Related JPH0694413B2 (en) | 1990-02-21 | 1992-08-31 | Insect paper |
| JP23117492A Expired - Fee Related JPH0694410B2 (en) | 1990-02-21 | 1992-08-31 | Insect repellent carpet |
| JP23117592A Expired - Fee Related JPH0694411B2 (en) | 1990-02-21 | 1992-08-31 | Insect repellent fiber |
| JP23117692A Expired - Fee Related JPH0694412B2 (en) | 1990-02-21 | 1992-08-31 | Insect repellent film |
Family Applications Before (3)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP23117792A Expired - Fee Related JPH0694413B2 (en) | 1990-02-21 | 1992-08-31 | Insect paper |
| JP23117492A Expired - Fee Related JPH0694410B2 (en) | 1990-02-21 | 1992-08-31 | Insect repellent carpet |
| JP23117592A Expired - Fee Related JPH0694411B2 (en) | 1990-02-21 | 1992-08-31 | Insect repellent fiber |
Country Status (1)
| Country | Link |
|---|---|
| JP (4) | JPH0694413B2 (en) |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2005029451A (en) * | 2003-07-11 | 2005-02-03 | Ishizuka Glass Co Ltd | Antibacterial and mite-proofing glass composition, and antibacterial / anti-mite resin composition and antibacterial / tick-proof fiber composition using the same |
| JP2017529892A (en) * | 2014-08-08 | 2017-10-12 | インヴィスタ テクノロジーズ エスアエルエルＩＮＶＩＳＴＡ ＴＥＣＨＮＯＬＯＧＩＥＳ Ｓ．ａ．ｒ．ｌ． | Carpet surface treatment composition and application method |
-
1992
- 1992-08-31 JP JP23117792A patent/JPH0694413B2/en not_active Expired - Fee Related
- 1992-08-31 JP JP23117492A patent/JPH0694410B2/en not_active Expired - Fee Related
- 1992-08-31 JP JP23117592A patent/JPH0694411B2/en not_active Expired - Fee Related
- 1992-08-31 JP JP23117692A patent/JPH0694412B2/en not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| JPH0694413B2 (en) | 1994-11-24 |
| JPH05246812A (en) | 1993-09-24 |
| JPH05246811A (en) | 1993-09-24 |
| JPH0694410B2 (en) | 1994-11-24 |
| JPH05271023A (en) | 1993-10-19 |
| JPH05262613A (en) | 1993-10-12 |
| JPH0694411B2 (en) | 1994-11-24 |
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