JPH0710736B2 - Taphole for mineral wool fiber manufacturing equipment. - Google Patents
Taphole for mineral wool fiber manufacturing equipment.Info
- Publication number
- JPH0710736B2 JPH0710736B2 JP57-503346A JP50334682A JPH0710736B2 JP H0710736 B2 JPH0710736 B2 JP H0710736B2 JP 50334682 A JP50334682 A JP 50334682A JP H0710736 B2 JPH0710736 B2 JP H0710736B2
- Authority
- JP
- Japan
- Prior art keywords
- hole
- passage
- orifice
- metal member
- tap outlet
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03B—MANUFACTURE, SHAPING, OR SUPPLEMENTARY PROCESSES
- C03B37/00—Manufacture or treatment of flakes, fibres, or filaments from softened glass, minerals, or slags
- C03B37/01—Manufacture of glass fibres or filaments
- C03B37/04—Manufacture of glass fibres or filaments by using centrifugal force, e.g. spinning through radial orifices; Construction of the spinner cups therefor
- C03B37/05—Manufacture of glass fibres or filaments by using centrifugal force, e.g. spinning through radial orifices; Construction of the spinner cups therefor by projecting molten glass on a rotating body having no radial orifices
- C03B37/055—Manufacture of glass fibres or filaments by using centrifugal force, e.g. spinning through radial orifices; Construction of the spinner cups therefor by projecting molten glass on a rotating body having no radial orifices by projecting onto and spinning off the outer surface of the rotating body
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03B—MANUFACTURE, SHAPING, OR SUPPLEMENTARY PROCESSES
- C03B5/00—Melting in furnaces; Furnaces so far as specially adapted for glass manufacture
- C03B5/16—Special features of the melting process; Auxiliary means specially adapted for glass-melting furnaces
- C03B5/26—Outlets, e.g. drains, siphons; Overflows, e.g. for supplying the float tank, tweels
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03B—MANUFACTURE, SHAPING, OR SUPPLEMENTARY PROCESSES
- C03B5/00—Melting in furnaces; Furnaces so far as specially adapted for glass manufacture
- C03B5/16—Special features of the melting process; Auxiliary means specially adapted for glass-melting furnaces
- C03B5/42—Details of construction of furnace walls, e.g. to prevent corrosion; Use of materials for furnace walls
- C03B5/44—Cooling arrangements for furnace walls
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03B—MANUFACTURE, SHAPING, OR SUPPLEMENTARY PROCESSES
- C03B7/00—Distributors for the molten glass; Means for taking-off charges of molten glass; Producing the gob, e.g. controlling the gob shape, weight or delivery tact
- C03B7/14—Transferring molten glass or gobs to glass blowing or pressing machines
- C03B7/16—Transferring molten glass or gobs to glass blowing or pressing machines using deflector chutes
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- General Life Sciences & Earth Sciences (AREA)
- Geochemistry & Mineralogy (AREA)
- Manufacturing & Machinery (AREA)
- Life Sciences & Earth Sciences (AREA)
- Furnace Housings, Linings, Walls, And Ceilings (AREA)
- Manufacture And Refinement Of Metals (AREA)
- Manufacture, Treatment Of Glass Fibers (AREA)
- Devices That Are Associated With Refrigeration Equipment (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
- Spinning Methods And Devices For Manufacturing Artificial Fibers (AREA)
- Blast Furnaces (AREA)
- Gasification And Melting Of Waste (AREA)
- Furnace Details (AREA)
Description
【発明の詳細な説明】
(産業上の利用分野)
本発明は熱絶縁用の鉱物ウールファイバを製造すること
に関し、特に、鉱物ウールファイバの製造装置のための
湯出口及び湯出口を有効に冷却する方法に関する。Description: FIELD OF THE INVENTION The present invention relates to the production of mineral wool fibre for thermal insulation, and more particularly to a taphole for a mineral wool fibre production apparatus and a method for effectively cooling the taphole.
(従来の技術)
鉱物ウールファイバ製造に関して。炉からの溶融材料が
湯出口を経てトラスに入り、ファイバ化スピンナの面に
導かれる。湯出口を通って流れる溶融材料の生ずる著し
く高い熱のため、ある場合には湯出口冷却装置を設ける
必要のあることは既知である。このためには、通常は湯
出口を鋼製として水で鋼を冷却する。しかし、この手段
は有効ではなく、冷却された金属の作動面に凝固材料の
殻が予測不可能の可変量で堆積し、このため溶融材料の
排出は不均等になる。PRIOR ART In the manufacture of mineral wool fibers, molten material from a furnace enters a truss through a taphole and is directed to the face of a fiberizing spinner. It is known that due to the significant heat generated by the molten material flowing through the taphole, it is sometimes necessary to provide a taphole cooling system. This is usually accomplished by constructing the taphole out of steel and cooling the steel with water. However, this approach is ineffective, as a crust of solidified material accumulates on the working surface of the cooled metal in unpredictable and variable amounts, resulting in uneven discharge of the molten material.
溶融材料供給用のトラフは多年の間設計者の悩みの種で
あった。耐火物構造は高価で空気中で短命であり、装置
が熱的定常状態に入る前に予測不可能の堆積を生じ、定
常供給が不可能になり、不安定な波状流を生ずる。水冷
金属トラフでも同じ問題が生ずる。この場合トラフを炭
素鋼又はステンレス鋼製として水冷却しなければならな
いから特にそうである。現在まで、トラフ排出端から一
定の均等な材料の流れを得るトラフを製造できなかっ
た。Troughs for molten material delivery have been a source of headache for designers for many years. Refractory construction is expensive, has a short life in air, and can cause unpredictable buildup before the system reaches thermal steady state, making steady delivery impossible and resulting in unstable, undulating flow. The same problems occur with water-cooled metal troughs, especially since the troughs must be water-cooled, typically made of carbon steel or stainless steel. Until now, no trough has been manufactured that provides consistent, even material flow from the trough discharge end.
ファイバ化スピンナの機能は溶融材料の流れに動エネル
ギを与え、これによって高速の空気、スチーム等の蒸気
が溶融材料の急速に動く流れに衝突して材料流を多数の
小直径の長いファイバに変形される。The function of a fiberizing spinner is to impart kinetic energy to a stream of molten material, whereby high velocity air, steam or other vapor impinges on the rapidly moving stream of molten material, causing the stream to be transformed into a multiplicity of small diameter, long fibers.
長いファイバの低密度鉱物ウールは、通常米国では屋根
の断熱に使用され、単輪のスピンナが有効であることが
明らかにされた。空洞壁改装又は工業用管被覆、天井タ
イル等のための高密度ファイバは通常世界中が四輪スピ
ンナを使用する。Long fiber, low density mineral wool is typically used for roof insulation in the United States and has proven effective with single wheel spinners. High density fiber for cavity wall retrofit or industrial pipe jacketing, ceiling tiles, etc. typically uses four wheel spinners worldwide.
この四輪スピンナは4個の平行の駆動スピンドルのそれ
ぞれの端部に水冷ホイールを有し、各ホイールは直径約
250〜350mm(10〜14インチ)、リム幅約100〜130mm(4
〜5インチ)であり、四輪は同一平面に取り付け、頂部
のホイールに滴下した溶融材料は速度を与えられて第2
のホイールに衝突し、順次動く、最下のすなわち第3、
第4のホイールを過ぎたときに高速の空気又はスチーム
が高エネルギ溶融材料を横方向に大きな力で押してファ
イバに分離させる。The four-wheel spinner has four parallel drive spindles with water-cooled wheels at the end of each, each wheel having a diameter of approximately
250-350mm (10-14 inches), rim width approx. 100-130mm (4
The four wheels are mounted on the same plane, and the molten material dripping onto the top wheel is given a velocity to move in the second direction.
The wheels collide with each other and move in sequence, the lowest one being the third,
As it passes the fourth wheel, high velocity air or steam pushes the high energy molten material laterally with great force, separating it into fibers.
この四輪スピンナはこれまで鋼製とされ、通常は水冷で
ある。この結果、ホイールはほぼ1週間の使用で摩耗
し、面仕上げの必要があり著しく費用がかかる。These four-wheel spinners have traditionally been made of steel and are usually water-cooled, resulting in wheels that wear out after about a week of use and require refinishing, which is extremely expensive.
出願人の米国特許第4032705号(この文献を先発明とす
る)に詳述した通り、出願人の発見によれば、大量のエ
ネルギ、IBTU/in2/s程度を急速、連続的に水冷金属壁を
経て除去するには、壁に損傷を生じないために、金属が
優れた熱伝導性と実用上の高い融点とを有し、背面での
スチームの生成と有効な除去とによって一定温度に強制
冷却することを必要とする。As detailed in Applicant's U.S. Pat. No. 4,032,705 (which reference is hereby cited as prior invention), Applicant has discovered that rapid, continuous removal of large amounts of energy, on the order of IBTU/ in2 /s, through a water-cooled metal wall requires that the metal have good thermal conductivity and a practically high melting point to avoid damage to the wall, and that forced cooling to a constant temperature is achieved by the generation and effective removal of steam at the backside.
水1ポンド(0.454kg)をスチームとするには、212°F
で967BTU(100℃でグラム当たり536カロリー)を必要と
する。冷却すべき部分に水を連続的に供給してスチーム
とし、次に直ちにスチームを除去して水を到達可能とす
れば、著しく効率の良い予測可能の冷却装置が得られ
る。冷却すべき部分は付加物がなく、有効な熱伝達に悪
影響のあるフィルム効果を生じないようにする必要があ
る。To steam 1 pound (0.454 kg) of water, you need 212°F.
967 BTU (536 calories per gram at 100°C). By continuously supplying water to the area to be cooled, turning it into steam, and then immediately removing the steam to make the water accessible, a significantly more efficient and predictable cooling system is obtained. The area to be cooled must be free of additives that would create film effects that would adversely affect effective heat transfer.
実験上、スチームのフィルムを生成直後に除去するに
は、金属壁背面に超高速冷却水を作用させるのが最良の
方法である。所要冷却水流速は少なくとも3.05m/s(10f
t/s)であり、この速度は金属面で生ずる必要があり、
金属壁を一方の壁面とする冷却通路の中央での速度では
ない。好適な水冷速度は少なくとも6.1m/s(20ft/s)で
ある。直ちに明らかである通り、この速度は狭い通路を
通る大流量を必要とし、これによって、冷却すべき部分
の面、形状、長さに応じて圧力低下約1.4〜4.2kg/cm
2(約20〜60psi)を生じる。Experiments have shown that the best way to remove the steam film immediately after it is formed is to apply a very high velocity of cooling water to the back of the metal wall. The required cooling water velocity is at least 3.05 m/s (10 f
t/s), and this velocity must occur on a metal surface.
This is not the velocity in the center of a cooling passage with one wall facing the metal. A preferred water cooling velocity is at least 20 ft/s (6.1 m/s). As is readily apparent, this velocity requires a high flow rate through the narrow passages, which results in a pressure drop of approximately 1.4 to 4.2 kg/cm, depending on the surface, shape, and length of the part to be cooled.
2 (approximately 20 to 60 psi).
この冷却の有効性を強調するために、使用可能な価格、
融点、高熱伝導率の加工可能金属を必要とする。素子の
物理的特性の表から、加工容易で、比較的安価であり、
融点が約1000℃であり、良好な熱伝導率の材料を次の表
に記す。To highlight the effectiveness of this cooling, the available price,
A processable metal with a high melting point and high thermal conductivity is required. From the physical properties of the device, it is easy to process, relatively inexpensive, and
The following table lists materials with melting points of approximately 1000°C and good thermal conductivity.
クロム、モリブデン、ニッケルは実際上加工容易でな
く、比較的高価である。さらに、この材料は熱伝導率が
銅の3分の1から5分の1である。 Chromium, molybdenum, and nickel are not very easy to process and are relatively expensive. Furthermore, the thermal conductivity of these materials is three to five times lower than that of copper.
銅は比較的低融点であり、鉄は高融点であるため、水冷
湯出口、トラフ、スピンナとして過去においては自動的
に鋼を選択したがこれは全く妥当でない。鉄は銅に比較
して熱伝導率は1/5以下であるにもかかわらずそれが実
情であった。更に、多くの理由によって、水冷の鋼は表
面に高絶縁性のフィルムを形成する傾向がある。The relatively low melting point of copper and the high melting point of iron have made steel the automatic choice in the past for water-cooled tapholes, troughs, and spinners, but this is completely unreasonable. This was despite the fact that iron has less than one-fifth the thermal conductivity of copper. Furthermore, for a number of reasons, water-cooled steel tends to form a highly insulating film on its surface.
この技術的な欠点を増すのは、出願人の知る限りでは、
湯出口オリフィス、トラフ、又はスピンナの背面から熱
エネルギを有効に除去する試みとして、スチームを清潔
な面に生成させ、超高速で動く新しい冷却水によってス
チームを直接除去することが行われなかったからであ
る。指摘すべきこととして、ステンレス鋼の使用は事態
を悪化させるだけである。この理由は、ステンレス鋼の
熱伝導率は銅の1/16〜1/24であるからである。Compounding this technical drawback, to the applicant's knowledge,
No attempt has been made to effectively remove heat energy from the tap orifice, trough, or back of the spinner by generating steam on a clean surface and removing it directly with new cooling water moving at very high speeds. It should be noted that the use of stainless steel only makes matters worse, since its thermal conductivity is 1/16 to 1/24 that of copper.
(発明が解決しよとする課題)
本発明は、予測可能な一定の厚さの固体物質すなわち殻
が作動面上に凝固可能とするようにして上記既知の問題
点を解決することである。SUMMARY OF THE INVENTION The present invention overcomes the known problems described above by allowing a solid material or shell of predictable and consistent thickness to solidify on a working surface.
(課題を解決するための手段)
本発明においては、鉱物ウールファイバ製造装置におい
て使用する溶融炉からの溶融材料の湯出口を、炉からの
溶融材料を通るオリフィスを形成する内側作動面を備え
た金属部材から構成し、前記オリフィスの周囲に、前記
内側作動面に近接して設けられた冷却液を流すための極
めて狭い通路を形成することによって上記問題点を解決
している。(Means for solving the problem) In the present invention, the above problem is solved by constructing a tap outlet for molten material from a melting furnace used in a mineral wool fiber manufacturing apparatus from a metal member having an inner working surface which forms an orifice through which molten material from the furnace passes, and by forming an extremely narrow passage for flowing coolant around the orifice, which is located close to the inner working surface.
更に、本発明においては、このような湯出口において、
溶融材料を通すオリフィスを形成する面に近接して冷却
液を少なくとも約3.05m/s(10ft/s)の速度で流すこと
によって湯出口を冷却することによって上記問題点を解
決している。Furthermore, in the present invention, at such a tap outlet,
This problem is solved by cooling the taphole by flowing a coolant at a velocity of at least about 3.05 m/s (10 ft/s) adjacent to the surface forming the orifice through which the molten material passes.
(実施例)
第1図は、本発明の原理に従って構成した超高速水冷銅
製湯出口の縦断面図を10として示している。湯出口10の
前端即ち図の左側は既知のグラファイトノズル12に固着
する。ノズル12は本発明の一部を形成せず、仮想線とし
て示し、本発明の外側を示すだけである。ノズル12は当
業界周知の方法で溶解炉のるつぼ壁に取り付ける。1 shows a longitudinal cross-section of an ultra-high velocity, water-cooled copper taphole constructed in accordance with the principles of the present invention, generally designated 10. The front end of taphole 10, i.e., the left side of the drawing, is secured to a known graphite nozzle 12. Nozzle 12 does not form a part of the present invention and is shown in phantom to represent its exterior only. Nozzle 12 is attached to the crucible wall of a melting furnace in a manner well known in the art.
湯出口10は3個の主要部分からなる。即ち、内側銅部材
14と、中間冷却液案内16と外側ジャケット18である。後
に詳述する銅部材前部を除いて、各素子14、16、18は比
較的薄壁管状であり、好適な例で円筒形即ち円形断面と
する。内側銅部材14、冷却液案内16、ジャケット18は互
いに同軸状とする。The taphole 10 consists of three main parts: an inner copper member;
The elements 14, 16, and 18 are relatively thin-walled tubular, preferably cylindrical or circular in cross section, with the exception of the front copper member 14, the intermediate coolant guide 16, and the outer jacket 18 being coaxial with one another.
銅部材14の内面20は湯出口10の作動面であり、炉からの
溶融物が図の左から右に通る開口を形成する。銅部材14
の壁面の厚さは前端22では増大して小直径の内径部とな
りオリフィス24を形成する。オリフィス24は内側作動面
26を含み銅部材の内側作動面20に連続する。The inner surface 20 of the copper member 14 is the working surface of the taphole 10 and defines the opening through which the molten material from the furnace passes from left to right in the figure.
The wall thickness of the valve increases at the forward end 22 to a small diameter inner portion forming an orifice 24. The orifice 24 is formed by the inner working surface
26 and is continuous with the inner working surface 20 of the copper member.
オリフィスの作動面を有効に冷却するために厚壁部22内
に孔あけして複数の通路28を形成する。各通路を形成す
るには、銅部材14の外部からオリフィス24の作動面26に
向けて孔あけする。第1の孔30から軸線方向にオフセッ
トした位置から第2の孔32をオフセット24の作動面26に
向けて内方に孔あけし、第1の孔30の内方端で交わらせ
る。To effectively cool the working surface of the orifice, a plurality of passages 28 are drilled into the thick wall portion 22. Each passage is formed by drilling from the exterior of the copper member 14 toward the working surface 26 of the orifice 24. A second hole 32 is drilled axially offset from the first hole 30 and inward toward the working surface 26 of the orifice 24, intersecting the inner end of the first hole 30.
それ故、各通路28はほぼV型であり、壁面34はオフセッ
トの作動面26の後方にある。面34は作動面26に比較的近
接しているが隔離されている。通路28を形成する各孔3
0,32は直径約4mm(5/32in)であるため冷却液の狭い通
路を形成する。図には2個の通路28のみを示したが、所
要数の通路とすることができ、好適な例ではオフセット
24の軸線を中心として等間隔に配置する。好適な例で
は、12個の通路を使用する。Thus, each passageway 28 is generally V-shaped, with a wall surface 34 aft of the offset working surface 26. The surface 34 is relatively close to, but spaced from, the working surface 26. Each hole 3 forming a passageway 28
The 0.32 is approximately 4 mm (5/32 in) in diameter, thus forming a narrow passage for the coolant. Although only two passages 28 are shown in the figure, any number of passages may be used, and in the preferred embodiment, offset
The passages are equally spaced about the axis of 24. In the preferred embodiment, 12 passages are used.
上述した通り、冷却液案内16は銅部材14を囲んで同一軸
線に配置する。冷却液案内16の前端は溶接等によって銅
部材14の外面に固着し、固着位置36は開口30、32の間と
する。狭い環状スペース38が内側銅部材14と冷却液案内
16との間に残り、湯出口10のほぼ全長に延長する。スペ
ース38は狭い絞り通路の一部を形成し、孔32を経て通路
28に連通する。As described above, the coolant guide 16 is disposed coaxially around the copper member 14. The front end of the coolant guide 16 is fixed to the outer surface of the copper member 14 by welding or the like, and the fixing position 36 is between the openings 30 and 32. A narrow annular space 38 is formed between the inner copper member 14 and the coolant guide
16 and extends for nearly the entire length of the taphole 10. The space 38 forms part of a narrow, restricted passageway, and the passageway passes through the hole 32.
It is connected to 28.
冷却液案内16と外側ジャケット18との間にも環状スペー
ス40が残る。この環状スペースは湯出口10の前端付近の
点から湯出口の排出端付近の点まで延長し、湯出口とは
離間している。湯出口10の前端付近において、ジャケッ
ト18は銅部材14に取付部42で固着する。Oリング44の前
端は孔30を介して通路28に連通する。An annular space 40 also remains between the coolant guide 16 and the outer jacket 18. This annular space extends from a point near the front end of the taphole 10 to a point near the discharge end of the taphole, and is spaced from the taphole. Near the front end of the taphole 10, the jacket 18 is secured to the copper member 14 by a mounting portion 42. The front end of an O-ring 44 communicates with the passage 28 via the hole 30.
冷却液案内16とジャケット18との間の湯出口10の後部の
環状スペース46は、Oリングシール48によって環状スペ
ース40の主成分から隔離され、冷却液案内16の後端の位
置の複数の開口50を経て環状スペース38に連通する。こ
の開口50は冷却液案内16の端部を胸壁状に形成すること
もでき、端部に複数の孔を孔あけすることもできる。入
口ポート52を環状スペース40に連通させ、出口ポート54
を環状スペース46に連通させる。The annular space 46 at the rear of the tap 10 between the coolant guide 16 and the jacket 18 is isolated from the main portion of the annular space 40 by an O-ring seal 48 and communicates with the annular space 38 through a number of openings 50 at the rear end of the coolant guide 16. The openings 50 can be formed by battlementing the end of the coolant guide 16 or by drilling a number of holes in the end. An inlet port 52 communicates with the annular space 40 and an outlet port 54
communicates with the annular space 46.
湯出口10の機能は次の通りである。溶融材料例えば溶融
スラグは炉からノズル12に流れ、オフセット24を通り、
銅部材14の作動スラグ20に沿い、湯出口の排出端から排
出される。溶融材料が湯出口を通って流れる間、大きな
熱が銅部材14に伝達される。水等の所要の冷却液を入口
ポート52に圧入し、環状スペース40を通って開口30を経
て通路28に入る。冷却液は開口32を通って通路28を出て
環状スペース38に流れる。湯出口10の後端では冷却液は
開口50を経て環状スペース46に入り出口ポート54を出
る。通路28、環状スペース38は極めて狭い絞り通路であ
るため、流入冷却液の圧力と組合わされて冷却液は面34
及び銅部材14の外面を超高速、少なくとも3.05m/s(約1
0ft/s)で通り、この面に生じた蒸気を滞留させずに流
し、銅部材を有効に冷却する。The function of the taphole 10 is as follows: molten material, e.g., molten slag, flows from the furnace into the nozzle 12, through the offset 24,
The molten material flows through the taphole, along with the working slug 20 of the copper member 14, and out the discharge end of the taphole. As the molten material flows through the taphole, a significant amount of heat is transferred to the copper member 14. The desired coolant, such as water, is forced into the inlet port 52, passes through the annular space 40, and enters the passages 28 through openings 30. The coolant flows out of the passages 28 through openings 32 and into the annular space 38. At the rear end of the taphole 10, the coolant enters the annular space 46 through openings 50 and exits the outlet port 54. Because the passages 28 and the annular space 38 are very narrow, the coolant, combined with the pressure of the incoming coolant, is forced against the surface 34.
and the outer surface of the copper member 14 is subjected to an ultra-high speed of at least 3.05 m/s (approximately 1
The steam generated on this surface flows without stagnating, effectively cooling the copper parts.
本発明による有効な冷却の結果、予測可能の一定の厚さ
の固体スラグ材料の被覆即ち殻がオリフィス及び湯出口
の作動面26,20上に凝着し、このため溶融材料の排出は
円滑且つ一定である。更に、この殻は熱絶縁性であり、
銅が過大温度となるのを防ぐ。殻は更に銅の作動面の物
理的摩耗を防ぐ。As a result of the effective cooling provided by the present invention, a coating or shell of solid slag material of predictable and consistent thickness is deposited on the orifice and taphole working surfaces 26, 20, resulting in smooth and consistent drainage of molten material. Furthermore, this shell is thermally insulating and
The shell also protects the copper from overheating and prevents physical wear on the copper working surfaces.
(参考例)
第2図は本発明の湯出口と同様の原理に従って構成した
超高速水水冷銅トラフを縦断面図で示し符号110とす
る。トラフ110は湯出口10の下方に位置し、このため、
溶融材料例えば溶融スラグ114は湯出口10から流れ、ト
ラフの上面に沿って案内されてスピンステーション又は
他の所要の位置に流れる。(Reference Example) Fig. 2 shows a vertical cross section of an ultra-high speed water-cooled copper trough, designated by the reference numeral 110, which is constructed according to the same principle as the tap outlet of the present invention. The trough 110 is located below the tap outlet 10, and therefore,
Molten material, such as molten slag 114, flows from the taphole 10 and is guided along the top surface of the trough to the spin station or other desired location.
端壁116以外の全トラフ110はほぼ半円筒形とし、第3図
に明らかに示す。トラフには長いほぼ円筒形の上部銅部
材118を有する。銅部材118の上面作動面120は溶融材料1
14を支持する。相補形の冷却液案内122は銅部材118の下
面124の下に取り付け、両者間を狭い間隔として極めて
狭い通路126を形成する。流通路126はトラフ110のほぼ
全長に亙って延長する。The entire trough 110, except for the end wall 116, is generally semi-cylindrical, as best seen in Figure 3. The trough has an elongated, generally cylindrical upper copper member 118. An upper working surface 120 of the copper member 118 is adapted to receive the molten material 118.
14. A complementary coolant guide 122 is mounted below the lower surface 124 of the copper member 118 and is closely spaced therebetween to form an extremely narrow passage 126. The passage 126 extends substantially the entire length of the trough 110.
冷却液案内122の下方に離間して戻り通路即ちスペース1
28を形成するのは下部ジャケット130である。ジャケッ
ト130の形状は上部銅部材118、冷却液案内122とほぼ同
じである。第3図に明示する通り、部材118、122、130
の側縁は封鎖部132、134によって封鎖する。複数の孔13
6をトラフ110の排出端付近で冷却液案内に形成し、第2
図の右側に示す通り、通路126と戻り通路128との間を連
通させる。Below the coolant guide 122 is a return passage or space 1
28 is formed by a lower jacket 130. The jacket 130 has a shape similar to that of the upper copper member 118 and the coolant guide 122. As shown in FIG.
The side edges of the holes 13 are closed by closing portions 132 and 134.
6 is formed in the coolant guide near the discharge end of the trough 110, and the second
As shown on the right side of the figure, communication is provided between the passage 126 and the return passage 128 .
トラフ110の端壁116には入口ポート138と出口ポート140
とを有する。入口ポート138に連通するチャンネル142は
トラフのほぼ全幅に亙って延長し通路126に連通する。
同様にして、出口ポート140に連通するチャンネル142は
戻り位置128に連通する。The end wall 116 of the trough 110 includes an inlet port 138 and an outlet port 140.
A channel 142 communicating with the inlet port 138 extends substantially the full width of the trough and communicates with the passage 126.
Similarly, a channel 142 communicating with the outlet port 140 communicates with the return location 128 .
トラフ110の機能は次の通りである。溶融材料例えば溶
融スラグ114は湯出口10から銅部材118の作動面120に流
れ、これからスピンナ等に流れる。溶融スラグ114が面1
20に沿って流れるときに大量の熱が銅部材118に伝達さ
れる。水等の所定の冷却液を入口ポート138に圧入し、
チャンネル142を経て通路126に流す。冷却液は開口136
を経て戻り通路128を経てチャンネル142に入り、出口ポ
ート140を出る。極めて狭い絞り通路126と流入冷却液圧
力の組み合わせによって、冷却液は銅部材118の下面124
を超高速即ち少なくとも3.05m/s(約10ft/s)で流れ、
この面に生成する蒸気を滞留させずに流し、銅部材118
を有効に冷却する。The function of the trough 110 is as follows: the molten material, e.g., molten slag 114, flows from the taphole 10 onto the working surface 120 of the copper member 118, and from there onto the spinner or the like.
A large amount of heat is transferred to the copper member 118 as it flows along the copper member 118. A selected coolant, such as water, is forced into the inlet port 138,
The coolant flows through the channel 142 into the passage 126.
The coolant flows through the return passage 128 into the channel 142 and out the outlet port 140. The combination of the extremely narrow restrictor passage 126 and the incoming coolant pressure forces the coolant against the underside 124 of the copper member 118.
flowing at very high speeds, i.e. at least 3.05 m/s (approximately 10 ft/s),
The steam generated on this surface is allowed to flow without stagnating, and the copper member 118
Effectively cools the
当該トラフによる有効な冷却の結果、予測可能の一定の
厚さの固体スラグ材料の被覆即ち殻がトラフの作動面上
に凝固し、トラフの出口端から一定の変動のない材料流
が得られる。更に、この殻は熱絶縁性であり、銅を過大
温度から保護する。更に、殻は銅作動面を摩耗から守
る。As a result of the effective cooling provided by the trough, a coating or shell of solid slag material of predictable and consistent thickness solidifies on the working surface of the trough, resulting in a consistent and stable material flow from the outlet end of the trough. Additionally, the shell is thermally insulating, protecting the copper from excessive temperatures. Additionally, the shell protects the copper working surface from wear.
第4図は、本発明の湯出口と同様の原理に従って構成さ
れた超高速水冷銅スピンナの断面図を示し符号210とす
る。スピンナ210にはほぼ円筒形の銅外殻212を有し、外
殻212の外側作動面214上に溶融材料例えば溶融スラグ11
4が噴射されて動エネルギを受け手ファイバを形成す
る。銅外殻212には内側円筒面216と端壁218とを円筒形
部212と一体として形成する。4 shows a cross-sectional view of an ultra-high speed water-cooled copper spinner, generally designated 210, constructed in accordance with the same principles as the tapping outlet of the present invention. The spinner 210 has a generally cylindrical copper shell 212 on the outer working surface 214 of the shell 212, on which molten material, e.g., molten slag 11, is deposited.
4 is jetted to form the kinetic energy receiving fiber. The copper shell 212 has an inner cylindrical surface 216 and an end wall 218 integrally formed with the cylindrical portion 212.
外殻212内に複数のボルト220によって冷却液案内222を
取り付ける。冷却液案内222はほぼ円筒形として外側円
筒壁224を有する。冷却液案内222は外殻212内に同一軸
線に配置し、面224を外殻212の内面216に対して狭い間
隔として極めて狭い絞り通路226を形成する。A coolant guide 222 is attached within the outer shell 212 by a plurality of bolts 220. The coolant guide 222 is generally cylindrical and has an outer cylindrical wall 224. The coolant guide 222 is coaxially disposed within the outer shell 212, and the surface 224 is closely spaced from the inner surface 216 of the outer shell 212 to form an extremely narrow throttle passage 226.
案内222の中央開口228を貫通して軸線方向に内部導管23
0を通す。導管230の前端は案内222に対して回転可能と
し、Oリング232を使用して液シールを行う。導管230の
後端、第4図の左端は固定の入口ポート234となる。The inner conduit 23 extends axially through the central opening 228 of the guide 222.
4. The front end of the conduit 230 is rotatable relative to the guide 222, and a liquid seal is provided using an O-ring 232. The rear end of the conduit 230, the left end in FIG. 4, is a fixed inlet port 234.
外側導管236は内側導管230と同一軸線として後述する戻
り通路を形成する。導管236の前端は、案内222の背面に
複数のボルト240によって固着しOリング242によってシ
ールする。The outer conduit 236 is coaxial with the inner conduit 230 and forms a return passage, which will be described later. The front end of the conduit 236 is fixed to the rear surface of the guide 222 by a plurality of bolts 240 and sealed by an O-ring 242.
外側導管236の他端は回転ユニオン246の第1の部分244
に固着する。回転ユニオン246の固定半部としての他の
半部248は内側導管230及び入口ポート234に固着する。
回転ユニオン246には出口ポート250を設けて図示の通り
環状スペース即ち戻り通路238に連通する。The other end of the outer conduit 236 is connected to a first portion 244 of a rotary union 246.
The other stationary half 248 of the rotary union 246 is fixed to the inner conduit 230 and the inlet port 234.
The rotary union 246 has an outlet port 250 which communicates with the annular space or return passage 238 as shown.
案内222の内部に後端部即ち第4図の左側付近にほぼ円
板状のスペース252を形成する。スペース252は環状スペ
ース即ち戻り通路238に連通する。スペース252は更に狭
い通路226と複数の孔254を経て連通する。孔254は半径
方向に案内222を外面224からスペース252に通る。好適
な例として、12個の孔254を案内222の外周に等角度間隔
で形成する。A generally disk-shaped space 252 is formed inside the guide 222 at its rear end, i.e., near the left side in FIG. 4. The space 252 communicates with the annular space, i.e., the return passage 238. The space 252 communicates with the narrower passage 226 via a plurality of holes 254. The holes 254 extend radially through the guide 222 from the outer surface 224 to the space 252. In a preferred example, twelve holes 254 are formed at equal angular intervals around the outer periphery of the guide 222.
案内222の前面256はほぼ皿形とする。即ち、面256と端
壁218との間隔は半径の増加と共に減少する。当業者に
周知の通り、これによって面256と端壁218との間を一定
流速とする。スピンナは周知の方法で外側導管236に固
着したギア又はプーリを介して回転させる。The front surface 256 of the guide 222 is generally dished. That is, the distance between the surface 256 and the end wall 218 decreases with increasing radius. As is well known to those skilled in the art, this provides a constant flow rate between the surface 256 and the end wall 218. The spinner is rotated via a gear or pulley secured to the outer conduit 236 in a well-known manner.
スピンナ210の機能は次の通りである。外殻212、案内22
2、外側導管236の組み合わせは所要速度で回転させ、こ
の間溶融材料、例えば溶融スラグ114が銅外殻212の作動
面214に供給されてファイバを形成する。溶融材料が面2
14に接触すれば大きな熱が銅外殻212に伝達される。水
等の所要の冷却液が入口ポート234に圧入され、導管230
を経て案内222の面256と端壁218との間のスペースに入
る。ここから冷却液は通路226、開口254を経てスペース
252に入り、戻り通路238を経て出口ポート250に流れ
る。極めて狭い絞り通路226と流入冷却液の圧力との組
み合わせによって冷却液は銅外殻212の内面216を超高
速、少なくとも3.05m/s(約10ft/s)で流れ、この面に
生成した蒸気を滞留させずに流し、銅外殻212を有効に
冷却する。The functions of the spinner 210 are as follows: outer shell 212, guide 22
The combination of 2 and outer conduit 236 is rotated at a desired speed while molten material, e.g., molten slug 114, is fed onto working surface 214 of copper shell 212 to form fibers.
14, significant heat is transferred to the copper shell 212. The desired cooling fluid, such as water, is forced into the inlet port 234 and flows through the conduit 230.
222 and into the space between the surface 256 of the guide 222 and the end wall 218. From there, the coolant flows through the passage 226, the opening 254, and into the space
252 and flows through return passage 238 to outlet port 250. The combination of the extremely narrow throttle passage 226 and the pressure of the incoming coolant causes the coolant to flow over the inner surface 216 of the copper shell 212 at an extremely high speed, at least 3.05 m/s (approximately 10 ft/s), without allowing any vapor generated on this surface to stagnate, thereby effectively cooling the copper shell 212.
当該スピンナによる有効な冷却の結果、予測可能の一定
の厚さの固体スラグ材料の外皮即ち殻がスピンナの作動
面に凝着し、ファイバ化過程の細かい制御を可能にす
る。更に、この殻は熱絶縁性であり、銅が過大温度にな
るのを防ぐ。尚、殻は銅の作動面を物理的摩耗から守
る。As a result of the efficient cooling provided by the spinner, a skin or shell of solid slug material of predictable and consistent thickness adheres to the spinner's working surface, allowing for fine control of the fiberization process. Additionally, the shell is thermally insulating, preventing the copper from overheating. Furthermore, the shell protects the copper working surface from physical wear.
上述の実施例及び参考例において、一方のポートを入口
ポートとし、他方のポートを出口ポートしたが、反対に
することもできる。冷却液を反対方向に流して出口ポー
トから入れて入口ポートから出しても同じ冷却効果を得
る。更に、冷却液案内、導管、ジャケットは銅製とする
こともでき、ステンレス鋼等の所要の材料製とすること
もできる。In the above-described embodiment and reference examples, one port is the inlet port and the other port is the outlet port, but the opposite is also possible. The same cooling effect can be achieved by flowing the coolant in the opposite direction, entering through the outlet port and exiting through the inlet port. Furthermore, the coolant guide, conduit, and jacket can be made of copper, stainless steel, or other required materials.
本発明は、本質を変更せずに他の実施例とすることもで
き、本発明の要旨は請求の範囲に記載されている。The present invention may be embodied in other ways without changing its essence, and the scope of the present invention is defined by the following claims.
図面の簡単な説明
第1図は本発明の原理による超高速水冷銅湯出口の断面
図であり、
第2図は超高速水冷銅トラフの縦断面図であり、
第3図は第2図の3−3線に沿った断面図であり、
第4図は超高速水冷銅スピンナの断面図である。BRIEF DESCRIPTION OF THE DRAWINGS FIG. 1 is a cross-sectional view of an ultra-high speed water-cooled copper taphole according to the principles of the present invention; FIG. 2 is a longitudinal cross-sectional view of an ultra-high speed water-cooled copper trough; FIG. 3 is a cross-sectional view taken along line 3-3 in FIG. 2; and FIG. 4 is a cross-sectional view of an ultra-high speed water-cooled copper spinner.
(符号の説明)
10……湯出口、12……グラファイトノズル、14……内側
鋼材料、16……中間冷却液案内、18……外側ジャケッ
ト、24……オリフィス、26……作動面、28……通路、30
……第1の孔、32……第2の孔、38,40,46……環状スペ
ース、50……開口、52……入口ポート、54……出口ポー
ト(Explanation of symbols) 10... tapping outlet, 12... graphite nozzle, 14... inner steel material, 16... intermediate coolant guide, 18... outer jacket, 24... orifice, 26... working surface, 28... passage, 30
First hole, 32, second hole, annular spaces 38, 40, 46, opening 50, inlet port 52, outlet port 54
Claims (10)
する、溶融炉からの溶融材料の湯出口であって、 炉からの溶融材料を通すオリフィスを形成する内側作動
面を備えた金属部材からなり、 前記オリフィスの周囲に、前記内側作動面に近接して設
けられた冷却液を流すための極めて狭い通路が形成され
ていることを特徴とする湯出口。[Claim 1] A tapping outlet for molten material from a melting furnace for use in a mineral wool fiber manufacturing apparatus, comprising a metal member having an inner working surface forming an orifice through which molten material from the furnace passes, the orifice being surrounded by an extremely narrow passage for the flow of cooling liquid located adjacent to the inner working surface.
る、特許請求の範囲第1項に記載の湯出口。2. The tap outlet of claim 1, wherein the passage is formed within the metal member.
ように設けられている、特許請求の範囲第3項に記載の
湯出口。3. The tap outlet according to claim 3, wherein the passage is provided so as to surround the outer periphery of the orifice.
記金属部材内に設けられ且つ当該金属部材の外壁に設け
られた第1の孔及び第2の孔を含み当該第1の孔と第2
の孔とを連通させるトンネル状の流路を含み、当該第1
の孔が前記冷却液の入口であり、当該第2の孔が前記冷
却液の出口である、特許請求の範囲第2項に記載の湯出
口。4. The passage includes a first hole and a second hole provided in the metal member adjacent to the orifice and in an outer wall of the metal member, the first hole and the second hole being connected to each other.
a tunnel-shaped flow path that communicates with the first hole,
3. A tap outlet as claimed in claim 2, wherein said first hole is the coolant inlet and said second hole is the coolant outlet.
個含み、当該トンネル状の流路各々が前記第1の孔及び
第2の孔を含み、当該第1の孔の全て及び当該第2の孔
の全てが、各々、互いに連通している、特許請求の範囲
第4項に記載の湯出口。[Claim 5] A tap outlet as described in claim 4, wherein the passage includes a plurality of tunnel-shaped flow paths, each of which includes the first hole and the second hole, and all of the first holes and all of the second holes are each connected to each other.
る領域から軸線方向に延びた中空の管状部分を含む、特
許請求の範囲第5項に記載の湯出口。6. A tap outlet according to claim 5, wherein said metal member includes a hollow tubular portion extending axially from the area in which said passage is provided.
くとも一部の周囲を包囲して軸線方向に延び、一端が前
記金属部材の通路が設けられている部分に結合されて当
該管状部分との間に極めて狭い第1の環状のスペースを
形成するように配設された、管状の冷却液案内部材を含
み、当該第1の環状スペースは、前記第2の孔を介して
前記トンネル状の流路と連通されている、特許請求の範
囲第6項に記載の湯出口。[Claim 7] A tap outlet as described in claim 6, including a tubular coolant guide member that is coaxial with the tubular portion, extends axially around at least a portion of the tubular portion, and has one end connected to the portion of the metal member where the passage is provided, so as to form an extremely narrow first annular space between it and the tubular portion, and the first annular space is connected to the tunnel-shaped flow path via the second hole.
内部材の周囲を包囲して軸線方向に延び、一端が前記金
属部材の通路が設けられている部分に結合されて前記冷
却液案内部材との間に第2の環状のスペースを形成する
ように配設された管状の外側管状ジャケットを含み、当
該第2の環状スペースは、前記第1の孔を介して前記ト
ンネル状の流路と連通されている、特許請求の範囲第7
項に記載の湯出口。8. The cooling fluid guide member according to claim 7, further comprising a tubular outer jacket extending axially around the cooling fluid guide member, coaxially with the cooling fluid guide member, and having one end connected to a portion of the metal member where the passage is provided, to form a second annular space between the cooling fluid guide member and the tubular outer jacket, and the second annular space is connected to the tunnel-shaped flow path via the first hole.
The tap outlet described in paragraph.
囲第1項に記載の湯出口。9. The tap outlet according to claim 1, wherein the metal member is made of copper.
融炉からの溶融材料の湯出口を有効に冷却する方法であ
って、 前記湯出口を炉からの溶融材料を通すオリフィスを形成
する内側作動面を備えた金属部材から構成し、 前記オリフィスの周囲に、前記内側作動面に近接して冷
却液を流すための極めて狭い通路を形成し、 溶融材料を通すオリフィスを形成する面に近接して、冷
却液を少なくとも約3.05m/s(10ft/s)の速度で流すこ
とを特徴とする湯出口冷却方法。[Claim 10] A method for effectively cooling the tap outlet of molten material from a melting furnace in a mineral wool fiber manufacturing apparatus, comprising: constructing said tap outlet from a metal member having an inner working surface forming an orifice through which molten material from the furnace passes; forming a very narrow passageway around said orifice adjacent said inner working surface for the flow of cooling liquid; and flowing cooling liquid adjacent to the surface forming the orifice through which the molten material passes at a velocity of at least about 3.05 m/s (10 ft/s).
Applications Claiming Priority (7)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US311042 | 1981-10-13 | ||
| US06/311,042 US4498610A (en) | 1981-10-13 | 1981-10-13 | Ultrahigh velocity water-cooled copper taphole |
| US311045 | 1981-10-13 | ||
| US06/311,043 US4468931A (en) | 1981-10-13 | 1981-10-13 | Ultrahigh velocity water-cooled copper spinner |
| US06/311,045 US4446995A (en) | 1981-10-13 | 1981-10-13 | Ultrahigh velocity water-cooled copper trough |
| PCT/US1982/001393 WO1983001422A1 (en) | 1981-10-13 | 1982-09-30 | Ultrahigh velocity water cooling |
| US311043 | 1999-05-13 |
Related Child Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP6084873A Division JPH0829959B2 (en) | 1981-10-13 | 1994-04-22 | Spinner for mineral wool fiber production equipment |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPH0710736B2 true JPH0710736B2 (en) | 1995-02-08 |
| JPH0710736B1 JPH0710736B1 (en) | 1995-02-08 |
Family
ID=27405488
Family Applications (3)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP57-503346A Expired - Lifetime JPH0710736B2 (en) | 1981-10-13 | 1982-09-30 | Taphole for mineral wool fiber manufacturing equipment. |
| JP57503346A Granted JPS58501674A (en) | 1981-10-13 | 1982-09-30 | Hot water outlet for mineral wool fiber production equipment |
| JP6084873A Expired - Lifetime JPH0829959B2 (en) | 1981-10-13 | 1994-04-22 | Spinner for mineral wool fiber production equipment |
Family Applications After (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP57503346A Granted JPS58501674A (en) | 1981-10-13 | 1982-09-30 | Hot water outlet for mineral wool fiber production equipment |
| JP6084873A Expired - Lifetime JPH0829959B2 (en) | 1981-10-13 | 1994-04-22 | Spinner for mineral wool fiber production equipment |
Country Status (8)
| Country | Link |
|---|---|
| EP (1) | EP0090843B1 (en) |
| JP (3) | JPH0710736B2 (en) |
| AU (1) | AU557818B2 (en) |
| CA (1) | CA1223727A (en) |
| DE (1) | DE3276697D1 (en) |
| DK (1) | DK161138C (en) |
| FI (1) | FI73407C (en) |
| WO (1) | WO1983001422A1 (en) |
Families Citing this family (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE3562572D1 (en) * | 1984-11-23 | 1988-06-16 | Rene Desaar | Improvements to molten metal ladles |
| US20080210718A1 (en) | 2007-01-25 | 2008-09-04 | General Kinematics Corporation | Fluid-Cooled Vibratory Apparatus, System and Method for Cooling |
| CN102154890B (en) * | 2011-01-19 | 2013-08-21 | 武汉凯比思电力设备有限公司 | Fusant chute |
| EP4095108A1 (en) * | 2021-05-25 | 2022-11-30 | Rockwool A/S | Baffle ring |
Family Cites Families (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US399263A (en) * | 1889-03-12 | Tuyere | ||
| US2529962A (en) * | 1947-05-17 | 1950-11-14 | Johns Manville | Method and apparatus for producing mineral wool |
| US2827279A (en) * | 1955-09-20 | 1958-03-18 | American Brake Shoe Co | Tuyeres provided with coolant passages |
| US2944284A (en) * | 1957-10-09 | 1960-07-12 | United States Gypsum Co | Binder distribution and atomizing system for fiberizing apparatus |
| USRE25306E (en) * | 1959-08-24 | 1962-12-25 | Apparatus for producing fibers from molten material | |
| US3650723A (en) * | 1969-03-12 | 1972-03-21 | Corning Glass Works | Glass gob delivery |
| JPS571495B2 (en) * | 1974-01-31 | 1982-01-11 | ||
| US4106921A (en) * | 1976-09-13 | 1978-08-15 | United States Gypsum Company | Apparatus for low pressure air fiberization of mineral fiber |
| JPS5540542A (en) * | 1978-09-14 | 1980-03-22 | Tokyo Shibaura Electric Co | Drum system washing machine |
| JPS571495A (en) * | 1980-06-06 | 1982-01-06 | Hiroyoshi Masuzawa | Methane gas generator |
-
1982
- 1982-09-30 JP JP57-503346A patent/JPH0710736B2/en not_active Expired - Lifetime
- 1982-09-30 EP EP82903388A patent/EP0090843B1/en not_active Expired
- 1982-09-30 JP JP57503346A patent/JPS58501674A/en active Granted
- 1982-09-30 AU AU90589/82A patent/AU557818B2/en not_active Ceased
- 1982-09-30 DE DE8282903388T patent/DE3276697D1/en not_active Expired
- 1982-09-30 WO PCT/US1982/001393 patent/WO1983001422A1/en not_active Ceased
- 1982-10-12 CA CA000413249A patent/CA1223727A/en not_active Expired
-
1983
- 1983-05-27 FI FI831909A patent/FI73407C/en not_active IP Right Cessation
- 1983-06-13 DK DK269983A patent/DK161138C/en not_active IP Right Cessation
-
1994
- 1994-04-22 JP JP6084873A patent/JPH0829959B2/en not_active Expired - Lifetime
Also Published As
| Publication number | Publication date |
|---|---|
| DK269983A (en) | 1983-06-13 |
| WO1983001422A1 (en) | 1983-04-28 |
| DK161138C (en) | 1991-11-25 |
| JPH0829959B2 (en) | 1996-03-27 |
| FI831909L (en) | 1983-05-27 |
| JPH06321570A (en) | 1994-11-22 |
| EP0090843B1 (en) | 1987-07-08 |
| JPS58501674A (en) | 1983-10-06 |
| EP0090843A4 (en) | 1984-02-07 |
| AU557818B2 (en) | 1987-01-08 |
| AU9058982A (en) | 1983-05-05 |
| DK161138B (en) | 1991-06-03 |
| EP0090843A1 (en) | 1983-10-12 |
| CA1223727A (en) | 1987-07-07 |
| FI831909A0 (en) | 1983-05-27 |
| DK269983D0 (en) | 1983-06-13 |
| JPH0710736B1 (en) | 1995-02-08 |
| DE3276697D1 (en) | 1987-08-13 |
| FI73407B (en) | 1987-06-30 |
| FI73407C (en) | 1987-10-09 |
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