JPH07119284B2 - Colored elastic powder rubber composite and method for producing the same - Google Patents
Colored elastic powder rubber composite and method for producing the sameInfo
- Publication number
- JPH07119284B2 JPH07119284B2 JP25805688A JP25805688A JPH07119284B2 JP H07119284 B2 JPH07119284 B2 JP H07119284B2 JP 25805688 A JP25805688 A JP 25805688A JP 25805688 A JP25805688 A JP 25805688A JP H07119284 B2 JPH07119284 B2 JP H07119284B2
- Authority
- JP
- Japan
- Prior art keywords
- rubber
- elastic powder
- weight
- parts
- powder rubber
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Links
Classifications
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
- Y02W30/00—Technologies for solid waste management
- Y02W30/50—Reuse, recycling or recovery technologies
- Y02W30/62—Plastics recycling; Rubber recycling
Landscapes
- Processes Of Treating Macromolecular Substances (AREA)
- Processing And Handling Of Plastics And Other Materials For Molding In General (AREA)
- Separation, Recovery Or Treatment Of Waste Materials Containing Plastics (AREA)
Description
【発明の詳細な説明】 （産業上の利用分野） 本発明は着色弾性粉末ゴム及び着色弾性粉末ゴムの製造
方法及びこれらの着色弾性粉末ゴムより製造された着色
弾性粉末ゴム複合物及びそれらの製造方法に関するもの
である。着色弾性粉末ゴム複合物は、公園歩道、商店街
の歩道、運動用の施設例えば、陸上競技場、屋内体育
館、ゴルフ場歩経路、球技用コート、ジョギングコース
等に使用される。The present invention relates to a colored elastic powder rubber, a method for producing a colored elastic powder rubber, a colored elastic powder rubber composite produced from these colored elastic powder rubbers, and their production. It is about the method. The colored elastic powder rubber composite is used for park sidewalks, sidewalks in shopping districts, sports facilities such as athletic fields, indoor gymnasiums, golf course walking paths, ball courts, jogging courses and the like.
（従来の技術） 従来、公園歩道、商店街の歩道、運動用の施設に使用さ
れる舗装体としては、アスファルト、プラスチックが使
用された。(Prior Art) Conventionally, asphalt and plastic have been used as pavements used in park sidewalks, shopping street sidewalks, and exercise facilities.
又、未着色の弾性粉末ゴムを液状バインダーを用いて結
合した複合物が使用されたり、又はその表面を塗装する
等により使用されていた。Further, a composite obtained by binding an uncolored elastic powder rubber with a liquid binder has been used, or the surface thereof has been used for coating.
最近特に、美観上から、着色した舗装体の要求が多くな
り、これらは施工する現場で、弾性粉末ゴムに液状バイ
ンダー、顔料、助剤等を混練り攪拌機に投入して混練り
したものを所定幅、所定厚みに流し込み、コテ、又は熱
ロールで展圧して常温硬化させ着色複合板を成形してい
た。Recently, especially from the viewpoint of aesthetics, there is a growing demand for colored pavements, and at these construction sites, elastic powder rubber is kneaded with a liquid binder, pigment, auxiliaries, etc. It was poured into a width and a predetermined thickness, spread by a trowel or a hot roll, and cured at room temperature to form a colored composite plate.
又、予め、工場で前述の原料を使用し、複合物を混練り
混合し、均一に熱ロールで展圧して常温硬化させ、又
は、混練りしたものを成形モールドに所定量投入して加
熱プレスで加圧、加熱して硬化させ、着色複合物を製造
していた。In addition, using the above-mentioned raw materials in the factory beforehand, the composites are kneaded and mixed, and uniformly spread by a hot roll to cure at room temperature, or the kneaded product is put into a molding mold in a predetermined amount and heated and pressed. In order to obtain a colored composite, pressurization and heating were performed to cure the composite.
又、着色した複合物の他の製法はゴム、ウレタンと顔
料、充填剤、助剤等を混練りし、シート状に圧延し、加
硫又は架橋して、着色ゴム板を製造し、これを粉砕機に
て粉砕して篩分け選別して着色粉末ゴムを製造して液状
バインダーにて結合一体化して着色粉末複合物を製造し
ていた。Another method for producing a colored composite is to knead rubber, urethane and a pigment, a filler, an auxiliary agent, etc., and then roll them into a sheet, vulcanize or crosslink them to produce a colored rubber plate. A colored powder rubber was manufactured by crushing with a crusher, sieving and selection, and combined with a liquid binder to manufacture a colored powder composite.
（発明が解決しようとする課題） 従来、アスファルトは、歩行者、利用者の足腰を痛め、
不快感を与え、プラスチックは舗装体の価格が高価とい
う欠点があった。未着色弾性粉末ゴムを液状バインダー
を用いて結合した複合物は、美観上好ましくなかった。(Problems to be Solved by the Invention) Conventionally, asphalt has hurt the legs and feet of pedestrians and users,
It was uncomfortable and plastic had the drawback of high pavement prices. A composite obtained by binding an uncolored elastic powder rubber with a liquid binder was aesthetically unfavorable.
着色弾性複合物を現場及び工場で製造する場合、弾性粉
末ゴム、バインダー、顔料の計量の精度、液状バインダ
ーの粘度、混練り混合時の材料の投入順序、作業時間、
混合練り物の経過時間、温度の変化等に敏感のため、色
むらが多く発生し、この色むらが問題となっていた。着
色ゴム板から製造する方法は、色むらはなくなるが、非
常に高価となり、問題となっていた。When manufacturing colored elastic composites in the field and in the factory, the accuracy of measurement of elastic powder rubber, binder, pigment, viscosity of liquid binder, order of feeding materials during kneading and mixing, working time,
Since the mixed paste is sensitive to the elapsed time, changes in temperature, etc., a large amount of color unevenness occurs, which is a problem. The method of manufacturing from a colored rubber plate eliminates color unevenness, but is very expensive and has been a problem.
本発明は着色弾性粉末ゴムの複合物を現場及び工場で製
造しても、色むらのない安価なものを製造する製造方法
および複合物を提供することを目的とする。そして、着
色弾性粉末ゴムを安価に製造するため、弾性粉末ゴムと
は従来廃棄していた、ゴム製品の粉末ゴムを使用して、
安価に提供することを目的とする。It is an object of the present invention to provide a manufacturing method and a composite for manufacturing a colored elastic powder rubber composite which is inexpensive and has no unevenness in color even if it is manufactured in the field or in a factory. And, in order to manufacture colored elastic powder rubber at low cost, elastic powder rubber is used as the powder rubber of the rubber product, which was conventionally discarded.
The purpose is to provide at low cost.
（課題を解決するための手段） 本発明はこれらの目的を解決するために、先ず、弾性粉
末ゴムと天然ゴム・ポリメチルメタクリレートのグラフ
ト共重合体、ポリクロロプレンゴム、エチレン・酢酸ビ
ニル共重合体、塩化ビニル・アクリル共重合体、アクリ
ル樹脂及びウレタン樹脂の中の少なくとも一つからなる
溶液、ラテックスならびにエマルジョンのいずれか一種
からなるバインダーと顔料とその他の添加剤とを、弾性
粉末ゴム100重量部に対し、バインダー３〜12重量部を
用い、攪拌混合し、加温乾燥機で乾燥中、バインダーで
粘結一体になることを防止するため攪拌しながら乾燥し
て、弾性粉末ゴムの表面に着色塗膜を形成した着色弾性
粉末ゴムを製造し、次に、その着色弾性粉末ゴムを用い
て、液状の硬化可能なポリクロロプレンゴム、エポキシ
樹脂、一液性ウレタン及び二液性ウレタンの中の少なく
とも一つからなるバインダーを着色弾性粉末ゴム100重
量部に対し、10〜50重量部を用い、結合させ一体化して
製造した着色弾性粉末ゴム複合物の製造方法により解決
した。(Means for Solving the Problems) In order to solve these objects, the present invention firstly describes a graft copolymer of elastic powder rubber and natural rubber / polymethylmethacrylate, polychloroprene rubber, ethylene / vinyl acetate copolymer. 100 parts by weight of elastic powder rubber, a binder, a pigment, and other additives made of at least one of a solution of at least one of vinyl chloride / acrylic copolymer, acrylic resin and urethane resin, latex and emulsion. On the other hand, 3 to 12 parts by weight of the binder is used, and the mixture is stirred and mixed, and while being dried in a warm dryer, the binder is dried while being stirred to prevent the binder from being clogged and integrated. A colored elastic powder rubber having a coating film is produced, and then the colored elastic powder rubber is used to produce a liquid curable polychloroprene rubber. Colored elastic powder produced by combining and integrating 10 to 50 parts by weight of a binder composed of at least one of epoxy resin, one-component urethane and two-component urethane with 100 parts by weight of colored elastic powder rubber. This has been solved by the method of manufacturing a rubber composite.
この安価で奇麗な着色弾性粉末ゴム複合物を製造するた
めには先ず、品質管理の行き届いた工場において、着色
弾性粉末ゴムを作り、そして、施工現場、又は工場で着
色弾性粉末ゴムに、液状の硬化可能なポリクロロプレン
ゴム、エポキシ樹脂、一液性ウレタン及び二液性ウレタ
ンの中の少なくとも一つからなるバインダーを混合攪拌
させ、結合一体化して着色弾性粉末ゴム複合物を作る。In order to manufacture this inexpensive and beautiful colored elastic powder rubber composite, first, a colored elastic powder rubber is made in a factory with thorough quality control, and the colored elastic powder rubber is made into a liquid form at a construction site or a factory. A binder composed of at least one of a curable polychloroprene rubber, an epoxy resin, a one-component urethane and a two-component urethane is mixed and stirred, and the components are bonded and integrated to form a colored elastic powder rubber composite.
着色弾性粉末ゴムを具体的に製造するためには、弾性粉
末ゴム100重量部に対して２〜５重量部のバインダーを
固形分濃度10〜30％になるよう水で希釈して弾性粉末ゴ
ムと混合攪拌する。弾性粉末ゴムの表面が、完全にバイ
ンダーにて濡れたことを確認した後、顔料分散物３〜10
重量部を水で固形分濃度10〜30％になるよう水で希釈し
たものを添加混合し、乾燥冷却して、着色弾性粉末ゴム
を製造する。In order to specifically manufacture a colored elastic powder rubber, 2 to 5 parts by weight of a binder is diluted with water to a solid content concentration of 10 to 30% with respect to 100 parts by weight of the elastic powder rubber to obtain an elastic powder rubber. Mix and stir. After confirming that the surface of the elastic powder rubber is completely wet with the binder, the pigment dispersion 3 to 10 is used.
A colored elastic powder rubber is produced by adding and mixing parts by weight of water diluted with water to a solid content concentration of 10 to 30%, drying and cooling.
顔料分散物は顔料100重量部、バインダー100〜200重量
部、乳化剤０、５〜３重量部、水を固形分濃度20〜50％
になるよう調整添加し、高速攪拌機にて十分攪拌し分散
物を作る。The pigment dispersion comprises 100 parts by weight of pigment, 100 to 200 parts by weight of binder, 0 to 5 to 3 parts by weight of emulsifier, and a solid concentration of water of 20 to 50%.
Add and adjust so that the mixture becomes sufficiently stir with a high-speed stirrer to form a dispersion.
着色弾性粉末ゴムを製造するために、弾性粉末ゴムの着
色に用いられるバインダーとしては、乾燥後の膜強度が
強靭で、弾性粉末ゴム及び複合用バインダーとの密着性
に優れた天然ゴム・ポリメチルメタクリレートのグラフ
ト共重合体、ポリクロロプレンゴム、エチレン・酢酸ビ
ニル共重合体、塩化ビニル・アクリル共重合体、アクリ
ル樹脂及びウレタン樹脂の中の少なくとも一つからなる
溶液、ラテックスならびにエマルジョンのいずれか一種
からなるバインダーの低固形分濃度、10〜50％の低粘度
物が使用できる。As a binder used for coloring elastic powder rubber to produce colored elastic powder rubber, natural rubber polymethyl, which has strong film strength after drying and excellent adhesion to elastic powder rubber and composite binder Methacrylate graft copolymer, polychloroprene rubber, ethylene / vinyl acetate copolymer, vinyl chloride / acrylic copolymer, solution of at least one of acrylic resin and urethane resin, latex or emulsion It is possible to use a low solid content concentration of 10 to 50% of a low-viscosity binder.
着色弾性粉末ゴム複合物を製造するための着色弾性粉末
ゴムと硬化可能な結合物は、液状高分子物質例えば、液
状の硬化可能なポリクロロプレンゴム、エポキシ樹脂、
一液性ウレタン及び二液性ウレタンの中の少なくとも一
つからなるバインダーが使用できる。The colored elastic powder rubber and the curable binder for producing the colored elastic powder rubber composite are liquid polymeric substances, for example, liquid curable polychloroprene rubber, epoxy resin,
A binder composed of at least one of one-component urethane and two-component urethane can be used.
これらのバインダーの使用量は着色弾性粉末ゴム100重
量部に対し、10〜50重量部が使用できる。The amount of these binders used can be 10 to 50 parts by weight based on 100 parts by weight of the colored elastic powder rubber.
又、着色弾性粉末ゴムを使用することにより複合用のバ
インダーの使用量が15〜30％削減できる。Further, the use of the colored elastic powder rubber can reduce the amount of the composite binder used by 15 to 30%.
更に、着色弾性粉末ゴムに使用される安価な粉末ゴムは
自動車タイヤ、チューブ、ベルト、ホース、窓枠ゴム、
型物製品の廃棄品を粉砕した粒状ゴム、ファイバー状ゴ
ム（通称ヒジキ状ゴム）、粉砕ゴムが使用できる。Further, inexpensive powder rubbers used for colored elastic powder rubbers include automobile tires, tubes, belts, hoses, window frame rubbers,
Granular rubber, fibrous rubber (commonly known as hijiki-shaped rubber), or crushed rubber obtained by crushing waste products of mold products can be used.
粒状ゴムの粒径は、３〜50メッシュの粒度、ファイバー
状ゴムは、断面がほぼ円形で、直径0.5〜3m/m、長さ５
〜30m/mの針状、ヒモ状、糸状の構造を持つものが良
く、破砕ゴムは粒状ゴムを製造するときに、破砕機を使
用して荒く粉砕されたもので、直径５〜15m/m又は15m/m
以下の不定形のものが使用できる。Granular rubber has a particle size of 3 to 50 mesh, and fibrous rubber has a circular cross section with a diameter of 0.5 to 3 m / m and a length of 5
Need to have a needle-like, string-like, or thread-like structure of ~ 30 m / m, and the crushed rubber is roughly crushed using a crusher when producing granular rubber, and has a diameter of 5-15 m / m. Or 15m / m
The following irregular shapes can be used.
顔料としては、それぞれの色の種類により、各種の無機
化合物、有機化合物が使用できる。例えば、茶色の場
合、弁柄、緑色の場合は酸化クロムグリーンが使用され
る。As the pigment, various inorganic compounds and organic compounds can be used depending on the type of each color. For example, in the case of brown, red iron oxide is used, and in the case of green, chromium oxide green is used.
更に、添加剤として、顔料の分散をよくするために、水
に可溶の表面活性剤等の乳化剤が使用される。Further, as an additive, an emulsifier such as a water-soluble surfactant is used in order to improve the dispersion of the pigment.
その他、滑り止め剤、防炎剤、防黴剤、及び殺虫剤等の
機能付与剤も添加可能である。In addition, function-imparting agents such as antiskid agents, flameproofing agents, antifungal agents, and insecticides can also be added.
（作用） 本発明は着色弾性粉末ゴムの製造を専門工場で製造でき
るため、品質管理が容易となり、着色用バインダーとし
て、溶液、ラテックス、エマルジョン等の低固形分、低
粘度物及び着色用顔料分散物も正確に製造でき、温度、
天候の影響を受けることもなくなり、品質の一定した着
色弾性粉末ゴムが得られた。(Function) Since the present invention can manufacture colored elastic powder rubber in a specialized factory, quality control becomes easy, and as a coloring binder, low solid content such as solution, latex, emulsion, low viscosity substance and coloring pigment dispersion Things can be manufactured accurately, temperature,
A colored elastic powder rubber having a constant quality was obtained without being affected by the weather.
次に実施例に基づいて詳細に説明する。Next, a detailed description will be given based on examples.
（実施例１） 茶色弾性粉末ゴムの製造方法 加硫弾性粉末ゴム（自動車タイヤのゴム部分を粉砕した
もの、５〜15m/mのファイバー状粉末ゴム）100重量部、
それにメガポリ40（天然ゴムラテックスとポリメチルメ
タクリレートのグラフト共重合体、アジアテイック開発
会社製）３重量部、水３重量部で希釈したものを添加混
合する。加硫粉末ゴムの表面が均一にメガポリ40にて濡
れたことを確認した後、弁柄分散物（メガポリ40、４重
量部、弁柄３重量部、乳化剤ロンヂスＫ−25（荒川林産
化学株式会社製）１重量部、水４重量部を高速攪拌し、
分散したもの）を添加し、約５分間攪拌混合する。混合
物の温風式回転乾燥機にて攪拌しながら約80℃15分間乾
燥し、冷却して、茶色の粉末ゴムが得られた。(Example 1) Method for producing brown elastic powder rubber 100 parts by weight of vulcanized elastic powder rubber (crushed rubber part of automobile tire, fiber powder rubber of 5 to 15 m / m)
To this, 3 parts by weight of Megapoly 40 (graft copolymer of natural rubber latex and polymethyl methacrylate, manufactured by Asiatic Development Co., Ltd.) and 3 parts by weight of water are added and mixed. After confirming that the surface of the vulcanized powder rubber was evenly wetted with Megapoly 40, the rouge dispersion (Megapoly 40, 4 parts by weight, Rouge 3 parts by weight, emulsifier Longis K-25 (Arakawa Hayashi Chemical Co., Ltd. 1 part by weight, 4 parts by weight of water are stirred at high speed,
(Dispersed) and stir-mix for about 5 minutes. The mixture was dried at about 80 ° C. for 15 minutes while stirring with a hot air rotary dryer, and cooled to obtain a brown powder rubber.
茶色弾性粉末ゴム複合物の製造方法 次に茶色粉末ゴム100重量部を一液性ウレタン（ポリプ
ロピレンポリオールの末端トリレンジイソシアネート及
び4,4′−ジフェニルメタンジイソシアネートアダク
ト、武田薬品工業株式会社製、商品名タケネートＦ−15
1）30重量部とを混練混合して、板状に展圧し、常温に
て硬化させ、一週間後、比重0.8、引っ張り強さ8Kg/c
m2、伸び率70％、透水性に優れた（透水係数４×10-1cm
/sec）茶色粉末ゴム複合物が得られた。Method for producing brown elastic powder rubber composite Next, 100 parts by weight of brown powder rubber was mixed with one-component urethane (terminal tolylene diisocyanate of polypropylene polyol and 4,4'-diphenylmethane diisocyanate adduct, manufactured by Takeda Pharmaceutical Co., Ltd., Takenate). F-15
1) Knead and mix with 30 parts by weight, spread into a plate and cure at room temperature, and after 1 week, specific gravity 0.8, tensile strength 8Kg / c
m 2 , elongation 70%, excellent water permeability (water permeability 4 × 10 -1 cm
/ sec) A brown powder rubber composite was obtained.
（実施例２） 緑色加硫粉末ゴムの製造方法 プラスチックとの接着性に優れたパンフレックスOM−40
00（エチレン・酢酸ビニルの共重合体エマルジョン、固
形分濃度50％、株式会社クラレ製）３重量部を水で約25
％に希釈したもので、窓枠粉末ゴム（Ｅ、Ｐ、Ｄ、Ｍ）
100重量部とを攪拌混合し、十分に濡らした後、高速攪
拌し、十分に分散した顔料分散液（パンフレックスOM−
4000 4重量部、酸化クロム（緑色顔料）３重量部、水４
重量部、乳化剤ロンヂスＫ−25 1重量部）と混合攪拌す
る。混合物を温風式回転乾燥機で攪拌しながら80℃×15
分乾燥し、冷却して緑色粉末ゴムが得られた。(Example 2) Method for producing green vulcanized powder rubber Panflex OM-40 excellent in adhesiveness to plastic
3 parts by weight of 00 (copolymer emulsion of ethylene / vinyl acetate, solid content concentration 50%, Kuraray Co., Ltd.) about 25 parts with water
Diluted to%, window frame powder rubber (E, P, D, M)
100 parts by weight is mixed with stirring, sufficiently wetted, and then stirred at high speed to sufficiently disperse the pigment dispersion (Panflex OM-
4000 4 parts by weight, chromium oxide (green pigment) 3 parts by weight, water 4
1 part by weight and 1 part by weight of emulsifier Longis K-25) and stirred. 80 ° C x 15 while stirring the mixture with a hot air rotary dryer
Minute drying and cooling gave a green powder rubber.
緑色加硫粉末ゴム複合物の製造方法 緑色加硫粉末ゴム100重量部、と一液性ウレタン25重量
部をバインダーとして混練混合し、コテ等で均一になら
し、展圧し、硬化させ、緑色粉末ゴム複合物が得られ
た。Method for producing green vulcanized powder rubber composite 100 parts by weight of green vulcanized powder rubber and 25 parts by weight of one-component urethane are kneaded and mixed as a binder, and then uniformly leveled with a trowel or the like, spread, and cured to give a green powder. A rubber composite was obtained.
アスファルト、コンクリート面に舗装するときには、ウ
レタン系のプライマーで下塗りをして、その上に展圧舗
装すると接着が良い。When paving on asphalt or concrete surface, it is better to undercoat with urethane type primer and spread pavement on it.
（実施例３） 二層着色弾性粉末ゴム複合物の製造方法 着色弾性粉末ゴム（ヒジキ状粉末ゴム）100重量部、一
液性ウレタン25重量部、硬化促進剤（ポリアミンのプロ
ピレンオキサイド付加物、武田薬品工業株式会社製、商
品名タケラックGR−11）２重量部を混合して、成型モー
ルドに表面層として15m/m厚みに均一に充填し、その上
にクッション層（破砕ゴム100重量部、ウレタン10重量
部、硬化促進剤１重量部）を60m/m厚みに充填し、50m/m
に成るまでに成型用モールド蓋の中合にて加圧し、150
℃×10分加熱硬化し、着色弾性粉末ゴム複層板が得られ
た。(Example 3) Method for producing two-layer colored elastic powder rubber composite 100 parts by weight of colored elastic powder rubber (Hijiki powder rubber), 25 parts by weight of one-component urethane, curing accelerator (propylene oxide adduct of polyamine, Takeda) 2 parts by weight of Takelac GR-11 manufactured by Yakuhin Kogyo Co., Ltd. is mixed and uniformly filled into a molding mold as a surface layer to a thickness of 15 m / m, and a cushion layer (crushed rubber 100 parts by weight, urethane) 10 parts by weight, 1 part by weight of a curing accelerator) to a thickness of 60 m / m, and 50 m / m
Until it becomes 150, pressurize it in the middle of the mold lid for molding to 150
It was cured by heating at ℃ × 10 minutes to obtain a colored elastic powder rubber multilayer plate.
破砕ゴムの表面積は粉末ゴムに比し非常に小さいので少
量のバインダーで強い物性弾性が得られた。Since the surface area of crushed rubber is much smaller than that of powdered rubber, strong physical properties and elasticity were obtained with a small amount of binder.
又、粉砕ゴムの価格は、ヒジキ状粉末ゴムの1/2、従っ
て、本実施例のように、厚い複合板を作る場合、下面に
破砕ゴムを使用することによって、安価で弾性に優れた
舗装体が得られた。又、着色弾性粉末ゴムの各種の色を
製造することにより各種の着色弾性粉末ゴム複合物を製
造でき、各種の色の組み合わせができる。In addition, the price of crushed rubber is 1/2 of powdered hydrangea, so when making a thick composite plate as in this example, by using crushed rubber on the lower surface, pavement that is inexpensive and has excellent elasticity can be used. I got a body. Further, various colored elastic powder rubber composites can be produced by producing various colored elastic powder rubbers, and various color combinations can be made.
（効果） 本発明の着色弾性粉末ゴムは工場で製造するために色む
らがなく、そのためにこれから製造した粉末ゴム複合物
は均一なものができる。(Effect) Since the colored elastic powder rubber of the present invention is manufactured in a factory, there is no color unevenness, and therefore the powder rubber composite manufactured from this can be made uniform.
本発明の着色弾性粉末ゴム複合物は各種の色の弾性粉末
ゴムを使用することにより各種の色の複合物を製造で
き、その複数の着色弾性粉末ゴムを組合せることによっ
て多彩色の舗装ができ、又、モザイク調舗装も出来る。The colored elastic powder rubber composite of the present invention can be used to produce various colored composites by using elastic powder rubbers of various colors, and by combining a plurality of colored elastic powder rubbers, multicolored pavement can be obtained. Also, mosaic-like pavement is possible.
現場では、着色粉末ゴムから製造できるために工程を削
減でき、顔料を使用する必要がないため、作業が簡単、
綺麗な作業環境が維持できる。作業する作業者も従来の
方法に比較して削減できる。In the field, because it can be manufactured from colored powder rubber, the number of steps can be reduced, and since there is no need to use pigments, the work is easy,
A clean working environment can be maintained. The number of workers can be reduced as compared with the conventional method.
Claims (4)
クリレートのグラフト共重合体、ポリクロロプレンゴ
ム、エチレン・酢酸ビニル共重合体、塩化ビニル・アク
リル共重合体、アクリル樹脂及びウレタン樹脂の中の少
なくとも一つからなる溶液、ラテックスならびにエマル
ジョンのいずれか一種からなるバインダーと顔料とその
他の添加剤とを、弾性粉末ゴム100重量部に対し、バイ
ンダー３〜12重量部を用い、攪拌混合し、加温乾燥機で
撹拌しながら乾燥して、弾性粉末ゴムの表面に着色塗膜
を形成することを特徴とする着色弾性粉末ゴムの製造方
法。1. At least one of a graft copolymer of elastic powder rubber and natural rubber / polymethylmethacrylate, polychloroprene rubber, ethylene / vinyl acetate copolymer, vinyl chloride / acrylic copolymer, acrylic resin and urethane resin. A binder, a pigment, and other additives made of any one of a solution, a latex, and an emulsion, which are composed of one, and 3 to 12 parts by weight of the binder are mixed with 100 parts by weight of the elastic powder rubber, and the mixture is heated. A method for producing a colored elastic powder rubber, which comprises forming a colored coating film on the surface of the elastic powder rubber by drying with stirring with a drier.
クリレートのグラフト共重合体、ポリクロロプレンゴ
ム、エチレン・酢酸ビニル共重合体、塩化ビニル・アク
リル共重合体、アクリル樹脂及びウレタン樹脂の中の少
なくとも一つからなる溶液、ラテックスならびにエマル
ジョンのいずれか一種からなるバインダーと顔料とその
他の添加剤とを、弾性粉末ゴム100重量部に対し、バイ
ンダー３〜12重量部を用い、攪拌混合し、加温乾燥機で
攪拌しながら乾燥して、弾性粉末ゴムの表面に着色塗膜
を形成することを特徴とする着色弾性粉末ゴム。2. At least one of a graft copolymer of elastic powder rubber and natural rubber / polymethylmethacrylate, polychloroprene rubber, ethylene / vinyl acetate copolymer, vinyl chloride / acrylic copolymer, acrylic resin and urethane resin. A binder, a pigment, and other additives made of any one of a solution, a latex, and an emulsion, which are composed of one, and 3 to 12 parts by weight of the binder are mixed with 100 parts by weight of the elastic powder rubber, and the mixture is heated. A colored elastic powder rubber, which is characterized in that a colored coating film is formed on the surface of the elastic powder rubber by drying with stirring with a dryer.
クリレートのグラフト共重合体、ポリクロロプレンゴ
ム、エチレン・酢酸ビニル共重合体、塩化ビニル・アク
リル共重合体、アクリル樹脂及びウレタン樹脂の中の少
なくとも一つからなる溶液、ラテックスならびにエマル
ジョンのいずれか一種からなるバインダーと顔料とその
他の添加剤とを、弾性粉末ゴム100重量部に対し、バイ
ンダー３〜12重量部を用い、攪拌混合し、加温乾燥機で
攪拌しながら乾燥して、弾性粉末ゴムの表面に着色塗膜
を形成した着色弾性粉末ゴムを、液状の硬化可能なポリ
クロロプレンゴム、エポキシ樹脂、一液性ウレタン及び
二液性ウレタンの中の少なくとも一つからなるバインダ
ーを着色弾性粉末ゴム100重量部に対し、10〜50重量部
を用い、結合させ一体化して製造したことを特徴とする
着色弾性粉末ゴム複合物の製造方法。3. At least one of a graft copolymer of elastic powder rubber and natural rubber / polymethylmethacrylate, polychloroprene rubber, ethylene / vinyl acetate copolymer, vinyl chloride / acrylic copolymer, acrylic resin and urethane resin. A binder, a pigment, and other additives made of any one of a solution, a latex, and an emulsion, which are composed of one, and 3 to 12 parts by weight of the binder are mixed with 100 parts by weight of the elastic powder rubber, and the mixture is heated. A colored elastic powder rubber having a colored coating film formed on the surface of the elastic powder rubber is dried with stirring with a drier, and a liquid curable polychloroprene rubber, epoxy resin, one-component urethane and two-component urethane The binder consisting of at least one of the above is used in an amount of 10 to 50 parts by weight, based on 100 parts by weight of the colored elastic powder rubber, and combined and integrated. Method for producing a colored elastic rubber powder composites, characterized in that it has produced.
クリレートのグラフト共重合体、ポリクロロプレンゴ
ム、エチレン・酢酸ビニル共重合体、塩化ビニル・アク
リル共重合体、アクリル樹脂及びウレタン樹脂の中の少
なくとも一つからなる溶液、ラテックスならびにエマル
ジョンのいずれか一種からなるバインダーと顔料とその
他の添加剤とを、弾性粉末ゴム100重量部に対し、バイ
ンダー３〜12重量部を用い、攪拌混合し、加温乾燥機で
攪拌しながら乾燥して、弾性粉末ゴムの表面に着色塗膜
を形成した着色弾性粉末ゴムを、液状の硬化可能なポリ
クロロプレンゴム、エポキシ樹脂、一液性ウレタン及び
二液性ウレタンの中の少なくとも一つからなるバインダ
ーを着色弾性粉末ゴム100重量部に対し、10〜50重量部
を用い、結合させ一体化して製造したことを特徴とする
着色弾性粉末ゴム複合物。4. At least one of a graft copolymer of elastic powder rubber and natural rubber / polymethylmethacrylate, polychloroprene rubber, ethylene / vinyl acetate copolymer, vinyl chloride / acrylic copolymer, acrylic resin and urethane resin. A binder, a pigment, and other additives made of any one of a solution, a latex, and an emulsion, which are composed of one, and 3 to 12 parts by weight of the binder are mixed with 100 parts by weight of the elastic powder rubber, and the mixture is heated. A colored elastic powder rubber having a colored coating film formed on the surface of the elastic powder rubber is dried with stirring with a drier, and is mixed with liquid curable polychloroprene rubber, epoxy resin, one-component urethane and two-component urethane. The binder consisting of at least one of the above is used in an amount of 10 to 50 parts by weight, based on 100 parts by weight of the colored elastic powder rubber, and combined and integrated. Colored elastic rubber powder composites, characterized in that it has produced.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP25805688A JPH07119284B2 (en) | 1988-10-13 | 1988-10-13 | Colored elastic powder rubber composite and method for producing the same |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP25805688A JPH07119284B2 (en) | 1988-10-13 | 1988-10-13 | Colored elastic powder rubber composite and method for producing the same |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPH02105828A JPH02105828A (en) | 1990-04-18 |
| JPH07119284B2 true JPH07119284B2 (en) | 1995-12-20 |
Family
ID=17314924
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP25805688A Expired - Fee Related JPH07119284B2 (en) | 1988-10-13 | 1988-10-13 | Colored elastic powder rubber composite and method for producing the same |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH07119284B2 (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR100802290B1 (en) * | 2007-06-26 | 2008-02-11 | 김성노 | Eco-friendly anion generating elastic chip and its manufacturing method |
Families Citing this family (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| ES2153244B1 (en) * | 1997-04-07 | 2001-09-01 | Retrainers Company S L | INTEGRAL RECYCLING PROCEDURE OF DISPOSED TIRES AND PRODUCTS OF THE SAME. |
| US6521706B1 (en) | 1998-01-12 | 2003-02-18 | Ppg Industries Ohio, Inc. | Composition of epoxy polymer, thermoplastic polymer, rubber particles and curing agent |
| GB2379934B (en) * | 2001-09-21 | 2003-08-13 | Cheng-Kuo Chiang | Method for making cushion pad |
| CN105419029A (en) * | 2015-12-14 | 2016-03-23 | 安徽都邦电器有限公司 | Heat-resistant and aging-resistant chloroprene rubber tube |
| CN108752671A (en) * | 2018-06-08 | 2018-11-06 | 明光速耐德实心轮胎有限公司 | A kind of wear-resisting solid tyre |
| CN111592840A (en) * | 2020-07-01 | 2020-08-28 | 邹小平 | A kind of chloroprene type high flash point adhesive and preparation method thereof |
Family Cites Families (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5116059A (en) * | 1974-06-12 | 1976-02-09 | Nippon Columbia | SOTAIGATAHOROGURA FUIISATSUEIHO |
| JPS6319231A (en) * | 1986-07-12 | 1988-01-27 | Sanjiyou Kogyo Kk | Preparation of soundproof, heat insulating and buffer molded article |
-
1988
- 1988-10-13 JP JP25805688A patent/JPH07119284B2/en not_active Expired - Fee Related
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR100802290B1 (en) * | 2007-06-26 | 2008-02-11 | 김성노 | Eco-friendly anion generating elastic chip and its manufacturing method |
Also Published As
| Publication number | Publication date |
|---|---|
| JPH02105828A (en) | 1990-04-18 |
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