JPH0713619B2 - Oxygen concentration detector - Google Patents
Oxygen concentration detectorInfo
- Publication number
- JPH0713619B2 JPH0713619B2 JP1865786A JP1865786A JPH0713619B2 JP H0713619 B2 JPH0713619 B2 JP H0713619B2 JP 1865786 A JP1865786 A JP 1865786A JP 1865786 A JP1865786 A JP 1865786A JP H0713619 B2 JPH0713619 B2 JP H0713619B2
- Authority
- JP
- Japan
- Prior art keywords
- gas
- oxygen concentration
- electrode
- current
- concentration detection
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
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- Measuring Oxygen Concentration In Cells (AREA)
Description
【発明の詳細な説明】 技術分野 本発明はエンジン排気ガス等の気体中の酸素濃度を検出
する酸素濃度検出装置に関する。TECHNICAL FIELD The present invention relates to an oxygen concentration detection device for detecting the oxygen concentration in a gas such as engine exhaust gas.
背景技術 内燃エンジンの排気ガス浄化、燃費改善等を目的とし
て、排気ガス中の酸素濃度を検出し、この検出結果に応
じてエンジンへの供給混合気の空燃比を目標空燃比にフ
ィードバック制御する空燃比制御装置がある。BACKGROUND ART An air-fuel ratio that detects the oxygen concentration in the exhaust gas and purifies the air-fuel ratio of the air-fuel mixture supplied to the engine by feedback control to the target air-fuel ratio according to the detection results for the purpose of purifying exhaust gas from internal combustion engines and improving fuel efficiency. There is a fuel ratio control device.
このような空燃比制御装置に用いられる酸素濃度検出装
置として被測定気体中の酸素濃度に比例した出力を発生
するものがある。例えば、平板状の酸素イオン伝導性固
体電解質部材の両主面に電極対を設けて固体電解質部材
の一方の電極面が気体滞留室の一部をなしてその気体滞
留室が被測定気体と導入孔を介して連通するようにした
限界電流方式の酸素濃度検出装置が特開昭52−72286号
公報に開示されている。この酸素濃度検出装置において
は、酸素イオン伝導性固体電解質部材と電極対とが酸素
ポンプ素子として作用して間隙室側電極が負極になるよ
うに電極間に電流を供給すると、負極面側にて気体滞留
室内気体中の酸素ガスがイオン化して固体電解質部材内
を正極面側に移動し正極面から酸素ガスとして放出され
る。このときの電極間に流れ得る限界電流値は印加電圧
に拘らずほぼ一定となりかつ被測定気体中の酸素濃度に
比例するのでその限界電流値を検出すれば被測定気体中
の酸素濃度を測定することができる。しかしながら、か
かる酸素濃度検出装置を用いて空燃比を制御する場合に
排気ガス中の酸素濃度からは混合気の空燃比が理論空燃
比よりリーンの範囲でしか酸素濃度に比例した出力が得
られないので目標空燃比をリッチ領域に設定した空燃比
制御は不可能であった。また空燃比がリーン及びリッチ
領域にて排気ガス中の酸素濃度に比例した出力が得られ
る酸素濃度検出装置としては2つの平板状の酸素イオン
伝導性固体電解質部材各々に電極対を設けて2つの固体
電解質部材の一方の電極面各々が気体滞留室の一部をな
してその気体滞留室が被測定気体と導入孔を介して連通
し一方の固体電解質部材の他方の電極面が大気室に面す
るようにした装置が特開昭59−192955号に開示されてい
る。この酸素濃度検出装置においては一方の酸素イオン
伝導性固体電解質部材と電極対とが酸素濃度比検出電池
素子として作用し他方の酸素イオン伝導性固体電解質材
と電極対とが酸素ポンプ素子として作用するようになっ
ている。酸素濃度比検出電池素子の電極間の発生電圧が
基準電圧以上のとき酸素ポンプ素子内を酸素イオンが気
体滞留室側電極に向って移動するように電流を供給し、
酸素濃度比検出電池素子の電極間の発生電圧が基準電圧
以下のとき酸素ポンプ素子内を酸素イオンが気体滞留室
側とは反対側に電極に向って移動するように電流を供給
することによりリーン及びリッチ領域の空燃比において
電流値は酸素濃度に比例するのである。しかしながら、
かかる酸素濃度検出装置においては、リッチ側とリーン
側とでは酸素濃度検出特性が異なり、広領域において直
線性の良好な酸素濃度検出出力が得られないのでリッチ
側又はリーン側の酸素濃度検出出力を補正しなければな
らず空燃比制御が複雑になるという問題点があった。As an oxygen concentration detecting device used in such an air-fuel ratio control device, there is one which generates an output proportional to the oxygen concentration in the gas to be measured. For example, an electrode pair is provided on both main surfaces of a flat plate-shaped oxygen ion conductive solid electrolyte member, one electrode surface of the solid electrolyte member forms a part of a gas retention chamber, and the gas retention chamber is introduced with the gas to be measured. Japanese Patent Laid-Open No. 52-72286 discloses a limiting current type oxygen concentration detecting device which is communicated through a hole. In this oxygen concentration detection device, when the oxygen ion conductive solid electrolyte member and the electrode pair act as an oxygen pump element to supply a current between the electrodes so that the gap chamber side electrode becomes the negative electrode, the negative electrode surface side Oxygen gas in the gas in the gas retention chamber is ionized, moves inside the solid electrolyte member toward the positive electrode surface, and is released as oxygen gas from the positive electrode surface. The limiting current value that can flow between the electrodes at this time is almost constant regardless of the applied voltage and is proportional to the oxygen concentration in the gas to be measured. Therefore, if the limiting current value is detected, the oxygen concentration in the gas to be measured is measured. be able to. However, when controlling the air-fuel ratio using such an oxygen concentration detection device, an output proportional to the oxygen concentration can be obtained from the oxygen concentration in the exhaust gas only when the air-fuel ratio of the air-fuel mixture is leaner than the stoichiometric air-fuel ratio. Therefore, the air-fuel ratio control in which the target air-fuel ratio is set in the rich region was impossible. Further, as an oxygen concentration detection device that can obtain an output proportional to the oxygen concentration in the exhaust gas in the lean and rich regions of the air-fuel ratio, two flat plate-like oxygen ion conductive solid electrolyte members are provided with electrode pairs, and two electrode pairs are provided. Each one electrode surface of the solid electrolyte member forms a part of the gas retention chamber, and the gas retention chamber communicates with the gas to be measured through the introduction hole. The other electrode surface of one solid electrolyte member faces the atmosphere chamber. An apparatus adapted to do so is disclosed in Japanese Patent Laid-Open No. 192955/1984. In this oxygen concentration detecting device, one oxygen ion conductive solid electrolyte member and the electrode pair act as an oxygen concentration ratio detecting battery element, and the other oxygen ion conductive solid electrolyte material and the electrode pair act as an oxygen pump element. It is like this. When the generated voltage between the electrodes of the oxygen concentration ratio detection battery element is equal to or higher than the reference voltage, a current is supplied so that oxygen ions move in the oxygen pump element toward the gas retention chamber side electrode,
When the voltage generated between the electrodes of the oxygen concentration ratio detection battery element is equal to or lower than the reference voltage, a lean current is supplied by supplying a current in the oxygen pump element so that oxygen ions move to the side opposite to the gas retention chamber side toward the electrodes. The current value is proportional to the oxygen concentration in the air-fuel ratio in the rich region. However,
In such an oxygen concentration detection device, the oxygen concentration detection characteristics are different between the rich side and the lean side, and good oxygen concentration detection output with good linearity cannot be obtained in a wide region, so the oxygen concentration detection output on the rich side or the lean side is obtained. There is a problem that the air-fuel ratio control becomes complicated because it must be corrected.
発明の概要 そこで、本発明の目的は空燃比のリーン及びリッチ領域
に渡って良好な直線性にて酸素濃度検出出力を得ること
ができる酸素濃度検出装置を提供することである。SUMMARY OF THE INVENTION Therefore, an object of the present invention is to provide an oxygen concentration detection device capable of obtaining an oxygen concentration detection output with good linearity over lean and rich regions of the air-fuel ratio.
本発明の酸素濃度検出装置は各々が酸素イオン伝導性固
体電解質壁部を有する第1及び第2気体滞留室並びに気
体導入室を形成する基体と、第1気体滞留室の電解質壁
部の内外壁面上にこれを挟んで対向するが如く設けられ
て第1センサを形成する2つの第1電極対と、第2気体
滞留室の電解質壁部の内外壁面上にこれを挟んで対向す
るが如く設けられて第1センサとは異なる検出特性を有
する第2センサを形成する2つの第2電極対と、2つの
第1電極対の一方の電極対間に発生した電圧と第1基準
電圧との差電圧に応じた値の電流を2つの第1電極対の
他方の電極対間に供給しかつ2つの第2電極対の一方の
電極対間に発生した電圧と第2基準電圧との差電圧に応
じた値の電流を2つの第2電流対の他方の電極対間に供
給する電流供給手段とを含み、気体導入室が第1気体拡
散制限手段を介して外部に連通し第1気体滞留室に第2
気体拡散制限手段を介して連通しかつ第2気体滞留室に
第3気体拡散制限手段を介して連通し、電流供給手段に
よる供給電流値に応じた酸素濃度検出値を得ることを特
徴としている。The oxygen concentration detection device of the present invention comprises a base forming first and second gas retention chambers and a gas introduction chamber each having an oxygen ion conductive solid electrolyte wall, and inner and outer wall surfaces of the electrolyte wall of the first gas retention chamber. Two first electrode pairs which are provided so as to face each other with this sandwiched therebetween to form a first sensor, and which are provided so as to face each other with the sandwiched therebetween on the inner and outer wall surfaces of the electrolyte wall portion of the second gas retention chamber. The two second electrode pairs, which form a second sensor having a detection characteristic different from that of the first sensor, and a difference between the voltage generated between one of the two first electrode pairs and the first reference voltage. A current having a value corresponding to the voltage is supplied between the other electrode pair of the two first electrode pairs, and the difference voltage between the voltage generated between the one electrode pair of the two second electrode pairs and the second reference voltage is used. A current supply means for supplying a current of a corresponding value between the other electrode pair of the two second current pairs. Wherein the door, the second to the first gas residence chamber communicates with the outside air introduction chamber through the first gas diffusion limiting means
It is characterized in that the oxygen concentration detection value corresponding to the supply current value by the current supply means is obtained by communicating through the gas diffusion restriction means and communicating with the second gas retention chamber through the third gas diffusion restriction means.
実 施 例 以下、本発明の実施例を図面を参照しつつ説明する。Embodiments Embodiments of the present invention will be described below with reference to the drawings.
第1図及び第2図は本発明による酸素濃度検出装置を用
いた空燃比制御装置を示している。本装置においては、
ほぼ立方体状の酸素イオン伝導性固体電解質部材1が設
けられている。酸素イオン伝導性固体電解質部材1内に
は第1及び第2気体滞留室2,3並びに気体導入室4が形
成されている。気体導入室4は固体電解質部材1外部か
ら被測定気体の排気ガスを導入する導入孔5に連通し、
導入孔5は内燃エンジンの排気管(図示せず)内におい
て排気ガスが気体導入室4に流入し易いように位置され
る。気体導入室4と第1及び第2気体滞留室2,3との間
の各壁部には連通孔6,7が形成されている。連通孔6の
径は連通孔7の径よりも大きくされている。第1気体滞
留室2には排気ガスが導入孔5、気体導入室4、そして
連通孔6を介して導入されるようになっており、また第
2気体滞留室3には排気ガスが導入孔5、気体導入室
4、そして連通孔7を介して導入されるようになってい
る。酸素イオン伝導性固体電解質部材1には外気等を導
入する参照気体室8が第1及び第2気体滞留室2,3と壁
を隔てるように形成されている。第1気体滞留室2と気
体導入室4との間の壁部及び第1気体滞留室2と参照気
体室8との間の壁部には電極対11a,11b,12a,12bが各々
形成され、また第2気体滞留室3と気体導入室4との間
の壁部及び第2気体滞留室3と参照気体室8との間の壁
部には電極対13a,13b,14a,14bが各々形成されている。
電極対11a,11bは中央部に連通孔6に連通する貫通孔を
有し、電極対13a,13bも中央部に連通孔7に連通する貫
通孔を有している。固体電解質部材1及び電極対11a,11
bが第1酸素ポンプ素子15として、固体電解質部材1及
び電極対12a,12bが第1電池素子16として各々作用す
る。また固体電解質部材1及び電極対13a,13bが第2電
池素子17として、固体電解質部材1及び電極対14a,14b
が第2電池素子18として各々作用する。また固体電解質
部材1の気体導入室4の外壁面及び参照気体室8の外壁
面にヒータ素子19,20が各々設けられている。ヒータ素
子19,20は電気的に互いに並列に接続されており、第1
及び第2酸素ポンプ素子15,17並びに第1及び第2電池
素子16,18を均等に加熱すると共に固体電解質部材1内
の保温性の向上を図っている。なお、酸素イオン伝導性
固体電解質部材1は複数の断片から一体に形成される。
また第1及び第2気体滞留室の壁部を全て酸素イオン伝
導性固体電解質から形成する必要はなく、少なくとも電
極対を設ける部分だけがその固体電解質からなれば良
い。1 and 2 show an air-fuel ratio control device using an oxygen concentration detection device according to the present invention. In this device,
An oxygen ion conductive solid electrolyte member 1 having a substantially cubic shape is provided. First and second gas retention chambers 2 and 3 and a gas introduction chamber 4 are formed in the oxygen ion conductive solid electrolyte member 1. The gas introduction chamber 4 communicates with an introduction hole 5 for introducing the exhaust gas of the gas to be measured from outside the solid electrolyte member 1,
The introduction hole 5 is located in the exhaust pipe (not shown) of the internal combustion engine so that the exhaust gas can easily flow into the gas introduction chamber 4. Communication holes 6 and 7 are formed in each wall portion between the gas introduction chamber 4 and the first and second gas retention chambers 2 and 3. The diameter of the communication hole 6 is larger than the diameter of the communication hole 7. Exhaust gas is introduced into the first gas retention chamber 2 through the introduction hole 5, the gas introduction chamber 4, and the communication hole 6, and the exhaust gas is introduced into the second gas retention chamber 3 through the introduction hole. 5, the gas introduction chamber 4, and the communication hole 7 are introduced. The oxygen ion conductive solid electrolyte member 1 is formed with a reference gas chamber 8 for introducing outside air or the like so as to separate the walls from the first and second gas retention chambers 2 and 3. Electrode pairs 11a, 11b, 12a, 12b are formed on the wall between the first gas retention chamber 2 and the gas introduction chamber 4 and on the wall between the first gas retention chamber 2 and the reference gas chamber 8, respectively. Further, electrode pairs 13a, 13b, 14a, 14b are provided on the wall between the second gas retention chamber 3 and the gas introduction chamber 4 and on the wall between the second gas retention chamber 3 and the reference gas chamber 8, respectively. Has been formed.
The electrode pair 11a, 11b has a through hole communicating with the communication hole 6 at the center, and the electrode pair 13a, 13b also has a through hole communicating with the communication hole 7 at the center. Solid electrolyte member 1 and electrode pair 11a, 11
b serves as the first oxygen pump element 15, and the solid electrolyte member 1 and the electrode pairs 12a and 12b serve as the first battery element 16. In addition, the solid electrolyte member 1 and the electrode pairs 13a and 13b are used as the second battery element 17, and the solid electrolyte member 1 and the electrode pairs 14a and 14b are used.
Respectively function as the second battery elements 18. Further, heater elements 19 and 20 are provided on the outer wall surface of the gas introduction chamber 4 and the outer wall surface of the reference gas chamber 8 of the solid electrolyte member 1, respectively. The heater elements 19 and 20 are electrically connected in parallel to each other, and
Also, the second oxygen pump elements 15 and 17 and the first and second battery elements 16 and 18 are heated uniformly, and the heat retention in the solid electrolyte member 1 is improved. The oxygen ion conductive solid electrolyte member 1 is integrally formed from a plurality of pieces.
Further, it is not necessary to form all the wall portions of the first and second gas retention chambers from the oxygen ion conductive solid electrolyte, and it suffices that at least the portion where the electrode pair is provided be formed of the solid electrolyte.
酸素イオン伝導性固体電解質部材1としては、ZrO2(二
酸化ジルコニウム)が用いられ、電極11aないし14bとさ
てはPt(白金)が用いられる。ZrO 2 (zirconium dioxide) is used as the oxygen ion conductive solid electrolyte member 1, and Pt (platinum) is used as the electrodes 11a to 14b.
第1及び第2酸素ポンプ素子15,17並びに第1及び第2
電池素子16,18には電流供給回路21が接続されている。
第2図に示すように電流供給回路21は差動増幅回路22,2
3,電流検出抵抗24,25,基準電圧源26,27及び切替回路28,
29からなる。第1酸素ポンプ素子15の外側電極11aは切
替回路28のスイッチ28a、電流検出抵抗24を介して差動
増幅回路22の出力端に接続され、内側電極11bは切替回
路29のスイッチ29aを介してアースされるようになって
いる。第1電池素子16の外側電極12aは差動増幅回路22
の反転入力端に接続され、内側電極12bは切替回路29の
スイッチ29bを介してアースされるようになっている。
同様に第2酸素ポンプ素子17の外側電極13aは切替回路2
8のスイッチ28b、電流検出抵抗25を介して差動増幅回路
23の出力端に接続され、内側電極13bは切替回路29のス
イッチ29aを介してアースされるようになっている。第
2電池素子18の外側電極14aは差動増幅回路23の反転入
力端に接続され、内側電極14bは切替回路29のスイッチ2
9bを介してアースされるようになっている。差動増幅回
路22の非反転入力端には基準電圧源26が接続され、差動
増幅回路23の非反転入力端には基準電圧源27が接続され
ている。基準電圧源26,27の出力電圧は理論空燃比に相
当する電圧(例えば、0.4V)である。電流検出抵抗24の
両端間が第1センサの出力をなし、電流検出抵抗25の両
端間が第2センサの出力をなしている。電流検出抵抗2
4,25の両端電圧は差動入力のA/D変換器31を介して空燃
比制御回路32に供給され、電流検出抵抗24,25を流れる
ポンプ電流値IP(1)、IP(2)が空燃比制御回路32に
読み込まれる。空燃比制御回路32はマイクロコンピュー
タからなる。空燃比制御回路32にはエンジン回転数、吸
気管内絶対圧、冷却水温等を検出する複数の運転パラメ
ータ検出センサ(図示せず)が接続されると共に、また
駆動回路33を介して電磁弁34が接続されている。電磁弁
34はエンジン気化器絞り弁下流の吸気マニホールド内に
連通する吸気2次空気供給通路(図示せず)に設けられ
ている。また空燃比制御回路32は切替回路28,29のスイ
ッチ切替動作を制御し、空燃比制御回路32からの指令に
応じて駆動回路30が切替回路28,29を駆動する。なお、
差動増幅回路22,23には正負の電源電圧が供給される。First and second oxygen pump elements 15, 17 and first and second
A current supply circuit 21 is connected to the battery elements 16 and 18.
As shown in FIG. 2, the current supply circuit 21 includes a differential amplifier circuit 22,2.
3, current detection resistors 24, 25, reference voltage sources 26, 27 and switching circuit 28,
It consists of 29. The outer electrode 11a of the first oxygen pump element 15 is connected to the output end of the differential amplifier circuit 22 via the switch 28a of the switching circuit 28 and the current detection resistor 24, and the inner electrode 11b is connected to the switch 29a of the switching circuit 29. It is designed to be grounded. The outer electrode 12a of the first battery element 16 is a differential amplifier circuit 22.
The inner electrode 12b is connected to the inverting input end of the switch and is grounded via the switch 29b of the switching circuit 29.
Similarly, the outer electrode 13a of the second oxygen pump element 17 is connected to the switching circuit 2
Differential amplifier circuit via switch 28b of 8 and current detection resistor 25
The inner electrode 13b is connected to the output terminal of 23 and is grounded via the switch 29a of the switching circuit 29. The outer electrode 14a of the second battery element 18 is connected to the inverting input terminal of the differential amplifier circuit 23, and the inner electrode 14b is connected to the switch 2 of the switching circuit 29.
It is designed to be grounded via 9b. A reference voltage source 26 is connected to the non-inverting input terminal of the differential amplifier circuit 22, and a reference voltage source 27 is connected to the non-inverting input terminal of the differential amplifier circuit 23. The output voltage of the reference voltage sources 26, 27 is a voltage (for example, 0.4 V) corresponding to the stoichiometric air-fuel ratio. Both ends of the current detection resistor 24 form an output of the first sensor, and both ends of the current detection resistor 25 form an output of the second sensor. Current detection resistor 2
The voltage between both ends of 4,25 is supplied to the air-fuel ratio control circuit 32 via the A / D converter 31 of the differential input, and the pump current values I P (1), I P (2 ) Is read into the air-fuel ratio control circuit 32. The air-fuel ratio control circuit 32 is composed of a microcomputer. The air-fuel ratio control circuit 32 is connected to a plurality of operating parameter detection sensors (not shown) for detecting the engine speed, the absolute pressure in the intake pipe, the cooling water temperature, etc., and the solenoid valve 34 is connected via the drive circuit 33. It is connected. solenoid valve
34 is provided in an intake secondary air supply passage (not shown) communicating with the intake manifold downstream of the engine carburetor throttle valve. Further, the air-fuel ratio control circuit 32 controls the switch switching operation of the switching circuits 28, 29, and the drive circuit 30 drives the switching circuits 28, 29 in response to a command from the air-fuel ratio control circuit 32. In addition,
Positive and negative power supply voltages are supplied to the differential amplifier circuits 22 and 23.
一方、ヒータ素子19,20には電流がヒータ電流供給回路3
5から供給されてヒータ素子19,20が発熱して酸素ポンプ
素子15,17及び電池素子16,18を排気ガスより高い適温に
加熱する。On the other hand, a current is supplied to the heater elements 19 and 20 by the heater current supply circuit 3
When supplied from 5, the heater elements 19 and 20 generate heat to heat the oxygen pump elements 15 and 17 and the battery elements 16 and 18 to an appropriate temperature higher than the exhaust gas.
かかる構成においては、排気管内の排気ガスが導入孔5
から気体導入室4内に流入して拡散し、更に連通孔6を
介して第1気体滞留室2内に流入して拡散すると共に連
通孔7を介して第2気体滞留室3内に流入して拡散す
る。In such a configuration, the exhaust gas in the exhaust pipe is introduced into the introduction hole 5
Flow into the gas introduction chamber 4 to diffuse, further flow into the first gas retention chamber 2 via the communication hole 6 to diffuse, and flow into the second gas retention chamber 3 via the communication hole 7. Spread.
切替回路28,29において、第2図の如くスイッチ28aが電
極11aを電流検出抵抗24に接続し、スイッチ28bが電極13
aの接続ラインを開放し、スイッチ29aが電極11bをアー
スしかつ電極13bの接続ラインを開放し、またスイッチ2
9bが電極12bをアースしかつ電極14bの接続ラインを開放
する選択位置にされると、第1センサの選択状態にな
る。In the switching circuits 28 and 29, the switch 28a connects the electrode 11a to the current detection resistor 24 and the switch 28b connects the electrode 13 as shown in FIG.
The connection line of a is opened, switch 29a grounds electrode 11b and opens the connection line of electrode 13b, and switch 2a
When 9b is placed in the selected position to ground electrode 12b and open the connection line of electrode 14b, the first sensor is in the selected state.
この第1センサの選択状態には、先ず、エンジン供給混
合気の空燃比がリーン領域のときには差動増幅回路22の
出力レベルが正レベルになり、この正レベル電圧が抵抗
24及び第1酸素ポンプ素子15の直列回路に供給される。
よって、第1酸素ポンプ素子15の電極11a,11b間にポン
プ電流が流れる。このポンプ電流は電極11aから電極11b
に向って流れるので第1気体滞留室2内の酸素が電極11
bにてイオン化して第1酸素ポンプ素子15内を移動して
電極11aから酸素ガスとして放出され、第1気体滞留室
2内の酸素が汲み出される。In the selected state of the first sensor, first, when the air-fuel ratio of the engine-supplied air-fuel mixture is in the lean region, the output level of the differential amplifier circuit 22 becomes a positive level, and this positive-level voltage is the resistance.
24 and the first oxygen pump element 15 are supplied to the series circuit.
Therefore, the pump current flows between the electrodes 11a and 11b of the first oxygen pump element 15. This pump current flows from electrode 11a to electrode 11b.
The oxygen in the first gas retention chamber 2 flows toward the electrode 11
At b, it is ionized, moves inside the first oxygen pump element 15, is released as oxygen gas from the electrode 11a, and oxygen in the first gas retention chamber 2 is pumped out.
第1気体滞留室2内の酸素の汲み出しにより第1気体滞
留室2内の排気ガスと参照気体室8内の気体の間に酸素
濃度差が生ずる。この酸素濃度差によって電池素子16の
電極12a,12b間に電圧Vsが発生する。この電圧Vsは差動
増幅回路22の反転入力端に供給される。差動増幅回路22
の出力電圧は電圧Vsと基準電圧源26の出力電圧Vr1との
差電圧に比例した電圧となるのでポンプ電流値は排気ガ
ス中の酸素濃度に比例する。By pumping out oxygen in the first gas retention chamber 2, an oxygen concentration difference occurs between the exhaust gas in the first gas retention chamber 2 and the gas in the reference gas chamber 8. Due to this difference in oxygen concentration, a voltage Vs is generated between the electrodes 12a and 12b of the battery element 16. This voltage Vs is supplied to the inverting input terminal of the differential amplifier circuit 22. Differential amplifier circuit 22
Since the output voltage of is equal to the voltage difference between the voltage Vs and the output voltage Vr 1 of the reference voltage source 26, the pump current value is proportional to the oxygen concentration in the exhaust gas.
リッチ領域の空燃比のときには電圧Vsが基準電圧源26の
出力電圧Vr1を越える。よって、差動増幅回路22の出力
レベルが正レベルから負レベルに反転する。この負レベ
ルにより第1酸素ポンプ素子15の電極11a,11b間に流れ
るポンプ電流が減少し、電流方向が反転する。すなわ
ち、ポンプ電流は電極11bから電極11a方向に流れるので
外部の酸素が電極11aにてイオン化して第1酸素ポンプ
素子15内を移動して電極11bから酸素ガスとして第1気
体滞留室2内に放出され、酸素が第1気体滞留室2内に
汲み込まれる。従って、第1気体滞留室2内の酸素濃度
が常に一定になるようにポンプ電流を供給することによ
り酸素を汲み込んだり、汲み出したりするのでポンプ電
流値IP及び差動増幅回路22の出力電圧はリーン及びリッ
チ領域にて排気ガス中の酸素濃度に各々比例するのであ
る。第3図の実線aはそのポンプ電流値IPを示してい
る。When the air-fuel ratio is in the rich region, the voltage Vs exceeds the output voltage Vr 1 of the reference voltage source 26. Therefore, the output level of the differential amplifier circuit 22 is inverted from the positive level to the negative level. Due to this negative level, the pump current flowing between the electrodes 11a and 11b of the first oxygen pump element 15 decreases and the current direction is reversed. That is, since the pump current flows from the electrode 11b to the electrode 11a, the external oxygen is ionized at the electrode 11a and moves in the first oxygen pump element 15 to move from the electrode 11b into the first gas retention chamber 2 as oxygen gas. It is released and oxygen is pumped into the first gas retention chamber 2. Accordingly, the pump current is pumped in and out by supplying the pump current so that the oxygen concentration in the first gas retention chamber 2 is always constant, so that the pump current value I P and the output voltage of the differential amplifier circuit 22. Is proportional to the oxygen concentration in the exhaust gas in the lean and rich regions, respectively. A solid line a in FIG. 3 shows the pump current value I P.
ポンプ電流値IPは電荷をe、導入孔5及び連通孔6によ
る排気ガスに対する拡散係数をσO、排気ガス中の酸素
濃度をPOexh、第1気体滞留室2内の酸素濃度をPOvとす
ると、次式の如くで表わすことができる。The pump current value I P is e, the diffusion coefficient for the exhaust gas through the introduction hole 5 and the communication hole 6 is σ O , the oxygen concentration in the exhaust gas is P O exh, and the oxygen concentration in the first gas retention chamber 2 is P O exh. If O v, it can be expressed by the following equation.
IP=4eσO(POexh−POv) ……(1) ここで、拡散係数σOは導入孔5の面積をA1、連通孔6
の面積をA2、ボルツマン定数をk、絶対温度をT、導入
孔5の長さをl1、連通孔6の長さをl2、拡散定数をDと
すると、次式の如く表わすことができる。I P = 4eσ O (P O exh−P O v) (1) where the diffusion coefficient σ O is the area of the introduction hole 5 is A 1 and the communication hole 6 is 6.
Where A 2 is the area, Boltzmann's constant is k, absolute temperature is T, the length of the introduction hole 5 is l 1 , the length of the communicating hole 6 is l 2 and the diffusion constant is D, the following equation can be expressed. it can.
σO=(A1/l1+A2/l2)D/kT ……(2) 次に、スイッチ28aが電極11aの接続ラインを開放し、ス
イッチ28bが電極13aを電流検出抵抗25に接続し、スイッ
チ29aが電極13bをアースしかつ電極11bの接続ラインを
開放し、またスイッチ29bが電極14bをアースしかつ電極
12bの接続ラインを開放する選択位置にされると、第2
センサの選択状態となる。σ O = (A 1 / l 1 + A 2 / l 2 ) D / kT (2) Next, the switch 28a opens the connection line of the electrode 11a, and the switch 28b connects the electrode 13a to the current detection resistor 25. Switch 29a grounds electrode 13b and opens the connection line of electrode 11b, and switch 29b grounds electrode 14b and the electrode
Once in the selected position to open the 12b connection line, the second
The sensor is selected.
この第2センサの選択状態には上記した第1センサの選
択状態と同様の動作により第2気体滞留室3内の酸素濃
度が常に一定になるようにポンプ電流が第2酸素ポンプ
素子17の電極13a,13b間に供給されて酸素が汲み込まれ
たり、汲み出されたりするのでポンプ電流値IP及び差動
増幅回路23の出力電圧はリーン及びリッチ領域にて排気
ガス中の酸素濃度に各々比例するのである。この第2セ
ンサ選択状態のポンプ電流値IPは上記した式(1)にお
いて拡散係数σOを導入孔5及び連通孔7によるものと
し、またPOvを第2気体滞留室3内の酸素濃度とするこ
とにより表わされる。ポンプ電流値IPの大きさは第4図
に示すように空燃比のリーン及びリッチ領域において拡
散係数σOの大きさに反比例する拡散抵抗が大きくなる
ほど小さくなることが明らかになっている。よって、第
2センサ選択状態には第1センサ選択状態よりも拡散抵
抗が大となるので第3図の破線bの如くポンプ電流値IP
の大きさはリーン及びリッチ領域において小さくなり、
連通孔7の大きさ及び長さを調整することにより第3図
に示すように第2センサ選択状態におけるリッチ領域の
ポンプ電流値特性が第1センサ選択状態におけるリーン
領域のポンプ領域値特性にIP=0にて直線的に連続する
のである。また差動増幅回路22,23の出力電圧特性も0
〔V〕にて直線的に連続したものになる。In the selected state of the second sensor, the pump current is the electrode of the second oxygen pump element 17 so that the oxygen concentration in the second gas retention chamber 3 is always constant by the same operation as the selected state of the first sensor described above. Oxygen is supplied to between 13a and 13b, and oxygen is pumped in or pumped out. Therefore, the pump current value I P and the output voltage of the differential amplifier circuit 23 are different from the oxygen concentration in the exhaust gas in the lean and rich regions, respectively. It is proportional. In the pump current value I P in the second sensor selected state, the diffusion coefficient σ O in the above equation (1) is determined by the introduction hole 5 and the communication hole 7, and P O v is the oxygen in the second gas retention chamber 3. It is represented by the concentration. It has been clarified that the magnitude of the pump current value I P becomes smaller as the diffusion resistance inversely proportional to the magnitude of the diffusion coefficient σ O becomes larger in the lean and rich regions of the air-fuel ratio as shown in FIG. Therefore, in the second sensor selection state, the diffusion resistance becomes larger than in the first sensor selection state, so that the pump current value I P becomes as shown by the broken line b in FIG.
Becomes smaller in the lean and rich regions,
By adjusting the size and length of the communication hole 7, as shown in FIG. 3, the pump current value characteristic in the rich region in the second sensor selected state becomes I in the lean region in the first sensor selected state. It is linearly continuous at P = 0. The output voltage characteristics of the differential amplifier circuits 22 and 23 are also 0.
It becomes linearly continuous at [V].
このように直線的に連続した出力特性を得るために空燃
比制御回路32は次の如く動作する。空燃比制御回路32は
第5図に示すように先ず、第1及び第2センサの選択状
態を表わすフラグFsが“1"であるか否かを判別する(ス
テップ51)。Fs=0の場合、第1センサ選択状態にある
のでA/D変換器31から出力される第1センサのポンプ電
流値IP(1)を読み込んでそのポンプ電流値IP(1)に
対応する酸素濃度検出出力値LO2が差動増幅回路22の出
力電圧Vs1の0〔V〕に対応する基準値Lref0以上であ
るか否かを判別する(ステップ52)。LO2≧Lref0(Vs1
≧0)ならば、リーン領域であるので第1センサ選択状
態が継続され、LO2<Lref0(Vs1<0)ならば、リッチ
領域であるので第2センサ選択指令を駆動回路30に対し
て発生し(ステップ53)、第2センサが選択されたこと
を表わすためにフラグFsに“1"がセットされる(ステッ
プ54)。一方、Fs=1の場合、第2センサ選択状態にあ
るのでA/D変換器31から出力される第2センサのポンプ
電流値IP(2)を読み込んでそのポンプ電流値IP(2)
に対応する酸素濃度検出出力値LO2が差動増幅回路23の
出力電圧Vs2の0〔V〕に対応する基準値Lref0以上で
あるか否かを判別する(ステップ55)。LO2≦Lref0(V
s1≦0)ならば、リッチ領域であるので第2センサ選択
状態が継続され、LO2>Lref0(Vs2>0)ならば、リー
ン領域であるので第1センサ選択指令を駆動回路30に対
して発生し(ステップ56)、第1センサが選択されたこ
とを表わすためにフラグFsに“0"がセットされる(ステ
ップ57)。駆動回路30は第1センサ選択指令に応じてス
イッチ28a,28b,29a,29bを上記した第1センサ選択位置
に駆動し、その駆動状態は第2センサ選択指令が空燃比
制御回路32から供給されるまで維持される。また第2セ
ンサ選択指令に応じてスイッチ28a,28b,29a,29bを上記
した第2センサ選択位置に駆動し、その駆動状態は第1
センサ選択指令が空燃比制御回路32から供給されるまで
維持される。このように第1又は第2センサを選択する
と、空燃比制御回路32はA/D変換器31から出力される第
1又は第2センサの酸素濃度検出出力値LO2が目標空燃
比に対応する目標値Lrefより大であるか否かを判別す
る(ステップ58)。LO2≦Lrefならば、供給混合気の空
燃比がリッチであるので駆動回路33に対して電磁弁34の
開弁駆動指令を発生し(ステップ59)、LO2>Lrefなら
ば、供給混合気の空燃比がリーンであるので駆動回路33
に対して電磁弁34の開弁駆動停止指令を発生する(ステ
ップ60)。駆動回路33は開弁駆動指令に応じて電磁弁34
を開弁駆動して2次空気をエンジン吸気マニホールド内
に供給することにより空燃比をリーン化させ、開弁駆動
停止指令に応じて電磁弁34の開弁駆動を停止して空燃比
をリッチ化させる。かかる動作を所定周期毎に繰り返し
実行することにより供給混合気の空燃比を目標空燃比に
制御するのである。なお、ステップ52,55においては基
準値Lref0、すなわち電圧Vs1、Vs2の判別基準電圧が共
に0〔V〕に設定されているが、ヒステリシスを持たせ
るために電圧Vs1の判別基準電圧を0〔V〕より若干小
さく設定し、電圧Vs2の判別基準電圧を0〔V〕より若
干大きく設定しても良い。The air-fuel ratio control circuit 32 operates as follows to obtain the linearly continuous output characteristic. As shown in FIG. 5, the air-fuel ratio control circuit 32 first determines whether or not the flag Fs indicating the selection state of the first and second sensors is "1" (step 51). When Fs = 0, the first sensor is in the selected state, so the pump current value I P (1) of the first sensor output from the A / D converter 31 is read to correspond to the pump current value I P (1). It is determined whether the oxygen concentration detection output value L O2 is greater than or equal to a reference value L ref0 corresponding to 0 [V] of the output voltage Vs 1 of the differential amplifier circuit 22 (step 52). L O2 ≧ Lref 0 (Vs 1
≧ 0), the first sensor selection state is continued because it is in the lean region, and when L O2 <Lref0 (Vs 1 <0), it is in the rich region and therefore the second sensor selection command is issued to the drive circuit 30. If so (step 53), the flag Fs is set to "1" to indicate that the second sensor has been selected (step 54). On the other hand, in the case of Fs = 1, the pump current value of the second sensor output from the A / D converter 31 because the second sensor selection state I P (2) and Loading the pumping current I P (2)
It is determined whether or not the oxygen concentration detection output value L O2 corresponding to is greater than or equal to the reference value L ref0 corresponding to 0 [V] of the output voltage Vs 2 of the differential amplifier circuit 23 (step 55). L O2 ≤ Lref0 (V
If s 1 ≦ 0), the second sensor selection state is continued because it is in the rich region, and if L O2 > Lref0 (Vs 2 > 0), it is in the lean region and therefore the first sensor selection command is sent to the drive circuit 30. Occurs (step 56) and the flag Fs is set to "0" to indicate that the first sensor has been selected (step 57). The drive circuit 30 drives the switches 28a, 28b, 29a, 29b to the above-mentioned first sensor selection position in response to the first sensor selection command, and the driving state is such that the second sensor selection command is supplied from the air-fuel ratio control circuit 32. Maintained until Further, the switches 28a, 28b, 29a, 29b are driven to the above-mentioned second sensor selection position in response to the second sensor selection command, and the driving state is the first
It is maintained until the sensor selection command is supplied from the air-fuel ratio control circuit 32. When the first or second sensor is selected in this way, the air-fuel ratio control circuit 32 causes the oxygen concentration detection output value L O2 of the first or second sensor output from the A / D converter 31 to correspond to the target air-fuel ratio. It is determined whether or not it is larger than the target value Lref (step 58). If L O2 ≤Lref, the air-fuel ratio of the supply air-fuel mixture is rich, so a command to open the solenoid valve 34 is issued to the drive circuit 33 (step 59). If L O2 > Lref, the supply air-fuel mixture is supplied. Since the air-fuel ratio of is lean, the drive circuit 33
To the solenoid valve 34 is generated (step 60). The drive circuit 33 operates the solenoid valve 34 in response to the valve opening drive command.
Is opened to supply secondary air into the engine intake manifold to make the air-fuel ratio lean, and the valve-opening drive of the solenoid valve 34 is stopped in response to the valve-opening stop command to enrich the air-fuel ratio. Let The air-fuel ratio of the supply air-fuel mixture is controlled to the target air-fuel ratio by repeatedly performing this operation every predetermined period. In steps 52 and 55, the reference value Lref0, that is, the discrimination reference voltage of the voltages Vs 1 and Vs 2 is set to 0 [V], but the discrimination reference voltage of the voltage Vs 1 is set to have hysteresis. It may be set to be slightly smaller than 0 [V], and the determination reference voltage of the voltage Vs 2 may be set to be slightly larger than 0 [V].
上記した本発明の実施例においては、第1ないし第3気
体拡散制限手段として導入孔5,連通孔6,7が用いられて
おり、連通孔6,7によって異なる拡散抵抗が各々得られ
ているが、これに限らず、異なる拡散抵抗を得るために
連通孔6,7の径を等しくしかつ第1気体滞留室2内の2
つの第1電極対間及び第2気体滞留室3内の2つの第2
電極対間のギャップを各々形成しそのギャップ幅を異な
らしても良く、また第6図に示すようにアルミナ(Al2O
3)等の多孔質体38,39,40を導入孔5及び連通孔6,7に充
填し多孔質拡散層を形成しても良いのである。In the embodiment of the present invention described above, the introduction hole 5 and the communication holes 6 and 7 are used as the first to third gas diffusion limiting means, and different diffusion resistances are obtained by the communication holes 6 and 7, respectively. However, not limited to this, in order to obtain different diffusion resistances, the diameters of the communication holes 6 and 7 are made equal, and 2 in the first gas retention chamber 2 is used.
Two second electrodes between the two first electrode pairs and in the second gas retention chamber 3
It is possible to form gaps between the electrode pairs and make the gap widths different, and as shown in FIG. 6, alumina (Al 2 O 3
The porous body 38, 39, 40 such as 3 ) may be filled in the introduction hole 5 and the communication holes 6, 7 to form a porous diffusion layer.
また、上記した本発明の実施例においては、第1又は第
2センサの出力に応じて2次空気を供給することにより
供給混合気の空燃比を目標空燃比に制御しているが、こ
れに限らず、第1又は第2センサの出力に応じて燃料供
給量を調整することにより空燃比を制御しても良い。Further, in the above-described embodiment of the present invention, the air-fuel ratio of the supply air-fuel mixture is controlled to the target air-fuel ratio by supplying the secondary air according to the output of the first or second sensor. However, the air-fuel ratio may be controlled by adjusting the fuel supply amount according to the output of the first or second sensor.
発明の効果 以上の如く、本発明の酸素濃度検出装置においては、排
気ガス等の被測定気体が第1気体拡散制限手段を介して
流入する気体導入室と、該気体導入室に第2又は第3気
体拡散制限手段を介して連通しかつ流入気体に対する拡
散抵抗が異なる第1及び第2気体滞留室とを設け、第1
及び第2気体滞留室各々の電解質壁部の内外壁面上にこ
れを挟んで対向するが如く第1及び第2電極対を設けて
例えば、各気体拡散制限手段による拡散抵抗を調整する
ことにより互いに異なる酸素濃度検出特性を有する第1
及び第2センサを得たので、リーン及びリッチの広い領
域において被測定気体中の酸素濃度に比例したリニアリ
ティの良好な酸素濃度検出出力特性を得ることができ
る。よって、酸素濃度検出出力を補正する必要がなく空
燃比制御が容易となり、空燃比制御精度の向上が図れる
のである。EFFECTS OF THE INVENTION As described above, in the oxygen concentration detecting device of the present invention, the gas to be measured such as exhaust gas flows in via the first gas diffusion limiting means, and the second or the second gas introducing chamber. The first and second gas retention chambers that communicate with each other through the three gas diffusion limiting means and have different diffusion resistances to the inflow gas are provided.
The first and second electrode pairs are provided so as to face each other on the inner and outer wall surfaces of the electrolyte wall portion of each of the second and second gas retention chambers so as to oppose each other, for example, by adjusting the diffusion resistance by each gas diffusion limiting means. First with different oxygen concentration detection characteristics
Since the second sensor is obtained, it is possible to obtain an oxygen concentration detection output characteristic with a good linearity proportional to the oxygen concentration in the gas to be measured in a wide lean and rich region. Therefore, it is not necessary to correct the oxygen concentration detection output, the air-fuel ratio control becomes easy, and the accuracy of the air-fuel ratio control can be improved.
第1図(a)は本発明による酸素濃度検出装置の実施例
を示す平面図、第1図(b)は第1図(a)のI b−I b
部分の断面図、第2図は空燃比制御装置を含む電流供給
回路を示す回路図、第3図は第1図の装置の出力特性を
示す図、第4図は拡散抵抗とポンプ電流値との関係を示
す特性図、第5図は空燃比制御回路の動作を示すフロー
図、第6図(a)は本発明の他の実施例を示す平面図、
第6図(b)は第6図(a)のVI b−VI b部分の断面図
である。 主要部分の符号の説明 1……酸素イオン伝導性固体電解質部材 2,3……気体滞留室 4……気体導入室 5……導入孔 6,7……連通孔 8……気体参照室 15,17……酸素ポンプ素子 16,18……電池素子 19,20……ヒータ素子 21……電流供給回路FIG. 1 (a) is a plan view showing an embodiment of the oxygen concentration detection device according to the present invention, and FIG. 1 (b) is Ib-Ib of FIG. 1 (a).
A sectional view of a portion, FIG. 2 is a circuit diagram showing a current supply circuit including an air-fuel ratio control device, FIG. 3 is a diagram showing output characteristics of the device of FIG. 1, and FIG. 4 is a diffusion resistance and a pump current value. 5 is a flow chart showing the operation of the air-fuel ratio control circuit, FIG. 6 (a) is a plan view showing another embodiment of the present invention,
FIG. 6 (b) is a sectional view of a VIb-VIb portion of FIG. 6 (a). Explanation of symbols of main parts 1 …… Oxygen ion conductive solid electrolyte member 2,3 …… Gas retention chamber 4 …… Gas introduction chamber 5 …… Introduction hole 6,7 …… Communication hole 8 …… Gas reference chamber 15, 17 …… Oxygen pump element 16,18 …… Battery element 19,20 …… Heater element 21 …… Current supply circuit
Claims (4)
有する第1及び第2気体滞留室並びに気体導入室を形成
する基体と、 前記第1気体滞留室の電解質壁部の内外壁面上にこれを
挟んで対向するが如く設けられて第1センサを形成する
2つの第1電極対と、 前記第2気体滞留室の電解質壁部の内外壁面上にこれを
挟んで対向するが如く設けられて前記第1センサとは異
なる酸素濃度検出特性を有する第2センサを形成する2
つの第2電極対と、 前記2つの第1電極対の一方の電極対間に発生した電圧
と第1基準電圧との差電圧に応じた値の電流を前記2つ
の第1電極対の他方の電極対間に供給しかつ前記2つの
第2電極対の一方の電極対間に発生した電圧と第2基準
電圧との差電圧に応じた値の電流を前記2つの第2電極
対の他方の電極対間に供給する電流供給手段とを含み、 前記気体導入室が第1気体拡散制限手段を介して外部に
連通し前記第1気体滞留室に第2気体拡散制限手段を介
して連通しかつ前記第2気体滞留室に第3気体拡散制限
手段を介して連通し、前記電流供給手段による供給電流
値に応じた酸素濃度検出値を得ることを特徴とする酸素
濃度検出装置。1. A substrate forming first and second gas retention chambers and a gas introduction chamber each having an oxygen ion conductive solid electrolyte wall, and on the inner and outer wall surfaces of the electrolyte wall of the first gas retention chamber. Two first electrode pairs that are provided so as to face each other with this sandwiched therebetween to form a first sensor, and are provided so as to face each other on the inner and outer wall surfaces of the electrolyte wall portion of the second gas retention chamber with this sandwiched therebetween. Forming a second sensor having an oxygen concentration detection characteristic different from that of the first sensor 2
Two second electrode pairs, and a current having a value corresponding to a difference voltage between a voltage generated between one of the two first electrode pairs and the first reference voltage is applied to the other of the two first electrode pairs. A current having a value corresponding to a difference voltage between a voltage generated between one electrode pair of the two second electrode pairs and a second reference voltage is supplied to the other electrode pair of the two second electrode pairs. An electric current supply means for supplying between the pair of electrodes, the gas introducing chamber communicates with the outside through a first gas diffusion limiting means, and communicates with the first gas retention chamber through a second gas diffusion limiting means, and An oxygen concentration detection device, which communicates with the second gas retention chamber via a third gas diffusion limiting means, and obtains an oxygen concentration detection value according to a supply current value by the current supply means.
らなり、前記第3気体拡散制限手段は前記第1連通孔と
大きさが異なる第2連通孔からなることを特徴とする特
許請求の範囲第1項記載の酸素濃度検出装置。2. The second gas diffusion limiting means comprises a first communicating hole, and the third gas diffusion limiting means comprises a second communicating hole having a size different from that of the first communicating hole. The oxygen concentration detection device according to claim 1.
間のギャップ幅と前記第2気体滞留室内の2つの第2電
極対間のギャップ幅とが異なることを特徴とする特許請
求の範囲第1項記載の酸素濃度検出装置。3. A gap width between two first electrode pairs in the first gas retention chamber and a gap width between two second electrode pairs in the second gas retention chamber are different from each other. 2. An oxygen concentration detector according to claim 1.
応じて前記他方の第1電極対間及び他方の第2電極対間
のいづれか一方に選択的に電流を供給してその供給電流
値に応じた酸素濃度検出値を出力することを特徴とする
特許請求の範囲第1項記載の酸素濃度検出装置。4. The current supply means selectively supplies a current to either one of the other first electrode pair and the other second electrode pair according to the oxygen concentration detection value to supply the current value. The oxygen concentration detection device according to claim 1, wherein the oxygen concentration detection value according to the above is output.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP60246846 | 1985-11-02 | ||
| JP60-246846 | 1985-11-02 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS62201353A JPS62201353A (en) | 1987-09-05 |
| JPH0713619B2 true JPH0713619B2 (en) | 1995-02-15 |
Family
ID=17154577
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP1865786A Expired - Fee Related JPH0713619B2 (en) | 1985-11-02 | 1986-01-30 | Oxygen concentration detector |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH0713619B2 (en) |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE19912102C2 (en) * | 1999-03-18 | 2002-09-05 | Bosch Gmbh Robert | Electrochemical gas sensor |
-
1986
- 1986-01-30 JP JP1865786A patent/JPH0713619B2/en not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| JPS62201353A (en) | 1987-09-05 |
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