JPH0714846B2 - Cosmetics - Google Patents
CosmeticsInfo
- Publication number
- JPH0714846B2 JPH0714846B2 JP62039803A JP3980387A JPH0714846B2 JP H0714846 B2 JPH0714846 B2 JP H0714846B2 JP 62039803 A JP62039803 A JP 62039803A JP 3980387 A JP3980387 A JP 3980387A JP H0714846 B2 JPH0714846 B2 JP H0714846B2
- Authority
- JP
- Japan
- Prior art keywords
- skin
- present
- cosmetic
- diol
- cosmetics
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
Classifications
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q19/00—Preparations for care of the skin
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/34—Alcohols
- A61K8/345—Alcohols containing more than one hydroxy group
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/20—Chemical, physico-chemical or functional or structural properties of the composition as a whole
- A61K2800/24—Thermal properties
- A61K2800/244—Endothermic; Cooling; Cooling sensation
Landscapes
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Animal Behavior & Ethology (AREA)
- General Health & Medical Sciences (AREA)
- Public Health (AREA)
- Veterinary Medicine (AREA)
- Dermatology (AREA)
- Emergency Medicine (AREA)
- Birds (AREA)
- Epidemiology (AREA)
- Cosmetics (AREA)
Description
【発明の詳細な説明】 〔産業上の利用分野〕 本発明は化粧料、更に詳しくはグリセリルエーテル及び
3−l−メントキシプロパン−1,2−ジオールを含有し
てなる皮膚冷感持続効果に優れた化粧料に関する。DETAILED DESCRIPTION OF THE INVENTION [Industrial field of application] The present invention relates to a cosmetic, and more specifically to a skin cold sensation sustaining effect containing glyceryl ether and 3-l-menthoxypropane-1,2-diol. Regarding excellent cosmetics.
主に、夏期に使用され、また脂性肌の人に使用される化
粧料に望まれる特性としては、(1)ほてった肌に清涼
感を与える、(2)冷感効果の持続性を有する、(3)
べとつかず、さらっとした感触を与える等が挙げられ
る。Mainly used in the summer and for cosmetics used for people with oily skin, the desired properties are (1) a refreshing feeling on the hot skin, and (2) a long-lasting cooling effect. (3)
It is not sticky and gives a dry feel.
これらの特性を得るために、従来より、化粧料に、冷感
剤、冷えば、メントール、カンファー、オイゲノール、
サリチル酸メチル及びハッカ油等を配合することが行わ
れてきた。In order to obtain these characteristics, conventionally, a cosmetic has a cooling sensation agent, if chilled, menthol, camphor, eugenol,
Methyl salicylate and peppermint oil have been blended.
しかしながら、従来用いられてきた上述の冷感剤は、何
れも皮膚に適用した場合、その冷感効果が一時的で持続
性に乏しく、しかも特異な刺激臭を有するという欠点を
有していた。However, all of the above-mentioned cooling sensation agents that have been conventionally used have the drawbacks that when applied to the skin, the cooling sensation effect is temporary and has poor sustainability, and has a peculiar irritating odor.
また、前記欠点を改良した冷感剤として、3−l−メン
トキシプロパン−1,2−ジオールが提案され、それらを
配合した化粧料も提案されている(特開昭58−88334号
公報、特開昭60−25908号公報)が、この冷感剤も実際
の使用状態において冷感効果の持続性が充分ではなかっ
た。Further, 3-l-menthoxypropane-1,2-diol has been proposed as a cooling sensation agent for improving the above-mentioned drawbacks, and cosmetics containing them have also been proposed (JP-A-58-88334, JP-A-60-25908), however, this cooling sensation agent was not sufficient in sustaining the cooling sensation effect in the actual use condition.
従って、本発明の目的は、皮膚冷感持続効果に優れた化
粧料を提供することにある。Therefore, an object of the present invention is to provide a cosmetic having an excellent effect of maintaining a feeling of cold skin.
本発明者らは上記目的を達成すべく鋭意研究した結果、
3−l−メントキシプロパン−1,2−ジオールを特定の
グリセリルエーテルと併用することにより、3−l−メ
ントキシプロパン−1,2−ジオールの皮膚冷感効果の持
続性が著しく改良されることを知見した。As a result of earnest research to achieve the above-mentioned objects, the present inventors have
By using 3-l-menthoxypropane-1,2-diol in combination with a specific glyceryl ether, the durability of the skin cooling effect of 3-l-menthoxypropane-1,2-diol is significantly improved. I found out that.
本発明は、上記知見に基づきなされたもので、 一般式(I): (Rは炭素数8〜24のアルキル基を示す) で表されるグリセリルエーテル、及び一般式(II) で表される3−l−メントキシプロパン−1,2−ジオー
ル を含有することを特徴とする化粧料を提供するものであ
る。The present invention has been made based on the above findings, and has the general formula (I): (R represents an alkyl group having 8 to 24 carbon atoms), and a general formula (II) And a 3-l-menthoxypropane-1,2-diol represented by the following.
以下、本発明の化粧料について詳述する。Hereinafter, the cosmetic material of the present invention will be described in detail.
本発明で用いられるグリセリルエーテルとしては、上記
一般式(I)で表わされるものであれば良いが、特に上
記一般式(I)においてRが式(III): (mは4〜10の整数、nは5〜11の整数を示し、m+n
=11〜17でm=7、n=8を頂点とする分布を有する)
で表されるグリセリルエーテルが好ましい。このグリセ
リルエーテルは、特開昭57−36260号公報に開示されて
いるように、乳化安定性に優れ皮膚刺激性が無いため皮
膚化粧料の乳化剤として公知であるが、これが3−l−
メントキシプロパン−1,2−ジオールと併用することに
より、その冷感効果の持続性を著しく改良し得ることは
本発明者らによって初めて見出された。The glyceryl ether used in the present invention may be any of those represented by the above general formula (I). In particular, in the above general formula (I), R is the formula (III): (M is an integer of 4 to 10, n is an integer of 5 to 11, m + n
= 11 to 17 and has a distribution with m = 7 and n = 8 as vertices)
The glyceryl ether represented by is preferable. As disclosed in JP-A-57-36260, this glyceryl ether is known as an emulsifier for skin cosmetics because it has excellent emulsion stability and does not cause skin irritation.
It was first discovered by the present inventors that the durability of the cooling sensation effect can be remarkably improved by the combined use with mentoxypropane-1,2-diol.
本発明の化粧料におけるグリセリルエーテルの好ましい
配合量は、化粧料全量中の0.1〜5.0重量%、更に好まし
くは0.5〜3.0重量%である。0.1重量%未満では本発明
で目的とする効果を発揮し難く、5.0重量%を超えると
使用時にべとつき感を与えるので好ましくない。The preferred blending amount of glyceryl ether in the cosmetic of the present invention is 0.1 to 5.0% by weight, and more preferably 0.5 to 3.0% by weight based on the total amount of the cosmetic. If it is less than 0.1% by weight, the desired effect of the present invention is difficult to exert, and if it exceeds 5.0% by weight, a sticky feeling is imparted during use, which is not preferable.
また、本発明の化粧料における3−l−メントキシプロ
パン−1,2−ジオールは前記一般式(II)で表される化
合物で、その好ましい配合量は、化粧量全量中の0.001
〜3.0重量%、更に好ましくは0.01〜1.0重量%である。
0.001重量%未満では本発明で目的とする効果を発揮し
難く、3.0重量%を超えると皮膚への刺激感(ほてり
感)が生じ好ましくない。Further, 3-l-menthoxypropane-1,2-diol in the cosmetic of the present invention is a compound represented by the general formula (II), and its preferable compounding amount is 0.001 in the total cosmetic amount.
˜3.0 wt%, and more preferably 0.01 to 1.0 wt%.
If it is less than 0.001% by weight, it is difficult to exert the intended effect in the present invention, and if it exceeds 3.0% by weight, irritation to the skin (hot feeling) occurs, which is not preferable.
本発明の化粧料は、前記一般式(I)及び(II)で表わ
される2成分を含有するもので、これら2成分の添加さ
れる化粧料は、冷感持続効果の望まれる化粧料であれば
特に制限されるものではなく、本発明の対象となる化粧
料としては、例えば、柔軟化粧水、収れん化粧水、ふき
とり用化粧水、カラミンローション、アフターシェーブ
ローション、メイクアップ透明ローション等の種々の化
粧水・美容液類、及びマッサージクリーム、クレンジン
グクリーム、スキンクリーム、夏用ファンデーションク
リーム、サンタンクリーム、ミルキィローション等の種
々のクリーム・乳液類等の皮膚化粧料の他に、シャンプ
ー、ヘアーリンス、ヘアートニック等の頭髪化粧料も挙
げることができる。The cosmetic of the present invention contains two components represented by the general formulas (I) and (II), and the cosmetic to which these two components are added may be a cosmetic for which a cooling sensation sustaining effect is desired. There is no particular limitation, and examples of the cosmetics to which the present invention is applicable include, for example, various types of cosmetics such as soft lotion, astringent lotion, wipe lotion, calamine lotion, aftershave lotion, and makeup transparent lotion. In addition to skin cosmetics such as various creams and emulsions such as water and beauty liquids, massage creams, cleansing creams, skin creams, summer foundation creams, suntan creams and milky lotions, shampoos, hair conditioners, hair nicks Mention may also be made of hair cosmetics such as.
また、本発明の化粧料には、上記の2成分の他に、化粧
料成分として一般に使用されている油分、界面活性剤、
保湿剤、紫外線吸収剤、アルコール類、キレート剤、pH
調整剤、防腐剤、増粘剤、色素、香料等通常化粧料に用
いられる成分を、本発明の効果を損なわない範囲で適宜
配合することができる。例えば、前記カラミンローショ
ン、メイクアップ透明ローション、夏用ファンデーショ
ンクリームには、顔料(例えば黄色酸化鉄、赤色酸化
鉄、酸化チタン、タルク、カオリン等)が配合される。In addition to the above-mentioned two components, the cosmetic of the present invention includes an oil component, a surfactant, and
Moisturizer, UV absorber, alcohol, chelating agent, pH
Ingredients usually used in cosmetics, such as regulators, preservatives, thickeners, pigments, and fragrances, can be appropriately added within a range that does not impair the effects of the present invention. For example, pigments (for example, yellow iron oxide, red iron oxide, titanium oxide, talc, kaolin, etc.) are blended in the calamine lotion, make-up transparent lotion, and summer foundation cream.
次に実施例を挙げて本発明を説明する。 Next, the present invention will be described with reference to examples.
実施例1 下記表1に示す組成のクリームを下記製造法により製造
した。Example 1 A cream having the composition shown in Table 1 below was produced by the following production method.
(製造法) 精製水に硫酸マグネシウム、メチルパラベン、グリセリ
ンを加えて加熱し、この水相部を70℃に保つ。一方、他
の親油性の成分を混合し加熱溶解し、この油相部を70℃
にする。次いで、この油相部に上記水相部を加えてこれ
らを乳化機にて乳化する。乳化物を熱交換機にて終温30
℃まで冷却した後、充填を行うことにより本発明のクリ
ーム(本発明品1)を得た。また、配合成分及び(又
は)配合を変えた以外は、本発明品1の製造と同様にし
て、それぞれ本発明品2、比較品1及び2を得た。(Manufacturing method) Magnesium sulfate, methylparaben, and glycerin are added to purified water and heated, and the aqueous phase is kept at 70 ° C. On the other hand, other lipophilic components are mixed and dissolved by heating, and this oil phase part is heated to 70 ° C.
To Next, the water phase portion is added to the oil phase portion and these are emulsified by an emulsifying machine. The final temperature of the emulsion is 30 using a heat exchanger.
After cooling to ° C, filling was performed to obtain a cream of the present invention (Product 1 of the present invention). Further, the present invention product 2 and comparative products 1 and 2 were obtained in the same manner as in the production of the present invention product 1, except that the compounding ingredients and / or the composition was changed.
皮膚冷感持続効果試験 上記製造法により得た本発明品1及び2、比較品1及び
2について、下記<試験方法>によりそれぞれの皮膚冷
感持続効果を調べ、<下記結果>を得た。Skin cold sensation sustaining effect test With respect to the present invention products 1 and 2 and the comparative products 1 and 2 obtained by the above-mentioned production methods, the skin chill sensation sustaining effects were examined by the following <test method>, and <the following results> were obtained.
<試験方法> (1)実用テスト(パネルテスト) 20〜40才の女性30名を被験者とし、比較品1と比較品
2、比較品1と本発明品1、比較品1と本発明品2を試
験する3群に分け、各群10名とし、それぞれクリームを
左右の顔面に片方ずつ塗布し、直後、3分後、10分後、
の「冷感持続効果」について調べた。<Test method> (1) Practical test (panel test) 30 women aged 20 to 40 were used as test subjects, and comparative product 1 and comparative product 2, comparative product 1 and inventive product 1, comparative product 1 and inventive product 2 Are divided into 3 groups to be tested, and each group has 10 persons, and one cream is applied to each of the left and right faces, immediately, 3 minutes later, 10 minutes later,
"Cold feeling lasting effect" was investigated.
<結果> 試験結果は下記表−2に示す通りであった。尚、表−2
には「皮膚冷感持続効果」について各被験クリームが冷
感がある/やや冷感があると答えた被験者の数を示し
た。 <Results> The test results were as shown in Table 2 below. Table-2
Shows the number of subjects who responded that "each skin cream had a cold sensation / somewhat a cold sensation" regarding "skin cold sensation sustaining effect".
上記表−2に示す結果から、3−l−メントキシプロパ
ン−1,2−ジオールを一般式(I)で表わされるグリシ
ジルエーテルと共に配合した本発明品1及び2は、グリ
シジルエーテルを配合しない比較品2に比して、皮膚冷
感持続効果が著しく優れていることが判る。 From the results shown in Table 2 above, the products 1 and 2 of the present invention in which 3-l-menthoxypropane-1,2-diol was blended with the glycidyl ether represented by the general formula (I) were compared without blending glycidyl ether. It can be seen that the skin cold feeling sustaining effect is remarkably superior to that of the product 2.
実施例2 重量% 油相成分:セタノール 0.5 スクワラン 2.0 ワセリン 1.0 ラノリンアルコール 0.5 流動パラフィン 2.0 ステアリン酸 1.0 POE(10)モノオレイン酸 エステ
ル 2.0 グリセリルエーテル* 1.0 3−l−メントキシプロパン−1,2−ジオー
ル** 0.3 水相成分:グリセリン 1.0 プロピレングリコール 1.0 トリエタノールアミン 0.5 メチルパラベン 0.3 エタノール 4.0 香料 0.1 精製水 バランス 計 100 * **:それぞれ実施例1の成分と同じ 上記油相成分を混合し加熱溶解して油相部を70℃に保
つ。上記水相成分も同様に70℃で加熱混合し、この水相
成分に上記の油相部を加えそれらを乳化機にて乳化す
る。乳化物を熱交換機にて終温30℃まで冷却した後、充
填を行うことにより乳液(本発明品3)を調製した。Example 2 Weight% Oil phase component: Cetanol 0.5 Squalane 2.0 Vaseline 1.0 Lanolin alcohol 0.5 Liquid paraffin 2.0 Stearic acid 1.0 POE (10) Monooleic acid ester 2.0 Glyceryl ether * 1.0 3-l-Mentoxypropane-1,2-diol ** 0.3 Aqueous phase component: Glycerin 1.0 Propylene glycol 1.0 Triethanolamine 0.5 Methylparaben 0.3 Ethanol 4.0 Perfume 0.1 Purified water Balance total 100 100 **: The same oil phase components as those of Example 1 were mixed and dissolved by heating. Keep the oil phase at 70 ° C. Similarly, the above-mentioned aqueous phase component is also heated and mixed at 70 ° C., the above-mentioned oil phase part is added to this aqueous phase component, and they are emulsified by an emulsifier. The emulsion was cooled to a final temperature of 30 ° C. with a heat exchanger and then filled to prepare an emulsion (invention product 3).
実施例3 重量% エタノール 30.0 ポリオキシメチレン硬化ヒマシ油(60E.O.) 3.0 グリセリルエーテル* 1.0 3−l−メントキシプロパン−1,2−ジオール**0.1 ジプロピレングリコール 5.0 メチルパラベン 0.1 乳酸 適量 乳酸ナトリウム 適量 香料 0.1 精製水 バランス 計 100 * **:それぞれ実施例1の成分と同じ 精製水に、ジプロピレングリコール、乳酸、乳酸ナトリ
ウムを溶解し、弱酸性(pH5〜6)にする。これにメチ
ルパラベン、香料、ポリオキシエチレン硬化ヒマシ油、
グリセリルエーテル、3−l−メントキシプロパン−1,
2−ジオールをエタノールに溶解したものを撹拌しなが
ら徐々に加え、可溶化し、ろ過して化粧水(本発明品
4)を得た。Example 3 wt% ethanol 30.0 polyoxymethylene hydrogenated castor oil (60 E.O.) 3.0 glyceryl ether * 1.0 3-l-menthoxypropane-1,2-diol ** 0.1 dipropylene glycol 5.0 methylparaben 0.1 lactic acid suitable amount sodium lactate Appropriate amount Fragrance 0.1 Purified water Balance 100 Total *****: Dipropylene glycol, lactic acid and sodium lactate are dissolved in the same purified water as the components of Example 1 to make it weakly acidic (pH 5 to 6). Methylparaben, fragrance, polyoxyethylene hydrogenated castor oil,
Glyceryl ether, 3-l-menthoxypropane-1,
A solution in which 2-diol was dissolved in ethanol was gradually added with stirring, solubilized, and filtered to obtain a lotion (invention product 4).
実施例4 重量% ベントナイト 15.0 カオリン 10.0 酸化亜鉛 5.0 ポリオキシメチレン硬化ヒマシ油(80E.O.) 5.0 グリセリルエーテル* 3.0 3−l−メントキシプロパン−1,2−ジオール**2.0 プロピレングリコール 5.0 エタノール 8.0 メチルパラベン 0.1 香料 0.1 精製水 バランス 計 100 * **:それぞれ実施例1の成分と同じ 精製水に、プロピレングリコールを加え、ビーガムを添
加して膨潤後、酸化亜鉛、カオリンを加え、その後ポリ
オキシエチレン硬化ヒマシ油、グリセリルエーテル、3
−l−メントキシプロパン−1,2−ジオール、香料、パ
ラベン類を溶解したエタノールを加え、これらをペース
ト状になるまでかきまぜてペースト状洗い流し型パック
(本発明品5)を調製した。Example 4 Wt% Bentonite 15.0 Kaolin 10.0 Zinc oxide 5.0 Polyoxymethylene hydrogenated castor oil (80E.O.) 5.0 Glyceryl ether * 3.0 3-l-Mentoxypropane-1,2-diol ** 2.0 Propylene glycol 5.0 Ethanol 8.0 Methylparaben 0.1 Perfume 0.1 Purified water Balance 100 Total **: Same as the components of Example 1 Propylene glycol was added to the purified water, veegum was added to swell, zinc oxide and kaolin were added, and then polyoxyethylene was cured. Castor oil, glyceryl ether, 3
Ethanol in which 1-menthoxypropane-1,2-diol, a fragrance, and parabens were dissolved was added, and the mixture was stirred until it became a paste to prepare a paste-like wash-off type pack (invention product 5).
実施例2〜4で調製した本発明品3〜5は、いずれも優
れた皮膚冷感持続硬化を有する化粧料であった。The products 3 to 5 of the present invention prepared in Examples 2 to 4 were all cosmetics having an excellent persistent sensation of cold skin sensation.
本発明の化粧料は優れた皮膚冷感持続効果を有している
ため、斯る特性(効果)の望まれる化粧料、例えば夏季
のほてった肌や脂っぽい肌、ひげそり後の肌等に適用す
る化粧料として有用性の高いものである。Since the cosmetic of the present invention has an excellent effect of maintaining a cool skin sensation, it is suitable for cosmetics for which such characteristics (effects) are desired, such as hot skin in the summer, oily skin, and skin after shaving. It is highly useful as an applied cosmetic.
Claims (4)
ル を含有することを特徴とする化粧料。1. General formula (I): (R represents an alkyl group having 8 to 24 carbon atoms), and a general formula (II) A cosmetic comprising a 3-l-menthoxypropane-1,2-diol represented by:
いてRが次式(III): (mは4〜10の整数、nは5〜11の整数を示し、m+n
=11〜17で、m=7、n=8を頂点とする分布を有す
る)であるグリセリルエーテルである特許請求の範囲第
(1)項記載の化粧料。2. A glyceryl ether, wherein R in the general formula (I) is represented by the following formula (III): (M is an integer of 4 to 10, n is an integer of 5 to 11, m + n
= 11 to 17 and a distribution having m = 7 and n = 8 as vertices). The cosmetic according to claim (1), which is glyceryl ether.
量%である特許請求の範囲第(1)項又は第(2)項記
載の化粧料。3. The cosmetic according to claim 1, wherein the amount of glyceryl ether is 0.1 to 5.0% by weight.
ールの配合量が0.001〜3.0重量%である特許請求の範囲
第(1)項又は第(2)項記載の化粧料。4. The cosmetic according to claim 1, wherein the amount of 3-l-menthoxypropane-1,2-diol is 0.001 to 3.0% by weight.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP62039803A JPH0714846B2 (en) | 1987-02-23 | 1987-02-23 | Cosmetics |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP62039803A JPH0714846B2 (en) | 1987-02-23 | 1987-02-23 | Cosmetics |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS63208505A JPS63208505A (en) | 1988-08-30 |
| JPH0714846B2 true JPH0714846B2 (en) | 1995-02-22 |
Family
ID=12563113
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP62039803A Expired - Lifetime JPH0714846B2 (en) | 1987-02-23 | 1987-02-23 | Cosmetics |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH0714846B2 (en) |
Families Citing this family (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2978043B2 (en) * | 1993-09-16 | 1999-11-15 | 高砂香料工業株式会社 | (2S) -3-{(1R, 2S, 5R)-[5-methyl-2- (1-methylethyl) cyclohexyl] oxy} -1,2-propanediol, its production method and use |
| JP4017758B2 (en) | 1998-08-04 | 2007-12-05 | 高砂香料工業株式会社 | Cooling agent composition |
| JP4018032B2 (en) | 2003-06-17 | 2007-12-05 | 高砂香料工業株式会社 | Hair and body cleaning composition |
| JP5981192B2 (en) * | 2012-03-29 | 2016-08-31 | ポーラ化成工業株式会社 | Method for stabilizing oil-soluble component with glyceryl monoalkyl ether and cosmetic containing the same |
| FR3040297B1 (en) * | 2015-08-28 | 2018-07-20 | Oreal | USE OF MONOTERPENES DERIVED FROM MENTHOL AS ANTI-DANDRUFF ACTIVE INGREDIENTS |
Family Cites Families (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5639033A (en) * | 1979-09-04 | 1981-04-14 | Kao Corp | Alpha-mono(methyl-branched alkyl glyceryl ether and skin cosmetic containing the same |
| JPS6025908A (en) * | 1983-07-20 | 1985-02-08 | Kanebo Ltd | Skin cosmetic |
-
1987
- 1987-02-23 JP JP62039803A patent/JPH0714846B2/en not_active Expired - Lifetime
Also Published As
| Publication number | Publication date |
|---|---|
| JPS63208505A (en) | 1988-08-30 |
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