JPH072328B2 - Corrosion resistant tube - Google Patents
Corrosion resistant tubeInfo
- Publication number
- JPH072328B2 JPH072328B2 JP3005834A JP583491A JPH072328B2 JP H072328 B2 JPH072328 B2 JP H072328B2 JP 3005834 A JP3005834 A JP 3005834A JP 583491 A JP583491 A JP 583491A JP H072328 B2 JPH072328 B2 JP H072328B2
- Authority
- JP
- Japan
- Prior art keywords
- aggregate
- self
- layer
- aggregates
- coarse
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
Landscapes
- Rigid Pipes And Flexible Pipes (AREA)
- Laminated Bodies (AREA)
- Manufacturing Of Tubular Articles Or Embedded Moulded Articles (AREA)
Description
【0001】[0001]
【産業上の利用分野】本発明はセメントコンクリート管
や鋼管に代る耐食性コンクリート管に関するものであ
る。BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a corrosion resistant concrete pipe which replaces a cement concrete pipe or a steel pipe.
【0002】[0002]
【従来の技術】従来、コンクリート管や鋼管は構造材と
して優れているが、化学作用を伴う侵食に弱いことは周
知の事実である。また化学作用に安定な陶管は高温焼成
過程を経るため鉄筋の配置が不可能であるため破壊強度
に不安がある。鋼管は化学作用に極めて弱く、寿命が短
かいばかりでなく、錆の発生で管路が閉鎖され、管路と
しての機能を失う。塩ビ管は化学作用には強いが原料が
高価な上鉄筋の配筋もなく土圧に対し容易に変形した
り、日光による劣化がはげしいなどそれぞれ欠点を持っ
ている。2. Description of the Related Art Conventionally, concrete pipes and steel pipes have been excellent as structural materials, but it is well known that they are vulnerable to erosion due to chemical action. Moreover, since the ceramic tube that is stable to chemical action undergoes a high temperature firing process, it is impossible to arrange the reinforcing bars, so there is concern about the breaking strength. Steel pipes are extremely vulnerable to chemical action and not only have a short service life, but also lose their function as pipelines due to the formation of rust that closes the pipelines. Although PVC pipes are strong in chemical action, they have drawbacks such as the fact that they are easily deformed against earth pressure without the reinforcement of the upper rebar, which is an expensive raw material, and are prone to deterioration due to sunlight.
【0003】例えば下水道では流入する酸や塩などの化
学薬品や汚水から発生する硫化水素など雑多な腐食性ガ
スによってセメント中のカルシュウム分が分解され、コ
ンクリートが劣化するため社会問題となっている。鋼管
も同様である。又、コンクリート用骨材と樹脂を混合し
た例えばレジンコンクリートブロックなどは既に存在し
ているが、これらはいずれもブロックなどの塊状加圧成
形品であって樹脂と骨材を混合したのち目的の形に成形
するため骨材表面を樹脂で被覆しているに過ぎないし、
樹脂の早期固化性、粘着性が大きすぎるなど、極めて作
業性が悪く、高級な製品を製造出来ないのが現状であ
る。For example, in sewers, calcium compounds in cement are decomposed by various corrosive gases such as inflowing chemicals such as acid and salt, and hydrogen sulfide generated from sewage, and concrete is deteriorated, which is a social problem. The same applies to steel pipes. Also, resin concrete blocks, etc., in which aggregate for concrete and resin are mixed already exist, but all of these are block pressure molded products such as blocks, and after mixing the resin and aggregate, the desired shape is obtained. The surface of the aggregate is simply coated with resin to form
At present, it is impossible to manufacture high-quality products because the workability is extremely poor due to the resin's early solidification and adhesiveness being too great.
【0004】又セメントコンクリート管の内面に遠心力
でレジンライニングを施したものがあるが、粗骨材にセ
メントペーストをまぶし、これをレジンライニングの骨
材とするものであるため、粗骨材とレジンとは密着しな
いし、粗骨材とレジンとのペースト部分に腐食成分の進
入が容易であるという問題がある(特公昭53−147
74号)。さらに又円筒型枠を回転させ、ポリエステル
樹脂を主材とし、メチル・エチル・ケトンパーオキサイ
ト等を添加混合した熱硬化性樹脂液に砂、砂利等の細骨
材を予め混合してモルタルとなし、これを上記回転型枠
内に投入し、型枠全体を養生函内に装入して加熱硬化さ
せる樹脂モルタル硬化管(特開昭49−106519
号)があるが、粗骨材を用いないので強度が出ないし、
加熱硬化中に回転による遠心力によって比重の大きい
砂、砂利等の無数の細骨材が外側に先に移動し、移動軌
跡に微小空洞を生じ多孔性樹脂コンクリート管となって
樹脂と骨材との密着性が不良であるという構造上の問題
があった。 Although there is a cement concrete pipe whose inner surface is subjected to a resin lining by centrifugal force, the coarse aggregate is sprinkled with cement paste and used as the aggregate for the resin lining. There is a problem that it does not adhere to the resin and that the corrosive component easily enters the paste portion of the coarse aggregate and the resin (Japanese Patent Publication No. 53-147).
74). In addition, rotate the cylindrical form, polyester
Resin as the main material, methyl ethyl ketone peroxide
Fine particles of sand, gravel, etc. in a thermosetting resin liquid mixed with
The materials are mixed in advance to form mortar, which is
Then, put the whole mold into the curing box and heat cure.
Resin mortar hardening tube (JP-A-49-106519)
No.), but since it does not use coarse aggregate, it does not give strength,
Large specific gravity due to centrifugal force due to rotation during heat curing
Countless fine aggregates such as sand and gravel move to the outside first,
A micro-cavity is created in the trace and it becomes a porous resin concrete pipe
Structural problem of poor adhesion between resin and aggregate
was there.
【0005】[0005]
【発明が解決しようとする課題】本発明はセメントを用
いることなく強度大で化学的に安定で耐食性に富み内面
平滑なコンクリート管を容易にかつ経済的に得ようとす
るものである。SUMMARY OF THE INVENTION The present invention is intended to easily and economically obtain a concrete pipe having high strength, chemical stability, corrosion resistance, and smooth inner surface without using cement.
【0006】[0006]
【課題を解決するための手段】上記の目的を達成するた
め本発明は耐食性自硬液によって粗骨材及び細骨材より
なる混合骨材層を固結形成してなる管であって、内部に
鉄筋を配筋し、かつ内周面に細骨材と上記自硬液とによ
るモルタル層を形成してなり、かつ粗骨材、細骨材及び
鉄筋が上記自硬液によって濡らされた状態で固結し、か
つ上記混合骨材層では粗骨材が上記管の外周面から内側
に相互に密に接触しかつ粗骨材間の間隙を細骨材と自硬
液とのモルタルで充填してなる耐食性管によって構成さ
れる。In order to achieve the above object, the present invention provides a pipe in which a mixed aggregate layer composed of coarse aggregate and fine aggregate is consolidated by a corrosion resistant self-hardening liquid, and A state in which the reinforcing bar is arranged in the inner part, and a mortar layer is formed on the inner peripheral surface by the fine aggregate and the self-hardening liquid, and the coarse aggregate, the fine aggregate and the reinforcing bar are wet by the self-hardening liquid. In the mixed aggregate layer, the coarse aggregates are in intimate contact with each other from the outer peripheral surface of the pipe to the inner side, and the gap between the coarse aggregates is hardened with the fine aggregates.
It is composed of a corrosion resistant tube filled with mortar with liquid .
【0007】[0007]
【作用】従って回転筒状型枠6の内周面に沿って保持さ
れる耐食性自硬液層7の内部に遠心力によって細骨材3
及び粗骨材2との混合骨材が進入して混合骨材層12を
形成する。この骨材層12では上記遠心力のため粗骨材
2相互が上記内周面(混合骨材層12の外周面)に向っ
て締め固められ図1、図2(ニ)(ホ)図及び図5に示すよう
に同粗骨材2は相互に密に接触する。そして上記自硬液
1は骨材2、3の表面を濡らし、かつ骨材2、3の占め
る容積によって同液1は型枠6の中心線側に骨材間に進
出し、同骨材層12は上記液層7内に没し粗骨材2間の
間隙に細骨材3と自硬液1とのモルタルを充填する。そ
して同骨材層12の内周に上記自硬液1の薄層13が形
成される。この状態において型枠6内にさらに細骨材3
を投入すると同細骨材はその遠心力によって上記薄層1
3内に進入し細骨材によるモルタル層5を形成しその状
態で同液1は硬化し上記骨材層12及び細骨材モルタル
層5を固結形成する。細骨材モルタル層5と上記骨材層
12内の細骨材3とは一体的に連続し両層は一体に形成
され、上記自硬液1の硬化後脱型され、下水管路など腐
食性雰囲気内で使用されるものである。Therefore, the fine aggregate 3 is generated by centrifugal force inside the corrosion-resistant self-hardening liquid layer 7 held along the inner peripheral surface of the rotary tubular form frame 6.
And the mixed aggregate with the coarse aggregate 2 enters to form the mixed aggregate layer 12. In the aggregate layer 12, due to the centrifugal force, the coarse aggregates 2 are compacted toward the inner peripheral surface (the outer peripheral surface of the mixed aggregate layer 12), and FIGS. 1, 2 (d), (e) and As shown in FIG. 5, the coarse aggregates 2 are in close contact with each other. The self-hardening liquid 1 wets the surfaces of the aggregates 2 and 3, and due to the volume occupied by the aggregates 2 and 3, the liquid 1 advances to the center line side of the mold 6 between the aggregates, and the aggregate layer 12 is submerged in the liquid layer 7 between the coarse aggregates 2.
The gap is filled with mortar of the fine aggregate 3 and the self-hardening liquid 1. So
Then, a thin layer 13 of the self-hardening liquid 1 is formed on the inner circumference of the aggregate layer 12. In this state, the fine aggregate 3 is further placed in the mold 6.
When the fine aggregate is charged, the thin aggregate 1
The mortar layer 5 made of fine aggregate is formed into the inside 3 and the liquid 1 is hardened in that state to solidify and form the aggregate layer 12 and the fine aggregate mortar layer 5. The fine aggregate mortar layer 5 and the fine aggregate 3 in the aggregate layer 12 are integrally continuous, and both layers are integrally formed. After the self-hardening liquid 1 is cured, it is demolded, and the sewer pipe is corroded. It is used in a sexual atmosphere.
【0008】そして上記自硬液1で濡らされた骨材2、
3及び鉄筋4の表面に水などは進入せず、水などによっ
て濡らされることはないし、上記混合骨材層12では粗
骨材2、2相互が密に接触して外力を分散させる。Then, the aggregate 2 which is wetted with the self-hardening liquid 1,
Water does not enter the surfaces of the reinforcing rods 3 and the reinforcing bars 4 and is not wet by water or the like. In the mixed aggregate layer 12, the coarse aggregates 2 and 2 are in close contact with each other to disperse the external force.
【0009】[0009]
【実施例】機台8に転輪9、9を軸支し、同転輪9、9
上に鋼製円筒型枠6を支持し、一方の転輪9を無段変速
モーター10によって回動させることにより同型枠6を
円筒の中心線aの回りに回転させることができる。この
型枠6の内周面には離型剤を塗布し又は紙等による離型
材11を張設する。そして同離型剤又は材11の内側に
内周面に沿ってかご状鉄筋4を配筋する。その後上記モ
ーター10を始動して同型枠6を中心線aの回りに回転
させ、その状態で耐食性樹脂液(不飽和ポリエステル樹
脂)、加熱コールタール液、加熱アスファルト液、溶剤
(シンナー等)による稀釈コールタール液、稀釈アスフ
ァルト液等の歴青剤のような耐食性自硬液1を上記回転
型枠6内に注入すると同液1はその粘性によって内周面
に沿って回動し遠心力によって一定厚さの耐食性自硬液
層7が形成されその状態が保持される(図2(ハ) 図にそ
の状態を示す)。[Embodiment] The wheels 9, 9 are pivotally supported on the machine base 8, and the wheels 9, 9 are supported.
It is possible to rotate the mold 6 around the center line a of the cylinder by supporting the steel cylindrical mold 6 on the top and rotating one of the wheels 9 by the continuously variable transmission motor 10. A mold release agent is applied to the inner peripheral surface of the mold 6 or a mold release material 11 made of paper or the like is stretched. Then, the cage-shaped reinforcing bars 4 are arranged inside the releasing agent or the material 11 along the inner peripheral surface. Then, the motor 10 is started to rotate the mold 6 around the center line a, and in that state, it is diluted with a corrosion-resistant resin liquid (unsaturated polyester resin), heated coal tar liquid, heated asphalt liquid, solvent (thinner, etc.). When a corrosion-resistant self-hardening liquid 1 such as a bituminous agent such as coal tar liquid or diluted asphalt liquid is injected into the rotary mold 6, the liquid 1 rotates along the inner peripheral surface due to its viscosity and becomes constant by centrifugal force. A corrosion resistant self-hardening liquid layer 7 having a thickness is formed and the state is maintained (the state is shown in FIG. 2C).
【0010】その状態において細骨材3及び粗骨材2の
混合骨材を同型枠6内に投入すると図2(ニ) 図に示すよ
うに混合骨材層12が遠心力によって均等厚さに形成さ
れ、これらの骨材2、3はその遠心力によって上記自硬
液層7内に進入し上記内周面に到達し骨材2、2、3、
3は外側(管の外周面から内側に)に向って締め固めら
れて相互に密に接触し、かつ自硬液1は骨材2、3及び
鉄筋4を濡らしかつ骨材2、3相互間及び骨材2、3と
鉄筋4との間隙に進出する。そしてこの進出自硬液1は
混合骨材層12内の粗骨材2、2の間隙に細骨材3と自
硬液1とのモルタルを形成し、さらに該骨材層12の内
周に現われ同層12は同液1内に没し自硬液薄層13を
内周に形成する(図2(ニ) 図)。When the mixed aggregate of the fine aggregate 3 and the coarse aggregate 2 is put into the same frame 6 in that state, the mixed aggregate layer 12 is made uniform in thickness by centrifugal force as shown in FIG. The aggregates 2, 3 are formed by the centrifugal force, enter the self-hardening fluid layer 7 and reach the inner peripheral surface, and the aggregates 2, 2, 3,
3 is compacted toward the outside (from the outer peripheral surface of the pipe to the inside) and in intimate contact with each other, and the self-hardening liquid 1 wets the aggregates 2 and 3 and the reinforcing bar 4 and between the aggregates 2 and 3 And it advances into the gap between the aggregates 2 and 3 and the reinforcing bars 4. Then, the advancing self-hardening liquid 1 is mixed with the fine aggregate 3 in the gap between the coarse aggregates 2 in the mixed aggregate layer 12 .
A mortar with the hard liquid 1 is formed, which appears on the inner circumference of the aggregate layer 12 , and the same layer 12 is submerged in the hard liquid 1 to form a self-hardening liquid thin layer 13 on the inner circumference (Fig. 2 (d)). Figure).
【0011】この状態において細骨材3のみ型枠6内に
投入すると同細骨材3は上記薄層13内に遠心力によっ
て進入し上記混合層12内の細骨材部分と一体化して細
骨材モルタル層5を形成する(図2(ホ) 図)。実験によ
るとこの時点で型枠6の回転を停止しても両層5、12
が崩れることなく保持された。その後比較的迅速に自硬
液1は硬化して骨材2、3相互並びに骨材2、3と鉄筋
4とを接着して結合させかつ凝結するから、上記型枠6
を脱型し耐食性コンクリート管14を取卸すことができ
る。When only the fine aggregate 3 is put into the mold 6 in this state, the fine aggregate 3 enters the thin layer 13 by centrifugal force and is integrated with the fine aggregate portion in the mixed layer 12 to form fine aggregate. The aggregate mortar layer 5 is formed (Fig. 2 (e) figure). According to the experiment, even if the rotation of the mold 6 is stopped at this point, both layers 5, 12
Was held without breaking. After that, the self-hardening liquid 1 hardens relatively quickly to bond the aggregates 2 and 3 and the aggregates 2 and 3 and the reinforcing bar 4 to each other and bond them together.
Can be demolded and the corrosion-resistant concrete pipe 14 can be unloaded.
【0012】上記自硬液1はその硬化後の接着性を保持
する範囲でなるべく粘性が低い方が良い。これは骨材
2、3が液中に進入し易いためである。又同骨材2、3
は乾燥状態に保たれ、かつ骨材2、3の投入に際しては
空隙ができるだけ少いように粗骨材2と細骨材3とを調
合したものを上記管14の厚さの8/10〜9/10ま
で添加し、これが均一な混合骨材層12となって自硬液
1中に没した後、残りの1/10〜2/10の上記薄層
13に細骨材3を遠心力で上述のように進入させる。こ
れは上記混合骨材層12の粗骨材2を内面に突出させず
に平滑内面を形成するためである。上記自硬液1と骨材
2、3の容積比は管14の用途により適度に調整する。
又自硬液1が骨材2、3を包含する割合は同液1の濃度
に左右されるから濃度は製品が要求する外圧強度、水密
性に応じて上記溶剤や加熱温度等で調整することができ
る。尚図中15で示すものは型枠6の両端フランジ、1
6は型枠6の外周に設けた転輪受タイヤ、17は一方の
転輪9の回動軸に設けた調車、18は上記モーター10
の出力軸に設けた調車、19は両調車17、18に掛渡
した調紐である。It is preferable that the self-hardening liquid 1 has a viscosity as low as possible within a range where the adhesiveness after curing is maintained. This is because the aggregates 2 and 3 easily enter the liquid. The same aggregate 2, 3
Is a mixture of the coarse aggregate 2 and the fine aggregate 3 which is kept in a dry state and has as few voids as possible when the aggregates 2 and 3 are charged. After adding up to 9/10, this becomes a uniform mixed aggregate layer 12 and submerged in the self-hardening liquid 1, and then the fine aggregate 3 is centrifugally applied to the remaining 1/10 to 2/10 of the above thin layer 13. And enter as described above. This is for forming the smooth inner surface without causing the coarse aggregate 2 of the mixed aggregate layer 12 to project to the inner surface. The volume ratio of the self-hardening liquid 1 to the aggregates 2 and 3 is appropriately adjusted depending on the use of the pipe 14.
Further, the ratio of the self-hardening liquid 1 containing the aggregates 2 and 3 depends on the concentration of the liquid 1, so that the concentration should be adjusted by the solvent, heating temperature, etc. according to the external pressure strength and water tightness required by the product. You can The reference numeral 15 in the figure indicates both end flanges of the form 6,
Reference numeral 6 is a wheel receiving tire provided on the outer periphery of the mold 6, 17 is a wheel adjuster provided on the rotating shaft of one of the wheels 9, and 18 is the motor 10 described above.
A reference numeral 19 is a string provided on the output shaft of the above, and a reference numeral 19 is a string attached to both the adjustment wheels 17 and 18.
【0013】[0013]
【発明の効果】本発明は上述のように構成したので、上
記骨材2、3及び鉄筋4の表面は上記自硬液1で濡らさ
れているため同表面に水等が進入するおそれがなく、そ
のため耐候性、耐酸性等耐食性に富み下水管路等腐食性
雰囲気で安全に使用し得て、しかも粗骨材2相互が確り
締め固められて密に接触し絡み合い、かつ該粗骨材2、
2の間隙には細骨材3と自硬液1とのモルタルが充填さ
れているため強度充分であり、かつ粗骨材2間の間隙が
少いから自硬液1の使用量を軽減し経済的な耐食性管が
回転筒状型枠6によって容易に得られる効果がある。Since the present invention is constructed as described above, since the surfaces of the aggregates 2 and 3 and the reinforcing bars 4 are wet with the self-hardening liquid 1, there is no risk of water or the like entering the surfaces. , therefore weather resistance, and obtained safely use in sewer pipe and the like corrosive atmosphere rich in acid resistance corrosion resistance and the like, tightly have contact tangling engagement addition to coarse aggregate 2 mutually compacted firmly tightened, and the crude bone Material 2,
The gap of 2 is filled with mortar of fine aggregate 3 and self-hardening liquid 1.
Is a sufficient strength for being, and the effect of coarse aggregate reduce the amount of the own hard liquid 1 from the gap is small between 2 and economical corrosion resistance tube can be easily obtained by a rotating cylindrical mold 6 is there.
【図1】本発明の耐食性管を示す縦断正面図である。FIG. 1 is a vertical cross-sectional front view showing a corrosion resistant pipe of the present invention.
【図2】(イ)(ロ)(ハ)(ニ)(ホ) 図は製造工程図である。2 (a) (b) (c) (d) (e) FIG. 2 is a manufacturing process diagram.
【図3】筒状型枠及び鉄筋の縦断正面図である。FIG. 3 is a vertical sectional front view of a tubular form and a reinforcing bar.
【図4】図3の縦断側面図である。FIG. 4 is a vertical sectional side view of FIG.
【図5】脱型直前の縦断面図である。FIG. 5 is a vertical cross-sectional view immediately before demolding.
1 耐食性自硬液 2 粗骨材 3 細骨材 4 鉄筋 5 モルタル層 12 混合骨材層 1 Corrosion resistant self-hardening liquid 2 Coarse aggregate 3 Fine aggregate 4 Reinforcing bar 5 Mortar layer 12 Mixed aggregate layer
Claims (2)
よりなる混合骨材層を固結形成してなる管であって、内
部に鉄筋を配筋し、かつ内周面に細骨材と上記自硬液と
によるモルタル層を形成してなり、かつ粗骨材、細骨材
及び鉄筋が上記自硬液によって濡らされた状態で固結
し、かつ上記混合骨材層では粗骨材が上記管の外周面か
ら内側に相互に密に接触しかつ粗骨材間の間隙を細骨材
と自硬液とのモルタルで充填してなる耐食性管。1. A pipe in which a mixed aggregate layer made of coarse aggregate and fine aggregate is consolidated and formed by a corrosion resistant self-hardening liquid, in which reinforcing bars are arranged inside and fine bone is formed on the inner peripheral surface. Made of a mortar layer composed of a material and the self-hardening liquid, and solidified in a state in which coarse aggregate, fine aggregate and rebar are wetted by the self-hardening liquid, and coarse bone in the mixed aggregate layer. The materials are in intimate contact with each other from the outer peripheral surface of the pipe to the inside, and the gap between the coarse aggregates is made into fine aggregates.
Corrosion-resistant pipe filled with mortar with self-hardening liquid .
材が外周面から内側に相互に密に接触してなる請求項
(1) 記載の耐食性管。2. The coarse aggregate is in intimate contact with each other from the outer peripheral surface to the inner side by a centrifugal force generated by the rotation of the tube.
(1) Corrosion resistant pipe as described.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP3005834A JPH072328B2 (en) | 1991-01-22 | 1991-01-22 | Corrosion resistant tube |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP3005834A JPH072328B2 (en) | 1991-01-22 | 1991-01-22 | Corrosion resistant tube |
Related Parent Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2911585A Division JPS61188110A (en) | 1985-02-14 | 1985-02-14 | Corrosion-resistant pipe and manufacture thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPH04211906A JPH04211906A (en) | 1992-08-03 |
| JPH072328B2 true JPH072328B2 (en) | 1995-01-18 |
Family
ID=11622070
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP3005834A Expired - Lifetime JPH072328B2 (en) | 1991-01-22 | 1991-01-22 | Corrosion resistant tube |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH072328B2 (en) |
Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN100380050C (en) * | 2005-09-26 | 2008-04-09 | 梁乙次 | Method for manufacturing stainless steel flue pipe for coal-fired stove |
| KR100787919B1 (en) * | 2007-10-05 | 2007-12-24 | 평산에스아이 주식회사 | Water pipe breakage prevention device |
| CN103358398A (en) * | 2012-09-26 | 2013-10-23 | 苏州混凝土水泥制品研究院有限公司 | Method for producing high-strength pipe pile |
Family Cites Families (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS49106519A (en) * | 1973-02-10 | 1974-10-09 | ||
| JPH03264306A (en) * | 1991-01-22 | 1991-11-25 | Asou Cement Kk | Corrosion-resistant pipe |
-
1991
- 1991-01-22 JP JP3005834A patent/JPH072328B2/en not_active Expired - Lifetime
Also Published As
| Publication number | Publication date |
|---|---|
| JPH04211906A (en) | 1992-08-03 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| EXPY | Cancellation because of completion of term |