JPH0725220B2 - Image receptor for thermal transfer recording - Google Patents
Image receptor for thermal transfer recordingInfo
- Publication number
- JPH0725220B2 JPH0725220B2 JP60120915A JP12091585A JPH0725220B2 JP H0725220 B2 JPH0725220 B2 JP H0725220B2 JP 60120915 A JP60120915 A JP 60120915A JP 12091585 A JP12091585 A JP 12091585A JP H0725220 B2 JPH0725220 B2 JP H0725220B2
- Authority
- JP
- Japan
- Prior art keywords
- image receptor
- dyeing
- thermal transfer
- transfer recording
- alicyclic epoxy
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 238000004043 dyeing Methods 0.000 claims description 25
- 239000003822 epoxy resin Substances 0.000 claims description 12
- 229920000647 polyepoxide Polymers 0.000 claims description 12
- 125000002723 alicyclic group Chemical group 0.000 claims description 11
- 239000000986 disperse dye Substances 0.000 claims description 7
- 239000003505 polymerization initiator Substances 0.000 claims description 6
- 239000000126 substance Substances 0.000 claims description 5
- 150000001989 diazonium salts Chemical class 0.000 claims description 4
- 229920001187 thermosetting polymer Polymers 0.000 claims description 4
- 239000000758 substrate Substances 0.000 claims description 3
- 238000003848 UV Light-Curing Methods 0.000 claims description 2
- 229920005989 resin Polymers 0.000 description 6
- 239000011347 resin Substances 0.000 description 6
- 238000004040 coloring Methods 0.000 description 5
- 238000001723 curing Methods 0.000 description 5
- 239000000463 material Substances 0.000 description 5
- 239000011248 coating agent Substances 0.000 description 4
- 238000000576 coating method Methods 0.000 description 4
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 3
- YMWUJEATGCHHMB-UHFFFAOYSA-N Dichloromethane Chemical compound ClCCl YMWUJEATGCHHMB-UHFFFAOYSA-N 0.000 description 3
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 3
- 230000004927 fusion Effects 0.000 description 3
- 238000010438 heat treatment Methods 0.000 description 3
- -1 polypropylene Polymers 0.000 description 3
- YXALYBMHAYZKAP-UHFFFAOYSA-N 7-oxabicyclo[4.1.0]heptan-4-ylmethyl 7-oxabicyclo[4.1.0]heptane-4-carboxylate Chemical compound C1CC2OC2CC1C(=O)OCC1CC2OC2CC1 YXALYBMHAYZKAP-UHFFFAOYSA-N 0.000 description 2
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 2
- 230000000052 comparative effect Effects 0.000 description 2
- 239000000975 dye Substances 0.000 description 2
- LNEPOXFFQSENCJ-UHFFFAOYSA-N haloperidol Chemical compound C1CC(O)(C=2C=CC(Cl)=CC=2)CCN1CCCC(=O)C1=CC=C(F)C=C1 LNEPOXFFQSENCJ-UHFFFAOYSA-N 0.000 description 2
- QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 description 2
- 229910052753 mercury Inorganic materials 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 238000000859 sublimation Methods 0.000 description 2
- 230000008022 sublimation Effects 0.000 description 2
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- XMLYCEVDHLAQEL-UHFFFAOYSA-N 2-hydroxy-2-methyl-1-phenylpropan-1-one Chemical compound CC(C)(O)C(=O)C1=CC=CC=C1 XMLYCEVDHLAQEL-UHFFFAOYSA-N 0.000 description 1
- GRWFFFOEIHGUBG-UHFFFAOYSA-N 3,4-Epoxy-6-methylcyclohexylmethyl-3,4-epoxy-6-methylcyclo-hexanecarboxylate Chemical compound C1C2OC2CC(C)C1C(=O)OCC1CC2OC2CC1C GRWFFFOEIHGUBG-UHFFFAOYSA-N 0.000 description 1
- OECTYKWYRCHAKR-UHFFFAOYSA-N 4-vinylcyclohexene dioxide Chemical compound C1OC1C1CC2OC2CC1 OECTYKWYRCHAKR-UHFFFAOYSA-N 0.000 description 1
- 239000004925 Acrylic resin Substances 0.000 description 1
- 239000004342 Benzoyl peroxide Substances 0.000 description 1
- OMPJBNCRMGITSC-UHFFFAOYSA-N Benzoylperoxide Chemical compound C=1C=CC=CC=1C(=O)OOC(=O)C1=CC=CC=C1 OMPJBNCRMGITSC-UHFFFAOYSA-N 0.000 description 1
- 229920002284 Cellulose triacetate Polymers 0.000 description 1
- 239000004677 Nylon Substances 0.000 description 1
- 239000004743 Polypropylene Substances 0.000 description 1
- NNLVGZFZQQXQNW-ADJNRHBOSA-N [(2r,3r,4s,5r,6s)-4,5-diacetyloxy-3-[(2s,3r,4s,5r,6r)-3,4,5-triacetyloxy-6-(acetyloxymethyl)oxan-2-yl]oxy-6-[(2r,3r,4s,5r,6s)-4,5,6-triacetyloxy-2-(acetyloxymethyl)oxan-3-yl]oxyoxan-2-yl]methyl acetate Chemical compound O([C@@H]1O[C@@H]([C@H]([C@H](OC(C)=O)[C@H]1OC(C)=O)O[C@H]1[C@@H]([C@@H](OC(C)=O)[C@H](OC(C)=O)[C@@H](COC(C)=O)O1)OC(C)=O)COC(=O)C)[C@@H]1[C@@H](COC(C)=O)O[C@@H](OC(C)=O)[C@H](OC(C)=O)[C@H]1OC(C)=O NNLVGZFZQQXQNW-ADJNRHBOSA-N 0.000 description 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 1
- 239000000981 basic dye Substances 0.000 description 1
- 235000019400 benzoyl peroxide Nutrition 0.000 description 1
- 229910000019 calcium carbonate Inorganic materials 0.000 description 1
- 239000001913 cellulose Substances 0.000 description 1
- 229920002678 cellulose Polymers 0.000 description 1
- 229920002301 cellulose acetate Polymers 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 238000004132 cross linking Methods 0.000 description 1
- 125000000753 cycloalkyl group Chemical group 0.000 description 1
- 239000012954 diazonium Substances 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 125000003700 epoxy group Chemical group 0.000 description 1
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 239000000314 lubricant Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 229920001778 nylon Polymers 0.000 description 1
- 239000000123 paper Substances 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 229920000515 polycarbonate Polymers 0.000 description 1
- 239000004417 polycarbonate Substances 0.000 description 1
- 229920001225 polyester resin Polymers 0.000 description 1
- 239000004645 polyester resin Substances 0.000 description 1
- 229920000139 polyethylene terephthalate Polymers 0.000 description 1
- 239000005020 polyethylene terephthalate Substances 0.000 description 1
- 229920001721 polyimide Polymers 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 229920006254 polymer film Polymers 0.000 description 1
- 229920001155 polypropylene Polymers 0.000 description 1
- KCTAWXVAICEBSD-UHFFFAOYSA-N prop-2-enoyloxy prop-2-eneperoxoate Chemical compound C=CC(=O)OOOC(=O)C=C KCTAWXVAICEBSD-UHFFFAOYSA-N 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- 229920001169 thermoplastic Polymers 0.000 description 1
- 229920006230 thermoplastic polyester resin Polymers 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
- B41M5/00—Duplicating or marking methods; Sheet materials for use therein
- B41M5/50—Recording sheets characterised by the coating used to improve ink, dye or pigment receptivity, e.g. for ink-jet or thermal dye transfer recording
- B41M5/52—Macromolecular coatings
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
- B41M5/00—Duplicating or marking methods; Sheet materials for use therein
- B41M5/26—Thermography ; Marking by high energetic means, e.g. laser otherwise than by burning, and characterised by the material used
- B41M5/40—Thermography ; Marking by high energetic means, e.g. laser otherwise than by burning, and characterised by the material used characterised by the base backcoat, intermediate, or covering layers, e.g. for thermal transfer dye-donor or dye-receiver sheets; Heat, radiation filtering or absorbing means or layers; combined with other image registration layers or compositions; Special originals for reproduction by thermography
- B41M5/41—Base layers supports or substrates
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
- B41M5/00—Duplicating or marking methods; Sheet materials for use therein
- B41M5/50—Recording sheets characterised by the coating used to improve ink, dye or pigment receptivity, e.g. for ink-jet or thermal dye transfer recording
- B41M5/52—Macromolecular coatings
- B41M5/5254—Macromolecular coatings characterised by the use of polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds, e.g. vinyl polymers
Landscapes
- Thermal Transfer Or Thermal Recording In General (AREA)
- Fax Reproducing Arrangements (AREA)
Description
【発明の詳細な説明】 産業上の利用分野 本発明は感熱転写記録に供される受像体に関する。Description: FIELD OF THE INVENTION The present invention relates to an image receptor for thermal transfer recording.
従来の技術 熱転写による感熱記録方法の中で特に昇華性染料を用い
た昇華型熱転写記録方式は、写真に近い画像を得ること
ができる。昇華性染料として分散染料，塩基性染料等が
主に用いられているが、特に分散染料を色材に用いた場
合、受像体の染着層には分散染料に対して高染着性を示
す熱可塑性のポリエステル樹脂が主に用いられている。2. Description of the Related Art Among the thermal recording methods by thermal transfer, the sublimation type thermal transfer recording method using a sublimable dye can obtain an image close to a photograph. Disperse dyes and basic dyes are mainly used as sublimation dyes, but when a disperse dye is used as a coloring material, the dyeing layer of the image receptor shows a high dyeing property to the disperse dye. Thermoplastic polyester resins are mainly used.
発明が解決しようとする問題点 しかし、上記樹脂は染着性に優れているが耐熱性がかな
り低いため記録時に転写体（カラーシート）と融着す
る。DISCLOSURE OF THE INVENTION Problems to be Solved by the Invention However, although the above-mentioned resin has excellent dyeing property, it has a considerably low heat resistance, so that it fuses with the transfer body (color sheet) during recording.
又、上記樹脂以外にエポキシ系樹脂，酢酸セルロース系
樹脂，ナイロン系樹脂等も提案されているが耐熱性が低
い，あるいは染着性が低い，あるいは染着色の色相がず
れる等の理由により従来単独ではほとんど用いられてい
ない（例えば、特開昭58−212994号公報，特開昭58−21
5398号公報）。In addition to the above resins, epoxy resins, cellulose acetate resins, nylon resins, etc. have also been proposed, but they have been conventionally used alone because of their low heat resistance, low dyeability, or a shift in dyeing and coloring hue. Are rarely used (for example, JP-A-58-212994 and JP-A-58-21).
5398 publication).
本発明は、単独でも高染着性，高耐熱性，優れた色相を
与える染着性物質を有する受像体を構成することによ
り、記録濃度が高く、熱融着がなく、染着色の色相の優
れた受像体を得ることを目的とする。The present invention comprises an image receptor having a dyeing substance that gives high dyeability, high heat resistance, and excellent hue even by itself, so that the recording density is high, there is no heat fusion, and the hue of dyeing and coloring is high. The purpose is to obtain an excellent image receptor.
問題点を解決するための手段 基材上に脂環族エポキシ樹脂の熱硬化物あるいは重合開
始剤であるジアゾニウム化合物を用いた脂環族エポキシ
樹脂の紫外線硬化物を分散染料に対する染着性物質とし
て含む染着層を設ける。Means for Solving Problems A thermosetting product of an alicyclic epoxy resin on a substrate or an ultraviolet curing product of an alicyclic epoxy resin using a diazonium compound as a polymerization initiator is used as a dyeing substance for a disperse dye. A dyeing layer containing is provided.
作用 上記硬化樹脂は架橋性が優れているため高い耐熱性を有
し、又、エポキシ基とシクロアルキル基の寄与により高
い染着性と優れた色相を示すものと考えられる。Action It is considered that the above-mentioned cured resin has high heat resistance due to its excellent cross-linking property, and also exhibits high dyeability and excellent hue due to the contribution of the epoxy group and the cycloalkyl group.
実施例 第１図に示す本発明の一実施例は、基材１上に染着層２
を設けたものである。EXAMPLE An example of the present invention shown in FIG. 1 is a dyeing layer 2 on a substrate 1.
Is provided.
基材１は特に限定されるものでない。例えば、セルロー
ス紙，合成紙，高分子フイルム（シート），塗工紙，塗
工フイルム等を用いることができる。特に表面平滑性の
優れた紙，合成紙，ポリプロピレン，ポリエチレンテレ
フタレート，トリアセチルセルロース等が良好な画質を
与えるため有用である。The base material 1 is not particularly limited. For example, cellulose paper, synthetic paper, polymer film (sheet), coated paper, coated film and the like can be used. Particularly, paper having excellent surface smoothness, synthetic paper, polypropylene, polyethylene terephthalate, triacetyl cellulose and the like are useful because they give good image quality.
染着層２は、脂環族エポキシ樹脂の熱硬化物あるいは重
合開始剤であるジアゾニウム化合物を用いた脂環族エポ
キシ樹脂の紫外線硬化物を分散染料に対する染着性物質
として含む層、あるいは硬化樹脂そのものの層である。The dyeing layer 2 is a layer containing a thermosetting product of an alicyclic epoxy resin or a UV-curing product of an alicyclic epoxy resin using a diazonium compound as a polymerization initiator as a dyeing substance for a disperse dye, or a cured resin. It is a layer of itself.
脂環族エポキシ樹脂は、いずれも良好な特性を示す。例
えば、ビニルシクロヘキセンジオキシド,3,4−エポキシ
−６−メチルシクロヘキシルメチル−3,4−エポキシ−
６−メチルシクロヘキサンカルボキシレイト,3,4−エポ
キシシクロヘキシルメチル−3,4−エポキシシクロヘキ
サンカルボキシレイト等が特に有用である。All of the alicyclic epoxy resins show good characteristics. For example, vinylcyclohexene dioxide, 3,4-epoxy-6-methylcyclohexylmethyl-3,4-epoxy-
6-Methylcyclohexanecarboxylate, 3,4-epoxycyclohexylmethyl-3,4-epoxycyclohexanecarboxylate and the like are particularly useful.
脂環族エポキシ樹脂の硬化物は、例えば、脂環族エポキ
シ樹脂にベンゾイルペルオキシド等の硬化剤を添加して
加熱硬化、あるいは芳香族ジアゾニウム塩の重合開始剤
を添加して紫外線硬化させて得ることができる。The cured product of an alicyclic epoxy resin may be obtained, for example, by adding a curing agent such as benzoyl peroxide to an alicyclic epoxy resin to heat-cur it, or by adding a polymerization initiator of an aromatic diazonium salt and ultraviolet-curing it. You can
特に紫外線による硬化物は染着色の色相変化が硬化時の
製造条件にあまり依存しないため良好である。In particular, a cured product due to ultraviolet rays is good because the hue change of dyeing and coloring does not much depend on the manufacturing conditions at the time of curing.
染着層２は上記染着性物質の硬化物以外にアルミナ，酸
化チタン，シリカ，炭酸カルシウム等の各種粒子，滑
剤，界面活性剤，熱可塑性高分子，硬化高分子等を必要
に応じて含有している。The dyeing layer 2 contains various particles of alumina, titanium oxide, silica, calcium carbonate, etc., a lubricant, a surfactant, a thermoplastic polymer, a cured polymer, etc., if necessary, in addition to the cured product of the dyeing substance. is doing.
第２図，第３図は本発明の他の実施例をそれぞれ示した
ものである。第２図のように、基材３と染着層４の間に
アンカーコート層５を設けたり、第３図のように、基材
６上に設けた染着層７上にオーバコート層８を設けたり
することができる。アンカーコート層，オーバコート層
が染着性を有しておればなお良好である。2 and 3 show other embodiments of the present invention, respectively. An anchor coat layer 5 is provided between the base material 3 and the dyeing layer 4 as shown in FIG. 2, or an overcoat layer 8 is provided on the dyeing layer 7 provided on the base material 6 as shown in FIG. Can be provided. It is even better if the anchor coat layer and the overcoat layer have dyeability.
染着層の厚さは特に限定されるものでない。１μｍ前後
から100μｍ前後が一般的に用いられる。The thickness of the dyeing layer is not particularly limited. Around 1 μm to around 100 μm is generally used.
以下、具体的実施例を示す。Specific examples will be shown below.
（実施例１） アート紙の片面に3,4−エポキシシクロヘキシルメチル
−3,4−エポキシシクロヘキサンカルボキシレイト,50重
量部，重合開始材（pp−33,旭電化工業株式会社）2.5重
量部，酢酸エチル100重量部からなる塗工液をワイヤー
バーで塗工し、60℃の熱風で乾燥させた後、1KWの高圧
水銀灯を照射して厚さ３μｍの染着層を形成させ受像体
を得た。(Example 1) 3,4-epoxycyclohexylmethyl-3,4-epoxycyclohexanecarboxylate on one side of art paper, 50 parts by weight, polymerization initiator (pp-33, Asahi Denka Co., Ltd.) 2.5 parts by weight, acetic acid A coating liquid consisting of 100 parts by weight of ethyl was applied with a wire bar and dried with hot air at 60 ° C., and then a high-pressure mercury lamp of 1 KW was irradiated to form a dyeing layer having a thickness of 3 μm to obtain an image receptor. .
次に厚さ４μｍのポリイミドフイルムの上面に下記の分
子構造で示される分散染料４重量部，ポリカーボネート
４重量部，酸化チタン５重量部，塩化メチレン100重量
部を混合したインキをワイヤーバーで塗工して転写体を
得た。Next, an ink mixed with 4 parts by weight of a disperse dye represented by the following molecular structure, 4 parts by weight of polycarbonate, 5 parts by weight of titanium oxide and 100 parts by weight of methylene chloride is coated on the upper surface of a polyimide film having a thickness of 4 μm with a wire bar. Then, a transfer body was obtained.
上記受像体と転写体をサーマルヘッドとプラテンの間に
挾み下記の記録条件にて記録した。 The image receiving member and the transfer member were sandwiched between the thermal head and the platen and recorded under the following recording conditions.
主及び副走査のドット密度:8ドット/mm 記録電力:0.4W/ドット ヘッドの加熱時間:1〜3.5ms この結果、受像体と転写体はまったく融着を起こさず、
又、加熱時間3.5msにおける記録濃度は1.65であり、CIE
表色系の色度座標はｘ＝0.4220,y＝0.2358であり良好な
マゼンタの色相を示した。Main and sub-scan dot density: 8 dots / mm Recording power: 0.4 W / dot Head heating time: 1 to 3.5 ms As a result, the image receptor and transfer body do not fuse at all,
The recording density at a heating time of 3.5 ms is 1.65,
The chromaticity coordinates of the color system were x = 0.4220 and y = 0.2358, showing a good magenta hue.
（比較例１） アート紙の片面に水性ポリエステル樹脂〔バイロナール
MD1200,東洋紡績（株）〕15重量部，水30重量部からな
る塗工液をワイヤーバーで塗工後乾燥して、厚さ約５μ
ｍの染着層を有する受像体を得た。この受像体と実施例
の転写体を用い、実施例の記録条件にて記録させた結
果、加熱時間1.5msで転写体と受像体が融着した。(Comparative Example 1) Water-based polyester resin [Vylonal on one side of art paper
MD1200, Toyobo Co., Ltd.] A coating solution consisting of 15 parts by weight and 30 parts by weight of water is applied with a wire bar and dried to a thickness of about 5μ.
An image receptor having a dyeing layer of m was obtained. Using this image receptor and the transfer body of the example, recording was performed under the recording conditions of the example. As a result, the transfer body and the image receptor were fused to each other in a heating time of 1.5 ms.
（比較例２） アート紙の片面にエポキシアクリレート樹脂30重量部,2
−ヒドロキシ−２−メチルプロピオフエノン1.5重量
部，酢酸エチル100重量部からなる塗工液をワイヤーバ
ーで塗工後、60℃の熱風で溶媒を蒸発させた後、1KWの
高圧水銀灯を照射して厚さ約４μｍの染着層を形成さ
せ、受像体を得た。(Comparative Example 2) 30 parts by weight of epoxy acrylate resin on one side of art paper, 2
After coating a coating solution consisting of 1.5 parts by weight of hydroxy-2-methylpropiophenone and 100 parts by weight of ethyl acetate with a wire bar, evaporate the solvent with hot air at 60 ° C and irradiate it with a 1 KW high pressure mercury lamp. A dyeing layer having a thickness of about 4 μm was formed to obtain an image receptor.
この受像体と実施例の転写体を用い実施例の記録条件に
て記録させた結果、融着はまったく発生せず、記録濃度
も1.4であったが、色度座標はｘ＝0.3800,y＝0.2170で
あり青味がかったマゼンタであった。As a result of recording under the recording conditions of the example using this image receptor and the transfer body of the example, no fusion occurred and the recording density was 1.4, but the chromaticity coordinate was x = 0.3800, y = It was 0.2170 and was bluish magenta.
発明の効果 本発明は、染着層に脂環族エポキシ樹脂の熱硬化物ある
いは重合開始剤であるジアゾニウム化合物を用いた脂環
族エポキシ樹脂の紫外線硬化物を含むことにより記録濃
度が高く、熱融着がなく染着色の色相の優れた受像体を
得ることができる。EFFECT OF THE INVENTION The present invention has a high recording density by containing a thermosetting product of an alicyclic epoxy resin or an ultraviolet curing product of an alicyclic epoxy resin using a diazonium compound which is a polymerization initiator in the dyeing layer. It is possible to obtain an image receptor which is free from fusion and has an excellent hue of dyeing and coloring.
【図面の簡単な説明】 第１図〜第３図は、本発明の実施例における受像体の概
略断面図である。 1,3,6……基材、2,4,7……染着層。BRIEF DESCRIPTION OF THE DRAWINGS FIG. 1 to FIG. 3 are schematic cross-sectional views of an image receiver in an embodiment of the present invention. 1,3,6 …… Base material, 2,4,7 …… Dyeing layer.
───────────────────────────────────────────────────── フロントページの続き (72)発明者 田口 信義 大阪府門真市大字門真1006番地 松下電器 産業株式会社内 (56)参考文献 特開 昭61−112693（ＪＰ，Ａ) 特開 昭61−121993（ＪＰ，Ａ) ─────────────────────────────────────────────────── ─── Continuation of the front page (72) Inventor Nobuyoshi Taguchi 1006 Kadoma, Kadoma City, Osaka Prefecture Matsushita Electric Industrial Co., Ltd. (56) References JP 61-112693 (JP, A) JP 61-121993 (JP, A)
Claims (1)
るいは重合開始剤であるジアゾニウム化合物を用いた脂
環族エポキシ樹脂の紫外線硬化物を分散染料に対する染
着性物質として含む染着層を形成した熱転写記録用受像
体。1. Dyeing containing a thermosetting product of an alicyclic epoxy resin or a UV-curing product of an alicyclic epoxy resin using a diazonium compound as a polymerization initiator on a substrate as a dyeing substance for a disperse dye. A thermal transfer recording image receptor having a layer formed thereon.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP60120915A JPH0725220B2 (en) | 1985-06-04 | 1985-06-04 | Image receptor for thermal transfer recording |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP60120915A JPH0725220B2 (en) | 1985-06-04 | 1985-06-04 | Image receptor for thermal transfer recording |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS61277493A JPS61277493A (en) | 1986-12-08 |
| JPH0725220B2 true JPH0725220B2 (en) | 1995-03-22 |
Family
ID=14798139
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP60120915A Expired - Lifetime JPH0725220B2 (en) | 1985-06-04 | 1985-06-04 | Image receptor for thermal transfer recording |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH0725220B2 (en) |
Families Citing this family (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS62173295A (en) * | 1986-01-27 | 1987-07-30 | Nisshinbo Ind Inc | Sublimation-type thermal transfer image-receiving paper |
| JP2504787B2 (en) * | 1987-10-27 | 1996-06-05 | 新王子製紙株式会社 | Method of manufacturing image receiving sheet for thermal transfer recording |
| JPH02279387A (en) * | 1989-04-21 | 1990-11-15 | Oji Paper Co Ltd | Dye thermal transfer image receiving sheet |
| JP2580042B2 (en) * | 1989-07-18 | 1997-02-12 | 新王子製紙株式会社 | Dye thermal transfer image receiving sheet |
-
1985
- 1985-06-04 JP JP60120915A patent/JPH0725220B2/en not_active Expired - Lifetime
Also Published As
| Publication number | Publication date |
|---|---|
| JPS61277493A (en) | 1986-12-08 |
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