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JPH0728492B2 - Fire spread prevention coating remover and method for peeling wire / cable spread prevention coat - Google Patents
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JPH0728492B2 - Fire spread prevention coating remover and method for peeling wire / cable spread prevention coat - Google Patents

Fire spread prevention coating remover and method for peeling wire / cable spread prevention coat

Info

Publication number
JPH0728492B2
JPH0728492B2 JP63113155A JP11315588A JPH0728492B2 JP H0728492 B2 JPH0728492 B2 JP H0728492B2 JP 63113155 A JP63113155 A JP 63113155A JP 11315588 A JP11315588 A JP 11315588A JP H0728492 B2 JPH0728492 B2 JP H0728492B2
Authority
JP
Japan
Prior art keywords
spread prevention
fire spread
cable
prevention coating
coating
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
JP63113155A
Other languages
Japanese (ja)
Other versions
JPH01286711A (en
Inventor
真吉 中川
静二 鈴木
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Hitachi Cable Ltd
Original Assignee
Hitachi Cable Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Hitachi Cable Ltd filed Critical Hitachi Cable Ltd
Priority to JP63113155A priority Critical patent/JPH0728492B2/en
Publication of JPH01286711A publication Critical patent/JPH01286711A/en
Publication of JPH0728492B2 publication Critical patent/JPH0728492B2/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

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  • Removal Of Insulation Or Armoring From Wires Or Cables (AREA)

Description

【発明の詳細な説明】 [産業上の利用分野] 本発明は、電線・ケーブル等の外周に設けられた延焼防
止被覆を効率的に剥離できる剥離剤およびこれを使用し
た電線・ケーブル延焼防止被覆の剥離方法に関するもの
である。
DETAILED DESCRIPTION OF THE INVENTION [Industrial application] The present invention relates to a release agent capable of efficiently peeling a fire spread prevention coating provided on the outer periphery of an electric wire, a cable, etc., and an electric wire / cable fire spread prevention coating using the same. The present invention relates to a peeling method.

[従来の技術] 電線・ケーブルの延焼を防止するための一方法として、
シース外周に延焼防止塗料を塗布する方法が採用されて
きている。延焼防止塗料は、一般に、水性エマルジョン
をベースに有機難燃剤、無機充填剤、不燃性繊維、可塑
剤等を加えたものであり、これらの延焼防止塗料を電線
・ケーブルのシース外周に塗布し乾燥させると、シース
と接着した延焼防止被覆が形成される。電線・ケーブル
のシースとしては、ポリエチレン、ビニル、クロロプレ
ンゴム、シリコーンゴム等が用いられているが、特にビ
ニルシースと延焼防止塗料とは良く接着する。このた
め、電線・ケーブルを撤去する場合に延焼防止被覆を剥
離する作業が困難になっている。
[Prior Art] As one method for preventing the spread of electric wires and cables,
A method of applying a fire spread prevention coating to the outer circumference of the sheath has been adopted. In general, fire spread prevention paints are based on an aqueous emulsion with organic flame retardants, inorganic fillers, noncombustible fibers, plasticizers, etc. applied, and these fire spread prevention paints are applied to the outer circumference of the electric wire / cable sheath and dried. When this is done, a fire spread prevention coating adhered to the sheath is formed. Polyethylene, vinyl, chloroprene rubber, silicone rubber, etc. are used for the sheath of electric wires / cables, and especially the vinyl sheath and the fire spread prevention paint adhere well. For this reason, it is difficult to remove the fire spread prevention coating when removing the electric wire or cable.

一般に、延焼防止被覆を剥離する方法としては、アルカ
リ性水溶液を用いる方法、あるいはジクロロメタンを主
材料とした剥離液を用いる方法がある。
Generally, as a method for peeling off the flame spread prevention coating, there is a method using an alkaline aqueous solution or a method using a stripping solution containing dichloromethane as a main material.

[発明が解決しようとする課題] しかし、アルカリ性水溶液を用いる方法は、一部の耐ア
ルカリ性に劣るエマルジョンポリマに対しては効果があ
るものの、通常の延焼防止被覆に対しては剥離効果が殆
どない。又、ジクロロメタンを主材料とした剥離液を用
いる方法は延焼防止被覆を膨潤させると共に、ケーブル
シースをも膨潤させるという問題がある。すなわち、電
線・ケーブルは複数本がグループとなって布設され、こ
れらを一括して延焼防止被覆が設けられるが、グループ
の中の一部の電線・ケーブルのみの撤去および張替えの
場合、全体の延焼防止被覆を剥離してから撤去および張
替えが行われ、再度、延焼防止被覆が設けられることに
なる。このように、延焼防止塗料の剥離に際しては、撤
去する電線・ケーブルのみならず、その後も更に使用さ
れる電線・ケーブルにも剥離液の影響が及ぶことになる
ので、電線・ケーブルシースを膨潤させない剥離剤が望
まれる。
[Problems to be Solved by the Invention] However, the method using an alkaline aqueous solution is effective for some emulsion polymers having poor alkali resistance, but has little peeling effect for ordinary fire spread prevention coatings. . Further, the method using a stripping solution containing dichloromethane as a main material has a problem that the fire spread prevention coating is swollen and the cable sheath is also swollen. That is, multiple wires / cables are laid as a group, and a fire spread prevention coating is provided for all of them, but if only some of the wires / cables in the group are removed or replaced, the entire fire spread After the protective coating is peeled off, the protective coating is removed and replaced, and the fire spread protective coating is provided again. In this way, when peeling off the fire spread prevention paint, the peeling liquid will affect not only the electric wires / cables to be removed but also the electric wires / cables to be used thereafter, so that the electric wire / cable sheath will not swell. A release agent is desired.

本発明は、上記に基いてなされたもので、剥離性に優
れ、しかも電線・ケーブルシース等の内部プラスチック
材料に悪影響を与えずに常温での剥離が可能である延焼
防止被覆剥離剤およびこれを用いた電線・ケーブル延焼
防止被覆の剥離方法の提供を目的とするものである。
The present invention has been made based on the above, and has a good spreadability, and is capable of being peeled at room temperature without adversely affecting internal plastic materials such as electric wires and cable sheaths, etc. The purpose of the present invention is to provide a method for peeling off the used wire / cable spread prevention coating.

[課題を解決するための手段] 本発明の剥離剤は、ジエチレングリコールモノエチルエ
ーテルアセテートに水、水性エマルジョン及び無水珪酸
を含有せしめてなることを特徴とするものである。ま
た、本発明の剥離方法は、電線・ケーブル外周に上記剥
離剤を塗布することにより延焼防止被覆にジエチレング
リコールモノエチルエーテルアセテートを浸透させ、し
かる後延焼防止被覆を剥離することを特徴とするもので
ある。
[Means for Solving the Problem] The release agent of the present invention is characterized by comprising diethylene glycol monoethyl ether acetate containing water, an aqueous emulsion and silicic acid anhydride. Further, the stripping method of the present invention is characterized in that diethylene glycol monoethyl ether acetate is permeated into the fire spread prevention coating by applying the above-mentioned release agent to the outer periphery of the electric wire / cable, and then the fire spread prevention coating is peeled off. is there.

本発明が適用される延焼防止被覆を形成する塗料として
は、水性エマルジョンをベースに有機難燃剤、難燃助
剤、無機充填剤、不燃性繊維、可塑剤等を加えたものが
代表例としてあげられる。水性エマルジョンとしては、
酢酸ビニル系エマルジョン、アクリル系エマルジョンな
どが、有機難燃剤としては、塩素化パラフィン、塩素化
ナフタリン、デカブロモジフェニルオキサイド、ポリり
ん酸アンモニウムなどが、難燃助剤としては、三酸化ア
ンチモン、ほう酸亜鉛などが、無機充填剤としては水和
アルミナ、炭酸カルシウム、含水ケイ酸マグネシウム、
クレー、チタン白、タルクなどが、不燃性繊維として
は、セラミック繊維、フェノール繊維、ガラス繊維など
が、可塑剤としては、トリス(β−クロロエチル)ホス
フェート、塩素化ビフェニル、フタル酸ジブチルなどが
それぞれあげられる。
As a typical example of a paint for forming a flame spread prevention coating to which the present invention is applied, an organic emulsion containing an organic flame retardant, a flame retardant aid, an inorganic filler, a nonflammable fiber, a plasticizer and the like is used. To be As an aqueous emulsion,
Vinyl acetate emulsions and acrylic emulsions, organic flame retardants such as chlorinated paraffin, chlorinated naphthalene, decabromodiphenyl oxide, ammonium polyphosphate, and flame retardant aids such as antimony trioxide and zinc borate. As an inorganic filler, hydrated alumina, calcium carbonate, hydrous magnesium silicate,
Clay, white titanium, talc, etc., nonflammable fibers such as ceramic fibers, phenol fibers, glass fibers, etc., plasticizers such as tris (β-chloroethyl) phosphate, chlorinated biphenyls, dibutyl phthalate, etc. To be

ジエチレングリコールモノエチルエーテルアセテートは
延焼防止被覆を膨潤させる機能を有するものである。こ
のものは、水との相溶性に優れており、どの割合でも希
釈できる。ジエチレングリコールモノエチルエーテルア
セテートに水を加えることによりその揮発性を低下さ
せ、安全性を大幅に改善できる。しかし、ジエチレング
リコールモノエチルエーテルアセテート〜水系では粘度
が極めて低いため、延焼防止被覆外周に設ける際のハケ
塗が困難であると共に、付着量が少ないため作業性に問
題がある。本発明ではこれを解決するために、ジエチレ
ングリコールモノエチルエーテルアセテート〜水系に、
水性エマルジョン及び無水珪酸を含有せしめることによ
り増粘して塗料化し、これを延焼防止被覆外周に塗布で
きるようにしたものである。
Diethylene glycol monoethyl ether acetate has a function of swelling the fire spread prevention coating. This product has excellent compatibility with water and can be diluted at any ratio. By adding water to diethylene glycol monoethyl ether acetate, its volatility can be lowered and safety can be greatly improved. However, since the viscosity of diethylene glycol monoethyl ether acetate to water is extremely low, it is difficult to apply a brush when it is provided on the outer periphery of the flame spread prevention coating, and the adhesion amount is small, which causes a problem in workability. In order to solve this in the present invention, diethylene glycol monoethyl ether acetate-water system,
By adding an aqueous emulsion and silicic acid anhydride, the viscosity is increased to form a paint, which can be applied to the outer periphery of the fire spread prevention coating.

無水珪酸は、平均粒径が8〜20mμの微粒子状のものが
増粘作用の点から好ましく、ジエチレングリコールモノ
エチルエーテルアセテート100重量部に対し3〜10重量
部含有せしめることにより増粘し、ハケ塗りが可能にな
る。
The silicic acid anhydride is preferably in the form of fine particles having an average particle size of 8 to 20 mμ from the viewpoint of thickening action. Thickening is achieved by adding 3 to 10 parts by weight to 100 parts by weight of diethylene glycol monoethyl ether acetate, and applying a brush. Will be possible.

水性エマルジョンは、剥離剤の乾燥後に塗膜を形成させ
るために含有させるもので、これによって剥離剤に含ま
れる無水珪酸等の無機粉末が脱落するのが防止される。
水性エマルジョンとしては、酢酸ビニル系エマルジョ
ン、アクリル系エマルジョンなどがあげられ、ジエチレ
ングリコールモノエチルエーテルアセテート100重量部
に対して0.3〜5重量部の範囲で含有させることが好ま
しい。
The aqueous emulsion is contained in order to form a coating film after the release agent is dried, and this prevents inorganic powder such as silicic acid anhydride contained in the release agent from falling off.
Examples of the aqueous emulsion include vinyl acetate emulsions and acrylic emulsions, and it is preferable to add 0.3 to 5 parts by weight to 100 parts by weight of diethylene glycol monoethyl ether acetate.

なお、本発明における延焼防止被覆剥離剤には、上記成
分のほかに必要に応じてクレー、酸化チタンのような無
機充填剤、顔料その他の添加剤を加えてもよい。
In addition to the above components, an inorganic filler such as clay and titanium oxide, a pigment and other additives may be added to the stripping agent for preventing spread of fire in the present invention.

[発明の実施例] 第1表に示すように2種類の延焼防止塗料A、Bを調整
し、これをビニルシースケーブル(外径12mm)外周に乾
燥後の厚さが1.5mmとなるように塗布し、塗布後室温で1
20時間乾燥して延焼防止被覆とした。次に、第2表に示
すように4種類の剥離剤a,b,c,dを調整し、これら剥離
剤をケーブルの延焼防止被覆外周にハケ塗りにより塗布
した。なお、塗布量は、ケーブル長さ20cm当り14gとし
た。
[Examples of the Invention] As shown in Table 1, two kinds of fire spread prevention paints A and B were prepared and applied to the outer circumference of a vinyl sheath cable (outer diameter 12 mm) so that the thickness after drying would be 1.5 mm. And apply at room temperature for 1
It was dried for 20 hours to give a fire spread prevention coating. Next, as shown in Table 2, four kinds of release agents a, b, c, d were prepared, and these release agents were applied by brush coating on the outer periphery of the fire spread prevention coating of the cable. The coating amount was 14 g per 20 cm of cable length.

延焼防止被覆とビニルシースとの剥離状況およびビニル
シース特性について評価した結果を第3表に示した。
Table 3 shows the results of evaluation of the peeling state between the flame spread prevention coating and the vinyl sheath and the vinyl sheath characteristics.

第3表から明らかな通り、ジエチレングリコールモノエ
チルエーテルアセテートを用いた剥離剤の場合は室温で
24時間後に容易に剥離を行えることができた。又、延焼
防止被覆を剥離した後のビニルシースの溶媒吸収率は2
%以下であり、ビニルシースへの影響は殆どなく、引張
強さおよび伸びの低下は極めて少ない。これに対し、ジ
クロロメタンを使用した場合(比較例)、剥離は容易に
行えるがビニルシースを膨潤軟化させることから、引張
強さは大幅に低下し、逆に伸びが大きくなる。
As is clear from Table 3, in the case of a release agent using diethylene glycol monoethyl ether acetate,
The peeling could be easily performed after 24 hours. Also, the solvent absorption rate of the vinyl sheath after peeling off the fire spread prevention coating is 2
% Or less, there is almost no effect on the vinyl sheath, and the decrease in tensile strength and elongation is extremely small. On the other hand, when dichloromethane is used (comparative example), peeling can be easily performed, but the vinyl sheath is swollen and softened, so that the tensile strength is significantly reduced and the elongation is increased.

[発明の効果] 以上説明してきた通り、本発明によれば、延焼防止被覆
への塗布が容易であり、しかもケーブルシース等の材料
に悪影響を与えることなく延焼防止被覆の剥離を行うこ
とができる延焼防止被覆剥離剤を実現でき、この使用に
より、極めて容易に電線・ケーブル外周の延焼防止被覆
を剥離することができるようになる。
[Effects of the Invention] As described above, according to the present invention, it is easy to apply the fire spread prevention coating, and the fire spread prevention coating can be peeled off without adversely affecting the material such as the cable sheath. A fire spread prevention coating release agent can be realized, and by using this, the fire spread prevention coating on the outer periphery of an electric wire or cable can be peeled off very easily.

又、本発明の剥離剤は、室温で十分な剥離効果を有する
と共に、揮発性、毒性が殆どなく安全性に優れたもので
ある。
In addition, the stripping agent of the present invention has a sufficient stripping effect at room temperature, is almost volatile and has little toxicity, and is excellent in safety.

Claims (2)

【特許請求の範囲】[Claims] 【請求項1】ジエチレングリコールモノエチルエーテル
アセテートに水、水性エマルジョン及び無水珪酸を含有
せしめてなることを特徴とする延焼防止被覆剥離剤。
1. A fire spread preventing coating release agent comprising diethylene glycol monoethyl ether acetate containing water, an aqueous emulsion and silicic acid anhydride.
【請求項2】電線・ケーブル上に設けられた延焼防止被
覆の外周にジエチレングリコールモノエチルエーテルア
セテートに水、水性エマルジョン及び無水珪酸を含有せ
しめてなる延焼防止被覆剥離剤を塗布し、しかる後延焼
防止被覆を剥離することを特徴とする電線・ケーブル延
焼防止被覆の剥離方法。
2. A fire spread prevention coating release agent comprising diethylene glycol monoethyl ether acetate containing water, an aqueous emulsion and silicic acid anhydride is applied to the outer periphery of the fire spread prevention coating provided on an electric wire / cable, and thereafter fire spread prevention. A method for stripping a wire / cable spread prevention coating, which comprises stripping the coating.
JP63113155A 1988-05-10 1988-05-10 Fire spread prevention coating remover and method for peeling wire / cable spread prevention coat Expired - Lifetime JPH0728492B2 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP63113155A JPH0728492B2 (en) 1988-05-10 1988-05-10 Fire spread prevention coating remover and method for peeling wire / cable spread prevention coat

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP63113155A JPH0728492B2 (en) 1988-05-10 1988-05-10 Fire spread prevention coating remover and method for peeling wire / cable spread prevention coat

Publications (2)

Publication Number Publication Date
JPH01286711A JPH01286711A (en) 1989-11-17
JPH0728492B2 true JPH0728492B2 (en) 1995-03-29

Family

ID=14604959

Family Applications (1)

Application Number Title Priority Date Filing Date
JP63113155A Expired - Lifetime JPH0728492B2 (en) 1988-05-10 1988-05-10 Fire spread prevention coating remover and method for peeling wire / cable spread prevention coat

Country Status (1)

Country Link
JP (1) JPH0728492B2 (en)

Family Cites Families (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH0669254B2 (en) * 1986-12-12 1994-08-31 日立電線株式会社 Peeling method for wire / cable spread prevention coating
JPH0669255B2 (en) * 1986-12-17 1994-08-31 日立電線株式会社 Peeling method for wire / cable spread prevention coating
JPH0687618B2 (en) * 1987-01-08 1994-11-02 日立電線株式会社 Fire spread prevention coating remover and method of peeling electric wire / cable spread prevention coat
JPH0687619B2 (en) * 1987-01-08 1994-11-02 日立電線株式会社 Fire spread prevention coating remover and method of peeling electric wire / cable spread prevention coat
JPH01117614A (en) * 1987-10-30 1989-05-10 Hitachi Cable Ltd Stripping agent of coating for preventing of spread of fire

Also Published As

Publication number Publication date
JPH01286711A (en) 1989-11-17

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