JPH0729900B2 - Solid alcohol-in-polyhydric alcohol emulsion cosmetics - Google Patents

Description

DETAILED DESCRIPTION OF THE INVENTION [Industrial field of application] The present invention relates to a solid type polyhydric alcohol in oil essentially containing silicone oil, a solid wax, a polyhydric alcohol and a polyoxyalkylene-modified organopolysiloxane. More specifically, it relates to a solid type polyhydric alcohol type oil-in-oil type cosmetic composition having a novel feeling of use that has good stability and is solid and has moistness and moisture when applied to the skin. .

[Prior Art] As a base type of solid cosmetics, there are solid oily type in which oil is solidified, solid press type in which powder or a mixture of powder and oil is pressed. , Each of which is used according to the purpose and method of use of the cosmetic. For example, solid oily types are used for stick-shaped cosmetics such as lipsticks, and solid press-types are generally used for foundations used for puffs and sponges. In recent years, lipsticks containing water and polyhydric alcohol have been investigated and put on the market, but those with a large amount of polyhydric alcohol are not known in the market because it is difficult to obtain stable products. . Furthermore, when a volatile oil agent is used, it is difficult to obtain a highly stable one, and there are many restrictions such as the need to fill a highly airtight container. That is, in the prior art, stable polyhydric alcohol type emulsion cosmetics in oil with good stability have not been found, and further, those containing a large amount of polyhydric alcohol using a volatile oil agent are not known. .

On the other hand, generally, emulsion type cosmetics are often used as basic cosmetics because they can be mixed with water and polyhydric alcohols and have high treatment properties. In the case of the emulsified type, the content state that can be selected is a fluid milky liquid or a liquid cream with a low fluidity, and the container form to be filled is restricted to have fluidity, and if it is a creamy fluid. A bottle or a tube-shaped container is filled in a bottle-shaped container if it is an emulsion. Therefore, the emulsified cosmetic composition has a high effect on the skin but is inferior in portability.

In recent years, studies have been conducted on cosmetics using silicone oil as a water-repellent base. This is because the silicone oil has excellent water repellent properties, so after application, the coating film of the cosmetic composition does not easily drop on water or sweat.
It is used in oily solid or water-in-oil emulsion type emulsion or creamy cosmetics in which the oil phase is a continuous phase. In addition, studies have been conducted on the blending of volatile oil agents. The purpose of this is to suppress the stickiness of the oil component, which is a drawback of the oily solid form or the water-in-oil type emulsion cream form due to the volatilization of the oil component after application to the skin by using a volatile oil agent. However, solid emulsified cosmetics using silicone oil, particularly solid emulsified cosmetics using volatile silicone oil, are not known because they are difficult to stabilize.

[Problems to be Solved by the Invention] In view of such circumstances, the present inventors have aimed to obtain a solid cosmetic having good stability and excellent feel in an emulsion system using silicone oil. As a result of earnest research,
A solid type polyhydric alcohol-type emulsified cosmetic in which a silicone oil, a solid wax, and a polyhydric alcohol are emulsified by using a polyoxyalkylene-modified organopolysiloxane has extremely good stability and is excellent in the skin. We found that it has a new feeling of use when applied, and also has excellent feeling of use such as "spreading", "tsuki", and "mochi", and that the range of container forms to be filled can be expanded. The present invention has been completed.

[Means for Solving the Problems] That is, the present invention comprises a silicone oil, and 3 to 30% by weight of a solid wax containing a straight-chain and / or branched hydrocarbon having 25 to 52 carbon atoms as a main component. A silicone oil containing 5% by weight or more of a polyhydric alcohol and one or more polyoxyalkylene-modified organopolysiloxanes represented by the following structural formulas [1], [2], [3] and [4]. Polyhydric alcohol type emulsification in solid oil, characterized in that it contains 10 to 60% by weight of the volatile silicone oil represented by the structural formulas [5] and [6] described below based on the total amount of the cosmetic. It is to provide cosmetics.

(In the formula, R is an alkyl group having 1 to 3 carbon atoms or a phenyl group, R'is hydrogen, or an alkyl group having 1 to 12 carbon atoms,
p is an integer of 1 to 5, m is an integer of 5 to 100, n and x are integers of 1 to 50, and t and y are integers of 0 to 50. ) The constitution of the present invention will be described below.

The polyhydric alcohol type emulsion cosmetics in solid oil described in the present invention are those which have no fluidity and solidify (including pastes) in the temperature range (0 ° C to 50 ° C) normally used as cosmetics.

The silicone oil used in the present invention is usually used in cosmetics. It is a dialkylpolysiloxane such as dimethylpolysiloxane, dimethylcyclopolysiloxane and diethylpolysiloxane, an alkylarylpolysiloxane such as methylphenylpolysiloxane, a diarylpolysiloxane and a fatty acid modification. Polysiloxane, higher alcohol-modified polysiloxane, amino-modified polysiloxane, and polyoxyalkylene-modified organopolysiloxane other than structural formulas [1], [2], [3], and [4] are used.

The blending amount of silicone oil is related to other oil phase components, but is preferably 30 to 97% by weight in the oil phase and 5 to 85% by weight in the total cosmetics. In particular, if it is desired to obtain a product that is less sticky to the touch, it is preferable to use the volatile silicone oil represented by the structural formulas [5] and [6].
30 to 97% by weight and 10 to 60% by weight of the total cosmetics can be blended in any ratio.

The solid wax used in the present invention may be one normally used in cosmetics, such as paraffin wax, petroleum wax such as microcrystalline wax, mineral wax such as ozokerite and ceresin, natural wax such as carnauba wax and candelilla wax, or It is possible to exemplify a mixture of two or more kinds of wax having a melting point of 50 ° C. or more, but particularly a mixture of linear and / or branched hydrocarbons having a linear hydrocarbon number of 25 to 52. What is contained as a main component is preferable. The type of wax used is selected according to the type of oil used, but wax esters such as carnauba wax and candelilla wax are difficult to obtain when used alone, and straight-chain and / or branched carbonization is difficult. It is preferable to mix with a hydrogen wax. In addition, since hydrocarbon solid waxes that are generally commercially available are obtained as a mixture, they have a distribution of carbon numbers, and also contain isoparaffin and naphthene, but even in that case, the main component has 25 to 52 carbon atoms. Anything will do. The amount of the solid wax can be adjusted according to the required hardness, but the ratio of oil phase component: solid wax is preferably 20: 1 to 3: 1 and is preferably 3 to 30% by weight of the total cosmetic composition. Is 5 to 20% by weight
Is blended.

The polyoxyalkylene-modified organopolysiloxane used in the present invention has the above general formulas [1], [2],
The one represented by [3] or [4], containing 5 to 40% of a polyoxyalkylene group in the molecule and having a molecular weight of 1000 or more of the polyoxyalkylene-modified organopolysiloxane is used. The amount of the polyoxyalkylene-modified organopolysiloxane blended is selected according to the amount of the aqueous phase to be emulsified, but is preferably 0.2 to 10% by weight based on the total cosmetics.

Examples of the polyhydric alcohol used in the present invention include ethylene glycol, propylene glycol, trimethylene glycol, 1,2-butylene glycol, 1,3-butylene glycol, tetramethylene glycol, 2,3-butylene glycol. , Pentamethylene glycol, dihydric alcohol, glycerin, trimethylolpropane,
Trivalent alcohols such as 1,2,6-hexanetriol, tetravalent alcohols such as pentaerythritol, pentavalent alcohols such as xylitol, hexavalent alcohols such as sorbitol and mannitol, diethylene glycol, dipropylene glycol, triethylene. Polyhydric alcohol polymers such as glycol, polypropylene glycol and polyglycerin, dihydric alcohols such as ethylene glycol monomethyl ether, ethylene glycol monoethyl ether, ethylene glycol monobutyl ether, ethylene glycol dimethyl ether, ethylene glycol diethyl ether and ethylene glycol dibutyl ether. Alkyl ethers, diethylene glycol monomethyl ether, diethylene glycol monoethyl ether, diethylene glycol Dihydric alcohol alkyl ethers such as nobutyl ether, dihydric alcohol ether esters such as ethylene glycol monomethyl ether acetate and propylene glycol monomethyl ether acetate, glycerin monoalkyl ethers such as batyl alcohol, sorbitol, maltitol, maltotriose, mannitol, Examples thereof include sugar alcohols such as sucrose, erythritol, fructose, maltose, xylitose, and starch-decomposing sugar reducing alcohols. The amount of polyhydric alcohol blended in the present invention is 5% by weight in the total cosmetics.
It is preferable to mix the polyhydric alcohol in the above manner, and it is preferable that the polyhydric alcohol and the other components in the polyhydric alcohol phase contain 50% by weight or more of the polyhydric alcohol.

Further, in the present invention, pigment powder can be blended in addition to the essential components of silicone oil, solid wax, polyhydric alcohol and polyoxyalkylene-modified organopolysiloxane. The pigment powder used in this case is not particularly limited as long as it is usually used in cosmetics, and inorganic pigments, organic pigments, powders of arbitrary pigments such as metal pigments can be blended, and as the inorganic pigment, for example, Talc, Kaolin, Calcium carbonate, Zinc flower, Titanium dioxide, Red iron oxide, Yellow iron oxide, Black iron oxide, Ultramarine, Titanium coated mica, Bismuth oxychloride, Red iron oxide, Caking pigment, Gunzhou pink, Chromium hydroxide, Mica titanium, yellow iron oxide, chromium oxide, aluminum cobalt oxide, navy blue, black iron oxide, carbon black, silicic anhydride, magnesium silicate, bentonite, mica, zirconium oxide, magnesium oxide, zinc oxide, titanium oxide, light calcium carbonate , Heavy calcium carbonate, light magnesium carbonate, heavy magnesium carbonate, calamine, etc. It is. It is particularly preferable that the pigment powder is hydrophobized. Hydrophobic treatment methods include those whose surface is treated with high-viscosity silicone, those whose surface has been coated with a silicone resin that has reacted with alkylhydrogenpolysiloxane, and those which have undergone alkene treatment, cationic activators, and anionic activators. Examples thereof include those treated with one kind or two or more kinds of nonionic activators, and those whose surface is coated with wax. However, the surface is not particularly limited as long as it is hydrophobic. Further, the blending amount of the pigment powder is preferably 50% by weight or less based on the total cosmetics.

Further, the polyhydric alcohol type emulsion cosmetics in solid oil of the present invention may contain components usually used in cosmetics as long as the effects of the present invention are not impaired. For example, water, mucopolysaccharides (sodium hyaluronate, etc.) as a water phase component, moisturizers such as organic acids and organic salts (amino acids, amino acid salts, oxy acid salts, etc.), petroleum jelly, lanolin as an oil phase component,
Solid / semi-solid oils such as silicone wax, higher fatty acids and higher alcohols, squalane, liquid paraffin, ester oils, triglycerides, volatile hydrocarbon oils, liquid oils such as fluorocarbons, cationic surfactants, anionic surfactants, Nonionic surfactants and other surfactants, vitamin E, vitamin E acetate and other drugs, astringents,
Antioxidants, preservatives, fragrances, dibasic sodium phosphate, etc.
The pH adjusting agent, clay mineral, thickening agent, ultraviolet absorber and the like can be added to the emulsified cosmetic composition of the present invention. It is preferable to mix water among the above-mentioned compoundable components within a range that does not impair the effects of the invention, in order to impart a refreshing feeling to use.

[Effects of the Invention] In the solid type polyhydric alcohol type emulsion cosmetic of the present invention, an oil phase containing a volatile silicone oil and a solid wax is used as an external phase, and a polyoxyalkylene-modified organopolysiloxane is used as an emulsifier. The polyhydric alcohol can be mixed in a large amount by the above, and it is a solid type without fluidity,
It has excellent temperature stability with no cracks or cracks, and has a new feel of "moisturizing and moisturizing" when applied, and also excellent feel of "spread", "stickiness", "mochi", etc. It has the characteristic that Especially when it is used as a makeup cosmetic, it is a novel product in that it has a long-lasting makeup and is solid, but it can also contain various polyhydric alcohols as an internal phase component, and that the feeling during use is moist and moist. It was Further, it has an effect that the range of the container form to be filled can be expanded due to excellent stability.

[Examples] The effects of the present invention will be described below with reference to Examples, but the scope of the present invention is not limited thereby. All blending amounts in the examples represent% by weight.

Example 1 (1) Decamethylcyclopentasiloxane 38 (2) Aristo wax 165 ° F 10 (3) Polyoxyalkylene-modified organopolysiloxane (general formula [1], molecular weight 6000 polyoxyethylene group 20
(% By weight) 2 (4) Glycerin 50 (1)-(3) raw materials are heated to 80 ℃, in which (4)
After adding and emulsifying, the mixture was cooled to room temperature to obtain an intended polyhydric alcohol type emulsion cosmetic in solid oil. Hereinafter, Examples 2 and 3 and Comparative Examples 1 to 6 were carried out by the same method as the manufacturing method of Example 1.

Example 2 (1) Decamethylcyclopentasiloxane 38 (2) Ceresin B 10 (3) Polyoxyalkylene-modified organopolysiloxane (general formula [1], molecular weight 6000 polyoxyethylene group 20
Wt%) 2 (4) Glycerin 50 Example 3 (1) Decamethylcyclopentasiloxane 38 (2) PM wax 82 10 (3) Polyoxyalkylene-modified organopolysiloxane (general formula [1], molecular weight 6000 polyoxyethylene Base 20
Wt%) 2 (4) Glycerin 50 Comparative Example 1 (1) Decamethylcyclopentasiloxane 38 (2) Dextrin palmitate partial ester 10 (3) Polyoxyalkylene-modified organopolysiloxane (general formula [1], molecular weight 6000 poly Oxyethylene group 20
Wt%) 2 (4) Glycerin 50 Comparative Example 2 (1) Decamethylcyclopentasiloxane 38 (2) Stearic acid 10 (3) Polyoxyalkylene-modified organopolysiloxane (general formula [1], molecular weight 6000 polyoxyethylene group) 20
Wt%) 2 (4) Glycerin 50 Comparative Example 3 (1) Decamethylcyclopentasiloxane 38 (2) Hydrogenated castor oil 10 (3) Polyoxyalkylene-modified organopolysiloxane (general formula [1], molecular weight 6000 polyoxyethylene Base 20
% By weight) 2 (4) Glycerin 50 A polyhydric alcohol type emulsion cosmetic in solid oil obtained by using the waxes of Examples 1 to 3 and Comparative Examples 1 to 3 was placed in a constant temperature bath at 25 ° C and 50 ° C. Table 1 shows the results of examining the stability of cracks, cracks, separation, etc., after leaving them for a long time.

-Stability: Cracked and cracked at 25 ° C, 50 ° C, 3 weeks, no change in state due to separation was rated as good, and a change in state was rated as poor.

As is clear from Table 1, the solid water-in-oil type emulsion cosmetics of Examples 1 to 3 were stable without cracks, cracks, and separation due to volatilization.

Example 4 (1) Dimethylpolysiloxane (6 cps) 38 (2) Aristo wax 165 ° F 10 (3) Polyoxyalkylene-modified organopolysiloxane (general formula [1], molecular weight 6000 polyoxyethylene group 20
Wt%) 2 (4) Glycerin 50 Comparative Example 4 (1) Decamethylcyclopentasiloxane 38 (2) Aristo wax 165 ° F 10 (3) Diglyceryl diisostearate 2 (4) Glycerin 50 Comparative Example 5 (1 ) Liquid paraffin 38 (2) Aristo wax 165 ° F 10 (3) Polyoxyalkylene-modified organopolysiloxane (general formula [1], molecular weight 6000 polyoxyethylene group 20
Wt%) 2 (4) Glycerin 50 Comparative Example 6 (1) Decamethylcyclopentasiloxane 85 (2) Aristo wax 165 ° F 10 (3) Polyoxyalkylene-modified organopolysiloxane (general formula [1], molecular weight 6000 poly Oxyethylene group 20
%) 2 (4) Glycerin 3 The solid-state water-in-oil type emulsion cosmetics of Examples 1 and 4 and Comparative Examples 5 and 6 were used to evaluate the feel of use. The results are shown in Table 2. The product obtained in Comparative Example 4 was separated immediately after emulsification and did not become a good solid form.

Panel 20 people More than 15 people answered "Good" ○ 7 to 14 people △ 6 people or less × The solid emulsified cosmetics obtained in Examples 1 and 4 gave a new moist and non-greasy feeling. It was something I had.

Example 5 Foundation (1) Decamethylcyclopentasiloxane 38 (2) Aristo wax 165 ° F 10 (3) Polyoxyalkylene-modified organopolysiloxane (general formula [1], molecular weight 6000 polyoxyethylene group 20
(% By weight) 2 (4) Hydrophobized pigment powder 30 (5) Glycerin 20 (6) Preservative proper amount (7) Perfume proper amount (1) to (3) and (7) are heated to 80 ° C and dissolved (4) ) And disperse with a homogenizer at 80 ° C. Further, the mixture of (5) and (6) previously heated to 80 ° C. is added and emulsified. Then, the mixture was filled in a container and cooled to room temperature to obtain a target solid polyhydric alcohol-in-oil emulsified foundation.

Comparative Example 7 (1) Decamethylcyclopentasiloxane 38 (2) Carnauba wax 10 (3) Polyoxyalkylene-modified organopolysiloxane (general formula [1], molecular weight 6000 polyoxyethylene group 20
Wt%) 2 (4) Hydrophobized pigment powder 30 (5) Glycerin 20 Preservative proper amount Perfume proper amount Produced by the same production method as in Example 5.

The solid foundations obtained in Example 5 and Comparative Example 7 were filled in glass bottles and allowed to stand in a thermostat at 25 ° C. and 50 ° C., and the stability was examined.

Safety: Cracked and cracked at 25 ° C, 50 ° C, 3 weeks, no change in state due to separation was considered good, and a change in state was considered poor.

As is clear from Table 3, the solid foundation of Example 5 was stable.

Example 6 Polyhydric alcohol type emulsion foundation in stick-like oil (1) Octamethylcyclotetrasiloxane 15 (2) Decamethylcyclopentasiloxane 20 (3) Glyceryltriisooctanate 3 (4) Polyoxyalkylene-modified organopolysiloxane (General formula [3], molecular weight 8,000 polyoxyethylene group 30
(% By weight) 2 (5) Cesylene wax 10 (6) Hydrophobized pigment powder 30 (7) Perfume proper amount (8) Ion-exchanged water 2 (9) Glycerin 12 (10) 1,3 Butylene glycol 6 (11) Preservative The appropriate amount (1) to (5) and (7) of the agent is heated to 80 ° C. and dissolved,
Add (6) and disperse with a homogenizer at 80 ° C. Further, the mixture of (8) to (11) previously heated to 80 ° C. is added and emulsified. Then, it was filled in a stick-shaped container and cooled to room temperature to obtain a target stick-shaped emulsion foundation.

Example 7 Urea-blended solid cosmetic (1) Trimethylsiloxysilicate 3 (2) Dimethylpolysiloxane 10 (3) Decamethylcyclopentasiloxane 20 (4) Hydrocarbon wax (32 to 40 carbon atoms) 10 (5) Polyoxyalkylene-modified organopolysiloxane (general formula [1], molecular weight 3000 polyoxyethylene group 20
Wt%) 2 (6) Propylene glycol 25 (7) Tetraethylene glycol 15 (8) Urea 3 (9) Glycine 3 (10) Diglycerin 3 (11) Ion-exchanged water 5 (12) Preservative Suitable amount (1) ~ (5) is heated to 80 ℃ and melted.
The mixture of (6) to (12) heated above is added and emulsified and dispersed. Then, it was filled in an ointment container and cooled to room temperature to obtain the desired urea-containing solid cosmetic.

Example 8 Compact emulsion foundation (1) Decamethylcyclopentasiloxane 38 (2) Dimethylpolysiloxane (6cs) 2 (3) Jojoba oil 2 (4) Ceresin 8 (5) Microcrystalline wax 1 (6) Polyoxyalkylene Modified organopolysiloxane (general formula [4], molecular weight 8000 polyoxyethylene group 40
(% By weight) 2 (7) Hydrophobized pigment powder 20 (8) Ion-exchanged water 5 (9) L sodium glutamate 1 (10) Glycerin 15 (11) Dipropylene glycol 6 (12) Preservative proper amount (13) Perfume proper amount After heating (1) to (6) and (13) to 80 ° C., (7) is added and dispersed. Next, it was previously heated to 80 ° C (8) ~
The mixture of (12) is added and emulsified and dispersed. Then, it was filled in a medium state in a fluid state, cooled to room temperature, and mounted in a compact container to obtain a target compact emulsion foundation. The obtained compact emulsion foundation was moist and non-greasy and was convenient to carry.

The production method of the following examples is such that the oil phase component is heated and dissolved at 80 ° C., the powder is dispersed, and the preheated aqueous phase component is emulsified and dispersed, and filled in a container in a fluid state. did. Then, it cooled and the target object was obtained. All were excellent in stability and were excellent in usability such as a moisturizing feeling.

Example 9 Blusher (1) Dimethylpolysiloxane (1.5cs) 20 (2) Decamethylcyclopentasiloxane 10 (3) Cetylisooctanoate 15 (4) Polyoxyalkylene-modified organopolysiloxane (general formula [1], molecular weight 6000 Polyoxyethylene group 20
% By weight) 3 (5) Hydrocarbon wax 12 (6) Dimethyl distearyl ammonium chloride 0.
2 (7) Perfume proper amount (8) Hydrophobized pigment powder 30 (9) Propylene glycol 5 (10) Ion-exchanged water 1.7 (11) Sodium hyaluronate 0.1 (12) Sodium chondroitin sulfate 1.5 (13) Polyethylene glycol 1.5 (13) ) Preservative Example 10 Lipstick (1) Octamethylcyclotetrasiloxane 15 (2) Dimethyl polysiloxane (6cs) 30 (3) Carnauba wax 3 (4) Aristo wax 165 ° F 13 (5) Polyoxyalkylene-modified organopolysiloxane (General formula [2], molecular weight 6000 polyoxyethylene group 15
(% By weight) 5 (6) Iron oxide red 0.5 (7) Iron oxide yellow 1 (8) Red No. 204 0.7 (9) Titanium dioxide 11 (10) Dibutylhydroxytoluene Appropriate amount (11) Perfume Appropriate amount (12) Ion-exchanged water 3 (13) Glycerin 17 (14) Atelocollagen 0.3 (15) Sodium pyrrolidonecarboxylate 0.5 Example 11 Lip treatment (1) Squalane 10 (2) Lanolin 2 (3) Octamethylcyclotetrasiloxane 34.69 (4) Isoparaffin (boiling point 155 ° C ) 10 (5) Trimethylsiloxysilicate 3 (6) Hydrocarbon wax 8 (7) Polyoxyalkylene-modified organopolysiloxane (general formula [3], molecular weight 10,000 polyoxyethylene group 3
0% by weight) 3 (8) Ion-exchanged water 3 (9) Glycerin 25 (10) Sodium lactate 0.3 (11) Sodium L-glutamate 0.3 (12) Sodium hyaluronate 0.1 (13) Sorbitol 0.5 (14) Red No. 202 0.01 (15) Menthol 0.1 (16) Perfume Suitable amount

 ─────────────────────────────────────────────────── ─── Continuation of the front page (72) Inventor Shin Takada 1050 Shinba-cho, Kohoku-ku, Yokohama City, Kanagawa Prefecture Shiseido Research Institute Co., Ltd. (56) References JP-A-60-126209 (JP, A)

Claims (4)

[Claims] 1. A silicone oil, 3 to 30% by weight of a solid wax containing 25 to 52 carbon atoms as a main component of a linear and / or branched hydrocarbon, 5% by weight or more of a polyhydric alcohol, and Containing one or more polyoxyalkylene-modified organopolysiloxanes represented by structural formulas [1], [2], [3], and [4], the following structural formula [5] is contained in the silicone oil: A polyhydric alcohol type emulsified cosmetic in a solid oil, which comprises 10 to 60% by weight of the volatile silicone oil represented by [6] with respect to the total amount of the cosmetic. (In the formula, R is an alkyl group having 1 to 3 carbon atoms or a phenyl group, R'is hydrogen, or an alkyl group having 1 to 12 carbon atoms,
p is an integer of 1 to 5, m is an integer of 5 to 100, n and x are integers of 1 to 50, and t and y are integers of 0 to 50. ) (In the formula, i is an integer of 1 to 4.) (In the formula, j is an integer of 0 to 3.) 2. The polyhydric alcohol-type emulsified cosmetic in solid oil according to claim 1, wherein the silicone oil is composed of only volatile silicone oil. 3. The amount of silicone oil is 5 relative to the total amount of cosmetics.
The polyhydric alcohol type emulsified cosmetic in solid oil according to claim 1 or 2, wherein the content is from 80 to 80% by weight. 4. A polyhydric alcohol type emulsified cosmetic in a solid oil is a pigment, a humectant, a solid / semi-solid oil, a fluid oil, a surfactant, a drug, an astringent, an antioxidant, a preservative. , Fragrance, pH
The solid polyhydric alcohol-type emulsified cosmetic in oil according to claims 1 to 3, which contains one or more of a preparation agent, a clay mineral, a thickener, and an ultraviolet absorber.