JPH0733494B2 - Method of making plastic floor materials conductive - Google Patents
Method of making plastic floor materials conductiveInfo
- Publication number
- JPH0733494B2 JPH0733494B2 JP2202451A JP20245190A JPH0733494B2 JP H0733494 B2 JPH0733494 B2 JP H0733494B2 JP 2202451 A JP2202451 A JP 2202451A JP 20245190 A JP20245190 A JP 20245190A JP H0733494 B2 JPH0733494 B2 JP H0733494B2
- Authority
- JP
- Japan
- Prior art keywords
- conductive
- polyol
- plastic
- plastic floor
- polyisocyanate
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 229920003023 plastic Polymers 0.000 title claims description 19
- 239000004033 plastic Substances 0.000 title claims description 19
- 239000000463 material Substances 0.000 title claims description 13
- 238000004519 manufacturing process Methods 0.000 title 1
- 229920005862 polyol Polymers 0.000 claims description 15
- 150000003077 polyols Chemical class 0.000 claims description 14
- 239000003792 electrolyte Substances 0.000 claims description 10
- 239000005056 polyisocyanate Substances 0.000 claims description 10
- 229920001228 polyisocyanate Polymers 0.000 claims description 10
- 229920002635 polyurethane Polymers 0.000 claims description 10
- 239000004814 polyurethane Substances 0.000 claims description 10
- 238000009408 flooring Methods 0.000 claims description 8
- 238000000034 method Methods 0.000 claims description 7
- 239000000758 substrate Substances 0.000 claims description 6
- 239000011248 coating agent Substances 0.000 claims description 5
- 238000000576 coating method Methods 0.000 claims description 4
- 229920005749 polyurethane resin Polymers 0.000 description 8
- KWGKDLIKAYFUFQ-UHFFFAOYSA-M lithium chloride Chemical compound [Li+].[Cl-] KWGKDLIKAYFUFQ-UHFFFAOYSA-M 0.000 description 6
- FKTHNVSLHLHISI-UHFFFAOYSA-N 1,2-bis(isocyanatomethyl)benzene Chemical compound O=C=NCC1=CC=CC=C1CN=C=O FKTHNVSLHLHISI-UHFFFAOYSA-N 0.000 description 4
- UPMLOUAZCHDJJD-UHFFFAOYSA-N 4,4'-Diphenylmethane Diisocyanate Chemical compound C1=CC(N=C=O)=CC=C1CC1=CC=C(N=C=O)C=C1 UPMLOUAZCHDJJD-UHFFFAOYSA-N 0.000 description 4
- 230000005611 electricity Effects 0.000 description 4
- 239000007788 liquid Substances 0.000 description 4
- 230000003068 static effect Effects 0.000 description 4
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 3
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 3
- 238000006243 chemical reaction Methods 0.000 description 3
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 3
- 150000002500 ions Chemical class 0.000 description 3
- DVKJHBMWWAPEIU-UHFFFAOYSA-N toluene 2,4-diisocyanate Chemical compound CC1=CC=C(N=C=O)C=C1N=C=O DVKJHBMWWAPEIU-UHFFFAOYSA-N 0.000 description 3
- VZXPHDGHQXLXJC-UHFFFAOYSA-N 1,6-diisocyanato-5,6-dimethylheptane Chemical compound O=C=NC(C)(C)C(C)CCCCN=C=O VZXPHDGHQXLXJC-UHFFFAOYSA-N 0.000 description 2
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 2
- 239000004721 Polyphenylene oxide Substances 0.000 description 2
- XSTXAVWGXDQKEL-UHFFFAOYSA-N Trichloroethylene Chemical compound ClC=C(Cl)Cl XSTXAVWGXDQKEL-UHFFFAOYSA-N 0.000 description 2
- 238000005299 abrasion Methods 0.000 description 2
- 238000009825 accumulation Methods 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- WNLRTRBMVRJNCN-UHFFFAOYSA-N adipic acid Chemical compound OC(=O)CCCCC(O)=O WNLRTRBMVRJNCN-UHFFFAOYSA-N 0.000 description 2
- 125000005442 diisocyanate group Chemical group 0.000 description 2
- 150000002009 diols Chemical class 0.000 description 2
- 230000001747 exhibiting effect Effects 0.000 description 2
- AYLRODJJLADBOB-QMMMGPOBSA-N methyl (2s)-2,6-diisocyanatohexanoate Chemical compound COC(=O)[C@@H](N=C=O)CCCCN=C=O AYLRODJJLADBOB-QMMMGPOBSA-N 0.000 description 2
- 125000004430 oxygen atom Chemical group O* 0.000 description 2
- 239000003973 paint Substances 0.000 description 2
- XNGIFLGASWRNHJ-UHFFFAOYSA-N phthalic acid Chemical compound OC(=O)C1=CC=CC=C1C(O)=O XNGIFLGASWRNHJ-UHFFFAOYSA-N 0.000 description 2
- 229920005906 polyester polyol Polymers 0.000 description 2
- 229920000570 polyether Polymers 0.000 description 2
- 229920005989 resin Polymers 0.000 description 2
- 239000011347 resin Substances 0.000 description 2
- 150000003839 salts Chemical class 0.000 description 2
- PUPZLCDOIYMWBV-UHFFFAOYSA-N (+/-)-1,3-Butanediol Chemical compound CC(O)CCO PUPZLCDOIYMWBV-UHFFFAOYSA-N 0.000 description 1
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 1
- BTBUEUYNUDRHOZ-UHFFFAOYSA-N Borate Chemical compound [O-]B([O-])[O-] BTBUEUYNUDRHOZ-UHFFFAOYSA-N 0.000 description 1
- 239000005057 Hexamethylene diisocyanate Substances 0.000 description 1
- 229910019142 PO4 Inorganic materials 0.000 description 1
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 1
- 239000002202 Polyethylene glycol Substances 0.000 description 1
- ZJCCRDAZUWHFQH-UHFFFAOYSA-N Trimethylolpropane Chemical compound CCC(CO)(CO)CO ZJCCRDAZUWHFQH-UHFFFAOYSA-N 0.000 description 1
- -1 acrylic polyol Chemical class 0.000 description 1
- 235000011037 adipic acid Nutrition 0.000 description 1
- 239000001361 adipic acid Substances 0.000 description 1
- 125000002723 alicyclic group Chemical group 0.000 description 1
- 125000001931 aliphatic group Chemical group 0.000 description 1
- 229910052783 alkali metal Inorganic materials 0.000 description 1
- 150000001340 alkali metals Chemical class 0.000 description 1
- 229910052784 alkaline earth metal Inorganic materials 0.000 description 1
- 150000001342 alkaline earth metals Chemical class 0.000 description 1
- 125000003118 aryl group Chemical group 0.000 description 1
- 239000003054 catalyst Substances 0.000 description 1
- 239000004020 conductor Substances 0.000 description 1
- KORSJDCBLAPZEQ-UHFFFAOYSA-N dicyclohexylmethane-4,4'-diisocyanate Chemical compound C1CC(N=C=O)CCC1CC1CCC(N=C=O)CC1 KORSJDCBLAPZEQ-UHFFFAOYSA-N 0.000 description 1
- 239000000539 dimer Substances 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000005868 electrolysis reaction Methods 0.000 description 1
- 238000001962 electrophoresis Methods 0.000 description 1
- 235000011187 glycerol Nutrition 0.000 description 1
- 150000004820 halides Chemical class 0.000 description 1
- 229910052736 halogen Inorganic materials 0.000 description 1
- 150000002367 halogens Chemical class 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- RRAMGCGOFNQTLD-UHFFFAOYSA-N hexamethylene diisocyanate Chemical compound O=C=NCCCCCCN=C=O RRAMGCGOFNQTLD-UHFFFAOYSA-N 0.000 description 1
- TZMQHOJDDMFGQX-UHFFFAOYSA-N hexane-1,1,1-triol Chemical compound CCCCCC(O)(O)O TZMQHOJDDMFGQX-UHFFFAOYSA-N 0.000 description 1
- XXMIOPMDWAUFGU-UHFFFAOYSA-N hexane-1,6-diol Chemical compound OCCCCCCO XXMIOPMDWAUFGU-UHFFFAOYSA-N 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- NIMLQBUJDJZYEJ-UHFFFAOYSA-N isophorone diisocyanate Chemical compound CC1(C)CC(N=C=O)CC(C)(CN=C=O)C1 NIMLQBUJDJZYEJ-UHFFFAOYSA-N 0.000 description 1
- SLCVBVWXLSEKPL-UHFFFAOYSA-N neopentyl glycol Chemical compound OCC(C)(C)CO SLCVBVWXLSEKPL-UHFFFAOYSA-N 0.000 description 1
- 150000002823 nitrates Chemical class 0.000 description 1
- 235000021317 phosphate Nutrition 0.000 description 1
- 150000003013 phosphoric acid derivatives Chemical class 0.000 description 1
- 229920001223 polyethylene glycol Polymers 0.000 description 1
- 229920001451 polypropylene glycol Polymers 0.000 description 1
- 239000011527 polyurethane coating Substances 0.000 description 1
- 238000007614 solvation Methods 0.000 description 1
- 150000003467 sulfuric acid derivatives Chemical class 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- 150000003567 thiocyanates Chemical class 0.000 description 1
- 229910052723 transition metal Inorganic materials 0.000 description 1
- 150000003624 transition metals Chemical class 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- 238000004383 yellowing Methods 0.000 description 1
Landscapes
- Floor Finish (AREA)
- Coating Of Shaped Articles Made Of Macromolecular Substances (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Paints Or Removers (AREA)
Description
【発明の詳細な説明】 産業上の利用分野 本発明は、硬化によりイオン伝導性を示すポリウレタン
樹脂が得られる組成物を基体上に塗布して、電気抵抗の
高いプラスチック床材を導電化する方法に関する。Description: TECHNICAL FIELD The present invention relates to a method for converting a plastic flooring material having a high electric resistance into a conductive material by applying a composition capable of obtaining a polyurethane resin exhibiting ion conductivity upon curing onto a substrate. Regarding
従来の技術 プラスチックは、加工性、着色性、耐久性等において優
れた性能を有する材料であり、様々な加工品として用い
られてきた。しかしながら、プラスチックは電気抵抗が
極めて高いことから、発生した静電気が消失せずに表面
に蓄積され、時として種々の問題を引き起こしていた。2. Description of the Related Art Plastic is a material having excellent performance in terms of processability, colorability, durability, etc., and has been used as various processed products. However, since plastic has an extremely high electric resistance, the generated static electricity is accumulated on the surface without disappearing, which sometimes causes various problems.
近年、このようなプラスチックの静電気に関する問題が
取り挙げられ、この解決のために現在までに様々な手法
が提案され、採用されてきている。例えばこの手法のひ
とつとして、界面活性剤を配合したコーティング剤を塗
布することにより、プラスチック製床材の表面抵抗を低
下させる方法があるが、得られる抵抗率およびその湿度
依存性あるいは吸湿性などの点で問題を抱えている。In recent years, such problems regarding static electricity of plastics have been raised, and various methods have been proposed and adopted up to the present for solving these problems. For example, as one of the methods, there is a method of reducing the surface resistance of a plastic flooring material by applying a coating agent containing a surfactant, but the obtained resistivity and its humidity dependence or hygroscopicity are I have a problem in terms.
発明が解決しようとする課題 本発明は、上記問題点を克服することを目的とし、イオ
ン伝導性を示す硬化物を与えるポリウレタン組成物を用
いたプラスチック製床材の導電化方法を提供するもので
ある。DISCLOSURE OF THE INVENTION Problems to be Solved by the Invention The present invention aims to overcome the above problems and provides a method for making a plastic flooring material conductive by using a polyurethane composition that gives a cured product exhibiting ion conductivity. is there.
発明の構成 本発明のプラスチック製床材の導電化方法は、電解質を
含むポリオールと、ポリイソシアネートとからなる導電
性ポリウレタン組成物で、高電気抵抗のプラスチック製
基体表面を被覆し、硬化せしめて導電性被膜を形成する
ことを特徴とする。Composition of the Invention The method for making a plastic flooring material of the present invention conductive is a conductive polyurethane composition consisting of a polyol containing an electrolyte and a polyisocyanate, coated on the surface of a plastic substrate having a high electrical resistance, and then cured to make it conductive. A characteristic coating is formed.
以下、本発明についてさらに詳細に説明する。Hereinafter, the present invention will be described in more detail.
電解質を含むポリオールとポリイソシアネートとを含む
組成物を導電性ポリウレタン塗料として用い、電気抵抗
の高いプラスチック製床材の基体上に硬化被膜を形成す
れば、プラスチック製床材を導電化して帯電防止能が付
与される。If a composition containing a polyol containing an electrolyte and a polyisocyanate is used as a conductive polyurethane paint and a cured coating is formed on the base of a plastic flooring material having high electrical resistance, the plastic flooring material becomes conductive and its antistatic property is improved. Is given.
本発明におけるポリオールおよびポリイソシアネートと
しては、従来からポリウレタン樹脂で用いられているも
のが使用できる。As the polyol and polyisocyanate in the present invention, those conventionally used in polyurethane resins can be used.
ポリイソシアネートとしては、汎用タイプ（芳香族系ポ
リイソシアネート）、非黄変タイプ（脂肪族系および脂
環族系ポリイソシアネート）のいずれでもよく、例え
ば、トリレンジイソシアネート（TDI）、4,4′−ジフェ
ニルメタンジイソシアネート（MDI）、キシリレンジイ
ソシアネート（XDI）、メタキシリレンジイソシアネー
ト（MXDI）、ヘキサメチレンジイソシアネート（HD
I）、リジンジイソシアネート（LDI）、水素化MDI（H12
MDI）、水素化TDI（HTDI）、水素化XDI（H6XDI）、イソ
ホロンジイソシアネート（IPDI）、トリメチルヘキサメ
チレンジイソシアネート（TMDI）、ダイマー酸ジイソシ
アネート（DDI）などが用いられる。The polyisocyanate may be either a general-purpose type (aromatic polyisocyanate) or a non-yellowing type (aliphatic and alicyclic polyisocyanate), for example, tolylene diisocyanate (TDI), 4,4′- Diphenylmethane diisocyanate (MDI), xylylene diisocyanate (XDI), metaxylylene diisocyanate (MXDI), hexamethylene diisocyanate (HD
I), lysine diisocyanate (LDI), hydrogenated MDI (H 12
MDI), hydrogenated TDI (HTDI), hydrogenated XDI (H 6 XDI), isophorone diisocyanate (IPDI), trimethylhexamethylene diisocyanate (TMDI), dimer acid diisocyanate (DDI) and the like are used.
ポリオールとしては、塩化リチウム等の電解質を溶解す
るものが使用され、ポリエーテルポリオール、ポリエス
テルポリオール、アクリルポリオールなど、反応に供す
るヒドロキシル基を分子末端に有するものが用いられ
る。As the polyol, one that dissolves an electrolyte such as lithium chloride is used, and one that has a hydroxyl group for the reaction at the molecular end, such as polyether polyol, polyester polyol, and acrylic polyol, is used.
ポリエーテルポリオールとしては、ポリエチレングリコ
ール、ポリプロピレングリコールなどが用いられる。Polyethylene glycol, polypropylene glycol or the like is used as the polyether polyol.
ポリエステルポリオールとしては、フタル酸、アジピン
酸などの酸に、ジオールまたはトリオールが縮合したも
のなどが用いられる。ここで、ジオールとしては、エチ
レングリコール、プロピレングリコール、ジエチレング
リコール、ブチレングリコール、1,6−ヘキサンジオー
ル、ネオペンチルグリコールなどがあり、トリオールと
して、ヘキサントリオール、トリメチロールプロパン、
グリセリンなどが挙げられる。As the polyester polyol, those obtained by condensing a diol or triol with an acid such as phthalic acid or adipic acid are used. Here, as the diol, there are ethylene glycol, propylene glycol, diethylene glycol, butylene glycol, 1,6-hexanediol, neopentyl glycol and the like, and as the triol, hexanetriol, trimethylolpropane,
Glycerin etc. are mentioned.
電解質としては、ポリオールに溶解するものが用いら
れ、アルカリ金属、アルカリ土類金属、遷移金属、アン
モニウム等のハロゲン化物、硫酸塩、硝酸塩、リン酸
塩、チオシアン酸塩、ハロゲン酸素酸塩、過ハロゲン酸
素酸塩、四ハロゲン化ホウ素酸塩などが用いられる。As the electrolyte, those which are soluble in polyol are used, and halides such as alkali metals, alkaline earth metals, transition metals and ammonium, sulfates, nitrates, phosphates, thiocyanates, halogen oxyacid salts and perhalogens are used. Oxygenate, tetrahalogen borate and the like are used.
電解質は、ポリオールの酸素原子１個に対して0.01〜１
グラム当量配合することが適当である。The electrolyte is 0.01 to 1 for each oxygen atom of the polyol.
It is suitable to blend in gram equivalent.
これら無機塩（電解質）のイオンは、比較的イオン半径
が小さく、ポリオールに対する溶媒和半径が小さいた
め、ポリオールの極性基（酸素原子）に対して会合しや
すく、かつ、硬化後も電解内での電気泳動が容易である
ので、良好なイオン伝導性を発揮すると考えられる。The ions of these inorganic salts (electrolytes) have a relatively small ionic radius and a small solvation radius with respect to the polyol, so that they easily associate with the polar group (oxygen atom) of the polyol, and after curing, they remain in the electrolysis. Since it is easy to perform electrophoresis, it is considered that it exhibits good ionic conductivity.
電解質を含むポリオールをＡ液とし、ポリイソシアネー
トをＢ液とし、両者を混合することにより反応して硬化
し、ポリウレタン樹脂が得られる。この反応は、常温で
も進行するが、加熱してもよく、また、必要により触媒
を用いてもよい。A polyol containing an electrolyte is used as a liquid A and a polyisocyanate is used as a liquid B, and the two are mixed to react with each other and cure, whereby a polyurethane resin is obtained. Although this reaction proceeds even at room temperature, it may be heated, or if necessary, a catalyst may be used.
上記のＡ液、Ｂ液を２液型のポリウレタン塗料とし、こ
れを混合して電気抵抗の高いプラスチック製基体に塗
布、硬化せしめて被膜を形成することにより、プラスチ
ック製床材を導電化できる。この硬化樹脂被膜は、イオ
ン伝導に基づく導電性に加え、ポリウレタン樹脂が有し
ている硬度、耐摩耗性、耐候性、耐水性、密着性などを
具えており、界面活性剤による導電化に比較して、高い
電導性が実現できるとともに、吸湿性や抵抗率の湿度依
存性を示さない。The above-mentioned liquids A and B are made into a two-liquid type polyurethane paint, which is mixed and applied to a plastic substrate having high electric resistance, and cured to form a film, whereby the plastic flooring material can be made conductive. This cured resin coating has the hardness, abrasion resistance, weather resistance, water resistance, and adhesion that polyurethane resin has in addition to conductivity based on ionic conduction. As a result, high electrical conductivity can be realized, and hygroscopicity and resistivity do not depend on humidity.
以上、２液型のポリウレタン組成物を中心に説明した
が、湿気硬化型ポリウレタン組成物やブロック型ポリウ
レタン組成物のような１液型のポリウレタン組成物にも
同様に応用できる。１液型の場合は、電解質を含むポリ
オールと過剰のポリイソシアネートとの反応で得られた
プレポリマーを、ポリウレタン組成物として使用に供す
ればよい。Although the two-component polyurethane composition has been mainly described above, the present invention can be similarly applied to a one-component polyurethane composition such as a moisture-curable polyurethane composition or a block-type polyurethane composition. In the case of the one-pack type, the prepolymer obtained by the reaction between the polyol containing the electrolyte and the excess polyisocyanate may be used as a polyurethane composition.
本発明により得られるプラスチック製床材は、適度な導
電性を具え、静電気の蓄積を防止することができる。よ
って、広範な用途に利用でき、例えば、コンピュータや
OA機械が設置される事務所等で用いられる床材、床に敷
いて用いられる帯電防止用の床敷物などとして用いられ
る。The plastic floor covering obtained by the present invention has appropriate conductivity and can prevent accumulation of static electricity. Therefore, it can be used in a wide range of applications, such as computers and
It is used as a floor material used in offices where OA machines are installed, and as an antistatic floor covering used on the floor.
発明の効果 本発明によれば、電解質を含むポリオールとポリイソシ
アネートとを含む組成物を導電性ポリウレタン塗料とし
て用い、電気抵抗の大きなプラスチック製基体上にポリ
ウレタン樹脂被膜を形成することにより、プラスチック
製床材を導電化できる。硬化後のポリウレタン樹脂は、
イオン伝導性を示し、表面での静電気の蓄積を有効に防
止して、優れた帯電防止能を示す。また、この導電性樹
脂被膜は、耐摩耗性等のポリウレタン樹脂のもつ優れた
特性を具えており、吸湿性や電気抵抗の湿度依存性もな
い。EFFECTS OF THE INVENTION According to the present invention, a composition containing a polyol containing an electrolyte and a polyisocyanate is used as a conductive polyurethane coating material to form a polyurethane resin film on a plastic substrate having a large electric resistance, thereby forming a plastic floor. The material can be made conductive. The polyurethane resin after curing is
It exhibits ionic conductivity, effectively prevents the accumulation of static electricity on the surface, and exhibits excellent antistatic ability. In addition, this conductive resin film has excellent characteristics of polyurethane resin such as abrasion resistance, and does not have hygroscopicity or humidity dependence of electric resistance.
実 施 例 ポリエチレンオキサイド（分子量400）に塩化リチウム
をLi/O＝0.01となるように溶解し、これをＡ液とした。
これにNCO/OH＝1.05となるようにＢ液（4,4′−ジフェ
ニルメタンジイソシアネート）を加え、プラスチック基
体の上に塗布し（厚さ10ミクロン）、オーブンを用い80
℃で２分間加熱して硬化させた。JIS K 6911による表面
抵抗測定値は、６×107オームであった。Example Lithium chloride was dissolved in polyethylene oxide (molecular weight 400) so that Li / O was 0.01, and this was used as solution A.
Solution B (4,4'-diphenylmethane diisocyanate) was added to this so that NCO / OH = 1.05, and it was coated on a plastic substrate (thickness 10 micron), and it was heated using an oven.
It was cured by heating at 0 ° C for 2 minutes. The measured surface resistance according to JIS K 6911 was 6 × 10 7 ohms.
また、塩化リチウムを配合しないポリウレタン樹脂を用
いた場合の表面抵抗値は、3.5×1010オームであった。Further, the surface resistance value when a polyurethane resin containing no lithium chloride was used was 3.5 × 10 10 ohms.
Claims (1)
ネートとからなる導電性ポリウレタン組成物で、高電気
抵抗のプラスチック製基体表面を被覆し、硬化せしめて
導電性被膜を形成することを特徴とするプラスチック製
床材の導電化方法。1. A plastic comprising a conductive polyurethane composition composed of a polyol containing an electrolyte and a polyisocyanate, which is coated on the surface of a plastic substrate having high electrical resistance and cured to form a conductive coating. Method for making flooring materials conductive.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2202451A JPH0733494B2 (en) | 1990-08-01 | 1990-08-01 | Method of making plastic floor materials conductive |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2202451A JPH0733494B2 (en) | 1990-08-01 | 1990-08-01 | Method of making plastic floor materials conductive |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPH0488057A JPH0488057A (en) | 1992-03-19 |
| JPH0733494B2 true JPH0733494B2 (en) | 1995-04-12 |
Family
ID=16457746
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2202451A Expired - Lifetime JPH0733494B2 (en) | 1990-08-01 | 1990-08-01 | Method of making plastic floor materials conductive |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH0733494B2 (en) |
Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP3578550B2 (en) * | 1996-04-09 | 2004-10-20 | 日本ポリウレタン工業株式会社 | Highly conductive polyurethane resin paint |
| EP0925590A1 (en) * | 1996-09-12 | 1999-06-30 | UNIROYAL CHEMICAL COMPANY, Inc. | Electrically conductive polyether polyurethanes |
| KR100329213B1 (en) * | 1999-07-20 | 2002-03-22 | 전종한 | Composition for Preparing Conductive Polyurethanes |
Family Cites Families (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3978258A (en) * | 1974-12-30 | 1976-08-31 | Gaf Corporation | Embossed decorative sheet-type material and process for making same |
| JPS57143355A (en) * | 1981-02-27 | 1982-09-04 | Nec Corp | Ionic conductive solid substance composition |
| JPS6355811A (en) * | 1986-08-26 | 1988-03-10 | 宇部興産株式会社 | Solid electrolyte composition |
| JPS63295667A (en) * | 1987-05-27 | 1988-12-02 | Showa Electric Wire & Cable Co Ltd | Transparent electroconductive resin composition |
| JPS641763A (en) * | 1987-06-24 | 1989-01-06 | Unitika Ltd | Polymer composition |
| JP2790467B2 (en) * | 1988-11-18 | 1998-08-27 | 日本カーリット株式会社 | Polymer solid electrolyte and method for producing the same |
| JPH03122165A (en) * | 1989-10-06 | 1991-05-24 | Japan Carlit Co Ltd:The | Electroconductive resin composition |
-
1990
- 1990-08-01 JP JP2202451A patent/JPH0733494B2/en not_active Expired - Lifetime
Also Published As
| Publication number | Publication date |
|---|---|
| JPH0488057A (en) | 1992-03-19 |
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