JPH0735600B2 - Degreasing container for plating and degreasing device - Google Patents
Degreasing container for plating and degreasing deviceInfo
- Publication number
- JPH0735600B2 JPH0735600B2 JP2842793A JP2842793A JPH0735600B2 JP H0735600 B2 JPH0735600 B2 JP H0735600B2 JP 2842793 A JP2842793 A JP 2842793A JP 2842793 A JP2842793 A JP 2842793A JP H0735600 B2 JPH0735600 B2 JP H0735600B2
- Authority
- JP
- Japan
- Prior art keywords
- degreasing
- electrode
- container
- spiral
- container body
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 238000005238 degreasing Methods 0.000 title claims description 69
- 238000007747 plating Methods 0.000 title claims description 12
- 239000007788 liquid Substances 0.000 claims description 52
- 238000005192 partition Methods 0.000 claims description 26
- 239000004020 conductor Substances 0.000 claims description 14
- 238000011282 treatment Methods 0.000 claims description 12
- 230000002093 peripheral effect Effects 0.000 claims description 9
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 19
- 238000000034 method Methods 0.000 description 10
- 239000000463 material Substances 0.000 description 8
- 239000012298 atmosphere Substances 0.000 description 5
- 238000009826 distribution Methods 0.000 description 5
- 239000000428 dust Substances 0.000 description 4
- 239000007789 gas Substances 0.000 description 3
- 239000002184 metal Substances 0.000 description 3
- 230000005611 electricity Effects 0.000 description 2
- 238000005868 electrolysis reaction Methods 0.000 description 2
- 239000003960 organic solvent Substances 0.000 description 2
- 239000004094 surface-active agent Substances 0.000 description 2
- 229920003002 synthetic resin Polymers 0.000 description 2
- 239000000057 synthetic resin Substances 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 1
- -1 but in this case Substances 0.000 description 1
- 238000005237 degreasing agent Methods 0.000 description 1
- 239000013527 degreasing agent Substances 0.000 description 1
- 238000007599 discharging Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 230000005484 gravity Effects 0.000 description 1
- 238000007689 inspection Methods 0.000 description 1
- 238000012423 maintenance Methods 0.000 description 1
- 238000003825 pressing Methods 0.000 description 1
- 238000003672 processing method Methods 0.000 description 1
- 238000011084 recovery Methods 0.000 description 1
- 238000009751 slip forming Methods 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
Landscapes
- Electroplating Methods And Accessories (AREA)
Description
【0001】[0001]
【産業上の利用分野】本発明は、メッキ工程の前処理と
して行われる被メッキ材の脱脂容器および脱脂装置に関
するものである。BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a degreasing container and a degreasing device for a material to be plated, which is performed as a pretreatment for a plating process.
【0002】[0002]
【従来の技術】金属製品に種々のメッキ処理を行う場
合、メッキの前処理として、プレスのような機械加工に
よって被メッキ材の表面に付着した油や塵埃等を除去す
るための脱脂処理が行われる。被メッキ材として、例え
ば、電気接点に使用する基材となる長尺材や大きな製品
の場合にはそれぞれの製品ごとにに脱脂処理を行うこと
が可能である。しかし、打ち抜かれて単体に形成された
電気接点のようなきわめて小さな部品は、個々の部品ご
とに脱脂処理を行うことができない。2. Description of the Related Art When a metal product is subjected to various plating treatments, a degreasing treatment for removing oil, dust and the like adhering to the surface of the material to be plated is carried out as a pretreatment for the plating by mechanical processing such as pressing. Be seen. As the material to be plated, for example, in the case of a long material serving as a base material used for electrical contacts or a large product, degreasing treatment can be performed for each product. However, extremely small parts such as punched and formed electrical contacts cannot be degreased individually.
【0003】このような小型部品を脱脂処理する場合、
従来はバレル処理法と称するバレル状容器に多数の小型
部品を投入し、容器全体を脱脂液槽に入れ、脱脂作業を
行っていた。When degreasing such small parts,
Conventionally, a large number of small parts are put in a barrel-shaped container called a barrel processing method, and the whole container is put in a degreasing liquid tank to perform degreasing work.
【0004】[0004]
【発明が解決しようとする課題】しかし、小型部品を収
容した容器は、全体が20〜30Kgの重さとなるた
め、人手によって容器を持ち、脱脂処理を行うことは大
変な重労働であり、経済効率が悪いものであった。ま
た、工程が不連続であったため生産性が悪いものであっ
た。However, since the container containing the small parts has a weight of 20 to 30 kg as a whole, it is very heavy labor to carry out the degreasing process by holding the container by hand, which is economically efficient. Was bad. In addition, productivity was poor because the steps were discontinuous.
【0005】小型部品は、金属板をプレスで打ち抜いた
時に油が付着し、また、これらを保管している時には油
の表面に更に塵埃が付着するものであった。脱脂処理を
するために、フロンのような有機溶剤を使用して脱脂を
行っていたが、環境破壊の問題からこのような溶剤を使
用できなくなってきた。The small parts had oil adhered to them when the metal plate was punched out by a press, and dust adhered to the surface of the oil when they were stored. In order to perform the degreasing treatment, degreasing was performed using an organic solvent such as CFC, but such a solvent cannot be used due to the problem of environmental damage.
【0006】フロンのような有機溶剤に代わってアルカ
リ性脱脂液が使用されるが、この場合、脱脂液の表面に
脱脂後の油や塵埃等が皮膜状となって浮いている。この
ため、脱脂処理後に容器を液槽から引き上げた時、膜状
の油や塵埃等が部品表面に付着し、脱脂処理を全く無駄
な状態とすることがしばしばあった。An alkaline degreasing liquid is used in place of an organic solvent such as CFC, but in this case, oil and dust after degreasing are floating in a film form on the surface of the degreasing liquid. For this reason, when the container is pulled out from the liquid tank after the degreasing treatment, film-like oil, dust, and the like are often attached to the surface of the component, and the degreasing treatment is often in vain.
【0007】これを防止するために、脱脂液にアルカリ
性界面活性剤を混入させて乳化状態とし、脱脂後の油を
界面活性剤で捕集することにより脱脂液表面への油膜の
形成をなくすようにしていた。しかし、油そのものが脱
脂液中に浮遊しているので、容器を引き上げる時、油が
部品に接触し、部品に油が付着するのを完全に防止する
ことができなかった。また、脱脂液を乳化するために多
大の経費を必要としていた。In order to prevent this, the degreasing liquid is mixed with an alkaline surfactant to make it an emulsified state, and the degreased oil is collected by the surfactant so as to eliminate the formation of an oil film on the surface of the degreasing liquid. I was doing. However, since the oil itself floats in the degreasing liquid, it was not possible to completely prevent the oil from coming into contact with the parts and adhering to the parts when the container was pulled up. Further, a large amount of cost is required to emulsify the degreasing liquid.
【0008】本発明は、上記する従来技術の問題点に鑑
み、単体に打ち抜かれた電気接点のような小型部品のメ
ッキ前処理として行われる脱脂処理を連続的に自動処理
可能としたメッキ処理用脱脂容器を提供するものであ
る。また、脱脂処理の際、水素ガスが発生し、ガス発生
に伴って部品の表面から油が剥離されるが、本発明は水
素ガスと油を脱脂液面に案内し、ガスは大気中に放出
し、油は液面で回収するようにしたメッキ処理用脱脂装
置を提供するものである。In view of the above-mentioned problems of the prior art, the present invention is for a plating process capable of continuously and automatically performing a degreasing process which is performed as a pre-plating process for a small component such as an electrical contact punched into a single body. A degreasing container is provided. Further, during the degreasing process, hydrogen gas is generated, and the oil is peeled off from the surface of the component due to the gas generation.The present invention guides the hydrogen gas and the oil to the degreasing liquid surface, and the gas is released into the atmosphere. However, the oil provides a degreasing device for the plating process so that the oil can be collected on the liquid surface.
【0009】[0009]
【課題を解決するための手段】上記の目的を達成するた
めに本発明は、一端を部品の投入口2、他端を脱脂後の
部品の排出口3として開口した多角形状筒状体4内を螺
旋状の仕切り板5により仕切り、仕切り板5間において
筒状体4には螺旋方向に複数の電極6を等配するととも
に筒状体4の外周に複数配設した環状導電体7と対応す
る電極6とを通電可能に接続し、仕切り板5によって形
成される円筒状中空部10の上部には電極6とは対極を
なし半円状に湾曲した流通案内面12を有する電極11
を独立して設置し、筒状体4は周方向に回転可能として
ある。In order to achieve the above object, the present invention provides a polygonal cylindrical body 4 having one end serving as a component inlet 2 and the other end serving as a degreased component outlet 3. Is partitioned by a spiral partition plate 5, and a plurality of electrodes 6 are equally arranged in the spiral direction in the cylindrical body 4 between the partition plates 5 and correspond to the annular conductors 7 arranged on the outer periphery of the cylindrical body 4. An electrode 11 having a flow guide surface 12 that is semi-circularly curved and does not have a counter electrode to the electrode 6 and is connected to the electrode 6 to be energized so as to be electrically conductive.
Are independently installed, and the tubular body 4 is rotatable in the circumferential direction.
【0010】一端を部品の投入口2、他端を脱脂後の部
品の排出口3として開口した多角形状筒状体4内を螺旋
状の仕切り板5により仕切り、仕切り板5間において筒
状体4には螺旋方向に複数の電極6を等配するとともに
筒状体4の外周に複数配設した環状導電体7と対応する
電極6とを通電可能に接続し、仕切り板5によって形成
される円筒状中空部10の上部には電極6とは対極をな
し半円状に湾曲した流通案内面12を有する電極11を
独立して設置し、筒状体4は周方向に回転可能とした脱
脂容器を脱脂液槽23内に回転可能に設置してある。The inside of a polygonal cylindrical body 4 having one end as a component inlet 2 and the other end as a degreased component outlet 3 is partitioned by a spiral partition plate 5, and a cylindrical body is provided between the partition plates 5. A plurality of electrodes 6 are evenly arranged in the spiral direction, and a plurality of annular conductors 7 arranged on the outer periphery of the tubular body 4 are electrically connected to the corresponding electrodes 6 to form a partition plate 5. An electrode 11 having a counter electrode opposite to the electrode 6 and having a semicircularly curved flow guide surface 12 is independently installed in the upper part of the cylindrical hollow portion 10, and the tubular body 4 is degreased so as to be rotatable in the circumferential direction. The container is rotatably installed in the degreasing liquid tank 23.
【0011】筒状体4は、両端部外周面に固定したギア
ー15とこれに噛み合うピニオン16からなる回転部材
13と、ギアー15に近接して筒状体4の外周面に固定
したガイドローラ19とこれに嵌まり合う支持ローラ2
0からなる支持部材14とで周方向に回転可能としてあ
る。The tubular body 4 has a rotating member 13 composed of a gear 15 fixed to the outer peripheral surfaces of both ends and a pinion 16 meshing with the gear 15, and a guide roller 19 fixed to the outer peripheral surface of the tubular body 4 close to the gear 15. And supporting roller 2 that fits in this
It can rotate in the circumferential direction together with the support member 14 made of zero.
【0012】電極11は、上端部に近い位置に形成した
流通孔29に流通パイプ30を立設し、上部周面に流出
孔31を有する流通パイプ30には筒状の遮蔽体33を
設置してある。In the electrode 11, a flow pipe 30 is provided upright in a flow hole 29 formed near the upper end, and a cylindrical shield 33 is installed in the flow pipe 30 having an outflow hole 31 on the upper peripheral surface. There is.
【0013】また、脱脂容器1は方形状支持枠体27内
に回転可能に設置し、支持枠体27は脱脂液槽23内に
セット可能としてある。The degreasing container 1 is rotatably installed in a rectangular support frame 27, and the support frame 27 can be set in the degreasing liquid tank 23.
【0014】[0014]
【実施例】以下、図面に従って、本発明の実施例を詳細
に説明する。図1、図2はメッキ工程の前処理として行
われる脱脂装置に使用する脱脂用容器の本体であり、こ
の容器本体1は、一端を被メッキ材である単体に形成し
た電気接点のような小型部品の投入口2とし、他端を脱
脂後の部品の排出口3として開口した合成樹脂製の多角
形筒状体4を基体としている。Embodiments of the present invention will now be described in detail with reference to the drawings. 1 and 2 show the body of a degreasing container used in a degreasing device performed as a pretreatment for a plating process. The container body 1 has a small size such as an electrical contact formed at one end as a single material to be plated. The base is a polygonal cylindrical body 4 made of synthetic resin, which is used as a component inlet 2 and has the other end opened as a degreased component outlet 3.
【0015】この筒状体4は、長さが1〜3m、内径は
30〜40cm程度であるが、大きさは任意に選択する
ことができる。また図示において、筒状体4は六角体と
してあるが、これに限定されるものではなく五角体や七
角体等とすることができ、多角体の形状も任意に選択す
ることができる。The cylindrical body 4 has a length of 1 to 3 m and an inner diameter of about 30 to 40 cm, but the size can be arbitrarily selected. Further, in the drawing, the tubular body 4 is a hexagon, but it is not limited to this and may be a pentagon, a heptagon, or the like, and the shape of the polygon can be arbitrarily selected.
【0016】筒状体4内は、投入口2から排出口3方向
へ螺旋状に連続して形成した合成樹脂製の仕切り板5に
よって仕切り、仕切り板5間において筒状体4には、筒
状体4に嵌め込み固定して内外に通電可能な複数個の電
極6を螺旋状に配設する。また、筒状体4の外周には、
筒状体4の長さ方向にそって複数本配設した環状の導電
体7を巻き回して固定し、各導電体7とこれに対応する
位置にある電極6とを通電可能に接続しておく。The inside of the tubular body 4 is partitioned by a partition plate 5 made of synthetic resin, which is continuously formed in a spiral shape from the input port 2 toward the discharge port 3, and between the partition plates 5 the tubular body 4 has a tubular shape. A plurality of electrodes 6 which can be energized inside and outside are spirally arranged by being fitted and fixed in the body 4. Also, on the outer periphery of the tubular body 4,
A plurality of annular conductors 7 arranged along the length direction of the tubular body 4 are wound and fixed, and each conductor 7 and the electrode 6 at a position corresponding thereto are electrically connected. deep.
【0017】各電極6は、導電体7を介して外部の電源
に接続してあるが、このため例えば、各導電体7に導電
用ローラ8を支持体9によって回転可能に圧接し、各ロ
ーラ8は、支持体9内を通した導電線(図示せず)を使
用して外部の電源に接続しておけば各導電体7および電
極6にそれぞれに通電可能である。Each electrode 6 is connected to an external power source through a conductor 7. For this reason, for example, a conductive roller 8 is rotatably pressed by a support 9 to each conductor 7 so that each roller can rotate. 8 is capable of energizing each conductor 7 and electrode 6 if connected to an external power source using a conductive wire (not shown) that passes through the inside of the support 9.
【0018】各ローラ8への通電は、図示しないタイマ
ーを使用して投入口2側のローラ8から排出口3側のロ
ーラ8へ経時的に順に行うようにしてある。尚、各ロー
ラ8は個々に支持してあるが、全てのローラ8を一本の
回転軸に固定し、各ローラ8にはタイマーを介して各別
に通電できるようにしてもよい。The energization of each roller 8 is performed sequentially from the roller 8 on the inlet 2 side to the roller 8 on the outlet 3 side by using a timer (not shown). Although each roller 8 is individually supported, all the rollers 8 may be fixed to one rotation shaft so that each roller 8 can be separately energized via a timer.
【0019】仕切り板5によって長さ方向に形成される
円筒状中空部10の上部には電極11を独立した状態で
配設する。この電極11は、図3に示すように長尺な導
電製金属板を長さ方向にそって下向きに湾曲させ、下面
を流通案内面12とした形状を有し、外部の電源に通電
可能に接続してある。上記の電極6と電極11とは、電
極6が(−)、電極11が(+)の対極を成している。Electrodes 11 are separately arranged above the cylindrical hollow portion 10 formed by the partition plate 5 in the longitudinal direction. As shown in FIG. 3, this electrode 11 has a shape in which a long conductive metal plate is curved downward along the length direction, and the lower surface serves as a flow guide surface 12, so that an external power source can be energized. It is connected. The electrode 6 and the electrode 11 are opposite electrodes of the electrode 6 (-) and the electrode 11 (+).
【0020】容器本体1内には投入口2から一定量の小
型部品群がまとめて投入され、仕切り板5の螺旋面にそ
って排出口3方向へ移動する。小型部品群の移動のため
に容器本体1は周方向に回転可能となっている。このよ
うに容器本体1には、投入口2から小型部品群が投入さ
れ、脱脂が終了した部品群は排出口3から排出され、更
に、筒状体4内には電極11が独立して存在し、外部電
源に接続しているので、筒状体4の外周胴部において回
転させることが望ましい。A certain amount of small parts are put into the container body 1 all at once through the inlet 2, and move in the direction of the outlet 3 along the spiral surface of the partition plate 5. The container body 1 is rotatable in the circumferential direction for the movement of the small component group. As described above, the small component group is charged into the container body 1 through the charging port 2, the degreased component group is discharged through the discharging port 3, and the electrode 11 is independently present in the tubular body 4. However, since it is connected to an external power source, it is desirable to rotate the outer peripheral body of the tubular body 4.
【0021】図4、図5、図6は容器本体1の回転支持
機構の一例を示すものである。この回転支持機構は、容
器本体1を周方向に回転させるための一対の回転部材1
3と、容器本体1の周面を下面で支える一対の支持部材
14とで構成されている。FIGS. 4, 5, and 6 show an example of the rotation support mechanism of the container body 1. This rotation support mechanism includes a pair of rotating members 1 for rotating the container body 1 in the circumferential direction.
3 and a pair of support members 14 that support the peripheral surface of the container body 1 on the lower surface.
【0022】回転部材13は、筒状体4の両端部外周に
巻き回して固定したギアー15とこのギアー15に噛み
合うピニオン16とからなり、ピニオン16は回転軸1
7によって回転可能に支持されている。符号18は、上
端に軸受を有する回転軸17の支柱である。回転軸17
は図示しないモータに回転可能に連結してある。The rotary member 13 is composed of a gear 15 wound around and fixed to the outer circumference of both ends of the tubular body 4, and a pinion 16 meshing with the gear 15, and the pinion 16 is the rotary shaft 1.
It is rotatably supported by 7. Reference numeral 18 is a column of the rotating shaft 17 having a bearing at the upper end. Rotating shaft 17
Is rotatably connected to a motor (not shown).
【0023】また、支持部材14は、ギアー15に近接
して筒状体4の外周に固定した環状のガイドレール19
と、筒状体4の下面周方向に配設した一対の支持用ロー
ラ20からなり、このローラ20は、立設した支柱21
の軸受によって支持されている。Further, the support member 14 is an annular guide rail 19 fixed to the outer periphery of the tubular body 4 in the vicinity of the gear 15.
And a pair of supporting rollers 20 arranged in the circumferential direction of the lower surface of the tubular body 4.
Supported by bearings.
【0024】回動支持機構は上記の構成であり、容器本
体1の自重は、ガイドレール19に嵌まり合うローラ2
0によって支持されている。この状態でピニオン16を
駆動すればギアー15が回転し、容器本体1は中空部で
周方向に回転することになる。容器本体1は、ガイドレ
ール19とローラ20によって長さ方向に位置ずれを起
こすことはなく、安定して回転する。The rotation supporting mechanism has the above-mentioned structure, and the weight of the container body 1 is adjusted by the roller 2 fitted on the guide rail 19.
Supported by 0. When the pinion 16 is driven in this state, the gear 15 rotates, and the container body 1 rotates in the circumferential direction in the hollow portion. The container body 1 is stably rotated by the guide rail 19 and the roller 20 without being displaced in the longitudinal direction.
【0025】図7は支持部材14の他の例を示すもので
あり、一対のローラ20に変え円形状としたベアリング
支持体22をガイドレール19の下方に嵌め合わせてお
けばよく、支持体22は容器本体1の自重および回転を
支持可能である。FIG. 7 shows another example of the support member 14. Instead of the pair of rollers 20, a circular bearing support 22 may be fitted under the guide rail 19 to support the support 22. Can support the weight and rotation of the container body 1.
【0026】上記する回動支持機構は一例を示すもので
あって、この構造に限定されるものではなく、容器本体
1を支持して周方向に回転可能であれば他の構造を使用
することができるものである。The rotation support mechanism described above is merely an example, and the structure is not limited to this structure. Any other structure can be used as long as it supports the container body 1 and can rotate in the circumferential direction. Is something that can be done.
【0027】次に、上記する容器本体1を使用した脱脂
装置により被メッキ材である電気接点のような小型部品
の脱脂処理作業について説明する。図8に示すように、
容器本体1は、アルカリ性脱脂剤等からなる脱脂用の液
体を充満した処理液槽23中に、投入口2が下側で排出
口3側が上側に位置するよう傾斜状に設置する。図面で
は示していないが、容器本体1は前記の回転支持機構に
よって周方向に回転可能に支持されている。Next, a degreasing process for a small part such as an electrical contact which is a material to be plated by the degreasing device using the container body 1 will be described. As shown in FIG.
The container body 1 is installed in a treatment liquid tank 23 filled with a degreasing liquid such as an alkaline degreasing agent so that the inlet 2 is on the lower side and the outlet 3 is on the upper side. Although not shown in the drawings, the container body 1 is supported by the rotation support mechanism so as to be rotatable in the circumferential direction.
【0028】このため回転部材13の支柱18および支
持部材14の支柱21等は液槽23の底板上に立設して
固定し、ギアー15とピヨオン16とは噛み合い、ガイ
ドローラ19と支持ローラ20は嵌め合った状態となっ
ている。また、回転軸17は、液槽23内で水密状態の
モータに連結するか、回転軸17は液槽23から密に外
部に貫通させてモータに連結するようにしてもよい。Therefore, the columns 18 of the rotating member 13, the columns 21 of the supporting member 14 and the like are erected and fixed on the bottom plate of the liquid tank 23, the gear 15 and the pyeon 16 mesh with each other, and the guide roller 19 and the supporting roller 20. Are in a fitted state. Further, the rotary shaft 17 may be connected to a watertight motor in the liquid tank 23, or the rotary shaft 17 may be tightly penetrated from the liquid tank 23 to the outside and connected to the motor.
【0029】単体に形成された小型部品群24は、液槽
23外に配置した部品収納ホッパー25から案内管26
を通して投入口2から容器本体1内に必要量ずつをまと
めて投入する。このようにして部品群24を投入した
後、容器本体4を回転支持機構により周方向に回転させ
れば、部品群24は自重により筒状体4の底面側にそっ
て螺旋状の仕切り板5により、順次、上方へ移動してい
く。The small component group 24 formed as a single unit includes a component storage hopper 25 arranged outside the liquid tank 23 and a guide pipe 26.
Through the charging port 2, the necessary amounts are collectively charged into the container body 1. When the container body 4 is rotated in the circumferential direction by the rotation support mechanism after the component group 24 is thus put in, the component group 24 is spirally divided along the bottom surface side of the tubular body 4 by its own weight. Will move upwards in sequence.
【0030】部品群24を投入すると同時に両電極6、
11に直流電流を通電すれば、(−)側電極6と(+)
側電極11間で電流が流れ、部品群24の表面で液体の
電気分解反応が進行し各部品表面から水素ガスが発生す
る。水素ガスは、各部品表面に形成されている油膜面を
破って脱脂液中に浮遊するので、この時、部品表面の油
膜は剥離され、脱脂液中に浮遊することになる。液面に
浮遊した油は、常時、回収作業が行われて除去される。At the same time when the component group 24 is put in, both electrodes 6,
When a direct current is applied to 11, the (−) side electrode 6 and the (+) side
An electric current flows between the side electrodes 11, the electrolysis reaction of the liquid proceeds on the surface of the component group 24, and hydrogen gas is generated from the surface of each component. Since the hydrogen gas breaks the oil film surface formed on the surface of each component and floats in the degreasing liquid, the oil film on the surface of the component is peeled off and floats in the degreasing liquid. The oil floating on the liquid surface is constantly removed by a recovery operation.
【0031】部品群24を形成する各部品表面の油は、
脱脂液によって除去されるとともに水素ガスの発生時に
剥離されるので、各部品は脱脂が行われつつ排出口3方
向に移動し、脱脂が完了部品は排出口3から取り出すこ
とができる。排出口3から取り出された脱脂完了後の部
品は、液槽23中に設置した図示しない受け容器に落と
し込むようにし、ある程度集積された時点で受け容器を
液槽23外に取り出せばよい。The oil on the surface of each component forming the component group 24 is
Since it is removed by the degreasing liquid and is peeled off when hydrogen gas is generated, each component moves toward the discharge port 3 while degreasing is performed, and the degreased component can be taken out from the discharge port 3. The degreased parts taken out from the discharge port 3 may be dropped into a receiving container (not shown) installed in the liquid tank 23, and the receiving container may be taken out of the liquid tank 23 when they are accumulated to some extent.
【0032】上記のようにして各部品から剥離された油
および水素ガスは、脱脂液よりも比重が軽いので浮遊し
つつ上昇するが、容器本体1内で上方に設置した電極1
1は半円状に湾曲してあり、かつ、容器本体1と同じく
傾斜しているので油と水素ガスは電極11の流通案内面
12に捕らえらる。このようにして捕らえられた油と水
素ガスは傾斜案内面12にそって排出口3方向に上昇、
移動する。The oil and hydrogen gas separated from each component as described above rise while floating because they have a lower specific gravity than the degreasing liquid, but the electrode 1 installed above in the container body 1
Since 1 is curved in a semicircular shape and is inclined similarly to the container body 1, oil and hydrogen gas are captured by the flow guide surface 12 of the electrode 11. The oil and hydrogen gas thus captured rise along the inclined guide surface 12 toward the discharge port 3,
Moving.
【0033】容器本体1から液槽23内に排出された油
は液面に浮遊するのでこれは回収して除去する。また、
水素ガスは自然に大気中に放出され、脱脂液中に滞留す
ることはない。電極11の流通案内面12から漏れた少
量の油や水素ガス等は、容器本体1内で電極11の上部
に浮遊するが、容器本体1は傾斜して回転しているので
上方の仕切り板5で徐々に上昇方向に移動され、排出口
3から前記と同じように排出されるので容器本体1内に
滞留することはない。The oil discharged from the container body 1 into the liquid tank 23 floats on the liquid surface and is collected and removed. Also,
Hydrogen gas is spontaneously released into the atmosphere and does not stay in the degreasing liquid. A small amount of oil, hydrogen gas, etc. leaking from the flow guide surface 12 of the electrode 11 floats above the electrode 11 in the container body 1, but since the container body 1 is inclined and rotated, the upper partition plate 5 Since it is gradually moved in the upward direction and discharged from the discharge port 3 in the same manner as described above, it does not stay in the container body 1.
【0034】容器本体1の回転速度(回転数)は任意の
値に設定可能としておけば、部品に付着している油の量
によって回転速度および脱脂時間を変えることができ
る。油の付着量が少ない時には回転速度を早め、脱脂時
間を短くすることができる。逆に油の付着量が多い場合
には回転速度をゆっくりさせ、脱脂時間を長くすること
ができる。If the rotation speed (rotation speed) of the container body 1 can be set to an arbitrary value, the rotation speed and the degreasing time can be changed depending on the amount of oil adhering to the parts. When the amount of oil adhered is small, the rotation speed can be increased and the degreasing time can be shortened. Conversely, when the amount of oil adhered is large, the rotation speed can be slowed down and the degreasing time can be lengthened.
【0035】各電極6は、個々に通電可能であるととも
に各電極6への通電はタイマーによって制御しているの
で、仕切り板5によって部品群24が上方へ移動した
時、移動位置にある電極6のみを通電するようにすれ
ば、部品群24の移動速度にあわせて当該位置の電極6
へ通電することができる。給電用の直流電流は、電圧規
制回路電源を用いるので、部品群24に接触していない
容器本体1上部の電極6からは殆ど電解電流は流れな
い。Since each electrode 6 can be individually energized and the energization of each electrode 6 is controlled by a timer, when the component group 24 is moved upward by the partition plate 5, the electrode 6 in the moving position is moved. By energizing only one of the electrodes, the electrode 6 at that position can be adjusted according to the moving speed of the component group 24.
Can be energized to. Since the DC current for power supply uses the voltage regulation circuit power source, almost no electrolytic current flows from the electrode 6 on the upper part of the container body 1 which is not in contact with the component group 24.
【0036】電極6は仕切り板5間に配設してあるが、
容器本体1全体が傾斜しているので、部品群24は仕切
り板5に近い位置で押し上げられるようにして傾斜上方
に移動することになる。従って、仕切り板5間の電極6
は、下方の仕切り板5に近い位置に設置するようにして
おけば、部品群24と電極6との接触位置はきわめて近
い位置となり、通電および電気分解を良好に行うことが
可能となる。The electrodes 6 are arranged between the partition plates 5,
Since the entire container body 1 is inclined, the component group 24 moves upward in the inclination so that it is pushed up at a position close to the partition plate 5. Therefore, the electrodes 6 between the partition plates 5 are
If it is installed at a position close to the lower partition plate 5, the contact position between the component group 24 and the electrode 6 will be extremely close, and it will be possible to favorably conduct electricity and electrolyze.
【0037】上記の脱脂装置は、容器本体1を直接脱脂
液槽23に取り付けた場合であるが、これに限定される
ものではなく、容器本体1を支持枠体内に設置し、支持
枠体を液槽23内に設置するようにしてもよい。図9は
容器本体1を支持枠体26内に設置した状態を示してい
る。支持枠体27は、型枠材を方形状に組み立て、その
内部に前記に示した容器本体1と同一構造の容器本体1
を周方向に回転可能に設置したものであり、図10に示
すように全体を液槽23内にセットする。The above degreasing device is a case in which the container body 1 is directly attached to the degreasing liquid tank 23, but the invention is not limited to this. The container body 1 is installed in the support frame body, and the support frame body is installed. You may make it install in the liquid tank 23. FIG. 9 shows a state in which the container body 1 is installed in the support frame 26. The support frame 27 is formed by assembling a mold material into a rectangular shape, and the inside of the support frame 27 has the same structure as the container body 1 described above.
Is rotatably installed in the circumferential direction, and the whole is set in the liquid tank 23 as shown in FIG.
【0038】全体を液槽23内にセットした時、容器本
体1を傾斜状態とするため、支持枠支持枠体27内であ
らかじめ容器本体1を傾斜状態で設置するか、支持枠体
27内に容器本体1を平行状態で設置し、図10に示す
ように、支持枠体27の下部一端に支持脚28を固定し
て支持枠体27全体を傾斜せればよい。支持枠体27内
に容器本体1を設置し、全体を液槽23内にセットした
場合の脱脂工程は前記実施例の場合と全く同じである。When the whole is set in the liquid tank 23, in order to make the container body 1 in an inclined state, the container body 1 is previously installed in an inclined state in the support frame support frame 27, or in the support frame 27. The container body 1 may be installed in a parallel state, and as shown in FIG. 10, the support leg 28 may be fixed to one lower end of the support frame 27 and the entire support frame 27 may be inclined. The degreasing process when the container body 1 is installed in the support frame 27 and the whole body is set in the liquid tank 23 is exactly the same as in the above-described embodiment.
【0039】図11は電極11の他の実施例を示すもの
であり、前記の実施例と同じ部分は同じ符号を使用して
いる。本実施例では湾曲して流通案内面12を有する電
極11の上端部に近い位置に流通孔29を形成してこの
流通孔29の上部に垂直状態で流通パイプ30を立設し
て固定する。流通パイプ30の上端には周方向に複数の
縦長な流出孔31を穿設しておき、この流出孔31を囲
むようにして流通パイプ30には複数本の連結棒32を
介して大径筒状の遮蔽体33が設置してある。FIG. 11 shows another embodiment of the electrode 11, and the same parts as those in the above-mentioned embodiment are designated by the same reference numerals. In this embodiment, a flow hole 29 is formed at a position near the upper end of the electrode 11 which is curved and has the flow guide surface 12, and a flow pipe 30 is vertically installed and fixed above the flow hole 29. A plurality of vertically elongated outflow holes 31 are formed in the upper end of the distribution pipe 30 in the circumferential direction, and the distribution pipe 30 is surrounded by the plurality of connecting rods 32 to form a large-diameter tubular shape. A shield 33 is installed.
【0040】本実施例の電極11は上記の構成であるか
ら、前記の如く脱脂処理が行われて部品群24から剥
離、浮遊した油と水素ガスは、前記と同様、電極11の
案内面12に捕集され、傾斜面にそって上昇し、流通孔
29から流通パイプ30を通って上昇する。水素ガスは
そのまま大気中に放出され、油は流出孔31から遮蔽体
33内の脱脂液面に放出される。油は、遮蔽体33内に
溜まるのでこの部分の油を回収して除去すればよい。Since the electrode 11 of the present embodiment has the above-described structure, the oil and hydrogen gas that has been degreased as described above and separated from the component group 24 and floating is the guide surface 12 of the electrode 11 as described above. Are collected by the ascendant, rise along the inclined surface, and rise from the circulation hole 29 through the circulation pipe 30. Hydrogen gas is released into the atmosphere as it is, and oil is released from the outflow hole 31 to the degreasing liquid surface in the shield 33. Since the oil collects in the shield 33, the oil in this portion may be collected and removed.
【0041】[0041]
【発明の効果】以上、説明した本発明によれば、容器本
体1は、一端を部品の投入口2、他端を脱脂後の部品の
排出口3として開口した多角形状筒状体4内を螺旋状の
仕切り板5によって仕切り、筒状体4には仕切り板5間
において電極6を螺旋方向に複数設けるとともに筒状体
4の外周に複数配設した環状の導電体7とこれに対応す
る電極6とを接続し、筒状体4内上部には電極6とは対
極をなす電極11を独立して設置したので、投入口2か
ら必要量の部品群24を投入し、筒状体4を周方向に回
転させることにより部品群24は螺旋状仕切り板5によ
り排出口3方向へ移動可能となる。As described above, according to the present invention described above, the container body 1 has the inside of the polygonal cylindrical body 4 having one end as the component inlet 2 and the other end as the degreased component outlet 3. Partitioned by a spiral partition plate 5, a plurality of electrodes 6 are provided in the tubular body 4 between the partition plates 5 in the spiral direction, and a plurality of annular conductors 7 are provided on the outer periphery of the tubular body 4 and corresponding thereto. Since the electrode 6 is connected and the electrode 11 opposite to the electrode 6 is independently installed in the upper portion of the tubular body 4, a required amount of the component group 24 is loaded from the loading port 2 to allow the tubular body 4 to be charged. The component group 24 can be moved in the direction of the discharge port 3 by the spiral partition plate 5 by rotating the.
【0042】容器本体1を脱脂液を充満した液槽23内
に、排出口3側が上に位置するよう傾斜状態で設置し、
容器本体1を周方向に回転しつつ両電極6、11に直流
電流を通電すれば、部品群24の表面に付着している油
は脱脂液によって除去されるとともに部品群24には電
気分解によって水素ガスが発生し、ガス発生時に各部品
の油膜を剥離するので部品表面の油は完全に剥離され
る。The container body 1 is installed in the liquid tank 23 filled with the degreasing liquid in an inclined state so that the discharge port 3 side is located above,
When a direct current is applied to both electrodes 6 and 11 while rotating the container body 1 in the circumferential direction, the oil adhering to the surface of the component group 24 is removed by the degreasing liquid and the component group 24 is electrolyzed. Hydrogen gas is generated, and the oil film on each part is peeled off when the gas is generated, so the oil on the surface of the part is completely peeled off.
【0043】水素ガスおよび剥離された油は浮遊状態で
上昇するが、容器本体1内の上部には湾曲した流通案内
面12を有する電極11が設置してあるので、水素ガス
および油は案内面12を通って傾斜方向へ上昇し、排出
口3から脱脂液中に排出される。水素ガスは脱脂液中を
そのまま上昇して大気中に放出される。また、油は液面
に浮遊するのでこれは回収して除去される。Although the hydrogen gas and the separated oil rise in a floating state, since the electrode 11 having the curved flow guide surface 12 is installed in the upper part of the container body 1, the hydrogen gas and oil are guided by the guide surface. It goes up in the inclination direction through 12 and is discharged from the discharge port 3 into the degreasing liquid. Hydrogen gas rises as it is in the degreasing liquid and is released into the atmosphere. Also, the oil floats on the liquid surface and is collected and removed.
【0044】筒状体4は多角形状としてあるので、内部
に部品群24を投入した状態で筒状体4を周方向に回転
させれば、内面角部で部品群24は反転して攪拌される
ので、各部品と脱脂液との接触が良好であり、全ての部
品表面で電気分解が行われて水素ガスが発生するので、
各部品表面に付着している油の剥離を完全に行うことが
できる。Since the tubular body 4 has a polygonal shape, if the tubular body 4 is rotated in the circumferential direction while the component group 24 is placed inside, the component group 24 is inverted and agitated at the inner surface corners. Therefore, the contact between each part and the degreasing liquid is good, and the electrolysis is performed on the surfaces of all parts to generate hydrogen gas.
It is possible to completely remove the oil adhering to the surface of each component.
【0045】各導電体7にはそれぞれに圧接したローラ
8を介して通電されるが、通電はタイマーを使用して投
入口2側の導電体7から排出口3側の導電体7に経時的
に順番に行われるので、容器本体1内で部品群24が位
置する電極6に通電すればよく、部品群24の移動に合
わせて給電状態を移動させることができ、他の導電体7
には通電する必要がないので電気の消費量を節約して経
済的である。The electric conductors 7 are energized through the rollers 8 which are pressed against each other. The energization is conducted from the electric conductor 7 on the inlet 2 side to the electric conductor 7 on the outlet 3 side by using a timer. Therefore, it is sufficient to energize the electrode 6 where the component group 24 is located in the container body 1, and the power supply state can be moved according to the movement of the component group 24.
Since it does not need to be energized, it saves electricity consumption and is economical.
【0046】容器本体1は方形状の支持枠体27内に回
転可能に設置し、支持枠体27を液槽23内にセット可
能とすれば、容器本体1の交換を容易に行うことができ
る。例えば、部品群24の大きさや脱脂量等によって容
器本体1の大きさを変える必要がある場合には支持枠体
27を液槽23から取り外し、他の容器本体1を有する
支持枠体27を液槽23内にセットすればよい。また、
容器本体1の交換ができるので、容器本体1の保守、点
検も簡単に行うことができる。If the container body 1 is rotatably installed in a rectangular support frame 27 and the support frame 27 can be set in the liquid tank 23, the container body 1 can be easily replaced. . For example, when it is necessary to change the size of the container body 1 according to the size of the component group 24 or the amount of degreasing, the support frame 27 is removed from the liquid tank 23, and the support frame 27 having another container body 1 is removed. It may be set in the tank 23. Also,
Since the container body 1 can be replaced, maintenance and inspection of the container body 1 can be easily performed.
【0047】電極11の上部に形成した流通孔29に流
通パイプ30を立設して固定し、流通パイプ30の上端
周面には複数の流出孔31を形成するとともにこの流出
孔31を囲むように流通パイプ30には筒状の遮蔽体3
3を設置したので、電極11の湾曲案内面12で捕らえ
られた水素ガスと油は流通孔29と流通パイプ30を通
して上昇するので、水素ガスは大気中に放出される。ま
た、油は、遮蔽体33内の液面に浮遊して他の液面に流
出することはなく、油の回収が容易であるとともに遮蔽
体33外の液面を油で汚すことがない。A flow pipe 30 is erected and fixed in a flow hole 29 formed in the upper part of the electrode 11, and a plurality of flow holes 31 are formed on the upper end peripheral surface of the flow pipe 30 so as to surround the flow hole 31. The distribution pipe 30 has a cylindrical shield 3
Since 3 is installed, the hydrogen gas and oil captured by the curved guide surface 12 of the electrode 11 rises through the flow hole 29 and the flow pipe 30, so that the hydrogen gas is released into the atmosphere. Further, the oil does not float on the liquid surface inside the shield 33 and flows out to other liquid surfaces, the oil can be easily collected and the liquid surface outside the shield 33 is not contaminated with the oil.
【図1】本発明脱脂処理に使用する脱脂容器の一部を断
面とした正面図である。FIG. 1 is a front view showing a cross section of a part of a degreasing container used in the degreasing treatment of the present invention.
【図2】図1のA−A線断面図である。FIG. 2 is a sectional view taken along the line AA of FIG.
【図3】電極の斜視図である。FIG. 3 is a perspective view of an electrode.
【図4】周方向に回転可能な容器本体の要部の正面図で
ある。FIG. 4 is a front view of a main part of a container body that is rotatable in the circumferential direction.
【図5】筒状体と回転部材の関係を示す側面図である。FIG. 5 is a side view showing a relationship between a tubular body and a rotating member.
【図6】筒状体と支持部材の関係を示す側面図である。FIG. 6 is a side view showing a relationship between a tubular body and a support member.
【図7】支持部材の他の実施例を示す側面図である。FIG. 7 is a side view showing another embodiment of the support member.
【図8】脱脂容器を脱脂液槽に設置した状態の断面図で
ある。FIG. 8 is a cross-sectional view showing a state in which a degreasing container is installed in a degreasing liquid tank.
【図9】容器本体を支持枠体に設置した状態の斜視図で
ある。FIG. 9 is a perspective view showing a state where the container body is installed on the support frame.
【図10】容器本体を有する支持枠体を脱脂液槽内にセ
ットした状態の断面図である。FIG. 10 is a cross-sectional view showing a state in which a support frame having a container body is set in a degreasing liquid tank.
【図11】電極の他の実施例を示す断面図である。FIG. 11 is a sectional view showing another embodiment of the electrode.
1 容器本体 2 投入口 3 排出口 4 筒状体 5 仕切り板 6 電極 7 導電体 8 ローラ 9 支持体 10 中空部 11 電極 12 流通案内面 13 回転部材 14 支持部材 15 ギアー 16 ピニオン 17 回転軸 18 支柱 19 ガイドレール 20 支持ローラ 21 支柱 22 支持体 23 脱脂液槽 24 部品群 25 ホッパー 26 案内管 27 支持枠体 28 支脚 29 流通孔 30 流通パイプ 31 流出孔 32 連結棒 33 遮蔽体 1 Container Main Body 2 Input Port 3 Discharge Port 4 Cylindrical Body 5 Partition Plate 6 Electrode 7 Conductor 8 Roller 9 Support 10 Hollow Part 11 Electrode 12 Flow Guide Surface 13 Rotating Member 14 Supporting Member 15 Gear 16 Pinion 17 Rotating Shaft 18 Strut 19 Guide Rails 20 Support Rollers 21 Supports 22 Supports 23 Degreasing Liquid Tank 24 Parts Group 25 Hoppers 26 Guide Tubes 27 Support Frames 28 Support Legs 29 Distribution Holes 30 Distribution Pipes 31 Outflow Holes 32 Connection Rods 33 Shields
Claims (5)
部品の排出口3として開口した多角形状筒状体4内を螺
旋状の仕切り板5により仕切り、仕切り板5間において
筒状体4には螺旋方向に複数の電極6を等配するととも
に筒状体4の外周に複数配設した環状導電体7と対応す
る電極6とを通電可能に接続し、仕切り板5によって形
成される円筒状中空部10の上部には電極6とは対極を
なし半円状に湾曲した流通案内面12を有する電極11
を独立して設置し、筒状体4は周方向に回転可能とした
ことを特徴とするメッキ処理用脱脂容器。1. A spiral partition plate 5 partitions the inside of a polygonal cylindrical body 4 having one end as a component inlet 2 and the other end as a degreased component outlet 3, and a cylinder between the partition plates 5. A plurality of electrodes 6 are equally arranged in the spiral direction in the spiral body 4, and a plurality of annular conductors 7 arranged on the outer periphery of the cylindrical body 4 are electrically connected to the corresponding electrodes 6, and are formed by a partition plate 5. An electrode 11 having a flow guide surface 12 curved in a semicircular shape which is a counter electrode to the electrode 6 and is provided above the cylindrical hollow portion 10 to be formed.
Is independently installed, and the cylindrical body 4 is rotatable in the circumferential direction.
部品の排出口3として開口した多角形状筒状体4内を螺
旋状の仕切り板5により仕切り、仕切り板5間において
筒状体4には螺旋方向に複数の電極6を等配するととも
に筒状体4の外周に複数配設した環状導電体7と対応す
る電極6とを通電可能に接続し、仕切り板5によって形
成される円筒状中空部10の上部には電極6とは対極を
なし半円状に湾曲した流通案内面12を有する電極11
を独立して設置し、筒状体4は周方向に回転可能とした
脱脂容器を脱脂液槽23内に回転可能に設置したことを
特徴とするメッキ処理用脱脂装置。2. A polygonal tubular body 4 having one end as a component inlet 2 and the other end as a degreased component outlet 3 is partitioned by a spiral partition plate 5, and a cylinder is provided between the partition plates 5. A plurality of electrodes 6 are equally arranged in the spiral direction in the spiral body 4, and a plurality of annular conductors 7 arranged on the outer periphery of the cylindrical body 4 are electrically connected to the corresponding electrodes 6, and are formed by a partition plate 5. An electrode 11 having a flow guide surface 12 curved in a semicircular shape which is a counter electrode to the electrode 6 and is provided above the cylindrical hollow portion 10 to be formed.
The degreasing device for plating treatment is characterized in that a degreasing container in which the cylindrical body 4 is rotatable in the circumferential direction is rotatably installed in the degreasing liquid tank 23.
アー15とこれに噛み合うピニオン16からなる回転部
材13と、ギアー15に近接して筒状体4の外周面に固
定したガイドローラ19とこれに嵌まり合う支持ローラ
20からなる支持部材14とで周方向に回転可能とした
ことを特徴とする請求項1、2に記載するメッキ処理用
脱脂容器および脱脂装置。3. The tubular body 4 comprises a rotating member 13 comprising a gear 15 fixed to the outer peripheral surfaces of both ends and a pinion 16 meshing with the gear 15, and a guide fixed to the outer peripheral surface of the tubular body 4 close to the gear 15. The degreasing container for plating treatment and the degreasing apparatus according to claim 1, wherein the roller 19 and the supporting member 14 formed of a supporting roller 20 fitted to the roller 19 are rotatable in the circumferential direction.
た流通孔29に流通パイプ30を立設し、上部周面に流
出孔31を有する流通パイプ30には筒状の遮蔽体33
を設置したことを特徴とする請求項1、2および3に記
載するメッキ処理用脱脂容器および脱脂装置。4. The electrode 11 has a circulation pipe 30 provided upright in a circulation hole 29 formed at a position close to the upper end portion, and a cylindrical shield 33 in the circulation pipe 30 having an outflow hole 31 on the upper peripheral surface.
The degreasing container for plating treatment and the degreasing device according to claim 1, 2 or 3, wherein
転可能に設置し、支持枠体27は脱脂液槽23内にセッ
トすることを特徴とするメッキ処理用脱脂装置。5. A degreasing device for plating treatment, wherein the degreasing container 1 is rotatably installed in a rectangular support frame 27, and the support frame 27 is set in a degreasing liquid tank 23.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2842793A JPH0735600B2 (en) | 1993-01-26 | 1993-01-26 | Degreasing container for plating and degreasing device |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2842793A JPH0735600B2 (en) | 1993-01-26 | 1993-01-26 | Degreasing container for plating and degreasing device |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPH06220700A JPH06220700A (en) | 1994-08-09 |
| JPH0735600B2 true JPH0735600B2 (en) | 1995-04-19 |
Family
ID=12248367
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2842793A Expired - Lifetime JPH0735600B2 (en) | 1993-01-26 | 1993-01-26 | Degreasing container for plating and degreasing device |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH0735600B2 (en) |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP4635221B2 (en) * | 2005-06-13 | 2011-02-23 | 学校法人福岡大学 | Electroplating apparatus and plating method for minute objects |
| JP5228964B2 (en) * | 2009-02-06 | 2013-07-03 | 株式会社村田製作所 | Barrel plating equipment |
-
1993
- 1993-01-26 JP JP2842793A patent/JPH0735600B2/en not_active Expired - Lifetime
Also Published As
| Publication number | Publication date |
|---|---|
| JPH06220700A (en) | 1994-08-09 |
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