JPH0749513B2 - Unsaturated polyester resin molding material - Google Patents
Unsaturated polyester resin molding materialInfo
- Publication number
- JPH0749513B2 JPH0749513B2 JP6047487A JP6047487A JPH0749513B2 JP H0749513 B2 JPH0749513 B2 JP H0749513B2 JP 6047487 A JP6047487 A JP 6047487A JP 6047487 A JP6047487 A JP 6047487A JP H0749513 B2 JPH0749513 B2 JP H0749513B2
- Authority
- JP
- Japan
- Prior art keywords
- polyester resin
- unsaturated polyester
- molding material
- resin molding
- filler
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 229920006337 unsaturated polyester resin Polymers 0.000 title claims description 18
- 239000012778 molding material Substances 0.000 title claims description 13
- 239000000945 filler Substances 0.000 claims description 8
- 239000000391 magnesium silicate Substances 0.000 claims description 8
- 229910052919 magnesium silicate Inorganic materials 0.000 claims description 8
- 235000019792 magnesium silicate Nutrition 0.000 claims description 8
- HCWCAKKEBCNQJP-UHFFFAOYSA-N magnesium orthosilicate Chemical compound [Mg+2].[Mg+2].[O-][Si]([O-])([O-])[O-] HCWCAKKEBCNQJP-UHFFFAOYSA-N 0.000 claims description 4
- -1 magnesium silicate compound Chemical class 0.000 claims description 4
- 239000003795 chemical substances by application Substances 0.000 claims description 3
- 239000003086 colorant Substances 0.000 claims description 3
- 239000003431 cross linking reagent Substances 0.000 claims description 3
- 239000003505 polymerization initiator Substances 0.000 claims description 3
- 150000001875 compounds Chemical class 0.000 claims description 2
- 238000000465 moulding Methods 0.000 description 4
- 238000005299 abrasion Methods 0.000 description 3
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- 230000000052 comparative effect Effects 0.000 description 2
- 239000011777 magnesium Substances 0.000 description 2
- KOMNUTZXSVSERR-UHFFFAOYSA-N 1,3,5-tris(prop-2-enyl)-1,3,5-triazinane-2,4,6-trione Chemical compound C=CCN1C(=O)N(CC=C)C(=O)N(CC=C)C1=O KOMNUTZXSVSERR-UHFFFAOYSA-N 0.000 description 1
- 229910018072 Al 2 O 3 Inorganic materials 0.000 description 1
- 239000004641 Diallyl-phthalate Substances 0.000 description 1
- 229910004298 SiO 2 Inorganic materials 0.000 description 1
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical group C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 1
- 239000010425 asbestos Substances 0.000 description 1
- QUDWYFHPNIMBFC-UHFFFAOYSA-N bis(prop-2-enyl) benzene-1,2-dicarboxylate Chemical compound C=CCOC(=O)C1=CC=CC=C1C(=O)OCC=C QUDWYFHPNIMBFC-UHFFFAOYSA-N 0.000 description 1
- 229910000019 calcium carbonate Inorganic materials 0.000 description 1
- 229910052620 chrysotile Inorganic materials 0.000 description 1
- 239000004927 clay Substances 0.000 description 1
- 229910052570 clay Inorganic materials 0.000 description 1
- 238000000748 compression moulding Methods 0.000 description 1
- 238000004132 cross linking Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000001125 extrusion Methods 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 239000003365 glass fiber Substances 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 238000001746 injection moulding Methods 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 239000006082 mold release agent Substances 0.000 description 1
- 239000000178 monomer Substances 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 229910052895 riebeckite Inorganic materials 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- 239000000454 talc Substances 0.000 description 1
- 229910052623 talc Inorganic materials 0.000 description 1
- 239000002562 thickening agent Substances 0.000 description 1
- 238000001721 transfer moulding Methods 0.000 description 1
- CWBIFDGMOSWLRQ-UHFFFAOYSA-N trimagnesium;hydroxy(trioxido)silane;hydrate Chemical compound O.[Mg+2].[Mg+2].[Mg+2].O[Si]([O-])([O-])[O-].O[Si]([O-])([O-])[O-] CWBIFDGMOSWLRQ-UHFFFAOYSA-N 0.000 description 1
- 239000002023 wood Substances 0.000 description 1
Landscapes
- Compositions Of Macromolecular Compounds (AREA)
- Macromonomer-Based Addition Polymer (AREA)
Description
【発明の詳細な説明】 〔技術分野〕 本発明は電気・電子機器部品用、電気構造部品用、電熱
器具ハウジング用等に用いられる不飽和ポリエステル樹
脂成形材料に関するものである。TECHNICAL FIELD The present invention relates to an unsaturated polyester resin molding material used for electric / electronic device parts, electric structural parts, electric appliance housings, and the like.
従来、不飽和ポリエステル樹脂成形材料はその優れた強
度、成形性により電気構造部品用等に広く用いられてい
るが、耐摩耗性に劣る問題があり、この為、充填剤とし
てアスベストを用いて耐摩耗性を向上させてきたが充填
剤として用いられているアスベストが公害問題で用いら
れなくなりアスベストに代替する充填剤が求められてい
た。Conventionally, unsaturated polyester resin molding materials have been widely used for electric structural parts due to their excellent strength and moldability, but they have a problem of poor wear resistance. There has been a demand for a filler that has improved abrasion resistance but is not used as a filler due to pollution problems and is replaced by asbestos.
本発明の目的とするところは、耐燃性、耐摩耗性に優れ
た成形品が得られる不飽和ポリエステル樹脂成形材料を
提供することにある。An object of the present invention is to provide an unsaturated polyester resin molding material capable of obtaining a molded article excellent in flame resistance and abrasion resistance.
本発明は不飽和ポリエステル樹脂に充填剤、架橋剤、重
合開始剤、離型剤、着色剤等を添加してなる不飽和ポリ
エステル樹脂成形材料において、充填剤として繊維状ケ
イ酸マグネシウム系化合物を用いたことを特徴とするも
ので、かくして得られた成形材料を加熱加圧成形するこ
とによって耐燃性、耐摩耗性に優れた不飽和ポリエステ
ル樹脂成形品を得ることができるもので、以下本発明を
詳細に説明する。INDUSTRIAL APPLICABILITY The present invention uses a fibrous magnesium silicate compound as a filler in an unsaturated polyester resin molding material obtained by adding a filler, a cross-linking agent, a polymerization initiator, a release agent, a colorant, etc. to an unsaturated polyester resin. It is characterized in that it is possible to obtain an unsaturated polyester resin molded article excellent in flame resistance and wear resistance by heating and molding the molding material thus obtained, and the present invention will be described below. The details will be described.
本発明に用いる不飽和ポリエステル樹脂は特に限定する
ものでなく不飽和ポリエステル樹脂全般を用いることが
できるものである。架橋剤としてはスチレンモノマー等
の常温液状のもの或は常温固体のものを用いることがで
き、これまた限定するものではないが耐熱性向上のため
にはジアリルフタレートモノマーを用いるのがよく、又
架橋剤と併用してトリアリルイソシアヌレートを配合し
架橋密度を上げることで耐熱性をより向上させることも
できるものである。The unsaturated polyester resin used in the present invention is not particularly limited, and any unsaturated polyester resin can be used. As the cross-linking agent, a liquid at room temperature such as a styrene monomer or a solid at room temperature can be used, but it is not limited thereto, but it is preferable to use a diallyl phthalate monomer for improving heat resistance. The heat resistance can be further improved by blending triallyl isocyanurate in combination with the agent to increase the crosslinking density.
充填剤としては少くとも繊維状のケイ酸マグネシウム系
化合物を用いるものである。繊維状のケイ酸マグネシウ
ムとしてはクリソタイル〔Mg6Si4O10（OH）８〕、セビ
オライト〔Mg8Si12O30（OH）４（H2O）48H2O〕商品名エ
ードプラス55〔武田薬品株式会社製、主成分SiO2・MgO
・Al2O3〕等があり、この他更にケイ酸マグネシウムを
主成分としてCaO,H2O等を含有する繊維状物質全般を包
含するものである。繊維状ケイ酸マグネシウム系化合物
の量は全量の３〜80重量％（以下単に％と記す）である
ことが望ましい。即ち３％未満では耐クラック性が向上
し難く、80％をこえると成形性が低下する傾向にあるか
らである。なお繊維状ケイ酸マグネシウム系化合物以外
の充填剤としてはパルプ、木粉、炭酸カルシウム、ガラ
ス繊維、クレー、シリカ、タルク等を添加することがで
きる。重合開始剤、離型剤、着色剤或は必要に応じて添
加される界面活性剤、増粘剤等については特に限定する
ものではなく通常用いられているものをそのまま用いる
ことができる。かくして得られた不飽和ポリエステル樹
脂成形材料を圧縮成形、押出成形、トランスフアー成
形、射出成形等により加熱加圧成形し耐燃性、耐摩耗性
に優れた成形品を得ることができるものである。As the filler, at least a fibrous magnesium silicate compound is used. As fibrous magnesium silicate, chrysotile [Mg 6 Si 4 O 10 (OH) 8 ] and ceviolite [Mg 8 Si 12 O 30 (OH) 4 (H 2 O) 4 8H 2 O] trade name Adeplus 55 [ Takeda Pharmaceutical Co., Ltd., main component SiO 2・ MgO
-Al 2 O 3 ] and the like, and also includes all fibrous substances containing CaO, H 2 O and the like with magnesium silicate as a main component. The amount of the fibrous magnesium silicate-based compound is preferably 3 to 80% by weight (hereinafter simply referred to as "%") of the total amount. That is, if it is less than 3%, it is difficult to improve the crack resistance, and if it exceeds 80%, the moldability tends to decrease. As a filler other than the fibrous magnesium silicate compound, pulp, wood powder, calcium carbonate, glass fiber, clay, silica, talc, etc. can be added. The polymerization initiator, mold release agent, colorant or surfactant, thickener, etc., which are added as necessary, are not particularly limited, and those commonly used can be used as they are. The unsaturated polyester resin molding material thus obtained can be molded under heat and pressure by compression molding, extrusion molding, transfer molding, injection molding or the like to obtain a molded article having excellent flame resistance and abrasion resistance.
以下本発明を実施例にもとづいて説明する。The present invention will be described below based on examples.
実施例１乃至３と比較例 第１表の配合表にもとづいて各材料をニーダーで混練
後、粉砕して不飽和ポリエステル樹脂成形材料を得、該
成形材料を金型温度150℃、成形圧力250kg/cm3で加熱加
圧成形して不飽和ポリエステル樹脂成形品を得た。Examples 1 to 3 and Comparative Example Each material was kneaded in a kneader based on the formulation table in Table 1 and pulverized to obtain an unsaturated polyester resin molding material. The molding material was molded at a mold temperature of 150 ° C. and a molding pressure of 250 kg. An unsaturated polyester resin molded product was obtained by heat and pressure molding at / cm 3 .
〔発明の効果〕 実施例１乃至３と比較例の不飽和ポリエステル樹脂成形
品の性能は第２表で明白なように本発明のものの性能は
よく、本発明の不飽和ポリエステル樹脂成形材料の優れ
ていることを確認した。 [Effects of the Invention] The performance of the unsaturated polyester resin moldings of Examples 1 to 3 and Comparative Example is good as shown in Table 2, and the performance of the present invention is good, and the unsaturated polyester resin molding material of the present invention is excellent. I confirmed that.
Claims (2)
剤、重合開始剤、離型剤、着色剤等を添加してなる不飽
和ポリエステル樹脂成形材料において、充填剤として少
くとも繊維状ケイ酸マグネシウム系化合物を用いたこと
を特徴とする不飽和ポリエステル樹脂成形材料。1. An unsaturated polyester resin molding material obtained by adding a filler, a cross-linking agent, a polymerization initiator, a release agent, a colorant and the like to an unsaturated polyester resin, and at least a fibrous magnesium silicate as a filler. An unsaturated polyester resin molding material characterized by using a system compound.
が、全量の３〜80重量％であることを特徴とする特許請
求の範囲第１項記載の不飽和ポリエステル樹脂成形材
料。2. The unsaturated polyester resin molding material according to claim 1, wherein the amount of the fibrous magnesium silicate compound is 3 to 80% by weight of the total amount.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP6047487A JPH0749513B2 (en) | 1987-03-16 | 1987-03-16 | Unsaturated polyester resin molding material |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP6047487A JPH0749513B2 (en) | 1987-03-16 | 1987-03-16 | Unsaturated polyester resin molding material |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS63227660A JPS63227660A (en) | 1988-09-21 |
| JPH0749513B2 true JPH0749513B2 (en) | 1995-05-31 |
Family
ID=13143305
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP6047487A Expired - Fee Related JPH0749513B2 (en) | 1987-03-16 | 1987-03-16 | Unsaturated polyester resin molding material |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH0749513B2 (en) |
-
1987
- 1987-03-16 JP JP6047487A patent/JPH0749513B2/en not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| JPS63227660A (en) | 1988-09-21 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| LAPS | Cancellation because of no payment of annual fees |