JPH075127B2 - Cans for canning - Google Patents
Cans for canningInfo
- Publication number
- JPH075127B2 JPH075127B2 JP40334890A JP40334890A JPH075127B2 JP H075127 B2 JPH075127 B2 JP H075127B2 JP 40334890 A JP40334890 A JP 40334890A JP 40334890 A JP40334890 A JP 40334890A JP H075127 B2 JPH075127 B2 JP H075127B2
- Authority
- JP
- Japan
- Prior art keywords
- structural unit
- unit surface
- equation
- line
- polyhedron
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
Landscapes
- Containers Having Bodies Formed In One Piece (AREA)
Description
【0001】[0001]
【産業上の利用分野】本発明は缶詰用缶に関するもので
あり、より詳細には内容物充填殺菌後の冷却過程或いは
その後の保存中に於ける減圧変形などに対する優れた耐
性を有し、これにより使用素材の薄肉化が可能である缶
詰用缶に関する。BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a can for cans, and more particularly, it has excellent resistance to deformation under reduced pressure during the cooling process after filling and sterilizing the contents or during the subsequent storage. The present invention relates to a can for can whose material used can be made thinner.
【0002】[0002]
【従来の技術】従来、缶詰用缶の素材としては、ガスバ
リヤー性、耐熱性、耐圧性等の点で、主に金属板が用い
られ、大別して、金属板等を筒状に成形して対向する端
線部を溶接、接着或いはハンダ付け等の手段で接合して
側面継ぎ目付き缶胴を成形し、この缶胴の両端を天地蓋
と巻締して成る所謂スリーピース缶、或いは金属板を有
底缶胴に絞り深絞り成形或いは更にしごき成形に付し、
この有底缶胴の上端に蓋を巻締して成る所謂ツーピース
缶が広く使用されている。2. Description of the Related Art Conventionally, as a material for a can for canning, a metal plate has been mainly used in view of gas barrier property, heat resistance, pressure resistance, etc. A so-called three-piece can or metal plate formed by joining opposite end line parts by means such as welding, adhesion or soldering to form a side canned can body, and fastening both ends of the can body to the top and bottom lid. Attached to the bottomed can body for deep drawing or ironing.
A so-called two-piece can in which a lid is wound around the upper end of the bottomed can body is widely used.
【0003】これらの缶詰用缶においては、缶の素材コ
ストを低減させ且つ缶自体を軽量化することを目的とし
て、素材の厚みを可久的に薄くすべく多くの努力が払わ
れている。しかしながら、素材の厚みを小さくすると、
缶胴の機械的強度が当然低下し、特に内容物充填殺菌後
の冷却過程或いはその後の保存や輸送中に、内部の減圧
による缶胴の変形(異形変形)が顕著に生じるようにな
る。また、缶詰製品では、その取扱いや輸送中に、缶同
士の衝突等が避け得ないこともあるが、この衝突等によ
っても缶胴の変形を生じることがある。In these canned cans, many efforts have been made to make the material thickness as thin as possible for the purpose of reducing the material cost of the can and reducing the weight of the can itself. However, if the material thickness is reduced,
The mechanical strength of the can body naturally lowers, and in particular, during the cooling process after the content filling and sterilization, or during the subsequent storage or transportation, the can body is significantly deformed (deformed) due to the reduced pressure inside. Further, in the case of a canned product, collision between cans may be unavoidable during handling or transportation, but the collision may cause deformation of the can body.
【0004】缶詰用缶の缶胴にこのような変形が生じる
と、製品の外観が不良となり、商品価値を損なうばかり
でなく、金属板の内外保護被覆層にもピンホール、クラ
ック、剥離等の被覆欠陥を発生し、腐食や金属溶出或い
は更に孔食等による漏洩等の問題を起こす虞がある。従
来、缶胴部材を補強する手段として、缶胴部材に周方向
のビード及び缶高さ方向(缶軸方向)のビードを形成さ
せることが知られている。When such a deformation occurs in the can body of a can for canning, not only the appearance of the product is deteriorated and the commercial value is impaired, but also pinholes, cracks, peeling, etc. are formed in the inner and outer protective coating layers of the metal plate. There is a possibility that coating defects may occur, causing problems such as corrosion, metal elution, or leakage due to pitting corrosion. Conventionally, as a means for reinforcing the can body member, it is known to form a bead in the circumferential direction and a bead in the can height direction (can axis direction) on the can body member.
【0005】[0005]
【発明が解決しようとする問題点】缶胴部材にビードを
形成させると、前述した減圧変形等を防止させるには、
かなり有効ではあるが、缶胴部材の前面に周状ビードを
設けたとしても、外圧による変形荷重の増大(外圧変形
強度の増大)はビードを設けてない同様な缶の高々2倍
程度のオーダーであって、素材を大幅に薄肉化した場合
にも、減圧変形を完全に防止するという目的には未だ充
分に満足し得るものではない。When the bead is formed on the can body member, in order to prevent the above-mentioned reduced pressure deformation and the like,
Although quite effective, even if a circumferential bead is provided on the front surface of the can body member, the increase in the deformation load due to external pressure (increase in external pressure deformation strength) is about twice as high as that of a similar can without a bead. However, even when the material is significantly thinned, the purpose of completely preventing the reduced-pressure deformation is still unsatisfactory.
【0006】加えて、缶胴にビードを形成すると、印刷
された外表面が凹凸状となって、缶の美観や商品価値が
失われると共に、缶内面にも被覆欠陥が表れるようにな
り、金属露出(ERV値)が高くなるという欠点があ
る。このため、現在実用に供されているビード付き缶胴
は、缶胴の極く限られた部分に周状ビードを設けるにと
どまっている。In addition, when a bead is formed on the can body, the printed outer surface becomes uneven, and the aesthetics and commercial value of the can are lost, and a coating defect appears on the inner surface of the can. There is a drawback that the exposure (ERV value) becomes high. For this reason, beaded can bodies currently in practical use are provided with circumferential beads only in a very limited portion of the can body.
【0007】従って、本発明の目的は、従来のビードに
代わる新規補強構造が導入され、外圧(乃至内部減圧)
による変形強度が著しく向上し、外観特性が良好で、し
かも内面塗装缶においては缶内面における金属露出等も
比較的小さい範囲に抑制される缶詰用缶を提供すること
にある。本発明の他の目的は、缶外面が多面体に基づく
特異な立体感と美観とを備え、缶内容物の喫飲等に際し
て缶胴の把持も容易であり、しかも打痕に対する耐性を
も有している缶詰用缶を提供することにある。Therefore, it is an object of the present invention to introduce a new reinforcing structure in place of the conventional bead, so that external pressure (or internal pressure reduction) can be achieved.
The object of the present invention is to provide a can for can which has a significantly improved deformation strength, good appearance characteristics, and in the case of an internally coated can, in which metal exposure on the inner surface of the can is suppressed to a relatively small range. Another object of the present invention is that the outer surface of the can has a peculiar three-dimensional appearance and aesthetics based on a polyhedron, the can body can be easily gripped when drinking the contents of the can, and also has resistance to dents. The purpose is to provide cans for canning.
【0008】[0008]
【問題を解決するための手段】本発明によれば、缶胴の
少なくとも一部に周状多面体壁が形成され、該多面体壁
は構成単位面と、構成単位面同士が接する境界稜線及び
境界稜線同士が交わる交叉部を有し、該境界稜線及び交
叉部は構成単位面に比べて相対的に缶外側に凸となって
おり、構成単位面の隣合った缶軸方向配列が位相差をな
して配列されている缶詰用缶であって、周方向の構成単
位面の数をn(個)、缶胴内半径をr(mm)、缶胴肉厚を
t(mm)、缶胴材料の弾性率をE(kg/mm^2)、缶胴材料の
降伏応力をσy(kg/ mm^2)及び缶高当たりの多面体壁以
外の部分の高さの比をαとしたとき、前記構成単位面の
数(n)、缶胴肉厚(t)及び缶高当たりの多面体壁以
外の部分の高さの比(α)を、式「数1」及び「数2」
を満足する範囲内に設定したことを特徴とする外圧に対
して耐変形性に優れた缶詰用缶が提供される。According to the present invention, a circumferential polyhedron wall is formed on at least a part of a can body, and the polyhedron wall has structural unit surfaces, and boundary ridge lines and boundary ridge lines at which the structural unit surfaces are in contact with each other. There is a crossing part where the parts intersect each other, and the boundary ridge line and the crossing part are convex to the outside of the can relative to the constitutional unit surface, and the adjacent can axial direction arrays of the constitutional unit surface form a phase difference. The number of the constituent unit surfaces in the circumferential direction is n, the inner radius of the can body is r (mm), the thickness of the can body is t (mm), and the can body material is When the elastic modulus is E (kg / mm ^ 2), the yield stress of the can body material is σy (kg / mm ^ 2), and the ratio of the height of the portion other than the polyhedral wall per can height is α, the above configuration The number of unit surfaces (n), the thickness of the can body (t), and the height ratio (α) of the portion other than the polyhedron wall per can height can be calculated using the equations "equation 1" and "equation 2".
A can for cans having excellent deformation resistance against external pressure, characterized by being set within a range that satisfies the above condition.
【0009】本発明の缶詰用缶において、前記構成単位
面の缶軸方向の最大長さをLとし、構成単位面の缶周方
向の最大巾をwとしたとき、L及びwが式「数3」の関
係を満たすことが望ましく、また構成単位面の周方向最
大巾を与える交叉点間対角線と構成単位面の軸方向最大
長さを与える交叉点間対角線との距離(両対角線をそれ
ぞれ直角に結ぶ線の長さ)をd0 及び前記距離d0 の測
定線が構成単位面と交わる位置と構成単位面の軸方向最
大長さを与える交叉点間対角線との距離をd1としたと
き、d1はd0の関係で次式「数4」を満足する範囲内に
あることが好ましい。更に、前記構成単位面同士が接す
る境界稜線部は、なだらかな一定のR(曲率半径)を有
する一箇所曲げ或いは複数箇所曲げ部であって、Rが板
厚t及び缶胴半径rに対して式「数5」を満足する範囲
内にあるのがよい。In the canned can of the present invention, when the maximum length of the structural unit surface in the axial direction of the can is L and the maximum width of the structural unit surface in the circumferential direction of the can is w, L and w are expressed by the formula 3 "is satisfied, and the distance between the diagonal line between the crossing points that gives the maximum width in the circumferential direction of the structural unit surface and the diagonal line between the crossing points that gives the maximum axial length of the structural unit surface (both diagonal lines are orthogonal to each other. D1) and the distance between the position where the measurement line of the distance d0 intersects the structural unit surface and the diagonal line between crossing points that gives the maximum axial length of the structural unit surface is d1. It is preferable that the value of d0 is within the range satisfying the following expression "Equation 4". Further, the boundary ridge line portion where the constituent unit surfaces contact each other is a single-point bending portion or a multiple-point bending portion having a gentle R (curvature radius), and R is relative to the plate thickness t and the can body radius r. It is preferable that the value is within the range that satisfies the expression "Equation 5".
【0010】[0010]
【作用】本発明の缶詰用缶では、缶胴の少なくとも一部
に周状多面体壁が形成され、該多面体壁は構成単位面
と、構成単位面同士が接する境界稜線及び境界稜線同士
が交わる交叉部を有し、該境界稜線及び交叉部は構成単
位面に比べて相対的に缶外側に凸となっており、構成単
位面の隣合った缶軸方向配列が位相差をなして配列され
ているが、周方向の構成単位面の数をn(個)、缶胴内
半径をr(mm)、缶胴肉厚をt(mm)、缶胴材料の弾性率を
E(kg/mm^2)、缶胴材料の降伏応力をσy (kg/mm^2)及
び缶高当たりの多面体壁以外の部分の高さの比をαとし
たとき、上記n、t及びαを式「数1」及び「数2」を
満足するように設定することが顕著な特徴である。In the can for cans of the present invention, the circumferential polyhedron wall is formed on at least a part of the can body, and the polyhedron wall has the structural unit surfaces, the boundary ridge lines where the structural unit surfaces are in contact with each other, and the intersections where the boundary ridge lines intersect each other. The boundary ridgeline and the intersecting portion are relatively convex to the outside of the can as compared to the constitutional unit surface, and adjacent can axial direction arrangements of the constitutional unit surface are arranged with a phase difference. However, the number of structural unit faces in the circumferential direction is n (pieces), the inner radius of the can body is r (mm), the wall thickness of the can body is t (mm), and the elastic modulus of the material of the can body is E (kg / mm ^). 2), where the yield stress of the can body material is σy (kg / mm ^ 2) and the ratio of the height of the portion other than the polyhedron wall per can height is α, the above n, t, and α are expressed by the formula It is a salient feature to set so as to satisfy "" and "Equation 2".
【0011】「図20」は、缶胴内半径 r(mm)、缶胴
材料の弾性率 E(kg/mm^2)及び缶胴材料の降伏応力σ
y(kg/mm^2)が一定の缶胴(詳細は後述する実施例参
照)について、肉厚 tを0.08乃至0.12mmの範囲で変
化させ、式「数1」の左辺と右辺とが等しい場合(右辺
は常数と見なせる)、即ち式FIG. 20 shows the inside radius of the can body r (mm), the elastic modulus of the can body material E (kg / mm ^ 2) and the yield stress σ of the can body material.
For a can body with a constant y (kg / mm ^ 2) (see the examples described later for details), the wall thickness t is changed in the range of 0.08 to 0.12 mm, and the left side and the right side of the formula "Equation 1" are equal. If (the right side can be regarded as a constant), that is, the formula
【0012】[0012]
【数6】 を、αを横軸、nを縦軸としてプロットしたものであ
る。上記式「数6」は、多数の実験とその解析とから導
き出された実験式であり、この式「数6」よりも下側の
領域(即ち式「数1」を満足する領域)であれば、過酷
なレトルト殺菌にも耐え得ることが見い出されたのであ
る。[Equation 6] Is plotted with α as the horizontal axis and n as the vertical axis. The above formula "Equation 6" is an empirical formula derived from a number of experiments and its analysis, and may be a region below the formula "Equation 6" (that is, a region satisfying the equation "Equation 1"). For example, it has been found that it can withstand severe retort sterilization.
【0013】「図18」は、実施例1乃至5及び比較例
1乃至3について、n及びαをプロットしたもので、式
「数1」を満足する領域では、優れたレトルト耐性が得
られ、式「数1」を外れる領域では満足なレトルト耐性
が得られないことが分かる。「図19」は、実施例6乃
至7及び比較例4乃至8について、また「図20」は、
実施例8乃至10及び比較例9乃至12について、更に
「図21」は、実施例11乃至12及び比較例13乃至
14について夫々n及びαをプロットしたものである
が、何れの場合にも、式「数1」を満足する領域では、
優れたレトルト耐性が得られ、式「数1」を外れる領域
では満足なレトルト耐性が得られないことがやはり明か
である。FIG. 18 is a plot of n and α for Examples 1 to 5 and Comparative Examples 1 to 3, and excellent retort resistance is obtained in a region satisfying the expression "Equation 1". It can be seen that a satisfactory retort resistance cannot be obtained in a region outside the formula "Equation 1". "FIG. 19" is for Examples 6 to 7 and Comparative Examples 4 to 8, and "FIG. 20" is
Regarding Examples 8 to 10 and Comparative Examples 9 to 12, “FIG. 21” is a plot of n and α for Examples 11 to 12 and Comparative Examples 13 to 14, respectively. In the area that satisfies the formula "Equation 1",
It is also clear that excellent retort resistance can be obtained, and satisfactory retort resistance cannot be obtained in a region outside the formula "Formula 1".
【0014】上述した結果は、次のことを物語ってい
る。即ち、(i) 缶高当たりの多面体壁以外の部分の高さ
の比 αを小さくすることがレトルト耐性を向上させる
のに有効である、(ii)周方向の構成単位面の数nを少な
くすることがレトルト耐性を向上させるのに有効であ
る、(iii) 厚みが小さくなる程、α及びnの値を小さく
することの効果が大きい。尚、αが大きく、nが小さい
場合、耐レトルト性の領域が狭くなるのは、nが小さい
とLが制約され、L/wが小さくなるため、耐外圧に弱
くなるためと考えられる。The above results show the following. That is, (i) it is effective to improve the retort resistance by reducing the height ratio α of the portion other than the polyhedron wall per can height, (ii) the number n of the constituent unit faces in the circumferential direction is reduced. It is effective to improve the retort resistance. (Iii) The smaller the thickness, the greater the effect of reducing the values of α and n. When α is large and n is small, the retort resistance region is narrowed. It is considered that when n is small, L is restricted and L / w becomes small, so that the resistance against external pressure becomes weak.
【0015】本発明では、缶胴内半径 rに関連して、
肉厚tを前記式「数2」を満足するように定めることも
重要である。即ち、缶胴肉厚 tを式「数2」を満足す
る厚みとする事により、缶胴表面の耐食性が大幅に向上
するという予想外の事実が見いだされた。この理由は、
缶胴表面に周状多面体壁を形成する場合、肉厚が大きい
と境界稜線部や交叉部での圧縮変形量が大きくなり、そ
のため塗膜の圧縮による剥離やクラック、ピンホール等
の発生が生じるのに対して、缶胴内半径r当たりの肉厚
tを式「数2」満足するように定めると、上記境界稜線
部や交叉部での圧縮変形量を小さい範囲に抑制すること
が可能となり、塗膜の圧縮による剥離やクラック、ピン
ホール等の発生を効果的に防止し得ることになる。更
に、缶胴肉厚を低減させることにより、素材コストを節
約し、缶を軽量化することが可能となるなど、経済的な
利点も大きい。In the present invention, in relation to the inner radius r of the can body,
It is also important to determine the wall thickness t so as to satisfy the above-mentioned expression "Equation 2". That is, an unexpected fact was found that the corrosion resistance of the surface of the can body is significantly improved by setting the thickness of the can body wall thickness t to satisfy the equation "Formula 2". The reason for this is
When forming a circumferential polyhedron wall on the can body surface, if the wall thickness is large, the amount of compressive deformation at the boundary ridges and intersections will be large, so peeling, cracks, pinholes, etc. will occur due to compression of the coating film. On the other hand, if the wall thickness t per the inner radius r of the can is determined so as to satisfy the expression "Equation 2", it becomes possible to suppress the amount of compressive deformation at the boundary ridge line portion or the intersection portion within a small range. Therefore, it is possible to effectively prevent peeling, cracks, pinholes, and the like due to compression of the coating film. Further, by reducing the thickness of the can body, it is possible to save the material cost and to reduce the weight of the can.
【0016】本発明において、L及びwの値を前記式
「数3」値を満足するようにすることが、耐外圧力の点
で望ましく、L/wが式「数3」の範囲外となると、座
屈変形等を生じ易い。In the present invention, it is desirable that the values of L and w satisfy the value of the above-mentioned "expression 3", from the viewpoint of the external pressure resistance, and L / w is outside the range of the expression "expression 3". If so, buckling deformation and the like are likely to occur.
【0017】また、d1/d0が前記式「数4」の範囲に
あることも、耐腐食性の点で好ましく、d1/d0が前記
式「数4」の範囲外となると、缶胴の腐食が著しく進行
するようになる。Further, it is also preferable that d1 / d0 is in the range of the above-mentioned formula "4" from the viewpoint of corrosion resistance, and when d1 / d0 is outside the range of the above-mentioned formula "4", the can body is corroded. Will progress significantly.
【0018】更に稜線部の曲率半径Rが前記式「数5」
の範囲にあることもやはり耐食性と耐圧強度のバランス
の点で望ましく、この範囲外では、バランスが崩れ易
い。Further, the radius of curvature R of the ridge portion is expressed by the above-mentioned equation "Equation 5".
It is also desirable to be in the range of from the viewpoint of the balance between corrosion resistance and pressure resistance, and if it is out of this range, the balance tends to be lost.
【0019】[0019]
基本構造及び形状 本発明の缶詰用缶の一例を示す第「図1」(aは側面
図、bは部分断面図)及び「図2」(上面図)におい
て、この缶詰用缶は両端開口の缶胴10と両端に巻締め
られた天地缶蓋18、18とから成っている。この缶胴
10には、周状に多面体壁が形成されており、この多面
体壁は、構成単位面1と、構成単位面同士が接する境界
稜線2及び境界稜線同士が交わる交叉部3を有し、該境
界稜線2及び交叉部3は構成単位面に比べて相対的に缶
外側に凸となっている。またこの多面体壁では、構成単
位面1の隣合った缶軸方向配列が位相差をなして配列さ
れている。Basic Structure and Shape In FIG. 1 (a is a side view, b is a partial cross-sectional view) and FIG. 2 (top view) showing an example of a can of the present invention, this can is of both-end opening. It is composed of a can body 10 and top and bottom can lids 18, 18 wound on both ends. The can body 10 is formed with a polyhedral wall in a circumferential shape. The polyhedral wall has a structural unit surface 1, a boundary ridge line 2 where the structural unit surfaces are in contact with each other, and a crossing portion 3 where the boundary ridge lines intersect with each other. The boundary ridgeline 2 and the intersecting portion 3 are relatively convex to the outside of the can as compared with the structural unit surface. In this polyhedron wall, adjacent can axis direction arrays of the constituent unit surfaces 1 are arrayed with a phase difference.
【0020】この具体例において、構成単位面1は、四
辺形(菱形)abcdから成っており、構成単位面1の
隣合った缶軸方向配列が丁度1/2の位相差をなして配
列されている。「図3」は、「図1」の缶胴に使用され
る多面体壁面の四辺形単位面1の一例を取り出して示し
たものであり、菱形abcdが構成単位面1となってい
る。菱形における各辺ab、bc、cd、daは缶側面
に形成される境界稜線2に相当する辺であり、外向きに
凸となる頂点a、b、c、dが交叉部3に該当する。In this specific example, the constitutional unit surface 1 is composed of a quadrilateral (diamond) abcd, and adjacent can axial direction arrangements of the constitutional unit surface 1 are arranged with a phase difference of exactly 1/2. ing. FIG. 3 shows an example of the quadrilateral unit surface 1 of the polyhedral wall surface used in the can body of FIG. 1, and the rhombus abcd is the constituent unit surface 1. Each side ab, bc, cd, da in the rhombus is a side corresponding to the boundary ridgeline 2 formed on the side surface of the can, and the outwardly convex vertices a, b, c, d correspond to the intersection 3.
【0021】上方頂点aと下方頂点cとは同一径の円周
面上に位置しており、左方頂点bと右方頂点dとは同一
径の円周面上に位置している。配列が1/2の位相差を
なしている場合、全ての頂点は同一径の円周面上に位置
しており、「図2」に示す通り、これら頂点に対応する
缶胴内半径は、最大半径rである。一方、各稜線ab、
bc、cd、daは端で径外方に最も突出しているが、
中間に行くに従って缶中心軸からの距離、即ち径が減少
するようになっている。周方向の対角線bdの中点の径
sをとると、この径sはrよりも小さく、「図2」の場
合最小内半径を与える。缶胴上の単位面を軸方向に投影
したとき、頂点acは重なるが、軸方向の対角線ac
は、周方向の対角線bdとは重ならずに対角線bdより
も径外方向に位置することから、四辺形abcdは湾曲
乃至折れ曲がった面となっていることが了解されよう。The upper apex a and the lower apex c are located on the circumferential surface having the same diameter, and the left apex b and the right apex d are located on the circumferential surface having the same diameter. When the array has a phase difference of ½, all the vertices are located on the circumferential surface of the same diameter, and as shown in “FIG. 2”, the radii inside the can body corresponding to these vertices are The maximum radius is r. On the other hand, each ridge line ab,
Although bc, cd, and da are projected most radially outward at the ends,
The distance from the center axis of the can, that is, the diameter, decreases as it goes to the middle. When the diameter s of the midpoint of the diagonal line bd in the circumferential direction is taken, this diameter s is smaller than r, and in the case of "FIG. 2", the minimum inner radius is given. When the unit surface on the can body is projected in the axial direction, the apex ac overlaps, but the diagonal line ac in the axial direction ac
Is located radially outward of the diagonal line bd without overlapping with the diagonal line bd in the circumferential direction, it will be understood that the quadrangle abcd is a curved or bent surface.
【0022】「図3」において、構成単位面としての菱
形寸法は、周方向対角線bdの長さをwとし、軸方向対
角線acの高さをLとすると、w及びLはそれぞれ構成
単位面の周方向最大巾及び軸方向の最大長さとなる。軸
方向対角線の長さac(高さL)と、実際の構成単位面
上のac断面での長さとが異なることは前述した説明か
ら既に明かであるが、周方向対角線bdの長さ(w)と
実際の構成単位面上のbd断面での長さとが異なる場合
がある点に注意する必要がある。例えば、「図2」で
は、周方向対角線bdと実際の構成単位面上のbd断面
とが一致していて、それらの長さが等しいが、「図1」
の(a)のAC断面を示す(b)の場合には、この断面
における辺acの中点eは周方向対角線bdの位置より
も径外方向に位置しており、従って辺bedは周方向対
角線bdの長さ(w)よりも大きい。構成単位面の周方
向最大巾を与える交叉点間対角線と構成単位面の軸方向
最大長さを与える交叉点間対角線との距離(両対角線を
それぞれ直角に結ぶ線の長さ)をd0 及び前記距離d0
の測定線が構成単位面と交わる位置と構成単位面の軸方
向最大長さを与える交叉点間対角線との距離をd1とす
ると、「図1」の(b)の場合d1はd0より小さいが、
逆にd1がd0より大きかったり、或いは等しかったりし
てもよい。In FIG. 3, the rhombus dimension as the structural unit surface is such that when the length of the circumferential diagonal line bd is w and the height of the axial diagonal line ac is L, w and L are respectively the structural unit surface. Maximum width in the circumferential direction and maximum length in the axial direction. It is already clear from the above description that the length ac (height L) of the axial diagonal line is different from the actual length in the ac cross section on the constituent unit surface, but the length of the circumferential diagonal line bd (w ) And the actual length of the bd cross section on the structural unit surface may differ from each other. For example, in "FIG. 2", the diagonal line bd in the circumferential direction and the bd cross section on the actual structural unit surface are the same, and their lengths are the same, but "FIG. 1"
In the case of (b) showing the AC cross section of (a), the midpoint e of the side ac in this cross section is located radially outward from the position of the diagonal line bd in the circumferential direction, and thus the side bed is in the circumferential direction. It is larger than the length (w) of the diagonal line bd. The distance between the diagonal line between the crossing points that gives the maximum width in the circumferential direction of the structural unit surface and the diagonal line between the crossing points that gives the maximum axial length of the structural unit surface (the length of the line connecting the diagonal lines at right angles) is d0 and the above. Distance d0
Assuming that the distance between the position where the measuring line intersects the structural unit surface and the diagonal line between the crossing points that gives the maximum axial length of the structural unit surface is d1, d1 is smaller than d0 in the case of (b) of "Fig. 1". ,
Conversely, d1 may be greater than or equal to d0.
【0023】このような単位構成面が組み合わされた多
面体壁を形成させた缶胴に於いては、「図1」の(b)
に示すように、構成単位面は湾曲やU乃至V形状のくぼ
みとなって表れる。このような単位面の構成と、ほぼ1
/2の位相配置は缶胴に耐変形性を付与し、しかも多面
体壁形成前の缶胴表面積と多面体壁形成後の缶胴表面積
とを実質的にほぼ等しく保ちながら成形が可能なため、
塗膜の損傷が発生することなく、優れた耐腐食性が維持
され、加工後に残留する応力も少なく、レトルト殺菌や
その後の経時に於ける塗膜密着性や継ぎ目接着力の経時
的低下も有効に解消される。In a can body having a polyhedral wall formed by combining such unit-constituting faces as described above, (b) of FIG. 1 is used.
As shown in FIG. 5, the structural unit surface appears as a curved or U-V shaped depression. With such a unit surface configuration,
The / 2 phase arrangement imparts deformation resistance to the can body, and since molding can be performed while keeping the surface area of the can body before forming the polyhedral wall and the can surface area after forming the polyhedral wall substantially equal,
Excellent corrosion resistance is maintained without causing damage to the coating film, less stress remains after processing, and effective for retort sterilization and subsequent reduction of coating film adhesion and seam adhesive strength over time. Will be resolved.
【0024】多面体壁の構成単位面を四辺形で構成し、
この構成単位面を缶側壁に交互にがっちり導入組み込ん
だものが缶の外圧による変形を防ぐ上で最も優れてい
る。また、この菱形単位面を線bdを中心として滑らか
に湾曲させ、この湾曲部を内向きに凸となるように配置
したものでは、缶の強度が大で、耐食性に特に優れてい
る。The constitutional unit surface of the polyhedral wall is constituted by a quadrangle,
It is the best to prevent the deformation of the can due to the external pressure by introducing the structural unit surface into the side wall of the can alternately and firmly. Further, in the case where the diamond-shaped unit surface is smoothly curved around the line bd and the curved portion is arranged so as to be convex inward, the strength of the can is large and the corrosion resistance is particularly excellent.
【0025】本発明では、周方向横断面における多面体
壁の角数n、缶胴肉厚t及び缶高当たりの多面体壁以外
の部分の高さの比αを、缶胴内半径r、缶胴材料の弾性
率E及び缶胴材料の降伏応力σy の関連のもとに、式
「数1」及び「数2」を満足するように設定する。缶胴
の周に存在する構成単位面の数nは最低限3以上、好適
には4以上である。nが3を下回る場合では缶胴に充分
な多面壁面を形成することができず、また、折り曲げ加
工による板曲げの程度が激しくなるため、塗膜の耐腐食
性が著しく低下し外観も悪くする。一方その上限は、式
「数1」及び「数2」を満足するように設定される。α
の値は、缶高をH0 、多面体壁部分の高さをH1とする
と、式In the present invention, the number of corners n of the polyhedral wall in the circumferential cross section, the can barrel wall thickness t, and the ratio α of the height of the portion other than the polyhedral wall per can height to the inner radius r of the can barrel, the can barrel Based on the relationship between the elastic modulus E of the material and the yield stress σy of the can body material, the equations “Equation 1” and “Equation 2” are set so as to be satisfied. The number n of constituent unit surfaces existing around the circumference of the can body is at least 3 or more, and preferably 4 or more. If n is less than 3, it is not possible to form a sufficient multi-faceted wall surface on the can body, and the degree of plate bending due to bending becomes severe, so that the corrosion resistance of the coating film is significantly reduced and the appearance is also deteriorated. . On the other hand, the upper limit is set so as to satisfy the equations "Equation 1" and "Equation 2". α
The value of is given by the formula, where H0 is the can height and H1 is the height of the polyhedral wall.
【0026】[0026]
【数7】α=1−H1/H0 で表される。「図1」では、αは0ではないが、0に近
い値をとるが、その上限値は一般には0.9以下、特に
0.8以下であり、n及びtとの関連で式「数1」及び
「数2」を満足するように定める。「図4」は、缶胴1
0の中央部にのみ多面体壁部10aを設け、上部及び下
部に未加工部、即ち円筒部10bを残したものである。
缶胴肉厚tは、第一には、最大内半径rとの関係で式
「数2」を満足するように定められるが、tが十分小さ
い場合にも、式「数1」が満足されるように、n及びα
を選択すれば、十分な耐レトルト性が得られるというの
が、本発明の根本思想である。## EQU7 ## This is represented by .alpha. = 1-H1 / H0. In FIG. 1, α is not 0 but takes a value close to 0, but its upper limit value is generally 0.9 or less, particularly 0.8 or less, and in relation to n and t, the expression “number 1) and “Equation 2” are satisfied. "Fig. 4" shows the can body 1.
The polyhedron wall portion 10a is provided only in the central portion of 0, and the unprocessed portion, that is, the cylindrical portion 10b is left in the upper and lower portions.
The can body wall thickness t is firstly determined so as to satisfy the expression "Equation 2" in relation to the maximum inner radius r, but even when t is sufficiently small, the expression "Equation 1" is satisfied. So that n and α
It is the basic idea of the present invention that sufficient retort resistance can be obtained by selecting.
【0027】w及びLの関係は、本発明の缶詰用缶の強
度を高める上で重要であると共に、缶の外観も大きく影
響するものである。即ち、wとLとの関係は、式「数
3」を満足することが望ましく、これは四辺形の構成単
位面に限らず、六角形等の構成単位面においても同様で
ある。L/wが前記範囲を越えると、缶の外観には余り
問題はないが、本来の目的である空缶耐外圧が低下す
る。一方、L/wが前記範囲より小さい場合には、空缶
耐外圧が良好であるものの缶胴自体は軸圧縮による変形
が生じやすい。これは、一般的なパイプ材の使用であれ
ば問題ないが、缶胴にとっては重要な問題であることが
理解される。また、L/wがこのような範囲以下では外
観も悪くなり、缶表面の印刷像の見栄え等を悪くする虞
がある。The relationship between w and L is important for increasing the strength of the can of the present invention, and also has a great influence on the appearance of the can. That is, it is desirable that the relationship between w and L satisfies the formula "Equation 3", and this is not limited to the quadrangular structural unit surface, and is the same for the hexagonal structural unit surface. When the L / w exceeds the above range, the outer appearance of the can is not so problematic, but the original can outer pressure resistance of the can is lowered. On the other hand, when L / w is smaller than the above range, the can body itself tends to be deformed by axial compression although the outer can pressure resistance is good. It is understood that this is not a problem if general pipe material is used, but it is an important problem for the can body. Further, when L / w is in such a range or less, the appearance is deteriorated, and the appearance of the printed image on the can surface may be deteriorated.
【0028】構成単位面の深さ量d1 が前記関係の範囲
より小さいと、充分な耐外圧に対する作用が得られな
い。一方、深さ量d1 が前記範囲より大であると、缶の
軸方向からの座屈が生じやすく、また、多面壁の構成前
と構成後の表面積の差が大きくなるため、缶の塗膜接着
力や継ぎ目接着力が低下し好ましくない。更に印刷上の
外観も悪化する。When the depth amount d1 of the structural unit surface is smaller than the range of the above relation, sufficient action against external pressure cannot be obtained. On the other hand, if the depth amount d1 is larger than the above range, buckling of the can from the axial direction is likely to occur, and the difference in surface area between before and after the formation of the multi-sided wall becomes large. The adhesive strength and the adhesive strength at the joint are lowered, which is not preferable. Further, the appearance on printing is also deteriorated.
【0029】また、d0は構成単位面の最大巾wと密接
に関係しており、wは前述した軸方向の最大長さLと関
係している。よって、深さ量dはこれらw及びLと密接
な関係にあり、これらの長さによってその許容範囲も変
化するものである。例えば、四辺形の構成単位面におい
ては、Further, d0 is closely related to the maximum width w of the structural unit surface, and w is related to the above-mentioned maximum length L in the axial direction. Therefore, the depth amount d has a close relationship with these w and L, and the permissible range also changes depending on their length. For example, in the quadrangular unit plane,
【0030】[0030]
【数8】d0=r−s であり、## EQU8 ## d0 = rs, and
【0031】[0031]
【数9】s=rcos(π/n)、S = rcos (π / n),
【0032】[0032]
【数10】w=2rsin(π/n) より、From w = 2rsin (π / n),
【0033】[0033]
【数11】 d0=1/2・w(sin(π/n))-1・(1-cos(π/n)) となり、d0が最大巾wと周方向に存在する構成単位面
の数nによって決定されることが理解され、深さ量d1
はwが大きくなればその採りうる範囲が大きな値とな
り、nが大きくなればその採りうる範囲も小さくなる。[Equation 11] d0 = 1/2 ・ w (sin (π / n)) -1・ (1-cos (π / n)), and d0 is the maximum width w and the number of constituent unit faces existing in the circumferential direction. It is understood that it is determined by n, and the depth amount d1
The larger the value of w, the larger the range that can be taken, and the larger the value of n, the smaller the range that can be taken.
【0034】このような構成単位面の上記作用効果は
「図4」に示すように缶胴の中央部に形成したものにつ
いても見られ、このように中央部に形成したものは端部
のみに形成したものに比べ作用効果が大となる傾向にあ
る。また、「図4」の缶胴においては少なくとも缶胴高
さに対して10%以上、特に20%以上の高さで形成さ
せることが好ましい。The above-mentioned effects of the structural unit surface can be seen also in the case of being formed in the central portion of the can body as shown in FIG. The action and effect tend to be greater than those formed. Further, in the can body of "FIG. 4", it is preferable to form the can body at a height of at least 10%, especially at least 20% of the height of the can body.
【0035】構造及び形状の変形 構成単位面が四辺形となる状態から更に進めて、前記
「図3」の構成単位面である四辺形の中央部に完全な折
り目を形成して、「図5」及び「図6」に示すようにす
ることができる。この場合も、反復する構成単位面は四
辺形(菱形)であるが、個々の構成単位面1は2個の二
等辺三角形ABC及びBCDが底辺BC同士で接続され
たものであり、2個の三角形の向きを考慮外とすれば、
二等辺三角形ABCが最小面構成単位(基本面構成単
位)となっているということもできる。構成単位面1の
AD断面は、「図5」の(b)に示す通り、V形状にな
っており、構成単位面1のBC断面の辺は対角線BCと
一致している。即ち、深さ量d1はd0に等しい。Deformation of Structure and Shape Further proceeding from the state in which the constitutional unit surface is a quadrilateral, a complete fold is formed in the central portion of the quadrilateral which is the constitutional unit surface in FIG. And “FIG. 6”. Also in this case, the repeating structural unit surface is a quadrangle (diamond), but each structural unit surface 1 is one in which two isosceles triangles ABC and BCD are connected at their bases BC and two Excluding the triangle orientation,
It can be said that the isosceles triangle ABC is the minimum surface constitutional unit (basic surface constitutional unit). The AD cross section of the structural unit surface 1 has a V shape as shown in (b) of FIG. 5, and the side of the BC cross section of the structural unit surface 1 coincides with the diagonal line BC. That is, the depth amount d1 is equal to d0.
【0036】即ち、この具体例の配置では、頂点3が缶
胴の径外方向に最も突出した位置にあり、底辺4が缶胴
の径内方向にくぼんだ位置にあり、対辺2、2はそれら
の中間の位置にあり、これらで構成される多面体は、対
辺2、2を稜線とし、底辺4を谷とした多面体壁と言う
ことができる。That is, in the arrangement of this specific example, the apex 3 is at the most projecting position in the radially outer direction of the can body, the bottom side 4 is at the recessed position in the radially inner direction of the can body, and the opposite sides 2 and 2 are The polyhedron in the middle position between them can be said to be a polyhedral wall having opposite sides 2 and 2 as ridges and bottom 4 as a valley.
【0037】更に、「図7」は構成単位面1の他の変形
を示す。この構成単位面1は四辺形で、構成単位面同士
が接する境界稜線2及び境界稜線同士が交わる交叉部3
を有し、該境界稜線2及び交叉部3は構成単位面に比べ
て相対的に缶外側に凸となっている点では、他のものと
共通しているが、周方向対角線bcよりも更に内側に窪
んだ面中心部f(最凹部6)を有し、この面中心部fを
通る周方向折れ線乃至湾曲線4と軸方向折れ線乃至湾曲
線5とを有している点で今までの例と相違している。こ
の構成単位面においては、構成単位面の深さ量d1 はd
0 よりも大きく、成形上の若干の誤差を無視するとほぼ
2d0 までにすることが可能である。このタイプの缶
は、幾何学的外観も耐腐食性も充分に維持され、把持性
にすぐれてる。Further, FIG. 7 shows another modification of the structural unit surface 1. The constituent unit surface 1 is a quadrangle, and the boundary ridge line 2 where the constituent unit surfaces contact each other and the crossing portion 3 where the boundary ridge lines intersect each other.
And the boundary ridge line 2 and the intersecting portion 3 are convex to the outer side of the can relative to the constitutional unit surface, but are more common than other ones, but further than the circumferential diagonal line bc. It has a surface center portion f (the most recessed portion 6) that is recessed inward, and has a circumferential polygonal line or curved line 4 and an axial polygonal line or curved line 5 that passes through this surface central portion f. It differs from the example. In this constitutional unit surface, the depth amount d1 of the constitutional unit surface is d
It is larger than 0, and can be up to about 2d0 by ignoring some molding error. This type of can has a good geometrical appearance and corrosion resistance, and excellent grip.
【0038】また、本発明においては、構成単位面は四
辺形に限定されず、他の多角形とする事も勿論可能であ
り、例えば六角形とすることができる。「図8」は構成
単位面が六角形であるである例を示す。この場合も、六
角形の構成単位面1は、構成単位面同士が接する境界稜
線2及び境界稜線同士が交わる交叉部3を有し、該境界
稜線2及び交叉部3は構成単位面に比べて相対的に径外
方に凸となっている点及び周方向に隣合った構成単位面
の軸方向配列が一定の位相差(この例ではほぼ1/2位
相差)をなして配置される点では、他のものと共通して
いる。「図8」の両サイドを見ると、構成単位面は、缶
胴の内部に向けて窪んでいることが了解されよう。Further, in the present invention, the constitutional unit surface is not limited to a quadrangle, and it is needless to say that it may be another polygon, for example, a hexagon. FIG. 8 shows an example in which the structural unit surface is a hexagon. Also in this case, the hexagonal structural unit surface 1 has a boundary ridge line 2 where the structural unit surfaces are in contact with each other and an intersecting portion 3 where the boundary ridge lines intersect with each other, and the boundary ridge line 2 and the intersecting portion 3 are compared with the structural unit surface. A point that is relatively convex outward in the radial direction and a point that the axial arrangement of the constituent unit surfaces that are adjacent to each other in the circumferential direction are arranged with a constant phase difference (in this example, approximately 1/2 phase difference) So it has something in common with others. It can be understood from the both sides of "Fig. 8" that the component unit surface is recessed toward the inside of the can body.
【0039】更に、「図9」乃至「図10」に示すよう
に、各構成単位面1の形状を角の丸められた多角形或い
は円乃至楕円とし、境界稜線部2及び境界稜線同士が交
わる頂点3を鋭角な角部とすることなく一定の曲率半径
Rを有するように形成することができる。またRは板厚
t及び缶胴の半径Dに基づいて関係付けることができ、
Rは式Further, as shown in FIGS. 9 to 10, the shape of each structural unit surface 1 is a polygon with rounded corners or a circle or an ellipse, and the boundary ridge line portion 2 and the boundary ridge lines intersect each other. It is possible to form the apex 3 so as to have a constant radius of curvature R without forming a sharp corner. R can be related based on the plate thickness t and the radius D of the can body,
R is the formula
【0040】[0040]
【数12】t≦R≦(2/3)D を満足するようにすることが望ましい。この範囲で境界
稜線沿いのカーブを形成すると、加工缶表面に施された
塗膜の密着性が充分に維持され、且つ境界部での形成時
の応力が緩慢となり膜の損傷がみられない。また、境界
稜線部付近のこのような曲げは1つのカーブ、即ち稜線
付近に曲げRの最大箇所が1箇所のみであってもよく、
また、複数の一定の曲げRを有したものが複数箇所分散
して存在していても問題ないが、稜線付近に形成される
Rは前記範囲にあることが望ましい。[Equation 12] It is desirable to satisfy t ≦ R ≦ (2/3) D. If a curve is formed along the boundary ridgeline in this range, the adhesion of the coating film applied to the surface of the processing can is sufficiently maintained, and the stress at the boundary is slow to be formed so that the film is not damaged. Further, such bending near the boundary ridge may be one curve, that is, the maximum position of the bend R near the ridge may be only one.
Further, although there is no problem even if there are a plurality of constant bends R distributed at a plurality of locations, it is desirable that the R formed near the ridgeline be within the above range.
【0041】尚、「図10」に示すように、構成単位面
1が四辺形である場合に於いても、交叉部3に曲率部R
を形成することができるのはいうまでもない。As shown in FIG. 10, even when the structural unit surface 1 is a quadrangle, the curved portion R is formed at the intersection 3 as well.
It goes without saying that can be formed.
【0042】更に、本発明は所謂ビード缶に適用するこ
ともできる。「図22」は巻締部18から小間隔をおい
て周方向ビード20を設けた缶であるが、「図23」に
示す通り、上下の周方向ビード間に構成単位面1からな
る多面体壁を刻設する事もできる。Furthermore, the present invention can be applied to so-called bead cans. 22. FIG. 22 shows a can with a circumferential bead 20 provided at a small distance from the winding portion 18, but as shown in FIG. 23, a polyhedral wall consisting of the structural unit surface 1 between the upper and lower circumferential beads. It is also possible to engrave.
【0043】製造法 本発明は、金属板等を筒状に成形し、対向する端線部を
溶接、接着或いはハンダ付け等の手段で接合して側面継
ぎ目付き缶胴を成形し、この缶胴の両端を天地蓋と巻締
して成る所謂スリーピース缶や、金属板を有底缶胴に絞
り深絞り成形或いは更にしごき成形に付し、この有底缶
胴の上端に蓋を巻締して成る所謂ツーピース缶に適用す
ることができる。Manufacturing Method According to the present invention, a metal plate or the like is formed into a tubular shape, and opposing end line portions are joined by means such as welding, adhesion, or soldering to form a side seamed can barrel, and the can barrel is formed. A so-called three-piece can, which is formed by winding both ends of the can with a top and bottom lid, or a metal plate is drawn into a bottomed can body or deep drawn or further ironed, and the lid is wound around the upper end of the bottomed can body. It can be applied to so-called two-piece cans.
【0044】本発明の缶詰用缶は、蓋を巻締る前の缶胴
を、内型と外型とで型押して前記多面体を形成すること
により製造される。使用する内型は、前記多面体の頂点
及び稜線に対応する突起を表面に有するものであり、一
方使用する外型は、前記多面体の谷に対応する突起を表
面に有するものであり、これらの内型及び外型を缶胴を
介して噛み合わせることにより、多面体の形成が行われ
る。The canned can of the present invention is manufactured by forming the polyhedron by pressing the can body before winding the lid with the inner mold and the outer mold. The inner mold used has projections corresponding to the vertices and edges of the polyhedron on the surface, while the outer mold used has projections corresponding to the valleys of the polyhedron on the surface. The polyhedron is formed by engaging the mold and the outer mold with each other through the can body.
【0045】「図12」乃至「図16」は、構成単位面
が四辺形である缶胴への多面体刻設の方法を示す説明図
であるが、構成単位面が四辺形以外の場合でも原理的に
これと変わりがない。缶胴10は内型11及び外型12
に挟まれた状態で回転される。内型11の表面には、多
面体の頂点に対応した突起13と、缶周面に対して屈折
乃至湾曲した菱形面14(「図12」は半面のみ示す)
とが形成されており、更に「図12」には、多面体壁の
屈折乃至湾曲部(谷部或いは対向二等辺三角の共通底
辺)に対応する凹部15が中央切断面の線として示され
ている。外型12の表面には、内型の突起13に対応す
る凹部16が形成されており、内型の凹部15に対応す
る突起部17が形成されていて、この突起部17は多面
体壁の窪んだ屈折乃至湾曲部(谷部或いは対向二等辺三
角の共通底辺)を形成する。「図14」及び「図15」
は、外型のこの突起部17を線V−Vで横断して示した
拡大断面図である。「図14」では湾曲した突起部17
及び「図15」ではV字型に屈曲した突起部17が夫々
缶胴10と噛み合って、窪んだ単位構成面1の成形が行
われることが了解されよう。また、「図14」および
「図15」において、外型12の素材としては、弾性
体、例えばゴム状のものを使用すれば、構成単位面の成
形が塗膜等の損傷無しに容易に行うことができる。FIGS. 12 to 16 are explanatory views showing a method of engraving a polyhedron on a can body whose constituent unit surface is a quadrangle, but the principle is applicable even when the constituent unit surface is other than a quadrangle. Is no different from this. The can body 10 includes an inner mold 11 and an outer mold 12.
It is rotated while being sandwiched between. On the surface of the inner mold 11, projections 13 corresponding to the vertices of a polyhedron and a rhombic surface 14 refracted or curved with respect to the can peripheral surface ("FIG. 12" shows only a half surface).
Further, in FIG. 12, the concave portion 15 corresponding to the bent or curved portion (valley portion or common base of the facing isosceles triangle) of the polyhedral wall is shown as a line of the central cut surface. . On the surface of the outer mold 12, a concave portion 16 corresponding to the inner protrusion 13 is formed, and a protruding portion 17 corresponding to the inner concave portion 15 is formed, and the protruding portion 17 is a recess of the polyhedral wall. Further, a refraction or curved portion (a valley portion or a common base of opposing isosceles triangles) is formed. "Figure 14" and "Figure 15"
[FIG. 8] is an enlarged cross-sectional view showing this protrusion 17 of the outer die, taken along the line V-V. In FIG. 14, the curved protrusion 17
Further, in FIG. 15, it will be understood that the protrusions 17 bent in a V shape are respectively engaged with the can body 10 to form the concave unit component surface 1. Further, in FIGS. 14 and 15, if the outer mold 12 is made of an elastic material, for example, a rubber-like material, the constituent unit surface can be easily molded without damaging the coating film or the like. be able to.
【0046】これらの内型11と外型12とを缶胴10
を介して噛み合わせ、且つこれらを同期した速度で回転
させることにより、缶胴への多面体の刻設が行われる。
尚、回転に際して一部に噛み合わせがずれる場合には内
型或いは外型の回転軸が若干上下動するようにしてもよ
い。The inner mold 11 and the outer mold 12 are connected to the can body 10.
The polyhedrons are engraved on the can body by engaging them through and rotating them at a synchronized speed.
Incidentally, when a part of the meshes is misaligned during the rotation, the inner or outer rotating shaft may be slightly moved up and down.
【0047】「図12」及び「図13」の具体例におい
て、内型11及び外型12は、缶胴10よりも小さい径
を有しているが、内型11と外型12の表面における基
本面構成単位の周方向への配置数は缶胴周囲のそれに比
べて1個或いは複数個少ないものとしているが、実用上
多面体の形成には問題はない。内型11と外型12とを
離すことにより、多面体刻設缶胴の取り出しが容易に行
われる。In the specific examples shown in FIGS. 12 and 13, the inner mold 11 and the outer mold 12 have a smaller diameter than the can body 10, but the inner mold 11 and the outer mold 12 have the same surface. The number of basic surface constitutional units arranged in the circumferential direction is set to be one or plural smaller than that in the periphery of the can body, but there is no problem in forming a polyhedron in practical use. By separating the inner mold 11 and the outer mold 12, the polyhedral carved can barrel can be easily taken out.
【0048】別法として、「図16」に示す通り、缶胴
の二分の一周よりも短い周長の部分外周面を有する内型
11aと同様の内周面を有する外型12aとを使用し、
缶胴を位置決めした状態で、内型11aと外型12aと
で、缶胴の全周囲に対して複数回厚印を行うことによっ
ても、多面体の刻設を行うことができる。この場合もど
ちらか一方、叉は双方を弾性材として使用することがで
きる。Alternatively, as shown in FIG. 16, an inner mold 11a having a partial outer peripheral surface having a peripheral length shorter than one half of the can body and an outer mold 12a having the same inner peripheral surface are used. ,
It is also possible to engrave a polyhedron by making thickness marking a plurality of times on the entire circumference of the can body with the inner mold 11a and the outer mold 12a while the can body is positioned. Also in this case, either one or both can be used as the elastic material.
【0049】これらの刻設処理は、缶胴の全面或いは中
央部、更には複数の箇所に行うことができる。缶胴の上
端及び下端にネックイン加工が行われている場合には、
ネックイン加工部を除いた部分に多面体の刻設処理を行
うとよい。These engraving treatments can be performed on the entire surface of the can body or in the central portion thereof, and also at a plurality of locations. If neck-in processing is applied to the top and bottom of the can body,
It is advisable to engrave the polyhedron on the portion excluding the neck-in processed portion.
【0050】また、図示していないが、「図8」乃至第
「図10」に示すように構成単位面が六角形、角の丸め
られた多角形或いはその他の形状である場合、それぞれ
に応じた型の使用が可能であり、更に各型の谷部及び頂
部となる部分を所定の曲率半径Rを有するものを使用す
ることによって、「図8」及び「図10」、更には「図
11」に示すように境界部を緩やかな曲部としたものを
製造することができる。Although not shown, when the constituent unit surface is a hexagon, a polygon with rounded corners, or another shape, as shown in FIGS. It is possible to use different molds, and by using those having a predetermined radius of curvature R for the troughs and tops of each mold, "FIG. 8" and "FIG. 10" It is possible to manufacture one having a gentle curved portion at the boundary as shown in FIG.
【0051】また、本発明においては、構成単位面をバ
ルジ方式で缶胴に設けることもできる。バルジ方式は、
膨縮構造の部材、例えばすりわり状構成の合成ゴムを缶
胴内に挿入し、これを缶胴内で拡張することによって缶
胴の径を大きくする方法である。このような方式にあっ
ては、構成単位面の外型を缶胴周囲に配し、膨縮部材に
よって缶胴を膨張させ、缶胴を外型に圧着させて缶胴の
径を大きく加工及び缶胴の厚みを薄く加工すると同時
に、前述した優れた構成単位面を缶胴に形成することが
できる。このような構成単位面の形成に於いては、缶胴
の両端部のネックイン加工を予め行うことができ、ま
た、本発明が目的とする薄型化が容易にできる。更に、
缶胴に構成単位面を正確な配置に形成することができ
る。Further, in the present invention, the structural unit surface may be provided on the can body by a bulge method. The bulge method is
This is a method of increasing the diameter of the can body by inserting a member having an expandable / contractible structure, for example, a synthetic rubber having a slip-like structure into the can body and expanding it. In such a system, the outer die of the structural unit surface is arranged around the can body, the can body is inflated by the expansion / contraction member, and the can body is pressure-bonded to the outer die so that the diameter of the can body is increased and processed. The thickness of the can body can be reduced, and at the same time, the excellent structural unit surface described above can be formed on the can body. In forming such a structural unit surface, the neck-in processing of both end portions of the can body can be performed in advance, and the reduction in thickness for the purpose of the present invention can be facilitated. Furthermore,
It is possible to form the constituent unit surfaces on the can body in an accurate arrangement.
【0052】金属素材 本発明では、金属板としては各種表面処理鋼板やアルミ
ニウム等の軽金属板が使用される。表面処理鋼板として
は、冷圧延鋼板叉はそれを焼鈍後二次冷間圧延し、亜鉛
メッキ、錫メッキ、ニッケルメッキ、電解クロム酸処
理、クロム酸処理等の表面処理の一種叉は二種以上行な
ったものを用いることができる。好適な表面処理鋼板の
一例は、電解クロム酸処理鋼板であり、特に10乃至2
00mg/m^2の金属クロム層と1乃至50mg/m^2(金属
クロム換算)のクロム酸化物層とを備えたものであり、
このものは塗膜密着性と耐腐食性との組み合わせに優れ
ている。表面処理鋼板の他の例は、0.5乃至11.2g/m^2
の錫メッキ量を有する硬質ブリキ板である。このブリキ
板は金属クロム換算で0.5乃至100mg/m^2のクロム酸叉
はクロム酸/リン酸処理が行われていることが望まし
い。Metal Material In the present invention, various surface-treated steel plates and light metal plates such as aluminum are used as the metal plate. As the surface-treated steel sheet, one or more surface treatments such as cold-rolled steel sheet or secondary cold-rolled after annealing, zinc plating, tin plating, nickel plating, electrolytic chromic acid treatment, chromic acid treatment, etc. What is done can be used. An example of a suitable surface-treated steel sheet is an electrolytic chromic acid-treated steel sheet, particularly 10 to 2
A metal chrome layer of 00 mg / m ^ 2 and a chromium oxide layer of 1 to 50 mg / m ^ 2 (metal chrome conversion) are provided,
This product has an excellent combination of coating film adhesion and corrosion resistance. Another example of surface-treated steel sheet is 0.5 to 11.2g / m ^ 2
It is a hard tin plate having the tin plating amount of. It is desirable that this tin plate has been treated with chromic acid or chromic acid / phosphoric acid of 0.5 to 100 mg / m ^ 2 in terms of metal chromium.
【0053】軽金属板としては、所謂純アルミニウム板
の他にアルミニウム合金板が使用される。耐腐食性と加
工性との点で優れたアルミニウム合金板は、Mn:0.2乃至
1.5重量%、Mg:0.8乃至5重量%、Zn:0.25乃至0.3重量
%、Cu:0.15乃至0.25重量%、残部がAlの組成を有する
ものである。これらの軽金属板も、金属クロム換算で、
クロム量が3乃至300mg/m^2となるようなクロム酸処
理或いはクロム酸/リン酸処理が行われることが望まし
い。As the light metal plate, an aluminum alloy plate is used in addition to the so-called pure aluminum plate. Aluminum alloy sheets with excellent corrosion resistance and workability are Mn: 0.2 to
The composition is 1.5% by weight, Mg: 0.8 to 5% by weight, Zn: 0.25 to 0.3% by weight, Cu: 0.15 to 0.25% by weight, and the balance is Al. These light metal plates are also converted into metal chromium,
Chromic acid treatment or chromic acid / phosphoric acid treatment is preferably performed so that the amount of chromium is 3 to 300 mg / m ^ 2.
【0054】缶胴部に於ける金属の厚みtは、前記式
「数1」及び「数2」を満足する厚みであり、厚みを小
さく設定した場合にも、構成単位面の数n及びαを所定
の範囲に選ぶことによって、優れた対レトルト性が達成
されることが本発明の利点の一つである。具体的な厚み
は、缶胴の最大半径や金属の種類によっても相違する
が、表面処理鋼板の場合、0.08乃至0.24mm、特に0.12乃
至0.17mmの薄手鋼板類や、アルミ板の場合、0.1乃至0.4
mm、特に0.14乃至0.3mmの薄手アルミ板の中から所定厚
みのものを選択して、高い外圧強度を有する缶を得るこ
とができる。The thickness t of the metal in the body of the can is a thickness that satisfies the above-mentioned equations "equation 1" and "equation 2". Even when the thickness is set to be small, the number n and α of the constituent unit faces are small. It is one of the advantages of the present invention that excellent anti-retort property can be achieved by selecting the above range. The specific thickness varies depending on the maximum radius of the can body and the type of metal, but in the case of surface-treated steel sheet, 0.08 to 0.24 mm, particularly 0.12 to 0.17 mm thin steel sheet, and in the case of aluminum sheet, 0.1 to 0.4
It is possible to obtain a can having a high external pressure strength by selecting a thin aluminum plate having a predetermined thickness from a thin aluminum plate having a thickness of 0.1 mm, particularly 0.14 to 0.3 mm.
【0055】保護被覆 本発明は、多面体刻設に先立った何れかの段階で金属板
に樹脂の保護被覆を施し、これを多面体刻設操作に付し
ても、保護被覆層を損傷させないことが顕著な利点であ
る。保護被覆の形成は、保護塗料を設けることにより、
或いは熱可塑性樹脂フィルムをラミネートすることによ
り行われる。Protective coating In the present invention, the protective coating of resin is applied to the metal plate at any stage prior to engraving the polyhedron, and the protective coating layer is not damaged even when this is subjected to the polyhedral engraving operation. This is a remarkable advantage. The formation of the protective coating, by providing a protective coating,
Alternatively, it is performed by laminating a thermoplastic resin film.
【0056】保護塗料としては、熱硬化性及び熱可塑性
樹脂からなる任意の保護塗料:例えばフェノール−エポ
キシ塗料、アミノ−エポキシ塗料等の変性エポキシ塗
料:例えば塩化ビニル−酢酸ビニル共重合体、塩化ビニ
ル−酢酸ビニル共重合体部分ケン化物、塩化ビニル−酢
酸ビニル−無水マレイン酸共重合体、エポキシ変性−、
エポキシアミノ変性−或はエポキシフェノール変性−ビ
ニル塗料等のビニルまたは変性ビニル塗料:アクリル樹
脂系塗料:スチレン−ブタジエン系共重合体等の合成ゴ
ム系塗料等の単独または2種以上の組合せが使用され
る。As the protective coating, any protective coating composed of thermosetting and thermoplastic resins: modified epoxy coating such as phenol-epoxy coating, amino-epoxy coating, etc .: vinyl chloride-vinyl acetate copolymer, vinyl chloride. -Partially saponified vinyl acetate copolymer, vinyl chloride-vinyl acetate-maleic anhydride copolymer, epoxy modified-,
Epoxyamino-modified or epoxyphenol-modified vinyl such as vinyl paint or modified vinyl paint: Acrylic resin-based paint: Styrene-butadiene-based copolymer or other synthetic rubber-based paint, etc., alone or in combination of two or more. It
【0057】これらの塗料は、エナメル或はラッカー等
の有機溶媒溶液の形で、或は水性分散液または水溶液の
形で、ローラ塗装、スプレー塗装、浸漬塗装、静電塗
装、電気泳動塗装等の形で金属素材に施す。勿論、前記
樹脂塗料が熱硬化性の場合には、必要により塗料を焼付
ける。保護塗膜は、耐腐食性と加工性との見地から、一
般に2乃至30μm、特に3乃至20μmの厚み(乾燥
状態)を有することが望ましい。また、加工性を向上さ
せるために、塗膜中に、各種滑剤を含有させておくこと
ができる。These paints are used in the form of an organic solvent solution such as enamel or lacquer, or in the form of an aqueous dispersion or aqueous solution, such as roller coating, spray coating, dip coating, electrostatic coating, and electrophoretic coating. Shaped on metal material. Of course, when the resin paint is thermosetting, the paint is baked if necessary. From the viewpoint of corrosion resistance and workability, the protective coating film preferably has a thickness (dry state) of generally 2 to 30 μm, particularly 3 to 20 μm. Further, in order to improve the processability, various lubricants can be contained in the coating film.
【0058】ラミネートに用いる熱可塑性樹脂フィルム
としては、ポリエチレン、ポリプロピレン、エチレン−
プロピレン共重合体、エチレン−酢酸ビニル共重合体、
エチレン−アクリルエステル共重合体、アイオノマー等
のオレフィン系樹脂フィルム:ポリエチレンテレフタレ
ート、ポリブチレンテレフタレート、エチレンテレフタ
レート/イソフタレート共重合体等のポリエステルフィ
ルム:ナイロン6、ナイロン6,6、ナイロン11、ナ
イロン12等のポリアミドフィルム:ポリ塩化ビニルフ
ィルム:ポリ塩化ビニリデンフィルム等を挙げることが
できる。これらのフィルムは未延伸のものでも、二軸延
伸のものでもよい。その厚みは、一般に3乃至50μ
m、特に5乃至40μmの範囲にあることが望ましい。
フィルムの金属板への積層は、熱融着法、ドライラミネ
ーション、押出コート法等により行われ、フィルムと金
属板との間に接着性(熱融着性)が乏しい場合には、例
えばウレタン系接着剤、エポキシ系接着剤、酸変性オレ
フィン樹脂系接着剤、コポリアミド系接着剤、コポリエ
ステル系接着剤を介在させることができる。As the thermoplastic resin film used for lamination, polyethylene, polypropylene, ethylene-
Propylene copolymer, ethylene-vinyl acetate copolymer,
Olefin-based resin films such as ethylene-acrylic ester copolymers and ionomers: Polyester films such as polyethylene terephthalate, polybutylene terephthalate, ethylene terephthalate / isophthalate copolymers: nylon 6, nylon 6,6, nylon 11, nylon 12, etc. Polyamide film: polyvinyl chloride film: polyvinylidene chloride film. These films may be unstretched or biaxially stretched. Its thickness is generally 3 to 50 μ
m, particularly preferably in the range of 5 to 40 μm.
Lamination of the film on the metal plate is carried out by a heat fusion method, dry lamination, extrusion coating method or the like. When the adhesiveness (heat fusion property) between the film and the metal plate is poor, for example, a urethane type is used. An adhesive, an epoxy adhesive, an acid-modified olefin resin adhesive, a copolyamide adhesive, or a copolyester adhesive can be interposed.
【0059】スリーピース缶の場合、上記樹脂被覆板を
使用し、これを筒状に成形し、樹脂未被覆の端線部をそ
れ自体公知の電気抵抗溶接法で溶接し、この溶接継目を
樹脂で被覆して、缶胴とする。また、端線部をナイロン
系接着剤を介して熱接着して缶胴とすることもできる
し、更に端線部に金属錫層が存在する場合にはハンダ付
で接合することもできる。In the case of a three-piece can, the above resin-coated plate is used, and this is molded into a tubular shape, and the end line portion not covered with the resin is welded by an electric resistance welding method known per se. Coat to make a can body. Further, the end line portion can be heat-bonded with a nylon adhesive to form a can body, and when a metal tin layer is present on the end line portion, they can be joined by soldering.
【0060】更に、ツーピース缶の場合、被覆金属板を
絞り加工或いは深絞り加工に賦して、総絞り比が1.1 乃
至4.0 、特に1.5乃至3.0 の範囲にある有底缶胴を製造
し、この有底缶胴に対して多面体の刻設を行う。勿論、
深絞り時或いはこれに引続いて、曲げ伸しによる薄肉化
加工やしごき加工を行うこともできる。しごき加工を行
う場合には、前以って樹脂被覆を設けておいてもよい
し、しごき加工後の缶胴に樹脂被覆を設けてもよい。Further, in the case of a two-piece can, the coated metal plate is subjected to drawing or deep drawing to produce a bottomed can barrel having a total drawing ratio in the range of 1.1 to 4.0, particularly 1.5 to 3.0. A polyhedron is engraved on the bottomed can body. Of course,
At the time of deep drawing or subsequent thereto, thinning processing by bending and stretching and ironing processing can also be performed. When performing ironing, a resin coating may be provided in advance, or a resin coating may be provided on the can body after the ironing.
【0061】[0061]
【実施例】「図17」は、缶の構成要素をTFS材(E=210
00Kg/mm^2,σy=60Kg/mm^2)、半径26.2mm、缶高さ120m
m、板厚t(0.08〜0.12)mmとしたとき、実験式「数1」を
満足するn,αの境界線を示している。「図17」にお
いて曲線よりn,αが小さい側の領域で周状多面体壁を
形成した缶はレトルト殺菌において外圧を受けた際、缶
胴の変形はなく良好な結果を示した。以下具体的に説明
する。[Example] "Fig. 17" shows that the components of the can are made of TFS material (E = 210).
00Kg / mm ^ 2, σy = 60Kg / mm ^ 2), radius 26.2mm, can height 120m
When m and the plate thickness t (0.08 to 0.12) mm, the boundary line between n and α that satisfies the empirical formula “Equation 1” is shown. In FIG. 17, the can having the circumferential polyhedron wall formed in the region where n and α were smaller than the curve showed good results without deformation of the can barrel when subjected to external pressure during retort sterilization. This will be specifically described below.
【0062】実施例1 エポキシ系塗料を5μmの厚みに塗布した板厚0.12mmのTF
S 材をポリアミド系の接着剤を介して重ね合せ接合して
なる半径26.2mm、缶高さ120 mmの接着缶の缶胴に、「図
3」に示す最小構成単位面を、缶高の中心を含み、円周
方向に9個連続させ、且つ缶軸方向に1/2位相差で60mm
幅で設け、L/Wを0.98,深さ比d1/d0を0.95となる
ように外面体を押し具を用いて形成した。この缶胴に蓋
を巻き締めた空缶にビーフシチューを真空度が25cmHgに
なるように真空巻締した後、125℃で60分のレトルト殺
菌処理を行い、1.3Kg/cm^2の圧力をかけながら冷却
後、缶胴部の変形を目視で観察し耐性を評価した。その
結果、ほとんど変形はなく、レトルト殺菌耐性を有して
いた。Example 1 TF having a plate thickness of 0.12 mm, which is obtained by applying an epoxy-based paint to a thickness of 5 μm.
The minimum constitutional unit surface shown in "Fig. 3" is placed at the center of the can height on the can body of an adhesive can with a radius of 26.2 mm and a can height of 120 mm, which is made by stacking and joining S materials with a polyamide adhesive. , Including 9 in the circumferential direction, and 60 mm with 1/2 phase difference in the can axis direction.
The outer surface body was formed by using a pressing tool so as to have a width and an L / W of 0.98 and a depth ratio d1 / d0 of 0.95. After vacuum-wrapping the beef stew in an empty can with the lid wrapped around the can body to a vacuum degree of 25 cmHg, perform retort sterilization treatment at 125 ° C for 60 minutes, and apply a pressure of 1.3 Kg / cm ^ 2. After cooling while applying, the deformation of the body of the can was visually observed to evaluate the resistance. As a result, there was almost no deformation and it had resistance to retort sterilization.
【0063】実施例 2、3、4、5 実施例 2、3、4、5 は、実験式「数1」を満足する
ようなn,α、をそれぞれ「表1」に示した値となるよ
うにした以外は実施例1と同様にして周状多面体壁を持
つ缶胴を成形した。この缶胴を用い実施例1と同様にし
て、レトルト殺菌耐性を評価した。その結果を「表1」
に示す。「図18」に実験式「数1」の境界線と実施例
1〜5の(n,α)の位置を○数字で示す。Examples 2, 3, 4, 5 In Examples 2, 3, 4, 5, n and α satisfying the empirical formula "Equation 1" are values shown in "Table 1". A can body having a peripheral polyhedron wall was formed in the same manner as in Example 1 except that the above procedure was performed. Using this can body, the retort sterilization resistance was evaluated in the same manner as in Example 1. The result is "Table 1"
Shown in. In FIG. 18, the boundary line of the empirical formula “Equation 1” and the positions of (n, α) in Examples 1 to 5 are indicated by circles.
【0064】比較例 1、2、3 比較例 1、2、3 は、実験式「数1」を満足しない
ようなn,αをそれぞれ「表2」に示した値となるよう
にした以外は実施例1と同様にして周状多面体壁を持つ
缶胴を成形した。この缶胴を用い実施例1と同様にし
て、レトルト殺菌耐性を評価した。 その結果を「表
1」に示す。 「図18」に実験式「数1」の境界線と
比較例1〜3の(n,α)の位置を△数字で示す。Comparative Examples 1, 2, and 3 Comparative Examples 1, 2, and 3 are different from each other except that n and α which do not satisfy the empirical formula "Equation 1" are set to the values shown in "Table 2". A can body having a peripheral polyhedron wall was formed in the same manner as in Example 1. Using this can body, the retort sterilization resistance was evaluated in the same manner as in Example 1. The results are shown in "Table 1". In FIG. 18, the boundaries of the empirical formula “Equation 1” and the positions of (n, α) in Comparative Examples 1 to 3 are indicated by Δ numbers.
【0065】実施例 6、7 実施例 6、7 は、実験式「数1」を満足するような
n,α、及び板厚tをそれぞれ「表2」に示した値とな
るようにした以外は実施例1と同様にして周状多面体壁
を持つ缶胴を成形した。この缶胴を用い実施例1と同様
にして、レトルト殺菌耐性を評価した。その結果を「表
2」に示す。「図19」に実験式「数1」の境界線と実
施例6、7の(n,α)の位置を○数字で示す。Examples 6 and 7 In Examples 6 and 7, except that n and α and plate thickness t satisfying the empirical formula "Equation 1" are set to the values shown in "Table 2", respectively. In the same manner as in Example 1, a can body having a circumferential polyhedron wall was formed. Using this can body, the retort sterilization resistance was evaluated in the same manner as in Example 1. The results are shown in "Table 2". In FIG. 19, the boundary line of the empirical formula “Equation 1” and the positions of (n, α) in Examples 6 and 7 are indicated by circles.
【0066】比較例 4、5、6、7、8 比較例 4、5、6、7、8 は、実験式「数1」を満足
しないようなn,α、及び板厚tをそれぞれ「表2」に
示した値となるようにした以外は実施例1と同様にして
周状多面体壁を持つ缶胴を成形した。この缶胴を用い実
施例1と同様にして、レトルト殺菌耐性を評価した。そ
の結果を「表2」に示す。「図19」に実験式「数1」
の境界線と比較例4〜8の(n,α)の位置を△数字で
示す。Comparative Examples 4, 5, 6, 7, and 8 Comparative Examples 4, 5, 6, 7, and 8 show the values of n, α, and plate thickness t that do not satisfy the empirical formula "Equation 1", respectively. A can body having a circumferential polyhedron wall was formed in the same manner as in Example 1 except that the values shown in "2" were set. Using this can body, the retort sterilization resistance was evaluated in the same manner as in Example 1. The results are shown in "Table 2". Empirical formula "Equation 1" in "Fig. 19"
Boundary line of and the position of (n, α) in Comparative Examples 4 to 8 are indicated by Δ numbers.
【0067】実施例 8、9、10 実施例 8、9、10 は、缶半径を32.7mm、板厚tを0.1
4mmとし、実験式「数1」を満足するようなn,αをそ
れぞれ「表1」に示した値となるようにした以外は実施
例1と同様にして周状多面体壁を持つ缶胴を成形した。
この缶胴を用い実施例1と同様にして、レトルト殺菌耐
性を評価した。その結果を「表1」に示す。「図20」
に実験式「数1」の境界線と実施例8〜10の(n,
α)の位置を○数字で示す。Examples 8, 9 and 10 In Examples 8, 9 and 10, the can radius was 32.7 mm and the plate thickness t was 0.1.
A can body having a peripheral polyhedron wall was prepared in the same manner as in Example 1 except that the thickness was 4 mm and the values of n and α satisfying the empirical formula "Equation 1" were respectively set to the values shown in "Table 1". Molded.
Using this can body, the retort sterilization resistance was evaluated in the same manner as in Example 1. The results are shown in "Table 1". "Figure 20"
In addition, the boundary line of the empirical formula “Equation 1” and (n,
The position of α) is indicated by a circle.
【0068】比較例 9、10、11、12 比較例 9、10 、11、12 は、缶半径を32.7mmと
し、実験式「数1」を満足しないようなn,αをそれぞ
れ「表2」に示した値となるようにした以外は実施例1
と同様にして周状多面体壁を持つ缶胴を成形した。この
缶胴を用い実施例1と同様にして、レトルト殺菌耐性を
評価した。その結果を「表2」に示す。「図20」に実
験式「数1」の境界線と比較例9〜12の(n,α)の
位置を△数字で示す。Comparative Examples 9, 10, 11, 12 Comparative Examples 9, 10, 11, 12 have a can radius of 32.7 mm and n and α that do not satisfy the empirical formula "Equation 1" are shown in Table 2 respectively. Example 1 except that the values shown in FIG.
A can body having a peripheral polyhedron wall was formed in the same manner as in. Using this can body, the retort sterilization resistance was evaluated in the same manner as in Example 1. The results are shown in "Table 2". In FIG. 20, the boundaries of the empirical formula “Equation 1” and the positions of (n, α) in Comparative Examples 9 to 12 are indicated by Δ numbers.
【0069】実施例 11、12 実施例 11、12 は、実験式「数1」を満足するよう
なn,α、t、及び缶胴材のE,σyをそれぞれ「表
1」に示した値となるようにした以外は実施例1と同様
にして周状多面体壁を持つ缶胴を成形した。この缶胴を
用い実施例1と同様にして、レトルト殺菌耐性を評価し
た。その結果を「表1」に示す。「図21」に実験式
「数1」の境界線と実施例11、12の(n,α)の位
置を○数字で示す。Examples 11 and 12 In Examples 11 and 12, the values of n, α, t, and E and σy of the can body which satisfy the empirical formula "Equation 1" are shown in "Table 1", respectively. A can body having a peripheral polyhedron wall was formed in the same manner as in Example 1 except that the above was adopted. Using this can body, the retort sterilization resistance was evaluated in the same manner as in Example 1. The results are shown in "Table 1". In FIG. 21, the boundary line of the empirical formula “Equation 1” and the positions of (n, α) in Examples 11 and 12 are indicated by circles.
【0070】比較例 13、14、15 比較例 13、14、15は、実験式「数1」を満足し
ないようなn,α、t、及び缶胴材のE,σyをそれぞ
れ「表2」に示した値となるようにした以外は実施例1
と同様にして周状多面体壁を持つ缶胴を成形した。この
缶胴を用い実施例1と同様にして、レトルト殺菌耐性を
評価した。その結果を「表2」に示す。「図21」に実
験式「数1」の境界線と比較例13〜14の(n,α)
の位置を△数字で示す。Comparative Examples 13, 14 and 15 In Comparative Examples 13, 14 and 15, n, α, t and E, σy of the can body material which do not satisfy the empirical formula "Equation 1" are shown in Table 2, respectively. Example 1 except that the values shown in FIG.
A can body having a peripheral polyhedron wall was formed in the same manner as in. Using this can body, the retort sterilization resistance was evaluated in the same manner as in Example 1. The results are shown in "Table 2". In FIG. 21, the boundary line of the empirical formula “Equation 1” and (n, α) of Comparative Examples 13 to 14 are shown.
The position of is indicated by a triangle.
【0071】実施例 13 実施例13は、実施例1と同様な缶胴に「図23」に示
すように少数ビードと周状多面体壁を形成したもので、
この缶胴を用い実施例1と同様にして、レトルト殺菌耐
性を評価した。その結果を「表1」に示す。Example 13 Example 13 is the same as that of Example 1 except that a small number of beads and a peripheral polyhedral wall were formed on the can body as shown in FIG. 23.
Using this can body, the retort sterilization resistance was evaluated in the same manner as in Example 1. The results are shown in "Table 1".
【0072】比較例 16 比較例 16 は、実施例1と同様な缶胴に周状多面体壁
を形成していないもので、この缶胴を用い実施例1と同
様にして、レトルト殺菌耐性を評価した。その結果を
「表2」に示す。Comparative Example 16 In Comparative Example 16, the same can barrel as in Example 1 was not formed with the peripheral polyhedron wall, and the retort sterilization resistance was evaluated in the same manner as in Example 1 using this can barrel. did. The results are shown in "Table 2".
【0073】比較例 17 比較例17は、実施例1と同様な缶胴に「図22」に示
すように少数ビードのみを形成したもので、この缶胴を
用い実施例1と同様にして、レトルト殺菌耐性を評価し
た。その結果を「表2」に示す。Comparative Example 17 In Comparative Example 17, only a small number of beads were formed on a can body similar to that of Example 1 as shown in FIG. 22. The retort sterilization resistance was evaluated. The results are shown in "Table 2".
【0074】[0074]
【表1】 [Table 1]
【0075】[0075]
【表2】 [Table 2]
【0076】実施例1〜7および比較例1〜8から、最
小構成単位面の円周方向への連なりの数nと軸方向の周
状多面体壁を持たない缶胴部幅の缶高さに対する割合α
が、缶胴部の半径r,板材の弾性率Eおよび降伏応力σ
y,板厚tから実験式「数1」の条件を満足するような
領域に設定されれば、レトルト殺菌においてほとんど変
形せず、良好な結果が得られた。From Examples 1 to 7 and Comparative Examples 1 to 8, the number n of the minimum constitutional unit surfaces connected in the circumferential direction and the can height of the can body width which does not have the circumferential polyhedron wall in the axial direction are compared. Proportion α
Is the radius r of the can body, the elastic modulus E of the plate material and the yield stress σ
If the region was set to satisfy the condition of the empirical formula "Equation 1" from y and plate thickness t, good results were obtained with almost no deformation in the retort sterilization.
【0077】実施例8〜10および比較例9〜12か
ら、缶径rの違いにおいても、「数1」の条件を満足す
るような(n,α)の領域に設定されれば、有効なレト
ルト殺菌耐性が得られる。From Examples 8 to 10 and Comparative Examples 9 to 12, even if the can diameter r is different, it is effective if the region is set to (n, α) so as to satisfy the condition of "Equation 1". Retort sterilization resistance is obtained.
【0078】実施例11、12および比較例13〜15
から、板材がアルミ材等の弾性率Eおよび降伏応力σy
においても、「数1」の条件を満足するような(n,
α)の領域に設定されれば、有効なレトルト殺菌耐性が
得られる。Examples 11 and 12 and Comparative Examples 13 to 15
Therefore, the elastic modulus E and the yield stress σy of the aluminum plate etc.
Also satisfies the condition of "Equation 1" (n,
If it is set in the area of α), effective retort sterilization resistance can be obtained.
【0079】比較例16は実施例1〜5における缶胴の
構成と同様であるが、周状多面体壁の成形をしておら
ず、レトルト殺菌耐性を満足しない。Comparative Example 16 has the same constitution as the can body in Examples 1 to 5, but the peripheral polyhedron wall is not formed, and the retort sterilization resistance is not satisfied.
【0080】比較例17は耐外圧性を向上させるため
に、少数ビードを形成したが、比較例16と同じ缶胴の
構成では、レトルト殺菌耐性に有効な結果が得られなか
った。In Comparative Example 17, a small number of beads were formed in order to improve the external pressure resistance, but with the same can barrel structure as in Comparative Example 16, no effective result for retort sterilization resistance was obtained.
【0081】実施例13は比較例17の少数ビードに加
え、周状多面体壁を形成したもので、レトルト殺菌耐性
を満足する結果が得られた。In Example 13, a peripheral polyhedral wall was formed in addition to the small number of beads of Comparative Example 17, and the result satisfying the retort sterilization resistance was obtained.
【0082】[0082]
【発明の効果】本発明によれば、缶胴の少なくとも一部
に、構成単位面と、構成単位面同士が接する境界稜線
と、境界稜線同士が交わる交叉部とからなる周状多面体
壁を形成し、この境界稜線及び交叉部を構成単位面に比
べて相対的に缶外側に突出させ、しかも構成単位面の周
方向に隣合った缶軸方向配列を位相差をなして配列し、
周方向の構成単位面の数をn(個)、缶胴内半径をr(m
m)、缶胴肉厚をt(mm)、缶胴材料の弾性率をE(kg/mm^
2)、缶胴材料の降伏応力をσy (kg/mm^2)及び缶高当た
りの多面体壁以外の部分の高さの比をαとしたとき、上
記n、t及びαを「数1」及び「数2」を満足するよう
に設定したことにより、缶胴の肉厚を著しく減少させな
がら、耐レトルト性を著しく向上させることが可能とな
る。更に、加工後に塗膜に残留応力が残留したり、塗膜
欠陥が入るのを防止して、缶の耐食性を向上させること
が可能となり、また缶の製造コストを低減させ、軽量化
することも可能となる。According to the present invention, at least a part of the can body is formed with a circumferential polyhedron wall composed of constituent unit surfaces, boundary ridges where the constituent unit surfaces are in contact with each other, and intersections where the boundary ridges intersect. Then, the boundary ridge line and the intersecting portion are projected relatively to the outside of the can as compared with the constituent unit surface, and the can axial direction arrays adjacent to each other in the circumferential direction of the constituent unit surface are arranged with a phase difference,
The number of structural unit surfaces in the circumferential direction is n (pieces), and the inner radius of the can body is r (m
m), the thickness of the can body is t (mm), the elastic modulus of the can body material is E (kg / mm ^)
2), assuming that the yield stress of the can body material is σy (kg / mm ^ 2) and the height ratio of the portion other than the polyhedron wall per can height is α, the above n, t, and α are expressed by “Equation 1”. Also, by setting so as to satisfy "Equation 2", it becomes possible to remarkably improve the retort resistance while significantly reducing the wall thickness of the can body. Furthermore, it is possible to prevent residual stress from remaining in the coating film after processing, and to prevent coating film defects from occurring, thereby improving the corrosion resistance of the can, and also reducing the manufacturing cost of the can and reducing the weight. It will be possible.
【0083】また、周方向の一部の谷部は滑らかな湾曲
であり、外観上デザインを付す場合の再現性がよく見栄
えが向上し、容器内での内容物の残留が従来の円筒缶と
同様にほとんどない。更に、上記構造において、缶胴の
外圧による変形強度に予想外の向上が認められ、外圧に
よる変形強度を、従来のビート補強構造とは比較になら
ないオーダーで向上させることが可能である。Also, some of the valleys in the circumferential direction have a smooth curve, which has good reproducibility when the design is applied to the appearance, improves the appearance, and leaves the contents in the container in a conventional cylindrical can. Few as well. Furthermore, in the above structure, an unexpected improvement in the deformation strength of the can body due to the external pressure is recognized, and it is possible to improve the deformation strength due to the external pressure in an order incomparable with the conventional beat reinforcing structure.
【図1】本発明に係る缶詰用缶の四辺形を構成単位面と
する一例の側面図(a)、縦断面図(b)FIG. 1 is a side view (a) and a vertical sectional view (b) of an example in which a quadrilateral of a can for can according to the present invention is used as a structural unit surface.
【図2】「図1」の水平断面図FIG. 2 is a horizontal sectional view of FIG.
【図3】「図1」の缶詰用缶の側面に形成される構成単
位面の一例の平面図(a)および断面図(b)FIG. 3 is a plan view (a) and a cross-sectional view (b) of an example of constituent unit surfaces formed on the side surface of the can for can of FIG.
【図4】「図3」の構成単位面を中央部にのみ施した缶
詰用缶の側面図FIG. 4 is a side view of a can for can in which the constituent unit surface shown in FIG. 3 is applied only to the central portion.
【図5】缶詰用缶の側面に形成される別の態様の構成単
位面、即ち二等辺三角形単位面の平面図及び断面図FIG. 5 is a plan view and a cross-sectional view of a structural unit surface of another mode formed on the side surface of a can for can, that is, an isosceles triangular unit surface.
【図6】「図5」の構成単位面を用いた缶詰用缶の側面
図(a)及び縦断面図(b)FIG. 6 is a side view (a) and a vertical sectional view (b) of a can for can using the constituent unit surface of “FIG. 5”;
【図7】構成単位面の更に別の態様を用いた缶詰用缶の
側面図FIG. 7 is a side view of a can for can using another aspect of the structural unit surface.
【図8】六角形を構成単位面とする本発明に係る缶詰用
缶の部分側面図FIG. 8 is a partial side view of a can for can according to the present invention having a hexagonal structural unit surface.
【図9】丸み(R)を付けた六角形構成単位面を用いた
缶詰用缶の2例を示す部分側面図FIG. 9 is a partial side view showing two examples of a can for can using a hexagonal structural unit surface with roundness (R).
【図10】丸み(R)を付けた六角形構成単位面を用い
た缶詰用缶の2例を示す部分側面図FIG. 10 is a partial side view showing two examples of a can for can using a hexagonal structural unit surface with roundness (R).
【図11】丸み(R)を付けた四辺形構成単位面を用い
た缶詰用缶の部分側面図FIG. 11 is a partial side view of a can for can using a quadrilateral structural unit surface with roundness (R).
【図12】缶胴への多面体刻設の方法を説明する断面図FIG. 12 is a cross-sectional view illustrating a method of engraving a polyhedron on a can body.
【図13】缶胴への多面体刻設の方法を説明する斜視図FIG. 13 is a perspective view illustrating a method of engraving a polyhedron on a can body.
【図14】外型の構成単位面への当接部を示す断面図FIG. 14 is a cross-sectional view showing a contact portion of the outer die with respect to the component unit surface.
【図15】外型の構成単位面への当接部を示す断面図FIG. 15 is a cross-sectional view showing a contact portion of the outer die with respect to the constituent unit surface.
【図16】缶胴への多面体刻設の別な方法を説明する断
面図FIG. 16 is a cross-sectional view illustrating another method for engraving a polyhedron on a can body.
【図17】缶胴の肉厚tを変化させて、缶高当たりの多
面体壁の高さの比αと周方向の構成単位面の数nとに関
する境界値をプロットした線図FIG. 17 is a diagram in which boundary values are plotted by changing the wall thickness t of the can body and plotting the ratio α of the height of the polyhedral wall per can height and the number n of constituent unit surfaces in the circumferential direction.
【図18】実施例1乃至5及び比較例1乃至3につい
て、n及びαをプロットした線図FIG. 18 is a diagram in which n and α are plotted for Examples 1 to 5 and Comparative Examples 1 to 3.
【図19】実施例6乃至7及び比較例4乃至8につい
て、n及びαをプロットした線図FIG. 19 is a diagram in which n and α are plotted for Examples 6 to 7 and Comparative Examples 4 to 8.
【図20】実施例8乃至10及び比較例9乃至12につ
いて、n及びαをプロットした線図FIG. 20 is a diagram in which n and α are plotted for Examples 8 to 10 and Comparative Examples 9 to 12.
【図21】実施例11乃至12及び比較例13乃至14
について夫々n及びαをプロットした線図FIG. 21 shows Examples 11 to 12 and Comparative Examples 13 to 14.
Plotting n and α for
【図22】周状ビード付き缶胴の側面図FIG. 22 is a side view of a can body with a circumferential bead.
【図23】周状ビード間に多面体壁を形成した缶胴の側
面図FIG. 23 is a side view of a can body having a polyhedral wall formed between circumferential beads.
1 構成単位面 2 境界稜線 3 交叉部 4 窪んだ凹部 10 缶胴 11 内型 12 外型。 DESCRIPTION OF SYMBOLS 1 Structural unit surface 2 Boundary ridgeline 3 Crossing part 4 Recessed concave part 10 Can body 11 Inner mold 12 External mold.
フロントページの続き (72)発明者 武石 澄夫 神奈川県横浜市神奈川区大口仲町179 (72)発明者 小林 誠七 神奈川県横浜市栄区犬山町52−8 (72)発明者 大島 則継 神奈川県横浜市緑区鴨居5丁目26−5− 305 (72)発明者 沢田 和裕 東京都府中市南町2−12−1Front page continuation (72) Inventor Sumio Takeishi 179 Oguchinaka-cho, Kanagawa-ku, Yokohama, Kanagawa Prefecture (72) Inventor Seishi Kobayashi 52-8 Inuyama-cho, Sakae-ku, Yokohama-shi, Kanagawa Prefecture (72) Noritsugu Oshima Yokohama-shi, Kanagawa Green Kamoi, 5-26-5-305 (72) Inventor Kazuhiro Sawada 2-12-1, Minamimachi, Fuchu-shi, Tokyo
Claims (4)
成され、該多面体壁は構成単位面と、構成単位面同士が
接する境界稜線及び境界稜線同士が交わる交叉部を有
し、該境界稜線及び交叉部は構成単位面に比べて相対的
に缶外側に凸となっており、構成単位面の隣合った缶軸
方向配列が位相差をなして配列されている缶詰用缶であ
って、周方向の構成単位面の数をn(個)、缶胴最大内
半径をr(mm)、缶胴肉厚をt(mm)、缶胴材料の弾性率を
E(kg/mm^2)、缶胴材料の降伏応力をσy (kg/mm^2)及
び缶高当たりの多面体壁以外の部分の高さの比をαとし
たとき、前記n、t及びαを、下記式 【数1】 及び 【数2】t/r≦0.0125 を満足する範囲内に設定したことを特徴とする外圧に対
して耐変形性に優れた缶詰用缶。1. A circumferential polyhedron wall is formed on at least a part of a can body, and the polyhedron wall has structural unit surfaces, a boundary ridge line where the structural unit surfaces are in contact with each other, and an intersection portion where the boundary ridge lines intersect each other. Border ridges and intersections are relatively convex to the outside of the can as compared to the structural unit surface, and adjacent can axial direction arrays on the structural unit surface are canned cans that are arranged with a phase difference. , The number of structural unit surfaces in the circumferential direction is n (pieces), the maximum inner radius of the can body is r (mm), the thickness of the can body is t (mm), and the elastic modulus of the material of the can body is E (kg / mm ^). 2), where the yield stress of the can body material is σy (kg / mm ^ 2) and the ratio of the height per can height to the portion other than the polyhedron wall is α, the above n, t and α are expressed by the following formulas: Number 1] And a can for canning excellent in deformation resistance against external pressure, which is set within a range satisfying t / r ≦ 0.0125.
とし、構成単位面の缶周方向の最大巾をwとしたとき、
L及びwが式 【数3】0.2≦L/w≦4 の関係を満たすことを特徴とする請求項第1項記載の缶
詰用缶。2. The maximum length of the constituent unit surface in the can axis direction is L
And w is the maximum width of the structural unit surface in the circumferential direction of the can,
2. The can for canning according to claim 1, wherein L and w satisfy the relationship of 0.2 ≦ L / w ≦ 4.
間対角線と構成単位面の軸方向最大長さを与える交叉点
間対角線との距離(両対角線をそれぞれ直角に結ぶ線の
長さ)をd0 及び前記距離d0 の測定線が構成単位面と
交わる位置と構成単位面の軸方向最大長さを与える交叉
点間対角線との距離をd1としたとき、d1はd0の関係
で次式 【数4】0.5≦d1/d0≦2 を満足する範囲内にあることを特徴とする請求項第1項
乃至第2項記載の缶詰用缶。3. The distance between the diagonal line between the crossing points that gives the maximum width in the circumferential direction of the structural unit surface and the diagonal line between the crossing points that gives the maximum axial length of the structural unit surface (the length of the line connecting the diagonal lines at right angles to each other). ) Is d0, and d1 is the distance between the position where the measurement line of the distance d0 intersects the constituent unit surface and the diagonal line between the crossing points that gives the maximum axial length of the constituent unit surface. 4. The can for canning according to claim 1 or 2, wherein the value is within a range satisfying 0.5 ≦ d1 / d0 ≦ 2.
なだらかな一定のR(曲率半径)を有する一箇所曲げ或
いは複数箇所曲げ部であって該Rが板厚t及び缶胴半径
rに対して式 【数5】t≦R≦(2/3)r を満足する範囲範囲内にあることを特徴とする請求項第
1項乃至第3項記載の缶詰用缶。4. The boundary ridge line portion where the constituent unit surfaces are in contact with each other is a single-point bend or a multiple-point bend portion having a gentle and constant R (radius of curvature), and the R is the plate thickness t and the can body radius r. On the other hand, the can for canning according to any one of claims 1 to 3, characterized in that it is within a range satisfying the formula: t ≤ R ≤ (2/3) r.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP40334890A JPH075127B2 (en) | 1990-12-18 | 1990-12-18 | Cans for canning |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP40334890A JPH075127B2 (en) | 1990-12-18 | 1990-12-18 | Cans for canning |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPH04327128A JPH04327128A (en) | 1992-11-16 |
| JPH075127B2 true JPH075127B2 (en) | 1995-01-25 |
Family
ID=18513088
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP40334890A Expired - Lifetime JPH075127B2 (en) | 1990-12-18 | 1990-12-18 | Cans for canning |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH075127B2 (en) |
Families Citing this family (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP4754713B2 (en) * | 2000-04-28 | 2011-08-24 | 大和製罐株式会社 | Defect detection device for inner surface coating of metal container body |
| JP2002274522A (en) * | 2001-03-16 | 2002-09-25 | Maruzen Group:Kk | Safety cup and manufacturing method of the safety cup |
| JP5845589B2 (en) * | 2011-02-14 | 2016-01-20 | Jfeスチール株式会社 | Cylindrical container design method and cylindrical container |
| JP6004893B2 (en) * | 2012-10-29 | 2016-10-12 | キヤノン株式会社 | Tube coating method on substrate |
| JP6458425B2 (en) * | 2014-08-29 | 2019-01-30 | 東洋製罐株式会社 | Peripheral polyhedral wall can |
| JP2016064872A (en) * | 2014-08-29 | 2016-04-28 | 東洋製罐株式会社 | Metal can having polyhedral wall, and forming method and forming mold of the same |
| JP6439354B2 (en) * | 2014-08-29 | 2018-12-19 | 東洋製罐株式会社 | Metal can having polyhedral wall and method of forming the same |
| JP6450929B2 (en) * | 2014-10-29 | 2019-01-16 | パナソニックIpマネジメント株式会社 | Electric vacuum cleaner |
| JP7170403B2 (en) * | 2018-02-19 | 2022-11-14 | ライオン株式会社 | cap |
| JP7505255B2 (en) * | 2019-05-22 | 2024-06-25 | 東洋製罐株式会社 | Metal can, positive pressure can, and method for manufacturing metal can |
| JP7346909B2 (en) * | 2019-05-22 | 2023-09-20 | 東洋製罐株式会社 | positive pressure can |
-
1990
- 1990-12-18 JP JP40334890A patent/JPH075127B2/en not_active Expired - Lifetime
Also Published As
| Publication number | Publication date |
|---|---|
| JPH04327128A (en) | 1992-11-16 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| EP0441618B1 (en) | Packing can | |
| JPH03180228A (en) | Canning can and its manufacture | |
| US5360649A (en) | Thickness-reduced draw-formed can | |
| AU638561B2 (en) | Thickness-reduced draw-formed can | |
| JPH075127B2 (en) | Cans for canning | |
| JPH0757390B2 (en) | Redrawing method | |
| US5111679A (en) | Method for forming barrel for two-piece can | |
| JP2513379B2 (en) | Drawing method for organic coated metal materials | |
| US5228588A (en) | Thickness-reduced deep-draw-formed can | |
| US4646930A (en) | Bottom profile for a seamless container body | |
| JP3915450B2 (en) | Positive pressure can with polyhedral wall formed in the body and method for manufacturing the same | |
| JPH075128B2 (en) | Thin metal container with excellent deformation resistance and decorative effect | |
| JPH0487939A (en) | Can body for canning | |
| JP2508780B2 (en) | Can body for two-piece can and its forming method | |
| KR100199890B1 (en) | Deep drawing canned thin can | |
| JPH0796139B2 (en) | Circular polyhedral wall can manufacturing method and apparatus | |
| JP2000109068A (en) | Lid for positive internal pressure can | |
| JP3850045B2 (en) | Beer stuffing can with excellent foaming properties | |
| JPH0457733A (en) | Lid-sealed type plastic container and its manufacture | |
| JP2000072143A (en) | 3-piece can with ultra-thin welded can body | |
| JPH04118121A (en) | Method for manufacturing coated seamless cans | |
| JP2004256178A (en) | Beverage (excluding beer) can with polyhedral wall formed as body and method of manufacturing the same | |
| JP2513367B2 (en) | Metal sheet drawing method | |
| CA1316764C (en) | Clamping ring for can body drawing apparatus | |
| JPH0232052B2 (en) |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| FPAY | Renewal fee payment (prs date is renewal date of database) |
Free format text: PAYMENT UNTIL: 20090125 Year of fee payment: 14 |
|
| FPAY | Renewal fee payment (prs date is renewal date of database) |
Free format text: PAYMENT UNTIL: 20090125 Year of fee payment: 14 |
|
| FPAY | Renewal fee payment (prs date is renewal date of database) |
Free format text: PAYMENT UNTIL: 20100125 Year of fee payment: 15 |
|
| FPAY | Renewal fee payment (prs date is renewal date of database) |
Free format text: PAYMENT UNTIL: 20100125 Year of fee payment: 15 |
|
| FPAY | Renewal fee payment (prs date is renewal date of database) |
Free format text: PAYMENT UNTIL: 20110125 Year of fee payment: 16 |
|
| EXPY | Cancellation because of completion of term |