JPH075395B2 - Method for manufacturing glazed foam ceramic product - Google Patents
Method for manufacturing glazed foam ceramic productInfo
- Publication number
- JPH075395B2 JPH075395B2 JP63145411A JP14541188A JPH075395B2 JP H075395 B2 JPH075395 B2 JP H075395B2 JP 63145411 A JP63145411 A JP 63145411A JP 14541188 A JP14541188 A JP 14541188A JP H075395 B2 JPH075395 B2 JP H075395B2
- Authority
- JP
- Japan
- Prior art keywords
- foamed
- glaze
- product
- foam ceramic
- molded body
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 239000006260 foam Substances 0.000 title claims description 19
- 239000000919 ceramic Substances 0.000 title claims description 7
- 238000004519 manufacturing process Methods 0.000 title claims description 5
- 238000000034 method Methods 0.000 title description 3
- 229910010293 ceramic material Inorganic materials 0.000 claims description 16
- 238000010304 firing Methods 0.000 claims description 9
- 238000005187 foaming Methods 0.000 claims description 7
- 238000003825 pressing Methods 0.000 claims description 3
- 239000000047 product Substances 0.000 description 16
- 239000000463 material Substances 0.000 description 6
- 239000006261 foam material Substances 0.000 description 5
- 238000000465 moulding Methods 0.000 description 5
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 3
- 239000004088 foaming agent Substances 0.000 description 2
- 229910052500 inorganic mineral Inorganic materials 0.000 description 2
- 239000011707 mineral Substances 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 229910052581 Si3N4 Inorganic materials 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- -1 chordite Inorganic materials 0.000 description 1
- 229910003460 diamond Inorganic materials 0.000 description 1
- 239000010432 diamond Substances 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 239000012467 final product Substances 0.000 description 1
- 239000010419 fine particle Substances 0.000 description 1
- 238000010097 foam moulding Methods 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 150000004767 nitrides Chemical class 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 229910001562 pearlite Inorganic materials 0.000 description 1
- 229910052611 pyroxene Inorganic materials 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 239000011435 rock Substances 0.000 description 1
- 239000004576 sand Substances 0.000 description 1
- HBMJWWWQQXIZIP-UHFFFAOYSA-N silicon carbide Chemical compound [Si+]#[C-] HBMJWWWQQXIZIP-UHFFFAOYSA-N 0.000 description 1
- 229910010271 silicon carbide Inorganic materials 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- HQVNEWCFYHHQES-UHFFFAOYSA-N silicon nitride Chemical compound N12[Si]34N5[Si]62N3[Si]51N64 HQVNEWCFYHHQES-UHFFFAOYSA-N 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/45—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
- C04B41/50—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with inorganic materials
- C04B41/5022—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with inorganic materials with vitreous materials
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Ceramic Engineering (AREA)
- Inorganic Chemistry (AREA)
- Materials Engineering (AREA)
- Structural Engineering (AREA)
- Organic Chemistry (AREA)
- Porous Artificial Stone Or Porous Ceramic Products (AREA)
Description
【発明の詳細な説明】 〔産業上の利用分野〕 本発明は、発泡セラミック材料で軽量且つ断熱性に優れ
た施釉製品を得るための製造方法に関するものである。Description: TECHNICAL FIELD The present invention relates to a manufacturing method for obtaining a glazed product which is made of a foamed ceramic material and is lightweight and has excellent heat insulating properties.
通常、発泡材料で軽量且つ断熱性に優れた製品を得る場
合は、発泡材料を成形型内で発泡させ、然る後に脱型し
て所望する形状の製品を得るようにしている。Usually, in order to obtain a product that is lightweight and has excellent heat insulating properties using a foam material, the foam material is foamed in a molding die and then demolded to obtain a product having a desired shape.
また発泡材料を押出成形機により、押し出しながら発泡
させて発泡成形体を得、然る後に発泡成形体を所定形状
に切除して所望する形状の発泡製品を得るようにしてい
る。Further, the foamed material is extruded by an extruder and foamed to obtain a foamed molded body, and then the foamed molded body is cut into a predetermined shape to obtain a foamed product having a desired shape.
しかも、このような発泡製品に釉薬面を形成する場合
は、発泡製品を成形した後、釉薬を塗布し、全体を焼成
して最終的な製品にすることが必要であった。In addition, when forming a glaze surface on such a foamed product, it was necessary to mold the foamed product, apply the glaze, and then bake the entire product to obtain the final product.
ところが、発泡材料を成形型内で発泡させる場合は、製
品の大きさや形状ごとに成形型を準備しなければなら
ず、段取り替えに手間を要し、また設備費用も高騰する
という欠点があった。しかも、このような発泡材料に釉
薬面を形成する場合は、いずれにしても一旦発泡成形体
を成形した後、施釉を行い、全体を焼成して釉薬をガラ
ス化させ、発泡材料と釉薬とを一体化させることが必要
である。要するに、少なくとも発泡成形体の成形工程
と、該発泡成形体への施釉焼成工程とを必要とし、それ
ぞれは別々に行わねばならなかった。そのため、複雑且
つ面倒で長時間を要する工程が多くなり、生産性が悪く
なるという欠点があった。However, when foaming a foamed material in a molding die, it is necessary to prepare a molding die for each size and shape of the product, which requires time and labor for setup change and has a drawback that the equipment cost also rises. . Moreover, in the case of forming a glaze surface on such a foamed material, in any case, after molding the foamed molded body once, glazing is performed, the whole is baked to vitrify the glaze, and the foamed material and the glaze are mixed. It is necessary to integrate them. In short, at least the step of molding the foamed molded article and the step of glazing and firing the foamed molded article are required, and these must be performed separately. Therefore, there are drawbacks in that the number of steps is complicated, troublesome, and takes a long time, resulting in poor productivity.
また発泡材料としてガラス質のものを用いる場合は、成
形型表面へ塗布した離型剤が発泡材料の表面へくっつ
き、発泡成形体の表面へ釉薬原料を塗布することは不可
能であった。すなわち、ガラス質の発泡材料では、釉薬
面を備えた製品を得ることはできないでいた。When a glass material is used as the foam material, the release agent applied to the surface of the mold sticks to the surface of the foam material, making it impossible to apply the glaze raw material to the surface of the foam molded article. That is, it was not possible to obtain a product having a glaze surface with a glassy foam material.
本発明は、従来の前記課題に鑑みてこれを改良除去した
ものであって、発泡成形と施釉焼成とを同時に行うこと
のできる施釉発泡セラミック製品の製造方法を提供せん
とするものである。SUMMARY OF THE INVENTION The present invention has been made by improving and removing the above problem in view of the conventional problems described above, and it is an object of the present invention to provide a method for producing a glazed foamed ceramic product capable of simultaneously performing foam molding and glaze firing.
而して、前記課題を解決するために本発明が採用した手
段は、無機質発泡セラミック材料の加圧工程の際に、成
形体の裏面側を前記加圧工程の後に行われる焼成工程に
おける発泡時の膨張量を補償するべく所定の凹部に成形
し、前記成形体の表面に、釉薬を塗布した後、全体を焼
成して発泡させる。Thus, the means adopted by the present invention to solve the above-mentioned problems is that when the inorganic foam ceramic material is pressed, the back side of the molded body is foamed in the firing step performed after the pressing step. In order to compensate for the amount of expansion of the above, a predetermined concave portion is formed, and after the glaze is applied to the surface of the formed body, the whole is baked to foam.
無機質発泡セラミック材料の加圧成形体の裏面側に加圧
工程の後に行われる焼成工程における発泡時の膨張量を
補償するべく所定の凹部を形成し、前記加圧成形体の表
面に、釉薬を塗布し、これを焼成すると、無機質発泡セ
ラミック材料が発泡すると同時に、前記釉薬がガラス化
して無機質発泡セラミック材料と結合する。A predetermined concave portion is formed on the back surface side of the pressure-formed body of the inorganic foamed ceramic material to compensate for the expansion amount at the time of foaming in the firing step performed after the pressure step, and a glaze is applied to the surface of the pressure-formed body. When applied and fired, the inorganic foam ceramic material foams, and at the same time, the glaze vitrifies and bonds with the inorganic foam ceramic material.
以下に、本発明の方法を図面に示す実施例に基づいて説
明すると次の通りである。The method of the present invention will be described below with reference to the embodiments shown in the drawings.
第1図乃至第4図は、本発明の一実施例に係る製造工程
を示すものである。先ず、火山性ガラス質鉱物からなる
微細状主材と、微粉末状発泡剤とを混合してなる無機質
発泡セラミック材料を準備する。火山性ガラス質鉱物
は、坑火石,流絞岩,真珠岩,黒躍石,シラス,伊勢珪
砂等の一種又は数種をクラッシャー及びミル等を用いて
微細状に粉砕して混合したものである。また微粉末状発
泡剤は、カーボン,炭化ケイ素等の炭化物,窒化ケイ素
等の窒化物等の一種又は数種からなる平均粒径15μm以
下の微粒なものである。次に、このような無機質発泡セ
ラミック材料を乾式プレス機械等で加圧し、第1図に示
すような所望する形状の加圧成形体1を得る。この加圧
成形体1は、後で行われる焼成工程における発泡時に、
加圧成形体1の施釉面(上面)1aの中央部分が膨隆する
傾向にあるので、この膨隆量を見越して予め裏面1b側に
凹部2を形成するようにしている。1 to 4 show a manufacturing process according to an embodiment of the present invention. First, an inorganic foam ceramic material prepared by mixing a fine main material made of volcanic glassy mineral and a fine powdery foaming agent is prepared. The volcanic glassy mineral is one or several kinds of mine pyroxene, chordite, pearlite, black rock, shirasu, Ise silica sand, etc., which are finely ground and mixed by using a crusher and a mill. . The fine powdery foaming agent is a fine particle having an average particle diameter of 15 μm or less, which is made of one kind or several kinds of carbon, carbide such as silicon carbide, nitride such as silicon nitride and the like. Next, such an inorganic foamed ceramic material is pressed by a dry press machine or the like to obtain a pressure molded body 1 having a desired shape as shown in FIG. This pressure-molded body 1 has
Since the central portion of the glazed surface (upper surface) 1a of the pressure molded body 1 tends to bulge, the recess 2 is formed in advance on the back surface 1b side in anticipation of this bulging amount.
そして、第2図に示すように、加圧成形体1の面1a,1c
に釉薬を塗布し、トンネル炉(図示せず)を通過させて
1180℃の焼成温度で30時間の焼成を行う。この焼成によ
り、前記無機質発泡セラミック材料は、発泡して独立気
泡を形成する。また前記釉薬は、発泡と同時にガラス化
され、無機質発泡セラミック材料と一体化する。発泡が
安定し、常温へ冷却された状態では、面1a,1cは略々フ
ラットである。これは、焼成発泡時に、面1aの中央側が
膨隆しようとする力は、面1bに形成された凹部2をフラ
ットにする力に変わるためである。Then, as shown in FIG. 2, the surfaces 1a, 1c of the pressure molded body 1 are
Apply glaze to a tunnel furnace (not shown)
Baking is performed at a baking temperature of 1180 ° C. for 30 hours. By this firing, the inorganic foam ceramic material foams to form closed cells. Further, the glaze is vitrified at the same time as foaming and is integrated with the inorganic foam ceramic material. In the state where foaming is stable and cooled to room temperature, the surfaces 1a and 1c are substantially flat. This is because the force that the center side of the surface 1a swells during firing and foaming changes to the force that flattens the concave portion 2 formed in the surface 1b.
然る後は、このようにして得られた焼成体3の非施釉面
を、第3図に示すように、ダイヤモンドホイール等で切
除し、第4図に示すような所望する形状の施釉された発
泡セラミック製品4を得る。After that, the non-glazed surface of the fired body 3 thus obtained was cut with a diamond wheel or the like as shown in FIG. 3 and glazed in a desired shape as shown in FIG. A foam ceramic product 4 is obtained.
このような施釉発泡セラミック製品4は、無数の独立気
泡が空気を閉じ込め、熱の伝導を防いで優れた断熱性を
発揮する。また非常に軽量であり、かつ全体がガラス質
であるので、燃える危険性がなく、吸水性もないので凍
害による損傷の虞れもない。In such a glazed foamed ceramic product 4, innumerable closed cells confine air, prevent heat conduction, and exhibit excellent heat insulating properties. Further, since it is extremely lightweight and is entirely glassy, there is no risk of burning and no water absorption, so there is no risk of damage due to frost damage.
ところで、本発明は上述した実施例に限定されるもので
はなく、例えば、釉薬の種類及び製品形状並びに施釉面
等は適宜の変更が可能である。By the way, the present invention is not limited to the above-mentioned embodiment, and for example, the kind and the product shape of the glaze, the glazed surface and the like can be appropriately changed.
以上説明したように本発明の方法によれば、無機質発泡
セラミック材料からなる加圧成形体の表面に釉薬を塗布
して後に焼成させるので、無機質発泡セラミック材料が
発泡すると同時に釉薬がガラス化して無機質発泡セラミ
ック材料と一体化して施釉面を形成することができる。
また、加圧成形体の裏面側を所定の凹部に成形している
ので、焼成発泡時に中央部を膨隆しようとする力が前記
凹部をフラットにする力に変わるので、フラット形状の
製品を得ることができる。As described above, according to the method of the present invention, since the glaze is applied to the surface of the pressure-molded body made of the inorganic foam ceramic material and then baked, the inorganic foam ceramic material is foamed and the glaze is vitrified to be an inorganic substance. The glazed surface can be formed integrally with the foam ceramic material.
Further, since the back surface side of the pressure molded body is molded into a predetermined concave portion, the force to bulge the central portion during firing and foaming is changed to the force to flatten the concave portion, so that a flat product can be obtained. You can
図面はいずれも本発明の一実施例に係るものであり、第
1図は発泡セラミック材料の成形体を示す側面図、第2
図は発泡セラミック材料の施釉焼成体を示す側面図、第
3図は施釉焼成体の切除部分を示す側面図、第4図は施
釉発泡セラミック製品を示す側面図である。 1……無機質発泡セラミック材料の成形体 4……施釉発泡セラミック製品The drawings are all related to one embodiment of the present invention. FIG. 1 is a side view showing a molded body of a foam ceramic material, and FIG.
FIG. 4 is a side view showing a glazed fired body of a foamed ceramic material, FIG. 3 is a side view showing a cut portion of the glazed fired body, and FIG. 4 is a side view showing a glazed foamed ceramic product. 1 …… Molded body of inorganic foam ceramic material 4 …… Glazed foam ceramic product
Claims (1)
に、成形体の裏面側を前記加圧工程の後に行われる焼成
工程における発泡時の膨張量を補償するべく所定の凹部
に成形し、前記成形体の表面に、釉薬を塗布した後、全
体を焼成して発泡させることを特徴とする施釉発泡セラ
ミック製品の製造方法。1. In the step of pressing an inorganic foamed ceramic material, the back side of the molded body is molded into a predetermined concave portion so as to compensate the expansion amount at the time of foaming in the firing step performed after the pressing step, A method for producing a glazed foamed ceramic product, which comprises applying a glaze to the surface of the molded body and firing the entire body to foam.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP63145411A JPH075395B2 (en) | 1988-06-13 | 1988-06-13 | Method for manufacturing glazed foam ceramic product |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP63145411A JPH075395B2 (en) | 1988-06-13 | 1988-06-13 | Method for manufacturing glazed foam ceramic product |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPH01313374A JPH01313374A (en) | 1989-12-18 |
| JPH075395B2 true JPH075395B2 (en) | 1995-01-25 |
Family
ID=15384638
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP63145411A Expired - Fee Related JPH075395B2 (en) | 1988-06-13 | 1988-06-13 | Method for manufacturing glazed foam ceramic product |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH075395B2 (en) |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP4644435B2 (en) * | 2004-03-25 | 2011-03-02 | 滋賀県 | Insulated container and manufacturing method thereof |
Family Cites Families (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS60176932A (en) * | 1984-02-17 | 1985-09-11 | Inax Corp | Glazed inorganic expansion molded article and production thereof |
| JPS6191078A (en) * | 1984-10-08 | 1986-05-09 | 新島物産株式会社 | Manufacture of inorganic lightweight foamed body |
-
1988
- 1988-06-13 JP JP63145411A patent/JPH075395B2/en not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| JPH01313374A (en) | 1989-12-18 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| LAPS | Cancellation because of no payment of annual fees |