JPH0759485B2 - White control method - Google Patents
White control methodInfo
- Publication number
- JPH0759485B2 JPH0759485B2 JP61137237A JP13723786A JPH0759485B2 JP H0759485 B2 JPH0759485 B2 JP H0759485B2 JP 61137237 A JP61137237 A JP 61137237A JP 13723786 A JP13723786 A JP 13723786A JP H0759485 B2 JPH0759485 B2 JP H0759485B2
- Authority
- JP
- Japan
- Prior art keywords
- control agent
- propetamphos
- agent according
- application
- margin control
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 238000000034 method Methods 0.000 title description 8
- BZNDWPRGXNILMS-VQHVLOKHSA-N propetamphos Chemical compound CCNP(=S)(OC)O\C(C)=C\C(=O)OC(C)C BZNDWPRGXNILMS-VQHVLOKHSA-N 0.000 claims description 24
- 239000002023 wood Substances 0.000 claims description 18
- 239000002689 soil Substances 0.000 claims description 11
- 239000004480 active ingredient Substances 0.000 claims description 7
- 239000000839 emulsion Substances 0.000 claims description 3
- 238000005507 spraying Methods 0.000 claims description 3
- 239000012141 concentrate Substances 0.000 claims description 2
- 238000005470 impregnation Methods 0.000 claims description 2
- 239000003795 chemical substances by application Substances 0.000 claims 10
- 230000002087 whitening effect Effects 0.000 claims 2
- 206010061217 Infestation Diseases 0.000 claims 1
- 241000607479 Yersinia pestis Species 0.000 claims 1
- 239000000203 mixture Substances 0.000 description 8
- 239000003085 diluting agent Substances 0.000 description 4
- 238000009472 formulation Methods 0.000 description 4
- 239000007788 liquid Substances 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- 241000866500 Reticulitermes speratus Species 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- 241001509964 Coptotermes Species 0.000 description 1
- 241001509962 Coptotermes formosanus Species 0.000 description 1
- 241000866592 Cryptotermes domesticus Species 0.000 description 1
- 241000173801 Incisitermes minor Species 0.000 description 1
- 241000866536 Odontotermes formosanus Species 0.000 description 1
- 230000004071 biological effect Effects 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000010790 dilution Methods 0.000 description 1
- 239000012895 dilution Substances 0.000 description 1
- 238000005553 drilling Methods 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 230000000749 insecticidal effect Effects 0.000 description 1
- 239000003350 kerosene Substances 0.000 description 1
- 239000003094 microcapsule Substances 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 230000002265 prevention Effects 0.000 description 1
- 230000001681 protective effect Effects 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- 230000001988 toxicity Effects 0.000 description 1
- 231100000419 toxicity Toxicity 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B27—WORKING OR PRESERVING WOOD OR SIMILAR MATERIAL; NAILING OR STAPLING MACHINES IN GENERAL
- B27K—PROCESSES, APPARATUS OR SELECTION OF SUBSTANCES FOR IMPREGNATING, STAINING, DYEING, BLEACHING OF WOOD OR SIMILAR MATERIALS, OR TREATING OF WOOD OR SIMILAR MATERIALS WITH PERMEANT LIQUIDS, NOT OTHERWISE PROVIDED FOR; CHEMICAL OR PHYSICAL TREATMENT OF CORK, CANE, REED, STRAW OR SIMILAR MATERIALS
- B27K3/00—Impregnating wood, e.g. impregnation pretreatment, for example puncturing; Wood impregnation aids not directly involved in the impregnation process
- B27K3/16—Inorganic impregnating agents
- B27K3/166—Compounds of phosphorus
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N57/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds
- A01N57/26—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having phosphorus-to-nitrogen bonds
- A01N57/28—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having phosphorus-to-nitrogen bonds containing acyclic or cycloaliphatic radicals
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B27—WORKING OR PRESERVING WOOD OR SIMILAR MATERIAL; NAILING OR STAPLING MACHINES IN GENERAL
- B27K—PROCESSES, APPARATUS OR SELECTION OF SUBSTANCES FOR IMPREGNATING, STAINING, DYEING, BLEACHING OF WOOD OR SIMILAR MATERIALS, OR TREATING OF WOOD OR SIMILAR MATERIALS WITH PERMEANT LIQUIDS, NOT OTHERWISE PROVIDED FOR; CHEMICAL OR PHYSICAL TREATMENT OF CORK, CANE, REED, STRAW OR SIMILAR MATERIALS
- B27K3/00—Impregnating wood, e.g. impregnation pretreatment, for example puncturing; Wood impregnation aids not directly involved in the impregnation process
- B27K3/34—Organic impregnating agents
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B27—WORKING OR PRESERVING WOOD OR SIMILAR MATERIAL; NAILING OR STAPLING MACHINES IN GENERAL
- B27K—PROCESSES, APPARATUS OR SELECTION OF SUBSTANCES FOR IMPREGNATING, STAINING, DYEING, BLEACHING OF WOOD OR SIMILAR MATERIALS, OR TREATING OF WOOD OR SIMILAR MATERIALS WITH PERMEANT LIQUIDS, NOT OTHERWISE PROVIDED FOR; CHEMICAL OR PHYSICAL TREATMENT OF CORK, CANE, REED, STRAW OR SIMILAR MATERIALS
- B27K3/00—Impregnating wood, e.g. impregnation pretreatment, for example puncturing; Wood impregnation aids not directly involved in the impregnation process
- B27K3/52—Impregnating agents containing mixtures of inorganic and organic compounds
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Wood Science & Technology (AREA)
- Forests & Forestry (AREA)
- Chemical & Material Sciences (AREA)
- Inorganic Chemistry (AREA)
- Plant Pathology (AREA)
- Pest Control & Pesticides (AREA)
- Agronomy & Crop Science (AREA)
- Health & Medical Sciences (AREA)
- Dentistry (AREA)
- General Health & Medical Sciences (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
- Chemical And Physical Treatments For Wood And The Like (AREA)
Description
【発明の詳細な説明】 ［産業上の利用分野］ この発明は、しろありの防除方法に関するものである。DETAILED DESCRIPTION OF THE INVENTION [Industrial field of application] The present invention relates to a method for controlling margins.
［発明の背景］ しろありの防除およびしろありによる損傷の防止は、多
くの国々で問題になっている。種々の方法が使用または
提案され、色々の程度で効果を得ているが、、毒性およ
び生態学的見地から比較的問題の少ない製品による有効
かつ持続的なしろあり駆除が可能な改良法の開発が望ま
れている。BACKGROUND OF THE INVENTION The control of margins and the prevention of marginal damage is a problem in many countries. Although various methods have been used or proposed and have been effective to various extents, the development of effective and sustainable marginal control methods with relatively less problematic products from the viewpoint of toxicity and ecological Is desired.
［発明の記載］ この発明によると、一般名プロペタムホス（Propetamph
os）として知られる（Ｅ）−Ｏ−２−イソプロポキシカ
ルボニル−１−メチルビニル・Ｏ−メチル・エチルホス
ホルアミドチオエートが、しろありの防除に用いるもの
として特に好適であり、しろありの攻撃から木質材料を
効果的に保護し得ることが見出された。DESCRIPTION OF THE INVENTION According to the present invention, the generic name Propetamph
(E) -O-2-isopropoxycarbonyl-1-methylvinyl-O-methyl-ethylphosphoramidothioate, known as os), is particularly suitable for use in marginal control and from marginal attack. It has been found that wood materials can be effectively protected.
すなわち、この発明は、しろありの座にしろありの防除
量のプロペタムホスを適用することにより、しろありの
防除方法を提供するものである。That is, the present invention provides a control method with margin by applying a control amount of propetamphos with margin to the margin.
防除を最適にするには、プロペタムホスを農業上許容さ
れる希釈剤と配合して殺虫組成物の形態で用いるのが好
適である。このような組成物は固体でも液体でもよく、
例えば慣用される希釈剤を用いてマイクロカプセル形、
または油もしくは乳剤用濃厚液製剤として使用すること
ができる。上記組成物は、常法により、例えば有効成分
を希釈剤および所望により界面活性剤のような他の製剤
用成分と混合することにより製造される。For optimal control, propetamphos is preferably used in the form of an insecticidal composition in combination with an agriculturally acceptable diluent. Such compositions may be solid or liquid,
For example, in a microcapsule form using a conventional diluent,
Alternatively, it can be used as a concentrated liquid preparation for oil or emulsion. The compositions are prepared in a conventional manner, for example by mixing the active ingredient with a diluent and optionally other formulation ingredients such as surfactants.
便宜上、以下の記載ではプロペタムホスの語を非製剤形
および製剤形の有効成分を含むものとして用いる。For convenience, the term propetamphos is used in the following description to include the non-formulated and the formulated active ingredients.
希釈剤の語は、液体または固体の農業上許容される物質
であって、有効成分に加えて適当な適用形または市販形
を作り、または適当な生物学的効果を達成するために有
効成分を希釈し得るものを意味する。The term diluent is a liquid or solid agriculturally acceptable substance which, in addition to the active ingredient, makes up the appropriate applied or commercial form, or the active ingredient in order to achieve the appropriate biological effect. Means that can be diluted.
プロペタムホスは、しろありの攻撃から木材を保護する
のに特に好適である。驚くべき土壌安定性により、それ
は家屋の地上および地下木質ベースメント部の保護に特
に適する。Propetamphos is particularly suitable for protecting wood from marginal attack. The surprising soil stability makes it particularly suitable for protecting aboveground and underground woody basement parts of houses.
木材の保護は、プロペタムホスのしろあり防除有効量を
用いて直接または間接に行なうことができる。直接的木
材保護は、例えば含浸、噴霧またはせん孔適用により達
成することができる。間接的保護は、例えば保護すべき
木材の周囲のしろあり出没領域にプロペタムホスを適用
することにより達成される。保護すべき木材が木質ベー
スメントの場合、間接的保護はベースメント部の周囲の
土壌内へプロペタムホスを混入しまたは土壌上へ適用す
ることにより達成される。The protection of wood can be carried out directly or indirectly by means of a marginal control effective amount of propetamphos. Direct wood protection can be achieved, for example, by impregnation, spraying or drilling. Indirect protection is achieved, for example, by applying propetamphos to the marginal outbreak area around the wood to be protected. If the wood to be protected is a wood basement, indirect protection is achieved by incorporating propetamphos into the soil around the basement or by applying it on the soil.
一般に、直接的および間接的木材保護に用いる適用形態
は、プロペタムホスを0.1〜10、好ましくは0.3〜3.0、
例えば１重量％含む希釈形態であるのが好便である。In general, the application forms used for direct and indirect wood protection are propetamphos 0.1 to 10, preferably 0.3 to 3.0,
For example, a diluted form containing 1% by weight is convenient.
木材の直接的保護の場合、適用形態は油状製剤が適当で
あり、間接的保護の場合、適用形態は乳剤用濃厚液の希
釈物が適当である。適用量は適用法および条件等の種々
の要因により異なるが、当業者の日常的な実験により確
立することができる。For direct protection of wood, the application form is suitably an oil formulation, for indirect protection the application form is a dilution of the emulsion concentrate. The applied amount varies depending on various factors such as the application method and conditions, but can be established by routine experimentation by those skilled in the art.
木材表面にプロペタムホスを直接噴霧適用して保護を行
なおうとする場合、満足すべき保護作用は、一般に、木
材表面１平方メートル当りプロペタムホス（有効成分）
0.5〜5.0g、例えば１重量％油状適用形態100〜200mlの
適用により得られる。このようなスプレイ適用は必要時
にいつでも反復することができる。化合物をいわゆるせ
ん孔法で適用する場合、これは特別の目的でせん孔した
木材の小孔に（好ましくは高い）圧で適当な製剤を注入
することによるが、このときの適用量は木材１立方メー
トル当りプロペタムホス１重量％適用形態500〜600リッ
トル、すなわちプロペタムホス5.0〜6.0kgの範囲が好適
である。When spraying propetamphos directly onto the wood surface for protection, the satisfactory protective action is generally that propetamphos (active ingredient) per square meter of wood surface.
Obtained by application of 0.5 to 5.0 g, for example 100 to 200 ml of 1% by weight oily application form. Such spray application can be repeated whenever necessary. When the compound is applied by the so-called perforation method, this is by injecting a suitable formulation at (preferably high) pressure into the perforations of a specially perforated wood, the application amount being per cubic meter of wood. A suitable range is 500 to 600 liters of 1% by weight propetamphos application form, ie 5.0 to 6.0 kg of propetamphos.
間接的木材保護を行なう場合、プロペタムホスは例えば
ベースメント枠の両側土壌に混入することができる。For indirect wood protection, propetamphos can be incorporated into the soil on both sides of the basement frame, for example.
これは、例えば、ベースメント枠に沿い、例えば幅15〜
30cm、深さ20〜30cmの溝を掘り、除去した土壌に適量の
プロペタムホスを混合し、溝を上記処理した土で埋め、
所望により埋めた溝の表面にさらにプロペタムホスを適
用することにより実施できる。１重量％のプロペタムホ
ス適用形を用いる場合、満足すべき結果は、一般に、上
記溝の走行メートル当りの掘り上げた土壌量（0.03〜0.
1m3）につき上記適用形態を１〜５リットル混合するこ
とによって得られる。処理土壌で充填した溝の表面に適
用するに好適なプロペタムホスの追加量は、例えば除去
土壌表面1m2当りプロペタムホスの１％適用形態として
0.5〜１リットルである。This is, for example, along the basement frame, for example width 15 ~
Dig a groove of 30 cm, depth 20-30 cm, mix an appropriate amount of propetamphos in the removed soil, fill the groove with the treated soil,
This can be done by further applying propetamphos to the surface of the optionally filled trench. With 1% by weight propetamphos application, satisfactory results are generally obtained by excavating soil (0.03-0.
Obtained by mixing 1 to 5 liters of the above application form per 1 m 3 ). A suitable additional amount of propetamphos to be applied to the surface of a ditch filled with treated soil is, for example, 1% propetamphos application per 1 m 2 of removed soil surface
It is 0.5 to 1 liter.
溝掘りが容易でない場合、適用する１重量％適用形態の
量はベースメントフレームが囲む地面1m2当り４〜５リ
ットルを超え、および／またはベースメントフレームの
外側の土壌処理の場合ベースメント走行メートル当り１
リットルを超えるのが好適である。If the grooving is not easy, apply 1% by weight to application forms exceed the ground 1 m 2 per 4-5 l surrounding the basement frames, and / or basement running meter soil treatment outside the basement frame 1 hit
Greater than liters is preferred.
適用形態が有効成分１重量％以上または以下を含むにし
たがって、適用量を適当に調節するのがよい。As the application form contains 1% by weight or more of the active ingredient or less, the application amount may be adjusted appropriately.
この発明の方法は、レチクリテルメス・スペラツス（コ
ルベ）〔reticulitermes speratus（Kolbe）〕、コプト
テルメス・ホルモサヌス（シラキ）〔coptotermes form
osanus（Shiraki）〕、クリプトテルメス・ドメスチク
ス（ハビランド）〔cryptotermes domesticus（Havilan
d）〕、インチシテルメス・ミノル（ハゲン）〔incisit
ermes minor（Hagen）、オドントテルメス・ホルモサヌ
ス（シラキ）〔odontotermes formosanus（Shiraki）〕
のような木質材料損傷しろありに対して特に有効であ
る。The method of the present invention comprises reticulitermes speratus (Kolbe), Coptothermes formosanus (silaki) [coptotermes form]
osanus (Shiraki)], cryptotermes domesticus (Havilan)
d)], Inch Citermez Minor (Hagen) [incisit
ermes minor (Hagen), odontotermes formosanus (Shiraki)
It is especially effective for damage such as wood materials.
［実施例］ 以下、この発明を実施例により説明する。[Examples] Hereinafter, the present invention will be described with reference to Examples.
実施例１ ケロセン１リットルにプロペタムホス10gを入れた製剤
を、200ml/m2の割合で木質ベースメント部に噴霧した。Example 1 A formulation prepared by adding 10 g of propetamphos to 1 liter of kerosene was sprayed on a wood basement portion at a rate of 200 ml / m 2 .
このように処理したベースメント材料は、レチクリテル
メス・スペラツス（コルベ）〔reticulitermes speratu
s（Kolbe）〕およびコプトテルメス・ホルモサヌス（シ
ラキ）〔coptotermes formosanus（Shiraki）〕の攻撃
に対して長期間抵抗性を示した。The basement material treated in this way is reticulitermes speratu.
s (Kolbe)] and coptotermes formosanus (Shiraki).
Claims (10)
ことを特徴とする、しろありの生息部位または場所に適
用するための、しろあり防除剤。1. A margin control agent for application to a habitat site or place where there are margins, which contains propetamphos as an active ingredient.
しろあり出没領域に適用するための、特許請求の範囲第
１項記載のしろあり防除剤。2. A whitening pest control agent according to claim 1, which is for application to a whitening or infestation area around or around a tree to be protected.
囲第２項記載のしろあり防除剤。3. The margin control agent according to claim 2 for application to wood.
めの、特許請求の範囲第３項記載のしろあり防除剤。4. The margin control agent according to claim 3 for application by impregnation, spraying or piercing.
範囲第３項または第４項記載のしろあり防除剤。5. The margin control agent according to claim 3 or 4, wherein propetamphos is in an oil form.
許請求の範囲第５項記載のしろあり防除剤。6. The margin control agent according to claim 5, which contains 0.1 to 10% by weight of peropertamphos.
適用するための、特許請求の範囲第２項記載のしろあり
防除剤。7. The margin control agent according to claim 2, which is applied to a margin occurrence area around a tree to be protected.
メントの周囲の土壌に混入または適用するための、特許
請求の範囲第２項記載のしろあり防除剤。8. The margin control agent according to claim 2, wherein the tree is a wood basement, and is mixed or applied to the soil around the basement.
である、特許請求の範囲第８項記載のしろあり防除剤。9. The margin control agent according to claim 8, wherein the propetamphos is a diluted form of a concentrate for emulsion.
特許請求の範囲第９項記載のしろあり防除剤。10. Containing 0.1 to 10% by weight of propetamphos,
The margin control agent according to claim 9.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB858514853A GB8514853D0 (en) | 1985-06-12 | 1985-06-12 | Controlling termites |
| GB8514853 | 1985-06-12 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS625907A JPS625907A (en) | 1987-01-12 |
| JPH0759485B2 true JPH0759485B2 (en) | 1995-06-28 |
Family
ID=10580617
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP61137237A Expired - Lifetime JPH0759485B2 (en) | 1985-06-12 | 1986-06-11 | White control method |
Country Status (6)
| Country | Link |
|---|---|
| JP (1) | JPH0759485B2 (en) |
| CN (1) | CN86103914A (en) |
| AU (1) | AU5848886A (en) |
| BR (1) | BR8602733A (en) |
| GB (2) | GB8514853D0 (en) |
| ZA (1) | ZA864414B (en) |
Families Citing this family (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB8614647D0 (en) * | 1986-06-16 | 1986-07-23 | Sandoz Ltd | Oil in water emulsion |
| CN104255347B (en) * | 2014-09-03 | 2016-06-01 | 广西师范大学 | A kind of prevention and controls afforesting big tree Coptotermes formosanus Shtrari�� |
| CN111096333B (en) * | 2019-12-25 | 2021-04-30 | 广东省科学院动物研究所 | Application of Biochar in Preparation of Termite Repellent |
| CN112720748A (en) * | 2020-12-30 | 2021-04-30 | 廊坊华日家具股份有限公司 | Phosphorus-nitrogen-boron wood flame retardant |
Family Cites Families (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CH526586A (en) * | 1969-07-18 | 1972-08-15 | Sandoz Ag | Anti parasitic thio phosphoric acid imide esters |
| BE794293A (en) * | 1972-01-21 | 1973-07-19 | Bayer Ag | NEW DIESTERAMIDES OF DICHLOROVINYLTHIONOPHOSPHORIC ACID, THEIR PREPARATION PROCESS AND THEIR APPLICATION AS INSECTICIDES AND ACARICIDES |
| JPS5016778A (en) * | 1973-06-14 | 1975-02-21 | ||
| US4159324A (en) * | 1976-06-29 | 1979-06-26 | Bayer Aktiengesellschaft | Combating insects, acarids and nematodes with O-(1-fluoro-2-halo-ethyl)(thiono)phosphoric(phosphonic) acid ester-amides |
-
1985
- 1985-06-12 GB GB858514853A patent/GB8514853D0/en active Pending
-
1986
- 1986-06-09 GB GB08613948A patent/GB2176109A/en not_active Withdrawn
- 1986-06-10 CN CN198686103914A patent/CN86103914A/en active Pending
- 1986-06-10 AU AU58488/86A patent/AU5848886A/en not_active Abandoned
- 1986-06-11 JP JP61137237A patent/JPH0759485B2/en not_active Expired - Lifetime
- 1986-06-11 BR BR8602733A patent/BR8602733A/en unknown
- 1986-06-12 ZA ZA864414A patent/ZA864414B/en unknown
Also Published As
| Publication number | Publication date |
|---|---|
| JPS625907A (en) | 1987-01-12 |
| CN86103914A (en) | 1986-12-10 |
| GB8514853D0 (en) | 1985-07-17 |
| BR8602733A (en) | 1987-02-10 |
| AU5848886A (en) | 1986-12-18 |
| GB8613948D0 (en) | 1986-07-16 |
| ZA864414B (en) | 1988-01-27 |
| GB2176109A (en) | 1986-12-17 |
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