JPH0759495B2 - Bath agent composition - Google Patents
Bath agent compositionInfo
- Publication number
- JPH0759495B2 JPH0759495B2 JP19272986A JP19272986A JPH0759495B2 JP H0759495 B2 JPH0759495 B2 JP H0759495B2 JP 19272986 A JP19272986 A JP 19272986A JP 19272986 A JP19272986 A JP 19272986A JP H0759495 B2 JPH0759495 B2 JP H0759495B2
- Authority
- JP
- Japan
- Prior art keywords
- weight
- parts
- agent composition
- bathing
- sodium
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
Classifications
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q19/00—Preparations for care of the skin
- A61Q19/10—Washing or bathing preparations
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/20—Chemical, physico-chemical or functional or structural properties of the composition as a whole
- A61K2800/24—Thermal properties
- A61K2800/242—Exothermic; Self-heating; Heating sensation
Landscapes
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Animal Behavior & Ethology (AREA)
- General Health & Medical Sciences (AREA)
- Public Health (AREA)
- Veterinary Medicine (AREA)
- Dermatology (AREA)
- Chemical & Material Sciences (AREA)
- Inorganic Chemistry (AREA)
- Birds (AREA)
- Epidemiology (AREA)
- Cosmetics (AREA)
Description
【発明の詳細な説明】 〔産業上の利用分野〕 本発明は優れた入浴効果、特に肌になめらかさを与える
点で優れた入浴剤組成物に関する。DETAILED DESCRIPTION OF THE INVENTION [Field of Industrial Application] The present invention relates to a bath agent composition which is excellent in that it has an excellent bathing effect, in particular, it imparts smoothness to the skin.
入浴には一日の疲れをとり、心身ともにリラックスさせ
るという効果の他、種々の効果がある。Bathing has various effects in addition to the effect of relieving fatigue from the day and relaxing the body and mind.
この入浴の効果をよりいっそう高めるため、各種の入浴
剤が開発されてきた。Various bathing agents have been developed in order to further enhance the effect of this bathing.
それらの中で、入浴によって肌をなめらかにするという
目的で、各種のオイルやアルカリ成分を入浴剤組成物に
添加する試みが以前からなされてきた（例えば特公昭50
−30687号参照）。Among them, attempts have been made for a long time to add various oils and alkaline components to a bath agent composition for the purpose of smoothing the skin by taking a bath (for example, Japanese Patent Publication No. Sho 50).
-See 30687).
しかし、従前のこの種入浴剤組成物ではオイルの質又は
量により、浴槽の壁面を汚したり、製剤化し保存する
際、酸化によって商品価値が低下する等の問題点があっ
た。However, this type of bath salt composition of the related art has a problem that the quality of the oil or the amount of the oil stains the wall surface of the bathtub or reduces the commercial value due to oxidation when it is formulated and stored.
その上、オイルの量が多いと、かえって肌がべたつき、
さわやかな入浴感が損なわれるという問題もあったので
ある。Moreover, when the amount of oil is large, the skin becomes rather sticky,
There was also the problem that the refreshing feeling of bathing was impaired.
一方、アルカリ成分の添加にも、アルカリ度が弱いとか
なりの量を使用しないと効果が出ず、さりとてアルカリ
度の強いものを使用すると浴場が少なくなったときアル
カリ度が強くなり過ぎ皮膚表面をおかす等の危険が生ず
るという問題点があった。On the other hand, even if the alkalinity is weak, if the alkalinity is weak, it will not be effective unless a large amount is used, and if a slightly strong alkalinity is used, the alkalinity will become too strong when the bath decreases and the skin surface There was a problem that there was a danger of being left behind.
本発明者は上記のような問題点のない、したがって入浴
効果のうち、特に肌がなめらかになる入浴剤組成物を得
るべく鋭意研究の結果、硫酸ナトリウム、炭酸水素ナト
リウム、炭酸カルシウム及び塩化カリウムの特定の配合
によりこれが達成できることを見出し、本発明を完成し
た。The present inventor has earnestly studied to obtain a bathing agent composition which does not have the above-mentioned problems and therefore has a particularly smooth skin, and as a result, sodium sulfate, sodium hydrogen carbonate, calcium carbonate and potassium chloride We have found that this can be achieved with a specific formulation and completed the present invention.
すなわち本発明は、硫酸ナトリウム4.0〜10.0重量部、
炭酸水素ナトリウム80.0〜90.0重量部、炭酸カルシウム
1.0〜3.0重量部及び塩化カリウム1.0〜3.0重量部を主成
分とする入浴剤組成物を提供するものである。That is, the present invention is sodium sulfate 4.0 to 10.0 parts by weight,
Sodium hydrogen carbonate 80.0-90.0 parts by weight, calcium carbonate
It is intended to provide a bath agent composition containing 1.0 to 3.0 parts by weight and 1.0 to 3.0 parts by weight of potassium chloride as main components.
以下本発明を詳細に説明する。The present invention will be described in detail below.
本発明で用いる硫酸ナトリウムは、その無水塩（Na2S
O4）、及び１水塩（Na2SO4・H2O）及び10水塩（Na2SO4
・10H2O）等が好適に使用できる。このうち10水塩（芒
硝）はいわゆる人絹芒硝、中性結晶芒硝、副生芒硝等と
して容易に入手できる。Sodium sulfate used in the present invention is its anhydrous salt (Na 2 S
O 4 ), and monohydrate (Na 2 SO 4 · H 2 O) and decahydrate (Na 2 SO 4
・ 10H 2 O) and the like can be preferably used. Of these, 10-hydrate salt (Glauber's salt) is easily available as so-called human silk Glauber's salt, neutral crystalline Glauber's salt, and by-product Glauber's salt.
硫酸ナトリウムの配合量は4.0〜10.0重量部である。The content of sodium sulfate is 4.0 to 10.0 parts by weight.
炭酸水素ナトリウム（NaHCO3:重曹）はアンモニアソー
ダ法などで製造された市販のものでよい。The sodium hydrogen carbonate (NaHCO 3 : sodium bicarbonate) may be a commercially available product manufactured by the ammonia soda method or the like.
その配合量は80.0〜90.0重量部である。The blending amount is 80.0 to 90.0 parts by weight.
炭酸カルシウムは分子式CaCO3で表わされる化合物であ
り、石灰石を原料として製造される一般に市販されてい
るものでよい。Calcium carbonate is a compound represented by the molecular formula CaCO 3 , and may be a generally commercially available product produced from limestone.
配合量は1.0〜3.0重量部である。The compounding amount is 1.0 to 3.0 parts by weight.
塩化カリウムは分子式KClで表わされる化合物であり、
カリ鉱石から分離精製された市販のものでよい。Potassium chloride is a compound represented by the molecular formula KCl,
It may be a commercially available product that is separated and purified from potassium ore.
配合量は1.0〜3.0重量部である。The compounding amount is 1.0 to 3.0 parts by weight.
本発明にとって、入浴剤組成物を構成する成分の上記配
合量は極めて重要である。For the present invention, the above-mentioned blending amounts of the components constituting the bath salt composition are extremely important.
表１からも明らかな通り、本発明の配合量（実施例）と
これを外された配合量（比較例）の間には「肌のなめら
かさ」において明瞭な効果の差が存在するからである。As is clear from Table 1, there is a clear difference in the "smoothness of the skin" between the compounding amount of the present invention (Example) and the compounding amount without this (Comparative Example). is there.
なお、本発明の入浴剤組成物の各成分は、相互に相関的
関係を有し、他成分の配合量と無関係に個々の配合量を
設定することが出来ず、種々のバランスを念頭におきな
がら、一体的なものとして最適配合量を決定しなければ
ならないという困難さを克服しなければならなかった。In addition, each component of the bath agent composition of the present invention has a mutual correlation, it is not possible to set the individual blending amount regardless of the blending amount of other components, keep in mind various balances. However, it has been necessary to overcome the difficulty of determining the optimum blending amount as a unit.
そのため数多くの実験の積み重ねが必要となり、それら
のデータにもとづいて本発明の配合量は決定されたので
ある。Therefore, many experiments were required to be accumulated, and the compounding amount of the present invention was determined based on those data.
本発明の組成物には、他に入浴剤配合剤として従来使用
されてきた次に示すような添加成分を配合することがで
きる。The composition of the present invention may further contain the following additive components which have been conventionally used as a bathing agent compounding agent.
１） 無機塩類 塩化ナトリウム、硝酸カリウム、硝酸ナトリウム、硝酸
カルシウム、硝酸アルミニウム、ポリリン酸ナトリウ
ム、塩化アンモニウム、硝酸鉄燐酸ナトリウム、チオ硫
酸ナトリウム、炭酸ナトリウム、硼酸、メタ珪酸、無水
珪酸等。1) Inorganic salts Sodium chloride, potassium nitrate, sodium nitrate, calcium nitrate, aluminum nitrate, sodium polyphosphate, ammonium chloride, sodium iron nitrate phosphate, sodium thiosulfate, sodium carbonate, boric acid, metasilicic acid, silicic acid anhydride, etc.
２） 有機酸類 安息香酸、クエン酸、フマル酸、酒石酸、ピロリドンカ
ルボン酸、コハク酸、リンゴ酸等。2) Organic acids Benzoic acid, citric acid, fumaric acid, tartaric acid, pyrrolidonecarboxylic acid, succinic acid, malic acid, etc.
３） 生薬類 ソウジュツ、ビャクジュツ、カノコソウ、ケイガイ、コ
クボク、センキュウ、橙皮、トウキ、ショウキョウ末、
ニンジン、ケイヒ、シャクヤク、ハッカ葉、オウゴン、
サンシン、ブクリョウ、ドクカツ、ショウブ、ガイヨ
ウ、マツブサ、ビャクシ、ジュウヤク、リュウノウ、サ
フラン、オウバクエキス、チンピ、ウイキョウ、カンピ
末、カミツレ、メリッサ、ローズマリー、マロニエ、西
洋ノコギリ草、アルニカ等。3) Crude drugs Sojutsu, sandalwood, valerian, kayigai, kokuboku, senkyu, orange peel, toki, ginger powder,
Carrot, cinnamon, peony, peppermint leaf, sardine,
Sanshin, Bukyou, Dokukatsu, Shobu, Guyou, Matsuba, Juniper, Juyaku, Ryuno, Saffron, Oataku extract, Chinpi, Fennel, Campi powder, Chamomile, Melissa, Rosemary, Marronnier, Sawgrass, Arnica etc.
４） 油脂類 イソプロピルパルミテート、イソプロピルミリステー
ト、スクワラン、トリ（カプリル−カプリン酸）グリセ
リン、糠油、米糠エキス、オリーブ油、ホホバ油、大豆
油、流動パラフィン、白色ワセリン等。4) Fats and oils Isopropyl palmitate, isopropyl myristate, squalane, tri (capryl-capric acid) glycerin, bran oil, rice bran extract, olive oil, jojoba oil, soybean oil, liquid paraffin, white petrolatum, etc.
５） 色素類 赤色２号、黄色４号、緑色３号、青色１号、赤色213
号、橙色205号、黄色202号の１、緑色204号、青色２号
等の厚生省令タール色素別表Ｉ及びIIの色素、クロロフ
ィル、リボフラビン、アンナット、カンタキサンチン、
クロシン、コチニール、べにばな、アントラキノン等の
食品添加剤として認められる天然色素。5) Pigments Red No. 2, Yellow No. 4, Green No. 3, Blue No. 1, Red 213
No. 205, Yellow No. 205, Yellow No. 2021, Green No. 204, Blue No. 2, etc., Tar Dyes in Appendix I and II, chlorophyll, riboflavin, annatto, canthaxanthin,
Natural pigments recognized as food additives such as crocin, cochineal, safflower, and anthraquinone.
６） アルコール類 エタノール、ステアリルアルコール、イソプロピルアル
コール、セチルアルコール、ヘキサデシルアルコール
等。6) Alcohols: ethanol, stearyl alcohol, isopropyl alcohol, cetyl alcohol, hexadecyl alcohol, etc.
７） 多価アルコール グリセリン、プロピレングリコール、ソルビトール等。7) Polyhydric alcohol Glycerin, propylene glycol, sorbitol, etc.
８） 界面活性剤類 アルキル硫酸ナトリウム、ポリオキシエチレンアルキル
エーテル硫酸塩、ラウリン酸ジエタノールアミド、ポリ
エチレングリコールモノステアレート等。8) Surfactants Sodium alkyl sulfate, polyoxyethylene alkyl ether sulfate, lauric acid diethanolamide, polyethylene glycol monostearate and the like.
９） その他 イオウ、鉱砂、湯の花、カゼイン、中性白土、サリチル
酸ナトリウム、カルボキシメチルセルロースナトリウ
ム、卵黄末、イリ糠、雲母末、脱脂粉乳、ポリビニルピ
ロリドン等 を添加使用することができる。9) Others Sulfur, mineral sand, yunohana, casein, neutral clay, sodium salicylate, sodium carboxymethyl cellulose, egg yolk powder, iris bran, mica powder, skim milk powder, polyvinylpyrrolidone and the like can be added and used.
さらに本発明の入浴剤組成物は、上記したもの以外に
も、必要に応じて殺菌防腐剤、金属封鎖剤、香料、その
他の広い範囲の配合剤を配合することができる。Further, the bath agent composition of the present invention may contain, in addition to the above-mentioned ones, a bactericidal preservative, a sequestering agent, a fragrance, and a wide range of other compounding agents, if necessary.
次に、本発明の入浴剤組成物の製造方法について説明す
る。Next, a method for producing the bath agent composition of the present invention will be described.
まず、5.0〜10.0重量部の硫酸ナトリウム、80.0〜90.0
重量部の炭酸水素ナトリウム、1.0〜3.0重量部の炭酸カ
ルシウム及び1.0〜3.0重量部の塩化カリウムと、必要に
より色素類等の成分を加え、この混合物を混合機に投入
して、常温にて均一に攪拌混合した後、香料、油脂類等
を適宜添加してさらに攪拌混合することによって製造す
る。First, 5.0 to 10.0 parts by weight of sodium sulfate, 80.0 to 90.0
Add parts by weight of sodium hydrogen carbonate, 1.0 to 3.0 parts by weight of calcium carbonate and 1.0 to 3.0 parts by weight of potassium chloride, and components such as pigments, if necessary, and put this mixture into a mixer to homogenize at room temperature. After stirring and mixing, the perfume, fats and oils are appropriately added, and the mixture is further stirred and mixed to produce.
混合機としては、粉体を攪拌、混合するために使用され
るものであればどのようなものでも使用できる。具体的
にはバートミキサー、ナウターミキサー、万能攪拌混合
機、リボンミキサー、Ｖ字型混合機等を挙げることがで
きる。Any mixer can be used as long as it is used for stirring and mixing the powder. Specific examples thereof include a Bart mixer, a Nauter mixer, a universal stirring mixer, a ribbon mixer, and a V-shaped mixer.
混合時間は、成分が均一に混合するのに必要な時間であ
ればよく、上記の例にあげた混合機を使用する場合に
は、通常５〜50分間でよい。The mixing time may be any time necessary for uniformly mixing the components, and when the mixer described in the above example is used, it is usually 5 to 50 minutes.
以下実施例、比較例をあげて本発明を具体的に説明す
る。The present invention will be specifically described below with reference to Examples and Comparative Examples.
なお、以下の夫々の入浴剤組成物に対し実施した入浴試
験における主観評価は次のようにして行った。The subjective evaluations in the bathing tests conducted on the following bathing agent compositions were carried out as follows.
パネラーの数:10名 処方：夫々の実施例、比較例に示す 浴場の温度:41℃ 入浴剤組成物の使用量:30g/200 入浴時間:5分 主観評価の方法：出浴後25℃の恒温室にて安静状態を保
持 評価内容：肌のなめらかさ 非常に肌がすべすべになったなどの良好な感触が得られ
たときを５点とし、べたついたり、かさついたりの不快
な感触となった場合を−５点とする。そしてサラ湯と大
差なしを±０点とし、＋５〜−５点の10段階評価を行っ
た。評価数値は10名の平均値である。Number of panelists: 10 Prescription: Shown in each example and comparative example Bath temperature: 41 ° C Amount of bathing agent composition: 30g / 200 Bathing time: 5 minutes Subjective evaluation method: 25 ° C constant temperature after bathing Keeping a resting state in the room Evaluation details: Smoothness of the skin 5 points were given when a good feeling such as smooth skin was obtained, and it became uncomfortable feeling such as stickiness or stickiness. The case is -5 points. Then, a 10-point evaluation of +5 to -5 was carried out, with ± 0 being no difference from Sarayu. The evaluation value is the average value of 10 persons.
実施例１及び２ 比較例１〜10 硫酸ナトリウム8.0重量部、炭酸水素ナトリウム88.0重
量部、炭酸カルシウム2.0重量部、塩化カリウム2.0重量
部を万能攪拌混合機（三英製作所製 25AM−rr−（Q
r））に入れ10分間攪拌混合した。Examples 1 and 2 Comparative Examples 1 to 10 8.0 parts by weight of sodium sulfate, 88.0 parts by weight of sodium hydrogen carbonate, 2.0 parts by weight of calcium carbonate, 2.0 parts by weight of potassium chloride were mixed with a universal stirring mixer (manufactured by Sanei Seisakusho 25 AM-rr- (Q
r)) and stirred and mixed for 10 minutes.
得られた入浴剤組成物を用いて先に示した入浴試験を実
施し、主観評価を行った。結果は表１に示す（実施例
１）。The bathing test described above was carried out using the obtained bathing agent composition, and subjective evaluation was performed. The results are shown in Table 1 (Example 1).
又、実施例１と同様に調製に、表１に示す配合にした実
施例２の入浴剤組成物、並びに比較のため本発明の配合
量と異なる配合にした他は、実施例１と同様にした比較
例１〜10の結果を表１に示す。Also, the same as in Example 1, except that the preparation was carried out in the same manner as in Example 1 except that the bathing agent composition of Example 2 having the composition shown in Table 1 and a composition different from the compounding amount of the present invention for comparison were prepared. The results of Comparative Examples 1 to 10 are shown in Table 1.
表１から明らかなように、本発明の入浴剤組成物である
実施例１及び２は本発明と異なる配合になっている比較
例１〜10に比べ肌のなめらかさが優れていることがわか
る。As is clear from Table 1, Examples 1 and 2 which are bath agent compositions of the present invention are superior in skin smoothness to Comparative Examples 1 to 10 which have different formulations from the present invention. .
実施例３ 硫酸ナトリウム6.4重量部、炭酸水素ナトリウム85.1重
量部、炭酸カルシウム2.0重量部、塩化カリウム2.0重量
部、緑色204号0.1重量部、青色２号0.1重量部及びデキ
ストリン0.3重量部を万能攪拌混合機（三英製作所製 2
5AM−rr−（Qr））に入れ10分間攪拌混合した。 Example 3 6.4 parts by weight of sodium sulfate, 85.1 parts by weight of sodium hydrogen carbonate, 2.0 parts by weight of calcium carbonate, 2.0 parts by weight of potassium chloride, 0.1 part by weight of green No. 204, 0.1 part by weight of blue No. 2 and 0.3 part by weight of dextrin were mixed by universal stirring. Machine (made by Sanei Seisakusho 2
5 AM-rr- (Qr)), and mixed with stirring for 10 minutes.
次にこれに香料2.0重量部及びホホバ油2.0重量部を加
え、上記攪拌混合機にて更に10分間攪拌混合して3kgの
入浴剤組成物を得た。Next, 2.0 parts by weight of fragrance and 2.0 parts by weight of jojoba oil were added thereto, and the mixture was further stirred and mixed for 10 minutes by the above stirring and mixing machine to obtain 3 kg of a bath agent composition.
この入浴剤組成物に対して前記の入浴試験を行い、主観
評価をしたところ肌のなめらかさ＋4.9の優れた結果を
得た。This bathing agent composition was subjected to the above-mentioned bathing test and subjected to subjective evaluation to obtain an excellent result of skin smoothness +4.9.
本発明の入浴剤組成物は従来の入浴剤組成物に比べ優れ
た入浴効果、特に肌になめらかさを与えるものであっ
て、これを用いて入浴することによって体を温め血行を
よくし新陳代謝を活発にするという効果の他に、肌のな
めらかさが豊化するという良質の温泉にいったのと同じ
ような入浴効果が達成できたのである。The bath agent composition of the present invention provides a superior bathing effect as compared with the conventional bath agent composition, in particular, provides smoothness to the skin, and bathing with this bath warms the body to improve blood circulation and metabolism. In addition to the effect of energizing, I was able to achieve a bathing effect similar to that of a high-quality hot spring where the smoothness of the skin was enriched.
Claims (1)
素ナトリウム80.0〜90.0重量部、炭酸カルシウム1.0〜
3.0重量部及び塩化カリウム1.0〜3.0重量部を主成分と
する入浴剤組成物。1. Sodium sulfate 4.0 to 10.0 parts by weight, sodium hydrogen carbonate 80.0 to 90.0 parts by weight, calcium carbonate 1.0 to
A bath agent composition containing 3.0 parts by weight and 1.0 to 3.0 parts by weight of potassium chloride as main components.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP19272986A JPH0759495B2 (en) | 1986-08-20 | 1986-08-20 | Bath agent composition |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP19272986A JPH0759495B2 (en) | 1986-08-20 | 1986-08-20 | Bath agent composition |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS6351323A JPS6351323A (en) | 1988-03-04 |
| JPH0759495B2 true JPH0759495B2 (en) | 1995-06-28 |
Family
ID=16296093
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP19272986A Expired - Fee Related JPH0759495B2 (en) | 1986-08-20 | 1986-08-20 | Bath agent composition |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH0759495B2 (en) |
-
1986
- 1986-08-20 JP JP19272986A patent/JPH0759495B2/en not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| JPS6351323A (en) | 1988-03-04 |
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