JPH076141B2 - Dyeing method using Yunohana - Google Patents

Description

TECHNICAL FIELD The present invention relates to a dyeing method using Yunohana. More specifically, the present invention relates to a dyeing method in which a mordant dye or a flower of a mordant, Yunohana, is directly mixed with a dyeing liquid in dyeing with a natural dye such as a plant dyeing.

[Conventional technology]

In the dyeing of plants and animals with natural dyes such as plant dyeing, it is usual to carry out a dyeing process called mordant for the purpose of effectively developing and dyeing. Examples of the mordant used for this mordant are ash of vegetation such as straw, rice husk and camellia; vinegar such as plum vinegar; fermented fermented acetacea and wood; iron acetate, aluminum acetate, alum, copper sulfate, lime. Metal salts such as tannin-based substances are generally used.

[Problems to be Solved by the Invention]

However, when mordanting is carried out using these mordanting agents, there are disadvantages that the dyeing tends to be uneven and the color becomes dark.

On the other hand, when mordanting is carried out using a tin compound such as stannous chloride or stannic chloride, the color is relatively well finished, but for this reason, there is a drawback that mordanting must be carried out 2-3 times.

[Means for Solving the Problems]

Therefore, as a result of intensive studies to overcome the above-mentioned drawbacks, the present inventor has found that when a hot spring flower, which is a deposit of hot spring water, is directly mixed with a dyeing solution and dyed, coloring and dyeing are effectively performed. The inventors have completed the present invention by discovering that the color tone can be finely adjusted and the color tone can be finely adjusted freely and easily by changing the number of times of immersion.

That is, according to the present invention, in a dyeing method using natural dyes of plants and animals, mordants such as straw, rice husk, and camellia ash such as camellia; vinegar such as ume vinegar; fermented acetate-based ogre and Metal salts of iron acetate, aluminum acetate, alum, copper sulfate, lime, etc .; tannin-based substances, etc. are strictly distinguished from dyeing liquors, and it is common knowledge that dyeing is accomplished by mixing a mordant in the dyeing liquor. I was believed not to go. The lye of plants such as straw, rice husk, camellia; vinegar such as plum vinegar; fermented fertilizer-based ogre and wood ferric acetate, aluminum acetate, alum,
Metal salts such as copper sulfate and lime; as is the case with mordants such as tannin-based substances, the inventor of the present application, when the hot spring flowers of hot springs are used as mordants, the hot spring flowers are used as mordants. In addition to functioning, it was discovered that it also functions as a dyeing liquor, and it was found that dyeing is possible even when this Yunohana is mixed directly into the dyeing liquor. Rather, by mixing hot water flowers directly into the dye liquor, coloring and dyeing can be effectively performed, and moreover, delicate adjustment of the hue can be performed freely and easily by changing the number of dippings. That is, the present invention has been completed.

[Action]

In the present invention, since Yunohana is used as a mordant or dyeing agent, dyeing can be performed smoothly, and the finish color can be freely and easily adjusted by changing the number of dippings. Therefore, the desired color and pattern can be dyed, and since the hot water flower is added to the dyeing solution, the mordant step can be omitted.

〔Example〕

Hereinafter, embodiments of the present invention will be described in detail with reference to the drawings, but the present invention is not limited thereto.

(Example 1) As one embodiment of the present invention, a dyeing method by dip dyeing was carried out. A flowchart of all the steps is shown in FIG.

In FIG. 1, 1 is a designing process, 2 is a drafting process, 3 is a material (fabric) selection process, 4 is a desizing process, a refining process, and if necessary, a soaking process, 5 is a dyeing process. An agent selection step, 6 is a dyeing step, 7 is a drawing step, 8 is a dyeing step, 9 is a yarn unwinding step, 10 is a finishing step, and a post-processing step is performed if necessary.

First, according to the purpose and intention, design decision 1, material selection 3
And 5 of dye selection. In the present embodiment, the pattern of plum blossoms and turtle shells was selected as the design, but of course, it is also possible to dye it plain. The material may be cloth such as silk, cotton, woolen fabric, or Japanese paper, without any particular limitation. Further, silk yarn, cotton yarn, wool yarn, or the like before weaving as a cloth may be used.

In this example, silk and cotton fabrics were used. In general, these materials are often pasted and the dye does not easily reach them, so desizing and refining treatment 4 are performed as pretreatments. As a treatment, if necessary, it is soaked in soybean soup and subjected to a soybean soaking treatment 4. This desizing treatment is performed by soaking the material in hot water to remove the glue, that is, by so-called blanching. In addition, refining is
The material is boiled in alkalis such as lye, lime, various soaps, caustic soda, sodium carbonate, and sodium silicate for about 1 hour. Kure is used to facilitate the coloring of the dye, and is generally not necessary for proteinaceous materials such as silk, but it is necessary for non-proteinaceous materials such as cotton. For example, in the case of cotton, it is desirable to do so twice in order to enhance the effect. In addition, you may use the milk diluted twice instead of the soy sauce. The material that has been grated is dried. In this embodiment, the silk fabric is not coated with Kure, and the cotton fabric is coated with 2 Kure.
I made a tie.

In this way, a work for applying the pattern selected as the design to the material subjected to the step 4 is performed. As described above, in this embodiment, since the pattern of plum blossoms and turtle shells was selected as the design,
Accordingly, sewing drawing and plate tightening were performed, respectively.

When you squeeze the sewing, use the material that has undergone the 4 steps,
First, draw a rough sketch with the flower juice of blue flowers (2), and then perform drawing work 7.

In the case of plate tightening, the drawing work 7 is performed by sandwiching and tightening a set of two folding plates for plate tightening.

In addition, when the soaking process was not performed in the step of 4, the squeezing work 7 was performed and then the material was immersed in water for about 2 to 3 hours.

On the other hand, the dye liquor collection 6 is performed from the dye material selected in 5.

As the dyeing material, natural animals and plants are used. Examples of plant dyeing materials include plant skins, flowers, fruits, leaves, stems, stems, roots, and the like. Specifically, cuticles of onion, sencha, kihada, daffodil tree, kunugi, cypress, cypress, cherry tree, etc.
Flowers such as small chrysanthemum, pyracanthus, marigold, trunks of dwarf trees, roots of madder grass, etc. Examples of animal dyeing materials include cochineal and lac (shellworm).

In this example, the onion cuticle was used as a dyeing material for the purpose of not utilizing waste, and this was treated as follows, and dyeing solution removal 6 was performed.

Put the onion cuticles in a pan, add water or hot water for about 7 to 8 minutes in the pan and heat. The amount of cuticle of the onion is about the same as the weight of the cloth of the material when the cuticle is dry, and about twice the weight of the cloth when the cuticle is wet. Instead of the pot, a basin (preferably enameled) or a pot may be used. about
After roasting for 20 minutes, pour the soup into a container such as a poly bucket with a shogi or colander on top (first liquid). Put the dyeing material back in the pot or kettle, add water or hot water in the same manner as when using the first liquid, heat roast for about 20 minutes, and take the second decoction (second liquid). Repeat the procedure for taking the No. 2 liquid, and usually take the No. 3 to No. 4 liquids, but depending on the case, take the No. 8 liquid. In this example, the second liquid was used. Each of these decoctions is passed through a silk-mesh screen or filter paper in each case and then mixed, or after mixing, it is applied to a silk-mesh screen or filter paper to obtain a dye liquor.

Dyeing 8 is performed as follows using the dyeing solution obtained as described above and the squeezing cloth subjected to the squeezing work 7.

A flowchart of the dyeing process 8 is shown in FIG. 2, and the dyeing process 8 will be described with reference to this.

About two-thirds of the dyeing liquor obtained by the dyeing liquor collection 6 is put in a dyeing pot and heated (step 11). A duralumin or enameled pot may be used instead of the dyeing pot.

A predetermined amount of Yunohana is mixed with the dye liquor (step 11 ').

When the dye liquor mixed with Yunohana is heated to about 80 ° C, the material cloth is dipped in the dye liquor (step 12).
When the squeezing cloth is soaked in water after the squeezing work 7, the water is drained and then the squeezing cloth is soaked in the dye liquor. The squeezed cloth soaked in the dyeing solution is boiled while stirring well with a stick so that it can be dyed evenly (step 13). Simmering is about 20 minutes after boiling the dyeing solution.
Do about 30 minutes.

In the present invention, as a mordant solution or a dye solution, a hot spring flower solution prepared by dissolving hot spring flowers in water or hot water or a hot spring (hot spring itself) is used.

The amount of Yunohana was about 1.5 to 5% by weight of the weight of the material cloth. However, the hue of the finish can be adjusted by changing the amount of this hot spring flower. When the amount of Yunohana is large, the color becomes astringent, and the color becomes deeper and darker. On the other hand, when the amount of hot spring flowers is small, the color becomes pale.

In addition, in order to make the color more vivid, in addition to the above method, so-called ordinary tin mordant may be applied before mordant with the flower of hot water. The amount of mordant in this tin mordant is about 1.5% by weight of the weight of the fabric.

In the examples of the present invention, the same Yunohana and spring were used throughout the examples. When I analyzed the Yunohana,
It contained the following components.

H ₂ O 6.79 wt% SiO ₂ 24.60 wt% Al ₂ O ₃ 3.66 wt% Fe ₂ O ₃ 58.14 wt% CaO 3.08 wt% MgO 0.17 wt% P ₂ O ₅ 1.60 wt% CO ₂ 0.47 wt% Also as a source The source of the above Yunohana was used.

Since Yunohana was added to the dye liquor from the beginning, the mordanting process peculiar to plant dyeing could be omitted.

The squeezed squeezed cloth is taken out from the dyeing solution containing hot water, squeezed, washed thoroughly with water (step 15), and then simmered again if necessary (step 16). In this case, the re-boiled dyeing takes about 20 minutes to about 30 minutes after the dyeing liquid containing the flowers of hot water has boiled.
Do the split and see the color development process at this stage.

After the simmering process 16, the squeezed cloth is washed with water (step 17) and then exposed to the sun to be dried in the middle (step 18).

Here, the used dye liquor and the remaining one-third of the dye liquor obtained in the dye liquor remover 6 are combined and fired. When the dye reaches about 80 ° C, put a cloth that has been dried in the middle and boil the dye again and boil again for about 20 to 30 minutes (step 19). Remove the squeeze cloth from the dye solution and wash it with water (step 20). At this time, in the case of plate tightening, remove the plate and wash with water. Then, dry the squeezing cloth lightly (step 21). The above is the dyeing step 8. However, this dyeing step 8 may be repeated if a particularly dark shade, astringent hue or the like is desired.

After finishing the dyeing process 8, the unwinding process 9 of the well-dried squeezing cloth
Do. A finishing process is applied to the cloth that has been unwound (step 10). In this case, if the unwound cloth has dregs etc., lightly wash it with water and dry it, then finish 10
do. The finishing step 10 is performed by finishing with hot water or applying a steam iron or the like from the back. With the finishing, or if necessary, post-processing is performed to complete all the steps of the dyeing method of the present embodiment.

The dyed product obtained as described above had a light brown color with warmth and taste.

(Example 2) In the same manner as in Example 1 except that instead of the onion cuticle in Example 1, the dyeing material was replaced with yellowfin skin, gardenia fruit, holly nanten fruit, marigold flower, and cypress tree skin. Each was dyed. A yellow-brown to light brown dyeing is obtained. In each case, the color was warm and rich.

(Example 3) In this example, stencil dyeing was performed using a rough sketch. First, the design was decided, and the material and the dyeing material were selected.

Draw a sketch on tracing paper of Mino or Washi according to the design. Put the rough sketch on the pattern paper of astringent paper, and carve it with a carving knife etc. to make a paper pattern. Soak the pattern you made in water.

In this embodiment, cotton and silk were selected as the materials.
For cotton and silk, desizing and refining 4 were carried out in the same manner as in Example 1.

Then, prepare a patterning plate, draw out the spread paste, apply a cloth, and drain the pattern paper previously dipped in water onto it. Use a spatula to apply a dye-proof paste on the pattern paper and place the paste.

On the other hand, the cuticle of onion was selected as the dyeing material, and the dyeing solution was removed in the same manner as in Example 1.

The cloth on which the paste is placed and a dyeing liquid in which hot spring flowers are mixed are prepared, and the dyeing process is started.

As the Yunohana in this case, water or a hot spring liquid obtained by dissolving Yunohana in hot water is used. In addition, in order to increase the concentration, you can use a hot spring with melted Yunohana.

Hereinafter, the dyeing process of this embodiment will be described with reference to the flowchart of FIG.

Put glue on the cloth, stretch the cloth on the tensioner, and hit Shinko (step
31).

Prepare soybean soup in the same manner as in Example 1, and draw the soybean soup with a brush on the cloth applied to the upholstery (step 32).

Kure soup is drawn twice for cotton and once for silk. The cloth soaked in goji juice is dried, but it is advisable to dry it in a sunny place for a short time. After sufficiently drying, the dye solution mixed with Yunohana is brushed twice (step 33).

Draw the same dye once to dry, then draw a second time.

After the cloth which has been subjected to the dye solution mixed with Yunohana is dried sufficiently, the Yunohana solution may be further applied with a brush (step 34).

In the step of drawing the dye liquor, according to the present invention, since the hot water is added to the dye liquor, one step can be omitted.

At this point, it is inspected whether or not a desired shade is obtained, and if the desired shade is obtained, the soybean juice is drawn in the same manner as in the soybean soup drawing step (32) (step 3
6).

If the desired shade is not obtained, the step 35 of drawing the dye liquor mixed with the hot spring flowers again is repeated to adjust to the desired shade.

At this time, if a deeper and deeper color is desired, the amount of hot spring flowers may be increased.

Further, at this stage, by using a sub-printing, a round-printing or the like, it is possible to carry out coloring, blurring, etc., and if desired, that step may be taken.

After carrying out the step 35 of drawing the dye liquor mixed with the hot water, the cloth is dried, and the gourd soup is drawn again in the same manner as in the gourd drawing step 32 (step 36).

The cloth soaked in Kure soup again is exposed to the air for a few days to allow the dye to settle, and then the stretcher is removed, the hand is taken in, and the cloth is dipped in water to remove the glue (step 37). In this case, it is preferable to immerse the cloth in a large container such as a bowl with plenty of water, and the immersing time is usually about 1 to about 2 hours.

After that, the glue is removed by alternately pulling the cloth in an oblique direction, the water is replaced, and the glue is thoroughly washed until the glue is removed (step 38).

After drying the cloth, steam it (step 39). The steaming time is about 40 minutes after the steam rises.

After the steamed cloth is stretched on the tensioner, Kure soup is drawn (step 40).

When the cloth soaked in Kure soup is dry, remove the stretcher, pull in the hand and take it in, and wash it with post-treatment water several times (Step 4
1).

After washing with this post-treatment water, the cloth is stretched on a hand (no stretcher is struck), and it is thoroughly dried with the back side up to then. After drying, if necessary, a hot water finish or a steam iron or the like is applied from the back to finish (step 42).

The dyed product thus obtained had a tasting and timeless shade.

In addition, it was confirmed that by adjusting the amount of hot spring flowers, it was possible to easily blur, the colors were abundant, and the shade and brightness could be adjusted to give a three-dimensional effect.

(Example 4) Dyeing material was dyed in the same manner as in Example 3 except that sencha, Kamizomi cherry bark, stems of small cucumber grass, leaves, roots of madder, etc. were used in place of the onion cuticle in Example 3 as the dyeing material. Was done. In each case, a dyed product having an elegant color tone with a sense of comfort was obtained.

(Example 5) In this example, stencil dyeing of Japanese paper was performed. A pattern is made in the same manner as in Example 3. Lay newspaper on a board (or a desk), place Japanese paper on top, and put a pattern on it. Use a spatula to apply a dye-proof paste on the pattern paper and place the paste. For Japanese paper, apply a softer dye-proof glue than for cloth. Peel off the pattern paper, fix the Japanese paper on which the glue is placed with the selective sandwich placed inside the room, and dry the glue. On the other hand, the cuticle of onion was selected as the dyeing material, and the dyeing solution was removed in the same manner as in Example 3. Place Japanese paper with dried glue on a newspaper and pull the dye twice with a brush. After the first dyeing solution has dried, draw the second dyeing solution. In the case of Japanese paper, it is not necessary to draw the goji juice before drawing the dye liquor, but in order to dye it without uneven color, draw konjac glue and dry it. For Japanese paper, be careful not to damage it with a brush. After drawing the dye liquor, use a brush to draw the flower liquor of the source or hot water which is the dye liquor or mordant. In the case of Japanese paper, it is also possible to put a dye solution or a mordant of Yunohana into the dye solution and draw it on the Washi paper to omit the step. Washi paper, which has been dyed with hot water, is dried for several hours. Coloring, blurring, etc. may be performed here. Soak the dried Japanese paper face down in water. After soaking for about 1 hour, lightly water the surface of Japanese paper to remove the glue. After changing the water and rinsing the washi paper, lift it out of the water and drain it well. Hang the dried Japanese paper on a string and dry it. The resulting dyed Japanese paper had a beautiful color with a unique taste of Japanese paper.

(Example 6) Dyeing was carried out in the same manner as in Example 5, except that instead of the cuticle of the onion in Example 5, the dyeing material was replaced with sencha, Kamizomi cherry bark, small chrysanthemum grass, and vine root. In each case, a beautiful shade with a unique taste of Japanese paper was obtained.

〔The invention's effect〕

In the present invention, since a hot spring flower is mixed with a hot spring water or a hot spring liquid or a hot spring mixed with a source spring, coloring and dyeing are effectively performed. Therefore, even one mordant can be dyed beautifully. When using Yunohana,
You can easily and subtly adjust the colors by simply changing the amount of hot water. Therefore, it is possible to freely select the shade of light and shade, and to express rich colors with taste such as bright colors, astringent colors, and deep colors. In addition, since various colors can be freely selected, it is possible to easily give a three-dimensional effect and to blur by the shade and the brightness. Therefore, it is possible to express a variety of different colors and patterns, and it is possible to create elegant and timeless dyeings.

Furthermore, it is expected that it will contribute to the local industry in the area where hot springs spring, since it is economical because it uses cheap Yunohana or hot springs, and it is also a resource utilization.

[Brief description of drawings]

FIG. 1 is a flow chart of all steps for carrying out a dyeing method by dip dyeing showing an embodiment of the present invention, FIG. 2 is a flow chart of a dyeing step 8, and FIG. 3 is a flow chart of a dyeing step according to a third embodiment. It is a flowchart. 1; Design creation process, 2; Draft drawing process, 3; Material (fabric) selection process, 4; Desizing, scouring process and, if necessary, brewing process, 5; Dye selection process, 6; dyeing process,
7; drawing work step, 8; dyeing step, 9; yarn unwinding step, 10; finishing step and, if necessary, 11; dyeing pot heating, 1
1 '; mix hot water flowers in dye liquor, 12; soak in dye liquor, 13; boil, 15; wash with water, 16; reboil, 17; wash with water, 18; dry in air,
19; Re-simmering again, 20; Re-washing, 21; Drying, 31; Stretching, 32; Pulling gourd, 33; Pulling dye solution, 35; Pulling dye solution mixed with hot water repeatedly, 36; Again Pull the gourd, 37;
Remove glue, 38; wash with water, 39; steam, 40; pull gourd, 41;
Post-treatment water washing, 42; finishing process

Claims (2)

[Claims] 1. A dyeing method using natural dyes of animals and plants, which comprises directly mixing a mordant dye or a flower of a mordant, Yunohana, into a dyeing solution for dyeing. 2. A dyeing method using natural dyes of animals and plants, comprising a first step of directly mixing a flower of a hot water into a dyeing solution, a second step of immersing an object to be dyed in the mixed dyeing solution, and a predetermined step. A dyeing method comprising a third step of immersing the object to be dyed again in a dyeing solution in which hot water is directly mixed with the dyeing solution after washing with water and drying in the air.