JPH0764589B2 - Enamel products - Google Patents
Enamel productsInfo
- Publication number
- JPH0764589B2 JPH0764589B2 JP20883187A JP20883187A JPH0764589B2 JP H0764589 B2 JPH0764589 B2 JP H0764589B2 JP 20883187 A JP20883187 A JP 20883187A JP 20883187 A JP20883187 A JP 20883187A JP H0764589 B2 JPH0764589 B2 JP H0764589B2
- Authority
- JP
- Japan
- Prior art keywords
- glaze
- frit
- parts
- pigment
- stipples
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 210000003298 dental enamel Anatomy 0.000 title claims description 11
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims description 18
- 239000010936 titanium Substances 0.000 claims description 18
- 229910052719 titanium Inorganic materials 0.000 claims description 18
- 239000000049 pigment Substances 0.000 claims description 16
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 12
- 229910052742 iron Inorganic materials 0.000 claims description 6
- 239000003086 colorant Substances 0.000 claims description 3
- 239000004575 stone Substances 0.000 description 9
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 4
- LPXPTNMVRIOKMN-UHFFFAOYSA-M sodium nitrite Chemical compound [Na+].[O-]N=O LPXPTNMVRIOKMN-UHFFFAOYSA-M 0.000 description 4
- 238000005507 spraying Methods 0.000 description 4
- 239000004927 clay Substances 0.000 description 3
- 239000000203 mixture Substances 0.000 description 3
- WCUXLLCKKVVCTQ-UHFFFAOYSA-M Potassium chloride Chemical compound [Cl-].[K+] WCUXLLCKKVVCTQ-UHFFFAOYSA-M 0.000 description 2
- 229910021538 borax Inorganic materials 0.000 description 2
- 238000010304 firing Methods 0.000 description 2
- NROKBHXJSPEDAR-UHFFFAOYSA-M potassium fluoride Chemical compound [F-].[K+] NROKBHXJSPEDAR-UHFFFAOYSA-M 0.000 description 2
- 239000000843 powder Substances 0.000 description 2
- 239000000377 silicon dioxide Substances 0.000 description 2
- 235000010288 sodium nitrite Nutrition 0.000 description 2
- 235000010339 sodium tetraborate Nutrition 0.000 description 2
- 239000004328 sodium tetraborate Substances 0.000 description 2
- 239000012463 white pigment Substances 0.000 description 2
- IRPGOXJVTQTAAN-UHFFFAOYSA-N 2,2,3,3,3-pentafluoropropanal Chemical compound FC(F)(F)C(F)(F)C=O IRPGOXJVTQTAAN-UHFFFAOYSA-N 0.000 description 1
- KLZUFWVZNOTSEM-UHFFFAOYSA-K Aluminum fluoride Inorganic materials F[Al](F)F KLZUFWVZNOTSEM-UHFFFAOYSA-K 0.000 description 1
- 241001122767 Theaceae Species 0.000 description 1
- 239000000440 bentonite Substances 0.000 description 1
- 229910000278 bentonite Inorganic materials 0.000 description 1
- SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical compound O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 description 1
- 229910052570 clay Inorganic materials 0.000 description 1
- 239000006071 cream Substances 0.000 description 1
- 238000005034 decoration Methods 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 235000019225 fermented tea Nutrition 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 238000003801 milling Methods 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 239000001103 potassium chloride Substances 0.000 description 1
- 235000011164 potassium chloride Nutrition 0.000 description 1
- 235000003270 potassium fluoride Nutrition 0.000 description 1
- 239000011698 potassium fluoride Substances 0.000 description 1
- 235000013616 tea Nutrition 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Landscapes
- Glass Compositions (AREA)
Description
【発明の詳細な説明】 （産業上の利用分野） 本発明は自然石のような外観を呈するほうろう製品に関
するものである。DETAILED DESCRIPTION OF THE INVENTION Industrial Field of the Invention The present invention relates to enamel products that have a natural stone-like appearance.
（従来の技術） 自然石のような斑点状の模様を持つほうろう製品は従来
から各種のものが製造されているが、従来は透明フリッ
トにグレー、茶、黒などの顔料を配合した釉薬により鉄
板上にグレー、茶、黒のスティップルを打つとともに、
透明フリットに白色顔料を配合した釉薬又はチタンフリ
ットに白色顔料を配合した釉薬によって白色のスティッ
プルを重ね打ちしたものが普通であった。ところがこの
ような従来品は個々の斑点や境界線が明確に現れるため
に、天然石とはやや異質な感じを与える欠点があった。(Prior Art) Various types of enamel products with spotted patterns such as natural stone have been manufactured so far, but in the past, iron plates were made by glaze with pigments such as gray, brown and black in transparent frit. While striking gray, brown, and black stipple,
It was common to use white glaze with a transparent frit containing a white pigment or titanium glaze with a white pigment overlaid with white stipples. However, such a conventional product has a defect that it gives a feeling slightly different from that of natural stone because individual spots and boundaries are clearly shown.
（発明が解決しようとする問題点） 本発明は上記のような従来の問題点を解決して、極めて
自然石に近い外観を呈するほうろう製品を目的として完
成されたものである。(Problems to be Solved by the Invention) The present invention has been completed with the object of solving the above-mentioned conventional problems and providing an enamel product having an appearance extremely similar to natural stone.
（問題点を解決するための手段） 本発明は鉄板上に形成された下釉層及び上釉層の上面
に、複数色のスティップルが形成されたほうろう製品で
あって、それらのスティップルの少なくとも一種が10〜
60部（重量部、以下同じ）の透明フリットと、40〜70部
のチタンフリットと、０〜20部の顔料とを含む釉薬によ
り形成されており、その他のスティップルは透明フリッ
トと顔料、又はチタンフリットと顔料とを含む釉薬によ
り形成されていることを特徴とするものである。(Means for Solving Problems) The present invention is an enamel product in which stipples of a plurality of colors are formed on upper surfaces of a lower glaze layer and an upper glaze layer formed on an iron plate, and at least one of those stipples. Is 10 ~
It is formed by a glaze containing 60 parts (parts by weight, the same below) of transparent frit, 40 to 70 parts of titanium frit, and 0 to 20 parts of pigment. Other stipples are transparent frit and pigment, or titanium. It is characterized by being formed by a glaze containing a frit and a pigment.
以下に本発明をその製造工程順に説明する。The present invention will be described below in the order of its manufacturing steps.
まず前処理された鉄板上に下釉が施釉され、焼成され
る。下釉としては一般に使用されている下釉用のフリッ
トに粘土、珪石粉、含水硼砂、亜硝酸ソーダ等を加えた
ものを用いればよく、スプレーによって施釉したうえ焼
成されて下釉層が形成される。次に下釉層の上面に上釉
層が形成される。上釉は上釉用のフリットに粘土、ベン
トナイト、塩化カリ、弗化アルミ、弗化カリ、顔料等を
加えたものであり、スプレーによって施釉され末焼成の
状態においてその表面に複数色のスティップルが打たれ
る。スティップルはピンク、うす茶、黒、グレー、黄、
濃茶等に着色された複数種、例えば２〜５種類の釉薬を
重ね打ちしたものであるが、本発明の最大の特色はステ
ィップルの少なくとも一種が10〜60部の透明フリット
と、40〜70部のチタンフリットと、０〜20部の顔料とを
含む釉薬により形成されていることである。このような
透明フリットの組成例を第１表に、白色チタンフリット
の組成例を第２表に、着色チタンフリットの組成例を第
３表に示す。First, a lower glaze is glazed on the pretreated iron plate and fired. As the lower glaze, generally used frit for lower glaze and clay, silica stone powder, hydrated borax, sodium nitrite, etc. may be used, and the lower glaze layer is formed by glaze by spraying and firing It Next, the upper glaze layer is formed on the upper surface of the lower glaze layer. Top glaze is made by adding clay, bentonite, potassium chloride, aluminum fluoride, potassium fluoride, pigment, etc. to the frit for top glaze, and in the state of glaze applied by spraying and in the state of final firing, multiple color stipple is on its surface. Be struck. Stipples are pink, light brown, black, gray, yellow,
Although a plurality of types of glaze such as dark tea, for example, 2 to 5 types of glaze are overlaid, the greatest feature of the present invention is that at least one type of stipples has a transparent frit of 10 to 60 parts and 40 to 70 parts. Part of the titanium frit and 0 to 20 parts of the pigment, which is a glaze. Table 1 shows a composition example of such a transparent frit, Table 2 shows a composition example of white titanium frit, and Table 3 shows a composition example of a colored titanium frit.
また本発明において用いられるその他のスティップルは
これらの表に示されたような透明フリットと顔料、又は
チタンフリットと顔料とを含む釉薬により形成されたも
のであり、これらの複数色のスティップルが上釉層上に
打たれたのち、上釉層とともに焼付けられる。 Further, other stipples used in the present invention are those formed by a glaze containing a transparent frit and a pigment, or a titanium frit and a pigment as shown in these tables, and stipples of a plurality of these colors have an upper glaze. After being struck on the layer, it is baked together with the upper glaze layer.
本発明によれば、透明フリットと顔料又はチタンフリッ
トと顔料とからなる釉薬により形成された境界線が明確
な斑点模様状のスティップルと、透明フリットと、チタ
ンフリットとを所定の比率で含む釉薬により形成された
ぼやけた感じのスティップルとが上釉層上で混ざり合う
ので、従来の境界線が明確なスティップルのみからなる
ほうろう製品に比較して極めて天然石に近い外観を得る
ことができる。なお本発明においてはぼやけた感じのス
ティップルを形成する釉薬中の透明フリットとチタンフ
リットとの比率は重要な意味を持つものである。即ち、
透明フリットの含有量が10部未満であると白色が強く出
すぎ、逆に60部を越すと従来品と同様に境界線がくっき
りと出て本発明に特有のぼやけた感じが表現できなくな
る。同様にチタンフリットの含有量が40部未満では白濁
した自然石の感じが不足し、70部を越えるとやはり境界
線がはっきりと出すぎて本発明に特有の感じが表現でき
なくなる。なお顔料は０〜20部の範囲で加えられるもの
で、顔料をゼロとすれば白濁色が得られるが、20部を越
えると色調が強くなりすぎて自然色のような外観を表現
するにはふさわしくない。According to the present invention, a stipple having a definite speckled pattern formed by a glaze consisting of a transparent frit and a pigment or a titanium frit and a pigment, a transparent frit, and a glaze containing a titanium frit at a predetermined ratio. The formed blurry stipple mixes on the upper glaze layer, resulting in a very natural stone appearance compared to conventional enamel products consisting only of stipple with well-defined boundaries. In the present invention, the ratio of the transparent frit and the titanium frit in the glaze that forms a blurry stipple has an important meaning. That is,
When the content of the transparent frit is less than 10 parts, the white color is too strong, and when it exceeds 60 parts, the boundary line is as sharp as the conventional product, and the blurry feeling peculiar to the present invention cannot be expressed. Similarly, if the content of titanium frit is less than 40 parts, the feeling of cloudy natural stone is insufficient, and if it exceeds 70 parts, the boundary line is too clear and the feeling peculiar to the present invention cannot be expressed. It should be noted that the pigment is added in the range of 0 to 20 parts, and if the pigment is set to zero, a cloudy color can be obtained, but if it exceeds 20 parts, the color tone becomes too strong and the appearance like a natural color is required. not appropriate.
次に本発明の実施例を示す。Next, examples of the present invention will be described.
（実施例） 一般的な下釉用フリット100部に対して粘土７部、珪石
粉５部、含水硼砂0.5部、亜硝酸ソーダ0.3部、水50部を
混合し、粒度５〜8g/200メッシュオン/50gでミル引きし
て下釉を準備し、これを前処理された300mm×300mm×1.
6mmの鉄板の表裏両面にスプレーで施釉して820℃×３分
の焼成を行い下釉層を形成した。(Example) Mixing 7 parts of clay, 5 parts of silica powder, 0.5 part of hydrated borax, 0.3 part of sodium nitrite, and 50 parts of water with 100 parts of a general frit for lower glaze, and a particle size of 5 to 8 g / 200 mesh Prepared a lower glaze by milling on / 50 g and pre-processed this 300 mm × 300 mm × 1.
Both the front and back of a 6 mm iron plate were glazed by spraying and fired at 820 ° C for 3 minutes to form a lower glaze layer.
次に第２表に示したＥ、Ｆ、Ｇの白色チタンフリット及
び第３表に示したＫの着色チタンフリット（クリーム
色）を用い、次の第４表に示される４種類の上釉を準備
し、下釉層が形成された鉄板の片面にそれぞれスプレー
により30〜36/300mm角前後施釉し、上釉層を形成した。Next, using the white titanium frits of E, F, and G shown in Table 2 and the colored titanium frits of K shown in Table 3 (cream color), four types of upper glazes shown in Table 4 below were used. On the one side of the iron plate on which the lower glaze layer was prepared, 30-36 / 300 mm square was glazed by spraying to form an upper glaze layer.
またこれとは別に第５表に示される６色のスティップル
用の釉薬を調合した。 Separately, 6-color glazes for stipples shown in Table 5 were prepared.
上記のスティップル用の釉薬のうち、ピンク、うす茶、
グレー、黄は10〜60部の透明フリットと40〜70部のチタ
ンフリットとを含有しており、また黒と濃茶とは透明フ
リットと顔料とからなるものである。これらの６種類の
スティップル用の釉薬を、第４表に示した実施例１〜実
施例４の上釉層上に次の第６表の組合わせに従ってステ
ィップルガンにより施釉し、820℃×３分焼成した。 Among the above glazes for stipples, pink, light tea,
Gray and yellow contain 10 to 60 parts of transparent frit and 40 to 70 parts of titanium frit, and black and dark brown are composed of transparent frit and pigment. These six types of glazes for stipples were glazed with a stipple gun on the upper glaze layer of Examples 1 to 4 shown in Table 4 according to the combination of the following Table 6, and then at 820 ° C for 3 minutes. Baked.
この結果、透明フリットとチタンフリットとを含むフリ
ットからなるピンク、うす茶、グレー、黄の境界線がぼ
やけた斑点状のスティップルと、透明フリットと顔料の
みからなる境界線の鮮明な黒及び濃茶のスティップルと
が上釉層上で混在し、自然石に極めて近い外観のほうろ
う製品を得ることができた。 As a result, there are spotted stipples in which the borders of pink, light brown, gray, and yellow, which are composed of frit containing transparent frit and titanium frit, are blurred, and clear black and dark brown of the border that is composed only of transparent frit and pigment. Stipple was mixed on the upper glaze layer, and an enamel product with an appearance very close to natural stone could be obtained.
（発明の効果） 本発明は以上の説明からも明らかなように、透明フリッ
トとチタンフリットとを所定の割合で含む釉薬によって
形成されたスティップルを通常のスティップルと組合わ
せることによって、境界線がぼやけた自然石に近い感じ
の模様を持つほうろう製品を得ることに成功したもの
で、特にビルの内装用等に用いれば、自然石を用いた場
合のような質感を生じさせることができる。よって本発
明は従来のこの種ほうろう製品の問題点を解決したもの
として、業界に寄与するところは大である。(Effect of the invention) As is apparent from the above description, the present invention makes it possible to blur a boundary line by combining a stipple formed by a glaze containing a transparent frit and a titanium frit in a predetermined ratio with a normal stipple. It succeeded in obtaining an enamel product having a pattern similar to that of natural stone. Especially when it is used for interior decoration of buildings, etc., it is possible to produce the texture as when using natural stone. Therefore, the present invention greatly contributes to the industry by solving the problems of the conventional enamel products of this type.
Claims (1)
面に、複数色のスティップルが形成されたほうろう製品
であって、それらのスティップルの少なくとも一種が10
〜60部（重量部、以下同じ）の透明フリットと、40〜70
部のチタンフリットと、０〜20部の顔料とを含む釉薬に
より形成されており、その他のスティップルは透明フリ
ットと顔料、又はチタンフリットと顔料とを含む釉薬に
より形成されていることを特徴とするほうろう製品。1. A enamel product in which stipples of a plurality of colors are formed on the upper surfaces of a lower glaze layer and an upper glaze layer formed on an iron plate, and at least one of those stipples is 10
~ 60 parts (weight part, the same below) 40 ~ 70
Part of titanium frit and 0 to 20 parts of a glaze, and other stipples are characterized by being formed of a transparent frit and a pigment, or a titanium frit and a glaze containing a pigment. Enamel product.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP20883187A JPH0764589B2 (en) | 1987-08-21 | 1987-08-21 | Enamel products |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP20883187A JPH0764589B2 (en) | 1987-08-21 | 1987-08-21 | Enamel products |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS6451344A JPS6451344A (en) | 1989-02-27 |
| JPH0764589B2 true JPH0764589B2 (en) | 1995-07-12 |
Family
ID=16562830
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP20883187A Expired - Fee Related JPH0764589B2 (en) | 1987-08-21 | 1987-08-21 | Enamel products |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH0764589B2 (en) |
Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2969592B2 (en) * | 1997-08-27 | 1999-11-02 | 株式会社東京機械製作所 | Ink supply device for keyless printing press |
| JP2010195640A (en) * | 2009-02-26 | 2010-09-09 | Ikebukuro Horo Kogyo Kk | Glass lining composition |
| CN110436962A (en) * | 2019-08-07 | 2019-11-12 | 烟台大学 | A method of making large-scale long-life landscape colored stone |
-
1987
- 1987-08-21 JP JP20883187A patent/JPH0764589B2/en not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| JPS6451344A (en) | 1989-02-27 |
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