JPH0765089B2 - Smelting reduction method and smelting reduction furnace - Google Patents
Smelting reduction method and smelting reduction furnaceInfo
- Publication number
- JPH0765089B2 JPH0765089B2 JP61031890A JP3189086A JPH0765089B2 JP H0765089 B2 JPH0765089 B2 JP H0765089B2 JP 61031890 A JP61031890 A JP 61031890A JP 3189086 A JP3189086 A JP 3189086A JP H0765089 B2 JPH0765089 B2 JP H0765089B2
- Authority
- JP
- Japan
- Prior art keywords
- tuyere
- bath
- furnace
- smelting reduction
- splash
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 238000003723 Smelting Methods 0.000 title claims description 17
- 238000000034 method Methods 0.000 title claims description 10
- 238000002485 combustion reaction Methods 0.000 claims description 18
- 238000007654 immersion Methods 0.000 claims description 4
- 239000002184 metal Substances 0.000 claims 1
- 238000002791 soaking Methods 0.000 claims 1
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 44
- 239000007789 gas Substances 0.000 description 23
- 229910052742 iron Inorganic materials 0.000 description 22
- 238000007664 blowing Methods 0.000 description 12
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 4
- 239000001301 oxygen Substances 0.000 description 4
- 229910052760 oxygen Inorganic materials 0.000 description 4
- 239000002245 particle Substances 0.000 description 4
- 239000002893 slag Substances 0.000 description 3
- 230000008021 deposition Effects 0.000 description 2
- 239000000843 powder Substances 0.000 description 2
- 229910000831 Steel Inorganic materials 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 239000003245 coal Substances 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 239000000498 cooling water Substances 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 230000006866 deterioration Effects 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000003595 mist Substances 0.000 description 1
- 238000011084 recovery Methods 0.000 description 1
- 238000001179 sorption measurement Methods 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21B—MANUFACTURE OF IRON OR STEEL
- C21B13/00—Making spongy iron or liquid steel, by direct processes
- C21B13/0006—Making spongy iron or liquid steel, by direct processes obtaining iron or steel in a molten state
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21B—MANUFACTURE OF IRON OR STEEL
- C21B2100/00—Handling of exhaust gases produced during the manufacture of iron or steel
- C21B2100/60—Process control or energy utilisation in the manufacture of iron or steel
- C21B2100/66—Heat exchange
Landscapes
- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Manufacturing & Machinery (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Carbon Steel Or Casting Steel Manufacturing (AREA)
- Manufacture Of Iron (AREA)
Description
【発明の詳細な説明】 〔産業上の利用分野〕 この発明は転炉あるいは鉄鉱石から直接溶鋼を製造する
溶融還元方法及び溶融還元炉、特に2次燃焼熱の利用の
高効率化に関する。Description: TECHNICAL FIELD The present invention relates to a smelting reduction method and a smelting reduction furnace for directly producing molten steel from a converter or iron ore, and more particularly to improving the efficiency of utilization of secondary combustion heat.
従来、転炉においては上吹きランスから酸素を吹込む上
吹法あるいは炉底に設けた羽口から酸素を吹込む底吹法
が用いられていた。Conventionally, in a converter, a top-blowing method in which oxygen is blown from a top-blowing lance or a bottom-blowing method in which oxygen is blown from tuyere provided at the bottom of the furnace has been used.
しかし、従来の上吹法あるいは底吹法を使用した転炉に
おいては、炉内でCOガスを2次燃焼させた場合その反応
熱を効率良く回収することは困難であるという問題点が
あつた。However, in the conventional converter using the top-blown method or the bottom-blown method, it is difficult to efficiently recover the heat of reaction when the CO gas is secondarily combusted in the furnace. .
これは、転炉内で吹錬中の1次燃焼C+O→COにより発
生するCOガスが鉄浴湯面上方において酸素と反応し、 と2次燃焼を行なつているが、この2次燃焼で発生する
熱の熱媒体として炉体を使うと炉上部の損耗が非常に激
しく、特に(CO2+H2O)/(CO+CO2+H2+H2O)で表は
される2次燃焼比が高くなるとこの傾向が大きく、この
ため2次燃焼熱の熱媒体として炉体を使うことは非実用
的であつた。上記鉄浴湯面は、以下、浴面と呼称する。
なお、該浴面秋戸の呼称容量に基づく基準の浴面位置で
ある。This is because CO gas generated by primary combustion C + O → CO during blowing in the converter reacts with oxygen above the iron bath level. However, if the furnace body is used as the heat transfer medium for the heat generated by this secondary combustion, the upper part of the furnace will be extremely worn, especially (CO 2 + H 2 O) / (CO + CO 2 + H This tendency increases as the secondary combustion ratio represented by ( 2 + H 2 O) increases, and thus it was impractical to use the furnace body as the heat medium for the secondary combustion heat. The iron bath surface is hereinafter referred to as a bath surface.
The reference bath surface position is based on the nominal capacity of the bath surface Akito.
また従来の上吹きランスを使用した転炉においても、上
吹きランスからの酸素ジエツトにより必然的に生成する
スラグと鉄浴のスプラツシユにより、2次燃焼熱のかな
りの部分が鉄浴中に回収されていたが、ランスのノズル
先端でガス膨張が起きることと、浴面をへこませるため
にかなりのガスエネルギを消費してしまうため、スプラ
ツシユの生成量に限界があり、2次燃焼比が高くなり0.
3以上になると着熱効率が低下し、さらにランスを冷却
する冷却水による2次燃焼熱の抜熱が大きく熱回収は不
十分となつていた。Even in a conventional converter using a top-blowing lance, a considerable part of the heat of secondary combustion is recovered in the iron bath due to the slag and the iron bath splash generated by the oxygen jet from the top-blowing lance. However, since gas expansion occurs at the tip of the lance nozzle and considerable gas energy is consumed to dent the bath surface, the amount of splash generated is limited, and the secondary combustion ratio is high. Becomes 0.
When it was 3 or more, the heat-adsorption efficiency decreased, and the secondary combustion heat was largely removed by the cooling water for cooling the lance, resulting in insufficient heat recovery.
このためスプラツシユ生成を目的としたランスや底吹き
羽口を設けてみても、十分な改善が得られなかつた。す
なわち底吹き羽口では鉄浴をかきわけるためにガスのエ
ネルギの大部分を消費してしまうためスプラツシユの生
成量に限界があり、鉄浴への高着熱にも限界があつた。Therefore, even if a lance or a bottom blowing tuyere was provided for the purpose of generating splash, sufficient improvement could not be obtained. That is, the bottom blowing tuyere consumes most of the energy of the gas in order to separate the iron bath, so the amount of splash produced is limited, and the high heat deposition to the iron bath is also limited.
この発明はかかる問題点を解決するためになされたもの
であり、スプラツシユ生成量を増すことにより、2次燃
焼熱を高効率で鉄浴に着熱することができる溶融還元方
法及び溶融還元炉を提供することを目的とするものであ
る。The present invention has been made to solve the above problems, and provides a smelting reduction method and a smelting reduction furnace that can heat secondary combustion heat to an iron bath with high efficiency by increasing the amount of splash generation. It is intended to be provided.
この発明に係る溶融還元方法は、羽口の吹出口の中心位
置から、羽口の中心線が浴面と交わる位置までの距離と
の関係において、特定範囲の距離でスプラッシュを高効
率に生成させることができるという知見に基づいてなさ
れたものであって、転炉あるいは溶融還元炉の浴面下
で、かつ浴面近傍の炉側壁より下記条件が満足する状態
を維持させてガスを吹ひ込み、浴湯をスプラツシユさせ
ることを特徴とする。The smelting reduction method according to the present invention, in relation to the distance from the center position of the outlet of the tuyere to the position where the centerline of the tuyere intersects the bath surface, produces a splash with a high efficiency in a specific range of distance. It was made based on the knowledge that it is possible to blow gas by maintaining the condition below the bath surface of the converter or smelting reduction furnace and from the side wall of the furnace near the bath surface. The feature is that the bath water is splashed.
ここで D;羽口吹出口浸漬深さ Θ;炉側壁に対する羽口角度 d0;羽口内径 またこの発明に係る溶融還元炉は、転炉あるいは溶融還
元炉の浴面下で、かつ浴面近傍の炉側壁に下記条件が設
定できる位置へ上向きにスプラツシユ生成羽口を設けた
ことを特徴とする。 Where D: tuyere outlet immersion depth Θ; tuyere angle to the furnace side wall d 0 ; tuyere inner diameter Further, the smelting reduction furnace according to the present invention is under the bath surface of the converter or the smelting reduction furnace, and It is characterized in that a splash generating tuyere is provided upward on a nearby furnace side wall at a position where the following conditions can be set.
この発明においては、上記条件で操業し、スプラッシュ
をおこなうことにより、また、上記操業条件を設定し得
る位置へ羽口を設けることにより、吹込みガスのガスエ
ネルギをスプラツシユ生成のために有効に活用すること
ができる。すなわち、距離Lがd0より小さい場合は距離
Lが短すぎるため、浴面における吹込ガスのエネルギー
が大きく、そのためにスプラッシュは非常に微細なミス
ト状となり、この生成したスプラッシュの質量が軽いた
め、ほとんどの流滴がガス流れにより炉外へ持し出され
てしまい、鉄浴への着熱効率が悪くなる。逆に距離Lが
100d0以上の場合は距離Lが長すぎて、スプラッシュ生
成用吹込ガスのエネルギーの大部分は浴面を盛上げるの
に使用されるため、スプラッシュ生成量が激減してしま
い、かつ生成したスプラッシュの径が大きすぎて、スプ
ラッシュ単位重量当たりの表面積が低下して受熱効率が
低下することにより、鉄浴への着熱効率が悪くなる。In the present invention, the gas energy of the blown gas is effectively utilized for splash generation by operating under the above conditions and performing the splash, and by providing the tuyere at a position where the above operating conditions can be set. can do. That is, when the distance L is smaller than d 0 , the distance L is too short, the energy of the blowing gas on the bath surface is large, and therefore the splash becomes a very fine mist, and the mass of the generated splash is light, Most of the droplets are carried out of the furnace due to the gas flow, and the heat deposition efficiency on the iron bath deteriorates. Conversely, the distance L is
In the case of 100d 0 or more, the distance L is too long, and most of the energy of the blowing gas for splash generation is used to raise the bath surface, so the amount of splash generation is drastically reduced, and the amount of splash generated Since the diameter is too large, the surface area per unit weight of the splash is reduced and the heat receiving efficiency is reduced, so that the heat transfer efficiency to the iron bath is deteriorated.
第1図はこの発明の一実施例を示す断面図であり、図に
おいて1は転炉、2は転炉1内の鉄浴、3は転戸1の炉
側壁に設けられた羽口、4は鉄浴2の浴面上に形成され
たスラグ層、5は鉄浴2の浴面上方に形成された2次燃
焼帯である。FIG. 1 is a cross-sectional view showing an embodiment of the present invention, in which 1 is a converter, 2 is an iron bath in the converter 1, 3 is tuyere provided on the side wall of the door 1 of the converter, 4 Is a slag layer formed on the bath surface of the iron bath 2, and 5 is a secondary combustion zone formed above the bath surface of the iron bath 2.
羽口3は第2図の部分詳細図に示すように、鉄浴2の浴
面下で、浴面2aに対して の条件を満足するように設けられている。ここでDは鉄
浴2の浴面2aから羽口3の吹出口中心位置7までの深
さ、すなわち羽口吹出口浸漬深さを示し、Θは炉側壁に
対する羽口角度、d0は羽口3の内径である。The tuyere 3 is under the bath surface of the iron bath 2 as shown in the partial detailed view of FIG. It is provided so as to satisfy the condition of. Here, D represents the depth from the bath surface 2a of the iron bath 2 to the blowhole center position 7 of the tuyere 3, that is, the tuyere outlet immersion depth, Θ is the tuyere angle with respect to the furnace side wall, and d 0 is the wing The inner diameter of the mouth 3.
上記(1)式の条件においてD/cosΘは羽口3の吹出口の中
心位置7から羽口3の中心線8が浴面2aと交わる位置9
までの距離Lを表わし、この距離Lが上記(1)式の条件
に入るように羽口3を設けることにより良好なスプラツ
シユが得られることを、この発明の発明者は見出した。Under the condition of the above formula (1), D / cos Θ is from the center position 7 of the outlet of the tuyere 3 to the position 9 where the center line 8 of the tuyere 3 intersects with the bath surface 2a.
The inventor of the present invention has found that a good splash can be obtained by providing the tuyere 3 so that the distance L can be expressed by the condition (1).
すなわち、吹込ガス量、ガス圧力一定のもとで羽口3の
角度Θ及び羽口吹出口浸漬深さDを種々変更して、スラ
グと鉄浴のスプラツシユ生成量を調べた結果第3図に示
すスプラツシユ生成量特性が得られた。第3図は横軸に
D/d0cosΘをとり、縦軸にスプラツシユ重量W(ton/H)
と鉄浴重量W0(ton)との比をとりスプラツシユ生成量
を示したものであり、斜線で示した範囲Aでスプラツシ
ユ生成量を表わす。That is, the angle Θ of the tuyere 3 and the tuyere outlet immersion depth D were variously changed under a constant amount of gas and gas pressure, and the amount of slag and iron bath splash generated was investigated. The following characteristics of the amount of splash production were obtained. Figure 3 is on the horizontal axis
D / d 0 cos Θ is taken and the vertical axis is the weight of the splash W (ton / H)
The iron bath is limited to showing weight W 0 (ton) taking the ratio of the Supuratsushiyu generation amount represents the Supuratsushiyu generation amount in the range A shown by oblique lines.
第3図に示すようにD/d0cosΘが1から100の範囲で良好
なスプラツシユを生成している。D/d0cosΘ1の場合
すなわち距離LがLd8の場合は浴面2における吹込ガ
スのエネルギが大きく、非常に微細なミスト状例えば粒
径が0.1mm以下の流滴が生成し、流滴の重量が軽く、そ
のためほとんどの流滴がガスの流れにより炉外へ持出さ
れてしまうため熱交換に有効なスプラツシユ生成量が少
なくなつている。逆にD/d0cosΘ≧100すなわち距離Lが
L≧100d0の場合には吹込ガスのエネルギの大部分は浴
面2aを盛上げるのに使用されるためにスプラツシユ生成
量は激減してしまう。また生成スプラツシユの径がかな
り大きくなり、スプラツシユ単位重量当りの表面積も小
さくなつてしまう。従って、製錬の進行目に伴って上昇
する浴面位置が前記条件を超えたらば、当然出湯して浴
面位置を降下させる。As shown in FIG. 3, a good splash is generated when D / d 0 cos Θ is in the range of 1 to 100. When D / d 0 cos Θ1, that is, when the distance L is Ld 8 , the energy of the blown gas on the bath surface 2 is large, and very fine mist-like droplets with a particle size of 0.1 mm or less are generated. Since the weight is light and most of the droplets are carried out of the furnace by the gas flow, the amount of splash generated that is effective for heat exchange is small. On the other hand, when D / d 0 cos Θ ≧ 100, that is, when the distance L is L ≧ 100d 0 , most of the energy of the blown gas is used to raise the bath surface 2a, and the amount of splash generation is drastically reduced. . Further, the diameter of the generated splash is considerably large, and the surface area per unit weight of the splash is also reduced. Therefore, if the bath surface position, which rises with the progress of smelting, exceeds the above condition, the bath surface position is naturally lowered to lower the bath surface position.
しかしD/d0cosΘが1から100までの範囲すなわち距離L
がd0<L<100d0の範囲においては、吹込ガスのスプラ
ツシユ生成のために必要なエネルギの損失が小さく、ス
プラツシユ生成量が大となり、かつ粒径も熱交換を効率
的に進めうる表面積で、かつガス流れに抗し運動,落下
する程度に大きくなる。この粒径が大で生成量も多いス
プラツシユを2次燃焼帯に吹込むことができるから、こ
のスプラツシユを熱媒体として2次燃焼熱を鉄浴2へ伝
えることができる。However, D / d 0 cos Θ is in the range of 1 to 100, that is, the distance L
In the range of d 0 <L <100d 0 , the energy loss required to generate the splash of the blown gas is small, the amount of splash generated is large, and the particle size is the surface area that can efficiently promote heat exchange. It also becomes large enough to move and fall against the gas flow. Since the splash having a large particle size and a large amount can be blown into the secondary combustion zone, the secondary combustion heat can be transferred to the iron bath 2 by using the splash as a heat medium.
また、溶融還元方法においては、ガス流量を変えれば当
然スプラツシユ生成量が変化するが、実際に0.01〜3Nm3
/min/ton程度の範囲ではこの発用のように とすることが必要である。すなわち羽口よりガスのみな
らず粉体を吹込むことにより、さらに熱交換効率を高め
うる。これは粉体の運動エネルギが大きいため、スプラ
ツシユ流速が大きくなり熱交換が円滑に行なわれるとと
もに、スプラツシユ生成量もガスのみよりも増加するた
めである。In addition, in the smelting reduction method, the amount of splash generated naturally changes when the gas flow rate is changed.
In the range of / min / ton It is necessary to That is, by blowing not only the gas but also the powder from the tuyere, the heat exchange efficiency can be further enhanced. This is because the kinetic energy of the powder is large, the flow velocity of the splash is high, the heat exchange is smoothly performed, and the amount of the splash generated is larger than that of the gas alone.
この発明は以上説明したように転炉あるいは溶融還元炉
を、浴面における吹込ガスのエネルギーが大きく、生成
するスプラッシュの質量が軽く、ほとんどの流滴がガス
流れにより炉外へ持ち出されてしまい、鉄浴への着熱効
率が悪くなるを除外できる最適な条件で操業し、また、
該スプラッシュ生成が最適である操業条件を設定し得る
位置へ羽口を設けることにより、粒径が比較的大きく最
適範囲にあり生成量も多いスプラツシユを2次燃焼帯に
吹込むことができるから2次燃焼熱を高効率で鉄浴中に
回収することができる。したがつて石炭原単位(kg/ton
鉄)を大幅に減少することができると共に2次燃焼によ
る炉耐火物の損傷を防止することができる効果も有す
る。This invention, as described above, the converter or the smelting reduction furnace, the energy of the blowing gas on the bath surface is large, the mass of the splash generated is light, most of the droplets are taken out of the furnace by the gas flow, Operate under optimal conditions that can eliminate the deterioration of heat transfer efficiency to the iron bath, and
By providing the tuyere at a position where the operating condition where the splash generation is optimum can be set, it is possible to blow the splashes having a relatively large particle size in the optimum range and a large amount of generation into the secondary combustion zone. The heat of secondary combustion can be recovered in the iron bath with high efficiency. Therefore, coal basic unit (kg / ton
(Iron) can be greatly reduced and damage to the furnace refractory due to secondary combustion can be prevented.
第1図はこの発明の実施例を示す断面図、第2図は上記
実施例の羽口部を示す部分詳細図、第3図はスプラツシ
ユ生成量特性図である。 1……転炉、2……鉄浴、2a……浴面、3……羽口、5
……2次燃焼帯。FIG. 1 is a sectional view showing an embodiment of the present invention, FIG. 2 is a partial detailed view showing a tuyere portion of the above embodiment, and FIG. 3 is a splash generation amount characteristic diagram. 1 ... Converter, 2 ... Iron bath, 2a ... Bath surface, 3 ... Tuyere, 5
...... Secondary combustion zone.
Claims (2)
る2次燃焼帯を形成する転炉あるいは溶融還元炉におい
て、浴面下でかつ浴面近傍の炉側壁より ここでD ;羽口吹出口浸漬深さ Θ ;炉側壁に対する羽口角度 d0;羽口内径 なる条件が満足する状態を維持させてガスを吹き込み、
溶湯をスプラッシュさせることを特徴とする溶融還元方
法。1. A converter or smelting reduction furnace that forms a secondary combustion zone in which CO gas emitted from a bath is burned on the bath, below the bath surface and from a furnace side wall near the bath surface. Where D is the tuyere outlet immersion depth Θ is the tuyere angle with respect to the furnace side wall d 0 is the tuyere inner diameter
A smelting reduction method characterized by splashing molten metal.
る2次燃焼帯を形成する転炉あるいは溶融還元炉におい
て、浴面下でかつ浴面近傍の炉側壁にスプラッシュ生成
羽口を ここでD ;羽口吹出口浸漬深さ Θ ;炉側壁に対する羽口角度 d0;羽口内径 なる条件が満足できる位置へ、上向きに設けたことを特
徴とする溶融還元炉。2. In a converter or smelting reduction furnace that forms a secondary combustion zone in which CO gas emitted from the bath is burned on the bath, splash-forming tuyere under the bath surface and on the side wall of the furnace near the bath surface. To Here, D is the soaking depth of the tuyere outlet Θ; Tuyere angle to the furnace side wall d 0 ; Tuyere inner diameter The smelting reduction furnace is installed upward at a position that satisfies the conditions.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP61031890A JPH0765089B2 (en) | 1986-02-18 | 1986-02-18 | Smelting reduction method and smelting reduction furnace |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP61031890A JPH0765089B2 (en) | 1986-02-18 | 1986-02-18 | Smelting reduction method and smelting reduction furnace |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS62192514A JPS62192514A (en) | 1987-08-24 |
| JPH0765089B2 true JPH0765089B2 (en) | 1995-07-12 |
Family
ID=12343625
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP61031890A Expired - Lifetime JPH0765089B2 (en) | 1986-02-18 | 1986-02-18 | Smelting reduction method and smelting reduction furnace |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH0765089B2 (en) |
Family Cites Families (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH06102808B2 (en) * | 1986-02-14 | 1994-12-14 | 日本鋼管株式会社 | Melt reduction method |
-
1986
- 1986-02-18 JP JP61031890A patent/JPH0765089B2/en not_active Expired - Lifetime
Also Published As
| Publication number | Publication date |
|---|---|
| JPS62192514A (en) | 1987-08-24 |
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