JPH0789825B2 - Improved flour - Google Patents
Improved flourInfo
- Publication number
- JPH0789825B2 JPH0789825B2 JP62201182A JP20118287A JPH0789825B2 JP H0789825 B2 JPH0789825 B2 JP H0789825B2 JP 62201182 A JP62201182 A JP 62201182A JP 20118287 A JP20118287 A JP 20118287A JP H0789825 B2 JPH0789825 B2 JP H0789825B2
- Authority
- JP
- Japan
- Prior art keywords
- wheat flour
- flour
- triglyceride
- improved
- mixed
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 235000013312 flour Nutrition 0.000 title claims description 40
- 241000209140 Triticum Species 0.000 claims description 29
- 235000021307 Triticum Nutrition 0.000 claims description 29
- UFTFJSFQGQCHQW-UHFFFAOYSA-N triformin Chemical compound O=COCC(OC=O)COC=O UFTFJSFQGQCHQW-UHFFFAOYSA-N 0.000 claims description 12
- 150000003626 triacylglycerols Chemical class 0.000 claims description 6
- DCXXMTOCNZCJGO-UHFFFAOYSA-N tristearoylglycerol Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCC(OC(=O)CCCCCCCCCCCCCCCCC)COC(=O)CCCCCCCCCCCCCCCCC DCXXMTOCNZCJGO-UHFFFAOYSA-N 0.000 description 10
- 230000000052 comparative effect Effects 0.000 description 7
- 235000009508 confectionery Nutrition 0.000 description 6
- 238000000034 method Methods 0.000 description 5
- 239000000203 mixture Substances 0.000 description 5
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 5
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 4
- PVNIQBQSYATKKL-UHFFFAOYSA-N tripalmitin Chemical compound CCCCCCCCCCCCCCCC(=O)OCC(OC(=O)CCCCCCCCCCCCCCC)COC(=O)CCCCCCCCCCCCCCC PVNIQBQSYATKKL-UHFFFAOYSA-N 0.000 description 4
- 244000068988 Glycine max Species 0.000 description 3
- 235000010469 Glycine max Nutrition 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 239000003921 oil Substances 0.000 description 3
- 235000019198 oils Nutrition 0.000 description 3
- 239000011248 coating agent Substances 0.000 description 2
- 238000000576 coating method Methods 0.000 description 2
- 235000014113 dietary fatty acids Nutrition 0.000 description 2
- 235000013601 eggs Nutrition 0.000 description 2
- 229930195729 fatty acid Natural products 0.000 description 2
- 239000000194 fatty acid Substances 0.000 description 2
- 230000005484 gravity Effects 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- 239000011088 parchment paper Substances 0.000 description 2
- 239000002994 raw material Substances 0.000 description 2
- 150000004671 saturated fatty acids Chemical class 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- 239000003549 soybean oil Substances 0.000 description 2
- 235000012424 soybean oil Nutrition 0.000 description 2
- 238000005507 spraying Methods 0.000 description 2
- 229960001947 tripalmitin Drugs 0.000 description 2
- LDVVTQMJQSCDMK-UHFFFAOYSA-N 1,3-dihydroxypropan-2-yl formate Chemical compound OCC(CO)OC=O LDVVTQMJQSCDMK-UHFFFAOYSA-N 0.000 description 1
- VBICKXHEKHSIBG-UHFFFAOYSA-N 1-monostearoylglycerol Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCC(O)CO VBICKXHEKHSIBG-UHFFFAOYSA-N 0.000 description 1
- DEXFNLNNUZKHNO-UHFFFAOYSA-N 6-[3-[4-[2-(2,3-dihydro-1H-inden-2-ylamino)pyrimidin-5-yl]piperidin-1-yl]-3-oxopropyl]-3H-1,3-benzoxazol-2-one Chemical compound C1C(CC2=CC=CC=C12)NC1=NC=C(C=N1)C1CCN(CC1)C(CCC1=CC2=C(NC(O2)=O)C=C1)=O DEXFNLNNUZKHNO-UHFFFAOYSA-N 0.000 description 1
- ZCYVEMRRCGMTRW-UHFFFAOYSA-N 7553-56-2 Chemical compound [I] ZCYVEMRRCGMTRW-UHFFFAOYSA-N 0.000 description 1
- UEZVMMHDMIWARA-UHFFFAOYSA-N Metaphosphoric acid Chemical compound OP(=O)=O UEZVMMHDMIWARA-UHFFFAOYSA-N 0.000 description 1
- 229910019142 PO4 Inorganic materials 0.000 description 1
- 235000019482 Palm oil Nutrition 0.000 description 1
- 229930006000 Sucrose Natural products 0.000 description 1
- BAECOWNUKCLBPZ-HIUWNOOHSA-N Triolein Natural products O([C@H](OCC(=O)CCCCCCC/C=C\CCCCCCCC)COC(=O)CCCCCCC/C=C\CCCCCCCC)C(=O)CCCCCCC/C=C\CCCCCCCC BAECOWNUKCLBPZ-HIUWNOOHSA-N 0.000 description 1
- PHYFQTYBJUILEZ-UHFFFAOYSA-N Trioleoylglycerol Natural products CCCCCCCCC=CCCCCCCCC(=O)OCC(OC(=O)CCCCCCCC=CCCCCCCCC)COC(=O)CCCCCCCC=CCCCCCCCC PHYFQTYBJUILEZ-UHFFFAOYSA-N 0.000 description 1
- YDHWWBZFRZWVHO-UHFFFAOYSA-N [hydroxy(phosphonooxy)phosphoryl] phosphono hydrogen phosphate Chemical compound OP(O)(=O)OP(O)(=O)OP(O)(=O)OP(O)(O)=O YDHWWBZFRZWVHO-UHFFFAOYSA-N 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 125000004432 carbon atom Chemical group C* 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000010924 continuous production Methods 0.000 description 1
- XPPKVPWEQAFLFU-UHFFFAOYSA-N diphosphoric acid Chemical compound OP(O)(=O)OP(O)(O)=O XPPKVPWEQAFLFU-UHFFFAOYSA-N 0.000 description 1
- 239000003995 emulsifying agent Substances 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 125000005313 fatty acid group Chemical group 0.000 description 1
- 150000004665 fatty acids Chemical class 0.000 description 1
- 238000005187 foaming Methods 0.000 description 1
- 238000001879 gelation Methods 0.000 description 1
- 239000008173 hydrogenated soybean oil Substances 0.000 description 1
- 239000008172 hydrogenated vegetable oil Substances 0.000 description 1
- 229910052740 iodine Inorganic materials 0.000 description 1
- 239000011630 iodine Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 230000010534 mechanism of action Effects 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 239000002540 palm oil Substances 0.000 description 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 1
- 239000010452 phosphate Substances 0.000 description 1
- 229920000137 polyphosphoric acid Polymers 0.000 description 1
- 229940005657 pyrophosphoric acid Drugs 0.000 description 1
- 239000004576 sand Substances 0.000 description 1
- 235000011888 snacks Nutrition 0.000 description 1
- 235000019830 sodium polyphosphate Nutrition 0.000 description 1
- 239000005720 sucrose Substances 0.000 description 1
- -1 sucrose fatty acid ester Chemical class 0.000 description 1
- 238000004381 surface treatment Methods 0.000 description 1
- PHYFQTYBJUILEZ-IUPFWZBJSA-N triolein Chemical compound CCCCCCCC\C=C/CCCCCCCC(=O)OCC(OC(=O)CCCCCCC\C=C/CCCCCCCC)COC(=O)CCCCCCC\C=C/CCCCCCCC PHYFQTYBJUILEZ-IUPFWZBJSA-N 0.000 description 1
- 229940117972 triolein Drugs 0.000 description 1
Landscapes
- Cereal-Derived Products (AREA)
- Bakery Products And Manufacturing Methods Therefor (AREA)
Description
【発明の詳細な説明】 〔産業上の利用分野〕 本発明は製菓特性の優れた改良小麦粉、更に詳細には、
焼成後の沈みが少なく、しかも優れた食感とボリユーム
をもつケーキ類を製造することのできる改良小麦粉に関
する。DETAILED DESCRIPTION OF THE INVENTION [Industrial field of application] The present invention provides improved wheat flour having excellent confectionery properties, and more specifically,
The present invention relates to an improved wheat flour which is capable of producing cakes having a low texture after baking and having an excellent texture and volume.
従来、焼成後の沈みがなく、しかも優れた食感とボリュ
ームをもつスポンジケーキ、カステラ等の菓子類を得る
ための多くの研究がなされており、例えば、原料とし
て高温熱処理又は塩素処理した小麦粉を使用する方法、
飽和脂肪酸又はそのモノグリセリドを添加し酸素の存
在下に加熱処理した小麦粉を使用する方法(特公昭51−
38776号)、焼成直後の菓子類にシヨツクを与える方
法等が報告されている。Conventionally, there is no sinking after baking, and many studies have been conducted to obtain confectionery such as sponge cakes and castellas having an excellent texture and volume, and for example, high-temperature heat-treated or chlorinated wheat flour is used as a raw material. How to use,
Method of using wheat flour which has been heat-treated in the presence of oxygen by adding saturated fatty acid or its monoglyceride (Japanese Patent Publication No. 51-
No. 38776), a method of giving a snack to sweets immediately after baking has been reported.
しかしながら、の方法は、焼成後の沈みは防止される
が、菓子類の体積が小さくなり、内相、食感が悪くなる
という欠点があり、の方法は、高温で長時間処理しな
ければならないので、余分な工程と設備を必要とし、更
に菓子類の体積が小さくなるという欠点があり、また
の方法は、連続生産の際に特殊な装置が必要となるとい
う欠点があり、何れの従来法も充分に満足し得るもので
はなかつた。However, although the method of (1) can prevent the sinking after baking, it has the drawback that the volume of the confectionery becomes small and the internal phase and texture become poor. Therefore, the method of (2) must be treated at a high temperature for a long time. Therefore, there is a drawback that extra steps and equipment are required and the volume of the confectionery is further reduced, and the other method has a drawback that a special device is required in continuous production. It wasn't entirely satisfactory.
斯かる実状において、本発明者は、上記欠点を解決せん
と鋭意研究を行つた結果、極性の高いトリグリセリドで
表面処理した小麦粉を原料として使用すれば焼成後の沈
みがなく、しかも優れた食感とボリユームをもつケーキ
類を製造できることを見出し、本発明を完成した。In such an actual situation, the present inventor has conducted diligent research to solve the above-mentioned drawbacks, and when wheat flour surface-treated with highly polar triglyceride is used as a raw material, there is no sinking after baking, and an excellent texture is obtained. The present invention has been completed by discovering that cakes having the following formula can be produced.
すなわち、本発明は、飽和トリグリセリドを80%以上含
むトリグリセリドを小麦粉に対して0.02〜1.0重量%
(以下%で示す)用いて、小麦粉表面を処理した改良小
麦粉を提供するものである。That is, the present invention, triglyceride containing 80% or more saturated triglyceride 0.02 to 1.0 wt% with respect to the flour
(Hereinafter, indicated in%) to provide an improved wheat flour having the surface of the wheat flour treated.
本発明において小麦粉としては何れのものも使用できる
が、その中でも薄力粉が特に好ましい。In the present invention, any wheat flour can be used, but soft flour is particularly preferable.
トリグリセリドは、その脂肪酸基が飽和脂肪酸によつて
構成される飽和トリグリセリドを80%以上含むことが必
要であり、不飽和トリグリセリドが20%を超えるトリグ
リセリドでは本発明の目的は達成されない。また当該飽
和トリグリセリドの脂肪酸は炭素数16以上のものが好ま
しい。斯かるトリグリセリドとしては、例えば、トリス
テアリン、トリパルミチン、1−パルミトジステアリ
ン、2−ステアロジパルミチン、1−ステアロ−2−ミ
リスト−パルミチン、大豆油もしくはパーム油等の植物
油を水素添加処理して硬化させたものなどが挙げられ
る。The triglyceride needs to contain 80% or more of saturated triglyceride whose fatty acid group is constituted by a saturated fatty acid, and the object of the present invention cannot be achieved with a triglyceride in which unsaturated triglyceride exceeds 20%. The fatty acid of the saturated triglyceride preferably has 16 or more carbon atoms. Examples of such triglycerides include hydrogenated vegetable oils such as tristearin, tripalmitin, 1-palmitodistearin, 2-stearodipalmitin, 1-stearo-2-myristo-palmitin, soybean oil or palm oil. Examples include cured products.
小麦粉のトリグリセリドによる表面処理は、例えば、ト
リグリセリドを加熱溶融するかエタノール等の溶剤に溶
解したものを小麦粉に添加又は噴霧して混合し、小麦粉
表面にトリグリセリドを付着ないしコーテイングするこ
とによつて行われる。トリグリセリドの付着ないしコー
テイング量は、小麦粉に対し0.02〜1.0%(重量)、特
に0.03〜0.1%が好ましく、このより少ないと本発明の
効果が不充分であり、また1.0%を超えるとボリユーム
が得られなくなる。Surface treatment of wheat flour with triglyceride is carried out, for example, by heating or melting triglyceride or dissolving it in a solvent such as ethanol and mixing it by adding or spraying to the flour, and adhering or coating the triglyceride on the flour surface. . The amount of triglyceride attached or coated is preferably 0.02 to 1.0% (weight), particularly 0.03 to 0.1%, relative to the wheat flour, and if it is less than this, the effect of the present invention is insufficient, and if it exceeds 1.0%, vorium is obtained. I will not be able to.
斯くして表面処理さた小麦粉を冷却するか又は溶剤を除
去すれば本発明の改良小麦粉が得られる。Thus, the wheat flour surface-treated is cooled or the solvent is removed to obtain the improved wheat flour of the present invention.
尚本発明において、リン酸塩(メタリン酸、ピロリン
酸、テトラリン酸、ポリリン酸)、シヨ糖脂肪酸エステ
ル糖の乳化剤を小麦粉に対し0.3〜1.0%添加すると起泡
安定性が向上したものが得られる。Incidentally, in the present invention, phosphate (metaphosphoric acid, pyrophosphoric acid, tetraphosphoric acid, polyphosphoric acid), the addition of 0.3-1.0% of emulsifier of sucrose fatty acid ester sugar to wheat flour gives improved foaming stability. .
本発明の改良小麦粉は、これを用いて菓子類を製造する
と焼成後の沈みがなく、優れた食感とボリユームを有す
るものが得られるという優れた効果を有する。The improved wheat flour of the present invention has an excellent effect that when a confectionery product is produced using the wheat flour, there is no sink after baking, and a product having an excellent texture and volume is obtained.
この作用機序の詳細は必ずしも明らかでないが、トリグ
リセリドが小麦粉表面の極性を改質し、ゲル化時間を早
めることによるものと推測される。The details of this mechanism of action are not necessarily clear, but it is presumed that triglyceride modifies the polarity of the flour surface and accelerates gelation time.
次に実施例を挙げて説明する。 Next, examples will be described.
実施例1 薄力小麦粉(水分14%)とトリステアリンを第1表に示
す比率で混合してフアリノミキサー(ブラベンダー社
製)に入れ、80℃に加温し、5分間混合した。次いでこ
れを取り出し、室温まで冷却して表面処理小麦粉を得
た。Example 1 Light wheat flour (water content 14%) and tristearin were mixed in the ratio shown in Table 1 and placed in a Farino mixer (manufactured by Brabender), heated to 80 ° C. and mixed for 5 minutes. Then, this was taken out and cooled to room temperature to obtain surface-treated wheat flour.
実施例2 薄力小麦粉(水分14%)3Kgに、大豆硬化油1.5gをエタ
ノール500mlに溶かしたものを噴霧しながら、フローコ
ーター(西独グラツト社製)により40℃の雰囲気中でフ
ローコーテイングを行い、改良小麦粉(発明品6)を得
た。 Example 2 While spraying 3 kg of light wheat flour (water content 14%) with 1.5 g of soybean hydrogenated oil dissolved in 500 ml of ethanol, flow coating was performed in an atmosphere of 40 ° C. by a flow coater (manufactured by Grad Co., Ltd., West Germany). , Improved wheat flour (invention product 6) was obtained.
実施例3 実施例2の大豆硬化油の代りにトリパルミチン1.5gを用
いる以外は同様に操作して改良小麦粉(発明品7)を得
た。Example 3 Improved wheat flour (Invention Product 7) was obtained in the same manner as in Example 2 except that 1.5 g of tripalmitin was used in place of the hydrogenated soybean oil.
実施例4 実施例2で得た改良小麦粉にポリリン酸ナトリウムを0.
5%添加混合し、改良小麦粉(発明品8)を得た。Example 4 Sodium polyphosphate was added to the improved wheat flour obtained in Example 2
5% was added and mixed to obtain improved wheat flour (Invention product 8).
比較例 次の如くして比較品4〜7を製造した。Comparative Example Comparative products 4 to 7 were manufactured as follows.
比較品4: 薄力小麦粉(実施例1と同じ)300gとトリステアリン0.
3gを加温することなく単に混合したもの。Comparative product 4: 300 g light wheat flour (same as in Example 1) and tristearin.
Simply mixed without heating 3g.
比較品5: 薄力小麦粉(実施例1と同じ)300gをフアリノミキサー
で80℃にて5分間加熱した後室温に冷却し、これにトリ
ステアリン0.3gを混合したもの。Comparative product 5: 300 g of light wheat flour (same as that in Example 1) was heated with a Farino mixer at 80 ° C. for 5 minutes and then cooled to room temperature, and 0.3 g of tristearin was mixed therein.
比較品6: 実施例2の大豆硬化油の代りにモノステアリン1.5gを使
用する以外は同様に操作して得た小麦粉。Comparative product 6: Wheat flour obtained in the same manner except that 1.5 g of monostearin was used in place of the soybean hydrogenated oil of Example 2.
比較品7: 実施例2の大豆硬化油の代りに大豆油(ヨウ素価127〜1
41)1.5gを使用する以外は同様に操作して得た小麦粉。Comparative product 7: Soybean oil (iodine number 127 to 1 in place of the soybean hydrogenated oil of Example 2)
41) Wheat flour obtained in the same manner except that 1.5 g was used.
試験例1 発明品1〜8及び比較品1〜7を用いてスポンジケーキ
を製造し、そのスポンジケーキについて沈み、体積、内
相、食感を調べた。その結果を第2表に示す。Test Example 1 Sponge cakes were produced using invention products 1 to 8 and comparative products 1 to 7, and the sponge cakes were examined for sinking, volume, internal phase, and texture. The results are shown in Table 2.
〈配合〉 小麦粉 100g 砂 糖 100g 全 卵(正味) 100g 水 40ml 〈製造法〉 全卵をボールに入れ、ホイツパーを用いてよく混合し、
砂糖を加え、30℃にてミキサーを用いて高速(240rpm)
で8〜9分間泡立て、水20mlを加えて高速で2分間泡立
てた。これに水20mlを加え、高速で2分間、次いで中速
(120rpm)で1分間泡立を行つてケーキ種を得た。ケー
キ種の比重を30℃で0.25±0.01になるように調整してボ
ールに入れ、これに小麦粉を加え60回混合した。粉合せ
は短時間に行い、しやもじでまぜ合せて生地の比重が0.
45±0.01になるようにした。焼成型の底と内側にパーチ
メント紙を敷き、これに生地を入れ、表面をならした
後、オーブンで190℃にて30分間焼成し、焼成後直ちに
型から取り出して室温まで冷却した。<Compound> Wheat flour 100g Sand sugar 100g Whole egg (net) 100g Water 40ml <Manufacturing method> Put all eggs in a bowl and mix well using a whipping machine,
Add sugar and use mixer at 30 ℃ for high speed (240 rpm)
For 8 to 9 minutes, 20 ml of water was added, and the mixture was whipped at high speed for 2 minutes. 20 ml of water was added thereto, and the mixture was bubbled at a high speed for 2 minutes and then at a medium speed (120 rpm) for 1 minute to obtain a cake seed. The specific gravity of the cake type was adjusted to 0.25 ± 0.01 at 30 ° C., put into a bowl, and flour was added to this and mixed 60 times. The dough is mixed in a short time and mixed with shijimoji so that the specific gravity of the dough is 0.
It was set to 45 ± 0.01. Parchment paper was laid on the bottom and inside of the baking mold, the dough was put into the baking paper, the surface was leveled, and baked in an oven at 190 ° C. for 30 minutes. Immediately after baking, the mold was taken out and cooled to room temperature.
実施例5 トリステアリンにトリオレインを20、40、60及び80%に
なるように混合しトリグリセリド混合物を調製した。薄
力小麦粉(実施例1と同じ)にトリグリセリド混合物を
0.1%混合し、実施例1と同様に操作して表明処理小麦
粉を得た。 Example 5 Tristearin was mixed with triolein in an amount of 20, 40, 60 and 80% to prepare a triglyceride mixture. Light flour (same as in Example 1) with triglyceride mixture
0.1% was mixed and the same operation as in Example 1 was carried out to obtain an expression-treated wheat flour.
試験例2 実施例5で得た小麦粉を用いて試験例1と同様にしてス
ポンジケーキを製造し、その沈み、体積、内相、食感を
調べた。その結果を第3表に示す。Test Example 2 Using the flour obtained in Example 5, a sponge cake was produced in the same manner as in Test Example 1, and its sink, volume, internal phase, and texture were examined. The results are shown in Table 3.
Claims (1)
リセリドを小麦粉に対して0.02〜1.0重量%用いて、小
麦粉表面を処理した改良小麦粉。1. Improved wheat flour in which the surface of the flour is treated with 0.02 to 1.0% by weight of triglyceride containing 80% or more of saturated triglyceride with respect to the flour.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP62201182A JPH0789825B2 (en) | 1987-08-12 | 1987-08-12 | Improved flour |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP62201182A JPH0789825B2 (en) | 1987-08-12 | 1987-08-12 | Improved flour |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS6443146A JPS6443146A (en) | 1989-02-15 |
| JPH0789825B2 true JPH0789825B2 (en) | 1995-10-04 |
Family
ID=16436705
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP62201182A Expired - Fee Related JPH0789825B2 (en) | 1987-08-12 | 1987-08-12 | Improved flour |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH0789825B2 (en) |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP6812290B2 (en) * | 2017-03-30 | 2021-01-13 | 日清フーズ株式会社 | Method for producing flour composition |
-
1987
- 1987-08-12 JP JP62201182A patent/JPH0789825B2/en not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| JPS6443146A (en) | 1989-02-15 |
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| Date | Code | Title | Description |
|---|---|---|---|
| LAPS | Cancellation because of no payment of annual fees |