JPH0789879B2 - A safe and long-term storable rice production method - Google Patents
A safe and long-term storable rice production methodInfo
- Publication number
- JPH0789879B2 JPH0789879B2 JP3359252A JP35925291A JPH0789879B2 JP H0789879 B2 JPH0789879 B2 JP H0789879B2 JP 3359252 A JP3359252 A JP 3359252A JP 35925291 A JP35925291 A JP 35925291A JP H0789879 B2 JPH0789879 B2 JP H0789879B2
- Authority
- JP
- Japan
- Prior art keywords
- rice
- acid
- cooked
- water
- cooking
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 235000007164 Oryza sativa Nutrition 0.000 title claims description 177
- 235000009566 rice Nutrition 0.000 title claims description 177
- 238000004519 manufacturing process Methods 0.000 title claims description 22
- 230000007774 longterm Effects 0.000 title claims description 19
- 240000007594 Oryza sativa Species 0.000 title 1
- 241000209094 Oryza Species 0.000 claims description 176
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 76
- 238000010411 cooking Methods 0.000 claims description 54
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 claims description 42
- 238000007654 immersion Methods 0.000 claims description 34
- 150000007524 organic acids Chemical class 0.000 claims description 30
- PHOQVHQSTUBQQK-SQOUGZDYSA-N D-glucono-1,5-lactone Chemical compound OC[C@H]1OC(=O)[C@H](O)[C@@H](O)[C@@H]1O PHOQVHQSTUBQQK-SQOUGZDYSA-N 0.000 claims description 26
- 235000012209 glucono delta-lactone Nutrition 0.000 claims description 26
- 239000000182 glucono-delta-lactone Substances 0.000 claims description 26
- 229960003681 gluconolactone Drugs 0.000 claims description 26
- 150000003839 salts Chemical class 0.000 claims description 22
- 235000002639 sodium chloride Nutrition 0.000 claims description 22
- RGHNJXZEOKUKBD-SQOUGZDYSA-N D-gluconic acid Chemical compound OC[C@@H](O)[C@@H](O)[C@H](O)[C@@H](O)C(O)=O RGHNJXZEOKUKBD-SQOUGZDYSA-N 0.000 claims description 18
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 claims description 15
- 241000894006 Bacteria Species 0.000 claims description 15
- 235000015165 citric acid Nutrition 0.000 claims description 14
- RGHNJXZEOKUKBD-UHFFFAOYSA-N D-gluconic acid Natural products OCC(O)C(O)C(O)C(O)C(O)=O RGHNJXZEOKUKBD-UHFFFAOYSA-N 0.000 claims description 12
- 206010016952 Food poisoning Diseases 0.000 claims description 12
- 208000019331 Foodborne disease Diseases 0.000 claims description 12
- 239000000174 gluconic acid Substances 0.000 claims description 12
- 235000012208 gluconic acid Nutrition 0.000 claims description 12
- 239000000203 mixture Substances 0.000 claims description 12
- 238000005406 washing Methods 0.000 claims description 11
- JVTAAEKCZFNVCJ-UHFFFAOYSA-N lactic acid Chemical compound CC(O)C(O)=O JVTAAEKCZFNVCJ-UHFFFAOYSA-N 0.000 claims description 10
- 230000004888 barrier function Effects 0.000 claims description 9
- CIWBSHSKHKDKBQ-JLAZNSOCSA-N Ascorbic acid Chemical compound OC[C@H](O)[C@H]1OC(=O)C(O)=C1O CIWBSHSKHKDKBQ-JLAZNSOCSA-N 0.000 claims description 8
- VZCYOOQTPOCHFL-OWOJBTEDSA-N Fumaric acid Chemical compound OC(=O)\C=C\C(O)=O VZCYOOQTPOCHFL-OWOJBTEDSA-N 0.000 claims description 8
- WNLRTRBMVRJNCN-UHFFFAOYSA-N adipic acid Chemical compound OC(=O)CCCCC(O)=O WNLRTRBMVRJNCN-UHFFFAOYSA-N 0.000 claims description 6
- BJEPYKJPYRNKOW-REOHCLBHSA-N (S)-malic acid Chemical compound OC(=O)[C@@H](O)CC(O)=O BJEPYKJPYRNKOW-REOHCLBHSA-N 0.000 claims description 5
- 235000011054 acetic acid Nutrition 0.000 claims description 5
- BJEPYKJPYRNKOW-UHFFFAOYSA-N alpha-hydroxysuccinic acid Natural products OC(=O)C(O)CC(O)=O BJEPYKJPYRNKOW-UHFFFAOYSA-N 0.000 claims description 5
- 239000004310 lactic acid Substances 0.000 claims description 5
- 235000014655 lactic acid Nutrition 0.000 claims description 5
- 239000001630 malic acid Substances 0.000 claims description 5
- 235000011090 malic acid Nutrition 0.000 claims description 5
- FEWJPZIEWOKRBE-JCYAYHJZSA-N Dextrotartaric acid Chemical compound OC(=O)[C@H](O)[C@@H](O)C(O)=O FEWJPZIEWOKRBE-JCYAYHJZSA-N 0.000 claims description 4
- IMQLKJBTEOYOSI-GPIVLXJGSA-N Inositol-hexakisphosphate Chemical compound OP(O)(=O)O[C@H]1[C@H](OP(O)(O)=O)[C@@H](OP(O)(O)=O)[C@H](OP(O)(O)=O)[C@H](OP(O)(O)=O)[C@@H]1OP(O)(O)=O IMQLKJBTEOYOSI-GPIVLXJGSA-N 0.000 claims description 4
- IMQLKJBTEOYOSI-UHFFFAOYSA-N Phytic acid Natural products OP(O)(=O)OC1C(OP(O)(O)=O)C(OP(O)(O)=O)C(OP(O)(O)=O)C(OP(O)(O)=O)C1OP(O)(O)=O IMQLKJBTEOYOSI-UHFFFAOYSA-N 0.000 claims description 4
- KDYFGRWQOYBRFD-UHFFFAOYSA-N Succinic acid Natural products OC(=O)CCC(O)=O KDYFGRWQOYBRFD-UHFFFAOYSA-N 0.000 claims description 4
- FEWJPZIEWOKRBE-UHFFFAOYSA-N Tartaric acid Natural products [H+].[H+].[O-]C(=O)C(O)C(O)C([O-])=O FEWJPZIEWOKRBE-UHFFFAOYSA-N 0.000 claims description 4
- 239000011668 ascorbic acid Substances 0.000 claims description 4
- 235000010323 ascorbic acid Nutrition 0.000 claims description 4
- 229960005070 ascorbic acid Drugs 0.000 claims description 4
- KDYFGRWQOYBRFD-NUQCWPJISA-N butanedioic acid Chemical compound O[14C](=O)CC[14C](O)=O KDYFGRWQOYBRFD-NUQCWPJISA-N 0.000 claims description 4
- 239000001530 fumaric acid Substances 0.000 claims description 4
- 235000011087 fumaric acid Nutrition 0.000 claims description 4
- 235000002949 phytic acid Nutrition 0.000 claims description 4
- 239000000467 phytic acid Substances 0.000 claims description 4
- 229940068041 phytic acid Drugs 0.000 claims description 4
- 239000011975 tartaric acid Substances 0.000 claims description 4
- 235000002906 tartaric acid Nutrition 0.000 claims description 4
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 claims description 4
- 239000001361 adipic acid Substances 0.000 claims description 3
- 235000011037 adipic acid Nutrition 0.000 claims description 3
- 159000000007 calcium salts Chemical class 0.000 claims description 3
- XAEFZNCEHLXOMS-UHFFFAOYSA-M potassium benzoate Chemical compound [K+].[O-]C(=O)C1=CC=CC=C1 XAEFZNCEHLXOMS-UHFFFAOYSA-M 0.000 claims description 3
- 159000000000 sodium salts Chemical class 0.000 claims description 3
- 239000004615 ingredient Substances 0.000 claims 1
- 235000020083 shōchū Nutrition 0.000 claims 1
- 235000019640 taste Nutrition 0.000 description 18
- 230000000052 comparative effect Effects 0.000 description 17
- 238000000034 method Methods 0.000 description 17
- 239000007864 aqueous solution Substances 0.000 description 14
- 238000003860 storage Methods 0.000 description 11
- 235000013339 cereals Nutrition 0.000 description 10
- 230000000694 effects Effects 0.000 description 7
- 239000007789 gas Substances 0.000 description 6
- 238000007789 sealing Methods 0.000 description 6
- 239000000243 solution Substances 0.000 description 6
- 239000003053 toxin Substances 0.000 description 6
- 231100000765 toxin Toxicity 0.000 description 6
- 239000000796 flavoring agent Substances 0.000 description 5
- 235000013305 food Nutrition 0.000 description 5
- 235000019614 sour taste Nutrition 0.000 description 5
- 229940123973 Oxygen scavenger Drugs 0.000 description 4
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 4
- -1 containers Substances 0.000 description 4
- 238000011109 contamination Methods 0.000 description 4
- 238000011049 filling Methods 0.000 description 4
- 229940093915 gynecological organic acid Drugs 0.000 description 4
- 238000010438 heat treatment Methods 0.000 description 4
- 235000005985 organic acids Nutrition 0.000 description 4
- 239000001301 oxygen Substances 0.000 description 4
- 229910052760 oxygen Inorganic materials 0.000 description 4
- 241001465754 Metazoa Species 0.000 description 3
- 239000004743 Polypropylene Substances 0.000 description 3
- 238000009826 distribution Methods 0.000 description 3
- 235000019634 flavors Nutrition 0.000 description 3
- 239000005022 packaging material Substances 0.000 description 3
- 238000011160 research Methods 0.000 description 3
- 230000001954 sterilising effect Effects 0.000 description 3
- 238000003756 stirring Methods 0.000 description 3
- 229920003002 synthetic resin Polymers 0.000 description 3
- 239000000057 synthetic resin Substances 0.000 description 3
- 238000012360 testing method Methods 0.000 description 3
- VLHWNGXLXZPNOO-UHFFFAOYSA-N 2-[4-[2-(2,3-dihydro-1H-inden-2-ylamino)pyrimidin-5-yl]-3-(2-morpholin-4-ylethyl)pyrazol-1-yl]-1-(2,4,6,7-tetrahydrotriazolo[4,5-c]pyridin-5-yl)ethanone Chemical compound C1C(CC2=CC=CC=C12)NC1=NC=C(C=N1)C=1C(=NN(C=1)CC(=O)N1CC2=C(CC1)NN=N2)CCN1CCOCC1 VLHWNGXLXZPNOO-UHFFFAOYSA-N 0.000 description 2
- 238000012371 Aseptic Filling Methods 0.000 description 2
- 241000193155 Clostridium botulinum Species 0.000 description 2
- 241000699670 Mus sp. Species 0.000 description 2
- 239000006096 absorbing agent Substances 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- 241001148470 aerobic bacillus Species 0.000 description 2
- 238000007796 conventional method Methods 0.000 description 2
- 235000013373 food additive Nutrition 0.000 description 2
- 239000002778 food additive Substances 0.000 description 2
- 239000002648 laminated material Substances 0.000 description 2
- 239000004033 plastic Substances 0.000 description 2
- 229920003023 plastic Polymers 0.000 description 2
- 239000000047 product Substances 0.000 description 2
- 230000001953 sensory effect Effects 0.000 description 2
- 238000002791 soaking Methods 0.000 description 2
- 239000006228 supernatant Substances 0.000 description 2
- 239000008399 tap water Substances 0.000 description 2
- 235000020679 tap water Nutrition 0.000 description 2
- OEPOKWHJYJXUGD-UHFFFAOYSA-N 2-(3-phenylmethoxyphenyl)-1,3-thiazole-4-carbaldehyde Chemical compound O=CC1=CSC(C=2C=C(OCC=3C=CC=CC=3)C=CC=2)=N1 OEPOKWHJYJXUGD-UHFFFAOYSA-N 0.000 description 1
- 239000004278 EU approved seasoning Substances 0.000 description 1
- 229920000219 Ethylene vinyl alcohol Polymers 0.000 description 1
- 241000233866 Fungi Species 0.000 description 1
- 241000699666 Mus <mouse, genus> Species 0.000 description 1
- 206010060860 Neurological symptom Diseases 0.000 description 1
- 239000004677 Nylon Substances 0.000 description 1
- CBENFWSGALASAD-UHFFFAOYSA-N Ozone Chemical compound [O-][O+]=O CBENFWSGALASAD-UHFFFAOYSA-N 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- 229920002472 Starch Polymers 0.000 description 1
- 241000746966 Zizania Species 0.000 description 1
- 235000002636 Zizania aquatica Nutrition 0.000 description 1
- 238000007792 addition Methods 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 230000001580 bacterial effect Effects 0.000 description 1
- 235000019658 bitter taste Nutrition 0.000 description 1
- 235000021329 brown rice Nutrition 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 125000000422 delta-lactone group Chemical group 0.000 description 1
- 238000007598 dipping method Methods 0.000 description 1
- 239000012153 distilled water Substances 0.000 description 1
- 230000005611 electricity Effects 0.000 description 1
- 239000003995 emulsifying agent Substances 0.000 description 1
- UFRKOOWSQGXVKV-UHFFFAOYSA-N ethene;ethenol Chemical compound C=C.OC=C UFRKOOWSQGXVKV-UHFFFAOYSA-N 0.000 description 1
- 239000004715 ethylene vinyl alcohol Substances 0.000 description 1
- 235000013410 fast food Nutrition 0.000 description 1
- 239000003925 fat Substances 0.000 description 1
- 239000011888 foil Substances 0.000 description 1
- 235000011194 food seasoning agent Nutrition 0.000 description 1
- 238000010030 laminating Methods 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 229920001778 nylon Polymers 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 238000001139 pH measurement Methods 0.000 description 1
- 238000012856 packing Methods 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 229920001155 polypropylene Polymers 0.000 description 1
- 235000013324 preserved food Nutrition 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 239000000565 sealant Substances 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 235000019698 starch Nutrition 0.000 description 1
- 239000008107 starch Substances 0.000 description 1
- 238000004659 sterilization and disinfection Methods 0.000 description 1
- 230000004936 stimulating effect Effects 0.000 description 1
- 208000024891 symptom Diseases 0.000 description 1
- 241001148471 unidentified anaerobic bacterium Species 0.000 description 1
Classifications
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02A—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
- Y02A40/00—Adaptation technologies in agriculture, forestry, livestock or agroalimentary production
- Y02A40/90—Adaptation technologies in agriculture, forestry, livestock or agroalimentary production in food processing or handling, e.g. food conservation
Landscapes
- Food Preservation Except Freezing, Refrigeration, And Drying (AREA)
- Cereal-Derived Products (AREA)
Description
【0001】[0001]
【産業上の利用分野】本発明は長期保存可能な米飯の製
造方法に関するものである。更に詳しくは、製造工程お
よび流通段階において米粒の結着、潰れが生じたりする
ことがなく、長期保存しても炊きたての味と香りが維持
できるような米飯の製造方法に関するものである。BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a method for producing cooked rice that can be stored for a long period of time. More specifically, the present invention relates to a method for producing cooked rice that does not cause binding or crushing of rice grains during the production process and distribution stage and can maintain the freshly cooked taste and aroma even after long-term storage.
【0002】[0002]
【従来の技術】米飯に於いても簡単な手段で短時間で調
理できる多種類のレトルト米飯類や無菌製造方法により
製造された米飯類が市場に出回っている。レトルト米飯
類の製造方法については数多くの方法が知られている。
例えば合成樹脂フィルム等の袋に熱水中で2〜10分間
湯炊きした米を充填、密封した後加圧殺菌して保存用米
飯を製造する方法(特公昭57−43222号公報)、
できるだけ均一に含水させた洗米を袋に入れ加圧殺菌し
て米粒表面が滑らかでべたつきの少ないレトルト米飯を
製造する方法(特開昭62−51959号公報)、炊飯
後レトルトパウチ内に御飯を充填、密封し加圧殺菌する
方法(特開昭56−72655号公報)等が知られてい
る。2. Description of the Related Art With respect to cooked rice, various types of retort cooked rice that can be cooked in a short time by simple means and cooked rice produced by an aseptic manufacturing method are on the market. There are many known methods for producing retort cooked rice.
For example, a bag of synthetic resin film or the like is filled with rice cooked in hot water for 2 to 10 minutes, sealed, and sterilized under pressure to produce cooked rice (Japanese Patent Publication No. 57-43222).
A method of producing retort cooked rice with smooth rice grain surface and less stickiness by placing washed rice with water as uniformly as possible in a bag (Japanese Patent Laid-Open No. 62-51959), and filling rice in the retort pouch after cooking rice. A method of sealing and sterilizing under pressure (Japanese Patent Laid-Open No. 56-72655) is known.
【0003】しかし、これらのレトルト米飯は高温加熱
処理(例えば、120℃、20〜30分間加熱)を行う
ため、炊きたての味と香りが維持できない、製造工程お
よび流通段階において米粒の結着、潰れが生じ、外観お
よび食感を損ね、家庭で味わう炊きたての風味、食感を
有していないなどの問題がある。However, since these retort cooked rice is subjected to high-temperature heat treatment (for example, heated at 120 ° C. for 20 to 30 minutes), the taste and aroma of freshly cooked rice cannot be maintained, and the binding and crushing of rice grains at the manufacturing process and distribution stage. Occurs, which impairs the appearance and texture, and does not have the freshly cooked flavor and texture to taste at home.
【0004】また常圧炊飯あるいは加圧炊飯した米飯を
無菌設備中で脱酸素剤と共にバリヤー性の耐熱容器に充
填し容器を完全密封するという従来の無菌製造法(例え
ば、特開平3−133348号公報、特開平3−985
42号公報など)により製造された即席米飯類は、常圧
炊飯の場合はレトルト米飯よりも香りや味が優れている
が、保存用米飯としては食品衛生上の問題が残されてお
り、加圧炊飯の場合は約105℃〜120℃の温度範囲
で炊飯するので炊きたての味と香りが維持できない、米
粒の結着、潰れが生じるなどの問題がある。Further, a conventional aseptic manufacturing method in which normal pressure cooked rice or cooked cooked rice is filled with a deoxidizer in a heat resistant container having a barrier property in an aseptic facility and the container is completely sealed (for example, JP-A-3-133348). Japanese Laid-Open Patent Publication No. 3-985
The instant cooked rice produced in accordance with Japanese Patent No. 42) has a scent and taste superior to that of the retort cooked rice in the case of normal pressure cooked rice, but there is a food hygiene problem as the cooked rice for storage, and In the case of pressure cooked rice, since it is cooked in a temperature range of about 105 ° C. to 120 ° C., there are problems that the taste and aroma of freshly cooked rice cannot be maintained and that rice grains are bound and crushed.
【0005】上記の常圧炊飯を行う従来の無菌製造法
は、炊飯のための加熱(約100℃)以降の工程を無菌
設備中で行うことにより米飯の細菌汚染を防止し、かつ
脱酸素剤の封入により容器内部の酸素濃度を0.1%以
下にして好気性細菌および真菌の増殖を防止すること
で、高温高圧のレトルト殺菌を不要にしようとするもの
である。しかしながら、精白米が当初よりボツリヌス菌
などの嫌気性の食中毒菌に汚染されていた場合、これら
の細菌は、炊飯時の加熱処理(約100℃)では完全に
死滅せず、酸素濃度0.1%以下の容器内の米飯中で増
殖するので、保存食品としての安全性が問題となる。ボ
ツリヌス菌による食中毒は、食品中で食中毒菌が増殖し
て特定の毒素を産生したものを摂取することによって発
症するもので、その症状は特異的な神経症状を示し、致
命率30〜60%にも及ぶという食中毒中最も恐れられ
ているものである。In the conventional aseptic manufacturing method for cooking rice under normal pressure, the steps after heating (about 100 ° C.) for cooking rice are carried out in an aseptic facility to prevent bacterial contamination of cooked rice and to remove oxygen scavenger. In order to prevent the aerobic bacteria and fungi from growing by making the oxygen concentration in the container 0.1% or less by encapsulating, the need for high temperature and high pressure retort sterilization is eliminated. However, when the polished rice was contaminated with anaerobic food poisoning bacteria such as Clostridium botulinum from the beginning, these bacteria were not completely killed by the heat treatment during cooking (about 100 ° C.), and the oxygen concentration was 0.1. Since it proliferates in cooked rice in a container of less than 100%, safety as a preserved food becomes a problem. Food poisoning caused by Clostridium botulinum develops when food poisoning bacteria grow in food and produce a specific toxin, and the symptoms show specific neurological symptoms with a fatality rate of 30 to 60%. It is the most feared food poisoning that spreads.
【0006】また精白米を洗米し、更に紫外線、マイク
ロ波、オゾンの何れかで無菌状態になるまで殺菌し、そ
れを無菌袋に真空で袋詰めにしたすぐ炊ける米の加工方
法(特開昭61−5750号公報)が知られている。し
かし実際には何れの方法でも米に汚染している菌は完全
殺菌することは至難である。Further, a method for processing ready-to-cook rice by washing polished rice, sterilizing it with ultraviolet rays, microwaves, or ozone until it becomes aseptic and packing it in a sterile bag under vacuum (Japanese Patent Application Laid-Open No. Sho-6). 61-5750) is known. However, in reality, it is difficult to completely sterilize the bacteria contaminated with rice by any of the methods.
【0007】[0007]
【発明が解決しようとする課題】米粒の結着、潰れなど
を起こすことがなく、常温で約6ケ月以上長期保存して
も炊きたての味と香りが維持できるような米飯の製造方
法を提供する。[PROBLEMS TO BE SOLVED BY THE INVENTION] A method for producing cooked rice is provided which does not cause binding or crushing of rice grains and which can maintain the freshly cooked taste and aroma even after being stored at room temperature for about 6 months or longer. .
【0008】[0008]
【課題を解決するための手段】本発明者等は、上記の問
題に鑑み鋭意研究した結果、グルコノデルタラクトン、
あるいはクエン酸、酒石酸、リンゴ酸、フマル酸、コハ
ク酸、グルコン酸、乳酸、酢酸、アジピン酸、フィチン
酸、アスコルビン酸などの食用有機酸あるいはその塩を
含有する浸漬水や炊き水を用いて、炊飯後の米飯のpH
が特定の値となるように調整して炊飯した米飯を無菌設
備中で容器中に脱酸素剤と共に充填し、完全に密封する
ことにより課題を解決することができることを見いだし
て本発明をなすに至った。Means for Solving the Problems As a result of intensive studies in view of the above problems, the present inventors have found that gluconodeltalactone,
Alternatively, using dipping water or cooking water containing an edible organic acid such as citric acid, tartaric acid, malic acid, fumaric acid, succinic acid, gluconic acid, lactic acid, acetic acid, adipic acid, phytic acid, ascorbic acid or a salt thereof, PH of cooked rice after cooking
Is adjusted to be a specific value, and cooked cooked rice is filled with a deoxidizer in a container in a sterile facility, and it is found that the problem can be solved by completely sealing the present invention. I arrived.
【0009】本発明の請求項1の発明は、精白米を洗米
後、浸漬水に浸漬し、次いで浸漬水から取り出し、炊飯
直前に炊き水を添加して炊飯後、無菌設備中でガスバリ
ヤー性耐熱容器中に脱酸素剤と共に充填し、完全に密封
する米飯の製造方法において、グルコノデルタラクト
ン、グルコン酸およびその塩あるいはこれらの混合物か
ら選択される少なくとも一つを必須成分として含有する
浸漬水および炊き水を用いて炊飯後の米飯のpHが4.
0〜4.8となるように調整し、ボツリヌス菌をはじめ
とする食中毒菌の増殖を防止することを特徴とする安全
かつ長期保存可能な米飯の製造方法。According to the first aspect of the present invention, the polished rice is washed, then immersed in immersion water, then taken out of the immersion water, and the cooking water is added just before the rice is cooked. In a method for producing cooked rice that is filled with a deoxidizer in a heat-resistant container and completely sealed, it contains at least one selected from glucono delta lactone, gluconic acid and salts thereof, or a mixture thereof as an essential component.
3. The pH of cooked rice after cooking with immersion water and cooking water is 4.
A method for producing a safe and long-term storable cooked rice, which comprises adjusting the concentration to be 0 to 4.8 and preventing the growth of food poisoning bacteria such as botulinum.
【0010】本発明の請求項2の発明は、クエン酸、酒
石酸、リンゴ酸、フマル酸、コハク酸、乳酸、酢酸、ア
ジピン酸、フィチン酸、アスコルビン酸およびその塩あ
るいはこれらの混合物から選択される少なくとも一つの
食用有機酸をさらに含有する浸漬水および/または炊き
水を用いることを特徴とする請求項1に記載の安全かつ
長期保存可能な米飯の製造方法である。The invention of claim 2 of the present invention is citric acid, liquor
Tartaric acid, malic acid, fumaric acid, succinic acid, lactic acid, acetic acid,
Dipic acid, phytic acid, ascorbic acid and its salts
At least one selected from these mixtures
Immersion water and / or cooking further containing edible organic acid
The method for producing cooked rice which is safe and can be stored for a long time according to claim 1, wherein water is used .
【0011】本発明の請求項3の発明は、該塩がカリウ
ム塩、ナトリウム塩、カルシウム塩およびこれらの混合
物から選択される少なくとも一つの有機酸の塩であるこ
とを特徴とする請求項1あるいは請求項2に記載の安全
かつ長期保存可能な米飯の製造方法である。[0011] The invention of claim 3 of the present invention, or the claims 1, wherein the salt is potassium salt, sodium salt, calcium salt and salts of at least one organic acid selected from mixtures thereof Safety according to claim 2
And a method for producing a shelf-stable rice.
【0012】本発明で用いる精白米とは、うるち米、も
ち米、ワイルドライス、玄米などの精白物である。また
必要に応じてこれらの半調理、半加熱物などのα化米お
よび他の穀類などを添加することもできる。The polished rice used in the present invention is a refined product such as non-glutinous rice, glutinous rice, wild rice and brown rice. If necessary, semi-cooked and semi-heated products such as pregelatinized rice and other grains may be added.
【0013】本発明において精白米は常法に従い洗米を
行う。精白米を洗米後、浸漬水に浸漬する。通常、生米
の水分含量は10〜18%であるので、精白米の水分含
量が約20〜50%となるように水に浸漬したり、水を
噴霧したりすることが知られているが、この範囲に限定
されるものではない。精白米を浸漬水から取り出し、引
き続き炊飯直前に米に対して例えば1.0〜1.5倍量
の炊き水を添加し、常法に従いガス、電気、蒸気などの
熱源を用いて常圧炊飯を行う。In the present invention, milled rice is washed by a conventional method. After washing the polished rice, it is immersed in immersion water. Usually, the water content of raw rice is 10 to 18%, so it is known to immerse it in water or spray it with water so that the water content of milled rice is about 20 to 50%. However, it is not limited to this range. Remove the polished rice from the immersion water, and then add 1.0 to 1.5 times the amount of cooking water to the rice immediately before cooking rice, and cook the rice under normal pressure using a heat source such as gas, electricity, or steam according to the usual method. I do.
【0014】このようにして炊飯した後、米飯が比較的
温かい約60℃以上のうちに、無菌設備中でバリヤー性
耐熱容器中に脱酸素剤と共に充填し、例えばヒートシー
ル機で完全に密封する。例えば、米国航空宇宙局(NA
SA)の規格でクラス100〜クラス10000のクリ
ーンルームやクリーンブース内等で無菌充填を行なう。
無菌充填を行なう際には使用する設備・包材・容器・脱
酸素剤等は充分に滅菌されたものを使用する。After the rice has been cooked in this manner, it is filled with a deoxidizer in a barrier heat-resistant container in a sterile facility while the rice is relatively warm, at about 60 ° C. or higher, and completely sealed by, for example, a heat-sealing machine. . For example, the United States Aerospace Agency (NA
Aseptic filling is performed in a clean room or clean booth of class 100 to class 10000 according to the SA standard.
When performing aseptic filling, use fully sterilized equipment, packaging materials, containers, oxygen absorbers, etc.
【0015】好ましいガスバリヤー性耐熱容器包装体
は、耐熱性合成樹脂のトレー容器か、耐熱性合成樹脂フ
ィルム及び/又は金属箔のラミネート材からなるプラス
チック袋である。例えば、トレー容器は、塩化ビニリデ
ンフィルムを中間層とし、上下層には、ポリプロピレン
を積層しこれをトレー状に成形したものとトレー容器上
蓋フィルム(PET/Kナイロン/ポリエチレン系シー
ラント)などが使用できる。A preferred gas barrier heat resistant container package is a tray container made of heat resistant synthetic resin or a plastic bag made of a laminated material of heat resistant synthetic resin film and / or metal foil. For example, for the tray container, a vinylidene chloride film is used as an intermediate layer, and upper and lower layers are formed by laminating polypropylene and molded into a tray shape, and a tray container upper lid film (PET / K nylon / polyethylene sealant) can be used. .
【0016】上記のような米飯の製造方法において、本
発明においては、グルコノデルタラクトンや食用有機酸
あるいはその塩を含有する浸漬水および/または炊き水
を用いて炊飯後の米飯のpHが4.0〜4.8となるよ
うに調整することが、長期保存しても炊きたての味と香
りが維持できるような米飯を製造するために必要であ
る。In the method for producing cooked rice as described above, in the present invention, the pH of cooked rice after cooking is 4 using immersion water and / or cooking water containing gluconodeltalactone, an edible organic acid or a salt thereof. It is necessary to adjust so as to be 0.0 to 4.8 in order to produce cooked rice that can maintain the taste and aroma of freshly cooked food even after long-term storage.
【0017】本発明で用いるグルコノデルタラクトンは
食品添加物であり、本発明において好ましく用いること
ができる。本発明で用いる上記の食用有機酸は食品添加
物として認められている食用酸であり、例えばクエン
酸、酒石酸、リンゴ酸、フマル酸、コハク酸、グルコン
酸、乳酸、酢酸、アジピン酸、フィチン酸、アスコルビ
ン酸あるいはこれらの混合物などを挙げることができる
が、長期保存性と食味とを同時に満足させるためにはク
エン酸、グルコン酸あるいはこれらの混合物は好ましく
使用することができる。本発明で用いる上記の食用有機
酸の塩としては、カリウム塩、ナトリウム塩、カルシウ
ム塩およびこれらの混合物などを挙げることができる。
またグルコノデルタラクトンとこれらの食用有機酸やそ
の塩との混合物も使用することができる。Gluconodelta lactone used in the present invention is a food additive and can be preferably used in the present invention. The above-mentioned edible organic acid used in the present invention is an edible acid recognized as a food additive, for example, citric acid, tartaric acid, malic acid, fumaric acid, succinic acid, gluconic acid, lactic acid, acetic acid, adipic acid, phytic acid. , Ascorbic acid, or a mixture thereof, and citric acid, gluconic acid, or a mixture thereof can be preferably used in order to satisfy both long-term storage stability and taste. Examples of the salt of the edible organic acid used in the present invention include potassium salt, sodium salt, calcium salt, and a mixture thereof.
Also, a mixture of glucono delta lactone and these edible organic acids or salts thereof can be used.
【0018】食用有機酸を使用せずに炊飯した炊飯後の
米飯のpHは約6.7であり、この米飯は食味は優れて
いるが、長期保存性に劣るので、本発明においては炊飯
後の米飯のpHを4.0〜4.8となるように調整する
ことにより食中毒菌の増殖を防止することが可能である
ことを究明した。pH値を低く調整するほど、食中毒菌
の増殖防止効果は高まるが、食味に悪影響がでるので好
ましくなく、逆にpH値を高く調整すると、長期保存性
が悪化するので、長期保存食品として商品化するために
は、常温で最低でも約6ケ月間は保存できる保存性が要
求されることを考えて、炊飯後の米飯のpHを4.0〜
4.8に制御するのが好ましいとの知見を得たものであ
る。The pH of cooked rice cooked without the use of edible organic acids is about 6.7. This cooked rice has an excellent taste but is inferior in long-term storability. It was clarified that it is possible to prevent the growth of food poisoning bacteria by adjusting the pH of the cooked rice to be 4.0 to 4.8. The lower the pH value is adjusted, the higher the effect of preventing food poisoning bacteria from growing, but it is not desirable because it adversely affects the taste. Conversely, if the pH value is adjusted to a high value, the long-term storage stability deteriorates, so commercialization as a long-term storage food In order to achieve this, the pH of cooked rice after cooking should be 4.0 to 4.0, considering that it needs to be stored at room temperature for at least about 6 months.
It has been found that it is preferable to control to 4.8.
【0019】本発明において、グルコノデルタラクトン
や食用有機酸などを浸漬水や炊き水に添加して上記範囲
内のpH値に制御された米飯を製造するための具体的方
法としては、 精白米を洗米後、一定時間水に浸漬後、炊飯直前に炊
き水にグルコノデルタラクトンや食用有機酸あるいはそ
の塩を添加し、炊飯する方法、 精白米を洗米後、グルコノデルタラクトンや食用有機
酸あるいはその塩を含む溶液中に一定時間浸漬し、pH
値を低下させ、そのまま炊飯する方法、 精白米を洗米後、グルコノデルタラクトンや食用有機
酸あるいはその塩を含む溶液中に一定時間浸漬し、pH
をある程度低下させ、さらに炊飯直前に炊き水にグルコ
ノデルタラクトンや食用有機酸あるいはその塩を添加
し、炊飯する方法、があるが、最終pH値の安定度と品
質の観点等より、の方法によるのが最も現実的であり
好ましい方法である。In the present invention, a specific method for adding glucono delta lactone, edible organic acid or the like to immersion water or cooking water to produce cooked rice having a pH value within the above range is polished rice. After washing rice, soaking it in water for a certain period of time, immediately before cooking rice, add glucono delta lactone or edible organic acid or its salt to the cooked water and cook the rice, after washing polished rice, glucono delta lactone or edible organic acid Alternatively, immerse in a solution containing the salt for a certain period of time, and
Decrease the value and cook the rice as it is, wash the polished rice and then soak it in a solution containing glucono delta lactone, edible organic acid or its salt for a certain period of time
There is a method of cooking by adding glucono delta lactone or an edible organic acid or its salt to the cooking water immediately before cooking rice, but from the viewpoint of stability and quality of final pH value, the method of Is the most realistic and preferred method.
【0020】以上のように調製された無菌充填米飯は、
電子レンジあるいは加熱水浴中で再加熱を行ない食に供
すことができる。The sterile-filled cooked rice prepared as described above is
It can be reheated in a microwave oven or a heated water bath and served.
【0021】本発明において、本発明の主旨を逸脱しな
い範囲で米飯や水に、さらに調味料、着色料、油脂、乳
化剤などを添加してもよい。In the present invention, seasonings, colorants, fats and oils, emulsifiers and the like may be further added to cooked rice and water without departing from the spirit of the present invention.
【0022】[0022]
【作用】本発明においては、グルコノデルタラクトン、
あるいはクエン酸、グルコン酸などの食用有機酸やその
塩を含有する浸漬水や炊き水を用いて、常圧炊飯後の米
飯のpHが4.0〜4.8に制御して炊飯した米飯を無
菌設備中でガスバリヤー性耐熱容器中に脱酸素剤と共に
充填し、完全に密封することにより、米粒の結着、潰れ
を起こすことなく、好気性菌や嫌気性菌などの増殖や活
動を抑えることができるので、長期保存しても炊きたて
の味と香りが維持できるような長期保存性に優れた米飯
を提供することができる。In the present invention, gluconodeltalactone,
Alternatively, using cooked water or immersion water containing an edible organic acid such as citric acid or gluconic acid, or salt thereof, the cooked rice is cooked by controlling the pH of the cooked rice after normal pressure cooking to 4.0 to 4.8. By filling the gas barrier heat-resistant container with the oxygen scavenger in an aseptic facility and completely sealing it, the growth and activity of aerobic bacteria and anaerobic bacteria can be suppressed without binding or crushing of rice grains. Therefore, it is possible to provide cooked rice excellent in long-term storability such that the taste and aroma of freshly cooked food can be maintained even after long-term storage.
【0023】[0023]
【実施例】次に実施例により本発明を詳しく説明する
が、本発明の主旨を逸脱しない限りこれらの実施例に限
定されるものではない。 (グルコノデルタラクトン、各食用有機酸の米飯の味覚
への影響)精白米をグルコノデルタラクトンや各食用有
機酸を含有する水溶液中に一定時間(60〜90分間)
浸漬してpHを低下させ、さらに炊飯直前に炊き水に食
用有機酸を添加し、炊飯後の米飯のpHが4.5および
5.5となるように、下記の(表1)に示した炊飯条件
で炊飯する方法により米飯を作りグルコノデルタラクト
ンや各食用有機酸の米飯の味覚への影響などを調べた。
pH測定は以下の方法によった。 米飯20gに対して、50ccの蒸留水を加え、ホモ
ゲナイザーにて処理する。 5分間放置後、pHメーター[東亜電波工業(株)製
HM−30S]にてPHを測定する。 米飯の食味は訓練された味覚審査員を用い、官能評価
し、結果を表2にまとめて示した。EXAMPLES The present invention will now be described in detail with reference to examples, but the present invention is not limited to these examples without departing from the gist of the present invention. (Effect of glucono delta lactone and each edible organic acid on the taste of cooked rice) Polished rice is kept in an aqueous solution containing glucono delta lactone and each edible organic acid for a certain time (60 to 90 minutes)
The pH was lowered by immersing the mixture, and the edible organic acid was added to the cooked water immediately before the rice was cooked, so that the pH of the cooked rice after cooking was 4.5 and 5.5, as shown in (Table 1) below. Cooked rice was prepared by cooking under the cooking conditions, and the effects of gluconodeltalactone and each edible organic acid on the taste of cooked rice were investigated.
The pH was measured by the following method. To 20 g of cooked rice, add 50 cc of distilled water and treat with a homogenizer. After standing for 5 minutes, the pH is measured with a pH meter [HM-30S manufactured by Toa Denpa Kogyo KK]. The taste of cooked rice was sensory evaluated by a trained taste judge, and the results are summarized in Table 2.
【0024】[0024]
【表1】 [Table 1]
【0025】[0025]
【表2】 [Table 2]
【0026】以上の結果より、酸味等による白飯の商品
価値の低下を最小限に抑えて、本発明の長期保存可能な
米飯の製造方法に使用することができる有効な添加剤と
しては上記の添加剤のいずれも使用できるが、グルコノ
デルタラクトンおよび食用有機酸としては、クエン酸、
グルコン酸およびこれらの組合わせが好ましいことが判
る。From the above results, the above-mentioned additions are effective additives that can be used in the method for producing a long-term storable cooked rice of the present invention while minimizing the decrease in the commercial value of the cooked rice due to the sourness and the like. Any of the agents can be used, but as glucono delta lactone and edible organic acid, citric acid,
It turns out that gluconic acid and combinations thereof are preferred.
【0027】(前記精白米を各種濃度のクエン酸水溶液
に浸漬した時の米のpHの経時変化)前記精白米10k
gを洗米後、常温で各種濃度のクエン酸水溶液(クエン
酸濃度0.05重量%、0.20重量%、0.50重量
%)25リットルに浸漬した時の米のpHの経時変化を
調べた結果を図1にまとめて示す。(Change in pH of Rice with Time when the Polished Rice is Soaked in Citric Acid Aqueous Solution of Various Concentrations) Polished Rice 10 k
After washing g of rice, the change in pH of rice when immersed in 25 liters of an aqueous citric acid solution of various concentrations (citric acid concentration of 0.05% by weight, 0.20% by weight, 0.50% by weight) at room temperature was examined. The results are summarized in Fig. 1.
【0028】(実施例1〜5、比較例1〜5)含水率1
5%の上記精白米を洗米後、浸漬水として水を用いるか
あるいはグルコノデルタラクトンや各種食用有機酸を添
加した浸漬水溶液を用い、それに60分間浸漬して含水
率32%とし、炊飯直前に炊き水として水を用いるかあ
るいはグルコノデルタラクトンや各種食用有機酸を添加
した炊き水を用い上記の炊飯条件下で、炊飯後の米飯の
pH値を制御して米飯を製造した。米飯が約60℃の状
態で、クラス100のバイオクリーンルーム内で、バリ
ヤー性耐熱容器として、PP/EVOH/PPからなる
ドライラミネート材を袋状に製袋し、一部ヒートシール
していない未溶着部を設けたプラスチック袋を用い、そ
れに脱酸素剤と共に充填し、ヒートシール機でヒートシ
ールして完全に密封した。(Examples 1 to 5, Comparative Examples 1 to 5) Water content 1
After washing 5% of the above polished rice, water is used as the immersion water or an immersion aqueous solution containing glucono delta lactone and various edible organic acids is added and immersed for 60 minutes to a water content of 32%, immediately before cooking rice. Boiled rice was produced by controlling the pH value of the cooked rice under the above-mentioned cooking conditions, using water as cooking water or using cooking water to which gluconodeltalactone and various edible organic acids were added. With the rice cooked at about 60 ° C, a dry laminated material consisting of PP / EVOH / PP was made into a bag as a barrier heat-resistant container in a class 100 bioclean room, and some parts were not heat-sealed and not welded. Using a plastic bag provided with a part, it was filled with an oxygen scavenger and heat-sealed by a heat-sealing machine to completely seal it.
【0029】これを常温で約6ケ月間保存した後、電子
レンジで3分間あたためて食し、米飯の食味と保存性を
評価した。実施例や比較例のいずれの場合も電子レンジ
で3分間あたためたところふっくらとしたボリューム感
のある色の白い米飯が得られ、また米粒の結着や潰れは
生じなかった。結果をまとめて(表3)に示す。After this was stored at room temperature for about 6 months, it was warmed and eaten in a microwave oven for 3 minutes to evaluate the taste and storability of cooked rice. In each of the examples and the comparative examples, when cooked for 3 minutes in a microwave oven, white cooked rice with a fluffy and voluminous color was obtained, and no binding or crushing of rice grains occurred. The results are summarized (Table 3).
【0030】[0030]
【表3】 [Table 3]
【0031】(実施例1)浸漬水として水を用い、グル
コノデルタラクトンを添加した炊き水を使用した場合で
ある。常温で約6ケ月間保存した後、電子レンジで3分
間あたためた米飯は異味異臭もなく、かすかに酸味を有
しており、たきたての食感を有していた。(Example 1) This is a case where water is used as the immersion water and cooking water containing glucono delta lactone is used. After storing at room temperature for about 6 months, the rice cooked in a microwave oven for 3 minutes had no off-taste, had a faint sour taste, and had a fresh texture.
【0032】(実施例2)浸漬水としてグルコン酸を添
加した浸漬水溶液を用い、水を炊き水として使用した場
合である。常温で約6ケ月間保存した後、電子レンジで
3分間あたためた米飯は異味異臭もなく、かすかに酸味
を有しており、たきたての食感を有していた。(Example 2) This is a case where an immersion aqueous solution containing gluconic acid was used as the immersion water and the water was used as cooking water. After storing at room temperature for about 6 months, the rice cooked in a microwave oven for 3 minutes had no off-taste, had a faint sour taste, and had a fresh texture.
【0033】(実施例3)浸漬水としてクエン酸を添加
した浸漬水溶液を用い、水を炊き水として使用した場合
である。常温で約6ケ月間保存した後、電子レンジで3
分間あたためた米飯は異味異臭もなく、穏やかな酸味を
有しており、たきたての食感を有していた。(Example 3) This is a case where an immersion aqueous solution containing citric acid was used as the immersion water, and the water was used as cooking water. Store at room temperature for about 6 months and then microwave for 3 months.
The cooked rice warmed for a minute had no offensive odor, had a mild sourness, and had a fresh texture.
【0034】(実施例4)浸漬水としてクエン酸を添加
した浸漬水溶液を用い、グルコン酸を添加した水溶液を
炊き水として使用した場合である。常温で約6ケ月間保
存した後、電子レンジで3分間あたためた米飯は異味異
臭もなく、穏やかな酸味を有しており、たきたての食感
を有していた。(Example 4) This is a case where an immersion aqueous solution containing citric acid was used as the immersion water and an aqueous solution containing gluconic acid was used as the cooking water. After being stored at room temperature for about 6 months, the cooked rice was warmed in a microwave oven for 3 minutes, had no offensive odor, had a mild sourness, and had a fresh texture.
【0035】(実施例5)浸漬水としてグルコノデルタ
ラクトンを添加した浸漬水溶液を用い、グルコン酸を添
加した水溶液を炊き水として使用した場合である。常温
で約6ケ月間保存した後、電子レンジで3分間あたため
た米飯は異味異臭もなく、かすかに酸味を有しており、
たきたての食感を有していた。(Example 5) This is a case where an immersion aqueous solution containing gluconodeltalactone was used as the immersion water and an aqueous solution containing gluconic acid was used as the cooking water. After being stored at room temperature for about 6 months, the rice cooked in a microwave for 3 minutes has no offensive odor and has a slightly sour taste.
It had a fresh texture.
【0036】(比較例1)浸漬水としてクエン酸を添加
した浸漬水溶液を用い、グルコン酸を添加した水溶液を
炊き水として使用した場合である。炊飯後のpHが本発
明のpHの範囲より大きいので、保存性に問題があり
(食中毒菌による毒素産生の危険性があり)、常温で約
6ケ月間保存したものは、官能検査に適さない。(Comparative Example 1) This is a case where an immersion aqueous solution containing citric acid was used as the immersion water and an aqueous solution containing gluconic acid was used as the cooking water. Since the pH after cooking rice is higher than the pH range of the present invention, there is a problem in storability (there is a risk of toxin production by food poisoning bacteria), and those stored at room temperature for about 6 months are not suitable for sensory tests. .
【0037】(比較例2)浸漬水としてグルコノデルタ
ラクトンを添加した浸漬水溶液を用い、グルコン酸を添
加した水溶液を炊き水として使用した場合である。炊飯
後のpHが本発明のpHの範囲より小さいので、常温で
約6ケ月間保存した後、電子レンジで3分間あたためた
米飯は異味異臭はなく、保存性に優れているが、酸味が
後を引き、たきたての食感はなかった。Comparative Example 2 This is a case where an immersion aqueous solution containing gluconodeltalactone was used as the immersion water and an aqueous solution containing gluconic acid was used as the cooking water. Since the pH after cooking rice is smaller than the pH range of the present invention, after being stored at room temperature for about 6 months, the rice cooked in a microwave oven for 3 minutes has no off-flavor and odor and is excellent in storability, but has a sour taste. And there was no fresh texture.
【0038】(比較例3〜5)浸漬水としてそれぞれ乳
酸(比較例3)、酢酸(比較例4)、リンゴ酸(比較例
5)を添加した浸漬水溶液を用い、水を炊き水として使
用した場合である。常温で約6ケ月間保存した後、電子
レンジで3分間あたためた米飯は異味異臭もなく、保存
性に優れているが、渋味のある酸味がある(比較例
3)、刺激的な酸味がある(比較例4)、苦味のある酸
味がある(比較例5)などのためにたきたての食感はな
かった。(Comparative Examples 3 to 5) Immersion aqueous solutions containing lactic acid (Comparative Example 3), acetic acid (Comparative Example 4) and malic acid (Comparative Example 5) were used as the immersion water, and water was used as cooking water. This is the case. After being stored at room temperature for about 6 months, the rice cooked in a microwave for 3 minutes has no off-flavor and has an excellent storability, but has an astringent sourness (Comparative Example 3), which has a stimulating sourness. There was no fresh texture due to certain (Comparative Example 4), bitter and sour taste (Comparative Example 5), and the like.
【0039】(実施例6〜8、比較例6〜7)下記のよ
うにして、上記精白米を炊飯前にボツリヌス菌(Closto
ridiumBotulinum )により汚染してから炊飯、充填、密
封、保存して長期保存性を試験した(初期汚染の影
響)。上記精白米を用いて実施例3の方法に準じて米飯
を作る時、浸漬米1g当たりに対して104 個になるよ
うにボツリヌス菌を接種した後、炊飯し、クラス100
のクリーンルーム内で無菌的にガスバリヤー性の包材に
充填した。合わせて脱酸素剤を封入し嫌気状態にして密
封し、30℃の恒温槽に保存し、1,3,6,9,12
ヶ月後に毒素の有無を判定した。なお、毒素の有無はマ
ウスへの投与による下記の判定法によった。 米飯50gに滅菌水100ccを添加・混合し、12
時間放置する。 ストマッカーにて20秒ストマッキング後、上澄液を
無菌的に採取し、1時間放置後、遠心分離機にて処理
(3000rpm×40分間)する。 上澄液を無菌的に採取し、37℃湯中に10分間放置
し、次いで35℃の恒温槽に40分間保管した後、室温
に放置する。 0.4ミリリットルを採取し、マウスに腹腔注射する
(1検体5匹)。 以後、常法にて飼育し、5匹中、1匹でも死亡したも
のを(+)、全数生存しているものを(−)とした。 結果をまとめて(表4)に示す。(Examples 6 to 8 and Comparative Examples 6 to 7) As described below, the polished rice was botulinum (Closto) before being cooked.
ridium Botulinum) was contaminated with rice, then cooked, filled, sealed and stored for long-term storability testing (effect of initial contamination). When making cooked rice using the above polished rice according to the method of Example 3, botulinum bacteria were inoculated so that 10 4 cells per 1 g of soaked rice were cooked, and then cooked to give a class 100.
In a clean room, the gas barrier packaging material was aseptically filled. In addition, an oxygen scavenger is enclosed and sealed in an anaerobic state and stored in a constant temperature bath at 30 ° C for 1, 3, 6, 9, 12
The presence or absence of toxin was determined after a month. In addition, the presence or absence of toxin was determined by the following determination method by administration to mice. Add and mix 100 cc of sterilized water to 50 g of cooked rice,
Leave for hours. After 20 seconds of stomaching with a stomacher, the supernatant is aseptically collected, left for 1 hour, and then treated with a centrifuge (3000 rpm × 40 minutes). The supernatant is collected aseptically, left in hot water at 37 ° C for 10 minutes, then stored in a thermostat at 35 ° C for 40 minutes, and then left at room temperature. 0.4 ml is collected and intraperitoneally injected into the mouse (5 animals per sample). After that, the animals were bred by a conventional method, and one of the five animals that died was (+), and the one that survived in total was (-). The results are summarized (Table 4).
【0040】[0040]
【表4】 コントロールは、グルコノデルタラクトンや食用有機酸
などを使用せずに作った米飯の場合であり、この米飯は
風味や食味は優れているが、長期保存性に劣ることが判
る。炊飯後の米飯のpHを4.0〜4.8となるように
調整することにより食中毒菌の増殖を防止することが可
能であることが判る。[Table 4] The control is the case of cooked rice made without using glucono delta lactone or edible organic acid. It is understood that this cooked rice has excellent flavor and taste, but has poor long-term storage stability. It is understood that it is possible to prevent the growth of food poisoning bacteria by adjusting the pH of cooked rice to be 4.0 to 4.8.
【0041】(実施例9〜11、比較例8〜9)上記精
白米を用いて実施例3の方法に準じて米飯を作る時、下
記のようにして、炊飯後の米飯を上記食中毒菌により汚
染して充填、密封、保存して長期保存性を試験した(充
填時の2次汚染の影響)。上記精白米を用いて実施例3
の方法に準じて米飯を作る時、浸漬米を炊飯し、クラス
100のクリーンルーム内で無菌的にガスバリヤー性の
包材に充填し、併せて脱酸素剤を封入し嫌気状態にした
後、ボツリヌス菌を米飯1g当たり103個となるよう
に接種して、密封し、30℃の恒温槽に保存し、1,
3,6,9,12ヶ月後に毒素の有無を判定した。なお
毒素の有無は、マウスへの投与法によった。初期汚染の
影響に関する試験と同様、検体中1匹でも死亡したもの
を(+)、5匹全数生存しているものを(−)とした。
結果をまとめて(表5)に示す。(Examples 9 to 11 and Comparative Examples 8 to 9) When cooked rice was prepared using the above-mentioned polished rice according to the method of Example 3, cooked rice was cooked with the above food poisoning bacteria as follows. Long-term storability was tested by contaminated filling, sealing, and storage (effect of secondary contamination during filling). Example 3 using the above polished rice
When making cooked rice according to the method of 1., cook the soaked rice, aseptically fill the gas barrier packaging material in a class 100 clean room, and at the same time put the oxygen absorber into the anaerobic state, then botulinum Inoculate with 10 3 bacteria per 1 g of cooked rice, seal, and store in a constant temperature bath at 30 ° C.
The presence or absence of toxin was determined after 3, 6, 9 and 12 months. The presence or absence of the toxin depends on the method of administration to mice. Similar to the test for the effect of initial contamination, one that died in the sample was (+), and one in which all five were alive was (-).
The results are summarized (Table 5).
【0042】[0042]
【表5】 コントロールは、グルコノデルタラクトンや食用有機酸
を使用せずに作った米飯の場合であり、この米飯は風味
や食味は優れているが、長期保存性に劣ることが判る。
炊飯後の米飯のpHを4.0〜4.8となるように調整
することにより食中毒菌の増殖を防止することが可能で
あることが判る。 (実施例12〜14) 精白米を洗米後、炊飯米のpHの平均値が4.5、4.
4および4.3となるように、グルコノデルタラクトン
や食用有機酸あるいはその塩を含む表6に示すpHを有
する溶液中に一定時間浸漬してpHをある程度低下さ
せ、さらに炊飯直前にグルコノデルタラクトンや食用有
機酸あるいはその塩を添加した表6に示すpHを有する
炊き水を用いて炊飯した。そして下記のサンプルの炊飯
米のpHを測定した。結果を表6に示す。直方体の形状
を有する炊飯釜の上面部の四隅と中央部から合計5箇
所、中間部の中央部から1箇所、底面部の四隅と中央部
から合計5箇所サンプリングしてpH測定用サンプルと
した。 (比較例10〜12) 精白米を洗米後、水道水に一定時間浸漬した後、炊飯米
のpHの平均値が4.5、4.4および4.3となるよ
うに、炊飯直前にグルコノデルタラクトンや食用有機酸
あるいはその塩を添加した表6に示すpHを有する炊き
水を用いて炊飯した。そして実施例12〜14と同様に
して炊飯米のpHを測定した。結果をまとめて表6に示
す。 (比較例13〜15) 精白米を洗米後、炊飯米のpHの平均値が4.5、4.
4および4.3となるように、炊飯直前にグルコノデル
タラクトンや食用有機酸あるいはその塩を添加した溶液
中に一定時間浸漬してpHを低下させ、水道水(炊き
水)を用いて炊飯した。そして実施例12〜14と同様
にして炊飯米のpHを測定した。結果をまとめて表6に
示す。[Table 5] The control is the case of cooked rice made without using glucono delta lactone or edible organic acid. It can be seen that this cooked rice has excellent flavor and taste, but poor long-term storage stability.
It is understood that it is possible to prevent the growth of food poisoning bacteria by adjusting the pH of cooked rice to be 4.0 to 4.8. (Examples 12 to 14) After washing polished rice, the average pH of cooked rice is 4.5, 4.
4 and 4.3 so that the pH is lowered to some extent by immersing in a solution containing glucono delta lactone, an edible organic acid or a salt thereof and having a pH shown in Table 6 for a certain period of time. Rice was cooked using cooking water having a pH shown in Table 6 to which delta lactone, an edible organic acid or a salt thereof was added. Then, the pH of the following cooked rice was measured. The results are shown in Table 6. A total of 5 points were sampled from the four corners and the center of the upper surface of the rice cooker having a rectangular parallelepiped shape, one from the center of the middle part, and five from the four corners and the center of the bottom to make a pH measurement sample. (Comparative Examples 10 to 12) After washing polished rice and immersing it in tap water for a certain period of time, gluco was prepared immediately before cooking so that the average value of pH of the cooked rice was 4.5, 4.4 and 4.3. Rice was cooked using cooking water having a pH shown in Table 6 to which nodeltalactone, an edible organic acid or a salt thereof was added. And pH of the cooked rice was measured like Example 12-14. The results are summarized in Table 6. (Comparative Examples 13 to 15) After washing polished rice, the average pH of cooked rice is 4.5, 4.
Immediately before cooking rice, it is immersed in a solution containing glucono delta lactone or an edible organic acid or its salt for a certain period of time to reduce the pH to 4 and 4.3, and then cooked with tap water (cooking water). did. And pH of the cooked rice was measured like Example 12-14. The results are summarized in Table 6.
【表6】 表6の結果から、実施例12〜14の場合は、炊飯米の
最大値と最小値との差(pH範囲)が0.5以下である
ので、pHの平均値が4.3〜4.5となるように調整
すると容易に本発明の炊飯米のpH範囲4.0〜4.8
とすることができる。それに対して比較例10〜12の
場合は、炊飯米の最大値と最小値との差(pH範囲)が
0.8以上であるので、本発明の炊飯米のpH範囲4.
0〜4.8を逸脱する危険性があり、安全性に問題があ
る。比較例13〜15の場合は、炊飯米の最大値と最小
値との差(pH範囲)が0.7以上であるので、やはり
本発明の炊飯米のpH範囲4.0〜4.8を逸脱する危
険性があり、安全性に問題がある。いずれの場合も攪拌
を行ったり、浸漬時間を長くしたりすることによりpH
のバラツキを低減することが可能であるが、米は重量が
あり攪拌を行うことが難しい上に、激しく攪拌を行うと
米の粒子が崩れて仕上がりが悪くなる問題があり、また
浸漬時間を長くすると米の澱粉質が流出し、ベタツキや
コゲの原因となるなどの弊害があり、手間や時間がかか
る割りには有効な手段とならない。炊飯米のpHは原料
米の品質などによっても±0.1程度は変化するので、
安全性の観点から実施例12〜14の方法により炊飯米
のpHを調整することが好ましい。[Table 6] From the results of Table 6, in the case of Examples 12 to 14, the difference between the maximum value and the minimum value (pH range) of the cooked rice is 0.5 or less, so the average value of pH is 4.3 to 4. When adjusted to be 5, the pH range of the cooked rice of the present invention is easily 4.0 to 4.8.
Can be On the other hand, in Comparative Examples 10 to 12, the difference (pH range) between the maximum value and the minimum value of the cooked rice is 0.8 or more, so that the pH range of the cooked rice of the present invention is 4.
There is a risk of deviating from 0 to 4.8 and there is a problem in safety. In Comparative Examples 13 to 15, since the difference (pH range) between the maximum value and the minimum value of cooked rice is 0.7 or more, the pH range of cooked rice of the present invention is set to 4.0 to 4.8. There is a risk of deviation and there is a safety issue. In any case, the pH can be adjusted by stirring or prolonging the immersion time.
However, the rice is heavy and difficult to stir, and vigorous stirring causes the particles of the rice to collapse and the finish to deteriorate. Then, the starch quality of rice leaks out, which causes stickiness and kogation, which is not an effective means because it takes time and labor. Since the pH of cooked rice changes by about ± 0.1 depending on the quality of the raw rice,
From the viewpoint of safety, it is preferable to adjust the pH of cooked rice by the method of Examples 12 to 14.
【0043】[0043]
【発明の効果】以上述べたように、精白米を洗米後、浸
漬水に浸漬し、浸漬水から取り出し、炊飯直前に炊き水
を添加して炊飯後、無菌設備中でガスバリヤー性耐熱容
器中に脱酸素剤と共に充填し、完全に密封する米飯を製
造する時、グルコノデルタラクトンや食用有機酸あるい
はその塩を含有する浸漬水や炊き水を用いて炊飯後の米
飯のpHが4.0〜4.8となるように調整することに
より、本発明の製造方法で製造された米飯は常温での保
存で約6ケ月以上の長期保存性を有すると共に、製造工
程および流通段階において米粒の結着、潰れが生じるこ
とがなく、長期保存しても異味異臭がなく、食感も優れ
たものとなる。さらに調理済み米飯類は、電子レンジあ
るいは熱水中で2〜20分間再加熱して喫食することが
できるため、ファーストフードチェーンやコンビニエン
スストアー等においては、加熱調理設備の省力化が図れ
るので、産業上の利用価値は甚だ大きい。Industrial Applicability As described above, after washing polished rice, soaking it in immersion water, taking it out of the immersion water, adding the cooking water immediately before cooking rice, and cooking the rice, and then in a gas barrier heat-resistant container in a sterile facility. When producing cooked rice which is filled with deoxidizer and completely sealed, the pH of cooked rice after cooking is adjusted by using immersion water or cooking water containing glucono delta lactone, edible organic acid or its salt. The rice cooked by the manufacturing method of the present invention has a long-term shelf life of about 6 months or longer when stored at room temperature, and at the same time, the grain size of the rice grains is adjusted in the manufacturing process and distribution stage. It does not cause wearing or crushing, has no offensive odor even after long-term storage, and has an excellent texture. Furthermore, cooked cooked rice can be reheated and eaten in a microwave oven or hot water for 2 to 20 minutes, which can save labor in heating and cooking equipment in fast food chains, convenience stores, etc. The utility value above is enormous.
【図1】 精白米を各種濃度のクエン酸水溶液に浸漬し
た時の米のpHの経時変化を示すグラフである。FIG. 1 is a graph showing changes in pH of rice with time when polished rice is immersed in an aqueous citric acid solution having various concentrations.
───────────────────────────────────────────────────── フロントページの続き (72)発明者 風間 朗弘 東京都板橋区宮本町38−8 ヱスビー食品 株式会社中央研究所内 (72)発明者 牟田 智英 東京都板橋区宮本町38−8 ヱスビー食品 株式会社中央研究所内 (72)発明者 椎谷 聡一 東京都板橋区宮本町38−8 ヱスビー食品 株式会社中央研究所内 (56)参考文献 特開 平2−128663(JP,A) 特開 昭59−88053(JP,A) 特開 平3−87152(JP,A) 特開 昭60−172262(JP,A) 特開 昭53−12438(JP,A) 特開 昭63−248353(JP,A) ─────────────────────────────────────────────────── ─── Continuation of the front page (72) Inventor Akihiro Kazama 38-8 Miyamoto-cho, Itabashi-ku, Tokyo Esubie Foods Co., Ltd. Central Research Institute (72) Inventor Tomohide Muta 38-8 Miyamoto-cho, Itabashi-ku, Tokyo Esubie Foods Co., Ltd. Inside Central Research Laboratory (72) Inventor Soichi Shiiya 38-8 Miyamoto-cho, Itabashi-ku, Tokyo Esu Foods Co., Ltd. Central Research Laboratory (56) Reference JP-A-2-128663 (JP, A) JP-A-59-88053 ( JP, A) JP 3-87152 (JP, A) JP 60-172262 (JP, A) JP 53-12438 (JP, A) JP 63-248353 (JP, A)
Claims (3)
で浸漬水から取り出し、炊飯直前に炊き水を添加して炊
飯後、無菌設備中でガスバリヤー性酎熱容器中に脱酸素
剤と共に充填し、完全に密封する米飯の製造方法におい
て、グルコノデルタラクトン、グルコン酸およびその塩
あるいはこれらの混合物から選択される少なくとも一つ
を必須成分として含有する浸漬水および炊き水を用いて
炊飯後の米飯のpHが4.0〜4.8となるように調整
し、ボツリヌス菌をはじめとする食中毒菌の増殖を防止
することを特徴とする安全かつ長期保存可能な米飯の製
造方法。1. Washing polished rice, immersing it in immersion water, then taking it out of the immersion water, adding the cooking water just before cooking rice and cooking the rice, and then deoxidizing it in a gas barrier shochu container in a sterile facility. In the method for producing cooked rice, which is filled together with and completely sealed, cooked rice using immersion water and cooking water containing at least one selected from gluconodeltalactone, gluconic acid and salts thereof or mixtures thereof as essential ingredients. A method for producing safe and long-term storable rice, which comprises adjusting the pH of the later cooked rice to be 4.0 to 4.8 and preventing the growth of food poisoning bacteria such as botulinum bacteria.
酸、コハク酸、乳酸、酢酸、アジピン酸、フィチン酸、
アスコルビン酸およびその塩あるいはこれらの混合物か
ら選択される少なくとも一つの食用有機酸をさらに含有
する浸漬水および/または炊き水を用いることを特徴と
する請求項1に記載の安全かつ長期保存可能な米飯の製
造方法。2. Citric acid, tartaric acid, malic acid, fumaric acid, succinic acid, lactic acid, acetic acid, adipic acid, phytic acid,
The safe and long-term storable cooked rice according to claim 1, wherein immersion water and / or cooking water further containing at least one edible organic acid selected from ascorbic acid and salts thereof or a mixture thereof are used. Manufacturing method.
シウム塩およびこれらの混合物から選択される少なくと
も一つの有機酸の塩であることを特徴とする請求項1あ
るいは請求項2に記載の安全かつ長期保存可能な米飯の
製造方法。3. The safe according to claim 1 or 2, characterized in that the salt is a salt of at least one organic acid selected from potassium salt, sodium salt, calcium salt and mixtures thereof. A method for producing cooked rice that can be stored for a long period of time.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP3359252A JPH0789879B2 (en) | 1991-12-27 | 1991-12-27 | A safe and long-term storable rice production method |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP3359252A JPH0789879B2 (en) | 1991-12-27 | 1991-12-27 | A safe and long-term storable rice production method |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPH05176693A JPH05176693A (en) | 1993-07-20 |
| JPH0789879B2 true JPH0789879B2 (en) | 1995-10-04 |
Family
ID=18463547
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP3359252A Expired - Fee Related JPH0789879B2 (en) | 1991-12-27 | 1991-12-27 | A safe and long-term storable rice production method |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH0789879B2 (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2004033131A (en) * | 2002-07-04 | 2004-02-05 | S & B Foods Inc | Method for producing sterile boiled brown rice |
Families Citing this family (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DK0821884T3 (en) * | 1996-08-02 | 2005-02-21 | Puratos Nv | Process for the preparation of softened grains for food and packaging thereof, ready for use |
| JP4878556B2 (en) * | 2007-01-09 | 2012-02-15 | ヱスビー食品株式会社 | Room temperature food set and processed cooked rice using the same |
| US20120003369A1 (en) * | 2010-06-30 | 2012-01-05 | Athula Ekanayake | Acidification of Food Products |
| JP5805544B2 (en) * | 2012-01-06 | 2015-11-04 | ヱスビー食品株式会社 | Wakame rice in a container and its manufacturing method |
| JP6343117B2 (en) * | 2012-07-17 | 2018-06-13 | テーブルマーク株式会社 | Method for producing sealed food |
| JP6576629B2 (en) * | 2014-10-31 | 2019-09-18 | 上野製薬株式会社 | Life improvement agent for cooked rice and method for improving shelf life of cooked rice |
| JP2017055776A (en) * | 2017-01-04 | 2017-03-23 | テーブルマーク株式会社 | Method for producing sealed food |
Family Cites Families (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5312438A (en) * | 1976-07-21 | 1978-02-03 | Toyo Suisan Kaisha | Production of portable boiled rice |
| JPS5930386B2 (en) * | 1982-11-10 | 1984-07-26 | 株式会社春陽堂 | Method for producing cooked rice food |
| JPS60172262A (en) * | 1984-02-17 | 1985-09-05 | Shiyunyoudou:Kk | Preparation of cooked rice food |
| JP2829989B2 (en) * | 1988-11-05 | 1998-12-02 | 三菱瓦斯化学株式会社 | Cooked rice packaging |
| JPH0387152A (en) * | 1989-08-31 | 1991-04-11 | Satake Eng Co Ltd | Rice boiling |
-
1991
- 1991-12-27 JP JP3359252A patent/JPH0789879B2/en not_active Expired - Fee Related
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2004033131A (en) * | 2002-07-04 | 2004-02-05 | S & B Foods Inc | Method for producing sterile boiled brown rice |
Also Published As
| Publication number | Publication date |
|---|---|
| JPH05176693A (en) | 1993-07-20 |
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