JPH0795002B2 - Sensor element - Google Patents
Sensor elementInfo
- Publication number
- JPH0795002B2 JPH0795002B2 JP62099323A JP9932387A JPH0795002B2 JP H0795002 B2 JPH0795002 B2 JP H0795002B2 JP 62099323 A JP62099323 A JP 62099323A JP 9932387 A JP9932387 A JP 9932387A JP H0795002 B2 JPH0795002 B2 JP H0795002B2
- Authority
- JP
- Japan
- Prior art keywords
- substrate
- shield
- sensitive film
- sensitive
- sensor element
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
Classifications
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N27/00—Investigating or analysing materials by the use of electric, electrochemical, or magnetic means
- G01N27/02—Investigating or analysing materials by the use of electric, electrochemical, or magnetic means by investigating impedance
- G01N27/04—Investigating or analysing materials by the use of electric, electrochemical, or magnetic means by investigating impedance by investigating resistance
- G01N27/12—Investigating or analysing materials by the use of electric, electrochemical, or magnetic means by investigating impedance by investigating resistance of a solid body in dependence upon absorption of a fluid; of a solid body in dependence upon reaction with a fluid, for detecting components in the fluid
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N33/00—Investigating or analysing materials by specific methods not covered by groups G01N1/00 - G01N31/00
- G01N33/0004—Gaseous mixtures, e.g. polluted air
- G01N33/0009—General constructional details of gas analysers, e.g. portable test equipment
- G01N33/0027—General constructional details of gas analysers, e.g. portable test equipment concerning the detector
- G01N33/0031—General constructional details of gas analysers, e.g. portable test equipment concerning the detector comprising two or more sensors, e.g. a sensor array
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Analytical Chemistry (AREA)
- General Health & Medical Sciences (AREA)
- Pathology (AREA)
- Immunology (AREA)
- Physics & Mathematics (AREA)
- Engineering & Computer Science (AREA)
- Biochemistry (AREA)
- General Physics & Mathematics (AREA)
- Combustion & Propulsion (AREA)
- Medicinal Chemistry (AREA)
- Food Science & Technology (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- Investigating Or Analyzing Materials By The Use Of Electric Means (AREA)
- Photometry And Measurement Of Optical Pulse Characteristics (AREA)
Description
【発明の詳細な説明】 <産業上の利用分野> 本発明は、参照用と検知用の少くとも2個以上の感応膜
を有するセンサ素子に関し、特に湿度,ガスまたは赤外
線センサに関するものである。The present invention relates to a sensor element having at least two sensitive films for reference and detection, and more particularly to a humidity, gas or infrared sensor.
<従来の技術とその問題点> 従来のサーミスタ湿度センサの構造断面図を第3図に示
す。これはサーミスタビード(7)をリード線(8)で
両側から支持した構造を有し、空気中の湿度変化により
サーミスタビード(7)が発生する熱量の放散状態が変
化する際のサーミスタビード(7)の温度変化を抵抗変
化として検知するものである。サーミスタには抵抗温度
係数の大きい材料が用いられ、感度の向上が図られてい
る。またサーミスタビード(7)から発生する熱量がリ
ード線(8)を通して逃散し難いようにリード線(8)
には極細の白金線が用いられている。湿度変化によるサ
ーミスタの抵抗変化は概して小さいため、電源電圧変動
や周囲温度変化などの影響をキャンセルする必要があ
る。そのために参照用と検知用の2つのサーミスタを設
け、参照用サーミスタは乾燥空気を封入した鑵(9)
に、また検知用サーミスタは外気にふれるよう小孔の開
いた鑵(9′)にそれぞれ納められている。<Conventional Technology and Its Problems> FIG. 3 shows a structural cross-sectional view of a conventional thermistor humidity sensor. This has a structure in which a thermistor bead (7) is supported by lead wires (8) from both sides, and the thermistor bead (7) is used when the heat dissipation state of the thermistor bead (7) changes due to humidity change in the air. ), The temperature change is detected as a resistance change. A material having a large resistance temperature coefficient is used for the thermistor to improve the sensitivity. Also, to prevent the amount of heat generated from the thermistor bead (7) from escaping through the lead wire (8), the lead wire (8)
An extremely fine platinum wire is used for. Since the resistance change of the thermistor due to the humidity change is generally small, it is necessary to cancel the influence of the power supply voltage change and the ambient temperature change. For that purpose, two thermistors for reference and detection are provided, and the thermistor for reference is a bite (9) containing dry air.
In addition, the thermistor for detection is housed in an ale (9 ') having a small hole so that it can be exposed to the outside air.
しかしながら鑵パッケージは組立に手間を要しコスト高
となる上必然的に大型になるという欠点を有していた。However, the iron bag package has a drawback that it requires a lot of labor for assembling, the cost is high, and the package is inevitably large.
<発明の目的> 本発明は以上の点に鑑みてなされたもので、気密封止を
得るために鑵パッケージを用いず、参照用感応膜を遮蔽
体で覆った小型で低価格のセンサ素子を提供することを
目的とする。<Objects of the Invention> The present invention has been made in view of the above points, and provides a small and low-priced sensor element in which a reference sensitive film is covered with a shield without using a bag package for obtaining hermetic sealing. The purpose is to provide.
<実施例> 本発明の一実施例であるセンサ素子の斜視図を第1図
(A)に構造断面図を同図(B)にそれぞれ示す。<Example> A perspective view of a sensor element according to an embodiment of the present invention is shown in FIG. 1 (A), and a structural sectional view thereof is shown in FIG. 1 (B).
シリコン基板(1)上に堆積されたSiO2スパッタ膜や熱
酸化等から成る絶縁膜(2)にEPW(エチレンジアミン
−ピロカテコール−水)等を用いたシリコンの異方性エ
ッチングにより1対の貫通溝が刻設され、この溝で挾ま
れた帯状部がブリッジ(3)となる。その上に薄膜サー
ミスタ材料からなる感応膜(4)が重畳されている。シ
リコン基板(1)は上記エッチングにより貫通孔及びブ
リッジ(3)下方の部分が除去され、空洞部となってい
る。従ってブリッジ(3)は両端で支えられることとな
る。またここでは図示されていないが、感応膜(4)の
インピーダンスを検出するための1対の櫛状電極が感応
膜(4)の上部もしくは下部に蒸着されてある。ブリッ
ジ(3)は感応膜(4)の熱容量を小さくするとともに
感応膜(4)から発生する熱量が基板(1)へ容易に逃
散しないように設けられたもので低熱伝導性の電気絶縁
材料が用いられる。上記ブリッジ(3)は並設して基板
(1)上に2箇所形成され、他方のブリッジ(3)上に
は同じ感応膜(5)が載置されている。即ち同種の感応
膜(4)及び(5)が同一基板(1)上に少なくとも2
箇所で並置されている。第1の感応膜(4)は外界に露
呈され、例えば空気中の湿度変化により感応膜(4)か
らの熱の放散状態が変わり感応膜(4)のインピーダン
スが変化する。A pair of penetrations by anisotropic etching of silicon using EPW (ethylenediamine-pyrocatechol-water) etc. for the insulating film (2) made of SiO 2 sputtered film or thermal oxidation deposited on the silicon substrate (1) A groove is engraved, and the strip-shaped portion sandwiched by the groove serves as a bridge (3). A sensitive film (4) made of a thin film thermistor material is superposed on it. The silicon substrate (1) has a hollow portion in which the through hole and the portion below the bridge (3) are removed by the above etching. Therefore, the bridge (3) is supported at both ends. Although not shown here, a pair of comb-shaped electrodes for detecting the impedance of the sensitive film (4) are vapor-deposited on the upper or lower part of the sensitive film (4). The bridge (3) is provided so as to reduce the heat capacity of the sensitive film (4) and prevent the amount of heat generated from the sensitive film (4) from easily escaping to the substrate (1). Used. The bridges (3) are arranged side by side at two positions on the substrate (1), and the same sensitive film (5) is placed on the other bridge (3). That is, at least two sensitive films (4) and (5) of the same kind are formed on the same substrate (1).
They are juxtaposed in some places. The first sensitive film (4) is exposed to the outside world, and the state of heat dissipation from the sensitive film (4) changes due to, for example, changes in humidity in the air, and the impedance of the sensitive film (4) changes.
一方、直方体ブロックのシリコンを片面からハーフエッ
チングして凹陥部を形成した遮蔽体(6)を低融点ガラ
スさ接着剤を用いて第2の感応膜(5)が載置されてい
る基板(1)の上面に接合することによって第2の感応
膜(5)は基板(1)と遮蔽体(6)内に気密封止さ
れ、外界の湿度変化の影響を受けない。また外気温が変
動したとき第1の感応膜(4)のインピーダンスは変化
するが第2の感応膜(5)のそれも同様に変化するの
で、温度補償が行なわれ2つの感応膜(4)(5)の出
力差から外界の湿度を正確に検知することが可能であ
る。この場合従来例のように鑵によって封止するよりも
本実施例のように小型の遮蔽体(6)を用いた方が、素
子全体の熱容量を小さくでき、外気温の変動に対する両
感応膜(4)(5)の追従応答性は速くなる。On the other hand, the shield (6) having a recess formed by half-etching the silicon of the rectangular parallelepiped from one side is formed on the substrate (1) on which the second sensitive film (5) is mounted using a low melting point glass adhesive. The second sensitive film (5) is hermetically sealed in the substrate (1) and the shield (6) by being bonded to the upper surface of (1), and is not affected by the change of humidity in the external environment. When the outside air temperature fluctuates, the impedance of the first sensitive film (4) changes, but the impedance of the second sensitive film (5) also changes, so that temperature compensation is performed and the two sensitive films (4). It is possible to accurately detect the external humidity from the output difference of (5). In this case, it is possible to reduce the heat capacity of the entire element by using a small shield (6) as in the present embodiment rather than by sealing with iron as in the conventional example, and it is possible to reduce the sensitivity of both sensitive films ( 4) The tracking response of (5) becomes faster.
上記実施例のセンサ素子は、基板(1)上の絶縁膜
(2)や感応膜(4)(5)の形成そして遮蔽体(6)
のエッチング及び接合まで一貫してウェーハ単位のバッ
チ処理ができる為、量産に適し安価に製造され得る。ま
た小型であるため消費電力が小さいという利点を有す
る。基板や遮蔽体としてシリコンといったIV族元素以外
にガリウムヒ素等のIII−V族化合物半導体を用いるこ
とも可能であり、また基板と遮蔽体の接合法として電界
印加接合も利用できる。さらに絶縁膜(2)の形状を第
2図に示すような片持ち梁(カンチレバー)(3′)に
することもできあるいはダイアフラムにしてもよい。第
2図は本発明の他の実施例を示すセンサ素子の構成断面
図であり第1図と同一符号同一内容を示す。この他、同
様な原理でガスセンサが得られる。ガス種の選択性が必
要な場合は、ガス選択透過膜を感応膜上やパッケージの
通気孔に設けたり、ガスクロマトグラフィーに用いられ
るようなカラムによるガス種の分離が考えられる。参照
用の封入ガスは、検知ガス種に応じて適宜選択してよく
真空であってもよい。In the sensor element of the above embodiment, the insulating film (2) and the sensitive films (4) and (5) are formed on the substrate (1) and the shield (6) is formed.
Since batch processing can be performed on a wafer-by-wafer basis consistently up to the etching and bonding, it is suitable for mass production and can be manufactured at low cost. In addition, the small size has an advantage of low power consumption. It is also possible to use III-V group compound semiconductors such as gallium arsenide as the substrate and the shield in addition to the group IV element such as silicon, and electric field application bonding can be used as the bonding method between the substrate and the shield. Further, the shape of the insulating film (2) may be a cantilever (3 ') as shown in FIG. 2 or may be a diaphragm. FIG. 2 is a sectional view of the configuration of a sensor element showing another embodiment of the present invention, in which the same symbols as those in FIG. Besides, a gas sensor can be obtained by the same principle. When gas species selectivity is required, it is possible to provide a gas selective permeable membrane on the sensitive membrane or in a vent hole of the package, or to separate the gas species by a column such as used in gas chromatography. The reference sealed gas may be appropriately selected depending on the type of detection gas and may be vacuum.
また感応膜上に金黒等を蒸着したセンサ素子は、赤外線
センサとして応用できる。この場合、湿度センサと異な
り感応膜は加熱されず、赤外線照射による感応膜の温度
上昇を検知する。Further, the sensor element in which gold black or the like is deposited on the sensitive film can be applied as an infrared sensor. In this case, unlike the humidity sensor, the sensitive film is not heated, and the temperature rise of the sensitive film due to infrared irradiation is detected.
シリコンは赤外線を透過するので参照用感応部の遮蔽体
として用いる場合その上に赤外線反射膜を形成する必要
がある。Since silicon transmits infrared rays, it is necessary to form an infrared reflection film on the reference sensitive portion when it is used as a shield.
また同一基板上に複数個の感応膜を設け湿度・ガス複合
センサを形成することも可能である。It is also possible to form a humidity / gas composite sensor by providing a plurality of sensitive films on the same substrate.
<発明の効果> 本発明のセンサ素子は、基板上の絶縁膜や感応膜の形
成、そして遮蔽体のエッチング及び基板との接合まで一
貫してウェーハ単位のバッチ処理ができるため、量産に
適し、安価に製造され得る。その上センサ素子が小型で
あるため実用性が高く、かつ参照用感応部を基板と同一
の材料である一体成形の小型の遮蔽体で気密封止してい
るので、熱容量を大幅に低減することができ、外気温の
変動に対する追従性が良く、高精度で低消費電力である
という利点を有する。<Effects of the Invention> The sensor element of the present invention is suitable for mass production because it can consistently perform batch processing on a wafer-by-wafer basis, including formation of an insulating film or a sensitive film on a substrate, etching of a shield, and bonding with a substrate. It can be manufactured inexpensively. In addition, the sensor element is small, so it is highly practical, and the reference sensitive part is hermetically sealed with a small, integrally molded shield made of the same material as the substrate, which significantly reduces the heat capacity. It has the advantages of being capable of following changes in the outside temperature, having high accuracy, and low power consumption.
第1図(A)は本発明の1実施例を示すセンサ素子の斜
視図、同図(B)は基線A−A′における構造断面図で
ある。 第2図は絶縁膜を片持ち梁(カンチレバー)状にした本
発明の他の実施例を示すセンサ素子の構造断面図であ
る。第3図は従来のサーミスタ湿度センサの構造断面図
である。 1……基板、2……絶縁膜、3……ブリッジ、3′……
カンチレバー、4……第1の感応膜、5……第2の感応
膜、6……遮蔽体、7……サーミスタビード、8……リ
ード線、9……鑵FIG. 1 (A) is a perspective view of a sensor element showing one embodiment of the present invention, and FIG. 1 (B) is a structural sectional view taken along the line AA ′. FIG. 2 is a structural sectional view of a sensor element showing another embodiment of the present invention in which the insulating film has a cantilever shape. FIG. 3 is a structural sectional view of a conventional thermistor humidity sensor. 1 ... Substrate, 2 ... Insulating film, 3 ... Bridge, 3 '...
Cantilever, 4 ... First sensitive film, 5 ... Second sensitive film, 6 ... Shield, 7 ... Thermistor bead, 8 ... Lead wire, 9 ...
───────────────────────────────────────────────────── フロントページの続き (72)発明者 枅川 正也 大阪府大阪市阿倍野区長池町22番22号 シ ャープ株式会社内 (72)発明者 田渕 宏樹 大阪府大阪市阿倍野区長池町22番22号 シ ャープ株式会社内 (56)参考文献 特開 昭57−178419(JP,A) 特開 昭60−167388(JP,A) 米国特許4177667(US,A) 米国特許4337658(US,A) 米国特許4343768(US,A) ─────────────────────────────────────────────────── ─── Continuation of the front page (72) Inventor Masaya Kabagawa 22-22 Nagaike-cho, Abeno-ku, Osaka-shi, Osaka Within Sharp Co., Ltd. (72) Hiroki Tabuchi 22-22 Nagaike-cho, Abeno-ku, Osaka-shi, Osaka Within Sharp Corporation (56) Reference JP-A-57-178419 (JP, A) JP-A-60-167388 (JP, A) US Patent 4177667 (US, A) US Patent 4337658 (US, A) US Patent 4343768 (US, A)
Claims (2)
るブリッジ状、片持ち梁状、またはダイアフラム状に加
工された絶縁支持体に載置された感応膜を2個並設し、
第1の感応膜は外界に露呈されかつ被検知量の変化に伴
ってインピーダンスが変化し、空隙部を有するように加
工された一体成形の遮蔽体は前記基板に固着され、第2
の感応膜は前記遮蔽体により気密封止されてなり、この
とき、前記基板及び遮蔽体がシリコン又はIII−V族化
合物半導体の中から選択された同一材料からなることを
特徴とするセンサ素子。1. Two sensitive films placed on an insulating support processed in a bridge shape, a cantilever shape, or a diaphragm shape in which a part of a substrate is anisotropically etched, are arranged in parallel,
The first sensitive film is exposed to the outside world, and the impedance changes in accordance with the change in the detected amount, and the integrally molded shield processed to have a void is fixed to the substrate.
The sensitive film of (1) is hermetically sealed by the shield, and at this time, the substrate and the shield are made of the same material selected from silicon or III-V group compound semiconductors.
線である特許請求の範囲第1項記載のセンサ素子。2. The sensor element according to claim 1, wherein the detected amount is water vapor, gas, or infrared rays.
Priority Applications (4)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP62099323A JPH0795002B2 (en) | 1987-04-22 | 1987-04-22 | Sensor element |
| US07/078,741 US4928513A (en) | 1986-07-29 | 1987-07-28 | Sensor |
| DE3724966A DE3724966C3 (en) | 1986-07-29 | 1987-07-28 | sensor |
| GB8717919A GB2194845B (en) | 1986-07-29 | 1987-07-29 | A sensor |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP62099323A JPH0795002B2 (en) | 1987-04-22 | 1987-04-22 | Sensor element |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS63263426A JPS63263426A (en) | 1988-10-31 |
| JPH0795002B2 true JPH0795002B2 (en) | 1995-10-11 |
Family
ID=14244428
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP62099323A Expired - Fee Related JPH0795002B2 (en) | 1986-07-29 | 1987-04-22 | Sensor element |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH0795002B2 (en) |
Families Citing this family (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH0795054B2 (en) * | 1988-12-29 | 1995-10-11 | シャープ株式会社 | Humidity sensor |
| EP0376721B1 (en) * | 1988-12-29 | 1998-07-15 | Sharp Kabushiki Kaisha | Moisture-sensitive device |
| JP2865939B2 (en) * | 1992-04-10 | 1999-03-08 | シャープ株式会社 | Sensor element |
| JP4575846B2 (en) * | 2005-06-07 | 2010-11-04 | 本田技研工業株式会社 | Gas sensor |
| US10598621B2 (en) * | 2017-04-11 | 2020-03-24 | Invensense, Inc. | Gas sensing device with chemical and thermal conductivity sensing |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4177667A (en) | 1978-03-03 | 1979-12-11 | The United States Of America As Represented By The Secretary Of The Navy | Quick response humidity chamber |
| US4337658A (en) | 1980-10-14 | 1982-07-06 | Honeywell Inc. | Humidity sensor |
| US4343768A (en) | 1979-07-25 | 1982-08-10 | Ricoh Co., Ltd. | Gas detector |
Family Cites Families (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS57178149A (en) * | 1981-04-28 | 1982-11-02 | Ricoh Co Ltd | Manufacture of electric heater |
| JPS60167388A (en) * | 1984-12-17 | 1985-08-30 | Mitsuteru Kimura | Photodetector |
-
1987
- 1987-04-22 JP JP62099323A patent/JPH0795002B2/en not_active Expired - Fee Related
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4177667A (en) | 1978-03-03 | 1979-12-11 | The United States Of America As Represented By The Secretary Of The Navy | Quick response humidity chamber |
| US4343768A (en) | 1979-07-25 | 1982-08-10 | Ricoh Co., Ltd. | Gas detector |
| US4337658A (en) | 1980-10-14 | 1982-07-06 | Honeywell Inc. | Humidity sensor |
Also Published As
| Publication number | Publication date |
|---|---|
| JPS63263426A (en) | 1988-10-31 |
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