JPH0814015B2 - Non-oriented electrical steel sheet having excellent magnetic properties and surface properties and method for producing the same - Google Patents
Non-oriented electrical steel sheet having excellent magnetic properties and surface properties and method for producing the sameInfo
- Publication number
- JPH0814015B2 JPH0814015B2 JP2006799A JP679990A JPH0814015B2 JP H0814015 B2 JPH0814015 B2 JP H0814015B2 JP 2006799 A JP2006799 A JP 2006799A JP 679990 A JP679990 A JP 679990A JP H0814015 B2 JPH0814015 B2 JP H0814015B2
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- rolling
- steel sheet
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- hot
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- 238000004519 manufacturing process Methods 0.000 title claims description 15
- 229910000565 Non-oriented electrical steel Inorganic materials 0.000 title claims description 14
- 238000000137 annealing Methods 0.000 claims description 66
- 229910000831 Steel Inorganic materials 0.000 claims description 58
- 239000010959 steel Substances 0.000 claims description 58
- 238000005097 cold rolling Methods 0.000 claims description 44
- 230000009467 reduction Effects 0.000 claims description 40
- 238000005096 rolling process Methods 0.000 claims description 39
- 238000000034 method Methods 0.000 claims description 26
- 239000013078 crystal Substances 0.000 claims description 19
- 239000000463 material Substances 0.000 claims description 17
- 239000012535 impurity Substances 0.000 claims description 13
- 238000005098 hot rolling Methods 0.000 claims description 10
- 229910052757 nitrogen Inorganic materials 0.000 claims description 9
- 229910052717 sulfur Inorganic materials 0.000 claims description 9
- 229910052698 phosphorus Inorganic materials 0.000 claims description 6
- 238000005554 pickling Methods 0.000 claims description 6
- 229910052799 carbon Inorganic materials 0.000 claims description 5
- 238000001953 recrystallisation Methods 0.000 claims description 5
- 238000010008 shearing Methods 0.000 claims description 5
- 238000001816 cooling Methods 0.000 claims description 4
- 230000008569 process Effects 0.000 claims description 3
- 238000004080 punching Methods 0.000 claims description 3
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical group [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 19
- 230000004907 flux Effects 0.000 description 14
- 230000000694 effects Effects 0.000 description 12
- 239000012467 final product Substances 0.000 description 9
- 229910052742 iron Inorganic materials 0.000 description 8
- 230000007423 decrease Effects 0.000 description 5
- 238000005516 engineering process Methods 0.000 description 5
- 239000002245 particle Substances 0.000 description 5
- 239000000203 mixture Substances 0.000 description 4
- 239000000047 product Substances 0.000 description 4
- 238000002791 soaking Methods 0.000 description 4
- 238000004804 winding Methods 0.000 description 4
- 230000002411 adverse Effects 0.000 description 3
- 230000035882 stress Effects 0.000 description 3
- 230000009466 transformation Effects 0.000 description 3
- 230000002159 abnormal effect Effects 0.000 description 2
- 230000006866 deterioration Effects 0.000 description 2
- 230000001771 impaired effect Effects 0.000 description 2
- 150000003568 thioethers Chemical class 0.000 description 2
- 230000009471 action Effects 0.000 description 1
- 230000032683 aging Effects 0.000 description 1
- 229910001566 austenite Inorganic materials 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 230000001276 controlling effect Effects 0.000 description 1
- 239000011162 core material Substances 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 238000005265 energy consumption Methods 0.000 description 1
- 230000001747 exhibiting effect Effects 0.000 description 1
- 230000006698 induction Effects 0.000 description 1
- 238000011835 investigation Methods 0.000 description 1
- 150000004767 nitrides Chemical class 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 230000035515 penetration Effects 0.000 description 1
- 239000002244 precipitate Substances 0.000 description 1
- 230000001105 regulatory effect Effects 0.000 description 1
- 238000003303 reheating Methods 0.000 description 1
- 239000006104 solid solution Substances 0.000 description 1
- 239000002436 steel type Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 230000009772 tissue formation Effects 0.000 description 1
- 229910000859 α-Fe Inorganic materials 0.000 description 1
Landscapes
- Manufacturing Of Steel Electrode Plates (AREA)
- Soft Magnetic Materials (AREA)
Description
【発明の詳細な説明】 〔産業上の利用分野〕 この発明は、磁気特性、特に磁束密度が優れ、しかも
表面性状の良好な無方向性電磁鋼板およびその製造方法
に関するものである。Description: TECHNICAL FIELD The present invention relates to a non-oriented electrical steel sheet having excellent magnetic properties, particularly magnetic flux density, and good surface properties, and a method for producing the same.
モーター、変圧器等の鉄芯材料として使用される無方
向性電磁鋼板は、これら電気機器の高効率化、小型化を
図るため鉄損が低く且つ磁束密度が高いことが要求され
る。Non-oriented electrical steel sheets used as iron core materials for motors, transformers, etc. are required to have low iron loss and high magnetic flux density in order to make these electric devices highly efficient and compact.
無方向性電磁鋼板の磁気特性を向上させるためには、
冷間圧延前の素材のフェライト結晶粒径を十分に粗大化
しておくことが有利であることは従来より知られてい
る。このような観点から、磁気特性を向上させる方法と
して下記の技術が開示されている。In order to improve the magnetic properties of the non-oriented electrical steel sheet,
It has been conventionally known that it is advantageous to sufficiently coarsen the ferrite crystal grain size of the material before cold rolling. From this point of view, the following techniques have been disclosed as a method for improving magnetic properties.
1)熱間圧延後、高温で巻取りを行ない、鋼帯の保有す
る熱で自己焼鈍を行なう技術(例えば、特公昭57−4313
2号)。1) After hot rolling, a technique of performing high temperature winding and self-annealing with the heat of the steel strip (for example, Japanese Patent Publication No.57-4313).
No. 2).
2)Ar3変態温度を超える温度で熱間圧延を終了した鋼
帯に、熱間状態で3〜30%の塑性歪を導入し、高温で巻
取り自己焼鈍させる技術(例えば、特開昭60−258414
号)。2) A technique of introducing 3 to 30% plastic strain in a hot state into a steel strip that has been hot-rolled at a temperature higher than the Ar 3 transformation temperature, and winding and self-annealing at a high temperature (for example, Japanese Patent Laid-Open No. Sho 60). −258414
issue).
3)圧延終了温度、巻取温度を制御した特定条件下で熱
間圧延を終了した鋼帯に焼鈍を施す技術(例えば、特開
昭58−204126号)。3) A technique of annealing a steel strip that has been hot-rolled under specific conditions in which the rolling end temperature and the coiling temperature are controlled (for example, JP-A-58-204126).
4)熱間圧延後の鋼帯に軽度のスキンパス圧延を施した
後、焼鈍を行なう技術(例えば、特公昭45−22211号、
特開昭63−186823号、特開平1−139721号)。4) A technique of performing mild skin pass rolling on the steel strip after hot rolling and then annealing (for example, Japanese Patent Publication No.
JP-A-63-186823, JP-A-1-139721).
5)熱間圧延後の鋼帯に予備焼鈍を施した後、軽度の冷
間圧延を行ない、さらに再加熱して焼鈍を行なう技術
(例えば、特開平1−191741号)。5) A technique of performing pre-annealing on the steel strip after hot rolling, then performing light cold rolling and further reheating to anneal (for example, Japanese Patent Laid-Open No. 1-191741).
上述した各種技術の中で、特公昭57−43132号、特開
昭60−258414号公報で開示されている高温巻取りによる
自己焼鈍の技術は、熱延板の結晶粒成長が不十分であ
り、結晶粒を十分に粗粒化させめためには、鋼板を極め
て高温で巻取る必要がある。しかし、このような高温巻
取を行なうと、後工程での酸洗性が劣化し、さらに粒界
酸化を生じやすく、最終製品の表面性状を損なうという
問題がある。Among the various techniques described above, the technique of self-annealing by high-temperature winding disclosed in JP-B-57-43132 and JP-A-60-258414 is insufficient in crystal grain growth of a hot rolled sheet. In order to make the crystal grains sufficiently coarse, it is necessary to wind the steel sheet at an extremely high temperature. However, when such high-temperature winding is performed, there is a problem that the pickling property in the subsequent step is deteriorated, grain boundary oxidation is more likely to occur, and the surface quality of the final product is impaired.
また、特開昭58−204126号公報に開示されている熱延
板焼鈍を施す技術では、熱延終了温度を700℃以下の低
温にする必要があり、圧延機の負荷が大きくなるという
問題がある。さらに、この技術は熱延板焼鈍前の熱延鋼
帯を微細な結晶組織とし、粒界エネルギーを駆動力とし
た2次再結晶的な異常粒成長により粗大粒を得ようとす
るものであるため、組織形成が不安定であり、安定して
最適な冷圧前組織に制御することは困難である。Further, in the technique of performing hot-rolled sheet annealing disclosed in JP-A-58-204126, it is necessary to set the hot-rolling end temperature to a low temperature of 700 ° C. or lower, which causes a problem that the load of the rolling mill increases. is there. Further, this technique is intended to obtain coarse grains by the secondary recrystallization abnormal grain growth using the grain boundary energy as a driving force, with the hot rolled steel strip before annealing of the hot rolled sheet having a fine crystal structure. Therefore, the tissue formation is unstable, and it is difficult to stably control the optimal pre-cold pressure tissue.
これに対し、上記4)、5)の熱延板に軽度の圧延を
付加した後、焼鈍を行なう技術では、歪エネルギーを駆
動力とした異常粒成長を起こすため、前述の熱延板焼鈍
のみを行なう場合よりも粗粒化が促進される。On the other hand, in the technique of annealing after applying mild rolling to the hot rolled sheets of 4) and 5) above, abnormal grain growth using strain energy as a driving force occurs, so that only the above-mentioned hot rolled sheet annealing is performed. Coarsening is promoted as compared with the case of performing.
しかし、特公昭45−22211号公報に開示された技術で
は、C,Sが高いため粒成長性が劣り、熱延板焼鈍前に圧
延歪を付加しても、最適な冷圧前組織に制御することが
困難である。さらに、多量に含有されたSは硫化物を生
成し、磁気特性そのものを著しく劣化させるため、たと
え最適冷圧前組織に制御できたとしても、最終製品の磁
気特性を十分ち向上させることができない。However, in the technology disclosed in Japanese Examined Patent Publication No. Sho 45-22211, grain growth is inferior because C and S are high, and even if rolling strain is applied before hot-rolled sheet annealing, the structure is controlled to an optimal pre-cold pressure structure. Difficult to do. Furthermore, since a large amount of S forms sulfides and significantly deteriorates the magnetic properties themselves, even if it is possible to control the structure before the optimum cold pressure, the magnetic properties of the final product cannot be sufficiently improved. .
また、特開昭63−186823号公報に開示されているよう
に、単に熱延板焼鈍前にスキンパス圧延を付加するたけ
で、鋼組成、軽圧延の圧下率に応じた熱延板焼鈍温度の
管理を適切に行なわない技術では、歪誘起により異常粒
成長した粗大な2次再結晶粒と細粒組織のままの1次再
結晶粒が混在した不均一なミクロ組織となり、最終製品
の磁気特性のコイル内各位置での均一性を劣化させる場
合や、2次再結晶粒が著しく粗粒化し、その痕跡が冷間
圧延後の鋼板表面に肌荒れ状に残り、うねりを形成する
場合がある。特に後者の場合は、結晶粒径の粗大化に伴
い磁気特性は向上するが、その反面、形成されるうねり
も大きくなるため占積率が低下してしまい、モーター、
変圧器等の電気機器の高効率化、小型化を図ることがで
きないという重大な問題点を有している。Further, as disclosed in JP-A-63-186823, by simply adding skin pass rolling before annealing the hot-rolled sheet, the steel composition, the hot-rolled sheet annealing temperature according to the rolling reduction of the light rolling. If the technology is not properly controlled, a non-uniform microstructure will be created in which coarse secondary recrystallized grains that have abnormally grown due to strain induction and primary recrystallized grains that remain fine grain are mixed, resulting in a magnetic property of the final product. In some cases, the uniformity at each position in the coil may be deteriorated, or the secondary recrystallized grains may be remarkably coarsened, and the traces thereof may remain rough on the surface of the steel sheet after cold rolling to form waviness. Especially in the latter case, the magnetic properties are improved with the coarsening of the crystal grain size, but on the other hand, the undulations formed are increased and the space factor is reduced, so that the motor,
There is a serious problem in that electrical equipment such as a transformer cannot be made highly efficient and miniaturized.
また、特開平1−139721号公報にも熱延板軽圧延後に
焼鈍を施す技術が開示されているが、この技術は1.0%
以上のMnと0.1%以上のNiを複合添加することにより集
合組織を改善し、磁気特性の向上を狙ったものであっ
て、熱延板焼鈍はこのMnとNiの複合添加による集合組織
改善効果を発揮させるための工程であり、本発明が目的
とするような冷間圧延前の組織を最適化し、磁気特性、
表面性状とも向上させることを狙いとした技術ではな
い。しかも、この技術では、多量に添加されたMnとNiが
ともにα−γ変態温度を低下させると同時に、粒成長性
を劣化させるため、本発明が目的とするような最適な冷
間圧延前組織とすることが不可能となる。Further, Japanese Patent Application Laid-Open No. 1-139721 also discloses a technique of annealing after hot rolling a light rolled sheet, which is 1.0%.
The aim is to improve the texture and improve the magnetic properties by adding the above Mn and 0.1% or more of Ni together, and hot-rolled sheet annealing is the texture improving effect of this addition of Mn and Ni. Is a process for exhibiting, the structure of the present invention before cold rolling is optimized, magnetic properties,
It is not a technology aimed at improving both surface properties. Moreover, in this technique, since Mn and Ni added in large amounts both lower the α-γ transformation temperature and, at the same time, deteriorate the grain growth property, an optimum pre-cold rolling microstructure as intended by the present invention is obtained. Will be impossible.
さらに、特開平1−191741号公報には熱延鋼帯に予備
焼鈍、軽圧下圧延、焼鈍を施す技術が開示されている
が、この技術は冷間圧延前の結晶粒を粗大化することの
みを目的としているため、最終製品の表面性状が劣ると
いう問題点を有している。すなわち、この技術では冷間
圧延前の結晶粒が粗大化し過ぎるため、前述のように最
終製品の鋼板表面に肌荒れ状の痕跡を残し、大きなうね
りを形成し、占積率が低下してしまう。さらに、軽圧下
圧延前の予備焼鈍を必須としているため、製造工程、製
造コストの増加をもたらすという欠点がある。Further, Japanese Patent Application Laid-Open No. 1-191741 discloses a technique of subjecting a hot-rolled steel strip to pre-annealing, light reduction rolling, and annealing, but this technique only coarsens the crystal grains before cold rolling. Therefore, there is a problem that the surface quality of the final product is inferior. That is, in this technique, since the crystal grains before cold rolling become too coarse, as described above, a rough surface-like trace is left on the surface of the steel sheet of the final product, large undulations are formed, and the space factor is reduced. Further, since the pre-annealing before the light reduction rolling is indispensable, there is a drawback that the manufacturing process and the manufacturing cost are increased.
本発明はこのような従来技術の問題に鑑み、高磁束密
度、低鉄損を有するとともに、占積率の低下をもたらす
ような鋼板表面の肌荒れ状の模様、うねりの形成を抑え
た、すなわち、磁気特性、表面性状ともに優れた無方向
性電磁鋼板およびその製造方法を提供しようとするもの
である。In view of such problems of the conventional technology, the present invention has a high magnetic flux density, a low iron loss, and a roughened pattern on the surface of a steel sheet that causes a decrease in the space factor, and suppresses the formation of undulations, that is, An object of the present invention is to provide a non-oriented electrical steel sheet having excellent magnetic properties and surface properties and a method for producing the same.
本発明者らは、冷間圧延前の素材の結晶組織と、磁気
特性および冷間圧延後に形成される肌荒れ状のうねりと
の関係について種々検討した結果、不純物元素の含有量
を低減した鋼の冷間圧延前の組織を2次再結晶組織と
し、その2次再結晶粒の平均粒径と2次再結晶粒の占め
る体積率(2次再結晶率)を適正範囲に制御することに
より、磁気特性を向上させ、且つ鋼板表面のうねりの増
大を抑えることが可能であることを見出した。さらに、
特定成分の熱延鋼帯に特定圧下率の軽圧下圧延を施した
後、(Si+Al)含有量と軽圧下圧延圧下率によって規制
される温度で熱延板焼鈍を行なうことにより、最適な冷
間圧延前組織とすることができ、上述したような磁気特
性、表面性状の良好な無方向性電磁鋼板を製造できるこ
とを究明した。The present inventors have variously studied the relationship between the crystal structure of the material before cold rolling and the magnetic properties and the rough waviness formed after cold rolling, and as a result, of the steel with a reduced content of impurity elements By making the structure before cold rolling into a secondary recrystallized structure and controlling the average grain size of the secondary recrystallized grains and the volume ratio (secondary recrystallized percentage) occupied by the secondary recrystallized grains to within an appropriate range, It has been found that it is possible to improve the magnetic characteristics and suppress the increase of the waviness on the surface of the steel sheet. further,
Optimum cold rolling is achieved by subjecting the hot-rolled steel strip of a specific component to light reduction rolling with a specific reduction ratio, and then performing hot-rolled sheet annealing at a temperature regulated by the (Si + Al) content and the light reduction rolling reduction ratio. It has been clarified that a pre-rolling structure can be obtained and a non-oriented electrical steel sheet having good magnetic properties and surface properties as described above can be produced.
本発明は、このような知見に基づいてなされたもの
で、その特徴とするところは、重量%で、C:0.006%以
下、Si:0.1〜1.0%、Al:0.004%以下または0.1〜0.5
%、Mn:0.1〜1.0%、P:0.01〜0.15%を含有し、残部Fe
および不可避的不純物からなり、不純物としてのS,N,O
の総量が0.025%以下であり、熱延板焼鈍後に行なわれ
る冷間圧延前の素材の結晶組織において、2次再結晶粒
の平均結晶粒径が150μm以上500μm未満で、且つ2次
再結晶粒の占める体積率が70%以上である、鋼板表面の
ろ波中心線うねりWCAが1.0μm以下の磁気特性および表
面性状の優れた無方向性電磁鋼板である。The present invention has been made on the basis of such findings, and is characterized in that, by weight%, C: 0.006% or less, Si: 0.1 to 1.0%, Al: 0.004% or less or 0.1 to 0.5%.
%, Mn: 0.1-1.0%, P: 0.01-0.15%, balance Fe
And unavoidable impurities such as S, N, O as impurities.
Of 0.025% or less, the average crystal grain size of the secondary recrystallized grains is 150 μm or more and less than 500 μm in the crystal structure of the material before cold rolling performed after hot-rolled sheet annealing, and the secondary recrystallized grains are Is a non-oriented electrical steel sheet having a volume ratio of 70% or more and a filtered center line waviness W CA of the steel sheet surface of 1.0 μm or less and excellent magnetic properties and surface properties.
また、本発明製造法の特徴とするところは、以下の通
りである。The features of the production method of the present invention are as follows.
(1) 重量%で、C:0.006%以下、Si:0.1〜1.0%、A
l:0.004%以下または0.1〜0.5%、Mn:0.1〜1.0%、P:0.
01〜0.15%を含有し、残部Feおよび不可避的不純物から
なり、不純物としてのS,N,Oの総量が0.025%以下である
熱延鋼帯を酸洗した後、圧下率ε(%)が3〜12%の範
囲の軽圧下冷間圧延を行ない、次いで(Si+Al)含有量
と軽圧下圧延圧下率εにより定まる下記条件(1),
(2) 3%≦ε≦10%のとき 50(Si+Al)-10ε+770≦T≦50(Si+Al)+5ε+810……(1) 10%<ε≦12%のとき 50(Si+Al)+670≦T≦50(Si+Al)+5ε+810……
(2) 但し、 Si…Si含有量(wt%) Al…Al含有量(wt%) を満足する温度T(℃)で30分〜12時間の熱延板焼鈍を
行うことにより、引き続き行なう冷間圧延前の素材の結
晶組織における2次再結晶粒の平均結晶粒径を150μm
以上500μm未満とし、且つ2次再結晶粒の占める体積
率を70%以上とする過程を経た後、所定の板厚まで冷間
圧延し、再結晶温度以上の温度で連続焼鈍を行ない、鋼
板表面のろ波中心線うねりWCAが1.0μm以下の鋼板を得
ることを特徴とする磁気特性および表面性状の優れた無
方向性電磁鋼板の製造方法。(1) C: 0.006% or less, Si: 0.1 to 1.0%, A by weight%
l: 0.004% or less or 0.1 to 0.5%, Mn: 0.1 to 1.0%, P: 0.
After pickling a hot-rolled steel strip containing 01 to 0.15%, the balance Fe and unavoidable impurities, and the total amount of S, N, O as impurities being 0.025% or less, the rolling reduction ε (%) is Light reduction cold rolling in the range of 3 to 12% is performed, and then the following conditions (1) determined by the (Si + Al) content and the light reduction rolling reduction ratio ε,
(2) When 3% ≦ ε ≦ 10% 50 (Si + Al) -10ε + 770 ≦ T ≦ 50 (Si + Al) + 5ε + 810 …… (1) When 10% <ε ≦ 12% 50 (Si + Al) + 670 ≦ T ≦ 50 (Si + Al) + 5ε + 810 ……
(2) However, the cooling is continuously performed by performing hot-rolled sheet annealing for 30 minutes to 12 hours at a temperature T (° C) that satisfies the Si ... Si content (wt%) Al ... Al content (wt%). The average grain size of secondary recrystallized grains in the crystal structure of the material before hot rolling is 150 μm
After less than 500 μm and a volume ratio of secondary recrystallized grains of 70% or more, cold rolling is performed to a predetermined plate thickness and continuous annealing is performed at a temperature equal to or higher than the recrystallization temperature. A method for producing a non-oriented electrical steel sheet having excellent magnetic properties and surface properties, which comprises obtaining a steel sheet having a filtered centerline waviness W CA of 1.0 μm or less.
(2) 上記(1)と同様の成分組成の熱延鋼帯を、
(1)と同様の工程で酸洗、軽圧下冷間圧延、熱延板焼
鈍、冷間圧延した後、連続焼鈍を施し、剪断または打抜
き加工を行なった後に、歪取焼鈍を行ない、鋼板表面の
ろ波中心線うねりWCAが1.0μm以下の鋼板を得ることを
特徴とする磁気特性および表面性状の優れた無方向性電
磁鋼板の製造方法。(2) A hot-rolled steel strip having the same composition as in (1) above,
In the same steps as in (1), pickling, cold rolling under light pressure, hot-rolled sheet annealing, cold rolling, continuous annealing, shearing or punching, and then strain relief annealing, steel sheet surface A method for producing a non-oriented electrical steel sheet having excellent magnetic properties and surface properties, which comprises obtaining a steel sheet having a filtered centerline waviness W CA of 1.0 μm or less.
(3) 上記(1)と同様の成分組成の熱延鋼帯を、
(1)と同様の工程で酸洗、軽圧下冷間圧延、熱延板焼
鈍、冷間圧延した後、連続焼鈍を施し、次いで3〜15%
の圧下率のスキンパス圧延を行ない、鋼板表面のろ波中
心線うねりWCAが1.0μm以下の鋼板を得ることを特徴と
する磁気特性および表面性状の優れた無方向性電磁鋼板
の製造方法。(3) A hot-rolled steel strip having the same composition as in (1) above,
In the same process as (1), pickling, cold rolling under light pressure, hot-rolled sheet annealing, cold rolling, continuous annealing, then 3-15%
A method for producing a non-oriented electrical steel sheet having excellent magnetic properties and surface properties, which is characterized in that a sheet having a filtered center line waviness W CA of 1.0 μm or less is obtained by performing skin pass rolling with the reduction ratio of 1.
以下、この発明の詳細と構成の限定理由について説明
する。Hereinafter, details of the present invention and reasons for limiting the configuration will be described.
まず、鋼成分の限定理由について説明する。 First, the reasons for limiting the steel components will be described.
Cは、磁気時効による磁気特性の劣化を防止し、且つ
焼鈍時の粒成長性の劣化を抑えるため0.006%以下とす
る。C is 0.006% or less in order to prevent deterioration of magnetic properties due to magnetic aging and to suppress deterioration of grain growth during annealing.
Siは、徹損を低減するのに有効であるが、0.1%未満
ではその効果が十分でなく、また1.0%を超えると磁束
密度が低下し、本発明の目的である高い磁束密度を得る
ことができない。以上の理由からSiは0.1〜1.0%とす
る。Si is effective in reducing penetration loss, but if it is less than 0.1%, its effect is not sufficient, and if it exceeds 1.0%, the magnetic flux density decreases, and the high magnetic flux density that is the object of the present invention is obtained. I can't. For the above reasons, Si is 0.1 to 1.0%.
Alは、Siと同様、鉄損低減に有効な元素であるが、鋼
中NとともにAlNを形成し、焼鈍時の粒成長性を悪化さ
せ、磁気特性を劣化させる場合がある。AlNによるこの
悪影響を排除するためには、Al量を低レベルに制限する
か、あるいは添加量を多くしてAlNを粗大化させる必要
がある。前者の場合、Al量を0.004%以下とすればよ
く、後者の場合は0.1%以上であればAlN粒子を粗大化さ
れることができる。しかし0.5%を超える添加は磁束密
度の低下をもたらす。以上の理由から、Alは0.004%以
下あるいは0.1〜0.5%の範囲とする。Al, like Si, is an element effective in reducing iron loss, but may form AlN together with N in steel to deteriorate grain growth during annealing and deteriorate magnetic properties. In order to eliminate this adverse effect of AlN, it is necessary to limit the amount of Al to a low level or increase the amount of addition to coarsen AlN. In the former case, the Al content may be 0.004% or less, and in the latter case, the AlN particles can be coarsened if the Al content is 0.1% or more. However, the addition exceeding 0.5% brings about a decrease in magnetic flux density. For the above reasons, Al is set to 0.004% or less or 0.1 to 0.5%.
MnもSi,Alと同様、固有抵抗を高め、鉄損低減に有効
であると同時に、鋼中SをMnSにして析出・粗大化さ
せ、磁気特性、粒成長性に対する悪影響を排除するため
に必要であるが、0.1%未満ではその効果が十分に得ら
れず、また1.0%を超えるとα−γ変態温度が低下し、
熱延板焼鈍時にオーステナイトが生成し易くなり、また
鋼中固溶Mnが熱延板焼鈍時の粒成長性を低下させ、最適
な冷間圧延前の結晶組織を得ることができなくなる。以
上の理由から、Mnは0.1〜1.0%とする。Mn, like Si and Al, is effective in increasing the specific resistance and reducing iron loss, and at the same time it is necessary to eliminate the adverse effects on magnetic properties and grain growth by converting S in steel to MnS to precipitate and coarsen it. However, if less than 0.1%, the effect cannot be sufficiently obtained, and if it exceeds 1.0%, the α-γ transformation temperature decreases,
Austenite is easily generated during hot-rolled sheet annealing, and solid solution Mn in steel deteriorates grain growth during hot-rolled sheet annealing, making it impossible to obtain an optimum crystal structure before cold rolling. For the above reasons, Mn is 0.1-1.0%.
Pは、鉄損低減、打抜き性向上のための硬度調整に有
効であるが、0.01%未満ではその効果が十分に得られ
ず、一方、0.15%を超えると鋼板を脆化させ、しかも磁
気特性、粒成長性ともに劣化させる。このためPは0.01
〜0.15%とする。P is effective for hardness adjustment to reduce iron loss and improve punchability, but if it is less than 0.01%, the effect is not sufficiently obtained, while if it exceeds 0.15%, the steel sheet becomes brittle and the magnetic properties , The grain growth property is deteriorated. Therefore, P is 0.01
~ 0.15%
S,N,Oは、それぞれ硫化物、窒化物、酸化物を生成
し、焼鈍時の粒成長を阻害する。さらに、これらの析出
物、介在物が微細で且つ多量に分散すると磁気特性その
ものを著しく劣化させるため、S,N,Oの総量を0.025%以
下に規制する必要がある。これらの元素は各々単独では
S:0.007%以下、N:0.003%以下、O:0.015%とすること
が望ましく、極力少なくすることが好ましい。S, N and O form sulfides, nitrides and oxides, respectively, and inhibit grain growth during annealing. Further, if these precipitates and inclusions are fine and dispersed in a large amount, the magnetic properties themselves are significantly deteriorated, so it is necessary to regulate the total amount of S, N, O to 0.025% or less. Each of these elements alone
S: 0.007% or less, N: 0.003% or less, O: 0.015% are desirable, and it is preferable to reduce them as much as possible.
次に鋼成分以外の構成の限定理由について説明する。 Next, the reasons for limiting the configurations other than steel components will be described.
第1表中の鋼Cを通常の方法に従い熱間圧延し、この
鋼板に酸洗後10%の圧下率で軽圧下圧延を施し、さらに
675〜925℃の種々の温度で2hr均熱の熱延板焼鈍を行な
い、2次再結晶粒の占める体積率が100%で且つ2次再
結晶粒の平均結晶粒径が異なる冷間圧延前素材を作成し
た。また、比較のため同様の鋼種について、軽圧下圧
延、熱延板焼鈍をともに施さない熱間圧延ままの素材も
準備した。これらの鋼板を板厚0.5mmまで冷間圧延し、
温度800℃、均熱時間90秒の連続焼鈍を行なった後、磁
気特性と鋼板表面のうねりを測定した。Steel C in Table 1 was hot-rolled according to the usual method, and this steel sheet was pickled and then lightly rolled at a reduction rate of 10%.
Before cold rolling, the hot-rolled sheet is annealed for 2 hours at various temperatures from 675 to 925 ℃, and the volume ratio of secondary recrystallized grains is 100% and the average grain size of secondary recrystallized grains is different. Created the material. Further, for comparison, with respect to the same steel type, a material as hot-rolled without light reduction rolling and hot-rolled sheet annealing was also prepared. Cold rolling these steel plates to a plate thickness of 0.5 mm,
After continuous annealing at a temperature of 800 ° C and a soaking time of 90 seconds, the magnetic properties and the waviness of the steel sheet surface were measured.
第1図はその結果を示したもので、冷間圧延前素材の
2次再結晶粒の平均粒径と、磁束密度B50および鋼板表
面のろ波中心線うねりWCAとの関係を示したものであ
る。同図から明らかなように、2次再結晶粒の平均粒径
の増大に伴い磁束密度は向上し、うねりは大きくなる
が、平均粒径が150μm以上500μm未満(好ましくは40
0μm未満)であれば、高い磁束密度を有し、しかもう
ねりを小さく抑えられることが判明した。また、鋼板表
面のうねりは、平均粒径が500μm以上となると著しく
大きくなる傾向が認められる。うねりWCAが1.0μm以下
であれば鋼板の占積率に及ぼす悪影響の程度が小さいた
め、上記の結果に基づき本発明では、うねりWCAが1.0μ
m以下となるよう、所定の板厚に仕上げるための冷間圧
延(熱延板焼鈍後に行なわれる冷間圧延)を行なう前の
2次再結晶粒の平均粒径を、150μm以上500μm未満と
規定した。Figure 1 shows the results and shows the relationship between the average grain size of the secondary recrystallized grains of the material before cold rolling, the magnetic flux density B 50 and the filtered centerline waviness W CA of the steel sheet surface. It is a thing. As is clear from the figure, the magnetic flux density increases and the waviness increases as the average grain size of the secondary recrystallized grains increases, but the average grain size is 150 μm or more and less than 500 μm (preferably 40 μm or less).
If it is less than 0 μm), it has been found that it has a high magnetic flux density and can suppress the twisting. Further, it is recognized that the waviness on the surface of the steel sheet tends to be remarkably large when the average particle diameter is 500 μm or more. If the waviness W CA is 1.0 μm or less, the degree of adverse effect on the space factor of the steel sheet is small. Therefore, in the present invention based on the above results, the waviness W CA is 1.0 μm.
The average grain size of the secondary recrystallized grains before cold rolling (cold rolling performed after hot-rolled sheet annealing) to finish to a prescribed plate thickness is defined as 150 μm or more and less than 500 μm did.
次に、冷間圧延前素材の結晶組織中の2次再結晶粒の
占める体積率の影響について検討した。第1表中の鋼C
を通常の方法に従い熱間圧延し、この鋼板に酸洗後1〜
12%の種々の圧下率で軽圧下圧延を施し、さらに750℃
の温度で2hr均熱の熱延板焼鈍を行ない、2次再結晶粒
の平均粒径が150μm以上500μm未満で、且つ2次再結
晶粒の占める体積率が異なる冷間圧延前素材を作成し
た。これらの鋼板を板厚0.5mmまで冷間圧延し、温度800
℃、均熱時間90秒の連続焼鈍を行なった後、磁気特性を
測定した。Next, the influence of the volume ratio of the secondary recrystallized grains in the crystal structure of the material before cold rolling was examined. Steel C in Table 1
Is hot-rolled according to a usual method, and the steel sheet is pickled 1 to
Light reduction rolling with various reduction rates of 12%, and further 750 ℃
The hot-rolled sheet was annealed at a temperature of 2 hours for 2 hours to prepare pre-cold-rolling materials with secondary recrystallized grains having an average grain size of 150 μm or more and less than 500 μm and different volume fractions of the secondary recrystallized grains. . These steel sheets are cold-rolled to a thickness of 0.5 mm at a temperature of 800
The magnetic properties were measured after continuous annealing at ℃ and soaking time of 90 seconds.
第2図はその結果を示すもので、冷間圧延前素材の2
次再結晶粒の占める体積率と磁束密度B50との関係を示
したものである。同図から明らかなように、2次再結晶
粒の平均粒径を適正範囲に制御しても、2次再結晶粒の
占める体積率が低いと磁束密度の向上効果は小さい。さ
らに、冷間圧延前組織の2次再結晶粒の占める体積率が
低いと、最終製品のコイル内位置による磁気特性のバラ
ツキが大きくなり、磁気特性の均一性を損なう。また、
2次再結晶粒の平均粒径が500μm以上の場合は、2次
再結晶粒の占める体積率を低くしても、うねりを十分に
小さくすることができず、磁気特性、表面性状の両者を
良好に保つことはできなかった。Fig. 2 shows the result, which is 2 of the material before cold rolling.
It shows the relationship between the volume ratio of secondary recrystallized grains and the magnetic flux density B 50 . As is clear from the figure, even if the average grain size of the secondary recrystallized grains is controlled within an appropriate range, the effect of improving the magnetic flux density is small if the volume ratio of the secondary recrystallized grains is low. Further, if the volume ratio of the secondary recrystallized grains in the pre-cold rolling structure is low, the magnetic properties vary greatly depending on the position inside the coil of the final product, and the uniformity of the magnetic properties is impaired. Also,
When the average particle size of the secondary recrystallized grains is 500 μm or more, the waviness cannot be sufficiently reduced even if the volume ratio of the secondary recrystallized grains is lowered, and both the magnetic properties and the surface properties are reduced. I couldn't keep it good.
以上のことから、本発明では十分な磁束密度の向上効
果が得られ、磁気特性の均一性を損なわず、しかも表面
性状も良好に保つための条件として、冷間圧延前素材の
2次再結晶粒の平均粒径を150μm以上500μm未満、2
次再結晶粒の占める体積率を70%以上と規定した。From the above, according to the present invention, a sufficient effect of improving the magnetic flux density can be obtained, and the secondary recrystallization of the material before cold rolling is performed as a condition for maintaining the uniformity of the magnetic properties and keeping the surface quality good. The average particle size of the particles is 150 μm or more and less than 500 μm, 2
The volume ratio of the secondary recrystallized grains was defined as 70% or more.
なお、最終製品の鋼板表面のろ波中心線うねりW
CAは、前述のように占積率の低下を防止するため、1.0
μm以下と規定した。In addition, the filtered center line waviness W on the steel plate surface of the final product
As mentioned above, the CA uses 1.0% to prevent the space factor from decreasing.
It was defined as μm or less.
次に、本発明の製造方法について説明する。 Next, the manufacturing method of the present invention will be described.
本発明では、上述した化学組成を有する連続鋳造スラ
ブを通常行なわれている条件で熱間圧延し、酸洗後、軽
圧下冷間圧延を行なう。この軽圧下圧延の圧下率は、3
%未満では鋼板内部に蓄積される歪量が少ないため、熱
延板焼鈍時に歪誘起粒成長する2次再結晶粒の占める体
積率を70%以上とすることができない。一方、圧下率が
12%を超えると蓄積される歪量が多過ぎるため、熱延板
焼鈍後の粒径が小さくなり、平均結晶粒径を150μm以
上とすることが困難となる。以上の理由から熱延板軽圧
下圧延の圧下率の範囲を3〜12%と規定した。In the present invention, the continuously cast slab having the above-mentioned chemical composition is hot-rolled under the conditions usually used, pickled and then cold-rolled under light pressure. The reduction ratio of this light reduction rolling is 3
If it is less than%, the amount of strain accumulated inside the steel sheet is small, so that the volume ratio occupied by the secondary recrystallized grains that undergo strain-induced grain growth during hot-rolled sheet annealing cannot be made 70% or more. On the other hand, the reduction rate is
If it exceeds 12%, the amount of accumulated strain is too large, so the grain size after hot-rolled sheet annealing becomes small, and it becomes difficult to set the average grain size to 150 μm or more. For the above reasons, the range of the reduction rate of light reduction rolling of hot-rolled sheet is defined as 3 to 12%.
引き続き行なう熱延板焼鈍は、焼鈍温度を軽圧下圧延
圧下率ε(%)と(Si+Al)含有量に応じて定まる適正
範囲に管理しないと、前述のような最適な結晶組織を得
ることはできない。In the subsequent hot-rolled sheet annealing, the optimum crystal structure as described above cannot be obtained unless the annealing temperature is controlled within an appropriate range determined by the light reduction rolling reduction ε (%) and the (Si + Al) content. .
第1表に示す5種類の(Si+Al)含有量の異なる鋼を
通常の方法に従い熱間圧延し、酸洗後1〜13%圧下率で
軽圧下圧延し、675〜925℃の温度で2hr均熱の熱延板焼
鈍を行ない、結晶組織を調査した。第3図は第1表中の
鋼Cについて、軽圧下圧延の圧下率ε(%)と熱延板焼
鈍温度(℃)の最適範囲との関係を示したものである。
同図から明らかなように、2次再結晶粒の平均粒径が15
0μm以上500μm未満であり、且つ2次再結晶粒の占め
る体積率が70%以上である最適冷間圧延前組織とするた
めの熱延板焼鈍温度T(℃)の範囲は、 3≦ε(%)≦10のとき −10ε+800≦T(℃)≦5ε+840 10<ε(%)≦12のとき 700≦T(℃)≦5ε+840 である。第4図は軽圧下圧延圧下率7%の場合の(Si+
Al)含有量(wt%)と熱延板焼鈍温度T(℃)の最適範
囲との関係を示したもので、前述の最適冷間圧延前組織
とするための熱延板焼鈍温度T(℃)の範囲は、 50(Si+Al)+700≦T(℃)≦50(Si+Al)+845 である。Five kinds of steels having different (Si + Al) contents shown in Table 1 are hot-rolled according to a usual method, pickled, and lightly rolled at a reduction rate of 1 to 13%, and uniformly heated at a temperature of 675 to 925 ° C for 2 hours. The hot rolled sheet was annealed and the crystal structure was investigated. FIG. 3 shows the relationship between the reduction ratio ε (%) of light reduction rolling and the optimum range of hot-rolled sheet annealing temperature (° C.) for steel C in Table 1.
As is clear from the figure, the average grain size of the secondary recrystallized grains is 15
The range of the hot-rolled sheet annealing temperature T (° C.) for obtaining an optimum pre-cold rolling structure in which the volume ratio occupied by the secondary recrystallized grains is 0 μm or more and less than 500 μm and 70% or more is 3 ≦ ε ( %) ≦ 10 −10ε + 800 ≦ T (° C) ≦ 5ε + 840 10 ≦ ε (%) ≦ 12 700 ≦ T (° C) ≦ 5ε + 840. Fig. 4 shows the case of (Si +
It shows the relationship between the Al) content (wt%) and the optimum range of the hot-rolled sheet annealing temperature T (° C), and the hot-rolled sheet annealing temperature T (° C for obtaining the optimum pre-cold rolling structure described above is shown. The range of () is 50 (Si + Al) + 700 ≦ T (° C.) ≦ 50 (Si + Al) +845.
他の鋼種に関する同様な調査により、軽圧下圧延圧下
率ε(%)によって規定される熱延板焼鈍温度T(℃)
の最適範囲は、(Si+Al)含有量(wt%)に比例して変
化することが明らかになった。従って、本発明において
は熱延板焼鈍温度T(℃)を、前述の圧下率εとの関係
と、(Si+Al)含有量との関係とを組み合わせた範囲、
すなわち、 3≦ε(%)≦10のとき 50(Si+Al)-10ε+770≦T≦50(Si+Al)+5ε+810 10<ε(%)≦12のとき 50(Si+Al)+670≦T≦50(Si+Al)+5ε+810 但し、 Si…Si含有量(wt%) Al…Al含有量(wt%) に規定した。By similar investigations on other steel grades, the hot rolled sheet annealing temperature T (° C) defined by the light reduction rolling reduction ε (%)
It has been revealed that the optimum range of is changed in proportion to the (Si + Al) content (wt%). Therefore, in the present invention, the hot-rolled sheet annealing temperature T (° C.) is a range in which the relationship between the above-mentioned reduction ratio ε and the relationship between (Si + Al) content is combined,
That is, when 3 ≦ ε (%) ≦ 10, 50 (Si + Al) -10ε + 770 ≦ T ≦ 50 (Si + Al) + 5ε + 810 10 <ε (%) ≦ 12, 50 (Si + Al) +670 ≦ T ≦ 50 (Si + Al) + 5ε + 810 However, it is defined as Si ... Si content (wt%) Al ... Al content (wt%).
熱延板焼鈍の均熱時間は、30分以上確保すればほぼ粒
成長が完了し、十分な磁気特性向上効果が得られるた
め、その下限を30分と規定した。一方、12時間を超す長
時間の焼鈍を行なってもその効果は格別向上せず、生産
能力の低下、エネルギー使用量の増大をもたらし、経済
的に不利となるため、その上限を12時間と規定した。If the soaking time of hot-rolled sheet annealing is secured for 30 minutes or more, grain growth is almost completed and a sufficient effect of improving the magnetic properties can be obtained. Therefore, the lower limit was defined as 30 minutes. On the other hand, even if annealing is performed for a long time exceeding 12 hours, the effect does not improve significantly, resulting in a decrease in production capacity and an increase in energy consumption, which is economically disadvantageous, so the upper limit is specified as 12 hours. did.
その後、常法に従い所定板厚まで冷間圧延し、連続焼
鈍を行なうが、フルプロセス製品の場合は、鉄損の低下
を図るため連続焼鈍は再結晶温度以上の温度で行なう必
要がある。また、ユーザーにて剪断・打抜き後歪取焼鈍
を施すセミプロセス製品の場合は、歪取焼鈍時に粒成長
し、鉄損の低下を図ることができるため、冷間圧延後の
連続焼鈍の条件は特に限定する必要はない。After that, cold rolling is performed to a predetermined plate thickness according to an ordinary method and continuous annealing is performed. However, in the case of a full-process product, continuous annealing needs to be performed at a temperature equal to or higher than the recrystallization temperature in order to reduce iron loss. Also, in the case of semi-processed products that are subjected to stress relief annealing after shearing / punching by the user, grain growth during stress relief annealing can reduce iron loss, so the conditions for continuous annealing after cold rolling are There is no particular limitation.
また、最終スキンパス圧延を施すセミプロセス製品の
場合は、このスキンパス圧延により鋼板表面のうねりは
さらに小さくなり、表面性状が改善されると同時に、ユ
ーザーでの歪取焼鈍時の粒成長が容易になり、鉄損がさ
らに低下する。しかし、このスキンパス圧延の圧下率が
3%未満では、その効果が十分でなく、また、15%を超
えると集合組織が変化し、磁気特性が劣化するため、圧
下率は3〜15%の範囲に限定する必要がある。In the case of semi-processed products that are subjected to final skin pass rolling, this skin pass rolling further reduces the waviness on the surface of the steel sheet, improving the surface texture and, at the same time, facilitating grain growth during stress relief annealing by the user. , Iron loss is further reduced. However, if the reduction rate of this skin pass rolling is less than 3%, its effect is not sufficient, and if it exceeds 15%, the texture changes and the magnetic properties deteriorate, so the reduction rate is in the range of 3 to 15%. Need to be limited to.
第1表に示す5種類の鋼を連続鋳造により220mm厚さ
のスラブとし、通常の熱間圧延により厚さ2.0mmの熱延
鋼帯に仕上げた。該鋼帯を通常の方法で酸洗後、圧下率
15%以下の範囲で軽圧下圧延し、725〜900℃の種々の温
度で均熱時間2〜10時間の焼鈍を行なった。さらにこの
鋼帯を所定板厚まで冷間圧延し、700〜850℃の範囲で連
続焼鈍を行ない、磁気特性と鋼板表面のろ波中心線うね
りを測定した。また、一部の鋼板については、 i)エプスタインサンプルに剪断し、750℃×2hrの歪取
焼鈍を施した後、または、 ii)最終スキンパス圧延後剪断し、歪取焼鈍を施した
後、 それぞれ磁気特性を測定した。これらの結果を具体的な
製造条件とともに第2表に示す。The five types of steel shown in Table 1 were continuously cast into slabs with a thickness of 220 mm, and hot rolled steel strips with a thickness of 2.0 mm were finished by ordinary hot rolling. The steel strip is pickled by a usual method and then the rolling reduction
It was lightly rolled in the range of 15% or less and annealed at various temperatures of 725 to 900 ° C for a soaking time of 2 to 10 hours. Further, this steel strip was cold-rolled to a predetermined plate thickness and continuously annealed in the range of 700 to 850 ° C, and the magnetic properties and the filtered centerline waviness of the steel plate surface were measured. For some steel plates, i) after shearing the Epstein sample and subjecting it to strain relief annealing at 750 ° C x 2 hr, or ii) after final skin pass rolling, shearing and subjecting to strain relief annealing, The magnetic properties were measured. These results are shown in Table 2 together with specific manufacturing conditions.
なお、冷間圧延後の板厚は最終スキンパス圧延を施さ
ないものは0.5mm厚さに仕上げ、スキンパス圧延を施す
ものは最終スキンパス圧延後の板厚が0.5mmとなるよう
に冷間圧延の仕上げ厚を調整した。また、スキンパス圧
延を施したものは、スキンパス圧延後にうねり測定を行
なった。The plate thickness after cold rolling is 0.5 mm for those without final skin pass rolling, and the finish for cold rolling is for those with skin pass rolling to be 0.5 mm after final skin pass rolling. The thickness was adjusted. For the skin-pass-rolled product, the waviness was measured after the skin-pass rolling.
第2表によれば、比較例では磁気特性、表面性状のい
ずれかが劣っているが、本発明例では磁気特性、表面性
状ともに良好な結果が得られている。According to Table 2, the magnetic properties and surface properties are inferior in the comparative example, but the magnetic properties and surface properties are good in the present invention.
第1図は冷間圧延前素材の平均結晶粒径と最終製品の磁
束密度B50および鋼板表面のろ波中心線うねりWCAとの関
係を示すグラフ、第2図は冷間圧延前素材の2次再結晶
粒の占める体積率と最終製品の磁束密度B50との関係を
示すグラフ、第3図は熱延板焼鈍温度の最適範囲を軽圧
下圧延圧下率との関係で示したグラフ、第4図は熱延板
焼鈍温度の最適範囲を(Si+Al)含有量との関係で示し
たグラフである。Fig. 1 is a graph showing the relationship between the average grain size of the material before cold rolling, the magnetic flux density B 50 of the final product and the filtered centerline waviness W CA of the steel plate surface, and Fig. 2 is the graph of the material before cold rolling. Fig. 3 is a graph showing the relationship between the volume ratio of secondary recrystallized grains and the magnetic flux density B 50 of the final product. Fig. 3 is a graph showing the optimum range of the annealing temperature of hot-rolled sheet in relation to the light rolling reduction. FIG. 4 is a graph showing the optimum range of the hot-rolled sheet annealing temperature in relation to the (Si + Al) content.
Claims (4)
%、Al:0.004%以下または0.1〜0.5%、Mn:0.1〜1.0
%、P:0.01〜0.15%を含有し、残部Feおよび不可避的不
純物からなり、不純物としてのS,N,Oの総量が0.025%以
下であり、熱延板焼鈍後に行なわれる冷間圧延前の素材
の結晶組織において、2次再結晶粒の平均結晶粒径が15
0μm以上500μm未満で、且つ2次再結晶粒の占める体
積率が70%以上である、鋼板表面のろ波中心線うねりW
CAが1.0μm以下の磁気特性および表面性状の優れた無
方向性電磁鋼板。1. C: 0.006% or less by weight%, Si: 0.1 to 1.0
%, Al: 0.004% or less or 0.1 to 0.5%, Mn: 0.1 to 1.0
%, P: 0.01 to 0.15%, the balance Fe and unavoidable impurities, the total amount of S, N, O as impurities is 0.025% or less, before cold rolling performed after hot-rolled sheet annealing. In the crystal structure of the material, the average grain size of secondary recrystallized grains is 15
Filter center line waviness W of the steel plate surface, which is 0 μm or more and less than 500 μm, and the volume ratio of secondary recrystallized grains is 70% or more
A non-oriented electrical steel sheet with a CA of 1.0 μm or less and excellent magnetic properties and surface properties.
%、Al:0.004%以下または0.1〜0.5%、Mn:0.1〜1.0
%、P:0.01〜0.15%を含有し、残部Feおよび不可避的不
純物からなり、不純物としてのS,N,Oの総量が0.025%以
下である熱延鋼帯を酸洗した後、圧下率ε(%)が3〜
12%の範囲の軽圧下冷間圧延を行ない、次いで(Si+A
l)含有量と軽圧下圧延圧下率εにより定まる下記条件
(1),(2) 3%≦ε≦10%のとき 50(Si+Al)-10ε+770≦T≦50(Si+Al)+5ε+810……(1) 10%<ε≦12%のとき 50(Si+Al)+670≦T≦50(Si+Al)+5ε+810……
(2) 但し、 Si…Si含有量(wt%) Al…Al含有量(wt%) を満足する温度T(℃)で30分〜12時間の熱延板焼鈍を
行なうことにより、引き続き行なう冷間圧延前の素材の
結晶組織における2次再結晶粒の平均結晶粒径を150μ
m以上500μm未満とし、且つ2次再結晶粒の占める体
積率を70%以上とする過程を経た後、所定の板厚まで冷
間圧延し、再結晶温度以上の温度で連続焼鈍を行ない、
鋼板表面のろ波中心線うねりWCAが1.0μm以下の鋼板を
得ることを特徴とする磁気特性および表面性状の優れた
無方向性電磁鋼板の製造方法。2. By weight%, C: 0.006% or less, Si: 0.1 to 1.0
%, Al: 0.004% or less or 0.1 to 0.5%, Mn: 0.1 to 1.0
%, P: 0.01 to 0.15%, the balance Fe and unavoidable impurities, the total amount of S, N, O as impurities is 0.025% or less after pickling, the rolling reduction ε (%) Is 3 ~
Lightly cold rolling in the range of 12% and then (Si + A
l) The following conditions (1) and (2) determined by the content and rolling reduction ε of 3% ≦ ε ≦ 10% 50 (Si + Al) -10ε + 770 ≦ T ≦ 50 (Si + Al) + 5ε + 810 …… (1) When 10% <ε ≦ 12% 50 (Si + Al) + 670 ≦ T ≦ 50 (Si + Al) + 5ε + 810 ……
(2) However, the cooling is continuously performed by annealing the hot-rolled sheet for 30 minutes to 12 hours at a temperature T (° C) that satisfies the Si ... Si content (wt%) Al ... Al content (wt%). The average grain size of secondary recrystallized grains in the crystal structure of the material before hot rolling is 150μ
m or more and less than 500 μm, and after the process of making the volume ratio of the secondary recrystallized grains 70% or more, cold rolling to a predetermined plate thickness and continuous annealing at a temperature equal to or higher than the recrystallization temperature,
A method for producing a non-oriented electrical steel sheet having excellent magnetic properties and surface properties, which comprises obtaining a steel sheet having a filtered centerline waviness W CA of 1.0 μm or less on the surface of the steel sheet.
%、Al:0.004%以下または0.1〜0.5%、Mn:0.1〜1.0
%、P:0.01〜0.15%を含有し、残部Feおよび不可避的不
純物からなり、不純物としてのS,N,Oの総量が0.025%以
下である熱延鋼帯を酸洗した後、圧下率ε(%)が3〜
12%の範囲の軽圧下冷間圧延を行ない、次いで(Si+A
l)含有量と軽圧下圧延圧下率εにより定まる下記条件
(1),(2) 3%≦ε≦10%のとき 50(Si+Al)-10ε+770≦T≦50(Si+Al)+5ε+810……(1) 10%<ε≦12%のとき 50(Si+Al)+670≦T≦50(Si+Al)+5ε+810……
(2) 但し、 Si…Si含有量(wt%) Al…Al含有量(wt%) を満足する温度T(℃)で30分〜12時間の熱延板焼鈍を
行なうことにより、引き続き行なう冷間圧延前の素材の
結晶組織における2次再結晶粒の平均結晶粒径を150μ
m以上500μm未満とし、且つ2次再結晶粒の占める体
積率を70%以上とする過程を経た後、所定の板厚まで冷
間圧延し、次いで連続焼鈍を施し、剪断または打抜き加
工を行なった後に、歪取焼鈍を行ない、鋼板表面のろ波
中心線うねりWCAが1.0μm以下の鋼板を得ることを特徴
とする磁気特性および表面性状の優れた無方向性電磁鋼
板の製造方法。3. By weight%, C: 0.006% or less, Si: 0.1 to 1.0
%, Al: 0.004% or less or 0.1 to 0.5%, Mn: 0.1 to 1.0
%, P: 0.01 to 0.15%, the balance Fe and unavoidable impurities, the total amount of S, N, O as impurities is 0.025% or less after pickling, the rolling reduction ε (%) Is 3 ~
Lightly cold rolling in the range of 12% and then (Si + A
l) The following conditions (1) and (2) determined by the content and rolling reduction ε of 3% ≦ ε ≦ 10% 50 (Si + Al) -10ε + 770 ≦ T ≦ 50 (Si + Al) + 5ε + 810 …… (1) When 10% <ε ≦ 12% 50 (Si + Al) + 670 ≦ T ≦ 50 (Si + Al) + 5ε + 810 ……
(2) However, the cooling is continuously performed by annealing the hot-rolled sheet for 30 minutes to 12 hours at a temperature T (° C) that satisfies the Si ... Si content (wt%) Al ... Al content (wt%). The average grain size of secondary recrystallized grains in the crystal structure of the material before hot rolling is 150μ
m and less than 500 μm and the volume ratio of secondary recrystallized grains to 70% or more, followed by cold rolling to a predetermined plate thickness, continuous annealing, and shearing or punching A method for producing a non-oriented electrical steel sheet having excellent magnetic properties and surface properties, which is characterized in that strain-relief annealing is subsequently performed to obtain a steel sheet having a filtered centerline waviness W CA of 1.0 μm or less on the steel sheet surface.
%、Al:0.004%以下または0.1〜0.5%、Mn:0.1〜1.0
%、P:0.01〜0.15%を含有し、残部Feおよび不可避的不
純物からなり、不純物としてのS,N,Oの総量が0.025%以
下である熱延鋼帯を酸洗した後、圧下率ε(%)が3〜
12%の範囲の軽圧下冷間圧延を行ない、次いで(Si+A
l)含有量と軽圧下圧延圧下率εにより定まる下記条件
(1),(2) 3%≦ε≦10%のとき 50(Si+Al)-10ε+770≦T≦50(Si+Al)+5ε+810 ……
(1) 10%<ε≦12%のとき 50(Si+Al)+670≦T≦50(Si+Al)+5ε+810……
(2) 但し、 Si…Si含有量(wt%) Al…Al含有量(wt%) を満足する温度T(℃)で30分〜12時間の熱延板焼鈍を
行なうことにより、引き続き行なう冷間圧延前の素材の
結晶組織における2次再結晶粒の平均結晶粒径を150μ
m以上500μm未満とし、且つ2次再結晶粒の占める体
積率を70%以上とする過程を経た後、所定の板厚まで冷
間圧延し、次いで連続焼鈍を施した後、3〜15%の圧下
率のスキンパス圧延を行ない、鋼板表面のろ波中心線う
ねりWCAが1.0μm以下の鋼板を得ることを特徴とする磁
気特性および表面性状の優れた無方向性電磁鋼板の製造
方法。4. By weight%, C: 0.006% or less, Si: 0.1 to 1.0
%, Al: 0.004% or less or 0.1 to 0.5%, Mn: 0.1 to 1.0
%, P: 0.01 to 0.15%, the balance Fe and unavoidable impurities, and the total reduction of S, N and O as impurities is 0.025% or less. (%) Is 3 ~
Lightly cold rolling in the range of 12% and then (Si + A
l) The following conditions (1) and (2) determined by the content and light rolling reduction ε: 3% ≦ ε ≦ 10% 50 (Si + Al) -10ε + 770 ≦ T ≦ 50 (Si + Al) + 5ε +810 ……
(1) When 10% <ε ≦ 12% 50 (Si + Al) + 670 ≦ T ≦ 50 (Si + Al) + 5ε + 810 ……
(2) However, the cooling is continuously performed by annealing the hot-rolled sheet for 30 minutes to 12 hours at a temperature T (° C) that satisfies the Si ... Si content (wt%) Al ... Al content (wt%). The average grain size of secondary recrystallized grains in the crystal structure of the material before hot rolling is 150μ
m to less than 500 μm and the volume ratio of the secondary recrystallized grains to 70% or more, cold rolling to a predetermined plate thickness, then continuous annealing, then 3% to 15% A method for producing a non-oriented electrical steel sheet having excellent magnetic properties and surface properties, which comprises performing a skin pass rolling with a reduction ratio to obtain a steel sheet having a filtered centerline waviness W CA of 1.0 μm or less on the steel sheet surface.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2006799A JPH0814015B2 (en) | 1990-01-16 | 1990-01-16 | Non-oriented electrical steel sheet having excellent magnetic properties and surface properties and method for producing the same |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2006799A JPH0814015B2 (en) | 1990-01-16 | 1990-01-16 | Non-oriented electrical steel sheet having excellent magnetic properties and surface properties and method for producing the same |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPH03211258A JPH03211258A (en) | 1991-09-17 |
| JPH0814015B2 true JPH0814015B2 (en) | 1996-02-14 |
Family
ID=11648229
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2006799A Expired - Fee Related JPH0814015B2 (en) | 1990-01-16 | 1990-01-16 | Non-oriented electrical steel sheet having excellent magnetic properties and surface properties and method for producing the same |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH0814015B2 (en) |
Families Citing this family (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH03274246A (en) * | 1990-03-23 | 1991-12-05 | Kawasaki Steel Corp | Nonoriented silicon steel sheet excellent in cuttability and blanking property |
| JP4585059B2 (en) * | 1999-08-17 | 2010-11-24 | 株式会社東芝 | Press-punched magnetic alloy ribbon, laminated magnetic core, and laminated magnetic core manufacturing method |
| CN102373367A (en) * | 2010-08-26 | 2012-03-14 | 宝山钢铁股份有限公司 | Cold-rolled electromagnetic steel plate for rapid cycling synchrotron and manufacturing method thereof |
| CN105925884B (en) * | 2016-05-30 | 2018-03-09 | 宝山钢铁股份有限公司 | A kind of high magnetic strength, low iron loss non-oriented silicon steel sheet and its manufacture method |
| JP7066698B2 (en) * | 2016-10-17 | 2022-05-13 | タタ、スティール、アイモイデン、ベスローテン、フェンノートシャップ | Steel base material for painted parts |
| US12104215B2 (en) | 2018-11-26 | 2024-10-01 | Baoshan Iron & Steel Co., Ltd. | High-magnetic-induction low-iron-loss non-oriented silicon steel sheet and manufacturing method therefor |
-
1990
- 1990-01-16 JP JP2006799A patent/JPH0814015B2/en not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| JPH03211258A (en) | 1991-09-17 |
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