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JPH089757B2 - Manufacturing method of aluminum alloy hard plate for forming - Google Patents
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JPH089757B2 - Manufacturing method of aluminum alloy hard plate for forming - Google Patents

Manufacturing method of aluminum alloy hard plate for forming

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Publication number
JPH089757B2
JPH089757B2 JP17164990A JP17164990A JPH089757B2 JP H089757 B2 JPH089757 B2 JP H089757B2 JP 17164990 A JP17164990 A JP 17164990A JP 17164990 A JP17164990 A JP 17164990A JP H089757 B2 JPH089757 B2 JP H089757B2
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JP
Japan
Prior art keywords
less
rolling
rate
forming
aluminum alloy
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
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JP17164990A
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Japanese (ja)
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JPH0459952A (en
Inventor
伸二 照田
Original Assignee
スカイアルミニウム株式会社
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Priority to JP17164990A priority Critical patent/JPH089757B2/en
Publication of JPH0459952A publication Critical patent/JPH0459952A/en
Publication of JPH089757B2 publication Critical patent/JPH089757B2/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

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Description

【発明の詳細な説明】 産業上の利用分野 この発明は、例えば2ピースアルミニウム缶の缶胴材
すなわちDI缶胴材の如く、塗装焼付け処理を行なって使
用される成形加工用アルミニウム合金硬質板の製造方法
に関し、特に高強度を有するとともに成形加工性に優れ
かつ耳率が低くしかも塗装焼付け処理後の成形が容易な
Al−Cu−Mg−Mn系アルミニウム合金硬質板の製造方法に
関するものである。
Description: TECHNICAL FIELD The present invention relates to an aluminum alloy hard plate for forming and used which is subjected to a paint baking treatment, such as a can body of a two-piece aluminum can, that is, a DI body. Concerning the manufacturing method, it has particularly high strength, excellent moldability, low ear rate, and easy molding after paint baking.
The present invention relates to a method for manufacturing an Al-Cu-Mg-Mn-based aluminum alloy hard plate.

従来の技術 成形加工用アルミニウム合金板、特にDI缶の缶胴材と
して用いられるアルミニウム合金板についてては、より
強度の高い薄板を使用することによる経済的効果を期待
するべく、近年は薄肉化と高強度化が進められている。
この種の用途には従来から種々のアルミニウム合金が用
いられているが、特にAl−Mg−Mn系合金であるJIS3004
合金硬質板は、強度を高めるために高圧延率の冷間圧延
を施した場合でも比較的良好な成形性を示すところか
ら、DI缶の缶胴材に使用されることが多い。
Conventional technology Aluminum alloy sheets for forming, especially aluminum alloy sheets used as can bodies for DI cans, have been made thinner in recent years in order to expect economic effects by using thinner sheets with higher strength. Higher strength is being promoted.
Various aluminum alloys have been conventionally used for this type of application, but in particular JIS 3004 which is an Al-Mg-Mn alloy.
The alloy hard plate shows relatively good formability even when subjected to cold rolling with a high rolling ratio to increase the strength, and therefore, it is often used for a can body of a DI can.

この3004合金硬質板の製造方法としては、その鋳塊に
均質化熱処理を施した後、常法に従って熱間圧延を施
し、次いで冷間圧延を施してからあるいは冷間圧延を施
さずに中間焼鈍を施し、その後最終冷間圧延を施して製
品板とすることが多い。このような工程中における中間
焼鈍としては、一般には箱焼鈍炉を用いて300〜400℃に
おいて30分〜3時間程度保持するバッチ焼鈍を適用する
ことが多く、この場合最終冷間圧延の圧延率は70%以上
とすることが通常である。また近年は連続焼鈍炉の普及
に伴ない、中間焼鈍に連続焼鈍を適用することによって
急速昇温、高温短時間加熱、急速冷却が可能となり、こ
れによる溶体化効果を利用して最終冷間圧延の圧延率が
比較的低くても高強度が得られるようにしたプロセスも
提案されている。
As a method for producing this 3004 alloy hard plate, after subjecting the ingot to homogenizing heat treatment, hot rolling is performed according to a conventional method, and then cold rolling is performed, or intermediate cold annealing is not performed. In many cases, the product sheet is subjected to the final cold rolling and then subjected to the final cold rolling. As the intermediate annealing in such a process, generally, a batch annealing in which a box annealing furnace is used and held at 300 to 400 ° C. for about 30 minutes to 3 hours is often applied. In this case, the rolling ratio of the final cold rolling is applied. Is usually 70% or more. In addition, with the spread of continuous annealing furnaces in recent years, rapid annealing, high-temperature short-time heating, and rapid cooling have become possible by applying continuous annealing to intermediate annealing. A process has also been proposed in which high strength can be obtained even if the rolling ratio is relatively low.

発明が解決しようとする課題 DI缶の缶胴材に要求される性能としては、前述のよう
に高強度を有することのほか、成形性が優れているこ
と、またDI加工時の耳率が低いことが要求される。さら
にDI缶の製造においては、缶胴の塗装焼付け処理後にさ
らに成形加工を行なう関係上、次のような問題がある。
DISCLOSURE OF THE INVENTION Problems to be Solved by the Invention As the performance required for a can body of a DI can, in addition to having high strength as described above, it has excellent moldability and a low ear rate during DI processing. Is required. Furthermore, in the production of DI cans, there are the following problems because of the further forming process after the coating and baking process of the can body.

すなわち、一般にDI缶の製造においては、DI加工によ
って缶胴を成形した後、塗装焼付け処理を行ない、さら
に缶胴の縁部に対してネッキング成形(口絞り加工)お
よびフランジ成形(つば出し加工)を行ない、その後缶
蓋とともにシーミング成形(縁部巻締め加工)を行なう
のが通常である。このように缶胴の縁部に対しては塗装
焼付後にさらに成形加工(ネッキング成形、フランジ成
形、シーミング成形)を施すことになるが、缶胴材の薄
肉化に伴ってこのような塗装焼付け処理後の成形加工時
に缶胴の座屈が生じやすくなる問題がある。すなわち、
缶胴の縁部は、塗装焼付け処理後の成形加工によって加
工硬化しやすいが、この縁部が硬化すれば各成形時にお
ける加工荷重を大きくしなければならなくなり、そのた
め缶胴の胴部で座屈が生じやすくなってしまうのであ
る。したがって缶胴材としては塗装焼付け処理後の加工
硬化が少ないことが望まれる。
In other words, in the manufacture of DI cans, generally, after the can body is formed by DI processing, paint baking is performed, and then necking forming (mouth drawing) and flange forming (flange forming) to the edge of the can body. After that, the seaming is usually performed together with the can lid (the edge winding process). In this way, the edge of the can body will be subjected to further forming processing (necking forming, flange forming, seaming forming) after baking, but such coating baking treatment is required as the thickness of the can body material becomes thinner. There is a problem that the can body is likely to buckle during the subsequent molding process. That is,
The edge of the can body is easily work-hardened by the molding process after paint baking, but if this edge hardens, the processing load at each molding must be increased. The buckle is likely to occur. Therefore, it is desired that the body of the can has little work hardening after the paint baking treatment.

ところで前述のような3004合金硬質板の従来の製造方
法の問題点は、中間焼鈍を箱型焼鈍炉で行なう場合と、
連続焼鈍炉で行なう場合とで異なる。
By the way, the problem with the conventional manufacturing method of the 3004 alloy hard plate as described above is that when performing intermediate annealing in a box-type annealing furnace,
It differs from when it is performed in a continuous annealing furnace.

すなわち先ず連続焼鈍炉を用いたプロセスでは、DI加
工時に発生する耳率の制御が難しく、そのため中間焼鈍
後の最終冷間圧延の圧延率を高くできない。また連続焼
鈍プロセスによる材料では、合金元素の固溶量が箱型焼
鈍プロセスの場合よりも多くなり、そのため加工による
硬化が大きく、したかってDI缶の塗装焼付け処理後の成
形時には析出硬化も加わって缶胴の縁部の硬化量が大き
くなり、成形が困難となる問題がある。但し連続焼鈍プ
ロセスによる材料は、一般に再結晶粒は細かく、したが
って成形性の点では優れている。
That is, first, in the process using the continuous annealing furnace, it is difficult to control the earring ratio that occurs during DI processing, and therefore the rolling ratio of the final cold rolling after the intermediate annealing cannot be increased. In addition, in the case of materials produced by the continuous annealing process, the solid solution amount of alloying elements is larger than in the case of the box-type annealing process, and therefore the hardening by processing is large, and therefore precipitation hardening is also added during the molding of the DI can after the baking process. There is a problem that the amount of curing at the edge of the can body becomes large and molding becomes difficult. However, the material obtained by the continuous annealing process generally has fine recrystallized grains and is therefore excellent in formability.

一方箱型焼鈍炉を用いたプロセスでは、強度を高めよ
うとすれば最終冷間圧延率を高めざるを得ず、このよう
に最終冷間圧延率を高くすれば耳率の制御が難しく、こ
の場合の耳率の制御については種々提案がされてはいる
が、概して再結晶粒が粗くなり、成形性も低下しがちと
なるという問題がある。但しこの箱型焼鈍プロセスによ
る材料では、DI缶の塗装焼付け処理後の緑部の加工硬化
は生じにくい長所がある。
On the other hand, in the process using the box-type annealing furnace, if the strength is to be increased, the final cold rolling rate must be increased, and if the final cold rolling rate is increased in this way, it is difficult to control the ear rate. Although various proposals have been made for controlling the ear rate in this case, there is a problem in that recrystallized grains become coarser and moldability tends to deteriorate. However, the material produced by this box-type annealing process has an advantage that the work hardening of the green part after the coating and baking treatment of the DI can hardly occurs.

この発明は以上の事情を背景としてなされたもので、
成形性および強度がともに優れ、かつ耳率の制御が容易
であって、しかも塗装焼付け処理後の加工硬化も少ない
アルミニウム合金硬質板を製造する方法を提供しようと
するものである。
This invention was made against the background of the above circumstances.
An object of the present invention is to provide a method for producing an aluminum alloy hard plate which has both excellent formability and strength, is easy to control the ear ratio, and has little work hardening after paint baking.

課題を解決するための手段 この発明の方法では、基本的には、Al−Mg−Mn−Cu系
の特定の成分のアルミニウム合金板を用い、熱間圧延に
おいては低い再結晶率でかつ微細な亜結晶粒が数多く生
じるようにし、引続く再結晶処理を急速加熱、短時間熱
処理として均一かつ微細な再結晶粒を生ぜしめ、その後
適切な圧延率で冷間圧延を行なうことによって、強度、
成形性に優れかつ耳率の制御も容易でしかも塗装焼付け
処理後の加工硬化の少ないアルミニウム合金硬質板を得
る。
Means for Solving the Problem In the method of the present invention, basically, using an aluminum alloy plate of a specific component of Al-Mg-Mn-Cu system, a low recrystallization rate and fine in hot rolling. A large number of sub-crystal grains are generated, and subsequent recrystallization treatment is performed by rapid heating and short-time heat treatment to produce uniform and fine recrystallized grains, and then cold rolling is performed at an appropriate rolling rate to obtain strength,
An aluminum alloy hard plate having excellent formability, easy control of ear ratio, and little work hardening after paint baking is obtained.

具体的には、この発明の成形加工用アルミニウム合金
硬質板の製造方法は、Mg0.5〜1.8wt%、Cu0.5wt%以
下、Mn0.6〜1.8wt%、Si0.1〜0.5wt%、Fe0.2〜1.0wt%
を含有し、かつFe/Siの重量比が3.0以下であり、残部が
Alおよび不可避的不純物よりなる合金を鋳造してその鋳
塊に均質化処理を施した後、熱間圧延を行なうにあた
り、熱間圧延上がり温度を270〜320℃とするとともに上
がり板厚を3mm以下とし、しかも熱延板の断面において
再結晶粒の占める面積率が30%以下となりかつ10μm以
下の亜結晶粒の占める面積率が50%以上となるように熱
間圧延し、その後1℃/sec以上の昇温速度で380〜620℃
の範囲内の温度に加熱して0〜10分保持して板断面のい
ずれの領域でも再結晶粒経が150μm以下となるように
再結晶処理を行ない、さらに70〜95%の圧延率で冷間圧
延を行なうことを特徴とするものである。
Specifically, the manufacturing method of the aluminum alloy hard plate for forming of the present invention, Mg 0.5 ~ 1.8 wt%, Cu 0.5 wt% or less, Mn 0.6 ~ 1.8 wt%, Si 0.1 ~ 0.5 wt%, Fe0.2-1.0wt%
And the Fe / Si weight ratio is 3.0 or less, and the balance is
After casting an alloy consisting of Al and unavoidable impurities and subjecting the ingot to homogenization treatment, when performing hot rolling, the hot rolling rise temperature is set to 270 to 320 ° C and the rise plate thickness is 3 mm or less. In addition, hot rolling is performed so that the area ratio of recrystallized grains in the cross section of the hot rolled sheet is 30% or less and the area ratio of subcrystalline grains of 10 μm or less is 50% or more, and then 1 ° C / sec. 380 to 620 ℃ at the above heating rate
It is heated to a temperature within the range of 0 to 10 minutes and then recrystallized so that the recrystallized grain size is 150 μm or less in any region of the plate cross section, and then cooled at a rolling rate of 70 to 95%. It is characterized by performing hot rolling.

作用 先ずこの発明におけるアルミニウム合金の成分限定理
由について説明する。
Action First, the reasons for limiting the components of the aluminum alloy in the present invention will be explained.

以下に示す各合金成分は、主として材料の強度を高め
るとともに、耳率や成形性の制御を目的として添加され
るものである。
The alloy components shown below are added mainly for the purpose of enhancing the strength of the material and controlling the ear ratio and formability.

Mg: MgはCu,Siとの共存によりG.P.ゾーン→β′Mg2Si→β
Mg2Si、あるいはG.P.ゾーン→S′Al2CuMg→SAl2CuMgの
ような析出過程をたどり、中間相の析出段階で強度向上
に寄与する。またMgは単独でも固溶融強化に寄与する元
素である。このようにMgは強度向上に不可欠な元素であ
るが、Mgが0.5wt%未満では強度向上の効果が少なく、
一方1.8wt%を越えれば、絞り成形上は特に問題ない
が、加工硬化しやすくなるため、再絞り性やしごき加工
性、さらにはDI缶における塗装焼付け後の緑部の成形性
を悪化させる。したがってMg量0.5〜1.8wt%の範囲内と
した。
Mg: Mg coexists with Cu and Si, GP zone → β′Mg 2 Si → β
It follows the precipitation process such as Mg 2 Si or GP zone → S'Al 2 CuMg → SAl 2 CuMg and contributes to the strength improvement at the precipitation stage of the intermediate phase. Further, Mg is an element that contributes to the solid-melt strengthening by itself. Thus, Mg is an essential element for improving strength, but if Mg is less than 0.5 wt%, the effect of improving strength is small,
On the other hand, if it exceeds 1.8 wt%, there is no particular problem in draw forming, but it becomes easy to work and harden, so that redrawability, ironing workability, and further the formability of the green part of the DI can after paint baking is deteriorated. Therefore, the amount of Mg is set within the range of 0.5 to 1.8 wt%.

Cu: この発明のプロセスでは再結晶処理時におけるCuの溶
体化を期待することができ、そのためCuが添加されてい
れば、塗装焼付け処理時におけるAl−Cu−Mg系析出物の
析出過程での時効硬化を利用して強度向上を図ることが
できる。但し、0.5wt%を越えてCuを添加した場合、時
効硬化は容易に得られるものの、成形加工中に加工硬化
が生じやすくなって成形性を損なうから、Cuの添加量上
限は0.5wt%とした。なおCu量の下限は特に定めない
が、Cu量が0.1wt%未満では上述の硬化がほとんど期待
できないから、0.1wt%以上添加することが好ましい。
Cu: In the process of the present invention, it is possible to expect solution treatment of Cu during the recrystallization treatment, and therefore, if Cu is added, in the precipitation process of Al-Cu-Mg-based precipitates during coating baking treatment. Strength can be improved by utilizing age hardening. However, if Cu is added in excess of 0.5 wt%, age hardening can be easily obtained, but work hardening tends to occur during molding, which impairs formability.Therefore, the upper limit of Cu addition is 0.5 wt%. did. The lower limit of the Cu content is not specified, but if the Cu content is less than 0.1 wt%, the above-mentioned curing can hardly be expected, so it is preferable to add 0.1 wt% or more.

Mn: Mnは強度向上に寄与するとともに成形性向上に有効な
元素である。特にこの発明における主用途である缶胴材
においては、苛酷なしごき成形が施され、しかも塗装焼
付け処理後にも縁部に成形加工が施されるから、これら
の成形性向上のためにMnの添加は重要である。通常数μ
m程度の金属間化合物は加工硬化を抑制することは良く
知られており、特にMnやFeの化合物は、しごき成形のよ
うな高度の加工を施した場合にはその後の成形では加工
硬化を生じにくくする作用を果たし、成形性の向上に寄
与する。また一方、通常アルミニウム合金板のしごき成
形においてはエマルジョンタイプの潤滑剤が使用されて
いるが、Mn系晶出物が少ない場合には、同程度の強度を
有していてもエマルジョンタイプの潤滑剤では潤滑能が
不足し、ゴーリングと称される擦り疵や焼付き等の外観
不良が生じるおそれある。Mn系晶出物はしごき成形時に
おいて固体潤滑的な効果をもたらして、しごき成形後の
外観不良の発生を防止するに有効であるが、その効果は
晶出物の大きい、量、種類に影響される。連続鋳造法を
用いた冷却速度の速い鋳造を行なう場合には、Mnが1.8w
t%を越えて添加されても特に支障なく鋳造できるばか
りでなく、晶出物サイズもその後の熱処理で調整可能で
あるが、現在主流を占めているDC鋳造法では、Mnが1.8w
t%を越えて添加されれば、MnAl6の初晶巨大金属間化合
物が生じ、逆に著しく成形性を損なうあそれがある。そ
こでMnの添加量の上限は1.8wt%とした。またMn量が0.6
wt%未満では、Mn化合物による前述の固体潤滑的な効果
および加工硬化の抑制作用が得られないため、Mn量の下
限は0.6wt%とした。
Mn: Mn is an element that contributes to the improvement of strength and is effective in improving the formability. In particular, in the can body material which is the main application in this invention, since severe ironing is carried out, and further, the molding is carried out at the edges even after the paint baking treatment, the addition of Mn for improving these moldability. Is important. Usually several μ
It is well known that intermetallic compounds of about m suppress work-hardening. Especially, compounds such as Mn and Fe cause work-hardening in subsequent molding when subjected to high-level processing such as ironing. It plays the role of making it harder and contributes to the improvement of moldability. On the other hand, emulsion type lubricants are usually used in the ironing of aluminum alloy sheets, but when the amount of Mn-based crystallized substances is small, an emulsion type lubricant with the same strength is used. In this case, the lubrication ability is insufficient, and there is a possibility that appearance defects such as scratches and seizure called "goring" may occur. Mn-based crystallized products bring about a solid lubricating effect during ironing and are effective in preventing the occurrence of appearance defects after ironing, but the effect affects the large amount, type, and type of crystallized products. To be done. When casting with a high cooling rate using the continuous casting method, Mn is 1.8w
Not only can it be cast without problems even if it is added in excess of t%, but the size of the crystallized substances can be adjusted by subsequent heat treatment, but in the DC casting method that is currently the mainstream, Mn is 1.8w.
If it is added in excess of t%, primary crystal giant intermetallic compounds of MnAl 6 will be formed, and conversely, formability will be significantly impaired. Therefore, the upper limit of the amount of Mn added is set to 1.8 wt%. The Mn content is 0.6
If it is less than wt%, the above-described solid lubricating effect and work hardening suppressing effect of the Mn compound cannot be obtained, so the lower limit of the Mn content was set to 0.6 wt%.

Fe: FeはSiとともにMnの晶出や析出を促進し、アルミニウ
ム基地中の固溶量やMn系不溶性化合物の分散状態を制御
するために必要な元素であり、そのためにはMn添加量に
応じた適切なFe量、Si量とする必要がある。Fe量が0.2w
t%未満では、適正な化合物分散状態を得ることが困難
となり、一方Fe量が1.0wt%を越えれば、Mn添加と相俟
って初晶巨大金属間化合物が発生して成形性を著しく損
なうおそれがある。そこでFe量は0.2〜1.0wt%の範囲内
とした。
Fe: Fe is an element necessary for promoting crystallization and precipitation of Mn together with Si, and controlling the amount of solid solution in the aluminum matrix and the dispersed state of Mn-based insoluble compound. It is necessary to set appropriate Fe content and Si content. Fe amount is 0.2w
If it is less than t%, it becomes difficult to obtain a proper compound dispersion state, while if the amount of Fe exceeds 1.0 wt%, the primary crystal giant intermetallic compound is generated together with the addition of Mn, and the formability is significantly impaired. There is a risk. Therefore, the Fe content is set within the range of 0.2 to 1.0 wt%.

Si: Siが添加されている場合、Mg2Si系化合物の析出過程
でも時効硬化が期待できることは良く知られているが、
この発明におけるSiの役割は、強度向上よりむしろ成形
加工時の方向性の制御にある。すなわちFeは再結晶粒を
微細にするためには積極的に添加して良い元素である
が、Feがアルミニウム基地中に固溶している場合、45°
耳が発生しやすくなるから、Feはアルミニウム基地中に
固溶させないことが好ましい。SiはFeの析出を促進し、
結果的にアルミニウム基地中のFeの固溶量を減少させ、
これにより成形加工性の方向性を良好にする。ここでFe
/Si比(重量比)が3.0を越えればSiが少な過ぎてFeの固
溶量が大きくなる。、Fe/Si比が3.0以下であれば、中間
焼鈍を箱型焼鈍プロセスとした場合でもFeの固溶量を少
なくして方向性を良好とすることができる。したがって
Si量はFe量に応じてFe/Si比が3.0以下となるように定め
る必要がある。またSiの絶対量が0.1wt%未満では最適F
e/Si比をえることが難しく、一方0.5wt%を越えればFe
の析出物を促進させる硬化が飽和し、しかもMg2Siによ
る時効硬化が進んで塗装焼付け処理後の成形性が悪くな
る。したがってSiの絶対量は0.1〜0.5wt%の範囲内とし
た。
Si: When Si is added, it is well known that age hardening can be expected even in the precipitation process of Mg 2 Si-based compound,
The role of Si in the present invention lies not in improving the strength but in controlling the directionality during molding. That is, Fe is an element that may be positively added in order to make the recrystallized grains fine, but when Fe is a solid solution in the aluminum matrix, 45 °
It is preferable that Fe is not solid-dissolved in the aluminum matrix because ears are likely to occur. Si promotes the precipitation of Fe,
As a result, the solid solution amount of Fe in the aluminum base is reduced,
This improves the directionality of molding processability. Where Fe
If the / Si ratio (weight ratio) exceeds 3.0, the amount of Si becomes too small and the solid solution amount of Fe increases. When the Fe / Si ratio is 3.0 or less, the directionality can be improved by reducing the solid solution amount of Fe even when the intermediate annealing is a box-type annealing process. Therefore
It is necessary to determine the Si amount so that the Fe / Si ratio is 3.0 or less according to the Fe amount. Optimum F when the absolute amount of Si is less than 0.1 wt%
It is difficult to obtain the e / Si ratio, while if it exceeds 0.5 wt% Fe
The hardening that accelerates the precipitation of is saturated, and the age hardening by Mg 2 Si proceeds, and the formability after the coating baking treatment deteriorates. Therefore, the absolute amount of Si is set within the range of 0.1 to 0.5 wt%.

以上の各成分の残部は、基本的にはAlおよび不可避不
純物とすれば良い。なお通常のアルミニウム合金におい
ては鋳塊結晶粒微細化のために、Ti、あるいはTiおよび
Bを微量添加することがあり、この発明の場合において
も微量のTi、あるいはTiおよひBを含有していも良い。
但し、Tiを添加する場合、0.01wt%未満ではTi添加の効
果が得られず、一方0.2wt%を越えれば初晶TiAl3か晶出
して成形性を害するから、Tiは0.01〜0.2wt%の範囲内
とすることが好ましい。またTiとともにBを添加する場
合、Bが1ppm未満ではB添加の効果が得られず、一方B
が500ppmを越えればTiB2の粗大粒子が混入して成形性を
害するから、Bは1〜500ppmの範囲内とすることが好ま
しい。そのほか、鋳造時の溶湯酸化防止のためにBeを0.
02wt%以下の範囲で添加しても良い。さらに不純物とし
てCr,Zn,V,Zr等の元素が微量含有されていても良く、Cr
0.3wt%以下、Zn0.1wt%以下、V0.3wt%以下、Zr0.3wt
%以下であれば特にこの発明の効果が損なわれることは
ない。
The balance of the above components may basically be Al and inevitable impurities. In addition, in a usual aluminum alloy, a minute amount of Ti or Ti and B may be added for refining ingot crystal grains. In the case of the present invention, a small amount of Ti, or Ti and B is also contained. Good.
However, in the case of adding Ti, if less than 0.01 wt%, the effect of Ti addition cannot be obtained, while if it exceeds 0.2 wt%, primary TiAl 3 crystallizes and impairs formability, so Ti is 0.01 to 0.2 wt%. It is preferably within the range. Also, when B is added together with Ti, if B is less than 1 ppm, the effect of B addition cannot be obtained.
Is more than 500 ppm, coarse particles of TiB 2 are mixed and impair the moldability, so B is preferably in the range of 1 to 500 ppm. In addition, Be is set to 0 to prevent molten metal oxidation during casting.
You may add in the range of 02 wt% or less. Furthermore, trace elements such as Cr, Zn, V, and Zr may be contained as impurities.
0.3wt% or less, Zn0.1wt% or less, V0.3wt% or less, Zr0.3wt
If it is at most%, the effect of the present invention is not particularly impaired.

次にこの発明の成形加工用アルミニウム合金硬質板の
製造方法におけるプロセスについて説明する。
Next, the process in the method for manufacturing an aluminum alloy hard plate for forming according to the present invention will be described.

先ず前述のような成分組成を有するアルミニウム合金
の溶湯を常湯を常法に従って溶製し、鋳造する。鋳造法
としては一般的なDC鋳造法(半連続鋳造法)を適用すれ
ば良い。得られた鋳塊に対しては。均質化熱処理として
の加熱を施した後熱間圧延前の予備加熱を施すか、また
は均質化熱処理を兼ねた熱間圧延前予備加熱を施し、引
続き熱間圧延を行なう。均質化熱処理の条件は特に限定
しないが、通常は、500〜620℃、1〜20時間とすれば良
い。
First, a molten aluminum alloy having the above-described composition is prepared by casting ordinary hot water according to a conventional method and casting. As a casting method, a general DC casting method (semi-continuous casting method) may be applied. For the obtained ingot. After heating as a homogenizing heat treatment, preheating before hot rolling is performed, or preheating before hot rolling that also serves as homogenizing heat treatment is performed, and then hot rolling is performed. The conditions for the homogenizing heat treatment are not particularly limited, but usually 500 to 620 ° C. and 1 to 20 hours may be used.

熱間圧延においては、熱延上がり温度(仕上げ圧延の
上がり温度)を270〜320℃、好ましくは280〜310℃と
し、かつ上がり板厚を3mm以下とする。また熱延上がり
状態での熱延板の再結晶状態として、その熱延板の断面
において再結晶粒が占める面積率(以下これを再結晶率
と称す)が30%以下であってしかも同じ熱延板の断面に
おいて常径10mm以下の亜結晶粒が占める面積率(以下こ
れを亜結晶粒と称す)か50%以上となるように制御す
る。
In hot rolling, the hot rolling temperature (temperature of finish rolling) is 270 to 320 ° C, preferably 280 to 310 ° C, and the rolled sheet thickness is 3 mm or less. In the recrystallized state of the hot rolled sheet in the hot rolled state, the area ratio of recrystallized grains in the cross section of the hot rolled sheet (hereinafter referred to as the recrystallization rate) is 30% or less and The area ratio occupied by subcrystal grains having a normal diameter of 10 mm or less (hereinafter referred to as subcrystal grain) in the cross section of the rolled sheet is controlled to be 50% or more.

ここで、一般に広く知られているように、アルミニウ
ム合金の熱間加工においては、初期の加工硬化によって
転位が増加・蓄積され、一方その転位の増加に伴なって
転位の運動、すべりが活発化して転位の消滅速度が生成
速度と一致するようになり、転位密度が平衡値に達する
ことになる。その過程で転位の再配列、すなわちポリゴ
ン化が生じ、規則的な転位配列からなる亜粒界(小角粒
界)によって区分される微細な編目組織(亜結晶粒組
織)が生成される。この状態で亜粒界によって取囲まれ
る微細な各領域をそれぞれ亜結晶粒(サブグレイン)と
称している。さらにこの亜結晶粒のうち、あるものが生
長してそれが再結晶の核となり、その再結晶核から再結
晶粒が成長し、再結晶粒組織が生成される。なお以上の
ような過程は、熱間加工が終了して最終的に熱延板が再
結晶温度以下の低温に冷却されるまで続く。
Here, as is generally known, in hot working of aluminum alloys, dislocations are increased / accumulated by the initial work hardening, and as the dislocations increase, dislocation motion and slip are activated. The dislocation annihilation speed becomes equal to the generation speed, and the dislocation density reaches the equilibrium value. In the process, rearrangement of dislocations, that is, polygonization occurs, and a fine knitting structure (subcrystalline structure) divided by subgrain boundaries (small-angle grain boundaries) having a regular dislocation arrangement is generated. In this state, each fine region surrounded by subgrain boundaries is called a subgrain. Further, some of these sub-crystal grains grow and serve as nuclei for recrystallization, and the re-crystal grains grow from the re-crystal nuclei to generate a re-crystal grain structure. The above process continues until the hot working is finished and the hot rolled sheet is finally cooled to a temperature lower than the recrystallization temperature.

そしてこの発明において熱延上がりの状態、すなわち
熱間圧延が終了して再結晶温度以下まで熱延板が冷却さ
れた状態での組織状態として、前述のように再結晶率が
30%以下であってしかも亜結晶率が50%以上となるよう
な状態に制御する。なお再結晶率は、熱延板断面の組織
を光学顕微鏡等で観察することにより判定することがで
き、また亜結晶粒の面積率は、透過電子顕微鏡等によっ
て同じく熱延板断面の組織状態を観察することによって
判定することができる。
And in the present invention, the state of hot rolling, that is, the structure state in the state where the hot rolling is completed and the hot rolled sheet is cooled to the recrystallization temperature or lower, the recrystallization rate is as described above.
It is controlled to be 30% or less and a subcrystal ratio of 50% or more. Note that the recrystallization rate can be determined by observing the structure of the cross section of the hot rolled sheet with an optical microscope, and the area ratio of the sub-crystal grains also shows the structure state of the cross section of the hot rolled sheet with a transmission electron microscope. It can be determined by observing.

前述のような再結晶状態は、概括的に言えば、未再結
晶状態もしくはそれに近い不完全再結晶状態ではある
が、微細な亜結晶粒が多数生じている状態と言うことが
でき、このような再結晶状態としておくことによって、
次の再結晶処理で微細かつ均一な再結晶組織を得ること
が可能となる。このような再結晶状態は、前述のように
熱間圧延上がり温度を規制するほか、仕上げ圧延段階で
の圧延パススケジュール、パス間時間、圧延速度等を適
切に定めることにより達成することができる。ここで、
熱延上がり温度が270℃未満では、如何なる圧延条件を
適用しても50%以上の再結晶粒を得ることは困難であ
り、一方320℃を越えれば、如何なる圧延条件を適用し
ても圧延上がりの再結晶率が30%を越えてしまい、板の
表面部およびエッジ部が再結晶する一方、それ以外の部
分(特に板の厚み方向の中央部分)は回復組織となって
その部分では焼鈍後(熱間圧延後の再結晶処理後)の再
結晶組織が粗大となり、その結果コイル内で組織の不均
一が生じ、ひいては成形性を悪化させる。したがって熱
延上がり温度は270℃以上320℃以下とした。また熱延上
がり板厚いが3mmを越えれば、所定の最終板厚を得るた
めには再結晶処理後の冷間圧延で圧延率を著しく大きく
せざるを得ず、そのため耳率の制御が困難となる。した
がって熱延上がり板厚は3mm以下とした。
Generally speaking, the recrystallized state as described above is an unrecrystallized state or an incomplete recrystallized state close to it, but it can be said that a large number of fine subcrystal grains are generated. By keeping it in a recrystallized state,
A fine and uniform recrystallized structure can be obtained by the next recrystallization treatment. Such a recrystallized state can be achieved by regulating the hot rolling finish temperature as described above and by appropriately determining the rolling pass schedule, the interpass time, the rolling speed, etc. in the finish rolling stage. here,
If the hot rolling temperature is less than 270 ° C, it is difficult to obtain 50% or more of recrystallized grains under any rolling condition, while if it exceeds 320 ° C, the rolling after rolling under any rolling condition is difficult. Recrystallization rate exceeds 30%, and the surface and edge of the plate recrystallize, while the other parts (especially the central part in the thickness direction of the plate) become a recovery structure after annealing in that part. The recrystallized structure (after the recrystallization treatment after hot rolling) becomes coarse, and as a result, the structure becomes nonuniform in the coil, resulting in deterioration of formability. Therefore, the hot rolling temperature is set to 270 ° C or higher and 320 ° C or lower. Further, if the hot rolled sheet thickness exceeds 3 mm, in order to obtain a predetermined final sheet thickness, the rolling rate must be remarkably increased in cold rolling after the recrystallization treatment, which makes it difficult to control the ear rate. Become. Therefore, the hot rolled sheet thickness is set to 3 mm or less.

上述のような熱間圧延により得られた圧延板には、そ
の後一旦冷却してから、あるいは冷却せずにそのまま、
1℃/sec以上の昇温速度で380〜620℃の範囲内の温度ま
で昇温し、その温度で0〜10分保持する再結晶処理を施
して、板表面から厚み方向の中央部までのいずれの部分
でも再結晶粒経が150mm以下となっている均一かつ微細
な再結晶組織を得る。このように均一かつ微細な再結晶
組織が得られれば、その後の冷間圧延後の板においても
成形性が優れる。またこのような再結晶処理により成形
加工時の耳率が0〜90℃高耳の板が得られら、その後の
冷間圧延率を高めても45°低耳材が得られる。これは、
圧延上がりの状態で生成された亜結晶粒は立方体方位
(キューブ方位)が多く、その後の1℃/sec以上の昇温
速度での再結晶処理のための加熱時にはそのキューブ方
位の亜結晶粒の成長を抑制するものが析出しないため、
その方位の亜結晶粒が優先的に成長して再結晶し、0〜
90°高耳の板が得られるのである。ここで、再結晶処理
における昇温速度が1℃/sec未満では前述のように板厚
方向のいずれの部分でも、150μm以下の微細な再結晶
粒とすることが困難となるとともに、キューブ方位の亜
結晶粒の成長が阻害されて耳率の制御が難しくなるおそ
れがある。また再結晶処理の温度が380℃未満では充分
に再結晶させることが困難となり、一方620℃を越えれ
ば共晶溶融のおそれがあるとともに粗大な再結晶率が生
じるおそれがある。また保持時間が10分を越える場合も
再結晶粒が成長して粗大となるおそれがある。なおこの
ような1℃/sec以上の昇温速度での再結晶処理は、連続
焼鈍炉を用いた加熱により達成できる。
The rolled plate obtained by the hot rolling as described above, after cooling once, or as it is without cooling,
The temperature is raised to a temperature in the range of 380 to 620 ° C at a heating rate of 1 ° C / sec or more, and a recrystallization treatment is performed by holding at that temperature for 0 to 10 minutes, from the plate surface to the center in the thickness direction. A uniform and fine recrystallized structure with a recrystallized grain diameter of 150 mm or less is obtained in any part. If such a uniform and fine recrystallized structure is obtained, the formability is excellent even in the plate after the cold rolling thereafter. Further, by such a recrystallization treatment, a plate having a high ear of 0 to 90 ° C. at the time of forming can be obtained, and a 45 ° low ear material can be obtained even if the cold rolling rate thereafter is increased. this is,
Sub-crystal grains generated in the as-rolled state have many cubic orientations (cube orientations), and during subsequent heating for recrystallization treatment at a heating rate of 1 ° C / sec or more, the sub-grain orientations of the cube orientations Since the substance that suppresses growth does not precipitate,
Subgrains in that direction grow preferentially and recrystallize,
A plate with 90 ° high ears can be obtained. Here, if the temperature rising rate in the recrystallization treatment is less than 1 ° C./sec, it becomes difficult to form fine recrystallized grains of 150 μm or less in any portion in the plate thickness direction as described above, and the cube orientation The growth of subgrains may be hindered and it may be difficult to control the ear rate. If the recrystallization temperature is lower than 380 ° C, it becomes difficult to recrystallize sufficiently, while if it exceeds 620 ° C, eutectic melting may occur and a coarse recrystallization rate may occur. Also, if the holding time exceeds 10 minutes, recrystallized grains may grow and become coarse. The recrystallization treatment at such a temperature rising rate of 1 ° C./sec or more can be achieved by heating using a continuous annealing furnace.

上述のように再結晶処理を施した後には、70%以上95
%以下の圧延率で冷間圧延を施して最終板厚とする。こ
の冷間圧延は、所要り最終板厚をえるために必要であ
る。ここで、この発明い用いている合金成分の系では、
再結晶処理後の冷間圧延率を70%以上とすれば、缶胴と
しての塗装焼付け処理後の成形加工時において加工硬化
が生じにくくなる。また、この発明で適用している熱間
圧延および再結晶処理の条件によれば、再結晶処理後に
70%以上の冷間圧延を施しても耳率の点で悪化すること
は避けることができる。
70% or more 95% after recrystallization as described above
The final strip thickness is obtained by cold rolling at a rolling rate of not more than%. This cold rolling is necessary to obtain the required final strip thickness. Here, in the alloy component system used in the present invention,
When the cold rolling rate after the recrystallization treatment is 70% or more, work hardening is less likely to occur during the molding process after the coating and baking treatment for the can body. Further, according to the conditions of hot rolling and recrystallization treatment applied in the present invention, after the recrystallization treatment
Even if cold rolling of 70% or more is performed, it is possible to avoid deterioration in ear ratio.

上述のような冷間圧延により得られた冷延板はそのま
ま最終板として製品としても良いが、深絞り加工等の成
形性がより一層重視される場合には、冷間圧延後にさら
に90〜150℃の低温で最終焼鈍を施しても良い。この最
終焼鈍の温度が150℃を越える高温では、塗装焼付け処
理時に硬化して、その後のネッキング成形、フランジ成
形、シーミング成形時の加工荷重を大きくしなければな
らない不都合が生じ、一方90℃未満では最終焼鈍によっ
て成形性を向上させる効果が得られない。
The cold-rolled sheet obtained by cold rolling as described above may be used as a final sheet as a product as it is, but if the formability such as deep drawing is further emphasized, it is further 90 to 150 after cold rolling. The final annealing may be performed at a low temperature of ° C. If the temperature of this final annealing is higher than 150 ° C, it will harden during the paint baking process, and the processing load will need to be increased during subsequent necking molding, flange molding, and seaming molding. The effect of improving the formability cannot be obtained by the final annealing.

以上のようにして、強度および方向性(耳率)、絞り
成形性、再絞り成形性、しごき成形性等の成形性に優
れ、しかも塗装焼付け処理後の成形時において加工硬化
せず、その塗装焼付け処理後のネッキング成形、フラン
ジ成形、シーミング成形における成形性も良好なアルミ
ニウム合金硬質板をえることができる。
As described above, it has excellent formability such as strength and directionality (ear ratio), drawability, redrawability, and ironing formability. Moreover, it does not work harden during molding after coating baking processing, and its coating It is possible to obtain an aluminum alloy hard plate having good formability in necking forming, flange forming, and seaming forming after baking treatment.

実施例 第1表に示すような本発明成分組成範囲内の合金A〜
Cおよび本発明成分組成範囲外の合金Dについて、常法
に従ってDC鋳造し、得られた鋳塊に対し600℃×6時間
の均質化熱処理を行なった後、熱間圧延を行なった。熱
間圧延は、上がり板厚および上がり温度が第2表中の製
造プロセス番号1〜8に示すような条件となるように行
ない、かつ圧延パススケジュール、パス時間、圧延速度
を調整することによって、同じく第2表中に示すように
熱延上がり板での再結晶率、10μm以下の亜結晶率を得
た。そして製造プロセス番号3〜7の場合は熱間圧延後
直ちに、また製造プロセス番号1,2,8の場合は一次冷間
圧延を施して第2表中に示す板厚とした後それぞれ第2
表中に示す条件で再結晶処理を施した。再結晶処理後の
最大結晶粒経を第2表中に示す。その後、冷間圧延を施
して、それぞれ板厚0.30mmの最終板とした。このように
して得られた各板について、塗装焼付け処理に相当する
200℃×20分の熱処理(ベーキング)後の耐力を調べる
とともに、方向性として絞り成形における耳率を調べ、
さらにDI加工における成形性と、DI加工後に前記同様に
ベーキングを行なった後の縁部の耐力、およびさらに縁
部にネッキング成形を施したときのネッキング成形性
(しわの発生の程度)、ネッキング成形に必要な最大荷
重を調べた結果を第3表に示す。
Example Alloys A within the composition range of the present invention as shown in Table 1
C and alloy D outside the compositional range of the composition of the present invention were DC-cast according to a conventional method, and the obtained ingot was subjected to homogenizing heat treatment at 600 ° C. for 6 hours and then hot-rolled. The hot rolling is performed such that the rising plate thickness and the rising temperature satisfy the conditions shown in the manufacturing process numbers 1 to 8 in Table 2, and by adjusting the rolling pass schedule, the pass time, and the rolling speed, Similarly, as shown in Table 2, the recrystallization rate in the hot-rolled sheet and the sub-crystallization rate of 10 μm or less were obtained. Then, in the case of manufacturing process Nos. 3 to 7, immediately after hot rolling, and in the case of manufacturing process Nos. 1, 2 and 8, primary cold rolling was performed to obtain the plate thickness shown in Table 2
Recrystallization treatment was performed under the conditions shown in the table. The maximum grain size after recrystallization treatment is shown in Table 2. Then, cold rolling was performed to obtain final plates each having a plate thickness of 0.30 mm. Corresponds to paint baking for each plate obtained in this way
In addition to examining the yield strength after heat treatment (baking) at 200 ° C for 20 minutes, the earring ratio in drawing forming was investigated as the directionality.
Furthermore, the formability in DI processing, the proof stress of the edge after baking as described above after DI processing, and the necking formability (the degree of wrinkling) when necking is applied to the edge, necking molding Table 3 shows the results of examining the maximum load required for

なお第3表において、DI成形性、ネッキング成形性
(しわ発生程度)の評価は、従来の一般的なプロセスに
相当するNo.1のプロセスを基準とし、これを良(○印)
とし、やや劣る場合に△印、不良率が甚だしい場合に×
印を付した。また方向性(耳率)は、ブランク径58mm
φ、ポンチ径32mmφ、クリアランス45%の条件で、しご
きを入れずに素材の特徴があらわれやすい深絞り加工を
行ない、深絞り後の耳率を調べた。さらにネッキング荷
重は、絞り率4%、クリアランス20%の条件で調べた。
In Table 3, the DI moldability and necking moldability (degree of wrinkle formation) are evaluated based on the No. 1 process, which corresponds to the conventional general process, and are evaluated as good (○).
And △ when it is slightly inferior, and × when the defect rate is extremely bad.
Marked. In addition, the directivity (ear ratio) is 58mm blank diameter.
Under the conditions of φ, punch diameter of 32 mmφ, and clearance of 45%, deep drawing was performed without ironing and the characteristics of the material were apt to appear, and the ear ratio after deep drawing was examined. Further, the necking load was examined under the conditions of a draw ratio of 4% and a clearance of 20%.

第3表から明らかなように、この発明の成分組成範囲
内の合金を用いて、この発明の条件にしたがって製造し
たNo.5、No.7によるアルミニウム合金圧延板では、この
発明の条件を外れる比較条件で製造したNo.1〜No.4、N
o.6による圧延板と比較して耳率の点では優れ、またDI
成形性は同等である。一方、この発明の成分組成範囲を
外れる合金によるNo.8の圧延板では、高い強度は容易に
得られるものの、缶胴材として薄肉化した場合に要求さ
れる塗装焼付け処理後の耐力28.5kgf/mm2を越える高強
度材とした場合は、成形性に劣るためDI加工以降の成形
か不可能であった。またNo.1〜No.7の圧延板もいずれも
塗装焼付け処理後の耐力が28.5kg/mm2以上となるように
調整したものであるが、元板のままでの塗装焼付け処理
後の耐力と、DI加工後に塗装焼付け処理を施した場合の
耐力との差は、再結晶処理後の冷間圧延率が70%以上の
材料(No.2〜No.7)では0.6〜0.7kgf/mm2程度と小さか
ったのに対し、再結晶処理後の冷間圧延率が70%未満の
材料(No.1、No.8)では、その差が1.2kgf/mm2以上あ
り、このことから、再結晶処理後の冷間圧延率が70%以
上でその後の成形加工時における加工硬化が少なくなる
ことが判る。さらに、比較条件によるNo.1と本発明条件
によるNo.7とを比較すれば、本発明条件によるNo.7の方
が縁部の耐力は1.2kgf/mm2も高くなっているにもかかわ
らず、ネッキング荷重は逆に小さくなっており、このこ
とから、本発明条件によれば塗装焼付け処理後の成形性
を悪化させることなく、塗装焼付け処理後の良好な成形
性を確保できることが判る。また、再結晶処理後の結晶
粒径に関しては、最大粒径で150μm以下の材料(No.
1、No.2、No.4、No.5、No.7)では、最大粒径が150μm
を越える材料(No.3、No.6)と比較してネッキング成形
性が良好でシワ発生程度が小さくなっており、したがっ
て再結晶処理後の粒径を最大でも150μm以下とするこ
とによって塗装焼付け処理後の成形性を良好になし得る
ことか明らかである。
As is clear from Table 3, the aluminum alloy rolled plates according to No. 5 and No. 7 manufactured according to the conditions of the present invention using the alloys within the compositional range of the present invention deviate from the conditions of the present invention. No. 1 to No. 4, N manufactured under comparative conditions
Compared with the rolled plate according to o.6, it has better earing rate and DI
Formability is equivalent. On the other hand, in No. 8 rolled plate made of an alloy out of the compositional range of the present invention, although high strength is easily obtained, the yield strength after coating baking treatment required when thinned as a can body material is 28.5 kgf / When a high-strength material exceeding mm 2 was used, it was impossible to perform molding after DI processing because of poor moldability. In addition, all the rolled sheets of No. 1 to No. 7 were adjusted so that the yield strength after painting and baking was 28.5 kg / mm 2 or more. And the yield strength when paint baking is performed after DI processing is 0.6-0.7 kgf / mm for materials with a cold rolling rate of 70% or more after recrystallization (No.2 to No.7). The difference was 1.2 kgf / mm 2 or more for the materials (No. 1 and No. 8) whose cold rolling rate after recrystallization treatment was less than 70%, while it was as small as about 2 . It can be seen that when the cold rolling rate after the recrystallization treatment is 70% or more, the work hardening during the subsequent forming process is reduced. Furthermore, comparing No. 1 according to the comparison conditions with No. 7 according to the conditions of the present invention, it is possible that No. 7 according to the conditions of the present invention has a higher proof strength of 1.2 kgf / mm 2 at the edge. On the contrary, the necking load is reduced, which means that according to the conditions of the present invention, it is possible to secure good formability after the coating baking treatment without deteriorating the formability after the coating baking treatment. Regarding the crystal grain size after recrystallization, the maximum grain size is 150 μm or less (No.
1, No. 2, No. 4, No. 5, No. 7), the maximum particle size is 150 μm
Necking moldability is better and wrinkles are less than those of materials exceeding No. 3 (No. 3, No. 6). Therefore, paint baking is possible by making the particle size after recrystallization treatment 150 μm or less at the maximum. It is obvious that the moldability after treatment can be excellently achieved.

発明の効果 以上の実施例からも明らかなように、この発明の製造
方法によれば、成形性が良好でかつ高強度を有し、しか
も方向性が良好で成形加工時の耳率が低く、なおかつ塗
装焼付け処理後の成形加工時における加工硬化の少ない
アルミニウム合金硬質板を得ることができる。そして特
に2ピース缶用のDI缶胴材の製造にこの発明の方法を適
用すれば、単にDI加工時の成形性が優れるばかりでな
く、薄肉化のために塗装焼付け処理後の強度を高めて
も、その後の成形加工時における加工硬化が少ないた
め、缶胴の縁部に対するネッキング成形、フランジ成
形、シーミング成形時における成形性を良好にして成形
不良の発生を防止できるとともに、これらの成形におけ
る加工荷重が少なくて済むため、これらの成形時に缶胴
が座屈を生じることを防止することができる。したがっ
てこの発明の製造方法は特にDI缶の缶胴材の製造に最適
であるが、もちろんその他の成形加工用の硬質板の製造
にも適用できる。
EFFECTS OF THE INVENTION As is clear from the above examples, according to the manufacturing method of the present invention, the moldability is good and has high strength, and the directionality is good and the earring rate during molding is low, Further, it is possible to obtain an aluminum alloy hard plate with less work hardening during the forming process after the paint baking process. If the method of the present invention is applied to the production of DI can body for 2-piece cans, in particular, not only the moldability during DI processing is excellent, but also the strength after paint baking is increased for thinning. However, since there is little work hardening during the subsequent molding process, the moldability during necking molding, flange molding, and seaming molding for the edge of the can body can be improved to prevent the occurrence of molding defects. Since the load is small, it is possible to prevent the can body from buckling during molding. Therefore, the manufacturing method of the present invention is particularly suitable for manufacturing can bodies for DI cans, but of course it can be applied to manufacturing other hard plates for molding.

Claims (1)

【特許請求の範囲】[Claims] 【請求項1】Mg0.5〜1.8wt%、Cu0.5wt%以下、Mn0.6〜
1.8wt%、Si0.1〜0.5wt%、Fe0.2〜1.0wt%を含有し、
かつFe/Siの重量比が3.0以下であり、残部がAlおよび不
可避的不純物よりなる合金を鋳造してその鋳塊に均質化
熱処理を施した後、熱間圧延を行なうにあたり、熱間圧
延上がり温度を270〜320℃とするとともに上がり板厚を
3mm以下とし、しかも熱延板の断面において再結晶粒の
占める面積率が30%以下となりかつ10μm以下の亜結晶
粒の占める面積率が50%以上となるように熱間圧延し、
その後1℃/sec以上の昇温速度で380〜620℃の範囲内の
温度に加熱して0〜10分保持して板断面のいずれの領域
でも再結晶粒径が150μm以下となるように再結晶処理
を行ない、さらに70〜95%の圧延率で冷間圧延を行なう
ことを特徴とする、強度、耳率および成形性に優れかつ
成形加工における加工硬化の少ない成形加工用アルミニ
ウム合金硬質板の製造方法。
1. Mg 0.5 to 1.8 wt%, Cu 0.5 wt% or less, Mn 0.6 to
Contains 1.8wt%, Si0.1-0.5wt%, Fe0.2-1.0wt%,
In addition, after casting an alloy having a weight ratio of Fe / Si of 3.0 or less and the balance of Al and unavoidable impurities and subjecting the ingot to homogenizing heat treatment, hot rolling is performed before hot rolling. Increase the plate thickness as the temperature rises to 270-320 ℃
Hot rolling is performed so that the area ratio occupied by recrystallized grains is 30% or less and the area percentage occupied by sub-crystal grains of 10 μm or less is 50% or more in the cross section of the hot rolled sheet,
Then, heat at a temperature rising rate of 1 ℃ / sec or more to a temperature in the range of 380 to 620 ℃ and hold for 0 to 10 minutes to recrystallize so that the recrystallized grain size becomes 150 μm or less in any region of the plate cross section. The aluminum alloy hard plate for forming is excellent in strength, earring rate and formability and has less work hardening in forming, which is characterized by performing crystallization treatment and cold rolling at a rolling rate of 70 to 95%. Production method.
JP17164990A 1990-06-29 1990-06-29 Manufacturing method of aluminum alloy hard plate for forming Expired - Lifetime JPH089757B2 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP17164990A JPH089757B2 (en) 1990-06-29 1990-06-29 Manufacturing method of aluminum alloy hard plate for forming

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP17164990A JPH089757B2 (en) 1990-06-29 1990-06-29 Manufacturing method of aluminum alloy hard plate for forming

Publications (2)

Publication Number Publication Date
JPH0459952A JPH0459952A (en) 1992-02-26
JPH089757B2 true JPH089757B2 (en) 1996-01-31

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Application Number Title Priority Date Filing Date
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Country Status (1)

Country Link
JP (1) JPH089757B2 (en)

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5913989A (en) * 1996-07-08 1999-06-22 Alcan International Limited Process for producing aluminum alloy can body stock

Also Published As

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JPH0459952A (en) 1992-02-26

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