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Zubovics et al., 1976 - Google Patents
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Zubovics et al., 1976 - Google Patents

The cycloadducts of hexafluoroacetone and-thioacetone with diphenylketene

Zubovics et al., 1976

Document ID
8023450166302966940
Author
Zubovics Z
Ishikawa N
Publication year
Publication venue
Journal of Fluorine Chemistry

External Links

Snippet

Hexafluoroacetone reacted with diphenylketene in the presence of potassium fluoride to give a 1: 1 cycloadduct of β-lactone structure. On the other hand, hexafluorothioacetone, liberated from 2, 2, 4, 4-tetrakis (trifluoromethyl)-1, 3-dithietane by potassium fluoride …
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    • C07C45/00Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/61Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups
    • C07C45/67Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups by isomerisation; by change of size of the carbon skeleton
    • C07C45/68Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups by isomerisation; by change of size of the carbon skeleton by increase in the number of carbon atoms
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    • C07ORGANIC CHEMISTRY
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    • C07D333/00Heterocyclic compounds containing five-membered rings having one sulfur atom as the only ring hetero atom
    • C07D333/02Heterocyclic compounds containing five-membered rings having one sulfur atom as the only ring hetero atom not condensed with other rings
    • C07D333/04Heterocyclic compounds containing five-membered rings having one sulfur atom as the only ring hetero atom not condensed with other rings not substituted on the ring sulfur
    • C07D333/26Heterocyclic compounds containing five-membered rings having one sulfur atom as the only ring hetero atom not condensed with other rings not substituted on the ring sulfur with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
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