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NZ738847B2 - Oxysterols and methods of use thereof - Google Patents
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NZ738847B2 - Oxysterols and methods of use thereof - Google Patents

Oxysterols and methods of use thereof Download PDF

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Publication number
NZ738847B2
NZ738847B2 NZ738847A NZ73884716A NZ738847B2 NZ 738847 B2 NZ738847 B2 NZ 738847B2 NZ 738847 A NZ738847 A NZ 738847A NZ 73884716 A NZ73884716 A NZ 73884716A NZ 738847 B2 NZ738847 B2 NZ 738847B2
Authority
NZ
New Zealand
Prior art keywords
compound
disorder
acceptable salt
pharmaceutically acceptable
iii
Prior art date
Application number
NZ738847A
Other versions
NZ738847A (en
Inventor
Botella Gabriel Martinez
Albert Jean Robichaud
Francesco G Salituro
Original Assignee
Sage Therapeutics Inc
Filing date
Publication date
Application filed by Sage Therapeutics Inc filed Critical Sage Therapeutics Inc
Priority to NZ777726A priority Critical patent/NZ777726B2/en
Priority claimed from PCT/US2016/041168 external-priority patent/WO2017007836A1/en
Publication of NZ738847A publication Critical patent/NZ738847A/en
Publication of NZ738847B2 publication Critical patent/NZ738847B2/en

Links

Classifications

    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K31/00Medicinal preparations containing organic active ingredients
    • A61K31/56Compounds containing cyclopenta[a]hydrophenanthrene ring systems; Derivatives thereof, e.g. steroids
    • A61K31/575Compounds containing cyclopenta[a]hydrophenanthrene ring systems; Derivatives thereof, e.g. steroids substituted in position 17 beta by a chain of three or more carbon atoms, e.g. cholane, cholestane, ergosterol, sitosterol
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61PSPECIFIC THERAPEUTIC ACTIVITY OF CHEMICAL COMPOUNDS OR MEDICINAL PREPARATIONS
    • A61P1/00Drugs for disorders of the alimentary tract or the digestive system
    • A61P1/04Drugs for disorders of the alimentary tract or the digestive system for ulcers, gastritis or reflux esophagitis, e.g. antacids, inhibitors of acid secretion, mucosal protectants
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61PSPECIFIC THERAPEUTIC ACTIVITY OF CHEMICAL COMPOUNDS OR MEDICINAL PREPARATIONS
    • A61P23/00Anaesthetics
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61PSPECIFIC THERAPEUTIC ACTIVITY OF CHEMICAL COMPOUNDS OR MEDICINAL PREPARATIONS
    • A61P25/00Drugs for disorders of the nervous system
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61PSPECIFIC THERAPEUTIC ACTIVITY OF CHEMICAL COMPOUNDS OR MEDICINAL PREPARATIONS
    • A61P25/00Drugs for disorders of the nervous system
    • A61P25/20Hypnotics; Sedatives
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61PSPECIFIC THERAPEUTIC ACTIVITY OF CHEMICAL COMPOUNDS OR MEDICINAL PREPARATIONS
    • A61P3/00Drugs for disorders of the metabolism
    • A61P3/08Drugs for disorders of the metabolism for glucose homeostasis
    • A61P3/10Drugs for disorders of the metabolism for glucose homeostasis for hyperglycaemia, e.g. antidiabetics
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61PSPECIFIC THERAPEUTIC ACTIVITY OF CHEMICAL COMPOUNDS OR MEDICINAL PREPARATIONS
    • A61P35/00Antineoplastic agents
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61PSPECIFIC THERAPEUTIC ACTIVITY OF CHEMICAL COMPOUNDS OR MEDICINAL PREPARATIONS
    • A61P43/00Drugs for specific purposes, not provided for in groups A61P1/00-A61P41/00
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61PSPECIFIC THERAPEUTIC ACTIVITY OF CHEMICAL COMPOUNDS OR MEDICINAL PREPARATIONS
    • A61P9/00Drugs for disorders of the cardiovascular system
    • A61P9/14Vasoprotectives; Antihaemorrhoidals; Drugs for varicose therapy; Capillary stabilisers
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07JSTEROIDS
    • C07J7/00Normal steroids containing carbon, hydrogen, halogen or oxygen substituted in position 17 beta by a chain of two carbon atoms
    • C07J7/0005Normal steroids containing carbon, hydrogen, halogen or oxygen substituted in position 17 beta by a chain of two carbon atoms not substituted in position 21
    • C07J7/001Normal steroids containing carbon, hydrogen, halogen or oxygen substituted in position 17 beta by a chain of two carbon atoms not substituted in position 21 substituted in position 20 by a keto group
    • C07J7/0015Normal steroids containing carbon, hydrogen, halogen or oxygen substituted in position 17 beta by a chain of two carbon atoms not substituted in position 21 substituted in position 20 by a keto group not substituted in position 17 alfa
    • C07J7/002Normal steroids containing carbon, hydrogen, halogen or oxygen substituted in position 17 beta by a chain of two carbon atoms not substituted in position 21 substituted in position 20 by a keto group not substituted in position 17 alfa not substituted in position 16
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07JSTEROIDS
    • C07J9/00Normal steroids containing carbon, hydrogen, halogen or oxygen substituted in position 17 beta by a chain of more than two carbon atoms, e.g. cholane, cholestane, coprostane
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07JSTEROIDS
    • C07J9/00Normal steroids containing carbon, hydrogen, halogen or oxygen substituted in position 17 beta by a chain of more than two carbon atoms, e.g. cholane, cholestane, coprostane
    • C07J9/005Normal steroids containing carbon, hydrogen, halogen or oxygen substituted in position 17 beta by a chain of more than two carbon atoms, e.g. cholane, cholestane, coprostane containing a carboxylic function directly attached or attached by a chain containing only carbon atoms to the cyclopenta[a]hydrophenanthrene skeleton

Abstract

Compounds are provided according to Formula (I): Formula (I) and pharmaceutically acceptable salts thereof, and pharmaceutical compositions thereof; wherein R1, R2, R3, R6, R7, R8, and n are as defined herein. Compounds of the present invention are contemplated useful for the prevention and treatment of a variety of conditions.

Claims (43)

What is claimed is:
1. A compound of Formula (III): (III) or a pharmaceutically acceptable salt thereof, wherein: R1 is C1-6 alkyl; each of R2 and R3 is independently hydrogen, n, C1-6 alkyl, or carbocyclyl; or R2 and R3, together with the carbon atom to which they are attached, form a 3-8 membered ring; and R6 is hydrogen; wherein each C1-6 alkyl is independently optionally substituted with 1-5 substituents independently selected from the group consisting of halogen, -CN, -NO2, -OH, - C1-6 alkoxy, and -NH2; and wherein each carbocyclyl and 3-8 ed ring is independently optionally substituted with 1-5 substituents independently selected from the group consisting of halogen, -CN, -NO2, - OH, -C1-6 alkoxy, -C1-6 alkyl, and -NH2.
2. The compound of claim 1, or a pharmaceutically acceptable salt thereof, wherein R1 is methyl, -CHF2, -CF3, -CH2OCH3, -CH2OCH2CH3, ethyl, or isopropyl.
3. The compound of claim 2, or a pharmaceutically acceptable salt thereof, wherein R1 is methyl or ethyl.
4. The nd of claim 1, or a pharmaceutically acceptable salt thereof, wherein each of R2 and R3 is ndently hydrogen, C1-6 alkyl, or carbocyclyl; or R2 and R3, together with the carbon atom to which they are ed, form a 3-8 membered ring.
5. The compound of claim 4, or a pharmaceutically acceptable salt thereof, wherein the 3-8 membered ring is a carbocyclyl ring.
6. The compound of claim 5, or a pharmaceutically acceptable salt thereof, wherein the carbocyclyl ring is cyclopropyl.
7. The nd of claim 4, or a pharmaceutically acceptable salt thereof, wherein each of R2 and R3 is independently hydrogen, C1-6 alkyl, or carbocyclyl.
8. The compound of claim 7, or a pharmaceutically acceptable salt thereof, wherein each of R2 and R3 is independently hydrogen, methyl, -CF3, ethyl, 3, propyl, isopropyl, ropyl, or butyl.
9. The compound of claim 7, or a pharmaceutically acceptable salt thereof, wherein R2 is hydrogen, methyl, -CF3, or ethyl.
10. The compound of claim 7, or a ceutically acceptable salt thereof, wherein R3 is methyl, -CF3, ethyl, -CH2CF3, propyl, isopropyl, cyclopropyl, or butyl.
11. The compound of claim 7, or a pharmaceutically acceptable salt thereof, wherein R2 is hydrogen and R3 is C1-6 alkyl.
12. The compound of claim 7, or a ceutically acceptable salt thereof, n R2 is C1- 3 is C 6 alkyl and R 1-6 alkyl.
13. The nd of claim 1, wherein the compound of Formula (III) is a compound of Formula (III-A) or Formula (III-B): (III-A) or (III-B), or a pharmaceutically acceptable salt f.
14. The compound of claim 13, wherein the compound of Formula (III-B) is a compound of Formula (III-C) or Formula (III-D): (III-C) or (III-D), or a pharmaceutically acceptable salt thereof.
15. The compound of claim 13, wherein the compound of Formula (III-A) is a compound of Formula ) or Formula (III-F): (III-E) or ), or a pharmaceutically acceptable salt thereof.
16. The compound of claim 1, wherein the compound of Formula (III) is a compound of Formula (III-A-i-a) or a (III-B-i-a): (III-A-i-a) or (III-B-i-a), or a ceutically acceptable salt thereof.
17. The compound of claim 1, wherein the compound is selected from: or .
18. The compound of claim 1, wherein the compound is a pharmaceutically acceptable salt of: or .
19. The compound of claim 1, wherein the compound is selected from: , , , , , , , , , , , , , , or
20. The compound of claim 19, wherein the compound is:
21. The compound of claim 19, n the compound is:
22. The compound of claim 19, wherein the compound is:
23. The compound of claim 1, wherein the compound is a pharmaceutically acceptable salt of: , , , , , , , , , , , , , , or
24. The compound of claim 23, n the compound is a pharmaceutically acceptable salt
25. The compound of claim 23, wherein the compound is a pharmaceutically acceptable salt
26. The compound of claim 23, wherein the compound is a pharmaceutically acceptable salt
27. A pharmaceutical composition comprising a nd of any one of claims 1-17 and 19- 22, and a pharmaceutically acceptable carrier.
28. A pharmaceutical composition comprising the pharmaceutically acceptable salt of any one of claims 1-16, 18, and 23-26, and a pharmaceutically acceptable carrier.
29. Use of a compound or pharmaceutically acceptable salt of any one of claims 1-26, or a pharmaceutical composition of claim 27 or 28, in the manufacture of a medicament for inducing sedation or anesthesia.
30. Use of a compound or pharmaceutically acceptable salt of any one of claims 1-26, or a pharmaceutical composition of claim 27 or 28, in the manufacture of a medicament for treating or preventing a disorder.
31. The use of claim 30, wherein the disorder is a intestinal (GI) disorder, a structural disorder ing the GI tract, an anal disorder, colon polyps, cancer, s, diabetes, a sterol synthesis disorder, or a metabolic er.
32. The use of claim 31, wherein the disorder is a GI disorder, n the GI disorder is inflammatory bowel disease.
33. The use of claim 31, wherein the er is cancer, diabetes, or a sterol synthesis disorder.
34. The use of claim 31, wherein the disorder is cancer.
35. The use of claim 31, wherein the disorder is a metabolic disorder.
36. Use of a compound or pharmaceutically acceptable salt of any one of claims 1-26, or a pharmaceutical composition of claim 27 or 28, in the manufacture of a medicament for treating or preventing a CNS-related condition.
37. The use of claim 36, wherein the CNS-related condition is an adjustment disorder, an anxiety disorder, a cognitive disorder, a dissociative disorder, an eating disorder, a mood disorder, a psychotic er, a sleep er, a substance-related disorder, a personality er, an autism spectrum disorder, a neurodevelopmental disorder, multiple sclerosis, a sterol synthesis disorders, pain, an encephalopathy secondary to a medical condition, seizure disorder, stroke, traumatic brain injury, a movement er, vision ment, hearing loss, or tinnitus.
38. The use of claim 37, wherein the lated condition is a sterol synthesis disorder.
39. The use of claim 37, wherein the CNS-related condition is a tic disorder, wherein the psychotic disorder is schizophrenia.
40. The use of claim 37, wherein the CNS-related condition is an autism spectrum disorder.
41. The use of claim 36, wherein the CNS-related condition is Huntington’s disease or Parkinson’s disease.
42. The use of claim 36, wherein the CNS-related condition is Alzheimer’s disease.
43. The use of claim 37, wherein the CNS-related condition is an encephalopathy ary to a medical ion, wherein the encephalopathy secondary to a medical condition is anti- NMDA receptor encephalitis. Sage Therapeutics, Inc. By the Attorneys for the Applicant SPRUSON & FERGUSON
NZ738847A 2016-07-06 Oxysterols and methods of use thereof NZ738847B2 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
NZ777726A NZ777726B2 (en) 2016-07-06 Oxysterols and methods of use thereof

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US201562189048P 2015-07-06 2015-07-06
US201662280394P 2016-01-19 2016-01-19
PCT/US2016/041168 WO2017007836A1 (en) 2015-07-06 2016-07-06 Oxysterols and methods of use thereof

Publications (2)

Publication Number Publication Date
NZ738847A NZ738847A (en) 2024-05-31
NZ738847B2 true NZ738847B2 (en) 2024-09-03

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