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NZ777726B2 - Oxysterols and methods of use thereof - Google Patents
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NZ777726B2 - Oxysterols and methods of use thereof - Google Patents

Oxysterols and methods of use thereof Download PDF

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Publication number
NZ777726B2
NZ777726B2 NZ777726A NZ77772616A NZ777726B2 NZ 777726 B2 NZ777726 B2 NZ 777726B2 NZ 777726 A NZ777726 A NZ 777726A NZ 77772616 A NZ77772616 A NZ 77772616A NZ 777726 B2 NZ777726 B2 NZ 777726B2
Authority
NZ
New Zealand
Prior art keywords
compound
disorder
acceptable salt
pharmaceutically acceptable
alkyl
Prior art date
Application number
NZ777726A
Other versions
NZ777726A (en
Inventor
Botella Gabriel Martinez
Albert Jean Robichaud
Francesco G Salituro
Original Assignee
Sage Therapeutics Inc
Filing date
Publication date
Application filed by Sage Therapeutics Inc filed Critical Sage Therapeutics Inc
Publication of NZ777726A publication Critical patent/NZ777726A/en
Publication of NZ777726B2 publication Critical patent/NZ777726B2/en

Links

Classifications

    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K31/00Medicinal preparations containing organic active ingredients
    • A61K31/56Compounds containing cyclopenta[a]hydrophenanthrene ring systems; Derivatives thereof, e.g. steroids
    • A61K31/575Compounds containing cyclopenta[a]hydrophenanthrene ring systems; Derivatives thereof, e.g. steroids substituted in position 17 beta by a chain of three or more carbon atoms, e.g. cholane, cholestane, ergosterol, sitosterol
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61PSPECIFIC THERAPEUTIC ACTIVITY OF CHEMICAL COMPOUNDS OR MEDICINAL PREPARATIONS
    • A61P1/00Drugs for disorders of the alimentary tract or the digestive system
    • A61P1/04Drugs for disorders of the alimentary tract or the digestive system for ulcers, gastritis or reflux esophagitis, e.g. antacids, inhibitors of acid secretion, mucosal protectants
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61PSPECIFIC THERAPEUTIC ACTIVITY OF CHEMICAL COMPOUNDS OR MEDICINAL PREPARATIONS
    • A61P23/00Anaesthetics
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61PSPECIFIC THERAPEUTIC ACTIVITY OF CHEMICAL COMPOUNDS OR MEDICINAL PREPARATIONS
    • A61P25/00Drugs for disorders of the nervous system
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61PSPECIFIC THERAPEUTIC ACTIVITY OF CHEMICAL COMPOUNDS OR MEDICINAL PREPARATIONS
    • A61P25/00Drugs for disorders of the nervous system
    • A61P25/20Hypnotics; Sedatives
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61PSPECIFIC THERAPEUTIC ACTIVITY OF CHEMICAL COMPOUNDS OR MEDICINAL PREPARATIONS
    • A61P3/00Drugs for disorders of the metabolism
    • A61P3/08Drugs for disorders of the metabolism for glucose homeostasis
    • A61P3/10Drugs for disorders of the metabolism for glucose homeostasis for hyperglycaemia, e.g. antidiabetics
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61PSPECIFIC THERAPEUTIC ACTIVITY OF CHEMICAL COMPOUNDS OR MEDICINAL PREPARATIONS
    • A61P35/00Antineoplastic agents
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61PSPECIFIC THERAPEUTIC ACTIVITY OF CHEMICAL COMPOUNDS OR MEDICINAL PREPARATIONS
    • A61P43/00Drugs for specific purposes, not provided for in groups A61P1/00-A61P41/00
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61PSPECIFIC THERAPEUTIC ACTIVITY OF CHEMICAL COMPOUNDS OR MEDICINAL PREPARATIONS
    • A61P9/00Drugs for disorders of the cardiovascular system
    • A61P9/14Vasoprotectives; Antihaemorrhoidals; Drugs for varicose therapy; Capillary stabilisers
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07JSTEROIDS
    • C07J7/00Normal steroids containing carbon, hydrogen, halogen or oxygen substituted in position 17 beta by a chain of two carbon atoms
    • C07J7/0005Normal steroids containing carbon, hydrogen, halogen or oxygen substituted in position 17 beta by a chain of two carbon atoms not substituted in position 21
    • C07J7/001Normal steroids containing carbon, hydrogen, halogen or oxygen substituted in position 17 beta by a chain of two carbon atoms not substituted in position 21 substituted in position 20 by a keto group
    • C07J7/0015Normal steroids containing carbon, hydrogen, halogen or oxygen substituted in position 17 beta by a chain of two carbon atoms not substituted in position 21 substituted in position 20 by a keto group not substituted in position 17 alfa
    • C07J7/002Normal steroids containing carbon, hydrogen, halogen or oxygen substituted in position 17 beta by a chain of two carbon atoms not substituted in position 21 substituted in position 20 by a keto group not substituted in position 17 alfa not substituted in position 16
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07JSTEROIDS
    • C07J9/00Normal steroids containing carbon, hydrogen, halogen or oxygen substituted in position 17 beta by a chain of more than two carbon atoms, e.g. cholane, cholestane, coprostane
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07JSTEROIDS
    • C07J9/00Normal steroids containing carbon, hydrogen, halogen or oxygen substituted in position 17 beta by a chain of more than two carbon atoms, e.g. cholane, cholestane, coprostane
    • C07J9/005Normal steroids containing carbon, hydrogen, halogen or oxygen substituted in position 17 beta by a chain of more than two carbon atoms, e.g. cholane, cholestane, coprostane containing a carboxylic function directly attached or attached by a chain containing only carbon atoms to the cyclopenta[a]hydrophenanthrene skeleton

Abstract

Compounds are provided according to Formula (I): Formula (I) and pharmaceutically acceptable salts thereof, and pharmaceutical compositions thereof; wherein R1, R2, R3, R6, R7, R8, and n are as defined herein. Compounds of the present invention are contemplated useful for the prevention and treatment of a variety of conditions.

Claims (45)

What is claimed is:
1. A compound of Formula (II-B): (II-B) or a ceutically acceptable salt thereof, wherein: R1 is C1-6 alkyl; and each of R2 and R3 is ndently hydrogen, n, C1-6 alkyl, or carbocyclyl; or R2 and R3, together with the carbon atom to which they are attached, form a 3-8 membered ring; wherein each C1-6 alkyl is independently optionally substituted with 1-5 substituents independently selected from the group consisting of halogen, -CN, -NO2, -OH, -C1-6 alkoxy, and -NH2; and wherein each carbocyclyl and 3-8 membered ring is independently optionally substituted with 1-5 substituents independently selected from the group ting of halogen, -CN, -NO2, - OH, -C1-6 alkoxy, -C1-6 alkyl, and -NH2.
2. The compound of claim 1, or a pharmaceutically acceptable salt thereof, wherein R1 is methyl, -CHF2, -CF3, -CH2OCH3, -CH2OCH2CH3, ethyl, or isopropyl.
3. The compound of claim 2, or a pharmaceutically acceptable salt thereof, wherein R1 is methyl or ethyl.
4. The compound of claim 1, or a pharmaceutically acceptable salt thereof, wherein each of R2 and R3 is independently hydrogen, C1-6 alkyl, or carbocyclyl, or wherein R2 and R3, taken er with the carbon atom to which they are attached, form a 3-8 ed ring.
5. The compound of claim 4, or a ceutically acceptable salt thereof, wherein the 3-8 membered ring is a carbocyclyl ring .
6. The compound of claim 5, or a pharmaceutically able salt thereof, wherein the carbocyclyl ring is cyclopropyl.
7. The compound of claim 4, or a pharmaceutically acceptable salt thereof, wherein each of R2 and R3 is ndently hydrogen, C1-6 alkyl, or carbocyclyl.
8. The compound of claim 7, or a pharmaceutically acceptable salt thereof, wherein each of R2 and R3 is ndently hydrogen, methyl, -CF3, ethyl, -CH2CF3, propyl, isopropyl, cyclopropyl, or butyl.
9. The compound of claim 7, or a pharmaceutically acceptable salt thereof, wherein R2 is en, methyl, -CF3, or ethyl.
10. The compound of claim 7, or a pharmaceutically acceptable salt thereof, wherein R3 is methyl, -CF3, ethyl, -CH2CF3, propyl, isopropyl, ropyl, or butyl.
11. The compound of claim 7, or a pharmaceutically acceptable salt thereof, wherein R2 is hydrogen and R3 is C1-6 alkyl.
12. The compound of claim 7, or a pharmaceutically acceptable salt thereof, wherein R2 is C1-6 alkyl and R3 is C1-6 alkyl.
13. The compound of claim 1, wherein the nd of Formula (II-B) is a compound of Formula (II-B-i) or Formula (II-B-ii): (II-B-i) (II-B- or a pharmaceutically acceptable salt thereof.
14. The compound of claim 1, wherein the compound of Formula (I) is a compound of Formula (II-B-iii): (II-B-iii), or a ceutically acceptable salt thereof.
15. The compound of claim 1, wherein the compound is:
16. The compound of claim 1, wherein the compound is a ceutically acceptable salt
17. The compound of claim 1, wherein the compound is selected from: , , , , , , , , , , , , , , , , , , , , or
18. The compound of claim 17, n the compound is selected from: , , , , , , , , , or .
19. The compound of claim 18, n the compound is:
20. The compound of claim 18, wherein the compound is:
21. The compound of claim 18, wherein the compound is:
22. The compound of claim 18, wherein the compound is:
23. The compound of claim 1, n the compound is a pharmaceutically acceptable salt , , , , , , , , , , , , , , , , , , , , or
24. The compound of claim 23, n the compound is a pharmaceutically acceptable salt , , , , , , , , , or .
25. The compound of claim 24, wherein the compound is a pharmaceutically acceptable salt
26. The compound of claim 24, wherein the nd is a pharmaceutically acceptable salt
27. The compound of claim 24, wherein the compound is a pharmaceutically acceptable salt
28. The compound of claim 24, wherein the compound is a pharmaceutically acceptable salt
29. A pharmaceutical composition comprising a compound of any one of claims 1-15 and 17- 22 and a pharmaceutically acceptable carrier.
30. A pharmaceutical composition comprising a pharmaceutically able salt of any one of claims 1-14, 16, and 23-28, and a pharmaceutically able carrier.
31. Use of a compound or pharmaceutically acceptable salt of any one of claims 1-28, or a pharmaceutical composition of claim 29 or 30, in the manufacture of a medicament for inducing sedation or anesthesia.
32. Use of a compound or ceutically acceptable salt of any one of claims 1-28, or a pharmaceutical composition of claim 29 or 30, in the manufacture of a medicament for treating or preventing a disorder.
33. The use of claim 32, wherein the disorder is a gastrointestinal (GI) disorder, a structural disorder ing the GI tract, an anal disorder, colon polyps, cancer, colitis, diabetes, a sterol synthesis disorder, or a metabolic disorder.
34. The use of claim 33, wherein the disorder is a GI disorder, wherein the GI disorder is matory bowel disease.
35. The use of claim 33, wherein the disorder is cancer, diabetes, or a sterol synthesis disorder.
36. The use of claim 33, wherein the disorder is cancer.
37. The use of claim 33, wherein the disorder is a lic disorder.
38. Use of a compound or ceutically acceptable salt of any one of claims 1-28, or a pharmaceutical composition of claim 29 or 30, in the manufacture of a medicament for treating or preventing a CNS-related condition.
39. The use of claim 38, n the CNS-related condition is an adjustment disorder, an anxiety disorder, a cognitive disorder, a dissociative disorder, an eating disorder, a mood disorder, a psychotic disorder, a sleep disorder, a nce-related disorder, a personality disorder, an autism spectrum disorder, a neurodevelopmental disorder, multiple sclerosis, a sterol synthesis disorder, pain, an encephalopathy secondary to a medical condition, a seizure disorder, stroke, traumatic brain injury, a movement disorder, vision impairment, hearing loss, and tinnitus.
40. The use of claim 39, wherein the CNS-related condition is a sterol synthesis er.
41. The use of claim 39, wherein the CNS-related ion is a psychotic disorder, n the psychotic disorder is schizophrenia.
42. The use of claim 39, wherein the lated condition is an autism spectrum disorder.
43. The use of claim 38, wherein the CNS-related condition is Huntington’s disease or Parkinson’s disease.
44. The use of claim 38, wherein the CNS-related condition is Alzheimer’s disease.
45. The use of claim 39, wherein the CNS-related condition is an encephalopathy secondary to a medical condition, wherein the encephalopathy secondary to a l condition is anti- NMDA receptor encephalitis. Sage Therapeutics, Inc. By the Attorneys for the Applicant N & FERGUSON
NZ777726A 2016-07-06 Oxysterols and methods of use thereof NZ777726B2 (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US201562189048P 2015-07-06 2015-07-06
US201662280394P 2016-01-19 2016-01-19
NZ738847A NZ738847B2 (en) 2016-07-06 Oxysterols and methods of use thereof

Publications (2)

Publication Number Publication Date
NZ777726A NZ777726A (en) 2024-05-31
NZ777726B2 true NZ777726B2 (en) 2024-09-03

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