AU714023B2 - Olefin solution polymerization - Google Patents

Olefin solution polymerization Download PDF

Info

Publication number: AU714023B2
Authority: AU; Australia
Prior art keywords: polymer; flow loop; catalyst; monomer; reactor
Prior art date: 1996-04-01
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Ceased

Application number

AU24332/97A

Other languages

English (en)

Other versions

AU2433297A (en

Inventor

Gary A. Camp

R. Bruce Combs

David P. Denton

David A Eversdyk

Pradeep Jain

Che I. Kao

Jeff H. Stultz

John R. Wilson

Larry D. Wilson

Greg A. Winter

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

Dow Chemical Co

Original Assignee

Dow Chemical Co

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1996-04-01

Filing date

1997-04-01

Publication date

1999-12-16

Family has litigation

First worldwide family litigation filed litigation Critical https://patents.darts-ip.com/?family=26686392&utm_source=google_patent&utm_medium=platform_link&utm_campaign=public_patent_search&patent=AU714023(B2) "Global patent litigation dataset” by Darts-ip is licensed under a Creative Commons Attribution 4.0 International License.

1997-04-01 Application filed by Dow Chemical Co filed Critical Dow Chemical Co

1997-10-22 Publication of AU2433297A publication Critical patent/AU2433297A/en

1999-12-16 Application granted granted Critical

1999-12-16 Publication of AU714023B2 publication Critical patent/AU714023B2/en

2017-04-01 Anticipated expiration legal-status Critical

Status Ceased legal-status Critical Current

Links

238000010528 free radical solution polymerization reaction Methods 0.000 title claims abstract description 84
150000001336 alkenes Chemical class 0.000 title abstract description 27
JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 title abstract description 26
229920000642 polymer Polymers 0.000 claims abstract description 230
239000003054 catalyst Substances 0.000 claims abstract description 196
238000000034 method Methods 0.000 claims abstract description 194
239000000178 monomer Substances 0.000 claims abstract description 174
238000006243 chemical reaction Methods 0.000 claims abstract description 126
239000002904 solvent Substances 0.000 claims abstract description 116
-1 polyethylene Polymers 0.000 claims abstract description 111
229920000573 polyethylene Polymers 0.000 claims abstract description 84
238000006116 polymerization reaction Methods 0.000 claims abstract description 77
239000004698 Polyethylene Substances 0.000 claims abstract description 20
238000005086 pumping Methods 0.000 claims abstract description 18
238000004064 recycling Methods 0.000 claims abstract description 9
230000000379 polymerizing effect Effects 0.000 claims abstract description 7
230000008569 process Effects 0.000 claims description 173
VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims description 64
239000005977 Ethylene Substances 0.000 claims description 64
238000012546 transfer Methods 0.000 claims description 38
238000002156 mixing Methods 0.000 claims description 33
230000003068 static effect Effects 0.000 claims description 32
238000009826 distribution Methods 0.000 claims description 24
239000012530 fluid Substances 0.000 claims description 21
125000004435 hydrogen atom Chemical group [H]* 0.000 claims description 16
229910052739 hydrogen Inorganic materials 0.000 claims description 12
239000001257 hydrogen Substances 0.000 claims description 12
238000004891 communication Methods 0.000 claims description 11
239000003795 chemical substances by application Substances 0.000 claims description 10
239000000126 substance Substances 0.000 claims description 10
239000002815 homogeneous catalyst Substances 0.000 claims description 9
239000002638 heterogeneous catalyst Substances 0.000 claims description 7
238000010828 elution Methods 0.000 claims description 6
238000005194 fractionation Methods 0.000 claims description 5
230000000630 rising effect Effects 0.000 claims description 5
239000007791 liquid phase Substances 0.000 claims description 4
230000026676 system process Effects 0.000 claims description 4
210000002683 foot Anatomy 0.000 claims 2
239000004568 cement Substances 0.000 claims 1
239000000463 material Substances 0.000 abstract description 31
239000000376 reactant Substances 0.000 abstract description 20
YSRFHVJGXPIDGR-UHFFFAOYSA-N dimethylsilane titanium Chemical compound [Ti].C[SiH2]C YSRFHVJGXPIDGR-UHFFFAOYSA-N 0.000 description 66
239000000203 mixture Substances 0.000 description 36
229920001971 elastomer Polymers 0.000 description 29
238000004519 manufacturing process Methods 0.000 description 29
239000000806 elastomer Substances 0.000 description 20
239000000243 solution Substances 0.000 description 20
239000010936 titanium Substances 0.000 description 20
KWKAKUADMBZCLK-UHFFFAOYSA-N 1-octene Chemical compound CCCCCCC=C KWKAKUADMBZCLK-UHFFFAOYSA-N 0.000 description 19
150000001993 dienes Chemical class 0.000 description 19
229920000098 polyolefin Polymers 0.000 description 18
239000004711 α-olefin Substances 0.000 description 18
229910052751 metal Inorganic materials 0.000 description 16
239000002184 metal Substances 0.000 description 16
229920001577 copolymer Polymers 0.000 description 15
125000000058 cyclopentadienyl group Chemical group C1(=CC=CC1)* 0.000 description 14
HQQADJVZYDDRJT-UHFFFAOYSA-N ethene;prop-1-ene Chemical group C=C.CC=C HQQADJVZYDDRJT-UHFFFAOYSA-N 0.000 description 14
150000004820 halides Chemical class 0.000 description 13
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 13
239000004615 ingredient Substances 0.000 description 12
125000001183 hydrocarbyl group Chemical group 0.000 description 11
PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 10
ZSWFCLXCOIISFI-UHFFFAOYSA-N endo-cyclopentadiene Natural products C1C=CC=C1 ZSWFCLXCOIISFI-UHFFFAOYSA-N 0.000 description 10
238000002844 melting Methods 0.000 description 10
230000008018 melting Effects 0.000 description 10
239000012968 metallocene catalyst Substances 0.000 description 10
PMJHHCWVYXUKFD-SNAWJCMRSA-N (E)-1,3-pentadiene Chemical compound C\C=C\C=C PMJHHCWVYXUKFD-SNAWJCMRSA-N 0.000 description 9
125000000129 anionic group Chemical group 0.000 description 9
230000008901 benefit Effects 0.000 description 9
229910052809 inorganic oxide Inorganic materials 0.000 description 9
PMJHHCWVYXUKFD-UHFFFAOYSA-N piperylene Natural products CC=CC=C PMJHHCWVYXUKFD-UHFFFAOYSA-N 0.000 description 9
239000005060 rubber Substances 0.000 description 9
150000003623 transition metal compounds Chemical class 0.000 description 9
229920001866 very low density polyethylene Polymers 0.000 description 9
KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 8
RRHGJUQNOFWUDK-UHFFFAOYSA-N Isoprene Chemical compound CC(=C)C=C RRHGJUQNOFWUDK-UHFFFAOYSA-N 0.000 description 8
239000004708 Very-low-density polyethylene Substances 0.000 description 8
125000004432 carbon atom Chemical group C* 0.000 description 8
230000000052 comparative effect Effects 0.000 description 8
150000001875 compounds Chemical class 0.000 description 8
238000001816 cooling Methods 0.000 description 8
239000000835 fiber Substances 0.000 description 8
229920000092 linear low density polyethylene Polymers 0.000 description 8
239000011777 magnesium Substances 0.000 description 8
229910052749 magnesium Inorganic materials 0.000 description 8
230000003647 oxidation Effects 0.000 description 8
238000007254 oxidation reaction Methods 0.000 description 8
229920002943 EPDM rubber Polymers 0.000 description 7
125000000217 alkyl group Chemical group 0.000 description 7
125000003710 aryl alkyl group Chemical group 0.000 description 7
125000003118 aryl group Chemical group 0.000 description 7
238000001125 extrusion Methods 0.000 description 7
238000005227 gel permeation chromatography Methods 0.000 description 7
238000002347 injection Methods 0.000 description 7
239000007924 injection Substances 0.000 description 7
239000003446 ligand Substances 0.000 description 7
239000004707 linear low-density polyethylene Substances 0.000 description 7
239000012071 phase Substances 0.000 description 7
XWJBRBSPAODJER-UHFFFAOYSA-N 1,7-octadiene Chemical compound C=CCCCCC=C XWJBRBSPAODJER-UHFFFAOYSA-N 0.000 description 6
LIKMAJRDDDTEIG-UHFFFAOYSA-N 1-hexene Chemical compound CCCCC=C LIKMAJRDDDTEIG-UHFFFAOYSA-N 0.000 description 6
YBYIRNPNPLQARY-UHFFFAOYSA-N 1H-indene Natural products C1=CC=C2CC=CC2=C1 YBYIRNPNPLQARY-UHFFFAOYSA-N 0.000 description 6
SDJHPPZKZZWAKF-UHFFFAOYSA-N 2,3-dimethylbuta-1,3-diene Chemical compound CC(=C)C(C)=C SDJHPPZKZZWAKF-UHFFFAOYSA-N 0.000 description 6
FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 6
VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 6
QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical group [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 description 6
125000004122 cyclic group Chemical group 0.000 description 6
229910052736 halogen Inorganic materials 0.000 description 6
125000005843 halogen group Chemical group 0.000 description 6
125000003454 indenyl group Chemical group C1(C=CC2=CC=CC=C12)* 0.000 description 6
230000007935 neutral effect Effects 0.000 description 6
229910052723 transition metal Inorganic materials 0.000 description 6
150000003624 transition metals Chemical class 0.000 description 6
229920001862 ultra low molecular weight polyethylene Polymers 0.000 description 6
229910052726 zirconium Inorganic materials 0.000 description 6
229910052782 aluminium Inorganic materials 0.000 description 5
125000004429 atom Chemical group 0.000 description 5
229910052799 carbon Chemical group 0.000 description 5
230000000875 corresponding effect Effects 0.000 description 5
125000003983 fluorenyl group Chemical group C1(=CC=CC=2C3=CC=CC=C3CC12)* 0.000 description 5
239000007789 gas Substances 0.000 description 5
239000004700 high-density polyethylene Substances 0.000 description 5
TVMXDCGIABBOFY-UHFFFAOYSA-N octane Chemical compound CCCCCCCC TVMXDCGIABBOFY-UHFFFAOYSA-N 0.000 description 5
150000002901 organomagnesium compounds Chemical class 0.000 description 5
150000002902 organometallic compounds Chemical class 0.000 description 5
125000001181 organosilyl group Chemical group [SiH3]* 0.000 description 5
125000002097 pentamethylcyclopentadienyl group Chemical group 0.000 description 5
238000002360 preparation method Methods 0.000 description 5
239000011541 reaction mixture Substances 0.000 description 5
239000011949 solid catalyst Substances 0.000 description 5
229910052719 titanium Inorganic materials 0.000 description 5
OJOWICOBYCXEKR-KRXBUXKQSA-N (5e)-5-ethylidenebicyclo[2.2.1]hept-2-ene Chemical compound C1C2C(=C/C)/CC1C=C2 OJOWICOBYCXEKR-KRXBUXKQSA-N 0.000 description 4
VXNZUUAINFGPBY-UHFFFAOYSA-N 1-Butene Chemical compound CCC=C VXNZUUAINFGPBY-UHFFFAOYSA-N 0.000 description 4
AFFLGGQVNFXPEV-UHFFFAOYSA-N 1-decene Chemical compound CCCCCCCCC=C AFFLGGQVNFXPEV-UHFFFAOYSA-N 0.000 description 4
IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 4
VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 4
UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 4
RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical group [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 4
229910007926 ZrCl Inorganic materials 0.000 description 4
125000001931 aliphatic group Chemical group 0.000 description 4
PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 4
230000015572 biosynthetic process Effects 0.000 description 4
230000001276 controlling effect Effects 0.000 description 4
125000000753 cycloalkyl group Chemical group 0.000 description 4
125000000118 dimethyl group Chemical group [H]C([H])([H])* 0.000 description 4
230000009977 dual effect Effects 0.000 description 4
HEAMQYHBJQWOSS-UHFFFAOYSA-N ethene;oct-1-ene Chemical compound C=C.CCCCCCC=C HEAMQYHBJQWOSS-UHFFFAOYSA-N 0.000 description 4
229910052735 hafnium Chemical group 0.000 description 4
VBJZVLUMGGDVMO-UHFFFAOYSA-N hafnium atom Chemical group [Hf] VBJZVLUMGGDVMO-UHFFFAOYSA-N 0.000 description 4
229920001903 high density polyethylene Polymers 0.000 description 4
229920001519 homopolymer Polymers 0.000 description 4
229910000041 hydrogen chloride Inorganic materials 0.000 description 4
IXCSERBJSXMMFS-UHFFFAOYSA-N hydrogen chloride Substances Cl.Cl IXCSERBJSXMMFS-UHFFFAOYSA-N 0.000 description 4
239000007788 liquid Substances 0.000 description 4
125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 4
230000000737 periodic effect Effects 0.000 description 4
229920002959 polymer blend Polymers 0.000 description 4
150000003254 radicals Chemical class 0.000 description 4
125000003698 tetramethyl group Chemical group [H]C([H])([H])* 0.000 description 4
JFLKFZNIIQFQBS-FNCQTZNRSA-N trans,trans-1,4-Diphenyl-1,3-butadiene Chemical compound C=1C=CC=CC=1\C=C\C=C\C1=CC=CC=C1 JFLKFZNIIQFQBS-FNCQTZNRSA-N 0.000 description 4
238000011144 upstream manufacturing Methods 0.000 description 4
229910052720 vanadium Inorganic materials 0.000 description 4
LEONUFNNVUYDNQ-UHFFFAOYSA-N vanadium atom Chemical compound [V] LEONUFNNVUYDNQ-UHFFFAOYSA-N 0.000 description 4
APPOKADJQUIAHP-GGWOSOGESA-N (2e,4e)-hexa-2,4-diene Chemical compound C\C=C\C=C\C APPOKADJQUIAHP-GGWOSOGESA-N 0.000 description 3
WSSSPWUEQFSQQG-UHFFFAOYSA-N 4-methyl-1-pentene Chemical compound CC(C)CC=C WSSSPWUEQFSQQG-UHFFFAOYSA-N 0.000 description 3
WAEGMAZJVUBLBI-UHFFFAOYSA-N C=[Ti](C1(C(=C(C(=C1)C)C)C)C)C1(C(=C(C(=C1)C)C)C)C Chemical compound C=[Ti](C1(C(=C(C(=C1)C)C)C)C)C1(C(=C(C(=C1)C)C)C)C WAEGMAZJVUBLBI-UHFFFAOYSA-N 0.000 description 3
OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical group [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 3
239000004215 Carbon black (E152) Substances 0.000 description 3
229920000089 Cyclic olefin copolymer Polymers 0.000 description 3
238000005481 NMR spectroscopy Methods 0.000 description 3
239000004793 Polystyrene Substances 0.000 description 3
YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
230000009471 action Effects 0.000 description 3
239000012967 coordination catalyst Substances 0.000 description 3
238000005516 engineering process Methods 0.000 description 3
230000004927 fusion Effects 0.000 description 3
125000003800 germyl group Chemical group [H][Ge]([H])([H])[*] 0.000 description 3
230000005484 gravity Effects 0.000 description 3
229930195733 hydrocarbon Natural products 0.000 description 3
150000002430 hydrocarbons Chemical class 0.000 description 3
239000000155 melt Substances 0.000 description 3
238000012986 modification Methods 0.000 description 3
230000004048 modification Effects 0.000 description 3
VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 3
RGSFGYAAUTVSQA-UHFFFAOYSA-N pentamethylene Natural products C1CCCC1 RGSFGYAAUTVSQA-UHFFFAOYSA-N 0.000 description 3
229920002223 polystyrene Polymers 0.000 description 3
238000012545 processing Methods 0.000 description 3
QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 3
229920005989 resin Polymers 0.000 description 3
239000011347 resin Substances 0.000 description 3
239000000377 silicon dioxide Substances 0.000 description 3
239000007787 solid Substances 0.000 description 3
229920006132 styrene block copolymer Polymers 0.000 description 3
NBRKLOOSMBRFMH-UHFFFAOYSA-N tert-butyl chloride Chemical compound CC(C)(C)Cl NBRKLOOSMBRFMH-UHFFFAOYSA-N 0.000 description 3
OJOWICOBYCXEKR-APPZFPTMSA-N (1S,4R)-5-ethylidenebicyclo[2.2.1]hept-2-ene Chemical compound CC=C1C[C@@H]2C[C@@H]1C=C2 OJOWICOBYCXEKR-APPZFPTMSA-N 0.000 description 2
BOGRNZQRTNVZCZ-AATRIKPKSA-N (3e)-3-methylpenta-1,3-diene Chemical compound C\C=C(/C)C=C BOGRNZQRTNVZCZ-AATRIKPKSA-N 0.000 description 2
PRBHEGAFLDMLAL-GQCTYLIASA-N (4e)-hexa-1,4-diene Chemical compound C\C=C\CC=C PRBHEGAFLDMLAL-GQCTYLIASA-N 0.000 description 2
QWUWMCYKGHVNAV-UHFFFAOYSA-N 1,2-dihydrostilbene Chemical group C=1C=CC=CC=1CCC1=CC=CC=C1 QWUWMCYKGHVNAV-UHFFFAOYSA-N 0.000 description 2
BOGRNZQRTNVZCZ-UHFFFAOYSA-N 1,2-dimethyl-butadiene Natural products CC=C(C)C=C BOGRNZQRTNVZCZ-UHFFFAOYSA-N 0.000 description 2
ZGEGCLOFRBLKSE-UHFFFAOYSA-N 1-Heptene Chemical compound CCCCCC=C ZGEGCLOFRBLKSE-UHFFFAOYSA-N 0.000 description 2
CRSBERNSMYQZNG-UHFFFAOYSA-N 1-dodecene Chemical compound CCCCCCCCCCC=C CRSBERNSMYQZNG-UHFFFAOYSA-N 0.000 description 2
GQEZCXVZFLOKMC-UHFFFAOYSA-N 1-hexadecene Chemical compound CCCCCCCCCCCCCCC=C GQEZCXVZFLOKMC-UHFFFAOYSA-N 0.000 description 2
HFDVRLIODXPAHB-UHFFFAOYSA-N 1-tetradecene Chemical compound CCCCCCCCCCCCC=C HFDVRLIODXPAHB-UHFFFAOYSA-N 0.000 description 2
238000001644 13C nuclear magnetic resonance spectroscopy Methods 0.000 description 2
125000003903 2-propenyl group Chemical group [H]C([*])([H])C([H])=C([H])[H] 0.000 description 2
XDTMQSROBMDMFD-UHFFFAOYSA-N Cyclohexane Chemical compound C1CCCCC1 XDTMQSROBMDMFD-UHFFFAOYSA-N 0.000 description 2
YNQLUTRBYVCPMQ-UHFFFAOYSA-N Ethylbenzene Chemical compound CCC1=CC=CC=C1 YNQLUTRBYVCPMQ-UHFFFAOYSA-N 0.000 description 2
LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 2
CPELXLSAUQHCOX-UHFFFAOYSA-N Hydrogen bromide Chemical compound Br CPELXLSAUQHCOX-UHFFFAOYSA-N 0.000 description 2
229920010126 Linear Low Density Polyethylene (LLDPE) Polymers 0.000 description 2
CPLXHLVBOLITMK-UHFFFAOYSA-N Magnesium oxide Chemical compound [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 description 2
IMNFDUFMRHMDMM-UHFFFAOYSA-N N-Heptane Chemical compound CCCCCCC IMNFDUFMRHMDMM-UHFFFAOYSA-N 0.000 description 2
239000004743 Polypropylene Substances 0.000 description 2
XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical group [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 2
GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 2
MCMNRKCIXSYSNV-UHFFFAOYSA-N Zirconium dioxide Chemical compound O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 description 2
229910007928 ZrCl2 Inorganic materials 0.000 description 2
230000002411 adverse Effects 0.000 description 2
VSCWAEJMTAWNJL-UHFFFAOYSA-K aluminium trichloride Chemical compound Cl[Al](Cl)Cl VSCWAEJMTAWNJL-UHFFFAOYSA-K 0.000 description 2
150000004945 aromatic hydrocarbons Chemical class 0.000 description 2
KCXMKQUNVWSEMD-UHFFFAOYSA-N benzyl chloride Chemical compound ClCC1=CC=CC=C1 KCXMKQUNVWSEMD-UHFFFAOYSA-N 0.000 description 2
229940073608 benzyl chloride Drugs 0.000 description 2
125000001797 benzyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])* 0.000 description 2
238000006555 catalytic reaction Methods 0.000 description 2
238000000576 coating method Methods 0.000 description 2
HGCIXCUEYOPUTN-UHFFFAOYSA-N cyclohexene Chemical compound C1CCC=CC1 HGCIXCUEYOPUTN-UHFFFAOYSA-N 0.000 description 2
LPIQUOYDBNQMRZ-UHFFFAOYSA-N cyclopentene Chemical compound C1CC=CC1 LPIQUOYDBNQMRZ-UHFFFAOYSA-N 0.000 description 2
NLDGJRWPPOSWLC-UHFFFAOYSA-N deca-1,9-diene Chemical compound C=CCCCCCCC=C NLDGJRWPPOSWLC-UHFFFAOYSA-N 0.000 description 2
238000013461 design Methods 0.000 description 2
238000011143 downstream manufacturing Methods 0.000 description 2
UAIZDWNSWGTKFZ-UHFFFAOYSA-L ethylaluminum(2+);dichloride Chemical compound CC[Al](Cl)Cl UAIZDWNSWGTKFZ-UHFFFAOYSA-L 0.000 description 2
229920006226 ethylene-acrylic acid Polymers 0.000 description 2
238000011156 evaluation Methods 0.000 description 2
238000002474 experimental method Methods 0.000 description 2
150000002367 halogens Chemical class 0.000 description 2
AWJFCAXSGQLCKK-UHFFFAOYSA-N icosa-1,19-diene Chemical compound C=CCCCCCCCCCCCCCCCCC=C AWJFCAXSGQLCKK-UHFFFAOYSA-N 0.000 description 2
238000010348 incorporation Methods 0.000 description 2
238000001746 injection moulding Methods 0.000 description 2
QWTDNUCVQCZILF-UHFFFAOYSA-N isopentane Chemical compound CCC(C)C QWTDNUCVQCZILF-UHFFFAOYSA-N 0.000 description 2
229910052747 lanthanoid Inorganic materials 0.000 description 2
150000007527 lewis bases Chemical class 0.000 description 2
229920001684 low density polyethylene Polymers 0.000 description 2
239000004702 low-density polyethylene Substances 0.000 description 2
150000002739 metals Chemical class 0.000 description 2
CPOFMOWDMVWCLF-UHFFFAOYSA-N methyl(oxo)alumane Chemical compound C[Al]=O CPOFMOWDMVWCLF-UHFFFAOYSA-N 0.000 description 2
230000000051 modifying effect Effects 0.000 description 2
229910052757 nitrogen Inorganic materials 0.000 description 2
SJYNFBVQFBRSIB-UHFFFAOYSA-N norbornadiene Chemical compound C1=CC2C=CC1C2 SJYNFBVQFBRSIB-UHFFFAOYSA-N 0.000 description 2
JFNLZVQOOSMTJK-KNVOCYPGSA-N norbornene Chemical compound C1[C@@H]2CC[C@H]1C=C2 JFNLZVQOOSMTJK-KNVOCYPGSA-N 0.000 description 2
CCCMONHAUSKTEQ-UHFFFAOYSA-N octadec-1-ene Chemical compound CCCCCCCCCCCCCCCCC=C CCCMONHAUSKTEQ-UHFFFAOYSA-N 0.000 description 2
125000002734 organomagnesium group Chemical group 0.000 description 2
239000002245 particle Substances 0.000 description 2
YWAKXRMUMFPDSH-UHFFFAOYSA-N pentene Chemical compound CCCC=C YWAKXRMUMFPDSH-UHFFFAOYSA-N 0.000 description 2
229920001155 polypropylene Polymers 0.000 description 2
239000011148 porous material Substances 0.000 description 2
125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 2
230000002829 reductive effect Effects 0.000 description 2
238000000518 rheometry Methods 0.000 description 2
238000012163 sequencing technique Methods 0.000 description 2
239000002002 slurry Substances 0.000 description 2
238000003756 stirring Methods 0.000 description 2
229920003048 styrene butadiene rubber Polymers 0.000 description 2
125000001424 substituent group Chemical group 0.000 description 2
230000003746 surface roughness Effects 0.000 description 2
229920001897 terpolymer Polymers 0.000 description 2
VXUYXOFXAQZZMF-UHFFFAOYSA-N titanium(IV) isopropoxide Chemical compound CC(C)O[Ti](OC(C)C)(OC(C)C)OC(C)C VXUYXOFXAQZZMF-UHFFFAOYSA-N 0.000 description 2
QQIMUPFCBBIKKN-SOFGYWHQSA-N (11E)-tetradeca-1,11-diene Chemical compound CC\C=C\CCCCCCCCC=C QQIMUPFCBBIKKN-SOFGYWHQSA-N 0.000 description 1
RRKODOZNUZCUBN-CCAGOZQPSA-N (1z,3z)-cycloocta-1,3-diene Chemical compound C1CC\C=C/C=C\C1 RRKODOZNUZCUBN-CCAGOZQPSA-N 0.000 description 1
OGQVROWWFUXRST-FNORWQNLSA-N (3e)-hepta-1,3-diene Chemical compound CCC\C=C\C=C OGQVROWWFUXRST-FNORWQNLSA-N 0.000 description 1
TVEFFNLPYIEDLS-VQHVLOKHSA-N (4e)-deca-1,4,9-triene Chemical compound C=CCCC\C=C\CC=C TVEFFNLPYIEDLS-VQHVLOKHSA-N 0.000 description 1
RJUCIROUEDJQIB-GQCTYLIASA-N (6e)-octa-1,6-diene Chemical compound C\C=C\CCCC=C RJUCIROUEDJQIB-GQCTYLIASA-N 0.000 description 1
MHCVCKDNQYMGEX-UHFFFAOYSA-N 1,1'-biphenyl;phenoxybenzene Chemical compound C1=CC=CC=C1C1=CC=CC=C1.C=1C=CC=CC=1OC1=CC=CC=C1 MHCVCKDNQYMGEX-UHFFFAOYSA-N 0.000 description 1
JVTMVUFBBYUSKS-UHFFFAOYSA-N 1,4-bis(prop-2-enyl)benzene Chemical compound C=CCC1=CC=C(CC=C)C=C1 JVTMVUFBBYUSKS-UHFFFAOYSA-N 0.000 description 1
PPWUTZVGSFPZOC-UHFFFAOYSA-N 1-methyl-2,3,3a,4-tetrahydro-1h-indene Chemical compound C1C=CC=C2C(C)CCC21 PPWUTZVGSFPZOC-UHFFFAOYSA-N 0.000 description 1
125000004134 1-norbornyl group Chemical group [H]C1([H])C([H])([H])C2(*)C([H])([H])C([H])([H])C1([H])C2([H])[H] 0.000 description 1
HECLRDQVFMWTQS-RGOKHQFPSA-N 1755-01-7 Chemical compound C1[C@H]2[C@@H]3CC=C[C@@H]3[C@@H]1C=C2 HECLRDQVFMWTQS-RGOKHQFPSA-N 0.000 description 1
CMSUNVGIWAFNBG-UHFFFAOYSA-N 2,4-dimethylpenta-1,3-diene Chemical compound CC(C)=CC(C)=C CMSUNVGIWAFNBG-UHFFFAOYSA-N 0.000 description 1
LAGGTOBQMQHXON-UHFFFAOYSA-N 2,6-octadiene Chemical compound CC=CCCC=CC LAGGTOBQMQHXON-UHFFFAOYSA-N 0.000 description 1
JOUWCKCVTDSMHF-UHFFFAOYSA-N 2-bromo-2-methylbutane Chemical compound CCC(C)(C)Br JOUWCKCVTDSMHF-UHFFFAOYSA-N 0.000 description 1
BSPCSKHALVHRSR-UHFFFAOYSA-N 2-chlorobutane Chemical compound CCC(C)Cl BSPCSKHALVHRSR-UHFFFAOYSA-N 0.000 description 1
CMAOLVNGLTWICC-UHFFFAOYSA-N 2-fluoro-5-methylbenzonitrile Chemical compound CC1=CC=C(F)C(C#N)=C1 CMAOLVNGLTWICC-UHFFFAOYSA-N 0.000 description 1
JFLOKYMVJXMYFI-UHFFFAOYSA-N 3-ethylpenta-1,3-diene Chemical compound CCC(=CC)C=C JFLOKYMVJXMYFI-UHFFFAOYSA-N 0.000 description 1
BBDKZWKEPDTENS-UHFFFAOYSA-N 4-Vinylcyclohexene Chemical compound C=CC1CCC=CC1 BBDKZWKEPDTENS-UHFFFAOYSA-N 0.000 description 1
QFUWXESVJSCLMD-UHFFFAOYSA-N 5-(2-cyclopenta-2,4-dien-1-ylethyl)cyclopenta-1,3-diene Chemical compound C1=CC=CC1CCC1C=CC=C1 QFUWXESVJSCLMD-UHFFFAOYSA-N 0.000 description 1
INYHZQLKOKTDAI-UHFFFAOYSA-N 5-ethenylbicyclo[2.2.1]hept-2-ene Chemical compound C1C2C(C=C)CC1C=C2 INYHZQLKOKTDAI-UHFFFAOYSA-N 0.000 description 1
WTQBISBWKRKLIJ-UHFFFAOYSA-N 5-methylidenebicyclo[2.2.1]hept-2-ene Chemical compound C1C2C(=C)CC1C=C2 WTQBISBWKRKLIJ-UHFFFAOYSA-N 0.000 description 1
OOVQLEHBRDIXDZ-UHFFFAOYSA-N 7-ethenylbicyclo[4.2.0]octa-1,3,5-triene Chemical class C1=CC=C2C(C=C)CC2=C1 OOVQLEHBRDIXDZ-UHFFFAOYSA-N 0.000 description 1
UCKITPBQPGXDHV-UHFFFAOYSA-N 7-methylocta-1,6-diene Chemical compound CC(C)=CCCCC=C UCKITPBQPGXDHV-UHFFFAOYSA-N 0.000 description 1
OSDWBNJEKMUWAV-UHFFFAOYSA-N Allyl chloride Chemical compound ClCC=C OSDWBNJEKMUWAV-UHFFFAOYSA-N 0.000 description 1
ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical group [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 description 1
CPKJVLOYWUSZRN-UHFFFAOYSA-N C=[Ti](C1(C=CC=C1)CCCC)C1(C=CC=C1)CCCC Chemical compound C=[Ti](C1(C=CC=C1)CCCC)C1(C=CC=C1)CCCC CPKJVLOYWUSZRN-UHFFFAOYSA-N 0.000 description 1
DQUAINJPECZAKA-UHFFFAOYSA-L CCCCC1=CC(C=C1)[Zr](Cl)(Cl)(C1C=CC(CCCC)=C1)[SiH](C)C Chemical compound CCCCC1=CC(C=C1)[Zr](Cl)(Cl)(C1C=CC(CCCC)=C1)[SiH](C)C DQUAINJPECZAKA-UHFFFAOYSA-L 0.000 description 1
MDCNUULPPQFEAB-UHFFFAOYSA-N CCCC[Mg]C(C)C Chemical compound CCCC[Mg]C(C)C MDCNUULPPQFEAB-UHFFFAOYSA-N 0.000 description 1
MVECFARLYQAUNR-UHFFFAOYSA-N CCCC[Mg]CC Chemical compound CCCC[Mg]CC MVECFARLYQAUNR-UHFFFAOYSA-N 0.000 description 1
YYOHSEOBMBTBOR-UHFFFAOYSA-L C[SiH](C)[Zr](Cl)(Cl)(C1C=CC=C1C(C)(C)C)C1C=CC=C1C(C)(C)C Chemical compound C[SiH](C)[Zr](Cl)(Cl)(C1C=CC=C1C(C)(C)C)C1C=CC=C1C(C)(C)C YYOHSEOBMBTBOR-UHFFFAOYSA-L 0.000 description 1
229920000742 Cotton Polymers 0.000 description 1
NHTMVDHEPJAVLT-UHFFFAOYSA-N Isooctane Chemical compound CC(C)CC(C)(C)C NHTMVDHEPJAVLT-UHFFFAOYSA-N 0.000 description 1
239000002879 Lewis base Substances 0.000 description 1
OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 1
KVOZXXSUSRZIKD-UHFFFAOYSA-N Prop-2-enylcyclohexane Chemical compound C=CCC1CCCCC1 KVOZXXSUSRZIKD-UHFFFAOYSA-N 0.000 description 1
NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical group [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 1
229910052770 Uranium Inorganic materials 0.000 description 1
101100497923 Viola odorata Voc1 gene Proteins 0.000 description 1
239000011954 Ziegler–Natta catalyst Substances 0.000 description 1
229910007930 ZrCl3 Inorganic materials 0.000 description 1
ZDVDCDLBOLSVGM-UHFFFAOYSA-N [chloro(phenyl)methyl]benzene Chemical compound C=1C=CC=CC=1C(Cl)C1=CC=CC=C1 ZDVDCDLBOLSVGM-UHFFFAOYSA-N 0.000 description 1
125000003342 alkenyl group Chemical group 0.000 description 1
150000004703 alkoxides Chemical group 0.000 description 1
150000001350 alkyl halides Chemical class 0.000 description 1
150000004791 alkyl magnesium halides Chemical class 0.000 description 1
QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
239000004305 biphenyl Substances 0.000 description 1
229920001400 block copolymer Polymers 0.000 description 1
238000000071 blow moulding Methods 0.000 description 1
229910052796 boron Inorganic materials 0.000 description 1
150000001639 boron compounds Chemical class 0.000 description 1
YHWCPXVTRSHPNY-UHFFFAOYSA-N butan-1-olate;titanium(4+) Chemical compound [Ti+4].CCCC[O-].CCCC[O-].CCCC[O-].CCCC[O-] YHWCPXVTRSHPNY-UHFFFAOYSA-N 0.000 description 1
230000008859 change Effects 0.000 description 1
238000012512 characterization method Methods 0.000 description 1
ZHXZNKNQUHUIGN-UHFFFAOYSA-N chloro hypochlorite;vanadium Chemical compound [V].ClOCl ZHXZNKNQUHUIGN-UHFFFAOYSA-N 0.000 description 1
239000011248 coating agent Substances 0.000 description 1
239000002131 composite material Substances 0.000 description 1
238000007796 conventional method Methods 0.000 description 1
239000002826 coolant Substances 0.000 description 1
230000002596 correlated effect Effects 0.000 description 1
125000004093 cyano group Chemical group *C#N 0.000 description 1
150000001925 cycloalkenes Chemical class 0.000 description 1
UVJHQYIOXKWHFD-UHFFFAOYSA-N cyclohexa-1,4-diene Chemical compound C1C=CCC=C1 UVJHQYIOXKWHFD-UHFFFAOYSA-N 0.000 description 1
125000003678 cyclohexadienyl group Chemical group C1(=CC=CCC1)* 0.000 description 1
URYYVOIYTNXXBN-UPHRSURJSA-N cyclooctene Chemical compound C1CCC\C=C/CC1 URYYVOIYTNXXBN-UPHRSURJSA-N 0.000 description 1
239000004913 cyclooctene Substances 0.000 description 1
230000007547 defect Effects 0.000 description 1
239000008367 deionised water Substances 0.000 description 1
229910021641 deionized water Inorganic materials 0.000 description 1
238000001514 detection method Methods 0.000 description 1
238000011161 development Methods 0.000 description 1
JJSGABFIILQOEY-UHFFFAOYSA-M diethylalumanylium;bromide Chemical compound CC[Al](Br)CC JJSGABFIILQOEY-UHFFFAOYSA-M 0.000 description 1
YNLAOSYQHBDIKW-UHFFFAOYSA-M diethylaluminium chloride Chemical compound CC[Al](Cl)CC YNLAOSYQHBDIKW-UHFFFAOYSA-M 0.000 description 1
238000000113 differential scanning calorimetry Methods 0.000 description 1
239000003085 diluting agent Substances 0.000 description 1
239000000539 dimer Substances 0.000 description 1
AFABGHUZZDYHJO-UHFFFAOYSA-N dimethyl butane Natural products CCCC(C)C AFABGHUZZDYHJO-UHFFFAOYSA-N 0.000 description 1
JVSWJIKNEAIKJW-UHFFFAOYSA-N dimethyl-hexane Natural products CCCCCC(C)C JVSWJIKNEAIKJW-UHFFFAOYSA-N 0.000 description 1
WODAGJKOTBCQIL-UHFFFAOYSA-N dimethylsilane titanium(2+) Chemical compound [Ti+2].C[SiH2]C WODAGJKOTBCQIL-UHFFFAOYSA-N 0.000 description 1
238000007599 discharging Methods 0.000 description 1
229940069096 dodecene Drugs 0.000 description 1
238000005265 energy consumption Methods 0.000 description 1
239000003623 enhancer Substances 0.000 description 1
LDLDYFCCDKENPD-UHFFFAOYSA-N ethenylcyclohexane Chemical compound C=CC1CCCCC1 LDLDYFCCDKENPD-UHFFFAOYSA-N 0.000 description 1
125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
239000005038 ethylene vinyl acetate Substances 0.000 description 1
239000004744 fabric Substances 0.000 description 1
125000000524 functional group Chemical group 0.000 description 1
229910052732 germanium Inorganic materials 0.000 description 1
GNPVGFCGXDBREM-UHFFFAOYSA-N germanium atom Chemical group [Ge] GNPVGFCGXDBREM-UHFFFAOYSA-N 0.000 description 1
239000011521 glass Substances 0.000 description 1
230000009477 glass transition Effects 0.000 description 1
GEAWFZNTIFJMHR-UHFFFAOYSA-N hepta-1,6-diene Chemical compound C=CCCCC=C GEAWFZNTIFJMHR-UHFFFAOYSA-N 0.000 description 1
DMEGYFMYUHOHGS-UHFFFAOYSA-N heptamethylene Natural products C1CCCCCC1 DMEGYFMYUHOHGS-UHFFFAOYSA-N 0.000 description 1
150000004678 hydrides Chemical class 0.000 description 1
229910000042 hydrogen bromide Inorganic materials 0.000 description 1
230000003301 hydrolyzing effect Effects 0.000 description 1
125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 1
238000011065 in-situ storage Methods 0.000 description 1
229910052738 indium Inorganic materials 0.000 description 1
APFVFJFRJDLVQX-UHFFFAOYSA-N indium atom Chemical compound [In] APFVFJFRJDLVQX-UHFFFAOYSA-N 0.000 description 1
230000010354 integration Effects 0.000 description 1
150000002500 ions Chemical class 0.000 description 1
150000002602 lanthanoids Chemical class 0.000 description 1
230000000670 limiting effect Effects 0.000 description 1
229920004889 linear high-density polyethylene Polymers 0.000 description 1
239000006193 liquid solution Substances 0.000 description 1
239000000395 magnesium oxide Substances 0.000 description 1
WRYKIHMRDIOPSI-UHFFFAOYSA-N magnesium;benzene Chemical compound [Mg+2].C1=CC=[C-]C=C1.C1=CC=[C-]C=C1 WRYKIHMRDIOPSI-UHFFFAOYSA-N 0.000 description 1
WCFJMDWWJOCLSJ-UHFFFAOYSA-N magnesium;methanidylbenzene Chemical compound [Mg+2].[CH2-]C1=CC=CC=C1.[CH2-]C1=CC=CC=C1 WCFJMDWWJOCLSJ-UHFFFAOYSA-N 0.000 description 1
KMYFNYFIPIGQQZ-UHFFFAOYSA-N magnesium;octane Chemical compound [Mg+2].CCCCCCC[CH2-].CCCCCCC[CH2-] KMYFNYFIPIGQQZ-UHFFFAOYSA-N 0.000 description 1
DQZLQYHGCKLKGU-UHFFFAOYSA-N magnesium;propane Chemical compound [Mg+2].C[CH-]C.C[CH-]C DQZLQYHGCKLKGU-UHFFFAOYSA-N 0.000 description 1
229910052748 manganese Inorganic materials 0.000 description 1
229910001507 metal halide Inorganic materials 0.000 description 1
150000005309 metal halides Chemical class 0.000 description 1
229910044991 metal oxide Inorganic materials 0.000 description 1
150000004706 metal oxides Chemical class 0.000 description 1
239000011259 mixed solution Substances 0.000 description 1
125000001971 neopentyl group Chemical group [H]C([*])([H])C(C([H])([H])[H])(C([H])([H])[H])C([H])([H])[H] 0.000 description 1
ZCYXXKJEDCHMGH-UHFFFAOYSA-N nonane Chemical compound CCCC[CH]CCCC ZCYXXKJEDCHMGH-UHFFFAOYSA-N 0.000 description 1
239000004745 nonwoven fabric Substances 0.000 description 1
BKIMMITUMNQMOS-UHFFFAOYSA-N normal nonane Natural products CCCCCCCCC BKIMMITUMNQMOS-UHFFFAOYSA-N 0.000 description 1
125000002524 organometallic group Chemical group 0.000 description 1
229910052760 oxygen Inorganic materials 0.000 description 1
239000001301 oxygen Substances 0.000 description 1
QYZLKGVUSQXAMU-UHFFFAOYSA-N penta-1,4-diene Chemical compound C=CCC=C QYZLKGVUSQXAMU-UHFFFAOYSA-N 0.000 description 1
235000020030 perry Nutrition 0.000 description 1
125000000951 phenoxy group Chemical group [H]C1=C([H])C([H])=C(O*)C([H])=C1[H] 0.000 description 1
125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 1
229910052698 phosphorus Inorganic materials 0.000 description 1
239000011574 phosphorus Substances 0.000 description 1
230000000704 physical effect Effects 0.000 description 1
229920003023 plastic Polymers 0.000 description 1
239000004033 plastic Substances 0.000 description 1
239000002574 poison Substances 0.000 description 1
231100000614 poison Toxicity 0.000 description 1
239000002685 polymerization catalyst Substances 0.000 description 1
229920000346 polystyrene-polyisoprene block-polystyrene Polymers 0.000 description 1
230000000135 prohibitive effect Effects 0.000 description 1
125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
238000010926 purge Methods 0.000 description 1
239000012429 reaction media Substances 0.000 description 1
238000001175 rotational moulding Methods 0.000 description 1
230000035945 sensitivity Effects 0.000 description 1
238000000926 separation method Methods 0.000 description 1
229920006300 shrink film Polymers 0.000 description 1
229910052710 silicon Inorganic materials 0.000 description 1
239000010703 silicon Substances 0.000 description 1
125000003808 silyl group Chemical group [H][Si]([H])([H])[*] 0.000 description 1
238000001374 small-angle light scattering Methods 0.000 description 1
230000003381 solubilizing effect Effects 0.000 description 1
238000004611 spectroscopical analysis Methods 0.000 description 1
150000003440 styrenes Chemical class 0.000 description 1
229910052717 sulfur Inorganic materials 0.000 description 1
239000011593 sulfur Substances 0.000 description 1
239000000454 talc Substances 0.000 description 1
229910052623 talc Inorganic materials 0.000 description 1
125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 description 1
238000010998 test method Methods 0.000 description 1
229920006029 tetra-polymer Polymers 0.000 description 1
229910052718 tin Inorganic materials 0.000 description 1
150000003608 titanium Chemical class 0.000 description 1
XJDNKRIXUMDJCW-UHFFFAOYSA-J titanium tetrachloride Chemical compound Cl[Ti](Cl)(Cl)Cl XJDNKRIXUMDJCW-UHFFFAOYSA-J 0.000 description 1
150000005671 trienes Chemical class 0.000 description 1
125000000026 trimethylsilyl group Chemical group [H]C([H])([H])[Si]([*])(C([H])([H])[H])C([H])([H])[H] 0.000 description 1
238000007666 vacuum forming Methods 0.000 description 1
150000003681 vanadium Chemical class 0.000 description 1
150000003682 vanadium compounds Chemical class 0.000 description 1
239000012808 vapor phase Substances 0.000 description 1
125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 1
229920002554 vinyl polymer Polymers 0.000 description 1
239000003643 water by type Substances 0.000 description 1
239000002759 woven fabric Substances 0.000 description 1
150000003755 zirconium compounds Chemical class 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J19/24—Stationary reactors without moving elements inside
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J19/24—Stationary reactors without moving elements inside
- B01J19/2415—Tubular reactors
- B01J19/2425—Tubular reactors in parallel
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J19/24—Stationary reactors without moving elements inside
- B01J19/2415—Tubular reactors
- B01J19/2435—Loop-type reactors
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J19/24—Stationary reactors without moving elements inside
- B01J19/245—Stationary reactors without moving elements inside placed in series
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J19/24—Stationary reactors without moving elements inside
- B01J19/2455—Stationary reactors without moving elements inside provoking a loop type movement of the reactants
- B01J19/2465—Stationary reactors without moving elements inside provoking a loop type movement of the reactants externally, i.e. the mixture leaving the vessel and subsequently re-entering it
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F10/02—Ethene
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2/00—Processes of polymerisation
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J2219/00049—Controlling or regulating processes
- B01J2219/00051—Controlling the temperature
- B01J2219/00074—Controlling the temperature by indirect heating or cooling employing heat exchange fluids
- B01J2219/00076—Controlling the temperature by indirect heating or cooling employing heat exchange fluids with heat exchange elements inside the reactor
- B01J2219/00085—Plates; Jackets; Cylinders
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J2219/00049—Controlling or regulating processes
- B01J2219/00051—Controlling the temperature
- B01J2219/00074—Controlling the temperature by indirect heating or cooling employing heat exchange fluids
- B01J2219/00087—Controlling the temperature by indirect heating or cooling employing heat exchange fluids with heat exchange elements outside the reactor
- B01J2219/00103—Controlling the temperature by indirect heating or cooling employing heat exchange fluids with heat exchange elements outside the reactor in a heat exchanger separate from the reactor
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J2219/00049—Controlling or regulating processes
- B01J2219/00051—Controlling the temperature
- B01J2219/00159—Controlling the temperature controlling multiple zones along the direction of flow, e.g. pre-heating and after-cooling
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J2219/00049—Controlling or regulating processes
- B01J2219/00162—Controlling or regulating processes controlling the pressure
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J2219/00049—Controlling or regulating processes
- B01J2219/00168—Controlling or regulating processes controlling the viscosity
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J2219/00761—Details of the reactor
- B01J2219/00763—Baffles
- B01J2219/00765—Baffles attached to the reactor wall
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F110/02—Ethene
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers

Landscapes

Chemical & Material Sciences (AREA)
Organic Chemistry (AREA)
Chemical Kinetics & Catalysis (AREA)
Health & Medical Sciences (AREA)
Medicinal Chemistry (AREA)
Polymers & Plastics (AREA)
Polymerisation Methods In General (AREA)
Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

AU24332/97A 1996-04-01 1997-04-01 Olefin solution polymerization Ceased AU714023B2 (en)

Applications Claiming Priority (5)

Application Number	Priority Date	Filing Date	Title
US1469696P	1996-04-01	1996-04-01
US1470596P	1996-04-01	1996-04-01
US60/014705		1996-04-01
US60/014696		1996-04-01
PCT/US1997/005420 WO1997036942A1 (fr)	1996-04-01	1997-04-01	Polymerisation en solution d'olefines

Publications (2)

Publication Number	Publication Date
AU2433297A AU2433297A (en)	1997-10-22
AU714023B2 true AU714023B2 (en)	1999-12-16

Family

ID=26686392

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
AU24332/97A Ceased AU714023B2 (en)	1996-04-01	1997-04-01	Olefin solution polymerization

Country Status (16)

Country	Link
EP (1)	EP0891381B2 (fr)
JP (1)	JP3334082B2 (fr)
KR (1)	KR100450855B1 (fr)
CN (1)	CN1152062C (fr)
AT (1)	ATE210688T1 (fr)
AU (1)	AU714023B2 (fr)
BR (1)	BR9708493A (fr)
CA (1)	CA2250763C (fr)
CZ (1)	CZ316498A3 (fr)
DE (1)	DE69709076T3 (fr)
ES (1)	ES2165049T5 (fr)
HU (1)	HUP9901742A3 (fr)
PL (1)	PL329192A1 (fr)
RU (1)	RU2190627C2 (fr)
TR (1)	TR199801973T2 (fr)
WO (1)	WO1997036942A1 (fr)

Families Citing this family (69)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
KR20010052195A (ko)	1998-03-04	2001-06-25	엑손 케미칼 패턴츠 인코포레이티드	폴리올레핀 중합체 분산액을 제조하기 위한 생성물 및 방법
US6319998B1 (en)	1998-03-04	2001-11-20	Exxon Mobil Chemical Patents Inc.	Method for making polymer blends by using series reactors
US6329477B1 (en)	1998-03-04	2001-12-11	Exxonmobil Chemical Patents Inc.	Method for increasing diene conversion in EPDM type polymerizations
US7268194B2 (en)	1998-03-20	2007-09-11	Exxonmobil Chemical Patents Inc.	Continuous slurry polymerization process and apparatus
US20020111441A1 (en)	1998-03-20	2002-08-15	Kendrick James Austin	Continuous slurry polymerization volatile removal
US6281300B1 (en)	1998-03-20	2001-08-28	Exxon Chemical Patents, Inc.	Continuous slurry polymerization volatile removal
KR100531628B1 (ko)	1998-03-20	2005-11-29	엑손모빌 케미칼 패턴츠 인코포레이티드	연속적인 슬러리 중합반응의 휘발물질 제거
US6858188B2 (en) *	2003-05-09	2005-02-22	Texas Petrochemicals, Lp	Apparatus for preparing polyolefin products and methodology for using the same
KR100349071B1 (ko)	2000-02-02	2002-08-14	삼성종합화학주식회사	생성물 순환 방식을 이용한 신디오탁틱 스티렌계 중합체의제조방법
US6455638B2 (en)	2000-05-11	2002-09-24	Dupont Dow Elastomers L.L.C.	Ethylene/α-olefin polymer blends comprising components with differing ethylene contents
AU2002238109B2 (en) *	2002-02-19	2007-12-06	Chevron Phillips Chemical Company Lp	Continuous slurry polymerization process and apparatus
ES2291668T3 (es) *	2002-09-23	2008-03-01	Total Petrochemicals Research Feluy	Reactor de poliolefina de bucle de suspension.
US7541402B2 (en)	2002-10-15	2009-06-02	Exxonmobil Chemical Patents Inc.	Blend functionalized polyolefin adhesive
US7700707B2 (en)	2002-10-15	2010-04-20	Exxonmobil Chemical Patents Inc.	Polyolefin adhesive compositions and articles made therefrom
WO2004046214A2 (fr)	2002-10-15	2004-06-03	Exxonmobil Chemical Patents Inc.	Systeme catalyseur multiple pour la polymerisation d'olefines et polymeres ainsi produits
US7223822B2 (en)	2002-10-15	2007-05-29	Exxonmobil Chemical Patents Inc.	Multiple catalyst and reactor system for olefin polymerization and polymers produced therefrom
US7550528B2 (en)	2002-10-15	2009-06-23	Exxonmobil Chemical Patents Inc.	Functionalized olefin polymers
DE10310091A1 (de)	2003-03-06	2004-09-16	Abb Lummus Global Gmbh	Segmentierter Rührreaktor
EP1564222A1 (fr) *	2004-02-13	2005-08-17	Total Petrochemicals Research Feluy	Production de polyoléfines avec une concentration élevée en oléfines
MXPA06010713A (es)	2004-03-19	2006-12-15	Dow Global Technologies Inc	Capas de pelicula hechas de formulaciones de polimero.
US7790826B2 (en)	2004-05-06	2010-09-07	DowGlobal Technologies Inc.	Polymer molding compositions
JP2008510872A (ja) *	2004-08-23	2008-04-10	エクソンモービル・ケミカル・パテンツ・インク	重合プロセス用装置
EP1802699B1 (fr) *	2004-10-13	2011-07-27	ExxonMobil Chemical Patents Inc.	Compositions elastomeres issues de melange de reacteur
TWI426089B (zh) *	2005-09-15	2014-02-11	Dow Global Technologies Llc	具受控嵌段序列分布之催化烯烴嵌段共聚物
ES2788060T3 (es)	2006-09-21	2020-10-20	Union Carbide Chem Plastic	Método de control de propiedades en sistemas multimodales
DE102008000432A1 (de) *	2008-02-28	2009-09-03	Evonik Röhm Gmbh	Rührkesselreaktor sowie Verfahren zur Durchführung einer Polymerisationsreaktion unter Verwendung eines solchen Rührkesselreaktors
RU2405001C2 (ru) *	2009-02-25	2010-11-27	Андрей Иванович Брункин	Способ получения (со)полимеров при фазовых переходах сверхкритических флюидов и устройство для его проведения
BRPI0923985B1 (pt)	2009-03-31	2019-10-08	Dow Global Technologies Llc	Película multicamada e artigo fabricado
WO2011011427A1 (fr) *	2009-07-23	2011-01-27	Univation Technologies, Llc	Système réactionnel de polymérisation
US9546446B2 (en)	2009-10-23	2017-01-17	Toyo Boseki Kabushiki Kaisha	Highly functional polyethylene fibers, woven or knit fabric, and cut-resistant glove
US20110182134A1 (en)	2010-01-22	2011-07-28	Dow Global Technologies Inc.	Mixing system comprising an extensional flow mixer
WO2011109465A2 (fr) *	2010-03-05	2011-09-09	H R D Corporation	Système à cisaillement élevé et procédé pour la production de paraffines halogénées et/ou sulfonées
WO2011163025A1 (fr)	2010-06-24	2011-12-29	Dow Global Technologies Llc	Module dispositif électronique comprenant un copolymère de polyalcène hétérogène et optionnellement du silane
BR112013022589A2 (pt)	2011-03-08	2016-12-06	Dow Global Technologies Llc	processo para reciclar solvente e sistema para reciclar solvente
EP2742995A1 (fr) *	2012-12-11	2014-06-18	Construction Research & Technology GmbH	Procédé continu de fabrication de copolymères
JP5998071B2 (ja) *	2013-01-31	2016-09-28	住友化学株式会社	連続重合装置、重合体組成物の製造方法およびインジェクションバルブ
KR20200096700A (ko) *	2013-07-09	2020-08-12	다우 글로벌 테크놀로지스 엘엘씨	개선된 펠렛 유동능을 갖는 에틸렌/알파-올레핀 인터폴리머
DE102013215664A1 (de) *	2013-08-08	2015-02-12	Evonik Industries Ag	Apparatur zur Durchführung eines ringöffnenden Polymerisationsverfahrens
KR101770099B1 (ko) *	2014-06-25	2017-08-21	바젤 폴리올레핀 게엠베하	개선된 열교환기 성능을 갖는 에틸렌 중합 방법
EP2995631A1 (fr)	2014-09-12	2016-03-16	Borealis AG	Procédé de production de copolymères greffés à un squelette de polyoléfine
EP3023450B1 (fr)	2014-11-21	2017-07-19	Borealis AG	Procédé de production de pastilles de copolymères mous
EP3307793B1 (fr)	2015-06-15	2018-10-24	Basell Polyolefine GmbH	Installation de polymérisation présentant des canaux de refroidissement parallèles dans une connexion de recyclage
CN106699949B (zh) *	2015-07-23	2019-12-24	中国石油化工股份有限公司	一种乙烯-α烯烃-非共轭二烯烃聚合物及其制备方法
CN106366226B (zh) *	2015-07-23	2019-11-12	中国石油化工股份有限公司	一种过渡金属催化剂组合物及其应用
KR102034973B1 (ko)	2015-09-29	2019-10-21	엑손모빌 케미칼 패턴츠 인코포레이티드	스파이럴 열교환기를 사용하는 중합
WO2017108963A1 (fr)	2015-12-21	2017-06-29	Borealis Ag	Procédé de récupération d'hydrocarbures dans un processus de polymérisation en solution
EP3243622B1 (fr)	2016-05-13	2020-09-09	Borealis AG	Procédé de transport hydraulique de granulés de polyoléfine
EP3463859B2 (fr)	2016-06-03	2025-03-26	Borealis AG	Structure multicouche
CN109601004B (zh) *	2016-06-30	2022-08-09	陶氏环球技术有限责任公司	乙烯/α-烯烃/多烯互聚物以及含有其的组合物
KR102359834B1 (ko) *	2016-07-06	2022-02-07	이네오스 유럽 아게	중합 방법
US11346047B2 (en)	2017-01-04	2022-05-31	Columbia Insurance Company	Carpets having an improved delamination strength and fluid barrier properties and methods of making same
US10029230B1 (en)	2017-01-24	2018-07-24	Chevron Phillips Chemical Company Lp	Flow in a slurry loop reactor
CA2969280C (fr)	2017-05-30	2023-12-12	Nova Chemicals Corporation	Procede de polymerisation non adiabatique a deux phases (liquide-liquide)
CA3067766C (fr)	2017-06-29	2022-08-16	Borealis Ag	Procede de reduction de l'entrainement de polymere dans la phase liquide pauvre en polymere dans un separateur
SG11202003567UA (en)	2017-12-04	2020-06-29	Borealis Ag	A method of recovering olefins in a solution polymerisation process
EP3720887A1 (fr)	2017-12-04	2020-10-14	Borealis AG	Procédé de récupération d'oléfines dans un procédé de polymérisation en solution
BR112020024095B1 (pt)	2018-05-31	2023-10-17	Dow Global Technologies Llc	Sistema para polimerização em solução, e, método
ES3008277T3 (en)	2018-05-31	2025-03-21	Dow Global Technologies Llc	Devolatilizer design
EP3947480A1 (fr) *	2019-04-05	2022-02-09	ExxonMobil Chemical Patents Inc.	Produit polymère à large distribution de poids moléculaire issu de réacteurs en boucle à gradients thermiques intentionnels
US11434309B2 (en)	2019-04-05	2022-09-06	Exxonmobil Chemical Patents Inc.	Controlling molecular weight distribution and chemical composition distribution of a polyolefin product
CN113646074B (zh) *	2019-04-05	2023-05-09	埃克森美孚化学专利公司	控制聚烯烃产物的分子量分布和化学组成分布
US11530279B2 (en)	2019-04-05	2022-12-20	Exxonmobil Chemicals Patents Inc.	Broad molecular weight distribution polymer product from loop reactors with intentional thermal gradients
ES2881354T3 (es)	2019-05-17	2021-11-29	Borealis Ag	Estructura de múltiples capas
CN114080400A (zh)	2019-07-08	2022-02-22	博里利斯股份公司	聚合方法
KR102462535B1 (ko) *	2019-10-17	2022-11-01	주식회사 엘지화학	올리고머 제조 장치
RU2748112C1 (ru) *	2020-09-11	2021-05-19	Публичное акционерное общество "Нефтяная компания "Роснефть" (ПАО "НК "Роснефть")	Способ получения лиганда 1-фенилэтан-1,2-диола прекатализатора для синтеза каучуков СКЭПТ/СКЭП
US20240002552A1 (en)	2020-12-08	2024-01-04	Borealis Ag	Polymerization Process and Arrangement
CN115141301B (zh) *	2022-08-08	2023-07-25	上海交通大学	一种生产聚烯烃的溶液聚合方法
CN117343226B (zh) *	2023-12-04	2024-04-09	万华化学集团股份有限公司	一种乙烯/α-烯烃共聚物及其应用

Family Cites Families (8)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US3242150A (en) *	1960-03-31	1966-03-22	Phillips Petroleum Co	Method and apparatus for the recovery of solid olefin polymer from a continuous path reaction zone
GB1509008A (en) *	1975-07-08	1978-04-26	Dart Ind Inc	Elongated reactor for conducting exothermic chemical reactions and method
US5565175A (en) *	1990-10-01	1996-10-15	Phillips Petroleum Company	Apparatus and method for producing ethylene polymer
DE4120203A1 (de) *	1991-06-19	1992-12-24	Basf Ag	Verfahren zur herstellung von schlagzaehem polystyrol
RU2053014C1 (ru) *	1991-09-30	1996-01-27	Филлипс Петролеум Компани	Устройство для получения этиленового полимера и способ получения этилового полимера
US5286884A (en) *	1992-07-24	1994-02-15	Texaco Chemical Company	Thermosyphonic reaction of propylene with tertiary butyl hydroperoxide and reactor
TW322495B (fr) *	1992-12-15	1997-12-11	Hoechst Ag
WO1995010548A1 (fr) *	1993-10-15	1995-04-20	Fina Research S.A.	Procede de production de polyethylene a large repartition de poids moleculaire

1997
- 1997-04-01 EP EP97920040A patent/EP0891381B2/fr not_active Expired - Lifetime
- 1997-04-01 CA CA002250763A patent/CA2250763C/fr not_active Expired - Lifetime
- 1997-04-01 KR KR10-1998-0707868A patent/KR100450855B1/ko not_active Expired - Lifetime
- 1997-04-01 AU AU24332/97A patent/AU714023B2/en not_active Ceased
- 1997-04-01 CZ CZ983164A patent/CZ316498A3/cs unknown
- 1997-04-01 BR BR9708493A patent/BR9708493A/pt not_active IP Right Cessation
- 1997-04-01 HU HU9901742A patent/HUP9901742A3/hu unknown
- 1997-04-01 ES ES97920040T patent/ES2165049T5/es not_active Expired - Lifetime
- 1997-04-01 RU RU98119840/04A patent/RU2190627C2/ru active
- 1997-04-01 JP JP53556497A patent/JP3334082B2/ja not_active Expired - Lifetime
- 1997-04-01 WO PCT/US1997/005420 patent/WO1997036942A1/fr not_active Ceased
- 1997-04-01 CN CNB971947791A patent/CN1152062C/zh not_active Expired - Lifetime
- 1997-04-01 TR TR1998/01973T patent/TR199801973T2/xx unknown
- 1997-04-01 PL PL97329192A patent/PL329192A1/xx unknown
- 1997-04-01 AT AT97920040T patent/ATE210688T1/de not_active IP Right Cessation
- 1997-04-01 DE DE69709076T patent/DE69709076T3/de not_active Expired - Lifetime

Also Published As

Publication number	Publication date
BR9708493A (pt)	1999-08-03
JP2000507634A (ja)	2000-06-20
EP0891381A1 (fr)	1999-01-20
CA2250763C (fr)	2004-01-27
AU2433297A (en)	1997-10-22
RU2190627C2 (ru)	2002-10-10
CZ316498A3 (cs)	1999-05-12
ES2165049T5 (es)	2007-02-16
CA2250763A1 (fr)	1997-10-09
PL329192A1 (en)	1999-03-15
KR20000005193A (ko)	2000-01-25
KR100450855B1 (ko)	2004-11-16
JP3334082B2 (ja)	2002-10-15
ES2165049T3 (es)	2002-03-01
DE69709076D1 (de)	2002-01-24
CN1152062C (zh)	2004-06-02
HUP9901742A3 (en)	2000-04-28
DE69709076T2 (de)	2002-05-02
EP0891381B2 (fr)	2006-05-24
DE69709076T3 (de)	2007-02-15
WO1997036942A1 (fr)	1997-10-09
EP0891381B1 (fr)	2001-12-12
ATE210688T1 (de)	2001-12-15
CN1219178A (zh)	1999-06-09
HUP9901742A2 (hu)	1999-08-30
TR199801973T2 (xx)	1998-12-21

Legal Events

Date	Code	Title	Description
2000-04-13	FGA	Letters patent sealed or granted (standard patent)

Publication	Publication Date	Title
AU714023B2 (en)	1999-12-16	Olefin solution polymerization
US5977251A (en)	1999-11-02	Non-adiabatic olefin solution polymerization
US6319989B1 (en)	2001-11-20	Broad MWD, compositionally uniform ethylene interpolymer compositions, process for making the same and article made therefrom
EP0898585B1 (fr)	2002-01-30	Composition polyolefinique presentant un poids moleculaire maximum dans sa partie ayant la teneur la plus elevee en comonomeres
AU713324B2 (en)	1999-11-25	Ethylene polymers having enhanced processability
EP1124868B1 (fr)	2004-11-17	Production d'un polyethylene multimodal
US6469103B1 (en)	2002-10-22	Narrow MWD, compositionally optimized ethylene interpolymer composition, process for making the same and article made therefrom
CN100535019C (zh)	2009-09-02	聚合监视和选择先行指标的方法
WO2001009200A1 (fr)	2001-02-08	Ameliorations relatives a des polymeres
KR20010080925A (ko)	2001-08-25	전단시닝 에틸렌／α―올레핀 인터폴리머 및 그의 제조 방법
JPH01501556A (ja)	1989-06-01	不飽和エチレンポリマー
AU744972B2 (en)	2002-03-07	Broad mwd, compositionally uniform ethylene interpolymer compositions, process for making the same and article made therefrom
US20210246288A1 (en)	2021-08-12	Bimodal ethylene-based polymers having high molecular weight high density fractions
WO2019241518A1 (fr)	2019-12-19	Films soufflés comprenant des polymères à base d'éthylène bimodaux ayant des fractions de haute densité de poids moléculaire élevé
JP3822633B2 (ja)	2006-09-20	ポリオレフィンの製造方法
CN111886262A (zh)	2020-11-03	喷雾干燥的二茂锆催化剂体系
JP3660067B2 (ja)	2005-06-15	ポリエチレン組成物
AU579446B2 (en)	1988-11-24	Molecular weight distribution modification
EP2470573A1 (fr)	2012-07-04	Procédés pour préparer des produits de polyoléfine ayant différentes propriétés de fluidification par cisaillement et trouble
TW201725179A (zh)	2017-07-16	以塞流反應器合成用於ast離線齊格勒－納塔(zn)催化劑之二氯化鎂撐體
KR100490509B1 (ko)	2005-09-30	공단량체함량이가장높은부분에서분자량이최대인폴리올레핀조성물